Document jem58LoZxEY3NV9KEGDNZOEZ
DEPARTMENT OF THE AIR FORCE
AIR F O R C E C IV IL E N G IN EE R C E N T E R T Y N D A LL A IR F O R C E B A S E FLO R ID A
22 August 2016
MEMORANDUM FOR ALL AIR FORCE FIRE DEPARTMENTS AND FIREFIGHTERS
FROM: AFCEC/CXF 139 Barnes Drive, Suite 1 Tyndall AFB, FL 32403-5319
SUBJECT: Replacement and Disposal of Legacy Aqueous Film Forming Foam (AFFF)
Reference: SAF/IEE Memo, AFFF Disposal and Replacement - Crash Response Vehicles, dated 9 Mar 16
1. The Air Force is totally committed to protecting human health and the environment so we are taking aggressive steps to replace our legacy AFFF with a new environmentally responsible six carbon chain formula and incinerating our existing stockpile. In accordance with the SAF/IEE memo provided at Attachment 1, we were directed to secure required funding and take specific actions. This memo provides guidance on the replacement and disposal of the legacy AFFF in our Fire Emergency Services Flights and includes other key initiatives associated with AFFF testing and the future use of AFFF.
2. As the Air Force Fire Chief, I am asking all Air Force firefighters to support me and the Air Force by assuming a leadership position, lead by example and be part of the solution because we understand the importance of using AFFF to save lives and property to include protecting our own lives during fire fighting operations involving hydrocarbon fuels where we use AFFF. We work with AFFF on a day-to-day basis, we use it in our vehicles, handlines and turrets and during large scale fire incidents we rapidly resupply our fire vehicles with it. We have received the proper training, we know how to handle AFFF and we have the required Personal Protective Equipment necessary to perform the tasks explained in Attachment 2 so I am soliciting your total support. This is important to human health, the environment and equally important to us as fire service professionals because AFFF is an integral part of our toolbox. To assist you with this effort, we have attached a copy of the Phos-Chek 3% AFFF information sheet (Attachment 3) along with a copy of the Safety Data Sheet (Attachment 4).
3. AFCEC/CXF awarded a contract to bulk purchase and deliver new Qualified Product List M il Spec approved (Mil-F-24385) AFFF to all Air Force installations which includes all active duty, Air Force Reserve and Air National Guard fire departments including our deployed locations in the AOR. Specifically, we purchased 418,300 gallons of new six carbon chain AFFF that is Perfluorooctane sulfonic acid (PFOS) free and contains little or no Perfluorooctanoic acid (PFOA) from ICL Performance Products. The contract was awarded for $6.2M and we anticipate deliveries to begin on 22 August 2016. All total we are disposing of 619,626 gallons of old legacy AFFF and replacing our operational stockpiles with a new environmentally responsible formula by 15 December 2016 or sooner if possible.
US00006403
4. AFCEC/CZ is working with Defense Logistics Agency (DLA) - Disposition Services on the AFFF disposal contract. The first phase of the contract includes delivering empty storage totes to our fire stations that will be used to collect the legacy AFFF and the effluent associated with rinsing the foam tanks. When the contractor drops off the totes they will pick up the fire station stockpile (backup supply) of AFFF and take it to be incinerated. Firefighters will then remove the legacy AFFF and effluent from our vehicles and place it into the empty storage totes. Once this is complete, the second phase of the contract involves the contractor coming back to pick up any and all legacy foam and taking it to the approved disposal facility.
5. DLA awarded a $4.7M contract to W.S. Darley to modify our fire vehicles with specialized equipment that will allow us to conduct daily fire vehicle operational checks and required National Fire Protection Association Standard 412 and 414 annual foam tests without discharging AFFF into the environment. The contract includes purchasing 167 Eco-Logic AFFF test carts with required hoses, fittings and user's manuals. The kit also includes required fire vehicle modification parts, retrofitting 806 fire vehicles with required plumbing connections and providing two days of customer-focused training on how to safely and effectively use the new system.
6. It will take approximately 15 months to retrofit the 806 fire vehicles. We are exploring options to see if we can reduce the timeline associated with retrofitting our fire vehicles. The manufacturer is currently fabricating the Eco-Logic test carts and assorted fire vehicle retrofit kits. The first batch of test carts and retrofit kits will be available for delivery and installation starting in October 2016 as explained the attached step by step procedures.
7. Until further notice, we will continue to restrict the use of AFFF to real world emergencies only. We will also continue to treat any AFFF discharge as a HazMat spill that will be managed and cleaned up to minimize the threat and potential impact on human health and the environment.
