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1 Table: Results from studies on PFSAs Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) PFBS PFBS (97.9% pure, K+-salt) 2-generation Increased liver 100 reproduction study weight according to OECD (maternal) guideline 416 Increased 100 Sprague Dawley rats hepatocellular Gavage. 0, 30, 100, 300, hypertrophy (P 1000 mg/kg bw per day. and F1 adult males) Parental (F0) animals (males and females, Increased 100 n=29-30 per sex per incidence of group) dosed from 70 mild days prior to mating, microscopic females were continued findings in through gestation and kidney lactation. F1 offspring (maternal). (n=29-30) was dosed from weaning Reproductive (lactational day 22) and onwards. F2 generation developmental was exposed through toxicity findings placenta and lactation. offspring not Experiment was observed terminated at lactational (highest dose day 22 of F2 generation LOAEL) animals Significant 30 increase in diestrus cycling only at 100 mg/kg bw/day 300 300 300 1000 100 Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce Immune system, thyroid system? Not determined Lieder et al. 2009b 2 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) Crl:CD(SD)IGS BR Decreased abs 60 VAF/PlusTM rats (m/f) &rel spleen Based on OECD 408 weight(m) Gavage: 0, 60, 200, or Decr red blood 600 mg/kg bw per day cells (m) 600 200 Duration: 90 days Decreased No/sex/group: 10 hematocrit (m) 200 Decr 60 hemoglobin (m) Increased 200 serum chloride 60 (m) Decreased 600 serum albumin 200 and total protein (f) 600 200 Decreased 100 300 PFBS, Sprague Dawley rats serum potassium salt (m/f) phosphorus and (98.2% purity) Gavage: 0, 100, 300, or potassium (m) 900 mg/kg bw per day. Incr rel and 300 900 Duration: 28 days absolute liver weight (m) No/sex/group: 10 Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce Not determined Lieder et al. 2009a Not determined NICNA S, 2005 3 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) PFBS (97% ICR mice Decreased body 50 200 pure, K+-salt) Dosing: 0, 50, 200, and weight from 500 mg/kg bw per day PND 1 to from GD 1 -20, orally. adulthood Only female offspring follow-up reported. Delayed eye 50 200 opening 30 dams per dose group, randomly allocated to Delayed vaginal 50 200 three experimental sub- opening groups per dose: group 1: perinatal Impaired 50 200 survival and growth, ovarian and pubertal onset, and uterine ovarian and uterine development development (10 dams, 50 female offspring per Delayed estrus 50 200 dose), cyclicity and group 2: hypothalamic- reduced E2/ pituitary-gonadal increased LH hormone and hypothalamic-pituitary- Decreased 50 200 thyroid hormone levels T3/T4, (10 dams, 30 PND 1 increased TSH female offspring, 10 female PND 30 offspring, Decreased 50 200 and 10 PND 60 female T3/T4, offspring), increased TSH group 3: levels of serum at GD 20 PFBS (10 dams) (maternal) Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce Mean (10 dams) serum concentration (ng/mL) on GD 20, 12h after last dosing, at 0, 50, 200 and 500 mg/kg bw per day: 1.73, 74, 332, 721. Feng et al., 2017 PFBS (>97% Sprague Dawley rats (m, Incr rel liver 62.6 purity) f) weigt (m) Gavage: 0, 62.6, 125, 250, 500, or 1,000 Incr rel liver 62.6 125 mg/kg bw per day weigt (f) No/sex/group: 10 Duration: 28 days Incr abs liver 125 125 weight (m) Incr abs liver 250 weight (f) Incr acyl-CoA- 250 oxidase activity (m) Decr 62.6 haematocrit (m,f) Decr RBC (m,f) 62.6 Decr chol (m,f) 62.6 Decr T3 (m,f) 62.6 Decr total+free 62.6 T4 (m,f) Incr albumin/globuli 62.6 125 n ratio (m,f) Plasma conc. (ug/ml) at 62.6mg/kg bw/day: 2.2 + 4.8 (m) 0.2 + 0.05 (f) Liver