Document jg2w8OQznqVE5rv2OVgvao0mO
ARL26- 0758
STUDY SUMMARY OF ENVIRONMENTAL EFFECTS OF LIGHT WATER BRAND AFFF AND COMPONENTS - 1991
IESTSUBSTANCE~~ Identity: A mixture containing perfluorooctanesutfonate, which may also be referred to as PFOS, FC-95, or as a component of FC-203CE. Octanesulfonic acid) (CAS # 2795-393).
Remarks: The 3M production lot number was not noted. The test`sample
is FC-203CE (2/21/89). Current information indicates it is a mixture of 1.84%
PFOS, 30% diethylene glycol butyl ether, 60.23% water, 2.56% Sultone
foamer, 3.1% sodium octyl sulfate, 2.1% polyoxyethylene monooctylphenyl
ether, 0.12% sodium lauryl sulfate, and 0.05% tolyltriazole. The 3Mproduct
lot number was 519.
-
The following summary applies to a mixture with incompletely rcehfalreaccttteorxiizceitdycoofnctehentfrlautoirooncsheomfiicmaplurciotimepso. nDeanttaofmtahyentoetstacscaumrpaltee.ly
R0 ESOW0 TS 000000000
Degradability
[[(SBBtOouDDds.y ---- JfVeeattlgweett(oEswMom)urce)
|||
[[BOBDwn------ TaTwaooggii@eomw)
|
680 g/L (3M)
[[BCOBDb2/OCODD r,atiojCODTwre0.z8m9gr(3lMe] mo) _____Togo@)||
Total Organic Carbon (TOC) [220g (3M)
|
OECD Method 301E
88-90% biodegradability in 14 days (3M)
Aquatic toxicity
Stud
[ Vawe(sourcey|
g
pi
"OECD Activated Sludge Respiration
Inhibition Test 209
SECs[NoneatiooomgL|
[Waterflea (Daphniamagna)
|
|
aehrStliclCy[>1000mgleM|
[Microtox (Phofobacteriumphosphoreurn) |
|
CC
SminECe[30mg
001178
ES L omnECe[somgt|
x Sn CONMAE FETS[,omg FatheadMinnow (Pimephalespromelas) |
|
96hr Cont9i6n-uhorusStFaltoicw LLCC:s[[250100000mmggr (aGMy)
* Any study marked with "3M" as the source includes studies done at the request of 3M by labs other than the 3M Environmental Lab.
Reliability: These studies have been assigned Klimish rankings = 4.
Values are from a summary list only.
Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133
Last changed: 6/28/00
001179
parle) 2
rToecmhanical ReportA Summary
3M
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Rpata of LIGHT
WATER
Brand
AFF?
and
Components|
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denevmiarnodn,meBnOtaDl,fcehcetmsi,catloxoixtyyg,eDnadpehmnaiando,xCiOcD,.Microtox, algal toxity, fish toxichy, degradabifty, blocherrical oxygen
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Aconmaptotneemnpttwcaonscemraidraetitooncionrrtehleatperotdhuectt.oxWchtiyleopfrFoGd-u2c0t3totoxcttheyctoouxlidncootf ibseccoonmcplounseivnetlsybcoyrtraekliantged1nt0cothneskolxeiractoanndthe bcuotnyclenCtarrabttioolnTMo,fainnddivDiudpuoanlacloTMmpoMneEnt(ss,odmiaujmolracuroymsurltfaotre)s. Ctoomprpoodnuecntttsoxeiltyyatroecboerliirebvuetdeolebses ttoheprfoidmuecrt, thoexfiocamaerer., feothmyulleanteioglnyscoslh,otuokldyeinaazbollee,bestotdeirucmororcetlyaltsiuolnlabtee,twaenednDci-owmaptoenr.eFnutrathnedrptrooxdiuyc tteosxtiincgso.f components and product
RoparT3Pe
[Socury
[-- Ferrer
10 7P1it4o0t PRienstear andDevelopment MANutactutng
CTP FactToirypoExFpieeriRmeepnotrt. Q ENGinsong
00 TGEoC. SPreovjeecnt 0 omen
MOapnaangfeomceonrtaSnUdNSiumnamryary 0 ClsedeROIcocosrmo dSoufmin mmvaernytion | Chama! O New Crorcal Reported
Tm Bee
Recley
inomt[niemcce
oem ey Timmcirion
001180
'
Contents
LE
SU 3
1 BAGKGIOUNG vss 2
ll. GONG COMMONS sss 4
IV. CONGIUSIONS and RECOMMENTRNONS verses 6
V. ENVIroNMantal Effects LIGAUTE SAIC...
1. EtYI0N0 GIYOO! (RMI0T7) verre, 10
2. Butyl Carbitol (RM 8887) vrs 12
3. Duponol (RM 3021); Duponol ME Dry Surfactant (Sodium Lauryl Sulfate) ....... 14
4. Tolyltiazole (RM 27513; Corrosion Inhibitor Tolylriazole Technical Grade) ..... 16
5. FORMBE (FM-4115)
sss
18
6.FIIMer (FM-O3F8FC2-905) vorLtrs 18
7. Na-octylsulfate (RM 32067 OF RM 55040) .......cecerrsmmrsssenne 19
8. DEWALT (RD 198) iors 20
9 F203 sss, 21
10. VW160390 (FC-203 without Tolyitriazole RM 27513) ns 23
11. FC-203CE worrisomefon.24
.
12. FC20B0E ovis 28
13. FC2030F nsdn. 26
V4. FCR0BCF tvtime 26
1614640 (NOW FORMEN) ccc, 26
16. WHCOIat 7093 (RM 45666) .....cvervhesrsrnssnssmsssssssmeeseins 27
17. THONNOIAMING
rrr
27
T8UIBR ons 20
19. THON X-305 cvs. 30
a1.
001181
Environmental Effects of LIGHT WATERTM Aqueous Film Forming Foam and Components
1. Purpose
The purposeofthis study is to increase LIGHT WATERTM aqueous film forming
3M's foam
knowledge of the and the individual
environmental effects components used to
of make
the
product. And, by understanding these effects, to minimize them through formulation changes.
IL. Background
"rTehpiosrstteuddiynw"aInsveusntdiegrattiaoknesnoifnTroexsipcoEnfsfeecttos taenstdinBgiodloogniecablyDtehgeraGdearbmilatny Aorf mFyowahmicEhxtwinagsuishing
AAgremnytsReipnorWta"s,teiwncaltuedre"dbdyatEakfkoerh1a6rdfiIresifnigg.htTihneg mraetpeorrti,alhse,roefafwtheircrheftewrorewdetroeas3Mt'hseF"CG-e2r0m3anand
FC-206. The 16 fire extinguishing agents were categorized as:
5 multi-range foam agents
6 film-forming foam agents
. 3 protein foam agents
1 film-forming fluorine-protein foam agent
1 special foam agentfor deep-fry pan fires
Environmental effects considered in the German Army Report were:
1. pAhcuotsephtooxriceiutymtuostihneg tmhaeriMniecrpohtootxolusmyisnteesmc.eTnhtebatocxtiecritiyumwaPshoetxopbraecstseerdiaums EC.oand
ECs,
have
bheoewenv1e0r,,2t0h,eeoxrp3o0sumrienuttiemse.
Tiws onotmucllie-arrafnrgoem
ftoheamGeagremnatns
Army
were
cRoenpsoirdteraendd
may
5
5
"bheig"htloxyitco"x.iFco"u.rTfhlrme-efomrumlitri-gr;anaglle3fopraomteaign,entthse afinldm2-fofrimlimnfgorflmuionrginaeg-epnrottseiwneargeenfto,unadntdo
the deep-fry agent in the "low toxicity"
were considered category.
to
have
"low
toxicity".
FC-203
and
FC-206
were
-
2.
Algae cell multiplication inhibition test organism with an exposure time of 72
using Scenedesmus subspicatus hours. Toxicity was expressed as
as the EC 1,
test and
"EtoCx.ic"Altlofaolgaame.agTehnetstwwoitphrtohteeienxfcoepatmioangeonfttswhoaodf twheeapkrototxeiicnitfyotaomalaggaeen.tsBowtehr3eM
products were considered "toxic" to algae.
