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foes R226 -- 359 SRPT T7001 MIN 315/022356 PERFLUOROOCTANESULFONYL FLUORIDE (POSF) T-Tebl> IN VITRO MAMMALIAN CHROMOSOME ABERRATION TEST IN HUMAN LYMPHOCYTES Sponsor 33MMCCeanrtpeorrt Toxicology SBiupilding T0250 UMsNa551333220 Page t0r3t ResearchLaboratory WHouomilnlgydRoenaLidfe Sciences Ld AHocnoinnbguiroyn PCeaamstradkgesire ENGLAND Reporsued 22 Osober 2002 001542 CONTENTS MIN3157022356 Page COMPLIANCEWITHGOODLABORATORY PRACTICESTANDARDS... 4 QUALITYASSURANCESTATEMENT. ccm eS RESPONSIBLE PERSONNEL... 6 INTRODUCTION sss 8 EXPERIMENTALPROCEDURE... HL ASSESOSFMREESUNLTTS ccc u-- ws 18 MAINTEONFARENCCOREDS... rs smm-- 15 CONCLUSION rss 2: 001543 sez `COMPLIANCEWITHGOODLABORATORYPRACTICE STANDARDS Ie ty dct se vs ceedi cmc ie lovin Ghoet Labor FE. ComisionDie PRoUf iEsh 590iorNo L770 OE RD pD ri ot Cou Ly Pre (ord 9) tone whsrl cic 5sof hint, epre t e pi Teg eobe es wo pny ofeS, ;i fBye ltTxS opnas.a VeF_oe So Toi Z2 other2m 2 ) 001544 QUALITY ASSURANCE STATEMENT "The following have been inspeorcautdietedd in relation tothis sudy MIN 3150022356 Study Phase Date of Inspection Date of Reporting Protocol Audit 11 January 2002 11 January 2002 StudyBased Inspection Culture reament 17 January 2002 17 January 2002 Process Based Inspections Formulation Cultre Estaiishment Harvesting and slide preparation Side scoring 59 preparation 14 January 2002 11 February 2002 7February2002 5 March 2002 15 January 2002 14 January 2002 11 February 2002 8February 2002 March 2002 15 January 2002 Report Audit 15 April 2002 15 April 2002 DPirroetcotcoorlaAnuddCito;mpAannyauMdiatnoafgtehmeepnraottoicnodlicfaotredthsibsosvt.udy was conducted and reporid 10 the Study SSttuuddyyDBiarsecetdorIansnpdecCtoimopn:anAynMinaspenctiaonogfaeaipmnhdiaecsaetneodftahbiosves.tudy was conducted and reported 10 the aPrnodcreespseBiaisveedprIoncsepdeucrtieosnes:mpAltoyoerdaobnoutitsheytpiemoefthsistusdtyudwyeweascairnepdroogurte.ssTihnesspeectwieornes coofnrdouucttiende indreported to appropriate Company Managemenats indicated above cRoenpdourcttAeuddnitd: rTehpiosrtreedpotrotthhaesbSetednyauDdiiterd baeynthdceCotQmuapolaintryyAMssauranncae Dgeapeasrmitndmeiecnna.tteTdhisbsoavued.it vas "Trehseulmtest0hordesf,lepc trheroawcdaeanaddobuserrvaetiosns were found obeaccurately descnrdtiherbepeortded ``AGnrgoeulpaMlearhingsn, ager, BSc. M.Sc.FRB, MRQA. Date DHuenptairnmgednotn oLfiQuaSlciiteyncAesssuLrida.nce, is 001545 RESPONSIBLE PERSONNEL Linda Alls, DEA Tox., DES Pharm. Vet. France, SDteupdayrtDmiernecttoofr,Genetic Toxicology. Lincoln Pritchard, B.Sc., S`DteupdayrStumpeenrtvoifsoGre,netic Toxicology. MIN 3150022356 6 001546 SUMMARY MIN 3157022356. A study was chromosomal apebrfeorrmerdaitnto hiausosmeansns ltyhempahboiclyittyesofcuPlteurrfelduoirnovoicturon.esulfony] Fluoride (POSF) to induce Hphuymtaohnacrmlaygmgplhuotciyntiens,,andinexwphoosleed tobltohoedesctulsuurbes,tanwceerbeothsiimnulthaetepdresteoncediavniddeabbseynceadodiftiSo9n mioxf nrdivoefdthreoimncaubavtieornsperSiovde, cnelpdivsisioin wacs oarenstcedlussingwCeolecesmidge,rtehedc,ellsTwhaorhverstsed afnod sslihdees prepsotahatrmeetapdha,secels cobeuexalminded for chromosomal damage. IInympohrodceyrtetso, atshseesmsitotthiec itonxdiecxitwyasofcaPlecrulfaltueodrofoocruanlelscuullftounryels