conc (ug/g) at 62.6mg/kg bw/day 1.3 + 0.2 (m) NTP, 2019b 4 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce PFBS, (L-7038, 98.2% pure) PFHxS PFHxS (potassium salt; 99.98% purity) male E3L.CETP mice on a C57Bl/6 background (a transgenic mouse model for human-like lipoprotein metabolism, APOE*3-Leiden.E3L CETP) Fed a western diet daily with 30 mg/kg bw/day for 4-6 weeks Sub-chronic, duration: 42 days,OECD guideline 422 (Combined Repeated Dose Toxicity Study with the Reproduction/Developm ental Toxicity Screening Test) Sprague Dawley rats (m) Gavage: 0, 0.3, 1, 3, or 10 mg/kg bw per day. No/sex/group: 10 for clinical/chemical parameters, 15 dams per group Reduced plasma triglycerides and cholesterol (VLDL-C an HDLC) Incr rel liver weight Decr prothrombin time Decr serum cholesterol Decr hemoglobin Decr hematokrit Decr RBC Thyroid hypertrophy/hy perplasia No reproductive or developmental effect No treatment related effects in dams 30 1 3 0.3 0.3 0.3 1 1 3 1 3 1 3 10 10 mean serum concentration ~33-38 g/ml Bijland et al., 2011 Concentration in g/g: m at 0.3 mg/kg bw per day: in liver 43.8 +/8.1, in serum 44.2 +/- 12.7 Butenh off et al., 2009 m at 3 mg/kg bw per day: in liver 339 +/- 128, in serum 128 +/10 m at 10 mg/kg bw per day in liver 593 +/81.4 in serum 201.5 +/- 20 Elaborated serum and liver values in dams and fetuses. Serum levels at study day 14 and GD 21 in dams were similar. For GD 21 females in serum and liver: 0 mg/kg per day: <LOQ of 0.1 g/mL and 0.1 g/g. 0.3 mg/kg per day: 3.32 g/mL and 0.79 g/g. 1 mg/kg per day: 10.65 g/mL and 2.61 g/g. 3 mg/kg per day: 32.75 g/mL and 7.80 g/g. 10 mg/kg per day: 59.80 g/mL and 16.53 g/g Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks 5 NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce PFHxS (3M, salt, purity not specified) PFHxS (potassium salt, 97% purity) SV129 mice (m) Duration: 7 days Gavage: 0, 3 or 10 mg/kg bw per day No/sex/group: 4 SV129 mice (m) Duration: 7 days Gavage: 0 or 10 mg/kg bw per day No/sex/group: 4 Incr rel liver weight Incr abs liver weight Incr abs and rel liver weight Incr hepatic lipid and triglyceride content 3 3 10 10 10 Not reported Rosen et al., 2017 Not reported Das et al., 2017 6 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce PFHxS Crl:CD1 (IRC) mice, OECD Incr abs & rel 0.3 1 (potassium salt; test guideline 422 liver weight (F0 98.9% purity) (Combined m,f) 1 Repeated Dose Toxicity Centrilobular 1 0.3 Study with the hypertrophy (F0 1 Reproduction/Developm m) ental Toxicity Incr ALP (F0 m) 3 Screening Test), modified (extended). Decr Serum 3 cholesterol (F0 Duration: 42 days. m) Gavage: 0, 0.3, 1, 3 Necrotic 3 mg/kg bw per day hepatocytes and lipid No/sex/group: 30 vesicles in hepatocytes (F0 For F0 males treatment m) from 14 days prior to cohabitation for to at least 42 days total (one day post-last dosing). Treatment of F0 females started 14 days prior to cohabitation with continuation through mating, gestation, and lactation. F0 dams were sacrificed on lactation day 22 (one day after last dosing). F1 offspring, first exposure in utero and via lactation. After weaning (PND 22), F1 direct dosing for 14 days at maternal dose. Liver conc. (g/g): F0M at 0.3 mg/kg bw/day: 25.9 3.5 F0M at 1 mg/kg bw/day: 98.5 22.7 F0M at 3 mg/kg bw/day: 281.1 45.4 Serum and liver in dams, and serum from pooled fetus on GD18: 0 mg/kg per day: <0.001 g/mL, <0.005 g/g and <0.001 g/mL. 0.3 mg/kg per day: 16.8 g/mL, 5.3 g/g, and 20.8 g/mL . 