3. eAxcpurteestsoexidciatsy tLoCD,apahnndiLaCmsa,gbnuat tahfteerefefxecptoscruirteerfioorn 2w4ashotuhres,orTghaentiosxmisc'itlyowssasof ability
atogesnwtis,m aalnl dfiwmi-llfobremirnegfeargreednttso aesxcEepCt1,FCa-n2d06E,Csa,ndintthheisdreeeppo-rTt.ryAlalg5enmtuwtie-rrea"ntgoexifc"oatmo
"2-
001162
i
fDialpmh-nfioarm.inOgnfelufoirlimn-ef-oprrmoitneginaaggeenntt(FhCa-d20"6l)o,w talolxitchirtey"e tporoDtaepihnnaigae,ntFsC,-2a0n3d:t"hteoxic"; FC-206: "low toxicity". ~~4. AcrciutetreiatowxaicsitdyetaothZeabnradfitshhe t(oBxricaicthyywdaasnieoxrperrieos)saefdtearsexLpCos,,uarnedfoLrCy4,8.Ohonulryst.wTohe fmiullmt-if-orramnignegfaogaemntasgwenetrsew"eborrede"rtloxiince"ttooxifics/hw.eTahkrlyeetomxiucl"t.i-"rWaenagkelfyotaomxica"gewnetrsea4nd two faiglemn-tfoarnmdintghaegfeinltms-,fo2rmpirnogtefilnuofroianem-pargoetnetisn,aagenndttwheerdeee"pno-nr-ytoaxgiec"n.t.FOC-n2e0f3ilamn-dforming FC-206 were in the "weakly toxic" category. 5. oCfhaem3i%caslolOuxtiyogneonf tDheemtaesntdma(tCeOriDa)lainn dwa5t-edr.ayTBhieocrahteimoiocfaBlOODxygteonCDOeDmawnads(uBseOdD a5)s bairoacthienmgigcuaildadleignrea,dwaittihona".BOTDwo/CmuOlDti-rraatnigoeofag0e.n5tosralnesdsocnoensfiidlem-rfeodrm"iinnsgufafgiecnietnt w(FaCs-200.365).wOenree cmoulntsii-drearnegde iangseufnfticainendtloyndeefgirlamdfeodrmbiinogchaegmeincatll(yF.C-T2h0e3)rawteiro efor FC-206 croenmsaiidneirnegdag"pernotbsawbleyreinaslulffsiucfifeincti"enbtewciatuhstehetihreBirOBDO/DC/OCDODratriaotsiorsanwgeirneg 0f.r5o5m. 0T.h6e0 9to
0.89.
Tbehleowd.atTahferodamttahefoGr ethremaMincrAortmoxy, RZeepbroarftisfohr,tChOeDt,woan3dMBprOoDdutcetsstasreseseummmtaorbieze"dreianstohneatbalbele
adantda"fsralofm-cpornesviisoteunst"3.MThsteuddiaetsaaanred caorensciodnesriedderreedassoenlafb-cloensbiesctaenutsebetchaeuysaegrtehes FfaCi-rl2y0w6eldlawtiath
are roughly half that of FC-203.
)
-
Summaryof German Army Report Data.
.
>
Ly
Microtox EC ECy
Daphnia. Low Low
Zebrafish
LC
Low
BOD,/COD. Rato
"6o2wTot2ty50 169Tote 160 ae"Tose 4% | 10W8o3sky T1o6r34r |
215=0| 0 c0o5t2 a =
20to0wTo1x5t0y0| 16"3Toi 10 | 3w s T2000 || 2W0o8ay To4noeers||ae--s Noo alconcantasons in mgt.
"3-
001183
For the algal toxicity data, there are two important points to consider. First, the German
Amy's algae data show essentially equivalent toxicity for our two products. One would expect
more toxicity for FC-203 than for FC-206, as shown in the Mictotox, Zebrafish, and Daphnia
tests. However, higher toxicity by FC-203 than by FC-206 may not always be true. For
example, there may be a component which is particularly toxic to algae, perhaps disrupting
the photosynthetic process. Second, our PED for FC-203 indicates no effect to two algal
species at concentrations up to 1,000 mg/L. While the two algal species on the the sameasthose in the German Army Report, they are all freshwater species
PED are and such
not a
large difference in toxicity wouldn't be expected. One important limitation with the PED data is
that it dates from 1974 and it has been impossible to verify the exact formulation of the
`sample used in those tests.
For the Daphnia data in the German Army Report, the difference between the FC-206 and
FC-203 values seems large when considering the water content of the two formulations. Also,
there is a considerable difference between the PED data and the German Army data. Our
PhaEsDah2a4s-har4s8t-ahtircsDtaatpichnDiaaphmnaiganmaaEgCna,LiCs 430ofm1g,/6L0.0Tmhge/LP,EwDhidlaettahies GqueirtmeaonldA(r1m9y73R)eapnodrtthe
formulation of the test sample cannot be verified. There is a major difference between the
PED data and the German Army data in that the PED data is the concentration which causes
death to 50% of the Daphnia test population (LC s,) and the German Army value is the
`concentration which causes 50% of the test population to stop swimming (Effective
Concentration `which show a
= ECy;). The German Army 48-hr static Daphnia magna
value ECs,
is of
in fair agreement 229 mg/L.
with
recent
results
*
One thing that should be kept in mind when considering the toxicity data s that reproducibility
and precision of toxicity tests can vary considerably from laboratory to laboratory and over
tmiomre.e Hliokweelyvedru,e tthoecdhiafnfgeeresncinesfobremtuwlaeteinontrhaetohledrdtahtaan(cchiracnag1e9s74in)taesntdptrhoetomcoolreorrteecsetntspdeactiaesi.s
At
be
acnoyncreatren,eoduwriptrhihmaavriynigntceurrersetnts,horeullidabblee
the toxicity
data on our
oPfEoDusr.current
products
and
We
should
il. General Comments
The following general statements summarize the factors guiding this study.
1. The primary purpose of the environmental effects data is for internal use in evaluating
formulations and ingredients and not intended for submission to govemmental
regulatory authorities. Therefore, non-GLP methods. An exception
any testing should be done using low-cost, may be data for the new foamer (L-4640) which
may need to be submitted for the European PMN currently underway.
1
DErnavftirRoeSpyosrttefmrsotmo ErnevpieraotStyhsetDemasphLnaibaortaetstosryfodraFteCd-2M0a3rcahnd10V,W11969013.9W0e.
have asked The preliminary
results from EnviroSystems on the rest of the samples were acceptable.
-a-
00118%
2. TAhremGyeirsmparnesAenrtmlyy upseirnfgortmhse eitvsaoluwantitoenstsincgheanmde nuoseadutihnortihteyroetphoerrt tchitaendtahbeoGvee.rman
`aTphpelriecfaobrlee, otnhleyre10isthneoGneeremdatno cAhromoyseteastlsacbohreamteor.y,Intsetsetapdr,otteosctolm,eotfhtoedsst sapnedcisepsecies
~~" should be chosen so that test resuits can be used in as many countries as possible.
3. Wfhreormethpeoslsiitbelrea,tudreatoarofnrotmheraewnvmiartoenrmiaelntsaulppelfifeercstsinoofrcdoemrtpoonreednutcsestheosutlidngbecoosbttsaiannedd
time.
4.
TrheelaNtiavteiotnoxailciItnystoiftuttheeocfoOmcpcoupnaetnitosnaalndSatfheetyfoarnmdulHaetailotnhs
(NIOSH) terminology will be used in the
for
the
dRiespcoursts,itohneoyfatroexigceneeffreacltlsy. aWchcielpettehdesinettheermUsS.weTrheentooxticuisteydanindtchoerGreesrpmoanndiAnrgmtyerms
are:
Concentration Acutely
:
Toxic to Test Population
NIOSH Terminology
<1 mL 1-10 mo 10-100 mg/L 100- 1,000 mg/L 1,000 mgiL
"Highly Toxic" "Moderately Toxic"
"Slightly ToxicTM "Practically Non-Toxic" "Insignificant Toxicity"
5.
-
The
LIGHT
WATER
AFFF
formulations
and
componen-ts
considered
are:
2
1. Ethylene Glycol (RM 3017)
2. Butyl Carbitol (RM 8887)
3. Duponol ME (RM 3021)
4. Tolyltriazole (RM 27513) 5. Foamer (FM-4115)
.
6. Filmer (FM-3820 = FC-95)
7. Na-octylsulfate (RM 32067 or RM 55040)
8, Dl-water (RD 199)
9.FC-203
10. 11.
VW160390 FC-203CE
(FC-203 (same as
without Tolyltriazole FC-203C)
RM
27513)
12. FC-206CE
13. FC-203CF
14. FC-206CF
>. :
-
-
_5-
001188
15. L-4640 16. Witcolate 7093 (RM 45666) 17. Triethanolamine
18. Urea -- 19. Triton X-305
Items
to 13
1 to
were
10 are
given
froma
to the
list given
author by
to Eric Reiner
Wim Vanneste
by Wim
2/5/91.
