Document jgv5g0wGEO6EzMnvey8veY9b5

STATUS OF MAJOR 1982 COLORED PIGMENTS R&D PROGRAMS KARL K DIETZ 5-6-82 MAJOR 1982 COLORED PIGMENTS R&D PROGRAMS PROGRAM BUDGET 1982 MP INCENTIVE ('83-'86) ($M) LOW RHEOLOGY QA'S YT-915-D RES INATED QA'S FOR PLASTICS (XRT-891-D) 2.5 - 0.6 4,200 -2,000 540 IMPROVED CPC PRODUCTS BP-565-D XBT-579-D XBT-584-D 1.0 OTHER ORGANICS HIGH SOLIDS DISPERSIONS 0.6 2,500 2,200 KHD-1 DU P050145498 LOW RHEOLOGY QUINACRIDONES KHD-2 DUP050145499 BACKGROUND FEDERAL REGULATIONS REQUIRE REDUCED SOLVENT EMISSIONS AT AUTOMOTIVE PLANTS TREND FROM LACQUERS TO HIGH SOLID ENAMELS (HSE) INCREASED PIGMENT LOADING CHANGES CAUSE RHEOLOGY PROBLEMS OBJECTIVE DEVELOP A LINE OF PRODUCTS THAT WORK WELL IN HSE TO PROTECT AND POSSIBLY EXPAND OUR CURRENT BUSINESS KHD-3 DU P050145500 MAJOR PRODUCTS THREATENED RT-243-D, "MONASTRAL" MAGENTA-- XRT-343-D RT-233-D, "MONASTRAL,' TRANSPARENT RED B-- XRT-333-D RT-759-D, "MONASTRAL" RED Y (IN SOME SYSTEMS) -- XRT-859-D APPROACH NEW FINISHING PROCESS (RT-243-D, RT-233-D) ACETONE MILLING - HIGH INVESTMENT, ABANDONED AQUEOUS MILLING - ACTIVE CHANGE POLARITY OF SURFACE (RT-759-D) KHD-4 DU P050145501 AQUEOUS MILLING - PROCESS OUTLINE PREMILLING QA 2,9-DICHLORO QA Na2S04 KHD-5 AQUEOUS MILLING PREMILL POWDER WATER NaOH PENTANOL EXTRACTION WATER, H2SG4 AQUEOUS MILLING SLURRY ALUM, QAMS ' t----------- FILTRATION i DRYING * GRINDING DU P050145502 VARIABLES STUDIED AT SEMI-WORKS MILLING TIME MILLING TEMPERATURE NaOH AND ALCOHOL CONCENTRATIONS EFFECT OF SURFACTANT COMPOSITION (1005G 2,9-DICHLORO QA VS, SOLID SOL) BASIC DATA + SCOPE SAFETY + ENVIRONMENTAL PENTANOL ODOR CONTROL MATERIAL HANDLING (NaOH, PENTANOL) PMN FOR SURFACTANT MINIMIZE INVESTMENT USE OF EXISTING FACILITIES MINIMUM ESSENTIAL DESIGN FOR NEW FACILITIES KHD-6 DUP050145503 RT-243-D XRT-343-D (ACETONE) XRT-343-D (AQUEOUS) YIELD STRESS (DYNES/CM?) 1307 VISCOSITY (POISE) GLOSS DOI (IN RED BLENDS IN HSE) 29 85 90 125 3.4 92 90+ 211 6.8 93.3 95+ KHD-7 DUP050145504 AQUEOUS MILLING - VENTURE GUIDANCE ESTIMATE ($M) MILL AREA MILL TEMPERATURE CONTROL PIPING FOR NaOH, H# SPOT VENTILATION DRUMMING BOOTH PARTITION CONTAINERS TOTE BINS OR "DYEPAKS" EXTRACTION AREA TOTEUNLOADING FACILITIES ^75 30 OR 5 20 KHD-8 DUP050145505 PROGRAM SCHEDULE PRODUCT/PROCESS PROCESS STUDIES DECISION ON VIABILITY CUSTOMER SAMPLING CUSTOMER RESULTS PLANT DEMONSTRATION 4-82 5A-82 6-82 9-82 3Q-82 PLANT DRAFT BASIC DATA SCOPE-ESTIMATE APPROVED BASIC DATA SCOPE AUTHORIZATION DESIGN COMPLETE CONSTRUCTION COMPLETE COMMERCIAL PRODUCTION 5A-82 6A-82 7B-82 11-82 2-83 3-83 KH.D-9 XRT-859-D, IMPROVED RHEOLOGY RT-759-D "MONASTRAL" RED Y APPROACH INCREASE SURFACE POLARITY OF RT-759-D BY APPLYING ALUMINUM QUINACRIDONE MONOSULFONATE (AQM) STATUS SUCCESSFUL