tFrleuaotreiddewit(hPOtShF)testtosucbuslttaunrceed human and the Solvent control. On the basisofthese data, th following concentrations were selected for metaphase analysis: First test `With and without S9 m-i3hoxurs treatment, 17 hours recovery: 1.252,.5and 5% viv atmosphere. Second test `Without 59 m-i20hoxurs continuoustreatment: 08, |and 2% v/v atmosphere. `With$9mix 3hourstreatment, 17hours recovery:2,5and7.5% ivatmosphere. Isnatbiosttchatlhlyeasbisgneinfciceaantndipncrreesaesneceinofth$e9mpriopxo,rPteirofnluoofromoecttaanpehsauslefofniyglurFelsuocroindtea(inPiOngSFc)hcraoumsoesdomnaol. aberrataitoanys dose level, whencomparedwiththe solvent control, ineitherest. dAosquealnetvielt,atiNvoesauntailsytsiicsaflolrpsoilgynpilfiociadnytwinacsreamsaedseiinthceuplrtuorpeosrttireoanteodfwpiotlyhptlhoeindecgealtlisvweceornetrseonl.nd highest Aalblerrpaonstiicevlels,codnetmroolnsctormapotuitnnhdegssecnasuistievdityloarfgethesutteissttiscyasltleymasingnditfhiecaenftfiicnaccryeoasfetshein$9thmeixp.roportion of ofticslcaosntcolguendiecd tahcattivtihteyteisnttshuibsstianncveirPoerfclyutoorgoeoncettaincestuelsftonsyylstFelmu,oruinddee(rPOtSheF)exhpaesrsimheonwtnalnocoenvdiidteinocnes: described. a 001547 INTRODUCTION MIN 3157022356 itauetpohnodmesecsrbeshsteudry odensisgnend aonasymepthshocaybsilcolfuPeedfliuncioroec.tnesafony Fucide (POSF) Th sty was condiunccomptlieancdewith oe fllowing guidelines OMaEmCmDaliGauniCdeoimnosfoormetheAbTeersatiionng Tofs,ChGeumsidcealln.e 4(7139.97) Genetic Toxicology: In Viro ChUrSomEoPsAo(m1e9A96b)emHaeaglotnh TEefstf.ectEsPTAes7t12G-uiCd9el5i.ne2s2. OPPTS $10575 In Vitro Mammalian uo19mm75nnSileymtopdehoaons:. DTuhhnaifvsoertbsdeseacnhnidseKveeiddklbiaynadidsd1iy9np0ge0po.hfyTcshhaaysymafaeogrgchuiurnmiebnde(rPiHoAfs)yretoatrbhsue(cEdlvoaanorstaenGhdaitOdrReiernsdslasnin gh mice ich (owe 1960, 1oCbrsthaeins esmeteuddyi,aFnlo.loTldhoeianukeerafemoemwse.heeltiietnyuceimltalseledwnenrmhes.amopekriednsendatoonfmoePrtUaAwpahasbseepfooosrlibenedigantgnhdwedamitieedcdweiilthohhehst,eest vCi{oiealsmcte eoomsinodomfr .eestChhaht eerrcoamemolonysiy.oecmTeeehse<tiebimrneeafittonhcepsreemsammenotofayfpdamhapahmhseaeogscebctermelalasstyiinwobenewrhfleooelsteqthudbeuelnrcoioyendgxicassamluibunstheeeedqui feifnrpostrrt ocetlxhlliemddaiptvrsieesslioeyonncs1.ea3f-1eoI4rfn hours Tohnshteadprvessenpceerfaonrdmehdoenbtwioesnpaofr$e3cemciaxs.ionIs.nthTen hseecsontd etss,,acoemsinHoiuorusreessmeennvtatswiussesdeid hou mie,and he 0 wi5 hix vaaEps fhe rt st Aeobernmtecioxnecs shwearfodsmoormheedisqncuioracinnitgn oD1NoAhfe(ccHrleoalmslaiesfoacmnideonBshooefmadhieoynsS.C_19N70S,(o1S9ma8ey9,aEFprT,arkdBsihOo,WnEHlNlu,y1fgdaapesPabhtaeavnke t1e9n91caTiinesy te rol umber of els conning aberions both with and without gaps has Ma any suhtbhset.taasrnmcheosetedofoanunondtdpierxeecrstelnaacremeofaesag.SeupTphleeefrfmeeecfntotreudnhellcetlrhueyfeushtaoavenndb(tee5es9tnsmmuibexsa)tbaponrcleeipeawrdeerdbyfinrecounmbzayrtameteds aeonnolndeAnmeeds i19t8%h, Naatanracjaen t(lA.r1l9o76)1.359 Known 10 duce igh lve of nay civiy . 