Vanneste 3/12/90. tems 11
tems 14 to 16 were given
10 the author by Roger Alm (2/4/91).
IV. Conclusions and Recommendations
Inorder to correlate the toxicityof the product to the toxicity of individual `components, the component concentration is taken into consideration. In the table-below, the toxicity to Daphnia of the pure components are given in the third column. The fifth column contains `estimated toxicities based on product formulation. This is the toxicity which would be expected when the component is diluted in water to the same concentration as in the product. For example, one would expect that since the toxicity of pure butyl Carbitol is about 700 mg/L, the toxicity of a solution made of 35% butyl Carbitol and 65% water `would haveatoxicity of
about 2,000.
Some interesting observations can be made from these numbers. First, even though
tolyltriazole is quite toxic, it is present at low concentration in the product and when diluted in
the product it probably does not contribute substantially to product toxicity. However, this
analysis does not exonerate tolyltriazole as amajorcontributor to product toxicity. Second, the
lowest numbers in the fifth column indicate components which will be the most likely
contributors to product toxicity: butyl Carbitol, Duponol ME (dodecylsulfate), the foamer, and
the filmer. Unfortunately, there is not a single component which stands out with a number in
tsyhneefrigfithstciocleufmfnectwhbiecthweis.e`nsucbosmtapnotniaelnltysl.ower than all the rest. This may mean that there is a
. EY
:
"6001186
i
Summary of Recent Daphnia Toxicity Data
fm,- Ware epg
SRE eFrorrsre
S100
200%
2a, ScEoSeaE?,
ET)
Probably sot
Tara
708 29-1000
asa
207
Frobaly
5 pe
2023-09)
oon 2000
Protatty
~r
Touz-29
=)
om
Probatoyt
Ee
EE)
2e0% ED)
Froaly
Hr ow wes
Tae
ser
Proatly
"
517 00-100)
200% Tm
Probably not
:
pa
Som
ras
ET
Yo
0 roms
225 (150-440)
x
se eIe e) pee sti x
The
~
important
conclusion
from
these
Daphnia
results
is
Le
that a more
complete
set
of5
toxicity
data is needed, to complete the
eesnpveicrioanlmleynftoarlalegffaeec.tTs hdeattaabbalseebeolnoowusrupmrmoadruictzsesantdhethaedidritiinognraeldideanttas.needed
5
Additional tests are indicated with an X.
2 Preliminary resuits from EnviroSystems, March 10, 1991. -7-
:
001154
4
va oe mews Fn `Summary of Additional Testing
1. Ea
> Eepy
xx
Saps)y
xx
TT ns
xx
ra
xx
x
(FM4115)
_
6 Fimer
x
x
p on ssi (FM-3=F8C2-905)
x
x
rwrr
roms
x
:
.x
10. VrW18e0390a(FsC-208.
x
x
x
Sromoe y
x IER:
= rom
x CH
13. FC-203CF
x
x
x
x
=14. oo FC-206CF
xx
xx
x
x
To otrime e
x x x x3
mp
-
oom
Tron
xxxx
Tom
=
.7
Now 0 in i' 1,sr o, rwe
oo sw
xx xx xx
xx
x
x
xi
x
x
x
N
. *
xx
xx .0
8
.
00118%
3
V. Environmental Effects Literature Search
Data from previous 3M Environmental Laboratory Studies and from the literature are
`summarized in this section. Toxicity data noted by "AQUIRE" wera obtained from a search of
the USEPA AQUIRE database on Feb. 12, 1991. Included as part of the reference for the
data from AQUIRE are the date of publication of the original joumal article and the review
`code established by a group of EPA reviewers. The reviewers have ranked toxicity data from
the literature by the following scale:
1. Meets all review criteria.
2. Procedures generally satisfactory.
3. Insufficient in some area of the test methodology or test report.
"4. Abstract or foreign paper with data in limited format.
`bTehceacuosmeptlheetedactoantbeanstesionfcltuhdeeAsQmUaInRyEodbasctuarbeassepefcorieesacofh lcithtelemiinctaelreisstn(ootpgoisvsenuminshthriismpre,port
Indian catfish, snakehead catfish, oysters, clams, sponges and many others) and data which
is considered by the EPA reviewers to be of questionable value,
Additional degradability and toxicity data have been taken from the Handbook of
Environmental Data on York, 1983). These are
Organic Chemicals referenced by page
by Karel Verschueren (Nostrand Reinhold, New numbeirn the Handbook followed by the date of
tahnedoirnigVienralscrhefueerreennceb.utThoenrlye tahreeAmQaUnIyRcEasreesfeirnewnhciecihs gthievesnabmeecaduastae aitpipnecalrudeedsotnheAEQPUIARE
`quality rating of the original reference.
Raw material suppliers were contacted and asked for any
identified from environmental
the 3M PRISM database and suppliers were data they have. Unfortunately, environmental
data
was not generally available from raw material suppliers. And, the suppliers were siow in
>
sending the limited data do have.
i
;
eTnhveirsoonumrecnetaalndasresleiasbsilmietyntofotfhtehelitceormatpuorenednattas waansd tthaekerneicnotmomceonndsiadteiroantsiofnorinfutrhteher testing.
3
Information for each component or formulation is organizedasfollows:
Formulation or component name and RM number Chemical Abstracts Service (CAS) Number
VDeegnrdaodrabsility data from the literature or from previous 3M assessments
Aquatic Toxicity data from the Environmental Assessment
literatureor
from
previous
3M
assessments
_
Recommendations for Additional Testing
-9-
001189
-3
lDiesttaaibloevdei.nformation for components and formulations are given in the same order as in the
1. Ethylene Glycol (RM 3017) CAS #107-21-1
Vendors: CUhneimotnecChar,bAidseh,laTnedxtCilheemCihceamli,caDlo,wAsChhleamnidcaClh,emTiecxaalc,oUCnhoecmailcal, Olin, Shell Ol,
Degra`dTahbeoirlettyi:cal Oxygen Demand (ThOD) 1.29 g/g (Verschueren p 646)
BOD,
0.44f0r.o2m2Vge/rgsc(ahvugeroefn12p c6i4t6a)tions
BOD,
0.52 g/g (Env. Lab.' Req. #1940) 0.67 gig (Verschueren p 646; 1953)
BOD,
1.19 g/g (Env. Lab. Req. #1940) 0.92 g/g (Verschueren p 646; 1953)
. BOD,
1.14 g/g (Env. Lab. Req. #1940) 1,000.08 g/g (avg of 3 citations
from Verschueren p 646)
cop
1.02 g/g (Env. Lab. Req. #1940)
1.240.04 g/g (avg of 3 citations.
2
1.28frgo/mg V(eEnrvs.chLuaebreRneqp. 6#149640)),"
:
* BBOODD,,//CCOODDRRaattiioo
~
00..84 ((EEnnvv.. LLaabb RReeqq,. ##11994400))
=
ToxiciGtyr:e*en
Algas
(Scenedesmus
quadricauda)
78--ddaayy sSttaattiiccPPooppuull..GGrroowwtthh IInnhhiibb..
:
1100,,000000
mmgg//LL
((AAQQUUIIRREE
2; 2;
11997880))
3 4
T3hMeEtnovxiicriotnymdeanttaalarLeaab database.
pwaortrikaldloinsteinignoDfe3c8.
t1e9s7t3s.on
16
species
from
the
EPAAQUIRE
5 Pporpeu-leaxtpioonnenGtrioalwtlhagInrhaitbeiteifofne:ctCsh.ange in cell number of algal species including
J10-
.
001190
Protozoa (Entosiphon sulcatum)
72-hr Static Popul. Growth Inhib. 10,000 mg/L (AQUIRE 2; 1980)
Blue-green Algae (Anacystis aeruginosa)
___. 8~day Static Popul. Growth Inhib. 2,000 mg/L (AQUIRE 2; 1978)
Bacteria (Pseudomonas putida)
10,000 mg/L (Verschueren p 647)
Algae (Microcystis aeruginosa)
2,000 mg/L (Verschueren p 647)
Protozoa (Uronema parducz)
>10,000 mg/L (Verschueren p 647)
Water flea (Daphnia magna)
48-hr Static ECs,
>1,000 mg/L (EnviroSystems 191)
24-hr Static LCs
10,000 mg/L (AQUIRE 2; 1977)
24-hr Static LCy
10,000 mg/L (AQUIRE 3; 1983)
48-hr Static LCq
10,000mg/L. (AQUIRE 3; 1983)
Brine shrimp (Artemia salina)
.
