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ACUTE TOXICITY TO AQUATIC INVERTEBRATES (COROPHIUM VOLUTATOR) TEST SUBSTANCE Identity:A mixturecontainingperfluorooctanesulfonatweh,ich may also be referredto as PFOS, FC-95, or as a component of FC-203. (1Octanesulfoniaccid)(CAS # 2795-39-3). Remarks: The 3M productionlotnumber was not noted.The testsample isFC-203. Currentinformationindicatesitisa mixtureof 1.34% PFOS, 35% diethyleneglycolbutylether,37.85% water,20% ethyleneglycol,2.66 % Sultonefoamer,3% sodium octylsulfate0,.1% sodium laurylsulfatea,nd 0.05% tolyltriazole. The followingsummary applies to a mixture with incompletely characterizedconcentrations of impurities.Data may not accurately reflecttoxicityof the fluorochemical component of the testsample. METHOD: Method: ASTM El 367-90,Standard guide forconducting10 day static sediment toxicittyestswith marine and estuarinesediments. Type: Acute static GLP: No Year completed: 2000 Species: Corophium volutator Supplier: Not given. Analyticalmonitoring: pH and dissolvedoxygen Exposure period: 10 days Test organism age: Adults Statisticamlethod: LC50 valuescalculatebdy PROBIT analysisN,ational Swedish EnvironmentalProtectionBoard (Version2.3,1990). Calculatioonf NOEC by single-factoArNOVA followedby Bonferronisprocedure. Test conditions: Dilutionwater: Naturalseawater (34 ppt salinityf)rom an unpolluted siteinByfjorden,outsideof Stavanger,Norway. Sediment collectedat an unpollutedsite.The sediment isa muddy sand an had an organic fractionof0.7% and a silftractionof0.8%. Dilutionwater chemistry: Not given. Lighting: Not given. Stock and testsolutionpreparation:Each testconcentrationwas prepared by adding the testsample to600 g damp sediment and 200 mL ofseawater, then shaken for3 hours. The sediment was splitintothreesub-samples,with an overlayof400 mL seawater added to each and aeratedovernightpriorto study initiation. Exposure vessels: 600 mL glass beakers containing200 g of testsediment and 400 mL of seawater withcontinuousaeration. Number ofreplicate3s: Number oforganismsperreplicat1e0: Number ofconcentrationfso:urplusa blanckontrol Waterchemistrdyuringthestudy: pH range(0-1d0ays): 7.7- 8.1(contreoxlposure) 8.0- 8.1(3060mg/kg exposure) Temperature range: 15 1 OC Dissolvedoxygen range (0-10days): 91 - 94 % (controelxposure) 74 - 97 % (3060mg/kg exposure) RESULTS Nominal concentrations:Bk control9,1.1,501,1030,and 3060 mg/kg (dry weight). Element values: 10-dayLC50= >3060 mg/kg (sedimentdryweight) 10-dayNOEC = 3060 mg/kg (sedimentdryweight) Element valuesbased on nominalconcentrations Remarks: Testingwas conductedon the mixtureas describedintheTest Substance Remarks field.The valuesreportedapplytothatmixtureand not the fluorochemicaplroportioanlone. CONCLUSIONS The FC-203 10-day LC5owas determinedtobe >3060 mg/kg (sedimentdry weight).The 10-day No Observed EffectConcentration(NOEC) was 3060 mg/kg (sedimentdryweight). Validitcyriterifaulfillaendd referencesubstancewas inthenormal range. Submifter: 3M Company, EnvironmentalLaboratory,P.O. Box 33331, St. Paul,Minnesota,55133 DATA QUALITY ReliabilityK:limischranking= 2.Thisstudy meets thecriterifaorquality testing.However, sample puritwyas notproperlycharacterizeadnd the study lacksanalyticaclonfirmatioonf theamount offluorochemicaplroportioninthe solution. REFERENCES Test was conducted by RF Rogaland Research,ofStavanger,Norway atthe requestof 3M Norge,Lab referencenumber 99312-2,2000. OTHER Last changed: 6/27/00 99312-2 na A 4G W. PC"$ ROGALAND RESEARCH "FC-203 LightWater Brand AFFF tv Toxicitytests Report RF-2000/002 Lab. ref.no.: 99312-2 No. ofpages: 31 ISBN: Author: ElinHorve Client(s): 3M Norge Distributornestriction: VersionNo. date: Vers.I /06.ol 2000 Research Program: Open from(date): Summary: The followingtestresultswere obtained with"FC@-203Ught Water Brand AFFF" Toxicity:Skeletonema costatum Acartfatonsa Corophium volutator 72 h EC, 48 h LCBD 10 d LCSD (mgA): 62 (mgA) : 200 (mg/kgdryweight): >3060 Theresultsrelatetothe product as suppliedby Novatech. Key-words: ToxicityS,keletonemacostatum,Acartiatonsa,Corqphium volutator. No parotfthisdocument may be reproduced inany formwithoutpermissioninwritinbgy RF -Rogaland Research 0. tStudy4iredor lngerUsa Andersen iDrRF - Rogaland Research Kire Netiand Lat)-rei-lio.: 99312-2 page uj),I CONTENTS: 1.PRFFAC F.................................................................... 2.TEST FOR To)ucrry wrrh SKELETOJVEMA COSTA Tum ...............................4........... 3.TEST FOR TOMCITY wrrh ACARYYA TONS@4 ....................................................1.0............... 4.TEST FOR TO)UCrrY WITH COROPHIUM VOLUTATOR ........................................1.5.............. 5. DATA SBEET(S) ......................................................................2.0............. 