8. The AFCEC/CO Fire Protection Engineers have also developed several courses of action to address the AFFF in our aircraft hangar fire suppression systems. Air Force leaders are currently evaluating those options to determine the best way forward.
9. I cannot overstate the importance of this initiative to the Air Force and entire Department of Defense. If you have questions on this important initiative, please contact my POC Mr. Kevin Matlock at DSN 523-6442 or by email at Kevin.Matlock. l@us.af.mil. Thanks for your support on this Air Force, Air Force firefighter and general public safety high visibility special interest item.
SofftWL /JAMES E. PODOLSKTR, GS-14, DAF
The Air Force Fire Chief
4 Attachments 1. SAF/IEE AFFF Disposal and Replacement - Crash Response Vehicles Memo 2. AFFF Step by Step Procedures 3. Phos-Chek 3% AFFF Information Sheet 4. Phos-Chek 3% Safety Data Sheet
US00006404
DEPARTMENT OF THE AIR FORCE
WASHINGTON, OC
OFFICE OF THE ASSISTANT SECRETARY
MEMORANDUM FOR A F C E C /C L
AFIMSC/CC
AF/A4 NGB/CF
ill 0 9 fill
FROM: SAF/IEE iObh A ir Force Pentagon Washington, DC 20330-1665
SUBJECT: AFFF Disposal and Replacement - Crash Response Vehicles
Pert!normated Chemicals (PFCs) are a class o f emerging contaminants that have become an environmental concern across the Air Force and DoD. The ll.S. Environmental Protection Agency (EPA) has issued drinking water Provisional Health Advisories for two PFCs: periluorooetanoic acid (P F O A ) and periluorooctane sulfonate (PFOS). PFOS and PPOA are associated with legacy C8-based formulations of Aqueous Film Forming Foam (AFFF) and are driving targe environmental investigation and response financial requirements. Replacing C8-based AFFF used in crash response vehicles is a lop Air Force priority to prevent and minimize future environmental liabilities. Effective immediately, I am directing A F C EC to work with AFIMSC to secure the funding necessary- to take the following actions:
Centrally purchase alternative, MILSPEC-approved C6-based AFFF to replace C8-based firefighting agent used in crash response vehicles
Drain, rinse and containerize C8-based AFFF and rinse effluent from crash response
vehicles
Utilize Defense Logistics Agency contracts to dispose of C8-based AFFF and rinse effluent
by incineration
Modify vehicles with a no-discharge foam testing system to ensure compliance with National Fire Protection Association standards.
These actions apply to the entire fleet o f Active Duty, Guard and Reserve vehicles. If you or a member o f your staff has any questions, please contact Daniel Rowalezyk, SAF/IEE, at (703) 697-1198 or
"MARK A. CORRELL, P.E, Deputy Assistant Secretary' o f the Air Force (Environment, Safety, and Infrastructure)
Attachment 1
US00006405
Air Force Aqueous Film Forming Foam (AFFF) Initiative Step by Step Procedures
Note: It is vitally important that all Air Force FES Flights execute the specific actions required below with absolutely no exceptions or deviations. Thank you so much for your support.
1. To make sure all Air Force firefighters are on the same page o f the playbook we ask that you conduct documented training classes for all shifts concerning this initiative. During the class we want you to read them the cover memo, the SAF/IEE memo, these step by step procedures and go over the AFFF information sheet and associated Phos-Check Safety Data Sheet. Additionally, please include your base specific plans for how you plan to take your vehicles out of service to complete the tasks required below to minimize degrading your local emergency response capability.
2. Take delivery of the new G, AFFF. For planning and information purposes, the new AFFF is being prepared for delivery to our long lead time locations such as PACAF, USAFE and some AFSPC locations. After the initial shipments, the AFFF will be shipped to those locations where the Air Force is currently providing mitigation actions but we expect the foam to be delivered to all Air Force locations in 10 weeks or less.
3. Verify the quantity received then send an email message to Mr. Kevin Matlock at Kevin,Matlock. 1@us.af.mil confirming that you received your new AFFF along with the amount you received. Anytime you are asked to send Mr. Matlock an email message during this process please send a courtesy copy of your email message to your respective Detachment FES representative so they are kept in the loop on this vitally important Air Force level initiative.
4. Store the AFFF in the fire station until you have sufficient empty totes delivered to you as part of the AFCEC/CZ disposal contract to collect the existing legacy AFFF and waste water effluent which will be explained in detail below.
5. Prepare your existing AFFF backup supply of 5 gallon pails and 55 gallon drums to be taken away for incineration. The incineration disposal method is the most environmentally safe way to eliminate future health and environmental risks associated with AFFF. The legacy backup supply AFFF will be taken away when the contractor drops off your empty totes. Do not retain any of the legacy AFFF. It all must be turned in for disposal even if for some reason your new AFFF has not arrived yet.