24-hr Static LCs
20,000 mg/L. (AQUIRE 2; 1974)
24-hr Static LCs
20,000 mg/L (AQUIRE 3; 1983)
Fathead Minnow (Pimephales promelas)
24-hr Static LCs
10,000 mg/L (AQUIRE 3; 1983)
48-hr Static Cy
10,000 mg/L (AQUIRE 3; 1983)
96-hr Static LCs
10,000 mg/L (AQUIRE 3; 1983)
. 96-hr Static LCs
49,000 mg/L, 53,000 mg/L, &
57,000 mg/L (AQUIRE 2; 1983)
Bluegill Sunfish (Lepomis macrochirus)
;
96-hr Static LC,
10,000 mg/L (AQUIRE 2; 1968)
Rainbow Trout (Salmo gairdner)
>
96-hr Static LCy
41,000 mg/L (AQUIRE 2; 1980)
Common Shrimp (Crangon crangon)
5
48-hr Renewal LCy,
100,000 mg/L (AQUIRE 2; 1974)
96-hr Renewal LCs, -
50,000 mg/L (AQUIRE 2; 1974)
Goldfish (Carassius auratus)
|
96-hr Static LCs,
- 5,000 mg/L (AQUIRE 2; 1879)
-
Guppy (Poecila reticulata)
7-day Renewal LCs,
49,300 mg/L (AQUIRE 3; 1981)
6
Acute 1991.
Daphnid
toxicity
testing
done
by
EnviroSystems
for
3M.
Test
results
dated
March
10,
S11-
vo1191
A
Eng
----
Eprtehsyelnetneinglhyicgohlchoansceinntsriagntiifoincainnttthoexipcfrtoyduacntd, aft phirgohbaBblOyDd/oCeOsDnortaticoo.ntErviebnuttehsouubsgthanittiisally to
product toxicity.
RNonee.commefnordAddaititonialToestninsg:
2. Butyl Carbitol (RM 8887)
CAS# 112.34-5 (Disthylene Glycol Monobutyl Ether)
SGlycyol EnthaeorndDBnve(nOdyxoyrcsmh:eBmus )t,ylBDuitoyxlitCoalr(bCiationlC(hUenmiiocnalC)a,rbPiodley-CSoorlpvoDraBti(oOnli-nLCionrdpeorDaitvi.o),n),
CBuhteymliDciaolxiPtorlod(uSchtesll,
Oil Company), Inc.)
Dowanol
DB
(Dow
Chemical),
Ektasolve-DB
(Eastman
DegrTadhabOilDity: .BOD, BOD, BOD, BOD; cop BOD,/COD Ratio BOD,/COD Ratio -
"2.47 gig (calculated)
00..2659 (g/Vger(sEcnhvu.sLraebn.'p R52e4q), #1940)
1.45 g/g (Env. Lab. Req. #1940)
1.61 g/g (Env. Lab. Req. #1940)
1.56 g/g (Env. Lab. Req. #1940)
21.8038 (g/Vger(sEncvh.uoLrabe.npRe5q2.4)#1940)7
.
00..1327 ((EVnevr.scLhaubs.rReenqp. 5#2149)40)
5
0.85 (Env. Lab. Req. #1940)
Toxicity
-
Bacteria (Pseudomonas putida)
255 mg/L (Verschueren p 524)
-
78 T3MhEtnovxiicriotnymdeanttaalarLeaabpwaortrikaldloinsteinignoDfe1c5. t1e9s7i3s.on 10 species from the EPA AQUIRE database.
-12-
VU119<
3
.
Green Algae (Scenedesmus quadricauda) 7-day Static Popul. Growth Inhib.
__ 8-day Static Popul. Growth Inhib. Blue-green Algae (Anacystis aeruginosa) 8-day Static Popul. Growth Inhib. Protozoa (Entosiphon sulcatum) 72-hr Static Popul. Growth Inhib. Protozoa (Uronema parduczi) Protozoa (Chilomonasparamecium) 48-hr Popul. Growth Inhib. Water Flea (Daphnia magna) 48-hr Static EC, 24-hr Static LCs Bluegill Sunfish (Lepomis macrochirus) 96-hr Static LC, Goldfish (Carassius auratus) 24-hr Static LCs Guppy (Poecilia reticulata)
: 7-day Renewal LCs, Silver ide (Leuciscus idus) Static LCs,
1,000 mg/L (AQUIRE 2; 1980) 1,000 mg/L (AQUIRE 2; 1978) 53 mg/L (AQUIRE 2; 1978) 73 mg/L (AQUIRE 2; 1980) 420 mg/L (Verschueren p 524) 2,774 mg/L (AQUIRE 4; 1980) 706 mg/L (EriviroSystems 1991) 2,850 mg/L (AQUIRE 2; 1977)
. 1,300 mg/L (AQUIRE 2; 1977) 2,700 mg/L (AQUIRE 2; 1979) 1,150 mg/L (AQUIRE 3; 1981) 1,805 mg/L and 2,304 mg/L
(AQUIRE 3; 1978)
Inland Silverside (Menidia beryliina)
~ 96-hr Static LCs
2,000 mg/L: (AQUIRE 2; 1977),
EnBvOiDrodnamteansthaolwAsssfeaisrlsymheingth;degradabilty. The literature data show this material to have
;
insignificant toxicity to fish and Daphnia. Thetwo freshwater green algae values from
AAQUIRE are consistent and indicate that butyl Carbitol is practically non-toxic to green
algae. There is considerably more toxicity shown to blue-green algae, however. We should
Bhave a sample4of butyl CagionalrbitetTseotaetldngf:or algal toxicityto be sure of its toxic effects.
Algae and Microtox.
-13-
)
001193
s
3. Duponol ME Dry Surfactant (RM 3021; Sodium Lauryl Sulfate) CA#S 151-21-3 (Sodium Dodecylsulfate CH(CHy),,OSONa)
Vendor; Dupont?
ThOD
BOD
Toxicity:
Green Algae (Chiorellasp) `Static Popul. Growth inhib.
Green Algae (Chlorella vulgaris) * - 72-hr Static Growth Inhibition"
Green Algas (Scenedesmus quadricauds) 7-day Static Popul. Growth Inhib. 8-day Renewal Growth Inhibition
Flagellate Euglenoid (Entosiphon suicatum) 72-hr Static Popul. Growth Inhib.
Blue-green Algae (Anacystis aeruginosa) 8-day Renewal Popul. Growth Inhib.
Bacteria (Pssudomonas putida) Call Multiplication Inhibition
Protozoa (Uronema parduczi) Call Multiplication Inhibition
2.03 g/g (calculated) Salwkiylshseulrf"atreespohratvsethlaotng"lbieneeanr primary recognized as extremely rapid in `primary biodegradation, often disappearing in less than aday" and cites approximately 100 references which show degradation rates of 80 to 100% within a few hours or days.
50 mg/L (AQUIRE 4; 1980)
0.05 mg/L (AQUIRE 4)
0.02 mg/L (AQUIRE 2; 1980)
0.02 mg/L (AQUIRE 2; 1978)
:
iL,
>
40mglL (AQURE2;)
Lo
7 mg/L (AQUIRE 2; 1978)
'
290 mg/L (Verschueren p 793; 1980)
0.75 mg/L (Verschueren p 793; 1980)
9 Phone: 302-774-1000. 2/15/91: will send information.
10 Swisher,
807-811.
R.
D.SurfactantBiodeg2nrd ead.dMaracetlDi ekkoern : Ne,w
York,
1987,
p
466,
11
The toxicity data are AQUIRE database.
a
partial
listing
of
the
409
tests
on
49
species
from
in
the
EPA
12 Growth Inhibition: Measurable change in length and/or weight.
S14
001194
3
.
