Document jgYnLEqm218jpxYoyBdkm6m1Q

+--- --'---------- - - - ------ -- --------------- -- -- -- -- -- -- - ---- _ -- -- -- -- ---------------______---- -- -- -- Date Printed: 08-15-1996 LA-MAR-KA (LM-00007.MSDS) MSDS for SODIUM HYDROXIDE, 13N TO 1.25N ---- 4. Page 1 1 -PRODUCT IDENTIFICATION PRODUCT NAME: COMMON SYNONYMS: CHEMICAL FAMILY: FORMULA: FORMULA WT.: CAS NO.: NIOSH/RTECS NO.: PRODUCT USE: SODIUM HYDROXIDE, 50% TO 5 % CAUSTIC SODA; SODIUM HYDRATE; AQUEOUS SOLUTIONS NAOH IN H20 40.00 1310-73-2 WB4 905000 LABORATORY REAGENT LYE CHEMTREC # (800) 424-9300 LA-MAR-KA, INC. 10272 SOUTH PERDUE STREET BATON ROUGE, LA. 70814 EFFECTIVE: 05/01/89 REVISION #04 ISSUED: 04/14/90 REVIEWED 1-1-95 PRECAUTIONARY LABELING LA-MAR-KA LABELING SYSTEM HEALTH 3 SEVERE (POISON) FLAMMABILITY 0 NONE REACTIVITY 2 MODERATE CONTACT 4 EXTREME (CORROSIVE) -LABORATORY PROTECTIVE EQUIPMENT GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES U.S. PRECAUTIONARY LABELING POISON DANGER HARMFUL IF INHALED. CAUSES SEVERE BURNS. MAY BE FATAL IF SWALLOWED. REACTS VIOLENTLY WITH ACIDS. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF SPILL, CAREFULLY NEUTRALIZE SPILL WITH DILUTE HCL. FLUSH SPILL AREA WITH WATER. INTERNATIONAL LABELING AVOID CONTACT WITH EYES. AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER. KEEP CONTAINER TIGHTLY CLOSED. LA-MAR-KA STORAGE COLOR CODE: WHITE STRIPE (STORE SEPARATELY) DO A 060798 CONFIDENTIAL H------ '--------------------------------------------------------------------------------------------------------------------------------------------------------------- 1- Date Printed: 08-15-1996 Page 2 LA-MAR-KA (LM-00007.MSDS) MSDS for SODIUM HYDROXIDE, 13N TO 1.25N 2 -COMPONENTS COMPONENT SODIUM HYDROXIDE WATER CAS NO. 1310-73-2 7732-18-5 WEIGHT % 50-5 50-95 OSHA/PEL ACGIH/TLV 2 MG/M3 2 MG/M3 N/E N/E THE TLV AND PEL LISTED FOR SODIUM HYDROXIDE DENOTE CEILING LIMITS. 3 -PHYSICAL DATA BOILING POINT: 142 C (287 F) (AT 760 MM HG) VAPOR PRESSURE (MMHG): 1 (20 C) MELTING POINT: 12 C (53 F) (AT 760 MM HG) VAPOR DENSITY (AIR=1): N/A SPECIFIC GRAVITY: 1.53 - 1.06 (H20=l) EVAPORATION RATE: N/A SOLUBILITY(H20): COMPLETE (100%) % VOLATILES BY VOLUME: 50 (21 C) : 14.0 (1.0M SOLUTION) ODOR THRESHOLD (P.P.M.): N/A PHYSICAL STATE: LIQUID COEFFICIENT WATER/OIL DISTRIBUTION: N/A APPEARANCE & ODOR: CLEAR, COLORLESS VISCOUS LIQUID. ODORLESS. 4 -FIRE AND EXPLOSION HAZARD DATA FLASH POINT (CLOSED CUP): N/A AUTOIGNITION TEMPERATURE: N/A FLAMMABLE LIMITS: UPPER - N/A LOWER - N/A FIRE EXTINGUISHING MEDIA USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. FLOOD WITH WATER, DO NOT SPLATTER OR SPLASH THIS MATERIAL. rZ A 06799 Cn^lDENTlAL H--------------------------------------------------- ------------------------------------------------------------------------------------------------------------------- h Date Printed: 08-15-1996 Page 3 LA-MAR-KA (LM-00007.MSDS) MSDS for SODIUM HYDROXIDE, 13N TO 1.25N 4 -FIRE AND EXPLOSION HAZARD DATA (continued) UNUSUAL FIRE & EXPLOSION HAZARDS REACTS WITH MOST METALS TO PRODUCE HYDROGEN GAS, WHICH CAN FORM AN EXPLOSIVE MIXTURE WITH AIR. TOXIC GASES PRODUCED NONE IDENTIFIED EXPLOSION DATA-SENSITIVITY TO MECHANICAL IMPACT NONE IDENTIFIED. EXPLOSION DATA-SENSITIVITY TO STATIC DISCHARGE NONE IDENTIFIED. 