Document jg5Kr8qgrEB4g498wMZx1m1pp

STLS F V F R N TRENT STL Chicago 2-117 Rond Street University Park, IL 60466 Tel: 708 534 5200 Fax; 708 534 5211 www.stl-inc.com V E R N T R E N T L A B O R A T O R IE S A N A L Y T IC A L R E PO R T JOB NUMBER: 233.2 5 P r e p a r e d 'For : W e s t o n . S o l u t i o n s , Inc. 1400 W e s t o n Way' Buil d i n g -5-2 West Cheater, PA 19360-1499 Project: Confidential Decatur - FC Investigation Attention: Cai Kesari Date: 0-1/13/2005 /(try 1 Signature f\ ^ Name; R i c h a r d C. Wright Ti t-l.e : Proj ect Manager E-Mail : rwr.i g h t @ s t l -ine .com j)p jt r Date STL Chicago 2417 Bond Street U n i v e r s i t y Park, II, 60466 PHONE: (70S) 534-5200 F A X . ,: (708) 534-5211 This Report Contains (_g_) Pages Leader; in Environmental Testing Severn Trent Laboratories, Inn, WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR - FC INVESTIGATION JOB# 233025 Data Summary............................................................... 1 Chain of Custody......................................................... 34 Case Narrative............................................................. 42 Raw D ata......................................................................44 STL Chicago is part of Severn Trent Laboratories, Inc. SAMPLE INFORMATION Date: 01/13/2005. Job Number. 233025 Customer... Weston Solutions, Inc. Attn...... Jai Kesari Project Number,....... : 20004691 Customer Project I D ,: CONFIDENTIAL D6CATUR Project Description___ : Confidential Decatur - Fc Investigation Laboratory Sample ID 233025-1 233025-2 233025-3 233025-4 233025-5 233025-6 233025-7 233025-3 233025-9 233025-10 233025-11 233025-12 233025-13 233025-14 233025-15 233025-16 233025-17 233025-18 233025-19 233025-20 233025-21 233025-22 233025-23 233025-24 233025-25 233025-26 .Customer .SampleID. " DF8b-SB-134R-0-Q050 DF8b-SBC-134R-0-0000 DF8b-SBC-134R-0-0050 DF8b-SBC-134R-0-0100 DFSb-SEC-134R-0-0150 DF8b-SBC-134R-0-0200 DF8b-SB-134R-0-0270 DF8b-SBC-134R-0-0250 DF14-SE-136B-0-0050 DF14-SE-136B-0-0290 DFSb-SB-134R-0-0000 DF8b-SB-134R-0-0005 DF&b-SB-134R-0-0010 DF8b-SB-134R-0-0020 DF8b-SB-1346-0-0050 DFSb-SB-134B-0-0Q9Q DF09-SB-130R-0-0050 DF09-SB-130R-0-0150 DF8b-SB-134B-0-0000 DF6b-SE-134B-0-0005 DF8b-SB-134B-0-00l0 DF8-SB-134B-0-0020 DF9-SB-13R--0 DF09-SE-130R-0-0005 DF09-SB-130R-0-0010 DF09-SB-130K-0-0020 sample Matrix sai l Sei 1 Soil Soil soi l Soil Soil Soil soi l Soil Soil soi l Sd 1 Soi L Soi L So} l Soi l soi l soi l Soi l Soil soi l soi l Soil Soil Soi L ' Pete Sampled 12/17/2004 12/17/2004 12/17/2004 12/17/2004 12/17/2004 12/17/2004 12/17/2004 12/17/2004 12/16/2004 12/16/2004 12/16/2004 12/16/2004 12/16/2004 12/16/2004 12/21/2004 12/21/2004 12/21/2004 12/21/2004 12/20/2004 12/20/2004 12/20/2004 12/20/2004 12/20/2004 12/20/2004 12/20/2004 12/20/2004 Time: Sampled 08:45 08:50 09:10 09:15 09:30 09:50 09:55 10:00 13:40 14:25 15:05 15:15 15:20 15:35 08:45 09:00 14:20 14:50 13:45 13:55 14:10 14:25 16:00 16:10 16:25 16:35 Time Received; : Received.- 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 12/27/2004 09:00 Page 1 1 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233025 CUSTCWR Weston So Eut ions, Inc. Customer Sample ID: DF8b-SB-134R-0-0050 Date Sampled..... : 12/17/2004 Time Sampled..... : 08:45 Sample Matrix.... : Soil .. LABORATORY TEST RESULTS PROJECT CONFIDENTIAL DECAWJR.;.' Laboratory Sanple ID: 233025-1 Date Received.......: 12/27/2004 Time Received.......: 09:00 Date:01/13/2005 ATTN: Jai Keri ' TEST METHOD Lloyd Kahn PARAMETEft/TE&T DESCRIPTION Total Organic Carbon (Soils) TOC Average Duplicates, Solid SAMPLE RESULT 3 FLAGS 1300 L 83 DILUTION UNITS- BATED-' 0T DATE/TTME TECH 320 1 mg/Kg 138154 12/28/D4 1527 els : * ]n Descripti on = Dry Ugt. Page 2 STL Chicago is part of Severn Trent Laboratories, Inc. Job Nuifcer: 233025 I:CUSTOMR:;Weston ;Solutions ,.Inc, Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix.... DF8b -SBC-13iR-0-0000 12/17/2004 08:50 Soi t TEST MCTHOC Lloyd Kahn PARAHETER/TESiiDESCRIPTION ; Total Organic Carbon (Soils) TOC Average DupLicates, Solid LAB0RATOR TEST RESULTS PROJECT: CONFIDENTIAL DECATUR ' Laboratory Sample ID: 233025-2 Date Received...... : 12/27/2004 Time Received...... : 09:00 Date:01/13/2005 ATTN: Jai Kesari SAMP LE-RESULT 2300 FLAOS 88 RL DILUTION UNITS BATOR OT DATE/TIME TECH 340 mg/Kg 130154 12/28/04 1541 els * In Description = Dry Ugt. Page 3 STL Chicago is part of Severn Trent Laboratories, Inc. STL Chicago is part of Severn Trent Laboratories, Inc, Job Humber: 233025 CUSTOMER: Weston Solutions, Inc.; . Customer Sample ID: DF8b-5BC-134R-CI-0100 Date Sampled..... : 12/17/2004 Time SampLed..... : 09:15 Sample Matrix.... : Soi l | TEST METHOD Lloyd Kahn PARAMETER/TST DSCRPT TON Total Organic Carbon {Soils) TOC Average Duplicates, Solid t/3 LABORATORY TEST RESULTS Date:01/13/2005 PROJECT: IOHFIDEWTTAL - D C A T R ' . . ATTN: !Jaf fcesri Laboratory Sample ID: 233025-4 Date Received.......: 12/27/2004 Time Received.......: 09:00 " :: ' : ----: : : : . SAMPLE. RESULT:; Q: FLAGS MW. 750 91 RL 360 DILUTION. UNITS j BATCH:: DT PA7E/TIME -, TECH 1 mg/Kg 133154 12/26/04 1612 cLs * In Description = Dry Ugt, Page 5 j ____ i1 i STL Chicago is part of Severn Trent Laboratories, (ne* Jab Number: 233025 CUSTOMER ::Weston SoEutions;Inc,: Customer Sample [D: DF8b-SBC-134R-0-O15D Date Sampled...... :12/17/2004 Time Sampled...... :09:30 Sample Matrix..... :Soi l TEST:; METHOD: ;PARAMETER/TEST;DISERIP T 1 0 ! Lloyd Ifahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS :PROJECT: CON FIDEKT IAL:DECATUR. Laboratory Sample ID 233025-5 Date Received..... ,, 12/27/2004 Time Received...... 09:00 Date:01/13/2005 ATTM:. Jai '(Cesari SAMPLE RESULT 940 FLAGS ML 100 RE DILUTION UNITS p a t e h ; pt d a t e /tihe TECH 410 mg/Eg 138574 12/28/04 1656 cis * In Description = Dry Ugt. Page 6 STL Chicago s part of Severn Trent Laboratories, Ine. Job Ntmber: 233025 CUSTOMER: We.ston Solutions, InC. Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix.... DF3b-SB C-134R-0-0200 12/17/2004 09:50 Soi l TEST KETH0D Lloyd Kahn :PARAMETE R/TEST. :DESCRl PT|ON Total Organic Carbon (Soils) TOC Average Duplicates, Solid IABOUTOH TEST RESULTS PRJECT:COWFIDEUTfAL DECATUR' ' Laboratory Sample ID 233025-6 Date Received...... 12/27/2004 Time Received...... 09:00 Date:01/13/2005 ATTN: Jai (Cesari SAMPLE RESULT 450 FLASS MDL 93 RL: 360 DILUTION UR ITS BATCH BT D A T E / T W TECH mg/Kg 138574 12/28/04 1729 els In Description = Dry Ugt. Page 7 STL Chicago is part of Severn Trent Laboratories, Inc. Job Member: 233025 CUSTOMER: Weston Solutions,. Tre. Customer Sample ED: DF8b-SB-134R-0-0270 Pate Sampled...... :12/17/2004 Time Sampled...... :09:55 Sample Matrix..... :Soi L TEST METHOD- :PARAMETER/TEST :DESCRIPT10 Lloyd Kahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS 'PRO&CT: CONFIDENTIAL DEATUR ' Laboratory Sample IP: 233025-7 Date Received.......: 12/27/2004 Time Received.......: 09:00 Pate:01/I3/2005 ATTN: Jar Kesari. SAMPLE RESULT 390 flags MOL. 110 RL BiLieM UNITS: :BATCH; 0T DATE/TJME TECH 4 20 mg/Kg 138574 12/28/04 1756 els * In Description = Dry Ugt. Page 8 STL Chicago is part of Severn Trent Laboratories, Inc. Job Ntmber: 233025 CUSTOMER: Weston Solutions, Inc, Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix.... DFSb-SB C-134R-0-0250 12/17/2004 10:00 soi l TEST METHOD Lloyd Kahn :PARAMETER/TST :0ESCITIPTION : Total Organic Carbon (Soils) TOC Average Dlicates, Solid LABORATORY TEST RESULTS PROJECT:.CONFIDENTIAL DECATUR Laboratory Sample 10 233025-8 Date Received...... 12/27/2004 Time Received...... 09:00 Date:01/13/2005 ATTN: ' Jai- Kfrsarn. SAILLE r e s u l t ; : f l a g s ; 520 mdl 82 mRL BtIUJT:IW UNITS BATCH d a t e /tihe t e c h ; 320 mg/Kg 138574 12/28/04 1809 c ls In Description = Dry Wgt. Page 9 STL Chicago is part of Severn Trent Laboratories, Inc. O * In Description = Dry Wgt, Page 10 H vi STL Chicago is part of Severn Treni Laboratories, Ine. Job Nunber: 233D25 CUSTOMER: Weston Solutions, Inc. Customer Sample ID: DF14-SB-136B-D-029Q Date Sampled...... :12/16/2004 Time Sampled...... :14:25 Sample Matrix..... :Soil LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233025-10 Date Received....... :12/27/2004 Time Received....... :09:00 Date:01/13/2005 ATTN: Jai ICesari TEST METHOD- PARAMETER/TEST DESCRIP T OPT ; ' Lloyd Kahn Total Organic Carbon (Soils} TOC Average Duplicates, Solid ' SAMPLE RESULT Q FLAGS 740 *>L 98 Rl' ' ' DILUTION : - LINKS' : BATCH DT DATE/TME TECH 3eo T mg/Kg 138154 12/28/04 1355 els * In Description = Dry Wgt. Page 11 __ l a STL Chicago is part of Severn Trent Laboratories, Inc. Job Ntnber: 233025 CUSTOMER:;Weston Solutions,:Inc. ' Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix.... DF3b-SE-134R-0- 0000 12/16/2004 15:05 soil TEST METHOD :PARWie TER/TEST iDESCRI P H O N ; Lloyd ICahn :Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID 233025-11 Date Received._____ 12/27/2004 Time Received...... 09:00 Date:01/13/2005 ATTN: Jai (Cesari SAMPLE RESULT 20000 FLAGS MOL 750 RL 290 0 Id lLUT ION .UNITS :BATCH DT GATE/TIME TECS mg/Kg T38154 H 2/28/04 1416 els In Descri P* ion = Dry Ugt. Page 12 STL Chicago is part of Severn Trent Laboratories, Inc. & STL Chicago is part of Severn Trent Laboratori es, Inc. Job Muirber: 333025 CUSTOMER: Weston solutions, Inc;. Customer Sample ]D: DFSb-5B-134R-0-0D10 Date Sampled..... : 12/16/2004 Time Sampled..... : 15:20 SampLe Matrix.... : Soil TEST: METHOD Lloyd Kahn ?PARAMETER/TEST:DESCRIPtlON Total Organic Carbon (Soils) TOC Average Duplicates, Solid vi LABORATORI TEST RESULT S PROJECT: CONFIDENTIAL DECATUR'' Laboratory SanpLe ID 233025-13 Date Received...... 12/27/2004 Time Received...... 09:00 Date:01/13/2005 .ATTN; Jai Kesari ' SAMPLE. RESULT 1500 FLAGS MDL 130 RL DILUTION UNITS 'BATCH OT DATE/TIME TCtt 500 mg/Kg 138154 12/28/04 1453 els n Description = Dry Wgt. Page 14 STL Chicago is part of Severn Trent Laboratories, Inc. i H * In Description = Dry Wgt. Page 15 STL Chicago is part of Severn Trent Laboratories, Inc. 