Water flea (Daphnia magna)
48-hr Static EC,
2.9 mg/L (EnviroSystems 1991)
24-hr Static LCq
33.0 mg/L (AQUIRE 2; 1977)
__. 24hrStaticiC,y 48-hr Static LCy,
72,100, & 12.0 (AQUIRE 3; 1983) . 7.082.1 mg (avg of 8; AQUIRE 2;
48-hr Static LCs
1982) 5.00.5 mg/L (avg of 3; AQUIRE 3;
48-hr Flow-through LCq
1983) 1.8 mg/L (AQUIRE 2; 1981)
Fathead Minnow (Pimephales promelas)
24-hrStatic LCy, 48-hr Static LCy,
7.4 8.5 mg/L (AQUIRE 3; 1983) 6.6 & 7.3 mg/L (AQUIRE 3; 1983)
96-hr Static LCs,
6.6 & 6.9 mg/L (AQUIRE 3; 1983)
Bluegil (Lepomis macrochirus)
96-hr Flow-through LC
4.5 mg/L (AQUIRE 2; 1981)
Mummichog (Fundulus heteroclitus)
96-hr Static LCs,
2.1 mg/L (AQUIRE 2)
Sheepshead Minnow (Cyprinodon variegatus)
24-hr Static LCs
10.0 mg/L (AQUIRE 2)
48-hr Static LCy
9.0 mg/L (AQUIRE 2)
: 96-hr Static LC,
9.0 mg/L (AQUIRE 2)
High-eyes Medaka (Oryzias latipes)
6-hr Renewal LCyo
67 mg/L (AQUIRE 2)
24-hr Renewal LCy _- 48-hr Renewal LCy
46 mg/L (AQUIRE 2)
46 mg/L (AQUIRE2)
Brine Shrimp (Arteria salin) 24-tr Static LCs,
i
2
3.6 mg/L (AQUIRE 2; 1974)
*
Atlantic Silverside (Menicia menidia)
96-hr Static LCs
2.8 mg/L (AQUIRE 2; 1982)
Killfish (Fundulus similis) 24-hr Static LCs,
-
_
4.7 mg/L (AQUIRE 2)
48-hr Static LCy, 96-hr Static LCq,
4.7 mg/L (AQUIRE 2) 4.5 mg/L (AQUIRE 2)
Rainbow Trout (Salmo gairdner)
48-hr Flow-through LCs, 96-hr Flow-through LCy
5.95 4.62
mg/L mg/L
(Verschueren (Verschueren
p p
793; 793;
1977) 1977)
10-day Flow-through LCs,
2.85 mg/L (Verschueren p 793; 1977)
15.
)
001195
Sa
Zebrafish (Brachydanio rerio)
48-hr Flow-through LCs, 96-hr Flow-through LC,
8.81 mg/L (Verschueren p 793; 1977) 7.97 mg/L (Verschueren p 793; 1977)
__. 10-day Flow-through LCs,
7.97 mg/L (Verschueren p 793; 1977)
Flagfish (Gordanslla floridae)
48-hr Flow-through LC, 96-hr Flow-through LCyy
10.0 mg/L (Verschueren p 793; 1977) 8.10 mg/L (Verschueren p 793; 1977)
10-day Flow-through LC,
6.90 mg/L (Verschueren p 793; 1977)
EnLivtierraotnumreendtaatlaAisnsdeicsastmesenfatir;ly low toxicity to bacteria and although no actual BOD test data
are available, this material should be obtained by our
oshwonulBdObDe
treesatdsi.ly
degraded
by
microorganisms.
A
BOD
value
dThaitsa amagtreereisalweisllmowidtehraltiteelryattuorxeidcattoafwishhi,cDhapghinveisa,usancdonafligdaeen.cOeuirn tmhoestcornetcreanctt lDaabpohrantioaryt'esst
`work on this material. Because there is sufficient fish toxicity data from the literature, no fish
testing is warranted.
:
Because of the algal toxicity shown in the literature data, algae testing should be done.
aEdvveenrstehoeufgfhectthsiswilmlatbeerimailniismatolxiifcitt oisapvaasrsieetdytohfraoquugahtiacwoarsgtaenwiastmesr,triteraetamdielnytdseygsrtaedmesorainfda
Wsiegnisfhiocaunltdnduomsbeormeofsmtuidcireosoringawnhiiscmhsoaurrepprroedsuecnttisinpaasnsaetusrtalhrwoautgehrtaomdoedgerlawdaesitterwaapitdelry.
treatment system and would be a simulation
tofheamneaatusruarlebtohdeytoofxiwcatefefrecutssinogf tahneamqoudaerli'usmefsftlouecnkte.dAwniotthhfeirshs,tTuhdiys
~~
Bwould give us a" n understanfidona)ing oTfetshteindge:gradation in a river, pond, or lake. "
BOD, COD, and Microtox.
4. Tolyltriazole (RM 27513; Corrosion Inhibitor Tolyitriazole Technical Grade)
CAS #29385-43-1
CHiN,
on
N
A
H
SynonyMemtshayln-d1vH-eBnednozrost:riazole
-
16
)
001196
C4
.
Methyibenzotriazole CPorebvreantteocl TCTI-71-01000((PMMoCb,aIyncC.oTMr)p.)
BOD
<60% ThOD (Mobay Corp.)
Toxicity:
Water Flea (Daphnia magna)
48-hr Static EC,
Lo.
Bluegil Sunfish 96hriCh
Rainbow Trout 96-hr LCyy
Fathead Minnow 96-hr LCs,
19mg/L (EnviroSystems 1991)
31.0 mg/L (Mobay Corp. and
PMC) -
:
-
+
21:4 mg/L PMC)
(Mobay
Corp.
and
5
:
25.5 mg/L. PMC)
(Mobay
Corp.
and
Add1iH-tBiednoaztonatrafiolarzoalseim(iCleaHrecNosm)pound:
Oy4
* CAS Number: 95-14-7 Synonyms:
Li
1,23-Benzotriazole Aziminobenzene
2
Benzene Azimide
SR
" Benzotriazole
_
Py
Bluegill sunfish (Lepomis macrochirus) Static 24-hr Stress
5 mg/L (AQUIRE 3; 1957)
;
Rainbow Trout (Salmo gairdiner)
`Static 24-hr Stress
5mg/L (AQUIRE 3; 1957)
~
Sea Lamprey (Petromyzon marinus)
Static 24-hr Stress :
5 mg/L (AQUIRE 3; 1957)
Chinook Salmon (Oncorhynchus tshawytscha)
Static 24-hr Mortality
10 mg/L (AQUIRE 3; 1969)
13 PMC Specialities (513-242-3300).
Group,
Inc.
Technical
Bulletin
3200.
Contact:
Bil
Mautiewicz
14 Mobay Corp. data given by Matthew Bartman 412-777-2000.
S17
001197
`a
Coho Salmon (Oncorhynchus kisutch) Static 24-hr Mortality
Northern Squawfish (Ptychocheilus orgonensis) Z_. Static 24-hr Morality
10 mg/L (AQUIRE 3; 1969) 10 mg/L (AQUIRE 3; 1969)
EWnhviilreontmhenltimailtAesdsdeastasmsehnotw:s that this material is moderately toxic, ts presentatsuch low `pcroondcuecntt.raBteiconau(s0e.0o5f%t)heinttohxieciptryodoufctth,istmmataeyrihala,vewelitnlee aedffaecct oimnptlheetoevesreatlolftodxaitcai.tyTohfertheeis 0 reason to repeat the fish data, however.
TUhSisEPmAat.erial is listed on thteonal TSCATes8t(di)ngl:ist and any testing done must be reporttotehde
BOD, COD, algae, and Microtox.
:
5. Foamer (FM-4115)
Toxicity;
Water Flea (Daphnia magna) 48-hr Static EC,
. 68 mg/L (EnviroSystems 1991)
En"TvhierfoonammeenrtaslhAoswssesslsigmhetnttox:icity to Daphnia, but there is no data for the remaining environmental effects. We should have a complete set of effects data for this material.
Creaprreessefnitoautiidvbeestaamkpelnetwhahticthhehsaasmbpeleenupsreoddiunctehdebeyntvhieromnamnaufnaaclteufrfiencgtsmteetsthiondgiwshaicghowoidll > bo used in the f. uture. ional Testing: BOD, COD, fish, alga, and Microtox.
6. Filmer (FM-3820 or FC-95)
Degradability:
BOD, BOD, BOD, cop ToxiciBtOy:DICOD
nil (PED) nil (PED) nil (PED) nil (PED)
8-
.
oo11vp
.
Water Flea (Daphnia magna)
48-hr Static EC,
49 mg/L (EnviroSystems 1991)
48-hr Static EC,
50 mg/L (PED)
-- Activated Sludge Inhibitory Conc.
>4,000 mg/L (PED)
Fathead Minnow (Pimephales promelas)
96-hr LCs
38 mg/L (PED)
Bluegill Sunfish (Lepomis macrochirus)
96-hr LCyo
68 mg/L (PED)
Rainbow Trout (Salmo gairdner)
96-hr LCs
11 mglL (PED)
En`vThierfoinlmmeernwtialllnAostsceosnstrmiebnutte;to the BOD/COD ratio, so toxicity.is the issue with this caogmrpeoenmeenntt.bTehtiwseemanteprrieavlioduosesansdhporwessleingthtDtaopxihcnitiyattooxfiicsihtyanddatDaawphhinciha.giTvheesreusIscognofoiddence in the most recent data from EnviroSystems.