99312-2 PREFACE: Ecotoxicologtiecsatlwsereperfor7noendwFC-203LightWaterBrandAFFF inagreementwith Novatech. The sampleisa concentrattehatnormallywillbe usedina 3% solution.Testswere conductedinaccordancewiththe"Har?nonisedOffshoreChemicalNotificatioFnormat" (OSPAR COM 1995 /SFT 1998). Theprojectwas carriedoutat RF -Rogaland Researchfor3MNorge. Allthetestswere performedby RF -Miljolab.Studydirectowras SeniorEngineerIngerLisaAndersen. The testresultasrepresentedinseparatesections.Yhe resultrselatetotheproductas supplied byNovatech. Thistestreportisissuedby a laboratorayccreditebdy Norwegian Accreditatio(nNA). The.accreditatiosntatesthatthelaboratormyeetstheNA requirementsconcerningcompetence, equipmentand workingproceduresforallthetestmethodscontainedintheaccreditation. Italsostatesthatthelaboratoryhasa satisfactoqruyalityassurancesystem,which includes internaqlualitycontrolschemes,participatioininterlaboratocroymparisons,and theuseof certifierdeferencematerialsand secondaryreferencematerials. The testpserformedarecoveredby theaccreditation. Y7zistestreportmay notbe reproducedinanyform otherthaninfullw,ithoutthepermissionin writingby RF -Miljolab. TEST FOR ToxiciTy Marinealga:Skeletonemcaostatum I'al)C./1.I,U.. 99312-2 I uj J, TESTREPORT GROWTH INH113MON ALGA Skeletonema TEST WITH THE MARINE costatum na 4G W. PM& ROGALAND RESEARCH TEST SUBSTANCE: "FC-203 Light Water Brand AFFF" TEST RESULT: The 72 hours EC50 was calculatetdo 62 mg/l. The testsubstancewas suppliedby Novatech, and thetestresultsrelatetothisproduct. TEST DETAELS: METHOD: NS-EN ISO 10253, 1998:Water quality-Marine algalgrowth inhibitiotnest withSkeletonemacostatumand Phaeodactylum thcornutum. TEST ORGANISM: Skeletonemacostatum,strainNWA BAC 1. A stockcultureofthetest organismiskept atRF - Rogaland Research. PREPARATIONS: Naturalseawater(salinity3:4 %o) fiom an unpollutedsiteinBAord was used asbasisforthe growth medium. The waterwas filteretdhrougha GF/C filter, and brieflyheatedto about75*C priorto use. The seawaterwas enrichedwith nutrientasccordingto ISO 10253,and recommendations from theParis Commission. Testsolutionwsere preparedfrom a stocksolution.A stocksolutioonf 500.8 mg/iwas preparedby stining0.5008grams oftheproductinI litroefgrowth medium. Otherconcentrationwsere preparedfrom thisstocksolution. INCUBATION: Testculturesof 50 ml were incubatedin 100 ml flat-bottomefdlaskson an orbitalshaker,3 replicatefsoreach concentrationT.estcultureswere moculatedtoabout 2000 cells/mflrom an exponentially owing moculum culture. The testwas run under continuouslight(> 50 Wm -sek)from fluorescenttubesofuniversalnaturalwhiteqW, ata temperatureof20 * 20C. The testwas run forabout 72 hours,and subsainpleosf 5 ml were takenfrom thetestflaskseach day forgrowth measurements.Algal growth was measured by fluorescence.pH measurements were performed as indicatedon datasheet. Lab.i-efiio.: 99312-2 Page6 of31 DATA ANALYSIS: CALCULATIONS: Growthratewserecalculatbeydloglinearregressioonnbiomas(sfluorescence) versustime,as describedinNS-EN ISO 10253. E,C5o: The inhibitoryeffecton the growth of Skeletonema costatum isexpressed as the concentratioonfa productgiving50% reductionof growth rate(E,,C5o)T.his effecctoncentratioannd the95% confidencelimitwere calculatedby theuse of thecomputerprogranuneTOXEDO developedby VKI (Denmark),assuming a logarithmincormal distributiofndata.The programme alsocalculateconcen- trationisnhibitinggrowth rate10% and 90% (EC Io and F-,Cgo). NOEC: CalculatioonfNOEC (No ObservedEffectConcentrationi)sdone by singlefactorANOVA followedby Bonferronisprocedureforcomparing each concentratiomnean with thecontrolmean. TEST RESULTS: COMNffiNTS: VALIDATION: Table 1. EC and NOEC valuesobtainedwith Skeletonemacostatum. Testsubstance FClo Fc5o Egw "FC-203UightWater 13 (8.3-18) 62 (48-83) >100 Brand AFFF" NOEC: 32 Valuesindicateconcentrationsgiving 1001o5,001oand 9001oinhibitioonfgrowth rate. Unitsinmgl7. Valuesare calculatedby thecomputer programme TOXEDO (VKI,Denmark), and 95% confidence intervalasre indicated.NOEC are calculatedby using thecomputer programme GraphPad InStat3.0. The resultasrebased on growth ratesforthetime span 0 - 72 h,theperiod duringwhich thegrowth isconsideredtobe exponentialinthecontrolcultures (seegrowth curves). The validitcyriterigaiveninthetestprotocolarefulfilleidn,thatthecontrol celldensityincreasedby a factorof more than16 inthetestperiod (correspondintgoa growthrateofmore than0,9d7l)t,hecontrolpH did not va,ryby more than 1,0unitsduringthetestand the72 hours testresultswith 3 5-dichlorophenowlas intherangenormallyfound. Lab.ref.no.: Sample received.: Test period: Report date: 99312-2 20.09.99 04-07.10.99 06.01.2000 ElinHorve Age Molversm5@- Engineer SeniorResearch Scientist Analyticatlechnician QualityAssurance Enclosed: Data sheets Thistestreporitsissuebdy a laboratorayccreditebdy NorwegianAccreditati(oNnA).Ile repormtay notbe reproducedinany formotherthaninfullw,ithouthepermissioinnwritinbgy RF - Miljolab. 