001548 MIN 3157022356. "T`ohne3p1roAtuogcuoslwt2a0s0a1papnrdobvyetdbeyStHuundtyiDnigrdoencLtiofenrS1c0ieJnacneusarMya2n0a0g2ement on 18 July2001,by the Sponsor `The study was conducted at Huntingdon Life Sciences Lid, Eye, Suffolk, [P23 7PX, England. Trehsepecetxipveerlyi.mental star and completion datesofthe study were 15 January 2002 and 15 March 2002, 9 001549 Identity: CAS No: Appearance: Storage conditions: Batch number Expiry: Purity: Date received: `TEST SUBSTANCE MIN 3150022356 Pefluorooctanesulfonyl Fluoride (POSF) 307357 Clear liquid Room temperature 040227 `Sponsor's responsibilty; assumed stable or the durationofthe study 955% 14 June 2001 or 001550 EXPERIMENTAL PROCEDURE MIN 315022356 CULTURE OF LYMPHOCYTES RHuEmMaIn1b6l4o0odsvuaes ccoulllteucrteedmseedpiiucmllsyupfprloemmehnetaeldhyw,intohn-1s0m%okfioncgalmlceafdosneorrusm,,po|oulendiavnd dHielpuatreidn,it2h0 LmedUiumpe0n.i1cimllinp?h20yoghiane]masggelpctioimnyonf taendcl2l0sumspMensgilountawmeirnee.plaAcleidqunotsste(l0e4unmilverbslaolodco:nt4ai5nemrls athnedcienlclubated a 37C for spproximatly 48 hours. The cultures were gently shaken daly oresuspend POSITIVE CONTROLS Inthe absence of$9 mix dSveppnioyr BApaptecahrnaunmcbe:er Sabvent: Final concentration: Inthe presenceof $9 mix MSuepnplii:er Appearance: SoBlavtechntnumber: Final concentration: MSiigtnoamCeheimniCcal CoLid B2lu0e p5o0wer Sterile purifidwater 0.2 pg/ml (3hourtreatment) 0.1 pg/ml (continuous treatment) CnyicalMoepdhiscpahLaniide Whicpowder OSeNr4l6e5pu(rTiefsited1)vaantder1H485(Test2) 10 pg/ml PREPARATION OF$9 FRACTION SoSpxaces MRaale SSouusrice: SCphraargeuseRDiavweireUyKderived pWeyigh: 7SoBwoepsks " 001551 MIN 3150022356 $li9vefrsacwteiroen swtaismuplrateepdarbeydAfrroocmloarg1r2o5u4,poafdmican.is1t0eraendiamsal.sinMgilexeindtafpuenrtiitoonneaolxiidnajsecetisoynstienmcsoimn itlheartaa daotssawgeeorefkSi0ll0edmga/nkdgthbiordyvweerigshtas.epOtincatlhleyfriefmthovdeady.after injection. following an overnight sarvation, the T0h1e5fMolKlCoIwi(n3smtiepKs Iwe:re1gcalrievedr)obuetfoare0be-4ingCtrunadnersafseeptrotieacdncohnodimtoigoenns.iseT.heFollivleorwsinwgerperepplaarcaetidoni,n hdiespheonmsoegdeinnaoteasliwqeuortescaenndtrsiofurgeeddaat 89000C0orfboerl1o0wmuinniulterse.quiTrehd.supernatant faction (59 fraction) was PREPARATION OF $9 MIX P59H7m.i4x1co0n0aimnMe)d,: g$l9cforsaect-i6opnh(o1sp0h%atvAe)(.5MmgMC),lN(8AmDMP).(4KmCbI.(33AmlM)th,e scoofdaicutmorosrwtheorpehofislpehra-tsetebruiflfsecrd befor us. TREATMENT OF CELLS WITHTEST SUBSTANCE - FIRST TEST Acufleturreapmperdoixuimma.teAltym4o8sphhoeurress,otfhPecruflltuuroersoowcearneescuelnftorniyflugFelduoarniddeth(ePcOeSlFls) wweerree reesstaubslpiesnhdeeddiinsefsrleesdh `2l0a,s4s0baontd7s0(%16v0ivmiatimnotsepmhaelrev.oAluimre)wawsiwtihtshedprtauwmnfcarposm0eagcihvbofirnaelacnodnctehnetnraatiaopnpsroofpr1i.a2t5e.v2o3l,u5m,e1o0f, Pheersfueopruomoscaapn.esAafftoernyevFaipoorraitdieon(oPfOPSeEf)lwuoarsoienccaondcuscuefdonuyilnFgluaosryirdien(gePOaSnPd)naenedde,quiilniebrraetdiotnhorfotuhgeh athtemnosipnhceurbeasteadt o3n7 thCe,itshiedelsymatph3o7cyCteicnualtruorlelserwaeprpeariantjuesct(esdeeinaopptehnedibxol3:e.AppTahraetgulsas{sorbovtalepsowuerrse paphparsoexiemxaptoelsyu.reTohfecullytmipvhatoecdytmeasmcmoaatlitahen icneslild)e,owfhthiechbororteastesantdhewebraeteismmoenrcseedevienrcyuletiugrhet mmienduituems `hoencreevvoelrutyiorne.volTuhtieonsoalnvdenetxpcoosnetdoldir(eActkl)y twoaPserefstuaobrloioscheadneisnufdounpyli!caFtleuocruildteur(ePsOSaFn)d