PLANT TRIAL (2 BATCHES, 2500 LB.) IN MARCH/APRIL '82 CUSTOMER SAMPLING LOT BLENDED AT NEWARK WAITING CUSTOMER RESPONSE KHD-10 DU P050145507 FUTURE WORK DIMETHYL QA XRT-353-D, PINK E COUNTERPART IMPROVED RT-201-D BETA QA VIOLET IMPROVED RT-233-D, XRT-333-D KHD-11 DUP050145508 YT-915-D "MONASTRAL" FAST GOLD KHD-12 DU P050145509 BACKGROUND DEVELOPED A NEW GOLD PIGMENT FOR AUTOMOTIVE FINISHES MORE DURABLE THAN YT-815-D BASED ON A SOLID SOLUTION OF QUINACRIDONEQUINONE (QAQ) WITH THE STABILIZER ANILINOACRIDONE (AA), LAKED WITH NICKEL CARBONATE, 0 It H AA KHD-13 00 QAQ DU P050145510 STATUS TECHNOLOGY PLANT DEMONSTRATED (MAY '81 - 1600 LB. ; JAN. '82 4500 LB.) AA SUPPLY FIRST AA PRODUCTION IN BLACKMAN /UHLER1S (B/U) SEMI-WORKS MAKE VS. BUY DECISION AUGUST '81 SHORT TERM CASH FLOW R&D EXPENSE NEWPORT PRODUCTION INTERFERENCE EVALUATED ALTERNATIVE TOLL MANUFACTURE AT HELIX ASSOC. AND GRANT CHEMICALS (FERRO) TOLL MANUFACTURE CONTRACT WITH B/U BEING NEGOTIATED INGREDIENTS FOR AA (AMINE + ESTER) FROM SINGLE SUPPLIERS STOCK PI LE VS. ALTERNATE SUPPLY TOLL MANUFACTURE KHD-14 DUP050145511 CHOICE OF BLACKMAN/UHLER B/U INVESTMENT ^ 350M CONVERSION COST ^33 EXPERIENCE + LONG TERM ECONOMIC VIABILITY + GRANT HELIX -^375M -100M -33 -21 +? OUTLOOK FINALIZE B/U CONTRACT IN MAY GET ^1000 LBS. OF AA FROM B/U BY 10-1-82 o AMINE ON HAND. o ESTER ORDERED - JUNE MANUFACTURE ^8000 LBS. OF YT-915-D BY JAN. '83 PURSUE ALTERNATE TOLL MANUFACTURE FOR ESTER KHD-15 DUP050145512 XRT-891-D RES INATEP V10UET OBJECTIVE DEVELOP A QA VIOLET OF IMPROVED HEAT STABILITY AND DISPERSIBILITY FOR AUTOMOTIVE PLASTICS BACKGROUND NEW QA OPPORTUNITIES RED 3B - INTENSE BUT EXPENSIVE HF4B - INTENSE BUT POOR LIGHTFASTNESS DU PONT PRODUCTS RT-791-D RT-899-D 1981 DOMESTIC USE IN PLASTICS 76M LBS. 11M LB S. LIST PRICE $23/LB, $23/LB. SALES DOLLAR $1.7MM $250M PRODUCT CHARACTERISTICS - DISPERSIBILITY MARGINAL IMPROVED - HEAT STABILITY MARGINAL IMPROVED - MASSTONE SHADE "PLUM" BROWN & DULL KHD-16 DUP050145513 APPROACH BETA QA DISPERSION MILLED WITH 10% "ELVACITE" 2046 DISPERSION MILL BETA-QA "ELVAC 1TE" ALUM PERCLENE ACID EXTRACT MILL POWDER H2SO4 QAAF FLOMO PRESS, WASH, DRY, PULVERIZE, BLEND WITH SHADING LOT CONTAINING BT-449-D STATUS AND PROGRAM PLANT TRIALS DEC. /JAN. MAR. /APR. '82 APR. '82 MAY '82 JUNE '82 5 NEWPORT MILLINGS TO STUDY MILLING TIME 15 NEWPORT MILLINGS 2 EXTRACTIONS 1 BLENDING LOT NEWARK DRYING FINAL CHESTNUT RUN EVALUATION AND BLENDING RECOMMENDATION CUSTOMER SAMPLING KHD-17 DUP050145514 IMPROVED CPC PRODUCTS OBJECTIVE: FILL CPC CAPACITY WITH ENHANCED PRODUCT MIX BP-565-D. FOR PLASTICS XBT-579-D FOR LDL XBT-584-D FOR HSE KHD-18 DUP050145515 BP-565-D OBJECTIVE: DEVELOP A HIGHLY DISPERSlBUE BLUE FOR POLYOLEFIN BLOWN FILMS AT AMPACET (120,000 LB. '82 OPPORTUNITY, INCREA/L EARN. $2.22/LB.) AND OTHER CUSTOMERS. APPROACH: 55% ALPHA CPC (BB CRUDE) KHD-19 PRESS DRY 1 BLEND DUP050145516 STATUS FIRST TWO PLANT TRIALS 6/81 AND 10/81 GAVE VARIABLE QUALITY THIRD TRIAL 12/81 GAVE EXCELLENT QUALITY FEB./MAR. '82 PRODUCTION (18,000 LBS.) GAVE EXCELLENT QUALITY LONG DRYING CYCLE REMAINS A CONCERN ASSESSING LONG TERM DRYING CAPACITY R&D AND NEWARK PRODUCTION EVALUATING DRYING ALTERNATIVES PROGRAM COMPLETE TURNOVER TO PRODUCTION, WRITE PROCESS DRYING ALTERNATIVES SAMPLE PRODUCT TO OTHER CUSTOMERS LOOK FOR OTHER OPPORTUNITIES TO APPLY THIS TECHNOLOGY KHD-20 DUP050145517 XBT-579-D OBJECTIVE REGAIN LOST BP-479-D BUSINESS IN DARK METALL1CS AT F&F APPROACH DEVELOP TONER PRODUCT SIMILAR TO BP-479-D IN COLOR AND TRANSPARENCY BY PREMILL + ACID GROWTH BBFZ 70C. im H2SO4 DI LUTE/70C. ISOLATE PROCESS PATENT APPLICATION FILED VALUE-IN-USE AT LEAST 60% BETTER THAN BP-479-D STATUS PLANT TRIALS COMPLETE (3 LOTS - 1200 LBS. EACH) LOTS 2 & 3 BLENDED FOR SAMPLING TO F&F PROGRAM F&F'S EVALUATION FOLLOW NEXT PRODUCTION FINISH DOCUMENTATION KHD-21 DUP050145518 XBT-584-D OBJECTIVE DEVELOP A BT-284-D COUNTERPART SUITABLE FOR HSE BACKGROUND BT-284-D HAS POOR RHEOLOGY BT-425-D EXTENDER INCOMPATIBLE WITH HSE APPROACH HIGH POLARITY SURFACE CPC FOR GOOD RHEOLOGY: TREATMENT WITH CATIONIC SURFACTANT AND CPC-MS N-8510 (ACETONE MILLED SEMICHLORO CPC) TREATMENT WITH ARQUAD'16-50 CPC-MS ALUM PRESS, WASH, DRY, PULVERIZE STATUS SAMPLED TO F&F AND OTHER CUSTOMERS F&F INTERESTED (1985 COLORS IN LDL; ENAMEL F/C AND COMMITMENT BY MAY) TMR CIRCULATING FOR SIGNATURES WAITING FOR F&F'S 5/82 RESPONSE BEFORE PLANT TRIAL KHD-22 DUP050145519 HIGH SOLIDS DISPERSIONS FOR TRADE SALES OBJECTIVE OFFER HIGH VALUE-IN-USE PRODUCTS FOR TRADE SALES TO PROTECT OUR EXISTING BUSINESS AND EXPAND SHARE BY DEVELOPING HIGH SOLIDS PIGMENT DISPERSION APPROACH FORMULATE STABl DISPERSIONS OF SAND MILLED PRESSCAKES PRESSCAKE (40-50% SOLIDS-MEMBRANE PRESS) 4 FLUIDIZE 4 SAND MILL 4 STANDARDIZE 4 PACKOUT (40-50% PIGMENT, 5-10% ADDITIVES, BALANCE WATER) KHD-23 DUP050145520 STATUS PRODUCT LINE COMPLETE PRODUCT LINE YW-958-P YW-911-P YW-928-P YW-968-P GW-951-P '81 SALES (M LBS.) 38.6 1.2 17.6 14.6 5.7 '82 F/C (M LBS.) MARKET 80 INTERIOR 96 EXTERIOR 30 EXTERIOR 30 EXTERIOR 25 EXT. /INT. PROGRAM CONSOLIDATE LINE REPLACE YW-968-P WITH YW-911-P? DROP YW-928-P? STUDY MIXING YW-958-P WITH YW-911-P FINALIZE RW-252-P FORMULA DEVELOPED 2.6% PETRO DISP., 2.5% IGEPAL, NALCO 2300, BIOCIDE, AMP 95, ETHYLENE GLYCOL CHESTNUT RUN TESTING PPG TESTING DEVELOP DIMETHYL QA DISPERSION LONG TERM SAND MILLING FACILITIES SECRECY AGREEMENT SIGNED WITH AMERICAN COLOR ESTABLISH TECHNICAL LIAISON TRANSFER TECHNOLOGY KHD-24 DUP050145521