1 mg/kg per day: 51.5 g/mL, 15.1 g/g and 62.3 g/mL. 3 mg/kg per day: 111.3 g/mL, 88.4 g/g and 137.7 g/mL. Chang et al., 2018 7 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks Toxicokinetic experiment: 12 animals per sex and dose. Subset 1 (5/sex/dose group) daily oral gavage for 14 days prior to sacrifice. Subset 2 (7/sex/dose group) dosing for 14 days prior to cohabitation. Serum and liver samples were collected at study day 14 for both sexes, at study day 28 for males and GD 18 (for females). On GD 18, pooled fetal blood and fetal liver samples were collected Reduced litter size (without impact on born pup to implant ratio). F1: Increased relative liver weight (m, f) F1: Increased thyroid weight (m) NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce 0.3 1 1 3 1 3 PFHxS ( potassium salt; >98% purity) Sprague Dawley rats (m, f) Duration: 28 days Gavage: 0, 0.625, 1.25, 2.5, 5, or 10 mg/kg bw per day (males) 0, 3.12, 6.25, 12.5, 25, or 50 mg/kg bw per day (females) No/sex/group: 10 Incr rel and abs liver weight (m) Incr rel and abs liver weight (f) Decr T3 and cholesterol (m) Decr total T4 (m) Decr total T4 (f) Decr free T4 (m) Decr free T4 (f) Incr acyl-CoAoxidase activity (m) 0.625 3.12 6.25 2.5 1.25 3.12 0.625 0.625 6.25 0.625 12.5 5 Plasma conc. (ug/ml) 0.625mg/kg bw/day: 66.8 + 3.5 (m) 3.12mg/kg bw/day: 37.0 + 1.7 (f) NTP 2019b Liver conc (ug/g) 0.625mg/kg bw/day 39.9 + 1.3 (m) 8 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce PFHxS, K+-salt, Wistar rats Increased liver 5 25 purity > 98% Dosing from GD 7 until weight, male F1 PND 22 (except for day of delivery). Increased liver 0.05 5 Gavage: 0, 0.05, 5, 25 weight, female mg/kg bw per day F1 Main study: 16 -20 time mated rats per group Pronounced 0.05 5 Dose range finding study reduction of T4 (8 time mated rats per levels, dams group): 0, 25, 46 mg/kg bw per day Pronounced 0.05 5 reduction of T4 levels, F1 Serum levels in dam at PND 22 in the dose range finding study. 139 and 174 g/mL in 25 and 45 mg/kg bw per day groups, respectively Ramh j et al. 2018 Mildly decreased body weight, male pups 5 25 Mildly decreased body 0.05 5 weight, female pups No relevant effects on anogenital distance, nipple retention or organ weights PFHpS: No studies identified PFOS 9 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) PFOS (91% K+- Reproductive/developm Decreased 1 2 Salt) ental postnatal "Our analysis survival indicated that Sprague-Dawley rats 2 approximately Decreased 71% of the Exposure: 0, 1, 2, 3, 5, 10 growth in 1 chemical was mg/kg per day per surviving pups straight-chain, gavage GD2 - GD21 and the Delay in eye remaining 29% opening 1 2 was branched. Additional Decreased analysis thyroxin (pups) 1 2 indicated that the chemical No consistent obtained from change in liver Fluka appeared weight or to be identical relative liver to that weight in produced by surviving pups 3M." PND 0-35 Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce Read from figures. Serum in pups at pnd 1: Control: 0; 1 mg/kg: 36 g/mL; 2 mg/kg: 71 g/mL; 3 mg/kg: 85 g/mL; 5 mg/kg: 108 g/mL; Slightly lower at pnd 5 Lau et al. 2003 Liver in pups at pnd 1: Control: 0; 1 mg/kg: 45 g/g; 2 mg/kg: 68 g/g; 3 mg/kg: 100 g/g; 5 mg/kg: 160 g/g PFOS (86.9%, 2-generations F0 males and 0.4 1.6 K+-Salt. Lesser reproductive/developm females: homologs (C4- ental reduced bw C7) at 8.4%; gain. impurities (by Sprague Dawley rats, 20 quantitative dams per group. In F0 shorter 1.6 3.2 19F Nuclear gestation, lower Magnetic Exposure: 0, 0.1, 0.4, n implantation Resonance) at 1.6, and 3.2 mg/kg bw sites, increase 1.9%; metals per day by gavage for 6 in stillborn pups (calcium, weeks prior to mating, or early magnesium, during mating, and neonatal death sodium, nickel, through gestation and of litter. and iron) at lactation, across two 1.5%; inorganic generations