fcoorntthaeinreedst aonf amnodspashoerceonoafinsiesd. aMniattommoyscpihnerCe,oaftaairfinal concentration of 02 gm, was added to duplicate culures cIumlmteurdeisaenldydibsecfaorrdeedt.reaTthmiesntwoafstrheeplsaecceodndwistehto1fmcuiltoufreSs9, m1ixm.lTohfemceudltiuurmeswwaesreretmhoevneadddferdom(0estchhe acopnptrrooplricsuelgelassswbeoruelecgsiivaiblnigsthheed suanmdeersarnsaomfofsipnbalerceoncoefntaria,tionCsycalsoapbhoovse,phTamhieddeupwlaicsataedsdoeldventto duplicate culturesa a final concentration of 10g/ml that were contained in an aimosphereofair. aTnhdereeshuosuprsenadefdeindofsriensgh,mtehedicuulmtuurnedsewrerane tcemntorisfupgehdoeaftariSe0r0in ufnoirve5rsmailnuctoens.tainTehrse.ceTlhlseyweweereritnhseend incubated for further 17 hours. in: 001552 MIN 3150022356 HARVESTING AND FIXATION T(Swiogmhao)urtso ebaecfhorcatlhluerecelaltsawefirnealhcaornvcesetnetdr,atmioinotfe0.ac1tivpigtym.wasAafrteerst2edhobuyrsaddiintcuiboantioofn,Coelaccehmciedll Swuesptentsreiaotnedwawsitthranhsyfpeorteodntiocascoelnuttriiofnu(g0e0tu7b5eManKCIcepnrteriwfaurgmededfoartS37miCn)u.teAs aft eSa01g00.miTnhueteceplerpieoldleotsf Hpyeplotsofnicxeidncbuybaatdidointioant o3f7rCe,htlhy psruesppaernesdiocnosldwfeirxeaticveea(i3iupagnesd matetSh0a0nogl :fo1 pSatmignluatcieasl aancedtitchecicde)l. "Thefixativews replaced urer times unlitbecame colourless. SLIDE PREPARATION "sTmhaellpevlolleutmweeorfe frreessuhspfiexnadteidve,.thAenfcoewntdiroupgseodfathe50c0egl. sfuosrpensmiionnustewseraenddrfionpaplelyd roenstuospperned<eedainncd3 pmriecpraorsecdopien bsulifdfeesrewdhiwcathewre(roeHt6h.e8n).alAlfotweerdri0nsiainrg-dirny.bufTehreedsliwdaetserwetrhe stihdeensswtaeirneedeifn t10s%rGriyemasnad. cfioemrplmeotuendted in DPX. The remaining cules in fative were stored at C until side analysis was MICROSCOPIC EXAMINATION "Tmhietporicepcaerllesd pselride1s0w0e0rceeelsxianmeiacnbhyelcuilgthutremwiascrrecoordusesdicnegoxacpelpotywfoprowpoesritoibvjeectciovnet.olThtereaptreodpocrutlituorneos.f SForlovmentthceosnetrroelsuvlatlsutehoerdoifsethelreveelwacsaunsoindgecaredaesce,retashemianxmiimtucimcacinhdieexvabolfeacpopnrcoexnitmraatteiloyn wSa0s%uosfdth8e5 hseelechtiegd.hest dose level for the metaphase analysis. The intermediate and ow dose levels were also "dTohseecdonucnleenstsratiporneloifamicnahrypsoesatniovfemceonttarpohlacseomfpigouurnesdisnedlieccatteeddfoan iannsaulfyfsiicsiewntsletvheelolfowbeesrtrcaonntcecnetsra.tion e"Txhaemsienleedctesdt salimdaesgnwiefriecatthieonn coofde1d.00M0etuaspihnagseanceGlills wimemrerisdieonntifoibejdecutsivien.g Olnowe phouwnedrreodbjemcettiavpehaasned: iSghouwriengwearehiegxhamlienveeld,ofwhsebreerraponstsicbellles,. froCmhreoamcohscoumleurea.berrTahtiisonsnuwmebreer swcaosrerdedauccceodrdiinngculturtehse nCldaosrseifdiucpaltiiocnatoefdthceelIsSCwNer(e19n8o5t).ed Ownhleyncseelnl.wiTht#eh4ve- n48icechrreoamdionsgosmoefsawlerbeearnralaytsemde.tPaoplhyapsleoifdigiunreds were recorded. "fTohreneignactiidveencceonotfroplocluylptluorieds amnetdacpuhlasueescetlrles,atoeudtwoifthS0t0hemheitgahpehsatdseosceellvs,ewlaofstdehfefresitnseudbsqtuaanncieautsievdeliyn theanalysis for chromosomal aberations. "vTahleuenuumsibnegsoFifshaebre'rsreasntt m(Feitsahpehra1s9e73c)l.l in each eatment grwaoscoumpapredwth hesolvent contol el 001553 