'H * In Description = Dry Ugt. Page 16 STL Chicago is part of Severn Trent Laboratories, Inc. i'* * In Description = Dry Ugt. Page 17 STL Chicago is part of Severn Trent Laboratories, Inc. STL Chicago is part of Severn Trent Laboratores, Inc. Job Humber: 233025 .CUSTOMER::Weston Sotutions, .Inc. Customer Sample 10: DFQ9-SB-130R-0-0I50 Date Sampled...... :12/21/2004 Time Sampled...... :14:50 Sample Hatrix..... :Soil TEST-METHOD Lloyd Kahn ;PARAMETER/fST DESCRIPTICH : Total Organic Carbon <Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: OWFIDRTI&L DECATUR;'. ' Laboratory Sample ID: 233025-18 Date Received...... : 12/27/2004 Time Received...... : 09:00 Date:01/13/2005 ' TM- JaT Kesari-' SAMPLE RESULT 620 FLAGS m d l 95 RL' 0 1LUT low 'LIMITS BATCH m DATE/TIME- TECH 370 mg/Kg 138574 12/28/04 2146 els In Description = Dry Wgt. Page 19 STL Chicago is part of Severn Trent Laboratories, Inc. O Jt * In Description = Dry Ugt. Page 20 STL Chicago is part oi Severn Trent Laboratories, ino. e-? STL Chicago is part of Severn Trent Laboratories, Inc. CM CM * In Description = Dry Ugt. Page 22 STL Chicago is part of Severn Trent Laboratories, Ine. C> STL Chicago is part of Severn Trent Laboratories, Inc. Job Nunber: 233025 CUSTOKE R: Wes ton ;SoLutions, :Inc. Customer Sample ID Date Sampled..... Tinte Sampled..... Sample Matrix.... DF09-SB-130R-C-000Q 12/20/2004 16:00 Soi l TEST METHCO Lloyd Kahn PARANETER/TE.ST:D ES0RIPTION ; Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS :PROJECT:!CONfIDENT IAL :DECATUR Laboratory Sample ID 233025-23 Date Received...... 12/27/2004 Time Received...... 09:00 Date:01/13/2005 ATTN : Jai Kesari SAMPLE RESULT 12000 flags; 270 RL 1100 DILUTION UNITS BATON er; DATE/TIM TEOtt mg/Kg 138574 12/29/04 0021 els * In Description = Dry Wgt. Page 24 STL Chicago is part of Severo Treni Laboratories, Ine. * [n Description = Dry Ugt. Page 25 STL Chicago is part of Severn Trent Laboratories, nc. O STL Chicago is part of Severn Trent Laboratories, [nc. Job Nimber: 233025 .CUSTOMER: Weston Solutions, Inc. Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix.... D F09-SB-13 Q R -0-0020 12/20/2004 16:35 Soil TEST METHOD !PARAMETER/TEST DESCRIPTtON Lloyd Kahn iTotal Organic Carbon (Soils) jTOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR ......... Laboratory Sample ID: 233025-26 Date Received.......: 12/27/2004 Time Received...... : 09:00 Date:01/13/2005 ATT Nr ifat Kessri SAMPLE:RESULT 1100 FLAGS 100 RL' iDILUTION UNtTS BATCH DTj DATE/TIME 'TECH 400 mg/Kg 138574 12/29/04 0101 els * In Description = Dry Wgt. Page 27 STL Chicago is part of Scvern Trent Laboratories, Ine. Job Number: 233025 LABORATORY CHRONICLE Hate: 01/13/2005 CUSTOMER;'.-Wstern Solutions,- Inc. PROJECT ; CONEtODITI AL DECATUR; ATTN', Jai .^sari Lab ID: 233025-1 METHOD EDD LLayd Kahn Client ID: DFSb-SB-134R-0-0050 DESCRIPTION Electronic Data Deliverable Total Organic Carbon (Soils) Lab ID: 233025-2 Client ID: DF8b-SBC-134R-0-0000 METHOD DESCRIPTION Lloyd Kahn Total organic Carbon (Soils) Lab ID: 233025-3 Client ID: DF8b-SBC-134R-0-0050 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-4 Client ID: DF8b-SBC-134R-0-0100 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-5 Client ID: DF8b"SBC-134R-0-D150 METHOD DESCRIPTION Lloyd Kahn Total organic Carbon (Soils) Lab ID; 233025-6 Client ID: DF8b-SBC-134R-0-0200 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (SoiLs) Lab ID: 233025-7 Client ID: DF8b-SB-134R-0-0270 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-8 Client ID: DFSb-SBC-134R-0-0250 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-9 Client ID: DF14-SB-136B-0-0050 METHOD DESCRIPTION L Loyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-10 Client ID: DF14-SB-136B-Q-Q290 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (SoiLs) Lab ID: 233025-11 Client ID: DF8b-SB-134R-0-0000 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (SoiLs) Lab ID: 233025-12 Client ID: DF8b-SB-134R-0-0005 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-13 Client ID: DF8b-SB-134R-0-0010 METHOD DESCRIPTION LLoyd Kahn TotaL Organic Carbon (Soils) Lab ID: 233025-14 client ID: DF8b-SB-134R-0-0020 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-15 Client ID: DF8b-SB-134B-0-OD50 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (SoiLs) Date Recvd: 12/27/2004 Sample Date: 12/17/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 1 133154 138154 12/28/2004 1527 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/17/2004 RUN# BATCH# PREP BT #(5) d a t e /t i me a n a l yze d 1 138154 138154 12/28/2004 1541 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/17/2004 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 138154 138154 12/28/2004 1556 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/17/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138154 138154 12/28/2004 1612 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/17/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138574 138574 12/28/2004 1656 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/17/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138574 138574 12/28/2004 1729 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/17/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138574 138574 12/28/2004 1756 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/17/2004 RUN# BATCH# PREP BT #(5> DATE/TIME ANALYZED 1 138574 138574 12/28/2004 1S09 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/16/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138154 138154 12/28/2004 1334 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/16/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138154 138154 12/28/2004 1355 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/16/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138154 138154 12/28/2004 1418 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/16/2D04 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138154 138154 12/28/2004 1433 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/16/2004 RUN# BATCH# PREP BT #(5> DATE/TIME ANALYZED 1 138154 138154 12/28/2004 1453 DILUTION Date Recvd: 12/27/2D04 Sample Date; 12/16/2004 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 138154 138154 12/28/2004 1512 DILUTION Date Recvd; 12/27/2004 Sample Date: 12/21/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138574 138574 12/28/2004 1958 DILUTION STL Chicago is part of Sovcrn Trent Laboratories, Ine. Job Number: 233025 LABORATORY CHRONICLE Data: 01/13/2005 CUSTOMER: Weston Solutions, Inc. '..PROJECT: CONFIDENTIAL DECATUR ' . ATTN:. Jaii Kesari Lab ID: 233025-16 Client ID: DF8b-5B-134B-0-0090 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-17 Client ID: DF09-SB-130R-0-0050 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-18 Client ID: DF09-SB-13R--0150 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-19 Client ID: DF8b-SB-134B-0-0000 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-20 Client ID: DF8b-SB-134B-0-0005 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-21 Client ID: DF8b-SB-134B-0-0010 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Lab ID; 233025-22 Client ID: DF8b-SB-134B--20 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-23 CLient ID: DF09-SB-130R-0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (SoiLs) Lab ID: 233025-24 Client ID: DF09-SB-130R-0-0005 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-25 Client ID: DFQ9-SB-130R-0-0010 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233025-26 Client ID: DF09-SB-130R-0-002Q METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Date Recvd: 12/27/2004 Sample Date: 12/21/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138574 138574 12/28/2004 2029 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/21/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 13S574 138574 12/28/2004 2053 DILUTION Date Recvd: 12/27/2004 sample Date: 12/21/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138574 138574 12/28/2004 2146 DILUTION Date Recvd: 12/27/2004 sample Date: 12/20/2004 RUN# BATCH# PREP BT #<S> DATE/TIME ANALYZED 1 138574 138574 12/28/2004 2227 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/20/2004 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 138574 1385 74 12/2S/2004 2304 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/20/2004 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 138574 138574 12/28/2004 2355 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/20/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138574 138574 12/29/2004 0007 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/20/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138574 138574 12/29/2004 0021 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/20/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 138574 138574 12/29/2004 0035 DILUTION Date Recvd: 12/27/2004 Sample Date: 12/20/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED DILUTION 1 138574 138574 12/29/2004 0050 Date Recvd: 12/27/2004 Sample Date: 12/20/2004 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED DILUTION 1 138574 138574 12/29/2004 0101 Job Number .: 233025 !CUST(WER : Weston So lut ions,,v:lnc*. ; Q U A L T Y CO N T R O l R E S U L T S PROJECT: CONFIDENTIAL DECATUR. Report Date : 01/13/2005 ATTN: J6 !Srr; Test Mpthnrf Method inser ptin.:::Tota 1 Organic Carbon (Soi Is) Parameter..,. organic Carbon,.Tot, .(TOC) ''' QC Lab JO Reagent uni ts ICV 138154-002 I04LSTTC2 ME 138154-003 LCS 138154-004 I0FSTLK3 LCD 138154-005 I00FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg QC Result QC ResuLt 1871,70 32.00 U 3267.53 5753.06 3267.58 CCV 138154-01 I04LSTTC2 mg/Kg CCB 138154-017 mg/Kg 1880.20 32.00 U FVntrh - nftlSi'. Equipment Code;...: TQC4 Test Code : TOC True Value 2000.00 4730.00 4780.00 2000.00 Orig. Va Lue QC Calc. F 94 165,70 184.84 U 68 U 120 55 94 * * Limits % 85-115 % 53-140 % 53-140 R 30 % 85-115 Date Time 12/28/2004 0946 12/23/2004 0950 12/28/2004 1004 12/28/2004 1016 12/28/2004 1305 12/28/2004 1308 Test Method. LlydiKahn Method D escription;To -al Organic Carbon (Si Is) Parameter...; .... .: Or janic carbon, Tot. <T0C> QC Lab ID Reagent Uni ts CCV 138574-016 I04LSTTC2 MB 138574-003 LCS 133574-004 IO0FSTLK3 LCD 133574-005 I00FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg QC Result QC ResuLt 2062.37 32.00 4231,18 3035,49 U CCV 138574-016 I04LSTTC2 CCB 138574-017 CCV 138574-016 I04LSTTC2 CCB 133574-017 mg/Kg mg/Kg mg/Kg mg/Kg 1310.95 32.00 1324.75 32.00 U U Batch...... 138574 Equipment :Cede....: TOC4 True Value 2000.00 Orig. Value 4780.00 4780.00 2000.00 2000.00 Analyst., >: c.ts ..... Test,'Code, TOC QC CLc. F * Limits Date Time 103 % 85-115 12/28/2004 1630 12/28/2004 1633 89 % 53-140 12/28/2004 1639 64 % 53-140 12/28/2004 1646 91 % 85-115 12/28/2004 2341 12/28/2004 2348 91 % 85-115 12/29/2004 0114 12/29/2004 0117 Test Method.. .Method Description.: Total Organic Carbon.(Soi Is) Parameter.,,. ......: TOC Average THjplicates Batch___ 138574 . Equipment Code___ : TOC4 QC Lab JD Reagent Uhi ts MS 233025-17 I04LSTTC2 mg/Kg MSD 233025-17 I04LSTTC2 mg/Kg QC ResuLt 2071.40 2528.18 QC Result 2071.40 True Value 2000.00 2000.00 Orig. Value 802.36 802.36 Analyst.. : els Test Code : TOCAV2 QC Calc. F * Limits 79 94 Date Time 12/28/2004 2119 12/28/2004 2132 Page 30 * 4=% REC, R=RPD, A=ABS Di ff., 0=% Dff. 20 QUALI TY A&Uf cAN: ; N. Hb$ R E F E R E NC E S AND NOTS Report Date: 01/13/2005 REPORT COMMENTS 1) All pages of this report are integral parts of the analytical data. Therefore, this report should be reproduced only in its entirety. 