99312-2 Page7of31 PRIMARY DATA: GrowthinhibititoenstwithSkeletonemcaostatum Testsubstance:"FC-203LightWaterBrandAFFP' Lab. ref.:99312-2 Startdate: 04.10.99 Conc. unit:mgA Measurement: The biomass was measured by fluorescencev;aluesinfluorescenceunits Time: 04.10.99 05.10.99 06-10.99 07.10.99 Concentration 14:05 09:25 10:30 10:40 Growth pH pH rate Corre- atstartatend day -1 lation oftest oftest 0 0.11 0.59 9.2 56 2.39 0.998 0 0.15 0.63 7.9 59 2.14 0.997 0 0.13 0.62 9 54 2.29 0.997 8.3 8.4 0 0.14 0.63 6.4 47 2.07 0.999 0 0.14 0.62 6.3 48 2.06 0.999 0 0.12 0.71 7.1 55 -2.20 1.000 0.32 0.13 0.82 9.2 61 2.30 1.000 0.32 0.13 0.77 9.6 66 2.32 1.000 8.4 8.4 0.32 0.14 0.84 12.5 71 2.43 0.999 1 0.14 0.77 11 70 236 0.999 1 0.14 0.69 12 65 2.41 0.996 8.4 8.5 1 0.16 0.63 8.3 60 2.13 0.995 3.2 0.18 0.58 8 63 2.05 0.990 3.2 0.14 0.59 7.1 52 2.12 0.997 8.4 8.5 3.2 0.12 0.6 6.6 50 2.17 1 0.999 10 0.14 0.58 8.5 64 2.22 0.995 10 0.16 0.34 4.4 48 1.79 0.974 8.4 8.5 10 0.16 0.6 7.6 68 2.09 0.994 32 0.14 0.43 4.4 42 1.86 0.992 32 0.12 0.39 5.3 46 2.05 0.990 8.4 8.4 32 0.13 0.3 3.6 30 1.79 1 0.979 100 0.1 0.04 0.1 0.3 0.00 100 0.09 0.18 0.3 1.35 0.65 0.987 8.4 8.2 100 0.08 0.06 0.21 1.3 0.52 0.784 Referencesubstance(3,5-dhiiorophe 1): 1.5mgA 014 0.47 1.85 4.2 1.5 mgA 0 .16 0.43 1.45 3 .3 1.5 mgA 0.16 0.45 1.45 2.9 1.39 0 1.19 .9090901 8.3 8.2 1.19 0.999 Mean values: 0 0.13 0.6 8 53 0.32 0.13 0.8 10 66 1 0.15 0.7 10 65 3.2 0.15 0.6 7 55 10 0.15 0.5 7 60 32 0.13 0.4 4 39 100 0.09 0.1 0 1 Reference subst.i 0.15 0.45 1.6 3.5 2.19 2.35 2.30 2.11 2.03 1.90 0.39 1.26 0.998 1.000 0.997 0.996 0.991 0.988 0.917 The resultofthe reference substanceis 1 .000000within the rdrige normally found Lab.refno.: 99312-2 Page8of31 GROWTH CURVES: GrowthInhibititoenstWithSkeletonemacostatum Testsubstance:"FC-203LightWaterBrandAFFF" Lab. ret.:99312-2 75. 20 3 control 7- 0,32 mg/l 5. 3 .0 1 @2@X48 24 48 7-2 -3 testduratio(nhours) 75. 4D 3 1 mgfl 1 48 72 testduratio(nhours) -3 71 3,2 mgA 51 3 -1 2244 @ @2 -31 testduratio(nhours) 75. 3 E .1 -3 10 MgA 48 72 testduratio(nhours) -1 9 -3 J 24 48 72 testduratio(nhours) 75. 03 -3@@tw 32 mgfl '401 48 72. durati(otnmrs) 75S0D 3 .E1 -3 100 mgfl -A 24 2 a(h@oouurrss)) Lab-i-ef.no.: 99312-2 Page9oj-3i Inhibition of the growth of Skeletonema costatum with: mg/l (FC-203 Light Water Brand AFFF) --------------------------------------------------------------- Experimental data: ---------------------------------------------------------------------- Concentration in Growth rate FC-203 Light Water Brand AFFF Inhibition in percent ---------------------------------------------------------------------- Control 1 control 2 Control 3 Control 4 Control 5 Control 6 2.39 2.14 2.29 2.07 2.06 2.20 - Control mean 2.19 0 0.32 0.32 0.32 2.30 0.0 2.32 0.0 2.43 0.0 1.00 1.00 1.00 2.36 0.0 2.41 0.0 2.13 2.8 3.20 3.20 3.20 2.05 6.5 2.12 3.3 2.17 1.0 10.00 10.00 10.00 2.22 1.79 2.09 0.0 18.3 4.6 32.00 32.00 32.00 1.86 2.05 1.79 15.1 6.5 18.3 100.00 0.00 100.0 100.00 0.65 70.3 100.00 0.52 76.3 ---------------------------------------------------------------------- STATISTICAL PARAMETERS CALCULATED FROM CONTINUOUS RESPONSES 5 doses and 11 responses have been used during calculations. EC 10 : EC 50 : EC 90 13.33 61.95 288.00 95 % confidence limits 95 % confidence limits 95 % confidence limits 8.29 48.25 186.95 Coefficient of determination :0.763 18.46) 83.10) 562.40) Lab.refno.: 99312-2 Page10of31 TEST FOR TOXICITY Marine herbivoreA:cartitaonsa 99312-2 TEST REPORT ACUTE TO)CICITYTEST WITH THE MARINE COPEPODAcartia tonsa an W. PM& ROGALAND --SEARCH TEST SUBSTANCE: "FC-203 Light Water Brand AFFF" TEST RESULT: The 48 hoursLC5o was calculatetdo 200 mg/l. The testsubstancewas suppliedby Novatech, and thetestresultsrelateto thisproduct. TEST DETAELS: METHOD: ISO/DIS 14669 - 1997:Water quality-Determinationofacutelethaltoxicity tomarinecopepods (Copepoda,Crustacea). TEST ORGANISM: Acartiatonsa(Dana),suppliedby theMarine BiologicalLaboratory, Universityof Copenhagen. CULTIVATION: The testorganismswere suppliedas eggs,and were cultivateidn accordance withthe"ParisCommission -Ring TestProtocol"(VKI). Largecopepodites and adultswere used inthetest. PREPARATIONS: Naturalseawater(salinit3y4: %0)from anunpollutedsiteinBAord was used asbasisforthedilutiownater.The waterwas filteretdhrougha GF/C filter priortouse. Testsolutionwsere preparedfrom a stocksolution.A stocksolutionof 1003 mg/l was preparedby stirrin0g.5017grams oftheproductinI litroefdilution water.Otherconcentrationwsere preparedfrom thisstocksolution. INCUBATION: 'Me testwas run inglasscontainer(s28ml rolledrim vials)each containing 25 ml of testsolutionand 5 animals,4 replicatefsoreach concentrationT.he vialswere keptunder a 16h/8hlight/dark.photoperiaotad temperatureof 20 I *C. pH and oxygen measurementswere performedas indicatedon the data sheet. Lab.rej.