MIN 315/022356 SECOND TEST tCruelattumreenstwwaerseusineidtiiantetdheanadbsmeanicnetoafinSe9d maisx.prIevnitohuselpyredseescnrcieboedf. S9Imnixth,isatsherceoenhdotuersttraeactomnetnitnuwoauss used,as inthefirsttest. Theharvesttime wasat20hoursforbothparts ofthetest. Concentratioonfs `Perluorooctanesulfonyl Fluoride (POSF) were as follows: WithoutS9mix: 0.1,02,04,06.08,1, 24nd 5% v/vatmosphere. With $9mix: 06,0a8nd.7.51%v/,vat2mos,phe5re. Duplicate cultures were used for each treatment and concentration of 0.1 ug/ml, and Cyclophosphamide, aa the solvent control. final concentration Mitomycin of 10 g/ml, C, at a final were added to duplicate cultures. Three hours resuspended after dosing, the cultures in fresh medium under containing S9 an atmosphere mix were of air in centrifuged. The cells universal containers. were They rinsed were and then incubated foar futher 17 hours. Cultures treated in the absence of S9 mix were incubatedfor20 hours. Al end cultures were treated with of the incubation period. Colcemid, They were at a then final concentrationof0.1 pg/ml, two hours harvested, fixed and the slides prepared as before the previously described. The slides were then examined microscopically as previously described. STABILITY, HOMOGENEITY AND FORMULATION ANALYSIS Tdehteersmtaibnieldityasapnadrthoofmotgheisnesitutdyy.ofAtnhaelytsesits soufbsatcahniceeveadncdonocfentthreatteisotnswuabsstnaontcpeeirnfothremesdolvaespnatrwtoerfetnhoits study. 1 001554 ASSESSMENT OF RESULTS MIN 3151022356 cAunrreanstsahyistisorciocanlsicdoenrtreodltroanbgee.acceptable if the negative and positive contol values le within the "The test substance is consideredtocause apositive response ifth following conditionsare met: cSthartiosmtoicsaollmyessig(neixfcilcuadnitnigngcraepass)erse(Po<b0s.e0r1v)eidntahteonfereoqrumeoncryeotfesmtectoanpcheantsreastiwoint.h aberrant "The increases exceed the negative control rangeofthis laboratory, taken at the 99% confidence limit `Theincreasesare reproducible between replicate cultures. "The increases are not associated with large changes in osmolality ofth treatment medium or extreme oricity. Evidence of a doserelationship is considered (0 support the conclusion. aAbonevgeactoinvceurrersepnotncsoentirsocllafriemqeudienfcnieosasraetoibstsiecravleyds,igantiafnicyadnotsienlcerveeals.es in the numberof aberrant cells A further evaluation may be carried out if the above criteria fora positive or a negalive response are not met. MAINTENANCE OF RECORDS All raw data, samples and specimens (if appropriate) arising from the performance of this study will remain the propertyofthe Sponsor. Taynpdeasrcohfisvainmgplmeaayndbespdeicsipmoesnedwhoifchaftaerre tuhnesuiptearbiloed,sbsyatreeadsoinn oHfunintsitnabgidloitny.LfiofrelSocnigentceersm Srettaenndtairodn Operating Procedures. aAlrlchoitvheerfosramappleersioadndofspfeicveimyeenasrsanfdroamll tahewddaatteaownilwlhbiechretthaeineSdtubdyy HDuinrteictnogrdosnigLnisfethSecifeinncaesreipnoritts r`eAftteenrtisounchotfimteh,ethmeatSeprioanlss.or wIifllrbeequceosntteadc,teHdunantdinhgidsoandvLiicfeesSociuenogcenshthtweilrletcuomn,tidniusepostaolroertfiunthtehre materials subject 0 reasonable fee being agreed with the Sponsor. oHfutnhteinfgidnoanreLpiofretSicinesncaerscwhiilvlerinedaeifnintitheelyQ.uality