6. Once you receive your new AFFF and the required empty totes conduct the following actions in 30 calendar days or less:
a. Using appropriate Personal Protective Equipment and in accordance with the applicable Fire Vehicle Technical Order or Manufacturers Technical Manual drain the existing AFFF from all fire vehicles, foam trailers and foam tanks and place it into the empty storage totes that were provided to you and mark them "AFFF for Disposal."
Attachment 2 - AFFF Step by Step Procedures
US00006406
b. Fill the fire vehicle AFFF tank completely with water and drive the vehicle for 5 minutes taking various right and left turns and starting and stopping so that you can effectively free up the residual foam contained in the foam tank and associated piping. This step is essential because the AFFF in many of our vehicles has been in these vehicles for 10 to 15 years. Once you have driven the vehicle the required 5 minutes let the agent in the foam tank settle for a few minutes then drain the water and residual foam (effluent) in the foam tank into an empty storage tote and mark it "AFFF Rinse Water for Disposal." This process is required to be completed a minimum of three times. Note: Foam trailers and foam storage tanks are not considered vehicles, therefore the AFFF stored in the trailers/tanks are not required to follow the three rinse procedure described above.
c. Once you have completed the required steps above, fill the fire vehicle foam tanks with the new Ce AFFF. A copy of the Phos-Chek 3% AFFF information sheet is provided at Attachment 3 along with a copy of the Safety Data Sheet provided at Attachment 4.
d. Ensure that all of the storage totes marked for disposal are located in one location inside or outside the fire station organized and ready for pickup and transport to the disposal facility.
e. Send Mr. Matlock an email message confirming that the new Cr, AFFF has been loaded into your fire vehicles and that the remaining AFFF has been placed in storage as part of your fire department resupply capability. Based on the quantities you provided to us during our data calls we have ordered enough AFFF for you to completely fill each fire vehicle foam tank and have one complete resupply for backup purposes.
7. Take delivery and store the new Eco-Logic unit and then send an email message to Mr. Matlock confirming that you received your new Eco-Logic unit.
8. The next step in the process involves a contractor and/or Air Force fire vehicle mechanics retrofitting our ARFF fire vehicles with various fittings and connections that will allow you to use the Eco-Logic system to conduct operational and annual fire vehicle foam system tests without discharging foam into the environment. The contractor will start off with the bases listed below so they can get the vehicle retrofit process down pat on each of the configuration types we have available in the Air Force before venturing out across the Air Force and publishing a vehicle retrofit service bulletin that our mechanics can follow to assist us with this part of the process. The vehicles they will retrofit in priority order are: Tyndall, Eglin, Hurlburt, Gulfport ANGB, Joint Base Charleston, Jacksonville ANGB and Robins AFB.
9. Once the ARFF vehicles have been retrofitted two days of customer focused training will be provided to your firefighters on how to use the new Eco-Logic system.
10. Send Mr. Matlock an email message confirming that all of your ARFF vehicles have been retrofitted and that the required Eco-Logic training is complete.
Thanks for your support - We appreciate your willingness to work with us on this.
US00006407
PHOS-CHeK
FIRE RETARDANT | FOAM | G EL
Phos-Chek 3% AFFF
3% AFFF CLASS B FOAM CONCENTRATE
1. DESCRIPTION. Phos-Chek 3% Aqueous Film Forming Foam (AFFF) concentrate is a mixture of water, hydrocarbon surfactants, solvents, and C6 fluorosurfactants. This C6 based AFFF is an environmentally responsible, next generation Aqueous Film Forming Foam (AFFF) product for use on Class B hydrocarbon fuels that have low water solubility. This new formulation demonstrates I d Performance Products' commitment to superior firefighting performance and environmental responsibility.
The pure C6 Phos-Chek 3% AFFF is designed for rapid control and knockdown by producing a thin aqueous film that minimizes vapor release, a foam blanket that separates the fuel from the air, and continual draining of water from the foam blanket provides cooling to the fuel surface.
2. APPLICATIONS. Phos-Chek 3% AFFF may be used with low expansion foam equipment (nozzles, monitors, foam chambers, etc.), non-aspirating devices (water spray nozzles and standard sprinklers) and medium expansion foam devices to fight fires involving Class B hydrocarbon fuel fires such as crude oil, aviation fuels, diesel, etc. It is not suitable for use on polar solvents
or water miscible fuels such as alcohols, ketones, esters, and ethers.