-Ilo.: 99312-2 i-ageI-,oj)i DATA ANALYSIS: CALCULATIONS: Theeffecotn thesurvivoaflAcartitaonsaisexpresseadstheconcentratoifon aproductlethalto50% ofthetestanimals(LC5o).The combined mortality pertestconcentratiownere used forcalculationT.he 24 hours and 48 hours LC50 valuesand the95% confidencelimitwere calculatebdy usingthe standardprocedurePROBIT Analysis,NationalSwedish Environmental ProtectioBnoard (Version2.3,1990).Thisprogramme alsocalculatteest concentrationlsethalto 10% and 90% of thetestanimals. NOEC: CalculatioonfNOEC (No Observed EffectConcentrationi)sdone by singlefactorANOVA followedby Bonferronisprocedureforcomparing each concentratiomnean with thecontrolmean. TEST RESULTS: Table 1. LC and NOEC valuesobtainedwith "FC-203 LightWater Brand AFFF". Acartiatonsa 24 hours 48 hours LCIO Lcso Lcgo 160 (84-220) 340 (260-460) 740 (530-1400) 76 (32-110) 200 (140-270) 510 (350-1100) NOEC: 100 Yalues indicate 1001o.5001oand 90"lolethalityafter24 and 48 houm Units in m&4. calculated by PROBIT analysis, and 95% confidence intervalsare indicated. NOEC the computerprogmmme GraphPad histat 3.0. 100 Yahies are are calculated by VALIDATION: The validitcyriterigaiveninthetestprotocolarefulfilleidn,thatthedissolved oxygen concentratioanttheend of thetestwas greaterdm or equalto 4 mg/l, thepercentagemortalityinthecontrolswas lessthan10%, and the48 hours LC5o of3,5-&chlorophenol(referencew)as intherangenormallyfound. Lab.ref no.: Sample received.: Testperiod: Report date: 99312-2 20.09.99 06-08.10.99 06.01.2000 ElinHorve Age Molver.5, Engineer SeniorResearch Scieii*st Analyticatlechnician QualityAssurance Enclosed: Data sheets This testreportisissuedby a laboratoryaccreditedby Norwegian Accreditation(NA). The reportmay not be reproducedin any form otherthan in fullw,ithoutthepermissioninwritingby RF - Miljolab. 99312-2 PRIMARY DATA: AcutetoxiciteystwithAcartitaonsa Testsubstance: "FC-203LightWater BrandAFFF' Lab. ref.: Startdate: Measurement: 99312-2 06.10-99 Number ofdead Concentration (mgA) Control 10 32 100 320 1003 Total number Specimen pr.conc. 30 20 20 20 20 20 Number of specimen pr.vessel A CE BD F 5 55 5 55 5 55 5 5 55 5 5 55 5 5 55 5 555 5 NUMBER OF DEAD 24 hours ACE B DF Total 0 00 001 1 000 0 0 000 1 1 100 0 1 212 2 7 5 55 5 20 48 hours AC E B DF Total 000 101 2 0 10 0 1 001 1 2 201 1 4 3 44 3- 14 5 55 5 20 Referencesubstanc (3,5-dichlorophenol): 1.0mgA 5 55 0 20 2 54 30 555 100 3 130 15 The resuftwiththe referencesubstance iswithinthe range noffnallyfound 99312-2 Testsubstance: "FC-203 LightWater Brand AFFF" Lab.ref.: Startdate: 99312-2 06.10-1999 A#easurements of oxygen and pH. Concentration (mgA) Start Oxygen pH (mgA) 24 hours 48 hours Oxygen pH Oxygen pH (mgA) (mgA) Control 7.6 8.1 7.2 8.1 10 8.1 8.1 7.3 8.2 32 8.1 8.1 7.1 8.2 100 8.1 8.1 6.7 8.2 320 8.0 8.2 6.1 8.1 1003 7.3 8.2 6.6 8.1 Referencesubstance(3,5-dichlorophenol)- mgA 7.7 8.1 7.3 8.2 99312-2 TEST FOR TOXICITY MarineAmphipode:Corophiumvolutator Lab.i-'eiji.o.: 99312-2 Page16of31 TEST REPORT ACUTE TO)ACITY SEDIMENT TEST WITH THE MARINE AMPHIPODCorophium volutator na iG ROGALAND RESEARCH TEST SUBSTANCE: "FC-203 Light Water Brand AFFF" TEST RESULT: The 10d LC50 was calculatetdo >3060 mg kg" dry weightsediment. The testsubstancewas suppliedby Novatech,and thetestresultsrelateto thisproduct. TEST DETAILS: METHOD: ASTM E1367-90, St@mdardGuide For Conducting 10 day StaticSediment ToxicityTestswith Marine and EstuarineSediments. TEST ORGANISM: Corophium volutatorf,rom an unpollutesditenearTrondheim. CULTIVATION: The testorganismswere suppliedasadults(4-8mm insize)and were heldin aeratedseawaterat 15*C. A smallamount of naturalseaweed was used for feeding. PREPARATION: Naturalseawater(salinit3y4: %o) from an unpollutedsiteinBAorden outside Stavangerwas used fordilutiownater.Sediment collecteadtan unpollutedsite was used forpreparingtestsediments.The sedimentisa muddy sandand was analysedfororganiccontentand proportionsilftoreachtest. Each testconcentrationwas preparedby adding theproductin600 grams of damp sedimentina plasticbucket.200 ml of seawaterwas added and the bucketwas shaken for3 hours.The sedimentwas dividedintothreebeakers, 400 ml of seawaterwas added to each,and thebeakerswere aeratedover night.10 animalswere thenrandomly selectedforeachbeaker.A sampleqf thedamp sedimentwas analysedforwatercontent,and allconcentrationasre calculatedas mg kg-1sedimentdryweight. INCU13ATION: The testwas run inglasscontainers(600riiie)ach containing200 g of test' sediment,app.400 ml of seawaterand 10 animals,3 replicatefsoreach concentration.The beakerswere keptunder continuousaerationata temperatureof 15 1'C. PH and oxygen measurementswere performed as indicatedon thedatasheet. 