Wmoaenunfeaectdutroinhgavloetawhciocmhplheatsebseeetnofprefofdeucctseddabtyatfhoer maasnaumfpalcteurreipnrgesmeentthatoidvewhoifcah rwielclebnte
used in the futu"re.
ional Testing:
Algae and Microtox.
7. Na-octylsulfate (RM 32067 or RM 55040")
.
CAS#142314
4
Vendors:Alcolac Incorporated" (POLYSTEP B-29).
(Sodium
Octyl
Sulfate
Solution);
Stepan
Company"
;
ThOD 1.88 g/g (calculated) -
15 16
WAlicmolaVca:nn3e0s1t-e3'5s5-P26R0O0F.SNonodtaetdaaatveadil0a3b/le1.2/1990
gives
this
RM#.
17 Called 708-446-7500 ext. 2283: they have no data.
-19-
001199
ca
BOD Srweciosghneirz"edreapsoretxstrtheamtel"ylirnaepairdprinimparriymaarlkyylbisoudlefgartaedsahtiaovne,loofntgenbediesnappearing
Lu
in less than degradation
a day* and rates of 80
ctiote1s0a0p%prwoixtihmiantaelfyew10h0ourresfeorrednacyess.which
show
ToxiciAtuys:t"ralian Barnacle (Elminius modestus)
30-min Water Flea
(SDtaatpihcniImamombaiglniaza)tion
ECs
3,970 mg/L (AQUIRE 2; 1976) 517 mg/L (EnviroSystems 1991)
48-hr Static ECs,
EnAvlithrooungmhenntoaBlOAsDsoerssCmOeDntd;ata are available, this material will most likely have a high wBhOiDc/hChOavDerabteioe.nBoObtDaiannedd CinOtDestdsatcaomsphaorualbdlbeetoobtthaoisneedusseodthfaotr twhee hraevmaeinnuimnegrical values components.
`hTohweereveirs sfuorrptrhiseinDgalpyhlniitlae dlaittearaittusrheodwastacaovnasiildaebrlaebolyn tlehsesatqouxaictiitcyttohxaicnittyheofCth,isssuurrffaaccttaanntt.,
aTlhgiases,uarfnadctMainctriostopxretsoexinctitayt ingredient.
3% so it data are
emsaseyntbiealatmoacjoomrpflaectteortthoe
taoxsisceitsysomfetnhteopfrtohdiusct,
Fish,
=
y
ional Testing:
BOD, COD, fish, algae, and Microtox.
8. Di-water (RD 199) .
'
.
.
Toxicity:
'
Wate4r8F-lheraSt(aDtaipchEniCa,magna- ) ~~ >1,000 mg/L (EnviroSystems 1991)
EtWnrhvaiiclreeodnittmomecanotynatslaeAmesismneaftsoeosldmiedshenittoo;ntiezsetdtwhea.tdeeriosunpipzleideswinatfhoetrptaosexti.ciTrthy,efDoaxipchenfifaecrtessuhlatviendbieceatnes~~ --
that the supply was not contaminated and no further testing of the deionized water sample
Bis warranted. .
gional Testing:
None.
11988TS0hw7ie-sr8he1e1rw.,asR.1 Dt.esSturgfiavcetnanintB theiEPoA AdQUeIRgE2nr ddaeta adb,aMdsaer.acet l Deikkoer:nN, ew York, 1987, p 466,
20
001200
CHE
9.FC-203
DegrBadOabDi;lity: BOD, cop BODYCOD
Toxicity: MicrotEoCx, ECs Activated Sludge Inhibition Algaean(dChPlohroerlmlaidpiyuremnioniudnodsaatum) . Algae72(-ShrceSntaetdiecsPmoupusls.uGbrspoiwctahtuIsn)hib. EC, 72-hr Static Popul. Growth Inhib. ECs, Wat- e2r4F-lheraSt(aDtaipchEnCia,magna) 24-hr Static ECy, 4488--hhrr SSttaattiicc EECC,,,
560 g/L (PED)
717 g/L (German Army Report)
1,060 g/L (PED)
11,,037703
g/L gL
((PGEeDr)man
Army
Report)
R0e.p5o2r(t)PED and German Army
.26,35200m.gm/gL/L(G(eGremramnanAmArymyReRpeoprotr)t) none at 1,000 mg/L. (PED) no effect at <1,000 mg/L (PED')
1166.09mmgg//LL((GGeerrmmaannAArrmmyyRReeppoorrtt)) .
4313.06mmgg//LL((GGeerrmmaannAAmrymyRReeppoorrtt)) > 212,6900mgm/gL/L(E(nPviErDo?S)ystems 1991)2
2+0A"r3m%yaRpepploircta.tiTonhesoGleutrimonasn" Awerrmeyuvsaeludetsowoebrtaein41t,h2e00BOmDg/,LaannddC2O1,D50d0atmagiinLtfhoerGtehermCaOnD
ainntdhiBsOrDep,ortr.espectively. The German Army values were multiplied by 33.3 to get the valuoes
21 22
TEensvtiirnogSdysotneembsyisInrdeupsetraitailngBitoh-isTetsetstLbaebocraautsoeryt,heJraen.w1a9s74n,ot
enough
variation
in
the
FC-203
23cToenscteinntgradtoinoensbtyheByiounsoemdictosdLeavboerlaotporayg,oDoedc.st1a9n7d3a.rd curve.
21.
001201
ca
Easte(rCnraOsyssotsetrreEambvriyrgoi-nlicaar)vae 48-hr Static ECs,
~~Grass96S-hhrriSmtapti(cPaLlCa,emonetes pugio) Fathe9a6-dhmriSntantoiwc L(CPismephales promelas) Zebra4f8i-shhr(SBtraatcichyLdCa,nio rerio) 48-hr Static LCy, Scud (Gammarus fasciatus)
48-hr Static LC,
Rain9b6o-whrtrSotuatti(cOnLCcso,rhyncus mykiss ) Rain9b6o-whrtrCoountt(iOnnucoourshFylnocwusLCmsyk,iss) Comm96o-nhrmSutmatmiiccLhCo,g (Fundulus heteroclitus) To Gras%s eShrrLimCpy(Palaemonstes pugio) En1v.iTrhoenmfiesnhttaoxliAcistsy edsatsamefrnotm;the German Army Report 3M studies, so no fish testing is needed.
47 mg/L (PED)
510 mg/L (PED) 750 mg/L (PED) 11,,065334 mmgg//LL ((GGeerrmmaann
1,100 mg/L (PED*) .
1,300 mg/L (PED) 400 g/L. (PED) 2,500 mg/L (PEDTM) 510 mg/L (PED) agree. s wll with data
Army Army
RReeppoorrtt))
from previous
2. The
not be
Microtox tests
repeated.
from
the
German
Army
Report
seem
reasonable,
so
this
tef
should
;
Es3C.aytT,ishfefir2eod4m-wihttrhheEtGhCee,rcmoDnaacnpehnAntrirmaatytiooRxneicspioturystferadorimentitnhhefeamiEronlsyvtigrorooeScdyesnatgrEenevmiweronortSk.y'saHtnoewmetsvheewryo,rakrweeanrwedeprteehante'4t8-h~r~ --
tems
d
ing
24 25
TTeessttiinngg
done done
by by
BBiioonnoommiiccss
LLaabboorraattoorryy,,
July Aug.
1199807..
26 27
FTeosrtmienrglydoSnaelmboy
gBaiiorndnoemriic.s
Laboratory,
Dec.
1973.
2298TNeostmionrgtadliotnyeobryabBnioornmoamlicesffLeacbtosraattotrhiys, cAoungc.ent1r9a7t9i.on.
.22-
.
001202
vay
tbheisdwuoerkt.o
fTohremullaartgieondicfhfearnegnecse
boretcwheaenngeGserinmtahne
Atorxmicyitvyatleuset
and the protocol
1973 PED value may but this cannot be
verified.