TYPICAL PHYSICAL PROPERTIES (Concentrate)
Specific gravity @ 68 F (20 C)
1.02
PH 8.0 + 0.5
Viscosity
2-10 cps
Lowest temperature for use
23"T
Freezing point
23" F
TYPICAL PROPERTIES (Solution)
Dilution rate Surface tension at @ 68" F (20" C) Interfacial tension with cyclohexane at @ 68" F (20" C) 25% Drain Time (minutes)
| 3% : i>.r. - 0 . 5 ' . r - ... ;0
3. APPROVAL CERTIFICATIONS. UL162 and EN 1568-3 (Class IB) listed
4. STORAGE AND HANDLING. The concentrate should be stored at temperatures between 23F (-5C) and 122F (+50C), preferably in the original containers, approved bladder tanks, stainless steel, high density polyethylene, fiberglass or epoxy lined tanks. Concentrate piping acceptable materials of construction include stainless steel (either 304 or 316), some plastic piping including fiberglass and PVC, red brass, and black iron as long as the system is completely flooded eliminating the air/foam concentrate/carbon steel interface. Avoid permanent contact with carbon steel, iron, some copper alloys, & aluminum when the piping material and concentrate will be exposed to air. Galvanized piping is not recommended for AFFF piping systems.
Foam concentrates are subject to evaporation, which accelerates when the product is exposed to air. Storage tanks should be sealed and fitted with a pressure vacuum vent to prevent free exchange of air.
5. SHELF LIFE, INSPECTION AND TESTING. The shelf life of any foam concentrate is maximized by proper storage conditions and
maintenance. Factors affecting shelf life are wide temperature changes, extreme high or low temperatures, evaporation,
dilution, and contamination by foreign materials. Properly stored Phos-Chek AFFF Class B foam concentrates should have no
significant loss of firefighting performance for 20+ years.
However, the National Fire Protection Association (NFPA)
----
-- t.
recommends annual testing of all firefighting foams.
6. PACKAGING.
ORDERING INFORMATION (LBS./kg.)
LBS.
5 gallon pails (19 liters)
42.5
55 gallon drums (208 liters)
467.9
265 gallon reusable tote tank (984 liters)
2254.3
kg-
19.3 212.7 1024.7
ICL Where needs take us
Attachment 3
US00006408
PHOS-CHeK
FIRE RETARDANT | FOAM | G EL
Phos-Chek 3% AFFF
3% AFFF CLASS B FOAM CONCENTRATE
HANDLING PRECAUTIONS.
FOR DETAILED SAFETY INFORMATION, please refer to the MSDS.
Precautionary Measure and First Aid: Handle In accordance with good industrial hygiene and safety practices. These practices include avoiding unnecessary contact and removal of the material from the eyes, skin and clothing.
Eye Protection: As a good industrial practice, the use of chemical goggles is recommended. If in the eyes, flush immediately with water. Eye flushing equipment should also be available.
Skin Protection: Wear protective gloves when handling concentrate to minimize skin contact. Wash hands and contaminated skin after handling.
Respiratory Protection: None required.
For complete MSDS, visit www.phoschek.com
For more information, contact any of our worldwide ICL Fire Safety offices or visit us at www.phos-chek.com
United States ICL Performance Products 10667 Jersey Blvd. Rancho Cucamonga, CA 91730
Tel: (800) 682-3626 (909) 983-0772
24 Hrs: (909) 946-7371 Fax: (909) 984-4770
Canada ICL Performance Products Canada LTD 3060 Airport Road Kamloops, BC Canada, V2B 7X2 Tel: (800) 665-2535
(250) 544-3530 Fax: (250) 554-7788
Europe Auxqulmia S.A.U. Poligono Industrial de Balna, Parc, 23 33682 Baina-Mleres Asturias - Spain Tel: +34 985 242945 Fax: +34 985 253809
NOTICE: Although the information and recom m endations set forth herein (hereinafter "information") are presented in good faith and believed to be correct a s o f the date hereof, ICL m akes no representations or warranties a s to the com pleteness or accuracy thereof. Information is supplied on the condition that the p erson s receiving sa m e will make their own determination a s to its suitability for their purp o se s prior to use. In no event will ICL be responsible for d am a ge s of any nature w hatsoever resulting from the use o f or reliance upon information or the product to which the information refers. N othing contained herein is to be construed a s a recommendation to use any product, process, equipm ent or formulation in conflict with any patent, and ICL m akes no representation or warranty, express or implied, that the use thereof will not infringe any patent. NO REPRESENTATIONS OR WARRANTIES, EITHER EXP RE SSE D OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF AN Y OTHER NATURE ARE M A D E HEREU NDER WITH RESPECTTO INFORMATION OR THE PRODUCT TO W HICH INFORMATION REFERS.