99312-2 DATA ANALYSIS: CALCULATIONS: TheeffecotnthesurvivoaflCorophiumvolutatiosrexpressaesdtheconcentratioonfa productlethatlo50% ofthetestanimals(LC50).The combined mortalitpyertestconcentratiownere used forcalculationT.he 10 day LCso valueand the95% confidencelimitarecalculatebdy usingthe standard PROBIT AnalysisN,ationalSwedish EnvironmentalProtectioBnoard (Version 2.3,1990).Thisprogranunealsocalculatteestconcentrationlsethalto 10% and 90% of thetestanimals. NOEC: CalculatioonfNOEC (No Observed EffectConcentrationi)sdone by singlefactorANOVA followedby Bonferronisprocedureforcomparing each concentratiomnean with thecontrolmean. TEST RESULTS: Table 1. LC andNOEC valueosbtainewdith"FC-203LightWaterBrandAFFF" Corophiumvolutator 10days LCIO >3060 Lcso >3060 LC90 >3060 NOEC: 3060 Yaluesindfcate100/a5.001oand 9001olethalitayfter10 days. Unitsinmg A;f sedimentdry Y.,eight. Valuesare calculatedby PROBIT analysis.NOEC are calculatedbythe computer programme GraphPad InStat3.0. VALIDANON: The validitcyriterigaiveninthetestprotocolarefulfilleidn,thatthedissolved oxygen concentratioanttheend of thetestwas greaterthanor equalto 60 %, thepercentagemortalityinthecontrolswere lessthan 15% and a testwith Fluorantene(referencew)as intherangenormallyfound. The sedimentused isfoundtobe withinacceptedlimitsfororganiccontentand siltfraction. Table2. Characteristiocfsthesedimentusedfortesting Organiccontent(0/o) 0.7 Silftractio(n0/o) 0.8 Lab. ref no.: Sample received.: Test period: Report date: 99312-2 20.09.99 03-13.12.99 06.01.2000 ElinHorve Engineer Analyticatlechnician Age Molversmyr SeniorResearch Scientist QualityAssurance Enclosed: Data sheets This testreport isissued by a laboratoryaccredited by Norwegian Accreditation (NA). The report may not be reproduced in any form other than in full,without the permission in writing by RF - Miljolab. 99312-2 PRIMARY DATA: AcutetoxicitteystwithCorophiumvolutator Testsubstance: "FC-203LightWater BrandAFFF' Lab. ref.: Startdate: Measurement: 99312-2 03.12.99 Number ofdead Total number Number of specimen pr.vessel Concentration Specimen A C E (mg/kg dryweight) pr.conc. B D F Control 10 10 10 60 10 10 10 10 10 10 91.1 30 10 10 10 501 30 10 10 10 1030 30 10 10 10 3060 30 NUMBER OF DEAD 5 days 10 days ACE BDF Total A. C E BDF Total 000 0 00 0 2 00 2 101 2 1 00 1 102 3 Referencesubstance(fluoranthe): 10 10 10 20.3 30 322 7 The resultwiththe referencesubstance iswithintherange normallyfound Lab.refn.o.: 99312-2 Page19of31 Testsubstance: "FC-203 LightWater Brand AFFF" Lab. ref.: Startdate: 99312-2 03.12.99 Measurements of oxygen and pH. Start Concentration Oxygen pH (mg/kgdryweight) (0/0) - Control 94 8.1 5 days Oxygen pH (%) - 91 8.1 91.1 96 8.1 93 8.1 501 77 7.8 92 8.1 1030 97 8.1 93 8.1 3060 97 8.1 74 7.7 10 days Oxygen pH . (%) - 91 8.0 88 8.1 90 8.1 86 7.9 91 8.0 Reference substance (fluoranthene): -3 2o 95 8.1 90 8.17 90 8.1 Lab.ref.no.: 99312-2 Page20of31 DATA SHEETS Lab.ref.no.: 99312-2 Page21of31 HMS-DATABLAD (Selse-, MiljO- og S;-kkerhetsdatablad) Dokumentnr.% Erstatter 10-3814-0 Utgitt 08/10/97 Skrevet ut : 03/11/98 Versjon : 11/11/98 Side 06.00 1 av i: HMS-databladet er uzarbe;-det av ZA4-ljoavdelingenved 3M Norge A/S. Tele,4on: 63 84 75 00 Telefax: 63 84 17 88 -----------------------------------------------------------------------1 lD-7NTIFIKASJON AV Kj=-'Ml.'-U-%LIOEGT ANSVARLIG FI.RMA. :-----------------------------------------------------------------------lmdorter: 3M Norge A/S Handelsnavn: FC-203 LIGHT WAT'-RR BRAND AQUEOUS FILM FORMING FOAM Deklarasjons.-it-,m-,n?erro,duktregisters-@: P-nr.: 002614. Telefon, Gi-,'-'t4-nfornasjonssentralen: 22 59 13 00 ------------------------------------------------------------------------ 2 OPPLYSN7-NG-7.R OK K--7-&v@-'SSK;LkiK-zNS7-TNING. ------------------------------------------------------------------------ ln&'o--masjonom enkel-tkomponenter, faresymbol(e.-) og risikosetninger STO.TFNAV.N- CAS-nr V---KT-PROSENT -------------------------------------------------------------------- VANN 2-(2-BUTOKSYETOKSY)-ETANOL (D!7-TYLENGLYKOLMONOBUTYLET--rR) 7732-18-5 112-34-5 36 40 35 Faresymboler/risi-kosetninger: Xi; 1,2-ETANDIOL Faresymboler/risikose--ninger: xn; SYNTETISKE DETERGENTER FLUORALKYL OVR-RFLATEMTIVE STOFF-7R RR-STER AV ORGANISKE FLUORKJEMIKALIER R:36 107-21-1 R:22 Trade Secret Trade Secret Trade'Secret 20 1 -5 1 -5 Ikke kjent ------------------------------------------------------------------------ 3 VIKTIGSTE FAREMOM-rNT7R. ------------------------------------------------------------------------- Lab.ref.no.: 99312-2 Page 22 of31 FC-203 LIGHT WATER BRAND AQUEOUS PILM roplaNG ROAM Viktigste skadevirkn;-nger Helse!are: Kan irritere synene og huden. Sikkerhet: Miljo!are: Spesialavfall. ----------------------------------------------------------------------- 4 