2) Soil, sediment and sludge sample results are reported on a "dry weight" basis except when analyzed for landfill disposal or incineration parameters. All other solid matrix samples are reported on an "as received" basis unless noted differently. 3) Reporting limits are adjusted for sample size used, dilutions and moisture content if applicable. A) The test results for the noted analytical itiethad(s) meet the requirements of NELAC. Lab Cert. ID# 100201 5) According to 40CFR Part 136,3, pH, Chlorine Residual and Dissolved Oxygen analyses are to be performed immediately after aqueous sample collection. When these parameters are not indicated as field (e.g. pH Field) they were not analyzed immediately, but as soon as possible on laboratory receipt. CLossary of flags, qualifiers and abbreviations (any number of which may appear in the report) Inorganic Qualifiers (Q-Column) U Analyte was not detected at or above the stated limit. < Not detected at or above the reporting limit. J Result is less than the RL, but greater than or equal to the method detection limit. B Result is less than the CRDL/RL, but greater than or equal to the IDL/MDL. S Result was determined by the Method of Standard Additions. F AFCEE: Result is less than the RL, but greater than or equal to the methoddetection Limit. Inorganic Flags (Flag column) ICV,CCV,ICB,CCB,ISA,I SB,CRl,CRA,MRL: Instrument related QC exceed the upper or Lower control limits. * LCS, LCD, MD: Batch QC exceeds the upper or lower control Limits. + MSA correlation coefficient is less than 0.005. 4 MS, MSD: The analyte present in the original sample is 4 times greater than the matrix spike concentration; therefore, control limits are not applicable. E SD: Serial dilution exceeds the cohtrol Limits. H MB, EB1, EB2, EB3: Batch QC is greater than reporting Limit or had a negative instrument reading Lower than the absolute value of the reporting Limit. N MS, MSD: Spike recovery exceeds the upper or Lower controL limits. W AS(GFAA) Post-digestion spike was outside 85-115% controL Limits. Organic Qualifiers (Q - Column) U Analyte was hot detected at or above the stated Limit. ND Compound not detected. J Result is an estimated value below the reporting Limit or a tentatively identified compound (TIC). Q Result was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/MS. Y The chromatographic response resembles a typical fuel pattern. 2 The chromatographic response does not resemble a typicaL fuel pattern. E Result exceeded ceLibratian range, secondary dilution required. F AFCEE:Result is an estimated value below the reporting limit or a tentativelyidentified compound (TIC) Organic Flags (Flags Column) B MB: Batch QC is greater than reporting Limit. * Lcs, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds the upper or lowercontrol Limits. EB1, EBZ, EB3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range a Concentration is below the method Reporting Limit (RL) B Compound was found in the blank and sample. D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for ahaLysis; also compounds analyzed at a diLution will be flagged with a D. H Alternate peak selection upon analytical review I Indicates the presence of an interfence, recovery is not calculated. M Manually integrated compound. P The lower of the two values is reported when the % difference between the results of two DC columns is Page 31 R E F E RE.N C S A N P N O T E S Report Date;.01/13/2005 greater than 25%. Abbreviations AS Post Digestion Spike (GFAA Samples - See Note 1 below) Batch Designation given to identify a specific extraction, digestion, preparation set, or analysis set CAP capillary Column CCB Continuing Calibration Blank CCV Continuing Calibration Verification CF Confirmation ana Lysis of original Cl Confirmation analysis of A1 or D1 C2 Confirmation analysis of A2 or D2 C3 Confirmation analysis of A3 or D3 CRA Low Level Standard Check - GFAA; Mercury CR1 Low Level standard Check - ICP CV CaliLbration Verification Standard Dil Fac Dilution Factor Secondary diLution analysis D1 Dilution 1 D2 DiLution 2 D3 Di Lution 3 DLFac Detection Limit Factor DSH Distilled Standard High Level DSL Distilled standard - Low Level DSM Distilled Standard - Medium Level EB1 Extraction Blank 1 EBZ Extraction Blank 2 EB3 DI Blank ELC Method Extracted LCS ELD Method Extracted LCD ICAL Initial calibration ICB Initial Calibration Blank lev initial Calibration Verification IDL Instrument Detection Limit ISA Interference Check Sample A - ICAP ISB interference Check Sample B - 1CAP Job No. The first six digits of the sample ID which refers to a specific client, project and sample group Lab ID An 8 number unique Laboratory identification LCD Laboratory Control Standard Duplicate LCS Laboratory Control Standard with reagent grade water or a matrix free from the analyte of interest MB Method Blank or (PB) Preparation BLank MD Method Duplicate MDL Method Detection Limit MLE Medium Level Extraction Blank MRL Method Reporting Limit Standard MSA Method of Standard Additions MS Matrix Spike MSD Matrix Spike Duplicate ND Not Detected PREPF Preparation factor used by the Laboratory's Information Management System (LIMS) PDS Post Digestion Spike (ICAP) RA Re-analysis of original Al Re-analysis of D1 A2 Re-analysis of D2 A3 Re-ana Lysis of D3 RD Re-extract ion of dilution RE Re-extract ion of original Rc Re-extraction Confirmation RL Reporting Limit RPD Relative Percent Difference of duplicate (unrounded) analyses RRF Relative Response Factor RT Retention Time Page 32 quality A ssurance m e T H0bs H E f E H E N C .$ A M D . N O T E S ;... report Dates 01/13/EQQ5 RTW Retention Time Window Sample ID A 9 digit nunber unique for each sample* the first six digits are referred as the job number SCB Seeded Control Blahk SD Serial Dilution (Calculated when sample concentration exceeds 50 times the MDL) UCB Unseeded Control Blank SSV Second Source Verification standard SLCS Solid Laboratory Control Standard(LCS) PHC pH Calibration Check LCSP pH Laboratory Control Sample LCDP pH Laboratory Control Sample Duplicate MDPH pH Sample Duplicate MDFP Flashpoint Sample Duplicate LCFP Flashpoint LCS Gl Gelex Check Standard Range 0-1 G2 Gelex check Standard Range 1-10 G3 Gelex Check standard Range 10-100 G4 Gelex Check Standard Range 100-1000 Note 1: The Post Spike Designation on Batch QC for GFAA is designated with an "S" added to the current abbreviation used. EX. LCS S=LCS Post Spike (GFAA); MSS=MS Post Spike (GFAA) Note 2: The MD calculates an absolute difference (A) when the sampLe concentration is less than 5 times the reporting limit. The control limit is represented as +/- the RL. Page 33 33 CHAIN OF CUSTODY CHAIN OF CUSTODY/ ANALYSIS REQUEST FORM Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE of PRO JECT INFORMATION CEient: W esto n S o lu tio n s, Inc. 1400 W eston W ay, Bldg. 5-2 W est Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai K esari email: i.kesa rifo)w esto nso lution s .com Project Name: Reference No: Decatur, Alabama 02181-129-081-0001 ANALYSES REQUESTED Sampler: T Frinak, A Murphy P.O.#: Quotation #: a SAMPLE ANALYSIS ExyLIMS # 1 Client Sam ple Identification DF8b SB 134R 0050 DF8b SBC 134R 0000 Collection Collection Date Time wo CL Ea 'oS. $oE o~ z o 17-Dec-04 8:45 X 17-Dec-04 8:50 Sample Matrix SOIL SOIL C o m m en ts DF8b SBC 134R 0050 17-Dec-04 9:10 X DF8b SBC 134R 0100 17-Dec-04 9:15 X DF8b SBC 134R 0150 17-Dec-04 9:30 X DF8b SBC 134R 0200 17-Dec-04 9:50 X DF8b SB 134R 0270 17-Dec-04 9:55 X JL DF8b SBC 134R 0250 17-Dec-04 10:00 SOIL SOIL SOIL SOIL SOIL SOIL CHAIN OF CUSTODY R e lin q u i^ iie j^ B y : Date fl/zi/iP*} !/ 4 T im e C ooler ID No,: Received By: Fed Ex 0 Cooler Tem p. (C): Date Tim e //jM . . O 4.4- X X X i~1 PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality ControE Summary Add Calibration Summary Add Raw Data Other: CHAIN OF CUSTODY / ANALYSIS REQUEST FORM 2^30 a s s e v e ri Trent Laboratories T: 708 -534-52 00 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE of PRO JECT INFORMATION Client: W esto n S olutions, Inc. 1400 W eston W ay, Bldg. 5-2 W est Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jar Kesari email: i.kesari@ w esto nso Iution s. com Project Name: Reference No: DecaturhAlabama 02181-129-081-0001 ANALYSES REQUESTED Sampler: T Frinak, A Murphy P.O. #: Quotation #: SAMPLE ANALYSIS E x y U M S ff lo U 13 Client Sample Identification DF14 SB 136B 0 0050 DF14 SB 136B 0290 DF14 SB 134R 0000 DF14 SB 134R 0005 DF14 SB 134R 0010 DF14 SB 134R 0020 CoHection Date 16-Dec4D4 16-Dec-04 16-Dec-04 16-Dec-04 16-Dec-04 16-Dec-04 Collection Time 13:40 14:25 15:05 15:15 15:20 15:35 e I'oS. eo zu Sample Matrix SOiL SOIL SOIL SOIL SOIL SOIL C o m m en ts X X CHAIN OF CUSTODY Cooler ID No.: R e J1n q u ----- Date Tim e fz/zzUi J/:eO */ Received By: Feti Ex Cooler Tem p. (C): Date Tim e fjd&Ay PROJECT REQUIREMENTS Results Deadline: L aboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other: CHAIN OF CUSTODY / ANALYSIS REQUEST FORM w 2 `i l o ' X 5 Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE of PRO JECT INFORMATION Client: W eston S olutions, Inc. 1400 W eston Way, Bldg. 5-2 W est Chester, PA 19330 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari email: i kesa ri (a)westan so Iution s .com Project Name: Reference No: Decatur, Alabama 02181-129-081-0001 ANALYSES REQUESTED Sampler: T Frinak, A Murphy 256-552-6189 P.O. #: Quotation #: SAMPLE ANALYSIS ExyLIM S # IS' n Co Ilection Client Sam ple Identification ate DB8b SB 134B 0050 21-Dec-04 DB8b SB 134B 0090 21-Dec-04 -Q B S -fer S&- 0090- 3 1 - r w . n a DB09 SB 130R 0050 21-Dec-04 DB09 SB 130R 0150 21 -Dec-04 Collection Time 8:45 9:00 14:20 14:50 X X c2 oo. 4oE3 zu Sample Matrix SOIL SOIL WATER. SOIL SOIL C o m m en ts o O X -- X- X CHAIN OF CUSTODY Relinquished Byr Date V/ C o o le r ID No.: T im e Received By: Fed Ex CU" 4 C ooler Tem p. (C): Date Tim e deo -- I- PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: ^Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other: CHAIN OF CUSTODY / ANALYSIS REQUEST FORM uO <T3 Severn Trent Laboratories T: 708-534-5200 F: 708-504-5211 2417 Bond Street University Park, IL 60466 PAGE of PROJECT INFORM ATION Client: W esto n S o lu tio n s, Inc. 1400 W eston W ay, Bldg. 5-2 W est Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari email: i.k e s a ri western sol uti o ns. com Project Name: Reference No: Decatur, Alabama 02181-129-061-0001 ANALYSES REQUESTED Sampler: T Frinak, A Murphy 256-552-6189 P.O. #: Quotation #: SAMPLE ANALYSIS ExyLIMS # _iL M. 23 2* 25 Client Sam ple Identification DF3b SB 134B 0000 DF6b SB 134B 0005 DF8b SB 134B 0010 DF8b SB 134B 0020 DF09 SB 130R 0000 DF09 SB 130R 0005 DF09 SB 130R 0010 DF09 SB 130R 0020 CoJlection Date 20-Dec-04 20-Dec-04 20-Dec-04 20-Dec-04 20-Dec-04 20-Dec-04 20-Dec-04 20-Dec-Q4 C o lle c tio n T im e 13:45 13:55 14:10 14:25 16:00 16:10 16:25 16:35 X X oo. z oaeo Sample Matrix SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL C o m m en ts CHAIN OF CUSTODY Date. C ooler ID No.: Tim e Received By: Fed Ex IC f Cooler Tem p. (C): Date fA^f Tim e 0^*0 PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other: Sample Lot#: ^ _____i_l _S_ STL Chicago Internal Sample Custody Transfer Record Client: C ~ - - ~ -- Sample No. /_o /- o Analysis cU-C fUC Relinquished by: V J b 4- d i t `X / J e Received by: Date Time Comments f7/wfc~? / y , 2 .