4t.esAtsingwiitshotfhkenfoowanmecromapnodsiftiimoenr,awned fnreoemdatoknbaowcnarmefaunluftahacttutrhiensgafmotp.le submitted for
p5.roSbianbcleyttohxiecimtoystto iamlpgoaretawnat.s of concem in the German Army Repor, the algae data is BBODe,cCOoD,manmd ealfgnoare.AdddaititonialToestninsg: 10. VW160390 (FC-203 without Tolyltriazole RM 27513)
ToxiciWtayt:er Flea (Daphnia magna)
-
48-hr Static EC,
165 mg/L (EnviroSystems 1991)
Enm1v.atiSerironicnalemeatnhleotnaoglnlAwyistsdhiefsFfCse-mra2en0nc3te:sbeeetwmeselniktehias gmoatoedriwaalyantoddFeCt-e2rm0i3nies tthoelyletfrfieacztoloef, ttoelsytitirnigaztohlies.
tFhoeretfhfeecrtecofenttolDylatprhianziolaedcaatan,notthebree sieselnit.teIndiffafcet,retnhceetboexitcwiteyeonfFFCC--220033awnadsVsWli1g6ht0l3y 9le0ssand
`trcheoapmnepatltheientgetdotxhtiehcieDtsyaeoptfhenVsitWsa1b6feo0fr3otr9hee0smeiankttiwhnoegsraaemncpeelnvteaslE,unavwtieironowi.Slylshtaevmestw-oowraki.tSuinnticleEEnnvviirrooSSyy%sstteemmsshiass >
c2.omApMaircerdottooxtahnedFCfi-s2h0to3xirceistuylttessttossheoeulidf tbheerdeoinseaomnetahsiusrmaabtleerieaflfeacntdctahueseredsublyts
Ch
tolytriazole in the product. ~~
B
,
tong Testing!
-
-
BOD, algae, fish, and Microtox.
30cEonnvceinrtorSaytsitoenmssthiseyreupseeadtitnogdtehviseltoesptabegcoaoudssettahnedraerdwacusrvneo.t enough variation in the
23
001203
11. FC-203CE.
Degradability:
BOD; BOD;
BOD
cop BOD,/COD ratio Total Organic Carbon (TOC) OECD Method 301E
91 gL (PED) 400 g/L (PED)
680 g/L (PED)
762 g/L (PED)
0.89 (PED)
220 gL (PED)
.
88-90% biodegradability
in 14 days (PED)
Toxicity:
Agas (Selenastrum capricornutum)
>1,000 mg/L (PED)
95-hr ICs
OECD Activated Sludge Respiration
none at 1,000 mg/L
Inhibition Test 209
Water Flea (Daphnia magna)
1,000 mg/L (PED)
- 48-hr Static LCs
Microtox (Photobacterium phosphoreurm)
Exposure:
ECw
5 min.
370 mg/L
15 min. "30min
260 mg/L 230 mg/L.
F
Killfish (Fundulus heterociitus)
E
96-hr Continuous Flow LCs,
1,400 mg/L (PED)
Fathead Minnow (Pimephafes promelas)
96-hr Continuous Flow LCs,
2,000 mg/L (PED)
96-hr Static LC,
>1,000 mg/L (PED)
-
EnTvhiereonnvmiernontmaelnAtsasleesfsfmecetnstd:at
a
fo
r
-
FC-203CE
Is
fai
rl
y
co
mpl
et
e.
AThremyPREeDpodrattaansdhofwrsomltohweerretocxeinctittyetsotsDbayphEnnivairtohSaynsitsesmsh.owDnapbhyniFaC-t2es0t3inign sthhoeuGled rbmeadnone
R`Bagain for assur"ance in our PioEnal D. Testing:
Algae and Daphnia.
24
001204
oxy
12. FC-206CE
B
_
BOD, BOD, BOD,, * cop BOD,/COD ratio Total Organic Carbon (TOC) OECD Method 301E
46 g/L (PED)
260 g/L (PED)
470 g/L (PED)
402 g/L (PED)
1.2 (PED)
130 g/L (PED)
.
89-92% biodegradability
in 14 days (PED)
Toxicity:
Aigas (Selenastrum capricornutum) 95-r ICs
1,000 mg/L (PED)
OECD Activated Sludge Inhibition Test 209
Respiration
~ none at 1,000 mg/L.
Water Flea (Daphnia magna) . 48hrStaticLCy
>1,000 mg/L (PED)
Microtox (Photobacterium phosphoreurm)
Exposure: 5 min.
ECy 650 mg/L
15 min. 30min
4500 mgiL 4200 mg/L
4
w
f-
.
Killfish (Fundulus heterociitus) 96-hr Continuous Flow LCs,
2,000 mg/L (PED)
;
Fathead Minnow (Pimephalespromelas)
96-hr
96-hr
Continuous
Static LC
Flow
LC,
>>21,,000000 mmgg//LL((PPEEDD))
-
EnTvhiereonnvmiernotnmaelnAtsasleesfsfemcetnstd:ata for F. C-203CEis fairly complete.
BAgain, the PEDy data shows-low toxicitowy to Daphnia which should be verified.
Algae and Daphnia.
25.
001205
13. FC-203CF EnNvoiernovnimreonntmaelntAaslseefsfsecmtesndta:ta for this product are available and a complete set of environmental effects data should be obtained. `Recommendations for Additional Testing: BOD, COD, algas, Daphnia, fish, and Microtox.
14. FC-206CF EnNvoirenovnimreonntmaenltAaslseefsfsemcetsntd:ata for this product are available and a complete set of environmental effects data should be obtained.
BOD, COD, algae, Daphnia, fish, and Microtox. :
15. L-4640 (New Foarmer)
Testing is curently underway 1. Daphnia toxicity study
for a European PMN by (C2 EEC test method).
NOTOX
Laboratories:
2. 3.
Fish toxicity (C1 method) Modified Sturm test (C5)
using Zebra fish (Brachydanio for ready biodegradabilty.
rerio).
Alltesting for the European PMN s being done by GLP.
Tcohmepifolleldowiinntgheenrveiproorntm"eEnntvailreofnfmeecnttsadlaDtaataareanfrdoImnfsoervmeraatlio3nMintSeucphnpiocratlorfetpohretPs MwhNicfhorare
Cartain-Chermical Substances Designated as L-4640", June 20, 1880.
>
Degradability:
.
BOD,
<0.038 g/g
BOD,
-
<0.038 g/g
BOD
<0.038g/g -
cop
.
0.419/g
3
Theoretical Oxygen Demand
0750/9
Toxicity:
Acute Effect on Microbial Respiration
8% reduction in rate of oxygen
Water Flea (Daphnia magna)
depletion at 1,000 mg/L --
48-hr Static LC,
100 mg/L and 111 mg/L
Fathead Minnow (Pimephales promelas)
96-hr Static LCs,
158 mg/L and 166 mg/L.
.26-
001206
EnBveicraounsmeenoftathleAismspeosrstmaencnet:of this material to future products, afull set of environmental etfhfeecptrsevdiatoausisstnuedeideseds.hoTuhled ebnevoibrtoanimneendt:alalegfafeecatsnddaMtiacrnoottoxi.ncluded in the PMN work or in BAlgeaecanod mMicmroteoxf.nordAddaititonialToestninsg:
16. Witcolate 7093 (RM 45666)
CAS#73665-23-2
'5W5it%cowaCtoerrp,or4a5ti%onC6(-7C131-043e3th-o7x2y8l1a)tehdassunlfoateec.oTtohxeyinrfeorcmoamtimoennadveaidlaSbwlies.hWeirtcfoolrate 7083 Is
biodegradation information.
i
No information on EPA AQUIRE database nor in Verschueren,
EnNvoierfofnemctesndtaatlaAisssaevsaislmaeblnet.:Testing in future products.
depends
on
the
likelihood
that
this
material
wil
be
used
BCOeD,cBOoD,malmgaee,fnfoirshdA,dDdaaitpihtonniaial,ToeasntndinMsgi:crotox.
17. Triethanolamine
:
CAS#102:71-6
Degradabilty.
ThoD BOD;
BOD, BOD, BOD,
-
-
)i
2049/9
ni
0.02 0.17
g/g g/g
with standard seed adapted sewage
0.039/g
0.029/g
nil with std. diluted sewage
0.05 gig
0.13 g/g
.
FR
-
31 All degradabity data are from Verschueren p 1150-1.
27
.
001207
cop BOD/COD BOD,/COD
Toxicity.
BacteProipaul(.PsGeruowdtohmoInnhaisb.putida)
AlgaePo(pMuilc.roGcryoswtitshaIenrhuibg.inosa)
Gree7n-AdlagyaSsta(tSiccePnopeudle.sGmruoswqtuhadInrhiicba.uda)
8-day 8-day
Static Static
Popul. Popul.
Growth Growth
Inhib. Inhib.
Blue-green Algae (Anacystis aeruginosa)
8-day Static Popul. Growth Inhib.