FORSTR-HJELPSTILTAK. ----------------------------------------------------------------------- Tiltak eyne: Skyll straks oynene med rikelige mengder vann. Kontakt lege um.4@.ddelbart. Ti-Itakhud: Sky!! huden med r4-keligemengder vann. Ev;s ir-i-asionen vedvareri kontaki--lege. Tilt&k inninding: Evis symp-.omerooms--Lr,.bring vedkommende bort fra eksponeringskilden.Sorg for frisk luft. Evis symptomene vedvarer, kontakt lege. Tiltak svelg;-ng: Kontakt lege u,.n;-ddelbartP.remkall brekn;-ngerkun i samrhd med med4-si-nskpersonell. Gi aldri-noe gjennom munnen t4-len bevisstlos person. -----------------------------------------------------------------------5 TILTAX VED B.RANNSLUKN"-rNG. ------------------------------------------------------------------------ Egnet brannslukningsm;ddel: P--odukte-@er et brannslukkingsmiddel. Ikke egnet brannslukn;-ngsmiddel: Eksponeringsrisiko ved brann: Forbrenningsprodukter ved bra-,in: Prosedyrer ved slukking av brann: Lab.refno.: 99312-2 Page23of31 FC-203 LIGHT WATER BRAND AQUEOUS FILH FORHING FOAH -----------------------------------------------------------------------6 TILTKK V---DUTILS---KTETUTSLIPP. --------------------------------------------------------z-------------- Personlige vernetiltak: Se vernetiltak under andre punkter i dette F"MS-databladet. Tiltak ved uzils4-k-.etutsliom: Ventiler amridet. Scill avgrenses umiddelbart. Dekk til med et absorberende ma--eriale. Smill samles opp umiddelbart. Rengior om--idetmed vann. Plasser;s i en egnet beholder med lokk. Fjern4-ngav kjem4-kalieavfall: Se punkt 13, Fjerni-ng av kjemikal;-eav-!-all.- -----------------------------------------------------------------7 :-i@OTE.RIONGG OPPBrV;@-.ATNG. ------------------------------------------------------------------------ Beti-ngelser '6or si-kker oopbevari-ng: Mi ikke lagres i om--&der hvor produk-.etkan kome i kontakt med mat eller legem;-dler. Lagres ved tempera-.ur under 49-grader cels;-us.Lagres ved -@emperaturer over 0 grader cel-sius. Hold beholderen ze@@tlukke-. nir oroduktet ;-kkeer i bruk. Uforene!4-ge mater-*-P-l-er: Vent;-I-asjon: Oppbevar embal-lasjen o& e-@ god,@ ventilert s@@ed. Sikkerhe-@s,6i!tak @-For & .1orhi-ndrebrann: Sikkerhe@@stiltak for i forh;-ndre eksidlosjon: ikkebrennbar. Sikkerhetstiltak for A forh;-ndrestatisk elek-@risitet: Forholdsregler ved bruk: Hold emballasjen te-@t lukket. Reyking -forbud-6:Under bruk av produktet kan reyking '6or&rsake forurensning av tobakken og/eller royken og farl;-ge dekomponeringsproduk-@er kan dannes. Se punkt 10, stabilitet og reaktivitet, skadelige dekomponenter. ---------------------------------7-------------------------------------1 - 8 EKSPONERINGSXONTROLL OG PERSONLIG VERNEUTSTYR. ------------------------------------------------------------------------ 99312-2 Page24of31 FC-203 LIGHT WATER BRAND AQU'-vOtIFSILM FORMING FOAM Oyevern: Unng& A f& damp, sprav eller tike i oynene. Bruk tatte vernebriller med vent,-"-er. Hindvern: Bruk egnede vernehansker av hens4iktsmessig materiale ved h&ndtering av produktez. Vernehansker av folgende materiale(r) anbef ales: Butylgurr,=;-. Annet hudvern enn hindvern: Unngi hudkontak-.. Andedrettsvern: Unng& inn&nd;-ngav luftbiret materiale. 3asert'pk konsentrasjonen av luftforurensninger ;-arbeidsatmosfaren velges en av folgende -%.ype(r)godkjent indedrettsvern: halvmaske med filter mot organiske da,-.ineorg vaskeformi-ge partikier: A/P2SL. Sve.lg4-ng: Det m& ikke sp;-ses, dr;-kkes ell---rroykes under arbei-dmed produk'@et. Vask utsat---eom--ider grundig med s&pe og vann. hendene e-@-.erhindter4-ng og for spising. Vask Anbe-zalt ventil-asjon: Evis utsugn;-ngsvent4-lasjon ;-kkeer tils-@rekkel;-g,m&-agnet godkjent Anded--eztsvern benyttes. Sorg for z;lstrekkelig ventilasjon sl;-k at da-mmkonsentzasjonene holdes under anbe,-Faite adm4-nistrat;-veno--mer og/eller kontroller spray eller t&ke. Adm. no--mer for forurensni-ng i arbe4dsatmosfare, Februar 1996: VANN (7732-18-5) A,merkni-nger: ingen ad--a.no=. 2-(2-BUTOKSYETOKSY)-r-T.kNOL / (DI-7m.YL7-.NC-LYKOLMONOBUTYLr-T-T-.(R1)12-34-5) 6-timers verdi Dom: 35 A,-Merkninger: A.-nerikansk grenseverdi anbe-4alt av produsen-@en. (Ingen norsk adm. norm). 1,2-ETANDIOL (107-21-1) 8-timers verdi pom: - (stev) 8-timers verdi mg/m3: 10 (stev) Takverdi-ppm: 25 (d=p) Takverd;- mg/m3: - (d--nz) SYNTETISKR- DETERGENT7-'.q (Trade Secret) A=erkninger: Ingen adm. norm. FLUORALKYL OV-zR.rLATEAKTIV---STOFFER (Trade Secret) Anmerkninger: Ingen adm. norm. RESTER AV ORGANISKE FLUORKJZMIKALIER.(Trade Secret) 8-timers verdi mg/m3: 0,1 Grenseverdi anbefalt,.av3M. LaD.rej.no.: 99312-2 Page 25 of31 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM ------------------------------------------------------------------------ 9 ?YSISKE OG KJEMISKE EGENSKA-DER. ------------------------------------------------------------------------ Ti!Standsfo--m, !arge, lukt: Kokepunkt/-in4-.ervall: Smelteounkt/-in%-ervall: Flanneounkt: Selvantennelighet: Eksolosjonsgrenser, nedre: Eksplosjonsgrenser, ovre: Da.