^ iJ) C3 C H 1 -2 2 -11-00 1/0-1/99 rpjsckl Job Sample Receipt checklist Report Job Number.: 233025 Location.: 57222 Check List Number.: 1 Description.: customer Job ID.... : Job Check List Date.: 12/27/2004 Project Number.: 20Q4891 Project Description.: Confidential Decatur - FC Investigation Customer___ Inc. Contact.: Jai Kesari Questions ? (Y/N) comments V2 Date of the Report..: 01/13/2005 Project Manager.... : rew Chain-of-Custody Present?........................ Y Here samples dropped off at or picked up by STL?.. N Custody seaL on shipping container?.... ,........ Y __ If "yes", custody seal intact?................. Y Custody seals on sample containers?.............. N ...If "yes", custody seal intact?................ Samples iced?........ Y Temperature of cooler acceptable? (4 deg C +/- 2). Y 4.4 Samples received intact (good condition)?......... Y Volatile samples acceptable? (no headspace)...... Correct containers used?............ Y Adequate sample volume provided?................. Y SampLes preserved correctly?.................... . Y Samples received within hoi ding-time?.......... .. Y Agreement between COC and sample labels?......... N Radioactivity at or below background levels?..... Y A Sample Discrepancy Report (SDR) was needed?.... Y If samples were shipped was there an air bill #?.. Y Sample Custodian Signature/Date........ Y Page 1 . 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FedEx 3Day Freight Tjrt U-5JEE:J| * Ct cLtet- vae * S r i S5B City U U L l 4 J L A l 2 YourInternal Billing Reference 3 To Ftedpierts Name 5 Ccmpany S " iJ / \ Address ^ <J ( 7 Tn'HDLTT*FJE<llEri(H Fi*l Fr>JL...>Vlii-a Albinees Q . t 5 \ State / l L ZIP 0 a O t;0 { y v v ^ Cj FPiona y ^ ;i S y V Y f Atj. - A J f _____^1 A / i B q Aj/j A t feoe rreJ JAp ' i P D t r i te P D ZJr r c t s i Dir-iHEin^ieiTXn !"~1 FedExPak* Ubpn^ftjeF.FfEci-:3;aifaeJ^Saici,iF^aPE*^: Qrher i~i 6 Special Handling . Lnuda f a jtx j ife tss liS t s r u 5- --. SAlUROfttBelhray I_JMi^Higri/krFE^Fhiu/ I-- : HOlGVttetftdav -" I at FedEx Locaiino1* I-- HU) Satjarfarf L i aiFrx Locatan A/K*t4ijP/bifcjrtOribiiDtwiartl-J ?idFedEg2DiYI.: Odes th e shipment rairtni d a tg e m s dws seted tentare- ------------- Ore tra u m a k e c k k i r i . --------- -- & hia Q V e s iI--_!trVft:eiIfhseji--'jJjinw- ; I Dry Ice ---- 1 MlLlU DaJgYU&ijJslirrtutvig.t l;jicon%ttF sb^E n^c-cts paL^Epr^. I ; Cargo Aircraft Only 7I Pr aayj ment jtfto; ,-n OCjBnF-:p. . Br^rFcdEjcAccLHccvOidCvd rh.btlH'jL -- -- -- i. Arct-Mc. 'Sendef aecipieet. LK&.3Becit-r iK ^ k n l [7|T^irciParty. | \Erede Ua d^ , [CashVQiec.lt- TotedPfickaa staUV^H feialOeclBredVelu1 i.Totl CtHwgns 2 jO ___ P jb*T,' leijiJ wlllXi JrJns ir-uredire^ |i;har lu. E m ba:th)r :e a 5 8 Release Signature Ston-Y^ris: Cm;iLCiLli-tL B-avr-di;aEy/-raiEg-jjhjaeuitTfTnit.^TEanuds hUo't-dUj^srFrft3:Nns>:;^ Questkins? VisitourtVab miMl 1.EU-j.Li:-.FEaiE-: BUj469-3359 *a DmI^.f Fji -*jf.iz*s-'fc*-:aai f x E - irrt: f.u : BSf. H CASE NARRATIVE Client: Job#: STL Chicago Wet Chemistry Case Narrative Weston Solutions, Inc, 233025 DateRec'd: 12/27/04 1. This narrative covers the analysis o f the samples in the above Job # for TOC by the Lloyd Kahn Method. The samples were analyzed for TOC in duplicate by furnace combustion and nondispersive infrared detection on aDohrmann Phoenix 8000 TOC analyzer, after acidification to remove inorganic carbon, and drying. No correction was made, therefore, for moisture content. The average o f the sample burns is reported, 2. The method-recommended holding time o f 2 weeks was met. Refer to the Laboratory Chronicle Page for dates o f sampling, receipt, and analysis. 3. The TOC calibration curve and the initial and continuing verification standards and blanks met acceptance criteria. 4. The method blanks were less than the reporting limit, 5. The LCSs were within acceptance limits, although the RPD between the LCS and LSD in each batch was high, 6. The matrix QC done on sample 233025-17 was within acceptance limits. 7. Sample 233025-11 was initially over-range and had to be repeated. The first attempt at sample 233025-20 was over-range, then the second attempt was too low. Both were immediately repeated, Please see the raw data. Qjc-vU Diane L. Harper Wet Chemistry Section Manager _____U - - Q Date 43 RAW DATA *** RUN LOG *## (V2 ) 1/11/05 17:45 Total Organic Carbon (Soils) Method Code..: TOCS j Batch Code.,.: 13(1154 / i 17 Status...... : RVWD Batch Date...: 12/28/04 Batch Time...: 1220 User Name...,..; els QC Code....... : TOCS Calc Code......: TOCS Location Code..: 57222 Equipment Code.: T0C4 Import Code--- : TEST CODE TTTTTTTTTTTTT OO 00D CCC I1 1 C C c c c cC sS SC CC 234AAA 2ASsS VVV V 2A 234 2 2 SAMPLE: Grp Pos 11 Sample ID __ ICAL_I04LSTTC1_ Dilution TEST POS Date /Time 1234 567 111222 789012 0000 0 12 __ ICVJ04LSTTC2_ 12/28/04 0946 0 13 __ MB__ 12/28/04 0950 0 14 15 ICS I00FSTLK3 3 __ LCDJ00FSTLK3_3 12/28/04 1004 0 12/28/04 1016 # 16 17 232881_1_S___ 232881_1_S_MS_I00FSTLK3_6 12/28/04 1023 12/28/04 1039 0 0 18 232BB1_1_S_MSD_IQFSTLK3_ 12/28/04 1047 0 19 232881_2_S___ 12/28/04 1055 0 1 10 232881 3 S 12/28/04 1106 0 1 11 232881_4_S___ 12/2B/04 1136 0 1 12 232881_5_S___ 12/28/04 1204 0 1 13 232881_6_S___ 12/28/04 1220 0 1 14 2 3 2 8 8 __ 12/28/04 1240 0 1 15 232881_8_S___ 12/28/04 1254 0 1 16 __ CCV_I04L5TTC2_ 12/28/04 1305 0 1 17 __ CCB__ 12/28/04 1308 0 1 18 233025_9_Si 12/28/04 1334 0 1 19 233025 10 S 12/28/04 1355 0 1 20 233025 I I S ' 12/28/04 1418 0 1 21 1 22 233025_12_S___ 233Q25_13_S___ 12/28/04 1433 12/28/04 1453 0 0 1 23 233025J 4 _ S ___ 12/28/04 1512 0 1 24 233025_1_S___ 12/28/04 1527 0 1 25 233025J_iS___ 12/28/04 1541 0 1 26 233025_3_S.__ 12/28/04 1556 0 1 27 233025_4_S___ 12/28/04 1612 0 1 28 ___CCV_I04LSTTC2_ 12/28/04 1630 45 *** RUN LOG (V2 ) Total Organic Carbon tsoils) Method Code..: TOCS Batch Code...: 136574 / Status.... Batch Date. Batch Time. SAMPLE: Grp Pos Sample ID 1 29 __ MB__ 1 30 ___LCSJD0FSTLK3_ 1 31 ___LCD_J0QFSTL!3_ 1 32 233025_5_S___ 1 33 233025_6_S___ 1 34 233025_7_S___ 1 35 233025_8_S__ 1 36 233025_15_S__ 1 37 233D25_16_S___ 1 38 233025_17_S__ 1 39 233025_17_S_MS_I04LSTTC2_38 1 40 233Q25_17_S_MSD_IQ4LSTTC2_38 1 41 233025_1B_S__ 1 42 233025_19_S___ 1 43 233025_20_S__ _ 1 44 __ CCV_JQ4LSTTC2_ 1 45 __ CCB__ 1 46 233025_21_S__ 1 47 233025_22_S__ _ 1 48 233025_23_S 1 49 233025_24_S__ 1 50 253025_25_S__ 1 51 233025_26^S_ 1 52 ,__ CCV_104LSTTC2_ 1 53 ___CCB_ 1/11/05 17:52 RVWD 12/20/04 1220 User Name. QC Code... Calc Code. els TOCS TOCS Location Code..: 57222 Equipment Code.: T0C4 Import Code___ : TEST CODE T T T TT T T T T TT T T OO00000CCC III C C cC cccS S S C C C 234AAA 2AsSS VVV V 2A 234 2 2 Di Luti on TEST POS Date / Time 1234567 111222 789 0 12 12/28/04 1633 0 12/28/04 1639 0 12/28/04 1646 * 12/28/04 1656 0 12/28/04 1729 0 12/28/04 1756 0 12/28/04 1809 0 12/26/04 1958 0 12/28/04 2029 0 12/28/04 2053 0 12/28/04 2119 0 12/28/04 2132 0 12/28/04 2146 0 12/28/04 2227 0 12/28/04 2304 0 12/28/04 2341 0 12/2B/04 2348 0 12/2B/D4 2355 0 12/29/04 0007 0 12/29/04 0021 0 12/29/04 0035 0 12/29/04 0050 0 12/29/04 0101 0 12/29/04 0114 0 12/29/04 0117 0 46 QC Surmary <V2 ) Total organic carbon (Soils) Method Code..: TOCS Batch Code...: 138154 Status...... : RVUD Batch Date...: 12/26/04 Batch Tine...: 1220 User Name....: cLs QC Code........ : TOCS Calc Code..,...: TOCS Location Code..: 57222 Grp Smp Sample ID 1 2 ___ICVJ04LSTTC2_ Pos Test Result 1 roc 1871.70 Known 2000 Original 1 3 ___MB_ 1 TOC -2.67 1 4 ___LCS_IOOFSTLK3_3 1 TOC 3267.5B 4780 -2.67 1 5 ___LCDJ00FSTLK33 1 TOC 5758.06 4780 -2.67 1 7 232881_1_S_MS_100FSTLK3_6 5 TOCAV2 3054.SB 1492.59 1 8 232881J_S_MSD_I0QFSTLK3_6 5 T0CAV2 3050.32 1492.59 1 16 ___CCV_I04LSTTC2_ 1 TOC 1880.20 2000 1 17 ___CCB__ 1 TOC -3.05 Report Date: 1/11/05 17:45 Equipment Code.: TOC4 Import Code....: Alternate QC Res 94 F QC Res F 3267.58 3054.88 68 120 93 84 94 55 * Page 1 47 *** QC Summary (V2 ) Total Organic Carbon (Soils) Report Date: 1/11/05 17:5Z Method Code..: TOCS Batch Code...: 138574 Statue--- RVUip Batch Data...: 12/28/04 Batch Time...: 1220 user Name....: cle QC Code...*....: TOCS Calc Code..... : TOCS Locstioh Code..: 57222 Equipment Coda.: T0C4 Import Code____: Grp Snip Sample ID Pos Test Result Known Original Alternate QC Res F QC Res F 1 28 ___CCV_IQ4LSTTC2_ 1 TOC 2062.37 2000 103 1 29 ___MB__ 1 TOC -4.15 1 30 ___LCSJ00FSTLK3_ 1 31 __ LCDJ00FSTLK3_ 1 TOC 1 TOC 4231.18 3035.49 4780 4780 89 64 33 * 1 39 233025J7mSJISj04L5TTC2_38 5 TOCAV2 2071.40 2000 802.36 79 1 40 233025J 7 S J 1 S D J 0 4 L S T T C 2 3 8 5 TCAV2 2528.18 2000 802.36 2071.40 94 1 44 ___CCV_I04LSTTC2_ 1 TOC 1B1.95 2000 91 1 45 ___CCB__ 1 TOC 1.71 1 52 CCV I04LSTTC2 1 TOC 1824.75 2000 91 1 53 ___CCB_ 1 TOC -1.90 Page 1 48 *** RAW TEST DATA ##* CV2 ) Total Organic carbon (Soils) Method Code.. TOCS / /^Hatch Date.