for females fluoride at (only 0, 0.1, 0.4 mg/kg 0.6%; bw per day continued to perfluorooctan F2). Cross fostering (0 oic acid at 0.3%; and 1.6 mg/kg bw per nonofluoropent day) as follow up study anoic acid at 0.3%; heptafluorobut yric acid at 0.1%. Serum levels (g/mL) from cross foster study at end of lactation available. Luebke r et al. 2005a 10 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) F1 reduced 0.4 1.6 survival and bw gain. Delayed eye 0.1 0.4 opening F1 Pre- and postnatal exposure was additive for pup toxicity Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce PFOS (86.9%, Reproductive/developm Decrease in BMDL05 K+-Salt. ental, Sprague Dawley gestation length 0.31 Impurities as in rats, 35 dams per group. Luebker 2005a Exposure: 0, 0.4, 0.8, Decrease in 1.0, 1.2, 1.6, 2,0 mg/kg postnatal BMDL05 bw per day by gavage survival day 5 0.89 from 6 weeks prior to mating to day four of Decreased lactation mean pup weight at birth BMDL05 0.39 Increase in serum T4 on lactation day 5 (F0 and F1) 0.4 Measured in dams GD 1, 7, 15 and 21. Constant GD 115, drop at GD 21. Serum levels GD 1-15 (g/mL): 0.1 mg/kg: 7.88.9 ; 0.4 mg/kg: 40.7- 41.4; 1.6 mg/kg: 154-160; 3.2 mg/kg: 275318 Luebke r et al 2005b 11 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) PFOS (98% K+- Developmental study, Reduced weight 10 20 Salt) ICR mice gain (F0). 15 dams/goup (5 each Increased liver selected for specific weight (F0). 1 10 endpoints Liver Exposure: 0, 1, 10, 20 hypertrophy mg/kg per day , GD 1 - (F0). 10 20 17/18 Decreased neonatal survival. 1 10 Developmental/ teratological alterations. 1 10 Sternal defects. Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce Not reported Yahia et al., 2008 1 Developmental study, Decrease in NK 0.1 1 B6C3F1 mice. cell activity at 8 weeks (F1 M). Exposure: GD 1-17, 0, Decrease in NK 0.1, 1.0, 5.0 mg/kg bw cell activity at 8 per day by gavage. weeks (F1 F). 1 5 Decrease in IgM production assessed by PFC assay at 8 1 5 weeks (spleen) (F1 M). Decrease in IgM production assessed by PFC assay at 8 weeks (spleen) F1 F). 5 Not reported Keil et al., 2008 12 Substance (%), EC/CAS, formula PFOS (purity 98%, K+-salt) study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks Developmental study ICR mice Exposure 0, 9, 13, 20, 30 mg/kg bw per day by gavage GD1-17 (3 dams/group). Sharp increase in cleft palate between 13 (7.3%) and 20 (78.35) mg/kg per day. 20 mg/kg bw per day GD 1-17 and 50 mg/kg per day GD11 - 15. 5 - 8 dams per group 67 - 103 fetuses: (examined animals, total number higher). 20 mg/kg per day GD 115/18 for histology. NO(A)EL (mg/kg bw/d) 13 LO(A)EL (mg/kg bw/d) Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce 20 50 % effective dose expected 17.7 mg/kg per day Serum level on GD17 (g/mL) reported for dams at 30 mg/kg per day and other values estimated from figure: 9 mg/kg bw per day: 58 in dam, 62 in fetus. 13 mg/kg bw per day: 105 in dam and fetus. 20 mg/kg bw per day: 135 in dam and fetus. 30 mg/kg bw per day: 162.3 in dams and 130 in fetus. 30 mg/kg bw per day: 162.3 in dams and 130 in fetus. Era et al., 2009 50 % effective fetal serum concentration for cleft palate: 121 g/mL 13 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) PFOS (purity 98%, salt not specified) Developmental study CD1 mice Exposure: 0, 0.3, 3 mg/kg per day GD1 - PND21 by gavage. Then no dosing in offspring until sacrifice at PND 63. Dams: 6 per group (sacrifice after weaning (PND 21)) Increased abs. 3 liver weight P0 Increased dam's liver weight F1 0.3 M Increased relative liver 0.3 weight P0 and F1 Offspring: animals per Increased treatment equally HOMA-IR (P0). 