5 -HEALTH HAZARD DATA THRESHOLD LIMIT VALUE (TLV/TWA): 2 MG/M3 TLV (CEILING) IS FOR SODIUM HYDROXIDE. TORT-TERM EXPOSURE LIMIT (STEL): NOT ESTABLISHED RMISSIBLE EXPOSURE LIMIT (PEL): 2 MG/M3 .PEL (CEILING) IS FOR SODIUM HYDROXIDE. TOXICITY OF COMPONENTS INTRAPERITONEAL MOUSE LD50 FOR SODIUM HYDROXIDE INTRAPERITONEAL MOUSE LD50 FOR WATER INTRAVENOUS MOUSE LD50 FOR WATER CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: 40 190 25 NO CARCINOGENICITY NONE IDENTIFIED. REPRODUCTIVE EFFECTS NONE IDENTIFIED. EFFECTS OF OVEREXPOSURE INHALATION: SEVERE IRRITATION OR BURNS OF RESPIRATORY SYSTEM, PULMONARY EDEMA, LUNG INFLAMMATION SKIN CONTACT: BURNS EYE CONTACT: BURNS, PERMANENT EYE DAMAGE MG/KG G/KG G/KG DO A 060800 CONFIDENTIAL ---------------------------------------------------------------------------------------------------------------------------------------------------------------------- + LA-MAR-KA (LM-00007.MSDS) Date Printed: 08-15-1996 Page 4 MSDS for SODIUM HYDROXIDE, 13N TO 1.25N 5 -HEALTH HAZARD DATA (continued) SKIN ABSORPTION: NONE IDENTIFIED INGESTION: IS HARMFUL AND MAY BE FATAL, SEVERE BURNS TO MOUTH, THROAT, AND STOMACH, NAUSEA, VOMITING CHRONIC EFFECTS: NONE IDENTIFIED TARGET ORGANS EYES, SKIN, RESPIRATORY SYSTEM, LUNGS MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED PRIMARY ROUTES OF ENTRY INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT EMERGENCY AND FIRST AID PROCEDURES INGESTION: CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. FOLLOW WITH DILUTED VINEGAR, FRUIT JUICE OR WHITES OF EGGS, BEATEN WITH WATER. INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. SKIN CONTACT: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE. EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SARA/TITLE III HAZARD CATEGORIES AND LISTS ACUTE: YES CHRONIC: YES FLAMMABILITY: NO PRESSURE: NO REACTIVITY: NO EXTREMELY HAZARDOUS SUBSTANCE: CERCLA HAZARDOUS SUBSTANCE: SARA 313 TOXIC CHEMICALS: GENERIC CLASS: TSCA INVENTORY: NO YES YES YES CONTAINS SODIUM HYDROXIDE (RQ = 1000 LBS) CONTAINS SODIUM HYDROXIDE C16 DO A 060801 CONFIDENTIAL +" -- ------ ------ ----------------------- -- -- -- -- -------- -------- ------------------------------------ -- -- -- -- ----------------------- -- -- -- ----------------------- " -- + Date Printed: 08-15-1996 Page 5 LA-MAR-KA (LM-00007.MSDS) MSDS for SODIUM HYDROXIDE, 13N TO 1.25N ----------------------------------------------------------------------------------------------------------------------------------------------------------------+ 6 -REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT INCOMPATIBLES: STRONG ACIDS, MOST COMMON METALS, COMBUSTIBLE MATERIALS, ORGANIC MATERIALS, WATER, ZINC, ALUMINUM, PEROXIDES, HALOGENATED HYDROCARBONS DECOMPOSITION PRODUCTS: NONE IDENTIFIED 7 -SPILL Sc DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. VENTILATE AREA. CAREFULLY NEUTRALIZE SPILL WITH DILUTE HCL. FLUSH AREA WITH FLOODING AMOUNTS OF WATER. (USE CAUTION.) 'SPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. -EPA HAZARDOUS WASTE NUMBER: D002, D003 (CORROSIVE, REACTIVE WASTE) 8 -INDUSTRIAL PROTECTIVE EQUIPMENT VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO PPM, A HIGH-EFFICIENCY PARTICULATE RESPIRATOR IS RECOMMENDED. ABOVE THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. 