*.: 12/28/04 Batch code... 130154 / i ^ v i Batch Tine...: 1220 Status...... RVWD ! User Marne___ : cLs SAMPLE: Grp Pos Sample ID 11 ICAL I04LSTTC1 12 ICV 704LSTTC2 13 MB 14 LCS I00FSTLK3 3 15 LCD I00FSTLK3 3 1 6 232881 1 S 1 7 232881 1 S MS I00FSTLK3 6 1 8 232881 1 S MSD I0QF5TLK3 6 1 9 232881 2 S 1 10 232881 3 S 1 11 232881 4 S 1 12 232881 5 S 1 13 232881 6 S 1 14 232881 7 S 1 15 232881 8 S 1 16 CCV I4LSTTC2 1 17 CCB 1 18 233025 9 s 1 19 233025 10 S 1 20 233025 11 S 1 21 233025 12 S 1 22 233025 13 S 1 23 233025 14 S 1 24 233025 1 S 1 25 233025 2 S 1 26 233025 3 S 1 27 233025 4 S 1 28 CCV I04LSTTC2 1 29 MB 1 30 LCS I0FSTLK3 1 31 LCD IQQFSLK3 1 32 233025 5 s 1 33 233025 6 S 1 34 233025 7 S 1 35 233025 8 S 1 36 233025 15 S 1 37 233025 16 S 1 38 233025 17 S 1 39 233025 17 S MS I04LSTTC2 38 1 40 233025 17 S MSD I04LSTTC2 3B 1 41 233025 18 S 1 42 233025 19 S 1 43 233025 20 S 1 44 CCV I04LSTTC2 1 45 CCB 1 46 233025 21 S 1 47 233025 22 s 1 48 233025 23 S 1 49 233025 24 S 1 50 233025 25 S 1 51 233025 26 S 1 52 CCV I04LSTTC2 1 53 ___CCB QC Cede.... Calc Code. Locatioh Code.: 57222 Di lut ion TOC mg/Kg TC2 mg/Kg Report Date; 1/11/05 17:46 Equipment Code.: TOC4 Import code--- : TOC3 mg/Kg TQC4 mg/Kg TOCAV2 mg/Kg 1871.70 -2.67 3267.58 5758.06 1384.17 3054.88 3050.32 2909.92 1618.28 1296.59 1334.96 1482.71 3707.80 1247.76 1880.20 -3.05 1856.81 869.54 15131.96 3254.29 1325.96 1001.31 1274.43 2172.44 956.02 632.97 2062.37 -4.15 4231.18 3035.49 624.86 328.63 191.53 225.61 1107.92 493.17 628.50 2071.40 2528.18 277.29 49264.77 3755.55 1810.95 1.71 3526.51 1847.69 12131.92 2458.86 1429.66 1209.24 1824.75 -1.90 1601.01 2834.76 1495.12 1540.31 1580.54 1308.71 3397.89 1021.76 1365.60 615.88 24272.64 3211.96 1605.36 1351.80 1334.33 2413.37 1016.06 862.54 1254.60 563.66 597.85 814.79 1367.41 842.78 976.22 952.89 21975.83 5128.51 1987.82 1563.12 11312.04 1768.38 1152.85 929.75 1492.59 3054.88 3050.32 2872.34 1556.70 1418.45 1457.75 1395.71 3552.85 1134.76 1611.20 742.71 19702.30 3233,12 1465,66 1176.56 1304.38 2292.90 986.04 747.75 939.73 446.14 394.69 520.20 1237.66 667.98 802.36 2071.40 2528.18 615.09 35620.30 4442.03 2757.16 1705.40 11721.98 2113.62 1291.26 1069.49 Page 1 43 *** RAW TEST DATA 4** <V2 ) Total Organic Carbon (Soils) Method Code.. Batch code__ TOCS 138154 it f i * 1* Batch Pate... Batch Time... 12/28/04 1220 Status...... RVWD User Name.... els SAMPLE: Grp Pdh Sample ID 11 ICAL IQ4LSTTC1 12 ICV I04LSTTC2 13 MB 14 LCS ID0FSTLK3 3 15 LCD I00FSTLK3 3 1 6 232881 1 S 1 7 232881 1 S MS I00FSTLK3 6 1 8 232881 1 S MSD I00FSTLK3 6 1 9 232881 2 S 1 10 232881 3 S 1 11 232881 4 S 1 12 232881 5 S 1 13 232881 6 S 1 14 232881 7 S 1 15 232881 8 S 1 16 CCV I4LSTTC2 1 17 CCB 1 18 233025 9 S 1 19 233025 1 S 1 20 233025 11 S 1 21 233025 12 S 1 22 233025 13 S 1 23 233025 14 S 1 24 233025 1 S 1 25 233025 2 S 1 26 233025 3 5 1 27 233025 4 S 1 28 CCV 04LSTTC2 1 29 MB 1 30 LCS I0FSTLK3 1 31 LCD I0FSTLK3 1 32 233025 5 S 1 33 233025 6 S 1 34 233025 7 S 1 35 233025 8 S 1 36 233025 15 S 1 37 233025 16 S 1 38 233025 17 S 1 39 233025 17 S MS I04LSTTC2 3B 1 40 233025 17 S MSD IQ4L5TTC2 38 1 41 233025 18 s 1 42 233025 19 S 1 43 233025 20 S 1 44 CCV I04LSTTC2 1 45 CCB 1 46 233025 21 s 1 47 233025 22 S 1 48 233025 23 S 1 49 233025 24 S 1 50 233025 25 S 1 51 233025 26 S 1 52 CCV I04LSTTC2 1 53 CCB QC Code....... : TOCS Calc C o d e . T O C S Location Code..: 57222 Dilution T0CAV3 mg/Kg TOCAV4 mg/Kg Report Date: 1/11/05 17:46 Equipment Code.: TQC4 Import Code...- : TOCR1 ug TGCR2 ug T0CR3 ug 93.5850 -0.4265 100.9681 159.4982 72.3923 181.1542 164.7172 172.2670 90,9472 69.4972 76.8937 81.2524 198.3675 40.8019 94.0099 -0.4885 99.1537 45.3030 78.6862 156.2057 51.3145 46.5611 77.8679 129.0429 49.9998 36.7758 103.1184 -0.6642 105.3565 83.4760 33.7427 16.3001 B.5995 13.8071 62.5975 29,3439 35,0701 128.8410 137.2804 15.1401 108.3825 53.7043 90.5473 0.2740 85.6943 47.3009 348.1862 59.9961 66.9082 48.9743 91.2375 "0.3044 93.0186 136.0685 74.3075 89.6460 84.4006 70.6701 181.4474 36.06B1 73.8788 32.3338 206.3174 140.6837 66.9434 68,1306 83.7958 137,0793 55.5785 46.5769 56.0807 33.9325 30.6101 51.7390 96.1290 62.0285 64.0403 50.2171 76.9154 96.9289 40.1539 54.2403 101.8084 115.1218 49.6878 55,0413 Page 2 50 *** RAW TEST DATA <V2 ) Total Organic Carbon (Soils) Method Code..: TOCS i Batch Code...: 138154 Status...... : RVUD ' / Botch Date...: 12/28/04 \ Batch Time,-.: 1220 User Name,,.,: cLs SAMPLE: Grp Pos Sample ID 11 ICAL I04LSTTC1 12 ICV I04LSTTC2 13 MB 14 LCS I0QFSTLK3 3 15 LCD I00FSTLK3 3 1 6 232881 1 S 1 7 232881 1 S fis 100FSTLK3 6 1 8 232881 1 S MSD 00FSTLK3 6 1 9 232881 2 S 1 10 232881 3 S 1 11 232881 4 S 1 12 232881 5 S 1 13 232881 6 S 1 14 2328B1 7 S 1 15 232881 8 S 1 16 CCV I04LSTTC2 1 17 COB 1 18 233025 9 S 1 19 233025 10 S 1 20 233025 11 S 1 21 233025 12 S 1 22 233025 13 S 1 23 233025 14 S 1 24 233025 1 S 1 25 233025 2 S 1 26 233025 3 S 1 27 233025 4 S 1 28 CCV IQ4LSTTC2 1 29 MB 1 30 ICS IO0FSTLK3 1 31 LCD I00FSTLK3 1 32 233025 5 S 1 33 233025 6 S 1 34 233025 7 S 1 35 233025 8 S 1 36 233025 15 S 1 37 233025 16 S 1 38 233025 17 S 1 39 233025 17 S HS I04LSTTC2 38 1 40 233025 17 B MSD J04LSTTC2 38 1 41 233025 18 S 1 42 233025 19 S 1 43 233025 20 S 1 44 CCV I04LBTTC2 1 45 CCB 1 46 233025 21 S 1 47 233025 22 S 1 48 233025 23 S 1 49 233025 24 S 1 50 233025 25 S 1 51 233025 26 S 1 52 CCV 04LSTC2 1 53 CCB QC Code....... : TOCS Calc Code.,,..,: TOCS Location Code..: 57222 Dilution TOCR4 ug WT1 fl Report Date: 1/11/05 17:46 Equipment Code,: TOC4 Import Code--- : WT2 WT3 WT4 ggg 0.05 0.16 0.0309 0.0277 0.0523 0.0593 0,0540 0.0592 0.0562 0.0536 0.0576 0.054B 0.0535 0.0327 0,05 0.16 0.0534 0.0521 0.0052 .4B 0.0387 0.0465 0.0611 0.0594 0.0523 0.0581 0.05 0.16 0.0249 0.0275 0.0540 0.0496 0.0449 0.0612 0.0565 0.0595 0.0558 0.0622 0.0543 0.0546 0.0022 0.0143 0.05 0.16 0.0243 0,0256 0.0287 0.0244 0.0468 0.0405 0.05 0.16 0.0581 0.0480 0.0497 0.0582 0.0534 0.0540 0.0534 0,0353 0.0541 0.0525 0.0085 0.0438 0.0417 0.0504 0.0628 0.056B 0.0547 0.0540 0.0447 0.0602 0.0512 0,0635 0,0703 0.0736 0.0656 0.0527 0.0035 0.0189 0.0202 0.0347 0.0090 0.0651 0.0431 0,0592 Page 3 51 *** RA TEST DATA *** (V2 ) Total Organic Carbon (Soi La) Method code..: TOCS , Batch Code...: 138154 Status...... : RVWD l /A Jt Batch Date...: 12/28/04 ' ' Batch Time...: 1220 User Name___ : cls SAMPLE: Grp Pos Sample ID 11 ICAL I04LSTTC1 12 ICV I04LSTTC2 13 MB 14 LCS I00FSTLK3 3 15 LCD I00FSTLK3 3 1 6 232881 1 S 1 7 232881 1 S MS I00FSTLK3 6 1 8 232881 1 S MSD I0QFSTLK3 6 1 9 232881 2 S 1 10 232881 3 s 1 11 232881 4 S 1 12 2328B1 5 S 1 13 232881 6 S 1 14 232881 7 S 1 15 232881 8 S 1 16 CCV I04LSTTC2 1 17 CCB 1 18 233025 9 S 1 19 233025 10 S 1 20 233025 11 S 1 21 233025 12 s 1 22 233025 13 S 1 23 233025 14 S 1 24 233025 1 S 1 25 233025 2 S 1 26 233025 3 S 1 27 233025 4 S 1 28 CCV IQ4LSTTC2 1 29 MB 1 30 LCS I00FSTLK3 1 31 LCD 100FSLK3 1 32 233025 5 S 1 33 233025 6 S 1 34 233025 7 S 1 35 233025 8 S 1 36 233025 15 S 1 37 233025 16 S 1 38 233025 17 S 1 39 233025 17 S MS I04LSTC2 38 1 40 233025 17 S MSD I04LSTTC2 38 1 41 233025 18 S 1 42 233025 19 S 1 43 233025 20 S 1 44 CCV IQ4LSTTC2 1 45 CCB 1 46 233025 21 S 1 47 233025 22 S 1 48 233025 23 S 1 49 233025 24 S 1 50 233025 25 S 1 51 233025 26 s 1 52 CCV I04LSTTC2 1 53 ___CCB OC Code....... : TOCS Cale Code*...,,: TOCS Location Code..: 57222 Dilution DLFAC N/A TC5 mg/Kg Report Date: 1/11/05 17:46 Equipment code.: TQC4 Import Code--- : TCS2 mg/Ka TCSAV2 mg/lfg TICS mg/Kg 3.2000 1.0000 5.1780 5.7762 2.8986 2,6981 2.9630 2.9851 3.0217 2*8623 2,BB29 2.9412 2.9935 4*7059 3,2000 1.0000 2.9767 3*0593 23,3577 3.4858 3.9801 3.3024 2.5827 2.7539 2.9907 2.8546 3.2000 1.0000 6*4257 5.8182 3.2421 2.9144 3.3299 2.5662 2.5237 2.4042 2.6359 2.5723 2.9466 2.9823 56.1404 9.6386 3.2000 1,0000 7.1910 5.3068 8.4881 3.5754 3.5595 3.2096 3.2000 1.0000 Page 4 52 STLChicago Total Organic/lnorganic Carbon Method: EPA 415.1 EPA 415.1, mod. for IC SW 846 9060 Lloyd Kahn L.S - Standard Curve: Date of curve loVfr:LabNet B atch: / 3 ^ ^ ^ d- / 57/ 4 )/h Instrum ent: Phoenix 8000 TOC 4 Matrix: soil water / 2 // iM ugC measured, ug C 0 ayez 10 / / . f< # 20 " Z ' / j y r 40 80 ------ 100 --- . 120 / 3 * - 200 300 400 y;`-<?02l.0Trf&f Corr. Coeff.: < ? , ? ? ? V-intercept: slope: Calculations: soils: mg/kg = ue C from instrument grams sample Soils are dried as part o f the preparation step, so do not correct for % solids. waters: mg/L ~ mg/L X dilution Standards Traceability: Stock I : Calibration and Curve : Stock II: LCS, 1CV, CCV, Matrix spikes Solid LCS : J T O 7 t fc > Spiking Levels; LCS mg/Kg lev ccv MS/MSD ) t> ifl'l) ' 1 ugC ugC mg/Kg I mg/Kg Analyst: Reviewer: V c S r r cj / T -tf e. ^ r r c Date of analysis: 11idDate: / / ).5 __________ STL Chicago TOC in Soils Method: Lloyd Kahn Page No. ns Book No.: Instrument: Phoenix 80QQ (TQC41 LabNet Batch: / 3 f f / W Ca lc u la tio n ; Date of Standard Curve: / / t 3 '/*? TOC (mg/kg) = ug C / grams sample Book # 3 7 ^ "* Faoe# MS, MSO Known Cone, (mg/kg) * 100 ug C / grams sample MS, MSD Observed (mg/kg) * ug C / grams sample MS, MSD Rec. * fobserved mo/ka - ava. sample result (ma/kal| x 100 known concentration in mg/kg Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve) f ^ ^ r r e f Stock II (ICV/CCV) t-6 r-t-c -L LCS Source ID LCS True Value h Acceptance Range _______ Sample ID: Sample Weight (g) ug C Comments: ... ifC S 'A O. OV 0. / G o Votr- ...... ....... T,. .....V . 0 0 .3 1, e. U T . g l i -7 ..x v % n - f \/ - / 7 . <7 < " / A *5. a . r f ? cy>" o- ^ L( w ?&Y / < r f . 99?s r 7 3 % 9 2 -s \ /y f- z , * 7 - , v ` <vi" <?3/yrC- / , / r /, / t v c . 3 * 7 .^ /#4LsY)Q,(/'V> /G V n m im , o , o r ^ 'Z . --O - O, fro / I l `D ", F3G. r v & C--t- O. & . 0~r> / ? (f.& s rc O , I ' T / X . O/" /' i ? /j.- 0<? 3? 7 Z ,'i^f O . T Y Z L CO, O v 9 ? n .G i'c c 1Y f r r s r ' . o 3?C -< r- n o f 3 / - e - C, O V VO . .. . ' * M 7 o, a .jv' :......... . -- 7 . OiO-^V > ~ r . O.0 3 0 ? ~ Y M iV O C \ fr i, 3X 2V 7 0 . 0 of. . ry ... ...... h tw <f/ f .......... * .......... .......... VO, Ibi9 Prep Analyst. A n a ly s t ^ Reviewed by; i/b u Date: m A q/ ^ Date: A7 Date: f X 54 CHI-22-12-096/B-Q5/01 STL Chicago TOC in Soils Page No,: _______ Book No.: 7 * ^ 7 Method: Lloyd Kahn Instrument: Phoenix 8000 (TQCA) LabNet Batch: / Calculation: Date of Standard Cun/:______________ TOC (mg/kg) = ug C / grams sample Book # _________Page # MS, MSD Known Cone, (mg/kg) = 100 ug C / grams sample MS, MSD Observed (mg/kg) * ug C / grams sample MS, MSD Ree. = [observed ma/ko - ava, sample result (mo/kgyi x 100 known concentration in mg/kg Standard Traceability; (Note: vyoridng Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve) Stock 11(ICV/CCV) LOS Source ID LCS True Value Acceptance Range, Sample ID: Sample W eight (g> ugC Comments: e .-Q .O ....... C O ^ , . ff ? - . - ' 0 ' ..... - W C . ^ l a e ry? , IfV l a y i o i v - ? r -r. - lo -H -- a. # y f fro -rl 0, n & 2. , r l7 , > ^ rrs T --- M A ? ? V? STW' 9 f': 7 ^ x y & t l & r -- - // , If ? ,o o tr W 2. -7 2- <2 O U F ' - / 7 > & 0 -3 * 7 ...........i ......~ / '!> o - o q t n " 14_ o .o ^ o (i - ' T -0 , 0 ( i l l - A - , 0<*TM ..... - 2 . - ( h O W i - 9... O 0 <r6 <7 ,ro. < 2 7 - . \ / (7 . o r Y 7 Prep Analyst: 7f j . m M . 'h n ; / / ) % , o n ; A i, >/lr i f rT^X H.lOlf Ti 1 , n i ^ r r F 'r f } iq , cr, r ? f r t T-3 3 /c A n a ly s t: Reviewed by:'"*y- " IQ j f U i n ) h n o r' CHI-22-12-096/8-06/01 STL Chicago TOC in Soils Page No.: Book No.: 117 7?7 Method; Lloyd Kahn instrument Phoenix ooo ;tqc4> LabNet ateh: / 3 ^ / C V C alculations: D a te a lStandard Curve: / 3 S ^ T 7 V . TOC (mg/kg) = ug C / grams sample B ook#_________Page # ......." " , MS, MSD Known Cone, (mg/kg) * 100 u g C / grams sample MS, M$D Observed (rtig/kg) * ug C / grams sample MS. MSD Rec. [observed ma/kg - avg. sample result fmo/ka)1 x100 known concentration in mg/kg Standard Traceability: (Note: Working Standards are prepared daily from the nqted Stock Solutions.) Stock I (Curve) LCS Source ID Acceptance Range Sample ID: 3 3 C O X -Y Sample Weight (g) O ,o rfi ug C Commente: C *C t/ c ) \ C cW LA p o - i C? ! < 3 . 