Protozoa (Entosiphon sulcatum) 72:hr Static Population Growth
Proto4z8o-ahr(RCehnileowmaolnaPosppualr.aGmreocwituhm)Inhib. Protozoa (Uronema parduczi) Bacteria (Pseudomonas)
LC, Algae (Scenedesmus)
"LG, Algae (Colpoda)
LC, WatLeCr,Flea (Daphnia) ~
24-hr Static LCy, Brine24S-hhrrimStpat(iAcrtLeCmyi,a saliria) *
1.50 glg nil00.11 0.09
>10,000 mg/L (Verschueren p 1151)
47 mg/L (Verschueren p 1151)
1.8 1.8
mg/L mg/L
((AAQQUUIIRREE
2; 2;
1980) 1978)
715 mg/L (AQUIRE 2; 1978)
.
19
mg/L and (AQUIRE
427;
1m9g7/8L)
56 mg/L (AQUIRE 2; 1980)
1,768 mg/L (AQUIRE 4; 180) >10,000 mgiL (Verschueren p 1151)
10,000 mg/L. (Verschueren p 1151)
100 mg/L"_ (Verschueren p 1151)
>
160 mg/L. (Verschueren p 1151)
21,,530900 mmgg//LL ((VAeQrUsIcRhuEe2r;en19p771)151) -
5,600 mg/L (AQUIRE 2; 1974)
32Thetoxicity database.
data
are
a
partial
listing
of
the
16
tests
on
10
species
given
in
the
AQUIRE
33 This value is from a different reference than the previous one.
.28-
-
001208
Goldfish (Carassius auratus)
24-hr Static LC, 24-hr LCs, (85% TEA)
5,000 mg/L (AQUIRE 75,000 mg/L at pH 7
2;
1979)
--
3,mg/5 L at0 pH10 0.3
(Verschueren p 1151)
EnTvhiisromantmeerniatlaslAhsoswessisnmsiegnnitf;icant toxicity to Daphnia and fish.
aHdodwietivoenr,,ittshhaoswsa cloonwsBidOeDra/bClOe Dtoxriactiitoyatnodalwgilale.coFntorritbhuteesetoreaalsoownsr,aittiowoinutlhdebperobdeusctt.noItnto
use this product
material in products unless wil be extremely low.
no
altemative
can
be
foundor
its
concentration .
in
the
The literature data be reported to US
is essentially completefor EPA under section TSCA
this 8(d).
material.
Any.testing
on
this
material
must
A
.
joa Testing:
None.
18. Urea
CAS#57-13-6
Degradability:*
Degrades abiotically: HNCONH, + H,0 --> CO, + NH,
Degradation rate at 20C - Degradation rate at 2'C
Concentration in domestic sewage
. 10.9 mg/i/hr 3.3 mg/Lnr
2106 mglL
PP
>
'
5
Toxicity:
Bacteria (Pseudomonasputida)
Popul. Growth Inhib.
Gree7n-AdlagyaSeta(tSiccePonpeudle.sGmruoswqtuhadInrhiicba.uds)
8-day Static Popul. Growth Inhib.
3 >10,000 mg/L (Verschueren p 1178) 10,000 mg/L (AQUIRE 2; 1980) 10,000 mg/L (AQUIRE 2; 1878)
34 35
All degradability The toxicity data
daarteaaarpeartfiraolmliVsetirnsgcohfu3e2retnespts1o17n81-97.species
from
the
EPA
AQUIRE
database.
29
001209
fw
Blue-green Algae (Anacystis aeruginosa)
8-day Static Popul. Growth Inhib.
47 mg/L (AQUIRE 2; 1978)
=. Proto7z2o:ar(SEtnattoisciPpohpounl.suGlrcoawttumh)Inhib.
29 mg/L (AQUIRE 2; 1980)
Protozoa (Chilomonas paramecium)
48-hr Popul. Growth Inhib.
2,683 mg/L (AQUIRE 4; 1980)
Water Flea (Daphnia)
24-hr Static LC,
10,000 mg/L (AQUIRE 2; 1977)
Creek Chub (Semotilus atromaculatus)
24-hr LC, 24hr [Copp
16,000 30,000
mg/L mg/L
(AQUIRE (AQUIRE
2; 2;
1952) 1952)
EngLvirtieereronantaumlregeandeta.atlFauAirsntsdhieecsramstoemrseetn,htai:ttdtehigsrmaadteesriraeladsihlyowasndinitsimgonisfticlainktelt:yoxwiocuitlydtonoDtabphenaiap,rofibslh,emanind
the product.
sHhoowuelvdebre,vietrdiofeiesdsbhyoowutroxoiwcintytoestbsliufei-tgisreteonbaelguasee,dainndthteheprloodwutcotxiactithyitgoh gcroenceenntarlagtaieons.
None.
19. Triton X-305
CAS#
9002-93-1 (PRISM ~composition of the
rsehmoawinsiTnrgit3o0n %X-n3o0t5gtiovebn)e.70%
this " ~
material
with
the
i.
>
`SynonPyomlsy(:oxy-1,2-ethanediyl), aipha-[4-(1,1,3,3-tetramethylbutyl)phenyl]-
`omega-hydroxy-polyethylene Octoxinol
glycol
p-1,1,3,3-tetramet-hylbutylphanyl
ether
~
P-tert-octylphenoxypolyethoxyethanol
VendorR;ohm & Haas Company
36 Independence Mall West, Philadelphia, PA 19105. Phone: 215-592-3000.
-30-
+
001210
Siw
}
Toxicity:
Bluegill (Lepomis macrochirus)
24-hr Static LC,
3.5 mg/L (AQUIRE 1; 1975)
24-hr Static LC,
16.2 mg/L (AQUIRE 1; 1975)
oT
24-hr Static LC,
1,080 mg/L (AQUIRE 1; 1975)
24-hr Flow-through LC, 10.0 mg/L (AQUIRE 2; 1975)
96-hr Static LC,
2.8 mg/L (AQUIRE 1; 1975)
96-hr Static LCs,
12.0mg/L (AQUIRE 1; 1975)
96-hr Static LC,
531 mg/L (AQUIRE 1; 1975)
-
96-hr Flow-through LC,
6-day Flow-through LCs,
10.0mg/L (AQUIRE 2; 1975)
9.6 mg/L (AQUIRE 2; 1975)
|
The reason for the high values
Static LC, (531 mg/L )are not
for the 24-hr
known.
Static
LC
0
(1,080
.
mg/L)
and
for
the
96-hr
Thevendorfor Triton X-305 (Rohm and Haas) has no data on the aquatic toxicity or biodegradability of Triton X-305. However, they are sending adata sheet on theaquatic toxicity of Triton X-100. Triton X-100 has a lower molecular `weight than X-305 and they believe that the toxicity of X-305 is less than X-100 because X-305 is less surface active. Triton X-305 is not believed to degrade biologically. Rohm and Haas has recently sold their Triton product line to Union Carbide (1-800-752-1 1827) and will be transferring the business iTnhtehefonleloawrinfugtduraet.aTihs efrCoAmSAQnUuImbReErognivtheins bCyARSonhummbaenrd. Haas for the series is 9036-19-5.
CAS#9036-19-5
Tore
:
\
~
Rainbow Trout (Salmo gairdner)
'
48-hr Static LC,
7.2 mg/L (AQUIRE 2; 1978)
96-hr Static LC,
Marine Polychaste Worm (Scolelepis fuliginosa)
7.2mg/L (AQUIRE 2; 1978)
48-hr Static LC,
17.0 mg/L (avg. of 7 points)
~
96-hr Static LC,
.
13.7 mg/L (avg. of 8 points)
(AQUIRE 2; 1978)
37 The toxicity data are a partial listing of 13 tests on 5 species from the EPA AQUIRE
oo
database.
38dTathaebtaosxei.city data are a partial listing of 36 tests on 5 species from the EPA AQUIRE
a1-
00111
cd
Marine Polychaete Worm (Capitslla capitata)
48-hr Static LC4, i 96-hr Static LCy,
8.2 mg/L (avg. of 6 points) 6.0 mg/L (avg. of 8 points)
(AQUIRE 2; 1978)
Aquatic Sowbug (dotea balthica)
48-hr Renewal LC, 96-hr Renewal LC,
51.00.0mmgg//LL((AAQQUUIIRREE 33;;11997722))
EnBvoithroCnAmeSnntuamlAbsersseshsamveenat:limited amount of toxicity data available which shows moderate
tcooxmicpiltey.teSsientceofTrdiattoan Xo-n3t0h5isismaatemraijaolrincorodmerpiononrodeefrntthtoe CcoErrperloadteuctthse,ewfefewicltlosnf.etehde aCE
products to their formulation.
BOD, COD, algae, Daphnia, fish, and Microtox.
.
Le
p
~
a
-32-
001212