60 EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, NEOPRENE GLOVES ARE RECOMMENDED. 9 -STORAGE AND HANDLING PRECAUTIONS LA-MAR-KA STORAGE COLOR CODE: WHITE STRIPE (STORE SEPARATELY) DO A oonfid 60802 DWTIa; LA-MAR-KA (LM-00007.MSDS) MSDS for SODIUM HYDROXIDE, 13N TO 1.25N Date Printed: 08-15-1996 Page 6 9 -STORAGE AND HANDLING PRECAUTIONS (continued) STORAGE REQUIREMENTS KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION-PROOF AREA. ISOLATE FROM INCOMPATIBLE MATERIALS. DO NOT STORE BELOW 12 C. 10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION DOMESTIC (D.O.T.) PROPER SHIPPING NAME: SODIUM HYDROXIDE, SOLUTION HAZARD CLASS: CORROSIVE MATERIAL (LIQUID) UN/NA: UN1824 REPORTABLE QUANTITY: 1000 LBS. LABELS: CORROSIVE REGULATORY REFERENCES: 49CFR 172.101; 173.249 INTERNATIONAL (I.M.O.) PROPER SHIPPING NAME: SODIUM HYDROXIDE, SOLUTION HAZARD CLASS: 8 I.M.O. PAGE: 8215 'T: UN1824 MARINE POLLUTANTS: NO PACKAGING GROUP: II 3ELS: CORROSIVE ..^GULATORY REFERENCES: 4 9CFR 172.102; PART 176; IMO -AIR (I.C.A.O.) PROPER SHIPPING NAME: HAZARD CLASS: UN: UN1824 LABELS: CORROSIVE REGULATORY REFERENCES: SODIUM HYDROXIDE, SOLUTION 8 PACKAGING GROUP: 49CFR 172.101; 173.6; PART 175; ICAO/IATA II U.S. CUSTOMS HARMONIZATION NUMBER: 28151200007 N/A = NOT APPLICABLE OR NOT AVAILABLE N/E = NOT ESTABLISHED THE INFORMATION IN THIS MATERIAL SAFETY DATA SHEET MEETS THE REQUIREMENTS OF THE UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ACT AND REGULATIONS PROMULGATED THEREUNDER (29 CFR 1910.1200 ET. SEQ.) AND THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM. THIS DOCUMENT IS INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PERSON TRAINED IN, OR SUPERVISED BY A PERSON TRAINED IN, CHEMICAL HANDLING. THE USER IS RESPONSIBLE FOR DETERMINING THE PRECAUTIONS AND DANGERS OF THIS CHEMICAL FOR HIS OR HER PARTICULAR APPLICATION. DEPENDING ON USAGE, PROTECTIVE CLOTHING INCLUDING EYE AND FACE GUARDS AND RESPIRATORS MUST BE USED TO AVOID CONTACT WITH MATERIAL OR BREATHING CHEMICAL VAPORS/FUMES. DO A 060803 CONFIDENTIAL LA-MAR-KA (LM-00007.MSDS) MSDS for SODIUM HYDROXIDE, 13N TO 1.25N Date Printed: 08-15-1996 Page 7 10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION (continued) EXPOSURE TO THIS PRODUCT MAY HAVE SERIOUS ADVERSE HEALTH EFFECTS. THIS CHEMICAL MAY INTERACT WITH OTHER SUBSTANCES. SINCE THE POTENTIAL USES ARE SO VARIED, LA-MAR-KA CANNOT WARN OF ALL OF THE POTENTIAL DANGERS OF USE OR INTERACTION WITH OTHER CHEMICALS OR MATERIALS. LA-MAR-KA WARRANTS THAT THE CHEMICAL MEETS THE SPECIFICATIONS SET FORTH ON THE LABEL. LA-MAR-KA DISCLAIMS ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, WITH REGARD TO THE PRODUCT SUPPLIED HEREUNDER, ITS MERCHANTABILITY OR ITS FITNESS FOR A PARTICULAR PURPOSE. THE USER SHOULD RECOGNIZE THAT THIS PRODUCT CAN CAUSE SEVERE INJURY AND EVEN DEATH, ESPECIALLY IF IMPROPERLY HANDLED OR THE KNOWN DANGERS OF USE ARE NOT HEEDED. READ ALL PRECAUTIONARY INFORMATION. AS NEW DOCUMENTED GENERAL SAFETY INFORMATION BECOMES AVAILABLE, LA-MAR-KA WILL PERIODICALLY REVISE THIS MATERIAL SAFETY DATA SHEET. APPROVED BY LA-MAR-KA, INC. DO A 060804 CONFIDENTIAL