Assurance records relevant to this study and a copy 15: 001555 RESULTS MIN 3157022356 FIRSTTEST Toxicity data MarietosthiocwinndnicTesabolfec2u.ltured human lymphocytes trated with Perflucrooctanesulfonyl Fluoride (POSF) Iinndtehxetaob5s7e7nc%eofofthSe9somlivse,ntPecronftlruoolrovoacltuaeneastudlofsoneyllevFelluoorfi5de%(vPiOvSaFt)mocsapuhesreed.a Trehdeucdtoisoenlienvetlhsesmeilteocttiecd forthe metaphaseanalysiswere 1.25, 2.520d 5%vivatmosphere. iInndtehxetpor5es2e%ncoefotfhe$9somlviexn,tPceornftlruoolrovoacltuaenaetsudlofsoenyllevFelluoofri5d%e (vP/vOSaEum)ocspahuesreed.aTrhedeudctoisoenlienvetlhsesemliteocttiecd forthe metaphaseanalysiswere 1.25, 2. nd 5%vivatmosphere. `fTihgeureqsuawnhietnaicvoempaanraleydtsiosthfoerspoollvyepnltociodnytrsolh.owed no increase in the number of polyploid metaphase Metaphase analysis TlheyemffepctshaorfoesPcherofwylnuiotrnoToeacubaslnees3ualfnodnys]umFmlauroriisdeed. (POSF) in Table on 1 the chromosomes of cultured. human sInuabtiostthcatlhye asbigsneinfciceanatndintchreeapsreesinentcheeopfro$p9ormtiixo,n PoefrcfellulosrowoictuhnecshurlofmoonsylomFalluoarbiedrera(tPiOonSsF)atcaaunsyeddonseo level, when compared with the solvent control. sBiogtnhifipcoasnttiivnecrecaosnetrso(lP<c0o.m0p0o1u)nidnst,heMpirtoopomrytciionn oCf aabnedraCnytccleolplh.osTphhiasmdiedmeo,nsctaruasteedd tlhaergeeffiscaatcsytoifctalhley `59 mix and the sensitivityofthe est system. SECOND TEST Toxicity data MarietosthiocwinndiinceTsaobfl4ceultured human lymphocytes treated with Perfluorooctanesulfonyl Fluoride (POS) Iinndtehxetaob6s1e9n%coefotfhSe9somlivxe,ntPceorfnltuoolrovoacltuaeneastudlofsoenyl]evFelluoorfi2de%(vPiOvSaFt)mocsapuhseerde.a Trehdeucdtoisoenlienvetlhsesmeilteocttiecd forthe metaphase analysis were 0.,1 and 2% viv atmosphere. 16: 001556 MIN 315022356 Iinndtehxe tpore3s9en%coefothfe9somlivxe,ntPecronftlruooloovcatlaueneastudfoosneyleFvleuloroifd7e.(5P%OSviFv). cTahuseeddoasereldeuvcetlisosnelinectthed mfiotrotthiec metaphase analysis were 2,5 and 7.5% viv. "wThheenqucaonmipaatrievdetaontahlyssioslfvoernptocloynptlrooli.dy showed no increas inthe number of polyploid metaphase cells Metaphase analysis Tlhyempehffoecctystaeroefs PsehrofwlnvoirnooTcaanebsulalfneodnysl uFlmuomriader. ni(PTsOaSebFld)e 1on the chromosomes of cultured human Isnuabiostichatlhley asibgsneinfciceanatndintchreeapsresienntche oprfo9pormtiixo,n PoefrfcleulosrowoiclthanceshurlofmoonsylomFalluoarbiederr(atPiOoSnF)atcaanusyeddosneo. level, when compared with thesolvent control Bsiogtnhifipcoasnittiivnecrceoansterso(lP<c0o.m0p0o1u)nidst,heMpirtoopmoyrtciionnoCf aabnedrraCnytccleollpsh.osphamide, caused large, statistically CONCLUSION 1ofsclcaosntcolguedniecd tahcaivtihty tiensthsiusbstianncveirPoerfclyutoorgoeoncettaincestuelstfonsyy! Fsl.uoruinddee(rPOthSeF)exhpaesrismheonwtnanl ocoenvdiidteinocnes described. 