-,ip-@rykk: Klar, rav4@arvet vaske. ca. 8.5 ca. loo C (Begynnende) Ikke relevant Ingen (Setaflash CC) Ikke relevant ikke relevant ikke relevant ca. 14.3 mmHg (Kalkulert v/romtemperatur) Loselighet i vann: Szes4-f;-kk vek-.: Da-motet'@het: Blandbar. ca. 1.05 (vann-1) ca. 1.21 (luft-1) (Kalkulert v/20C) Flyktige organiske -4orb4ndelser.(VOC): = 578 g/i SCAQMD v/20C. Xalkulert Forda.-noningshast4-ghet: < 1 (butylaceta@.-l) V 46skosite-%..: Ikke kjent -----------------------------------------------------------------------10 STABILITET OG Rr-A-KTIVITET. ------------------------------------------------------------------------ Forhold som skal unng&s: ma@-erialer som skal unngis: ikke kjent. Farl;-ge spaltningsprodukter: Karbonmonoksid og karbondioksid. Hydrogenfluorid. Giftige damper, gasser eller partikler. Dekomponering av bruksferdig blanding forventes ikke i representere n@en ri3ikO. Lab.refn.o.: 99312-2 Page26of31 FC-203 LIGHT WATER BRANZ)AQUEOUS FILM FOPHING FOAH Stab4-l4-telo@g reakt;-vitet: Stabilt- Farlig polymer;sasjon vil ikke forekomne. -----------------------------------------------------------------------11 OPPLYSNING7-R OM F.-77-SEF;LRE. ------------------------------------------------------------------------ Ef!ekter eyne: M4-ld eyeirritasjon: svmmtomer kan vare rodhet, hevelse, smerter og tirer. Effekter hud: Mild hud;-rri-*.asjo(net@-erlangvarig eller g:fentattkontakz): symptomer kan vare redhe-@, hevelse og kloe. Effek-L.eri-nn&ndi-"g: En enkelt ove--eksponer;-ngsom overstiger anbe'6alte administrative no--mer,kan .'oretil: ?Avirkn;-ng av sen-6ralnervesystemet: symptomer kan vare hodenine, orhet, sov-i;-ghe=,manglende koordin asjonsevne, nedsatt reaksjonsevne, sioret tale, svimmel'het og i-ekstreme tilfeller bev4-ss@lieshe'.. irritasion (evre luftve;er): symptomer kan vare sirhe@ i.nese og svelg, host4-ng og nys;-ng. 7--f-4ektesrvelg;-ng: Dyre!orsek u,@---ormted organ;-ske fluorkjem4-kalier, som finnes i del@,@eproduk-6et, v;-ser effek,@-ersom leverforstyrrelser, vekttap, manglende slovhet samt effekter som pivirker neurologi, buksoyt-@,b2.nyreog hematologi. Det foreligger ingen kjente helseeffek,@-erfor mennesker fra eksponering overfor organiske '61uorkjemikaliernilrde brukes som forutsatt og I henhold ti' veiledning. Svelging kan-fore til: Phvirkning av nyrene: symotomer kan vare redusert urinmengde, blod i urinen og ryggsmerter. Aspirasjonsnneumoni (Lungebetennelse som skyldes at frenunedlegemer kommer ned 1 lungene. En alminnelig irsak til tilstanden er o.opkast.): symplomer kan vare hosting, pustevansker, gisp4ng, hoste opp blod ;g lungebe-.ennelse som kan vare livstruend.;. Informasjon om allerg;-,overfalsomhet: Kreftfremkallende egenskaper: Lab.ref.no.: 99312-2 Page27of31 FC-203 LIGHT WATER BRAND AQUEOUS FILH FORMING FOAM Arves,@ofl&skadeligeegenskaper: Reproduksjonsskadelige egenskaper: Andre skadevirkninger, helse: Et resym* vedrerende produkte@.sgiftighet er tilgjengelig pk, foresoorsel. Dette produk@6et inneholder en eller -Flereorgan4ske fluorkjemikalier, som muligens kan absorberes og lagres i kroppen over lengre tid, enten som utgangsmolekylet eller som nedbrytningssto'6.'6e(rmetaboli-tter),og kan akkilmuleres ved gjentatte eksponeringer. Det foreligger i-ngenkjente helsee'6fekter for mennesker fra eksponering overfor organiske fluorkjemikalier n&r de brukes som .1oru-6sat-o@g i hen!-,oldtil veiledning. Forekomsten av orgar4ske fluorkjem--*kal;-eirblodet til den generelle befolkn4.ngen og underpopulasjoner som arbe;-dere, har vart publ4-sert s4-den 1970 irene. 3Ms epidemiologiske studier av egne arbeidere viser ingen skadelige e-l@'ekter. - -----------------------------------------------------------------------12 OPPLYSNINGER OM MILJO.T@LR-=. ------------------------------------------------------------------------ Pe=,sis,6ens/Biolog4-sk nedb@--y-lbarhet: De@6te produkte-6 -i-nneholderen eller flere organ4-ske fluorkjemikalier to-amuligens ikke er nedbrytbare og miljoet (persis-.en-.e). forblir Andre skadevirkn;-nger, m4-ljo: Nedbry-6,barhet: COC (Chemical Oxygen Demand) 1,1 g/g; BOD 20 dagers (Bioc^emical Oxygen Demand) BOD 20 dagers/COD = 1,00. Akvatisk giftighet: 1,1 g/g; Statisk 96 timers LC50 for fisk (Fathead minnow (Pimephales promelas)) - 750 mg/l; Statisk 96 timers LCSO for fisk (Rainbow trout mykiss)) - 1300 mg/l; Statisk 48 timers LC50 for daphnia (Water flea 1600 mg/l (1300-2100 mg/1); (Oncorhyncus (Daphnia magna)) Statisk 48 timers LC50, Amfipode (Scud (Ga=arus fasciatus)) 1100 mg/l (840-1300 mg/1); 48 timers EC50, Eastern Oyster embro-larvae (Crassastrea virginica)'- 47 mg/l (10-234 mg@1); 48 timers LC50, Common mummichog (rundulus