3 distributed in a low and a high fat feeding group. Increased Termination on PND 63 HOMA-IR (F1) 3 Elevated fasting glucose (F1 PND 21) 3 Elevated fasting glucose (F1 PND 63) 0.3 Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce Liver levels in dams at 0, 0.3 and 3 mg/kg per day: 0.15, 49.1 and 338.9 g/g. Wan et al., 2014 Serum levels in pups PND21 at 0.3 mg/kg per day: 12.7 g/mL in males and 11.4 g/mL in females. Serum levels at 3 mg/kg per day: 98.7 g/mL in males and 87.2 g/mL in females. Liver levels in pups PND21 at 0.3 mg/kg per day: 20.1 g/g in males and 18.0 g/g in females Liver levels at 3 mg/kg per day: 243 g/g in males and 178 g/g in females 14 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) PFOS (purity Developmental study Body weight 2 8 not specified, CD1 mice decrease (P0) K+-salt) Exposure: Gavage, 0, 0.5, 2, 8 mg/kg per day, Dose GD11 - GD16 dependent 0.5 decrease of 10 dams per group placental weight and capacity. Dose dependent 0.5 increase of number of resorptions and dead foetuses. Decrease in the numbers of glycogen 0.5 trophoblast cells in the junctional zone and the number of sinusoidal trophoblast giant cells in the labyrinth zone. Decrease of mPL-II, mPLP- C and mPLP-K expression levels and 0.5 serum concentrations Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce Not reported Lee et al., 2015 15 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) PFOS (>96% purity) 28 days toxicity study Incr rel and abs SD rats (m, f) liver weight (m/f). Gavage: 0, 0.312, 0.625, 1.25, 2.5, 5 mg/kg bw Incr acyl-CoA- per day oxidase activity 1.25 (m). No/sex/group: 10 Decr blood cholesterol (m) Decr total and free T4 (m, f) No change sin reporductive parameters (m) Increased probability of transitioning to extended diestrous in F (all exposure groups,Markov analysis). 0.312 2.5 0.312 0.312 Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce Plasma conc. (ug/ml) at 0.312mg/kg bw per day: 23.7 + 1.1 (m), 30.5 + 0.9 (f). Information available for all doses. Liver conc (ug/g) at 0.312 mg/kg bw per day: 87.2 + 3.04 (m) information available for all doses (m only) NTP, 2019b PFOS, 98% PFOS, 98% PFOS, 98% Repeated dose, immunotox. C57BL/6 mice (4-8 males per group), administered via diet for 10 days, at 0.001 or 0.02% (2 or 40 mg/kg bw per day) (0.02% equals a total of 6 mg/animal over 10 days) Repeated dose study, immunotox. C57BL/6 mice (4 males), restricted food diet, 10 days, 0.001, 0.002, 0.02 (1.6, 3.1 or 23.5 mg/kg bw per day) Repeated dose study, immunotoxicity, Balb/c mice (8 per group, males and females), gavage, 5, 20 mg/kg bw per day, 14 days Several immune parameters up or down, but also reduced body weight gain Reduced B-cell numbers Thymus and spleen histopathology, but in addition to liver effects and PPAR changes 0.001% (1.6 mg/kg bw per day) 5 0.02% (40 mg/kg bw per day) 0.02% (23.5 mg/kg bw per day) 20 340 g/mL Qazi et al. (2009a ,b) 50.8 g/mL at 0.001%, 340 g/mL at 0.02% Qazi et al. (2012) 4.89 g/mL at 5 mg/kg bw per day, 25.2 g/mL at 20 mg/kg bw per day Wang et al. (2011a ) 16 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) PFOS, 85% Repeated dose study, Values various 20 immunotoxicity,, Balb/c immune mice (5 females per parameters group), gavage, 20 reduced, but in mg/kg bw per day, 7 addition to days body weights PFOS, 98% Repeated dose study, Inconsistent; 1 5 immunotoxicity,, some ex vivo C57BL/6 mice (12 males apoptotic per group), gavage, 1, 5, parameters in 10 mg/kg bw per day, 7 splenocytes and days thymocytes up and others go down Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce Not reported Vetvick a and Vetvick ova (2013) 24.37 g/mL at 1 