7: 001557 REFERENCES MIN 3150022356 EVANS, HJ. and O'RIORDAN, M.L. (1975) Human peripheral blood chromosome aberrations in mutagen tests. Mutation Research, 31, 135 lymphocytes for theanalysis of FISHER, RA. (1973)TheExact Treatmentof HafnerPublishingCompany, New York. 2 x2 Table in: SarisicalMethods forResearch Workers. GBRAALDLLOEWYA,YM,OS.M(.198D7)EAESfYf, eoDfcAhti.gshBoEsAmNot,icCsLtr.engKthRoAnGcNhrAoKm,osAoRme.abAerRrMatSioTnRs,OsNisGte,r cMhJro.mataindd exchanges and DNA strandbreaks,and the elation to toxicity. Mutation Research, 189, 15. HEDDLE, JA. and BODYCOTDE.J,. (1970) On the formationofchromosomal aberrations. Mulation Research,, 117, ISCN (1985) An KLINGERH,. P. Intemational System for Human (Eds). S. Karger AG, Basel. Cytogenetic Nomenclature, HARNDEN, DG. and MMAutRaOtiNon,RDesMe.arcahn,d 1A1M3E, S17,3.B. N. (1983). RevisedmethodsfortheSalmonella mutagenicitytest NATARAJAN, AT., TATES, AD. van BUUL, PPW., MEUERS, M. and de VOGEL, N. (1976) `RCesyetaorgcehn,e3t7,e8ff3e.cts of mutagens/carcinogens after activation in a microsomal system in vitro. Mulation NOWELL, P.C. (1960) Phytohaemaggluinin: leukocytes. Cancer Research 20,462. an initiator of mitosis in cultures of normal human SATYA-PRAKASH, K.L., HSU,T.C. and PATHAK, morphology. Cytogeneticsand Cell Genetics, 30, 248. . (1981) Chromatd lesions and chromatid core. SCOTT, D., DEAN, B.. aberration assays in vitro inDAKNIFROKRDL,ANN.DDD..J,.a(nEdd)KIBaRsKiLc AMuNtDa,genDi.Jc.ity(1T9e9st0s): MUetKaEpMhaSseRecchorommmoesnodmee.d rPervoicseeddurpe.s6.2.RCeampboorfirdtghteeUUnKivEeMrsSitsyuPbr-escso,mmCiatmibreiodnge.guifdor emutlageniicintyteestsing. Report, Par|t 18 00155! 8 Testl Epxeproiosde (hous) 3 3s TABLE1 `SumomfRaesrulyts MIN3151022356 Pefs`oCroonocceunnteastuonlfoofnyl CeElxlcslwuitdhinabgegr3aptions | CelIlnsclwuidhinagbgearapisons | RMeiltaottiivce Fluoride (POSF) (Govivamosphere) | Iodividal | Mean | Individual Mean | Index wes ) | ies () @) oan 125 T1102 2 20 100 5 4 as |s os so 25 300 as [32 as n s s 1 30 |1 1 a0 02pm Mitomycin) [#18 26 200s *28 *28 2600 5 - ocin 125 2 2 20 |e4 4 a0 100 voso20 [1s 30 9 25 30s a0 [3 6 as 0 5 ora [12 as 2 10ngm)Cyelopposphamite)| 20 23 mows [m2 29 267eee Tea2 pEexrpoisoudre (hows) Perf`lCuoonrcoeonctuantcisoinfofony! CaElxscwhiutdhisnbgegraapisons| CellIsnwcihtihnsgbegraapisons | RMeiltaottiivce Fluoride (POSF) (5 viv mosphere) [ dvd" Vin] vIanlduievsid(u8al) M(e%)an In)dex oan 08 2 0 10 |2 0 10 o 2 10 |o 3 us 100 21 2 1 as [31 20 & o 0 00 [0 o 00 a OlugmMiomycinC)| 9 7 sowe| 9 7 some - own toro [22 20 10 2 ror 32 as 7 5 o 1 es 12 as 0 25 oo 1 07 [0 2 13 ES 10pm(Cyclopposphamide)| *18 +18 1sovee [20 *20 20wee - Otherwise 2P0<00010l 5500ccellllswweerreeaanaylyssed rroommttessccuurreesoeetoo sigh clevelseoafpsbharasisopnrseesteon de 19: 001559 MIN 3150022356 TABLE2 Mitotic indexdata - first test `Without S9 mix, 3 hours treatment and 17 hours recovery Concentration of Perluoroocunesulfonyl Fluoride (POSF) (% viv atmosphe 0 (ain Mioticindex# | Relaitnivdeexmi#totic Incidence __%Mean ) 1000 90 100 92/1000 Polypiowdy Incidence %Mean vs00 02 S00 125 511000 sa 51000 25 741000 [a n 551000 5s 4S571100000 si 51 2500 02 500 10 a 0 bb " bb Ek) b b #3 CVearlycufleswomnsehatvebaeeppnrehasedanetsosniengsdreounded values b Nocels.no meaphases presenonside 120: " 001560 MIN 3150022356 TABLE2 Mitotic index data - first test (continued) `With $9 mi, 3hourstreatmentand17hoursrecovery PerflCuoonrcoeoncmuanctsounlfoofnyl (5Flwuioriadmeo(sPpOhSePr) o "wn Mote index # | Reliivnedemxooie Incidence %Mean ome 99 100 1001000 Faiypondy Incidence %oMean s50o0o 02 125 1o1w371000 91 2 25 s93n10o00 79 s 2de0m1000000 si 2 0550000 00 0 a 2 b " bb 0 b B5b