01~ Y ( o . 02 .7 r ' ' 'T - 'V i ______I 0. 0 *\D ' -u -3- o. O . GUO?. ; o ' O . i/X ' -6 O .O o ia - ?.0 <<>s I " * f 5 - 05(0*5 ......I : 0 7T703 . - I l o O'. O W ' - K/ .o m u > ,i - )7 0 . 0 5 5 0 " ...(/ o -- 17/45 0 . / -f/kb . 0 - 0 f H 3 V "W .& z r/ >3 / / & / < r.m r w , y 7 o "P... . " 3 3 .7 4 3 7 - ....'r.... Su. o f ' .... ./.........:: ,,......... .../ ..3 0 I ... T... m ^szS ', 0 -9 *5 , 3 0 . ( il 07 73. S m p 5 1.0 3 30 (p'2 .s t 7 S <"*...... . '. .. .... '..'... ..`..- ...*- ^ ..--....' - ' '' ' ......... - ........ 3),:-s73^ ... ..- .......... .............. l o i . -... '....;... . ....-.-...-.. i 3 5 . 0 7 0 / \ . VZ.3, - - - - - -----L ^ f.O ` 103.. / .. - .....: ................... 19^ : Y i l Q L2 6 7 /. 'o f/fs & i n i s i V 3 7 . 2 8 0 '? d iv` 7 f:17 p w m y ,9 i : : Prep Analyst: A n alvst r ^ ^ r ^ Reviewed bv: U CHW2*73m/B-05/01 STL Chicago TOC in S o il* Page No.: * 1 .1 8 Book No.: ^ ^ I Method:- Lloyd Kahn Instrument Phoenix 6000 (TOC4 LabNet Batch: / 3 Y / t Y C a lc u la tio n : Date of Standard Curve: %YS~?Y ; TOC (mg/kg) = g C / grams sample .............. Book#________ P a g e # MS, MSD Known Cone, (mg/kg) * 100 ug C / grams sample MS, MSD Observed (mg/kg) = ug C / grams sample " ' >: MS, MSD Ree. - fobserved mo/ko - avo sample result (m o/ktiil x 100 known concentration in mg/kj Standard Traceability: (Note: Workiri sera prepared daily from the noted Stock Solutions.) Stock I (Curve) LCS Source ID Acceptance Range. Sample ID: Sample Weight (g) -i ........ Comments: - a a a 3 E r i & ..O . 0 5 4 U -- 16 , o s a 1 rS o.Q ni -- i \... . O) ,G -E > 4 5 OVeartrG$_ ....- j S e .. tfrQ O H ^ c i ic&.yizS - 1 ^ Oo.SS' --:.. : - ^ 5 "l|T 0 'y z M im " --GU-OCit^--- - / '9 0 v' ..90 O / 4 3 ... T- 1 ......... CcV .... o . o s ' 4 iiXoO m iV cfl r.1. csJ jQe-i4^ ... -- G^rtzr .c>t> .......... c ir> ..-1 f ) : | U .... < 3 3 2 0 % . 2J .....0 O Z 43 .... 0 5 rti? 1 ', - a / ' r? / 0 2 0 2 . ' .... .. '9 3 . . fi 0 3 0 (.0 *fl;3 (Y n ~9r - . 5 4. ;>f05.. ... -3t3 0 . 0 2 6 -/ ...'t ' ' ....-<23 . ...... J,,.- ........ .... 1 1-3 ? O - OP :4^'irif'f 4iS9^T- : ^rkec( ir\ TVipuKl -*3 O^G^fi i .O'Ro X ......: .. v " .' 0 6 * / * t - " Prep Analyst: Analyst: R eview ed by: Date:, /O lc ^ U f Date: Date; lU j.n S CHI-22-12-O96JB-S/01 STL Chicago Page No,:^ 1 1 9 . TOC in-Soils Book No.; Method: Lloyd Kahn Instrument: Phoenix BOQQ.(TOC4 LabNet Batch; C a lcu la tio n : Date of Standard Curve: sy? V TOC (mg/kg) * ug C / grams sample B o o k # _________ P a g e# MS, MSD Known Cone. (mg/kg) = 100 ug C / grams sample MS, MSD Observed (mg/kg) * ug C / grams sample MS, MSD Ree. * (observed mo/ko - ava, sample result fmo/kall x 100 known concentration irwTTSj/kg Standard Traceability: (Note: ;ing Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve) Stock II (ICV/CCV)___________ LOS Source ID LCS True Value Acceptance Range Sample ID: 3 ^ 025-230 J li? c ~ r\) o rft \ \ \ Sample Weight (g) r> C i4 c & O - O S ^ SL o .o < C .u ,, * ugC s s . o 4 iS ~, U(X, ! ' Comments: V V X ........................ V . `'V X ... . '' X \ ............. ..... ....................; " X : .. X ........... ...X ............................ ... 1 ' -- X .. ...... ......... : ........... .. - X .................. .TM.......... Prep Analyst: < ^ ^ < p ^ ^ - Analyst_ L M t y j L 'Z, //I Reviewed bv: " Date: Date: : ,>/>/, ./___ Dat: mi M 42.2-M 3/B 43S01 5S uaiiurHtiUM n e p u it r u m uaiv/i rrnc. u w r u uvo u . t j . u Cal. Curve ID: SOILCURVE Created: 12/13/2004 13:36 Calibration Factor (m): 9.841e+04 Y Intercept (b): -250134 r-squared: 0.99935 Standard ID Y X Expected Measured Message Date & Raw Data ug C ug C Time 0 ugram C -8891 0.000 2.451 No Sample Det 12/13/2004 11:24 10ugramC 911065 10.000 11.800 12/13/200411:42 20 ugram C 1853385 20.000 21.375 12/13/200411:48 40 ugram C 3745719 40.000 40.605 12/13/2004 12:04 120 ugram C 11194916 120.000 116.302 Endpoint Time 12/13/200412:28 200 ugram C 18654032 200.000 192,099 12/13/2004 12:46 300 ugram C 29462156 300.000 301.928 12/13/2004 12:59 400 ugram C 39451668 400.000 403.439 Endpoint Time 12/13/2004 13:19 Multiple Analysis Report Print Date/Time: 2004/12/29 12:27:02 Sample ID Result Std. Dev. RSD Mode ICV 93.5850 TC ICB-MB -0.4265 TO LCS 100.9681 TC LCD...................... ..........159.4982.. ...........TC .. 232881-1 72.3923 TC 232881-1 93.0186 TC 232881-1 m s........ ................181.1542... ...........TC .. 232881-1m sd 164.7172 TC 232881-2 172.2670 TC 232881-2.............. .............136.0685... ...........TC .. 232881-3 90.9472 TC 232881-3 265.0371 TC 232881-4.............. .............69 4972... .......... TC .. 232881-4 89.6460 TC 232881-3 74.3075 TC 232881-5.............. .............76.8937... 232881-5 84.4006 .......... TC TC 232881-6 81,2524 TC 232881-6.............. .............70.6701... ...........TC .. 232881-7 198.3675 TC 232881-7 181.4474 TC 232881-8.............. .............40.8019... ...........TC ,, 232881-8 36.0681 TC CCV 94.0099 TC CCB...................... ......... -0.4885... . ...TC ,, 233025-9 99.1537 TC 233025-9 73.8788 TC 233025-10............ ..............45.3030... .. ...TC .. 233025-10 32.3338 TC 233025-10 1446.1906 TC 233025-11............ ..............78.6862... .......... TC .. 233025-11 206.3174 TC 233025-12 156.2057 TC 233025-12............ ............. 140.6837... ...........TC .. 233025-13 51.3145 TG 233025-13 66.9434 TC 233025-14............ ..............46.6611... 233025-14 68.1306 233025-1 77.8679 233025-1..... ..................... 83.7958... ...........TC TC TC ...........TC ,. .. 233025-2 233026-2 129.0429 137.0793 TC TC 233025-3.............. ............ 49.9998... .......... TC ,. 233025-3 55.5785 TC 233025-4 36,7758 TC 233025-4........................... 46.5769... CCV 103.1184 CCB-MB -0.6642 LCS.................. ........ 105.3545... ...........TC .. TC TC .......... TC .. LCD 83.4760 TC 233025-5 33.7427 233025-5.............. ............ 56.0807... TC .......... TC .. 233025-6 233025-6 16.3001 33.9325 TC TC 233025-7,................ ......... 8.5995............. ...TC .. 233025-7 30.6101 TC 233025-8 13.8071 TC 233025-8.................. .........51.7390............... ...TC 233025-15 62.5975 TC 233025-15 96.1290 TC 233025-16................ ......... 29.3439... ...........TC 233025-16 62.0285 TC 233025-17 35.0701 TC ms233025-17................ ..........64.0403... 233025-17 128.8410 ...........TC TC 233025-17 msd 137.2804 TC 233025-18..... .......... ......... 15,1401... ...........TC 233025-18 50,2171 TC 233025-19 1344,3428 TC 233025-19................ ..........108.3825... ...........TC 233025-19 76.9154 TC 233025-20 595.4701 TC 233025-20................ .......... 9,6101... . ...TC . 233025-20 53.7043 TC 233025-20 96.9289 ccv......................... ...... 84,2260.............. TC ...TC .. ccv 90,5473 TC CCB 0.2740 TC 232025-21.......................... 85.6943... ...........TC 232025-21 40.1539 TC 232025-22 47.3009 TC 232025-22............... .......... 54.2403... ...........TC 232025-23 348.1862 TC 232025-23 101.8084 TC 232025-23.......................... 59.9961... ...........TC 232025-24 115.1218 TC 232025-25 66.9082 TC 232025-25.... ..................... 49.6878... ...........TC 232025-26 48.9743 TC 232026-26 55.0413 TC CCV......................... ...... 91.2375.............. ...TC .. CCB -0.3044 TC 61 Multiple Analysis Report Print Date/Time: 2004/12/29 12:27:02 Method ID Sample Type Vial Timestamp Message boat Cal. Verification 12/28/2004 09:46 boat S a m ple 12/28/2004 09:50 No Sample Detected boat Sample 12/28/2004 10:04 boat ...S am ple ..12/28/2004 10:16 boat Sample 12/28/2004 10:23 boat Sample 12/28/2004 10:30 boat ...S am ple .12/28/2004 10:39 boat S am ple 12/28/2004 10:47 boat Sample 12/28/2004 10:55 boat ...S am ple ..12/28/2004 11:01 boat Sample 12/28/200411:06 boat Sample 12/28/2004 11:23 boat ..Sample ..12/28/2004 11:36 boat S a m ple 12/28/200411:47 boat S am ple 12/28/2004 11:55 boat ...S am ple ..12/28/2004 12:04 boat Sample 12/28/2004 12:13 boat Sample 12/28/2004 12:20 boat ...S am ple ,,12/28/200412:33 boat S a m ple 12/28/2004 12:40 boat Sample 12/28/2004 12:46 boat ...S am ple ,,12/28/2004 12:54 boat Sample 12/28/2004 12:59 boat Cal. Verification 12/28/2004 13:05 boat ...S am ple ,,12/28/2004 13:08 ,,N o Sample Detected boat Sample 12/28/2004 13:34 boat Sample 12/28/2004 13:41 boat ...S am ple ,,12/28/2004 13:55 boat Sample 12/28/2004 14:02 boat Sample 12/28/2004 14:11 Over-range boat ...S am ple ,,12/28/2004 14:18 boat Sample 12/28/2004 14:27 boat Sample 12/28/2004 14:33 boat ...S am ple ,,12/28/2004 14:39 boat Sample 12/28/2004 14:53 boat Sample 12/28/2004 15:05 boat ...S am ple ..12/28/200415:12 boat Sample 12/28/2004 15:19 boat Sample 12/28/2004 15:27 boat ...S am ple .12/28/2004 15:33 boat S a m ple 12/28/2004 15:41 boat Sample 12/28/2004 15:48 boat boat ...S am ple Sample ,,12/28/200415:56 12/28/2004 16:04 boat Sample 12/28/2004 16:12 boat boat ...S am ple ,,12/28/2004 16:21 Cal. Verification 12/28/2004 16:30 boat boat Sample ...S am ple 12/28/2004 16:33 No Sample Detected .12/28/2004 16:39 boat Sample 12/28/2004 16:46 boat Sample 12/28/2004 16:56 boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat boat ...S am ple .12/28/2004 17:23 Sample 12/28/2004 17:29 Sample 12/28/2004 17:42 ,,.Sam ple ,,12/28/2004 17:56 Sample 12/28/2004 18:03 Sample 12/28/2004 18:09 ...Sample ,,12/28/2004 18:51 Sample 12/28/2004 19:58 Sample 12/28/2004 20:11 .,,Sam ple ,,12/28/2004 20:29 Sample 12/28/2004 20:45 Sample 12/28/2004 20:53 ...S am ple ,,12/28/2004 21:11 Sample 12/28/2004 21:19 Sample 12/28/2004 21:32 ,,.Sam ple ,,12/28/2004 21:46 Sample Sample 12/28/2004 22:01 12/28/2004 22:21 O ver-range ...S am ple ,,12/28/2004 22:27 Sample 12/28/2004 22:36 Sample 12/28/2004 22:52 ,,.Sam ple ,,12/28/2004 22:58 Sample 12/28/2004 23:04 Sample 12/28/2004 23:17 ...Cal. Verification.. ,,12/28/200423:35 ,,O ut of Calibration CaL Verification 12/28/2004 23:41 Sample 12/28/2004 23:48 No Sample Detected ,,.Sam ple ,,12/28/2004 23:55 Sample 12/29/2004 00:00 Sample 12/29/2004 00:07 ...S am ple ,,12/29/2004 00:13 Sample 12/29/2004 00:21 Sample 12/29/2004 00:27 ,,,Sam ple ,,12/29/2004 00:35 Sample 12/29/2004 00:43 Sample 12/29/2004 00:50 ...S am ple ..12/29/2004 00:55 Sample 12/29/2004 01:01 Sample 12/29/2004 01:07 ...Cal. Verification.. ,,12/29/2004 01:14 Sample 12/29/2004 01:17 No Sample Detected Detailed Analysis Report Print Date/Time: 2004/12/23 13:34:53 Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12280941 Z Timestamp: 