mg/kg bw per day, 87.56 g/mL at 5 mg/kg bw per day Zhang et al. (2013d ) PFOS, 98% PFOS, 85% PFOS PFOS, 98% PFOS, 98% PFOS, 98% PFOS, 98% Repeated dose study, immunotoxicity, C57BL/6 mice (12 males per group), gavage, 5, 20, 40 mg/kg bw per day, for 7 days Repeated dose study, immunotoxicity, BALB/c mice (5 females per group), gavage, 20 mg/kg bw per day, 21 days Reduced NK activity, antibody response, lymphocyte proliferation Reduced antibody response and NK activity, but accompanied by body weight effects Repeated dose study, Effects on body 0.25 immunotoxicity, B6C3F1 weight and liver mice (5 males per , no immune group), food, 0.25 mg/kg effects bw per day for 28 days Repeated dose study, immunotoxicity, B6C3F1 mice (5 females per group), gavage, 0.0331, 0.0993, 9.3 mg/kg bw per day, 28 days TNF and IL-6 up and down, but no doseresponse 5 30 0.0331 Repeated dose study, B6C3F1 mice (5-10 females), gavage, 3.31, 16.6, 33.1, 166 g/kg bw per day, 28 days Increased ex vivo IL-6 0.00331 Repeated dose study, Sprague-Dawley rats (15 males or female per group), diet, 0.14, 1.33, 3.21, 6.31 mg/kg bw per day, 28 days Repeated dose study, B6C3F1 mice (5 males or females per group), gavage, 0.166, 1.66, 3.31, 16.6, 33.1, 166 g/kg per day, 28 days Reduced total IgG1 levels in serum Reduced specific antibody Response (PFCs) 0.14 1.33 0.000166 0.00166 97.25 g/mL Zheng et al. (2009, 2011) Not reported Vetvick a and Vetvick ova (2013) 11.6 g/mL Qazi et al. (2010) Not reported Mollen hauer et al. (2011) <1 ng/mL (LOQ) Fair et al. (2011) 0.95 g/mL at 0.14 mg/kg bw per day, 13.45 g/mL at 1.33 mg/kg bw per day 17.8n/ ng/mL at 0.000166 mg/kg bw per day, 91.5 ng/mL at 0.00166 mg/kg bw per day Lefebv re et al. (2008) PedenAdams et al. (2008) 17 Substance (%), EC/CAS, formula study design, species, route of exposure, doses (guideline/similar to guideline/nonguideline), n animals Observed effects and remarks NO(A)EL (mg/kg bw/d) LO(A)EL (mg/kg bw/d) PFOS PFOS, 98% PFOS, 98% PFOS, 98% PFOS, 98% PFOS (purity NR) PFDS Repeated dose study, B6C3F1 mice (30 females per group), gavage, 5, 25 g/kg per day, 21 days Reduced survival after challenge with influenza virus 0.005 Repeated dose study, C57BL/6 mice (10-12 males per group), gavage, 8.3, 16.7, 83.33, 416.7, 833.3 g/kg bw per day for 60 days Repeated dose study, C57BL/6 mice (6 males per group), gavage, 8.3, 16.7, 83.33, 416.7, 833.3 g/kg bw per day for 60 days Repeated dose study, C57BL/6 mice (12 males per group), gavage, 8.3, 16.7, 83.33, 416.7, 833.3 g/kg bw per day for 60 days Repeated dose study, C57BL/6 mice (4 per group), 6-8 weeks old, exposed to 2 mg PFOS/kg bw per day for 7 days Repeated dose study, ICR mice (number, sex NR), sensitized to ovalbumin on day 0, and orally exposed to 50-150 mg PFOS/kg bw on days 9, 11, and 13 Antibody responses down. IL-4 and IL-10, TNF-a, IL-1b, values up and down. IgM decrease IgG, IgE increase Apoptotic lymphocytes, IL 12 production after Citrobacter rodentium infection Aggrevated allergic inflammation in an ovalbumin model 0.0083 0.0167 0.0167 0.025 0.0833 0.0833 0.0833 2 50 mg/kg, three times Key parameters / targets not add-ressed Serum/tissue concentrate-ion of PFAS /metabolites (time of sampling) Refere nce 189 ng/mL at 0.005 mg/kg bw per day, 670 ng/mL at 0.025 mg/kg bw per day 0.84 g/mL at 0.0083 mg/kg bw per day, 8.21 g/mL at 0.0833 mg/kg bw per day 10.75 g/mL at 0.0833 mg/kg per day , 2.36 g/mL at 0.0167 mg/kg per day Guruge et al. (2009) Dong et al. (2009) Dong et al., 2011 0.84 g/mL at 0.0833 mg/kg per day, not reported at 0.0167 mg/kg per day Not reported Dong et al., 2012 Suo et al., 2017 Not reported Lee et al., 2018 TFMS