heteroclitus) - 2500 mg/l (1700-3600 mg/1); Lab.ref.no.: 99312-2 Page28of31 FC-203 LIGHT WATER BRAND AouEous riLH PoRHiNG FOAH (360-710 mg/1); ICSO Respirasjon, Activated sludge m > 1000 mg/l; TTC (2,5,5-trifenyltetrazoliumklorid) test viste 4-ngen ensymhe=ing '6or konsentrasjoner opo t4-l-1000 mg/l. Sorg for avfallshindtering iht. gjeldende forskrifter. -----------------------------------------------------------------------13 FJERNING AV KJEMIKALIEAVFALL. ------------------------------------------------------------------------ Me'@oder!or fjerni-ngav kjemikalieavfall: Soes;-alavf-allL.ever avfall til en ofgen-.li-gqodkjent innsamler, mot@6aks- eller behandl4ngsanlegg for spes4-alav!all. Anbe@'alte av-fallsgruoper: HOVEDKATEGOR! 07: AV@--ALL FRA ORGANISK7- '--7.ROSESSER. UNDE.RKATEGOR! 07 06: Avfall fra PBDB av .4etts--.offers,ipe, rengjoringsmi-dier, desinfeksjonsm4-dler og kosmetikk. E;@-K-kode07 06 03: Malogenerte o.-gan4-skeloseml-'dler,vaskev;esker og moderlu-,.. Avfallstofalnu,=ner: 7!51 Organisk av&lall--@iedhalogen. S-zes4-ellekor,;ponenter: inneholder 4-lo-ar4@orb4-ndel-ser. -----------------------------------------------------------------------14 OPPLYSNINGT-R OM TRANSPORT. ------------------------------------------------------------------------ ADR-kiasse: S;-ffer: bokstav: margnummer: - CEFIC-kort: - UN-nummer: - ICAO-klasse: - IMDG-klasse: IMDG-side: EMS-nr.: MFAG: Lab.refno.: 99312-2 Page29of31 FC-203 LIGHT WATER BRAND AOUEOUS FILM FORMING FOAM Ovrige opplysni-nger: Ikke transport!arlig gods. -----------------------------------------------------------------------15 OPPLYSNINGER OM LOV-ZR OG rORSKRIFTER. ------------------------------------------------------------------------ Merkeeti-kel@t: Symbol(er): H7-LSES'.<ADELIG (Xn) inneholder: 2-(2-butoksyetoksy)-etanol 35% Etylenglykol 20% R-setninger: Farlig ved svelgi-ng.Kan irritere eynene og huden. S-setn4-nger: Unngi inn&nding av damo/so--oyte-@Ake. Unngh kontakt med huden og' eynene. Fir man s"@oflet i eynene; skyll straks grundig med s4@-ore mengder vann og kontakt lege. Etter hudkon-%.akt,vask-med skoe og vann. Ved svelgi-ng, kontak@-.lege omg&ende og vis denne beho;-deren eller el@iket'@enK.un til 4-ndustr;-ellbruk. Ikke k>eregnet til bruk som medi-s4-nsk u"@s%-.Yreller legem4-ddel. YL-gruppe: 00 Korr. yrkeshyg. lul-tbehov: Ovrige applysn;-nger om merkeetiketten: Ovennevn-@e merk;-ng er basert p& tidligere merkeforskrifter og v;-l vare i finne p& produktet en tid fremover. Merk4-ngen vil imidlertid erstattes av folgende merking, som er basert pl reviderte merkeforskri--4terav januar 1998. Symbol: ingen Inneholder: 2-(2-Butoksyetoksy)-etanol, 1,2-etandiol Kan irritere eynene og huden. Unng& inn&nding av damp/sproytet&ke.'Unng! kontakt med huden og oynene. Fir man stoffet i eynene; skyll sl@raks grundig med store mengder vann og kon-.akt lege. Fir man stoff pi huden, vaskes straks med store mengder sipe og vann. Ved svelging, drikk to glass vann og kontakt lege umiddelbart. YL-grumme: 00 Lab.ref.no.: 99312-2 Page30of31 rC-203 LIGHT MATER BRAND AQUEOUS FILH roRMING FOAM Spesielle lover og bestemmelser: 1. Forskri!t om u-@arbeidelse og distribusjon av Helse-, Milje- ag Sikke--hetsdatablad for farlige kjemik&14-e--2. Forskrilt om klassi.'iseringog merk;ng av farl4ge kjamikalier. 3. Forskri--4tom klassifisering, merk;-ngm.v. av stoff som kan med!ore m;-I-jofare. 4. Forskri-ft om stof46kartol.ek. S. Forskri@'t om spesi-alavfall. 6. E-@c. ------------------16 ANDP@R OPPLYSNINGER AV BETYDNING FOR B;TUXERNES SIKK-rRM---TOG HELSE. ------------------------------------------------------------------------ Anvendelseso=ide--: Filmdannende skumkonsen,--ratfor slukking av brann i hydrokarboner. Vi-kt;-gstekilde(r) ved utarbeidelsen av HMS-databladet: Datablad fra 3M General offices, S-,.Paul, Minnesota, USA. Arsak til opodateri-ng: Rele datablade&@ er revi-dert. Til.casse-@nye me.-ke- og HMS-databladforskril6ze=, fastsa--ti januar 1998. Etci Egne opplysn;-.-ger: in@'o--masjonenzi dette .=.MS-da*-abladeetr i henhold til vire nivarende onolysninger og bes@@e bonfatning ang&ende rikt;-gbruk og hkndteringen av de-@te produkte-@ urder no--male fo--hold. Enhver bruk av produktet som ;-kkeer i samsvar med dette HMS-databladet, eller som medforer bruk av produktet i kombinasjon med andre produkter eller enhver annen prosess er brukerens ansvar. Lab.ref.no.: 99312-2 Page31of31 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMIIGC;FOAH FOLGENDE PRODUKTER D-rXXr-S AV DETTE F"%JS-DATABLADET: 3M ID-nr. : XT-0008-0217-3 3H A-7FF FC-203 Brannslukningss kum Produksjon 3M ID-nr. : XF-0008-0099-5 3H Light Water 3% AFFF Fire Fighting Foam, FC-203,1000 L 3M ID-nr. : XF-0008-0070-6 3H Light Water 3% AFFF Fire Fighting Foam, PC-203, 200 L- 3M ID-nr. X'@'-0008-0069-8 3M Light Water 3% A?FF Fire ri-ght4-ng Foe-m, FC-203, 20 L