12/28/2004 09:46 Sample Type: Cal. Verification Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 93.5850 93.5850 8959410 1.768 2 J 6 7 293 Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE O peratorio: CAROL Mode: TC Filename: 12280947 Timestamp: 12/28/200409:50 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.4265 -0.4265 -16207 2.086 1.864 120 Last Message: No Sample Detected Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12280959 Timestamp: 12/28/2Q4 10:04 Sample Type: Sample V y Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 100.9681 100.9681 9961871 2.084 3.083 267 Sample ID: LCD Method: boat CaL Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281011 / Timestamp: 12/28/2004/10:16 Sample Type: Sample ( R ep# ppm C u g C Raw Data Beginning Ending Integration^ Baseline Baseline Time 1 159.4982 159.4982 15721718 3.087 4.085 269 Sample ID: 232881-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC _ Filename: 12281019 f Timestamp: 12/28/200^10:23 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 64 1 72.3923 72.3923 7149769 2.869 3.866 242 Sample (D: 232881-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281024 Timestamp: 12/28/2004 10:30 Sample Type: Sample R ep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 93.0186 93.0186 9179569 2.638 3.636 272 Sample ID: 232881-1ms Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281033 x Timestamp: 12/28/2004 10:39 Sample Type: Sample R ep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 181.1542 181.1542 17852856 3.518 4.517 281 Sample ID: 232881-1msd Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281041 Timestamp: 12/28/2* Sample Type: Sample / / !4 10:4 Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 164.7172 164.7172 16235315 2.976 3.974 326 Sample ID: 232881-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281050 Timestamp: 12/28/2) 'I04 10:55 Sample Type: Sam ple/ R ep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 172.2670 172.2670 16978274 2.817 3.816 278 Sample ID; 232881-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281056 Timestamp: 12/28/2004 11 :G1 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 136.0685 136.0685 13416044 2.873 3.871 275 Z X = C !S : Sample ID: 232881-3 Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode; TC Filename; 12281101 Timestamp: 12/28/200^ 11:06 Sample Type: Sample V Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 90.9472 90.9472 8975732 2.914 3.911 251 r SampleJD: 232881-3 Method: boat Cal. Curv^: SOILCURVE Operator ID: CAROL j ^ Mode: TC P Filename; 12281117 Timestamp: 12/28/2004 11:23 Sample Type: Sample Rep # ppm Q ug Raw Data Beginning Ending Integration Baseline Baseline Time 1 265.0371 $65.0371 26107632 1.901 2.901 357 Sample ID: 232881-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281131 Timestamp: 12/28/2004 11:36 Sample Type: Sam plt Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 69.4972 69.4972 6864870 1.957 2.956 265 Sample ID: 232881-4 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281141 Timestamp: 12/28/2004 11:47 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending integration Baseline Baseline Time 1 89.6460 89.6460 8847678 2,017 3.014 294 Sample ID: 232881-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281150 Timestamp; 12/28/2004 11:55 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 74.3075 74.3075 7338247 2.088 3,086 262 6b Sample ID: 232881-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281158 f Timestamp: 12/28/2004 12:04 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 1 76.8937 76.8937 7592745 2.097 3,093 274 Sample ID: 232881-5 Mode: TC Method: boat Filename: 12281208 Cal. Curve: SOILCURVE Timestamp: 12/28/2004 12:13 Operator ID: CAROL Sample Type: Sample R ep# ppm C ugC Raw Data Beginning Ending Integration Baseline Baseline Time 1 84.4006 84.4006 8331489 2.258 3.255 258 Sample ID: 232881-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281215 / Timestamp: 12/28/2004 12:20 Sample Type: Sample ( Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 81.2524 81.2524 8021685 2.368 3.365 274 Sample ID: 232881-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281228 Timestamp: 12/28/2004 12:33 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 70.6701 70.6701 6980297 2,053 3.053 259 Sample ID: 232881-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281234 / Timestamp: 12/28/2004 12:40 Sample Type: Sample \ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 198.3675 198.3675 19546788 2.351 3.350 340 Sample ID: 232881-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281241 Timestamp: 12/28/200412:46 Sample Type: Sample Rep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 181.4474 181.4474 17881712 2.792 3789 294 Sample ID: 232881-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281249 ^" Timestamp: 12/28/200412:54 Sample Type: S a m p le / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 40.8019 40.8019 4041016 2.313 3.306 236 vr / Sample ID: 232881-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename; 12281255 Timestamp: 12/28/2004 12:59 Sample Type: Sample R ep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 36.0681 36.0681 3575164 2.940 3.939 219 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281300 ^ Timestamp: 12/28/20Q4 13:05 Sample Type: Cal. Verification // Rep # ppm C ug C Raw Data Beginning Ending iW gratibh Baseline Baseline Time 1 94.0099 94.0099 9001224 2.161 3.160 278 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281306 X Timestamp: 12/28/2004 13:08 Sample Type: S a m p le / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.4885 -0.4885 -22308 2.506 2.232 120 Last Message: No Sample Detected 6S Detailed Analysis Report Print Date/Time: 2004/12/29 12:27:25 Sample ID: 233025-9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281329 Timestamp: 12/28/200413:34 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 99.1537 99.1537 9783314 1.997 2.996 288 Sample ID: 233025-9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281336 Timestamp: 12/28/2004 13:41 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 73.8788 73.8788 7296056 2.362 3.362 255 Sample ID: 233025-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281350 Timestamp: 12/28/200413:55 Sample Type: Sample ( Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 45.3030 45.3030 4483961 2.121 3.117 243 Sample ID: 233025-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281356 Timestamp: 12/28/2004 14:02 Sample Type: Sample R ep# p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 32.3338 32,3338 3207684 2,432 3,431 340 Sample ID: 233021MDU t0H Method: boat V } # * Cal. Curve: SOILCURVE Operator ID: CAROL \ Mode: TC , Filename: 12281403 Timestamp: 12/28/200414:11 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1446.1906 1446.1906 142343008 2.520 5.289 480 Last Message: Over-range Sample ID: 233025-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281413 Timestamp: 12/28/2004 U : 18 Sample Type: Sample Rep# p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 78.6862 78.6862 7769147 4.244 5.236 278 Sample ID: 233025-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281420 Timestamp: 12/28/200414:27 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 206.3174 206.3174 20329128 2.495 3.494 338 Sample ID: 233025-12 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281427 Timestamp: 12/28/2004 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 156.2057 156.2057 15397715 2.750 3.747 288 Sample ID: 233025-12 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281434 Timestamp: 12/28/2004 14:39 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 140.6837 140.6837 13870216 3.238 4.235 288 Sample ID: 233025-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281448 Timestamp: 12/28/20(5414:53 Sample Type: Sample t \ / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 51.3145 51.3145 5075537 2.533 3.529 251 filialIm i Sample ID: 233025-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TO Filename; 12281500 Timestamp: 12/28/2004 15:05 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 66.9434 66.9434 6613558 2.321 3.317 312 Sample ID: 233025-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281508 Timestamp: 12/28/2 Sample Type: Sample R e p # p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 46.5611 46.5611 4607769 2.280 3.279 257 Sample ID: 233025-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281514 Timestamp: 12/28/2004 15:19 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 68.1306 68.1306 6730382 2.884 3.883 262 ==================================^^=3================= Sample ID: 233025-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC ^ ____ Filename: 12281521 // V yTimestamp: 12/28/200415:27/ Sample Type: Sample R ep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 77.8679 77.8679 7688621 2.177 3.177 276 Sample ID: 233025-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281527 Timestamp: 12/28/2004 15:33 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 83.7958 83.7958 8271974 2.293 3.292 267 SS =!-i; 71 Sample ID: 233025-2 Method: boat Cal. Curve; SOILCURVE Operator ID: CAROL Mode: TC JFilename: 12281535 Z ' ) Timestamp: 12/28/2004 16:41 Sample Type: Sample V J Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 129,0429 129.0429 12724662 2r475 3.474 283 Sample ID: 233025-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Sample Type: Sample Mode: TC Filename: 12281542 Timestamp: 12/28/2004 15:48 Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 137.0793 137.0793 13515514 2,120 3.118 338 Sample ID: 233025-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281550 f Timestamp: 12/28/2004 15:56 Sample Type: Sample ( Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 49.9998 49.9998 4946168 2.131 3,130 281 Sample ID: 233025-3 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281558 Timestamp: 12/28/2004 16:04 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 55.5785 55.5785 5495151 1.824 2,823 289 Sample ID: 233025-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281605 f Timestamp: 12/28/2004 16:12 Sample Type: Sample V Rep# ppm C ug C Raw Data Beginning Ending integration Baseline Baseline Time 1 36,7758 36.7758 3644810 2.120 3.118 244 Sample ID: 233025-4 Method: boat Cat. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281613 Timestamp: 12/28/2004 16:21 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 46.5769 46.5769 4609324 1.886 2.883 290 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281623 Timestamp: 12/28/20 Sample Type: Cal. Verifi Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 103.1184 103.1184 9897583 2.202 3.194 345 Sample ID: CCB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC ^ ____ Filename: 12281630 Timestamp: 12/28/2004 16:33. Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.6642 -0.6642 -39597 2.670 2.071 120 Last Message: No Sample Detected = x ; ^ ^ S ^ " ^ = --^ ^ = = = = = = = = = = = = = = = = ? s = = = = = = = = ;= ir^ = = = = = = = = = = = = = = = = = = = = = = = = A = = E :^ : Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281633 Timestamp: 12/28/201 Sample Type: Sample 16:39 R ep# p p m C u g C Raw Data Beginning Ending Inte Baseline Baseline Time 1 105.3545 105.3545 10393534 1.959 2.955 288 Sample ID: LCD Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281640 f Timestamp: 12/28/20Ei4 16:46 Sample Type: Sample ( Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 83.4760 83.4760 8240501 2.108 3.104 316 Sample ID: 233025-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281652 X^ / Timestamp: 12/28/2004 16:56 VSample Type; Sample R e p# p pm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 33.7427 33.7427 3346333 2.050 <3.050 249 Sample ID: 233025-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281718 Timestamp: 12/28/200417:23 Sample Type; Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 56.0807 56.0807 5544570 1.872 2.870 248 Sample ID: 233025-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC ____ _ Filename: 12281725 X^ ) Timestamp: 12/28/2004 17:29 Sample Type: Sample ( Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 16.3001 16.3001 1629833 2.344 3.340 190 Sample ID: 233025-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281737 Timestamp: 12/28/2004 17:42 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 33.9325 33.9325 3365010 1.801 2.798 239 Sample ID: 233025-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode; TC Filename: 12281752 / Timestamp: 12/28/2004i7:56 j Sample Type: Sample ( j Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 8.5995 8.5995 872024 3.266 4.260 159 !H =fiK S = = 74 Sample ID: 233026-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281759 Timestamp: 12/28/2004 18:03 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 30.6101 30.6101 3038069 2.870 3.866 207 Sample ID: 233026-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281805 Timestamp: 12/28/20 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 13.8071 13.8071 1384502 2.350 3.348 189 Sample ID: 233026-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12281846 Timestamp: 12/28/2004 18:51 Sample Type: Sample R e p # p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 51,7390 51.7390 5117312 1.870 2.867 270 Sample ID: 233025-15 Mode: TC Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Filename: 12281954 f Timestamp: 12/28/2004 19:58 Sample Type: Sample \ Rep # ppm C ug C Raw Data Beginning Ending Integi :ion Baseline Baseline Time 1 62.5975 62.5975 6185879 2.250 3.245 232 Sample ID: 233025-15 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12282006 Timestamp: 12/28/2004 20:11 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 96.1290 96.1290 9485664 1.853 2.851 273 Sample ID: 233025-16 Method: boat CaL Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12282024 Timestamp: 12/28/; Sample Type: Sample .7 \QA 20:29 Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 29.3439 29.3439 2913453 2.014 3.011 214 Sample ID: 233025-16 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12282040 Timestamp: 12/28/2004 20:45 Sample Type: Sample R ep# p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 62.0285 62.0285 6129889 1.761 2.760 254 Sample ID: 233025-17 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12282049 Timestamp: 12/28/2 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 35.0701 35.0701 3476954 2.314 3.312 218 Sample ID: 233025-17 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12282106 Timestamp: 12/28/200421:11 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 64.0403 64.0403 6327869 1.840 2.835 248 Sample ID: 233025-17 ms Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC __ Filename: 12282114 Timestamp: 12/28/200421:19 Sample Type: Sample l v Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 128.8410 128,8410 12704800 2.456 3.451 263 Sample ID; 233025-17 msd Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12282126 / Timestamp: 12/28/2004 21:32 Sample Type: Sample y Rep# p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 137.2804 137.2804 13535305 2.082 3.081 345 Sample ID: 233025-18 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC __ Filename: 12282139 /^ Timestamp: 12/28/2004/21:46 Sample Type: Sample l Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 15.1401 15.1401 1515679 3.008 4.005 184 Sample ID: 233025-18 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12282157 Timestamp: 12/28/2004 22:01 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 50.2171 50.2171 4967552 1.778 2.769 246 Sample ID: 233025-19 Method: boat \ Cal. Curve: SOILCURVE Operator ID: C AR O L\ \0 ) Mode: TC Filename: 12282212 Timestamp: 12/28/2004 22:21 Sample Type: Sample Rep # ppm C ug QV VRaw Data Beginning Ending \ Baseline Baseline Time 1 1344.3428 1344.3428 132320344 2.592 3.801 Integration 480 Last Message: Over-range Sample ID: 233025-19 Method: boat Cal. Curve: SOILCURVE Operator ID. CAROL Mode: TC __-- _ Filename: 12282222 j Timestamp: 12/28/2004 22:27 Sample Type: Sample \ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 108,3825 108.3825 10691507 3.453 4.447 241 ====^==s=^:x Sample ID: 233025-19 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12282231 Timestamp: 12/28/2004 22:36 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 76.9154 76.9154 7594884 2.065 3.063 246 Sample ID; 233025-20 Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL if Mode: TC a 7 r Filename: 12282241 a ' Timestamp: 12/28/20p4 Sample Type: Sample R e p # p p m C u g C Raw Dank Beginning Ending Integration q " ] /^ Baseline vaseline Time 1 595.4701 595.4701 58625004 \ 2,107 3.106 363 Sample ID: 233025-20 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12282254 Timestamp: 12/28/2004 Sample Type: Sample tS i , Lfil Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline7 iseline Time 1 9.6101 9.6101 971475 2X74 3.472 172 Sample ID: 233025-20 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: \ TC Filename: 12282259 Tim estam p 12/28/2 Sample Typer^am ple R ep# p pm C ugC Raw Data Beginning Ending Baseline Baseline Time \ 1 53.7043 53.7043 5310717 2.375 3.374 Integration . . {0 ' Sample ID: 233025-20 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC _-- * Filename: 12282311 r\ \ Timestamp: 12/28/2004 23^17 \ Sample Type: Sample .M Rep # ppm C ug C 1 96.9289 96.9289 9564382 Raw Data Beginning Ending Baseline Baseline Time 1.860 2.856 262 Integration Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL -^W lode: TC Ffnarqe: 12282329 Tm&BtacQ. 12/28/20' Sample TypeTCaLyerifica Rep # ppm C -ug C Raw Data Beginning Ending Baseline Baseline Time 1 84.2260 84.2260 8038406 1.728 2.725 269 Last Message: p u t of Calibration Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12282336 Timestamp: 12/28/20(^4 23:41 Sample Type: Cal. Verification Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 90.5473 90.5473 8660476 2.046 3.045 258 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC , Filename: 12282345 X^ Timestamp: 12/28/2004 23:48 Sample Type: Sample V _ . Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.2740 0.2740 52733 1.969 2.366 120 Last Message: No Sample Detected Sample ID: 232025-21 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12282350 X" Timestamp: 12/28/2004 23:55 Sample Type: Sample R e p# p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 85.6943 85.6943 8458799 2.687 3.684 245 Sample ID: 232025-21 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12282356 Timestamp: 12/29/2004 00:00 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration 79 Baseline Baseline Time 1 40.1539 40.1539 3977240 2.262 3.259 221 Sample ID: 232025-22 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12290003 Timestamp: 12/29/2' Sample Type: Sample R e p # p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 47.3009 47.3009 4680573 2.122 3.120 229 Sample ID: 232025-22 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12290009 Timestamp: 12/29/2004 00:13 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 54.2403 54.2403 5363469 1.927 2.927 244 Sample ID: 232025-23 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12290015 \) Timestamp: 12/29/2004 00:2' Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 348.1862 348.1862 34290200 1.982 2.979 339 =i^:^=-============z:^"i;-- = = = = = = = = = = = = ^ -- ===========^;^.~-- ==== Sample ID: 232025-23 Method: boat Cal. Curve: SOILCURVE Operator ID; CAROL Mode: TC Filename: 12290022 Timestamp: 12/29/2004 00:27 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 101.8084 101.8084 10044585 2.499 3.497 253 Sample ID: 232025-23 Method: boat (y y Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12290030 Timestamp: M!2$I204W:Z. Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 59.9961 59.9961 5929882 2.248 3.247 250 Sample ID: 232025-24 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12290038 Timegtarbp: 12/29/2004 00:43 Sample Type: Sample R e p# p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 115.1218 115.1218 11354708 2.409 3.407 262 Sample ID: 232025-25 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12290045 Timestamp: 12/29/2 Sample Type: Sample R ep# p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 66.9082 66.9082 6610088 2.485 3.484 242 Sample ID: 232025-25 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12290050 Timestamp: 12/29/2004 00:55 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 49.6878 49.6878 4915455 2.451 3.448 229 Sample ID: 232025-26 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12290057 f Timestamp: 12/29/2004/01 :Q1 Sample Type: Sample R ep# p p m C ugC Raw Data Beginning Ending integration Baseline Baseline Time 1 48.9743 48.9743 4845247 2.348 3.344 231 Sample ID: 232025-26 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12290103 Timestamp: 12/29/2004 01:07 Sample Type: Sample R ep# p p m C ugC Raw Data Beginning Ending Integration Baseline Baseline Time 1 55.0413 55.0413 5442294 2.691 3.687 226 :SKPJ :a a ? = = = = = ^ = = t s ; Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 12290109 Timestamp: 12/29/20* Sample Type: Cal. Verifio Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 91.2375 91.2375 8728400 2.356 3.350 253 Sample ID: CCB Method: boat ilename: 12290115 Cal. Curve: SOILCURVE Operator ID: CAROL Mode: F TC Timestamp: 12/29/2* Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3044 -0.3044 -4193 2.079 1.962 120 Last Message: No Sample Detected ss