NVCeorcayefllwsonnhovmehcalev.bameeonrpmapaprhdehesaeissnieonsengsrriossudnedeodnisliees: T Nomensd a 001561 MNsis22356 TABL3E [I -------- Wau 59mi,hs esterand 17 hors covey reCPpoomemstornostsD |NT owe] FO omion |tTaobemedi_[Re--jlre rs cooee||eom | fo en w;n wwll Vo| lwee]: ww us wa|H x w0| s s ww|| Ces ae sls so] @ : s|e ass|: wm 2 l:s slr: ww oanroems || 00 | |B i|Bmol m=o - 32@ I CEwme m ooiBwRe Cometem SEeE r pR ies Snr onwo rFoooom 2 001562 MIN 3150022356 TABLES Metaphaseanalysisdata - rst est (continued) With$9mix, 3hourswean:ad 1 hours covery PeFrCrooonrcdeaean(ctOloSonDnly|c|xaNnoisnteld]|Coma [CRroomemsaoni?n (% viv atmosphere) @on wtyopee. | obopeoe ww| |: |Noolsen [RVieiinc] :2 20|e: wo mw 12s ww|| , 2s ww| |3s 3 s ww| [1 3L201s se] w ssals`a) mw Li owe 2 oas| = rye 0 (Cyclophosphamide) 100 7a] 1 24 0 zo|u ar| - 23 ee |29 e- @GGQS CCGmmErRtTeeteSG CGaoenmmmieecnmoomnde Th C CeE p teni s hea eds ones r00o1m 5: 001563 MIN 3150022356 TABLE4 Mitotic index data - second test `Without $9 mix, 20 hours continuous treatment PerfClounocroecncaunieosnufoofnyl Wioieindox # | Reliivnederxao Fl(uwoirvidseum(osPpOhSeFr)e) | Incidence __%Mean o nenoo 17 100 an 1071000 Palypody Incidence %oMean 50 0 0500 or v1131i000 109 5 02 n103e110o00 109 0 04 s571u10o00 94 0 06 s64n10o0w0 85 08 0n10o00 81 ' 80 11000 77 o 2 71e0n0o0 71 a a5s00 00 s 2w010i00 22 1 & Caclaions hveben made ingrondedvies 24: 001564 MIN 3157022356 TABLE4 Mitoticindex data- second test (continued) `Wit$h9mix, 3hours treatmeanntd 17hoursrecovery Per"fClouonrcoearciurnacusounloffony! Monitor | Reliivnedemxio Fluiovrideam(oPsOphSeFr)e) | tncidence 9% Mean ) o an eno 82 941000 10 Polygon Incidence &Mean 550000 01 06 7m41i00o0 82 100 0s 0 7911000 76 E ' s81e00o0 70 8 2 5a9710000 60 5 sS6m10o00 57 3 2s 0 39/1000 32 oonns 00 # Calusihavoebneesnmdewing rounded aes 25: 001565 Concemeatonal PeruFclruooorciudnee(sPaOlSfFo)ny! (%viv atmosphere) ioo MIN315022356 TABLES Metaanalyspisdaht -asecsondteest. `Without 9mix, 20hourscontinuous esment Remon| No orwenamas [Ree romana [Gromoson| Gare [Bc ew] Mdieoixc obtypec. olorypea og cs gps % * w0 | 1 2 10)2o 10] w os 100 w| 2 | w| 2 100 2 100 100 0 w0|o us| e 23 2 oas|a 20 a 1 1 0 oofo oof a o 01 ppm domyene) | w a0 | 3[6 23 To osollo soomf - @SD Obenie eCCmmmomwitmbrteekk rP2o00m1 cmew OOvrormsodeocumen GSGr CCrolvemaamnemmrseerrSneimnmseesr pbesed els 126: 001566 APPENDI2X MIN 315022356 Historical positive controWlidatteh(Jo$a9numuiatxry 199-9 December 2001) O xctinggaps,lower99% confidence i = 8.5%,mean= 17.12% {Ehcludinggaps,lower 99% confidence limit = 10.0%,mean = 19.95% LoEY a Sa i gE 5s BIRITEHA Eo s fll | iBl 0 13 Hl 5 10 15 2 25 W IB 0 & 0 5 60 6 Frequency of aberrant metaphases (%) Matorical positive controlWdiantsSJoamniuxary 1999- December 2001) Ecchigaps,owerS9%confidenceli = 7.0%,moan = 14.95% hold gas,ower99%confidence i 8.5%,moan = 18.40% PF so gia= Iis 5 0 5 10 1s m 25 % 3 0 45 0 5 Frequency of sberrant metaphases 2 001567 JR-- OAR SOR ReHeEE Culture bottle (volume 160ml) Cote apdr ams ------m--stcl O `Rotating bottle holder O 30 | Motorised rollers 001568 he oi opt St 1 or, *RTay & wm: HEav F-- E Eom-- ns covuusonsonsracrce ann EE STATEMENTOFCOMPLIANCE ere BEEpA rain sEEsppmaEacs, H. E Mutagenicity eR eerrereinecn T A Se um m Be Jt In RR . : : VU1569