2015 ICL Performance Products. All rights reserved.
04-2015-1
/A% \CL Where needs take us
rformance
du s
www.phoschek.com
Responsible Care*
Good Chemistry at Work
US00006409
ICL Performance Products LP
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC
Phos-Chek 3% AFFF MilSpec - [AQUAFILM AF-3MS]
1.1 Product identifier:
Phos-Chek 3% AFFF MilSpec - [AQUAFILM AF-3MS]
1.2 Relevant identified uses of the substance or mixture and uses advised against:
Relevant uses: Fire-extinguishing. For professional use only.
Uses advised against: All uses not specified in this section or in section 7.3
1.3 Details of the supplier of the safety data sheet: 1.4 Emergency telephone number:
AUXQUIMIA, S.A.U. Polgono Industrial de Baia, parcela 23 33682 Baia (Mieres) - Asturias - Spain Phone.: +34 985 242 945 / +34 985 242 946 Fax: +34 985 253 809 auxquimia@icl-group.com www.auxquimia.com
+34 985 242 945 / +34 985 242 946
2.1 Classification of the substance or mixture: NFPA 704: Health Hazards: 3 Flammability Hazards: 0 Instability Hazards: 0 Special Hazards: Non-applicable Directive 67/548/EC and Directive 1999/45/EC: This product was classified in accordance with Directive 67/548/EC and Directive 1999/45/EC, adapting the requirements to Regulation (EC) n1907/2006 (REACH regulation). Xi: R36 - Irritating to eyes
2.2 Label elements: NFPA 704:
#
Directive 67/548/EC and Directive 1999/45/EC: In accordance with the legislation, the elements on the label are as follows:
Xi
Si Irritant
R Phrases: R36: Irritating to eyes S Phrases: S25: Avoid contact with eyes Supplementary information: Non-applicable 2.3 Other hazards: Non-applicable
Chemical description: Aqueous solution of tensoactives Components: In accordance with Annex II of Regulation (EC) n1907/2006 (point 3), the product contains:
Date of compilation: 09/03/2015
- CONTINUED ON NEXT PAGE Version: 1
Page 1/12
Attachment 4
US00006410
ICL Performance Products LP
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC
Phos-Chek 3% AFFF MilSpec - [AQUAFILM AF-3MS]
SECTION 3: COMPOSITTON/INFORMATION ON INGREDIENTS (continue)
: Identification
: Ch e mica! name/Ciassificatio n :
Concentration
C A S : 112-34-5
2-(2-butoxietoxi)etanol
E C : 203-961-6 Index: 603-096-00-8
Directive 67/548/EC Xi: R36
R E A C H : 0 T 2 1 1 9 4 7 5 1 0 4 -4 4 -X X ) : Regulation 1272/2008 Eye Irrit. 2: H319 - Warning
ATP CLPOO
M 15 - <20 %
!
CAS: Non-applicable EC: Non-applicable Index: Non-applicable REACH: Non-applicable
Mixture of fluorosurfactants
Not classified
1 - <3 %
CAS: Non-applicable EC: Non-applicable Index: Non-applicable REACH: Non-applicable
Non-ionic hydrocarbon surfactant 6607700000 Directive 67/548/EC Xi: R41 Regulation 12/2/2008 Eye Dam. 1: H318 - Danger
Self-classified
m 1 - <3 %
CAS: Non-applicable EC: Non-applicable Index: Non-applicable REACH: Non-applicable
Anionic hydrocarbon surfactant 6201310000
Self-classified
Directive 67/548/EC
., J
Xi: R38, R41; Xn: R22
Acute Tox. 4: H302; Aquatic Chronic 3: H412; Eye Dam. 1: H318; Skin Irrit. 2: H315. Danger
w!. .!< .
1 - <3 %
CAS: Non-applicable EC: Non-applicable Index: Non-applicable REACH: Non-applicable
Anionic hydrocarbon surfactant 6608700000 Directive 67/548/EC Xi: R38, R41 Regulation 1272/2008 Eye Dam. 1: H318; Skin Irrit. 2: H315 - Danger
Self-classified
m
,X>;.
1 - <3 %
CAS: Non-applicable EC: Non-applicable Index: Non-applicable REACH: Non-applicable
Amphoteric hydrocarbon surfactant 6608110000 Directive 67/548/EC Xi: R36, R43 Regulation 1272/2008 Eye Irrit. 2: H319; Skin Sens. 1: H317 - Warning
Self-classified
m 0,1- <1%
CAS: Non-applicable EC: Non-applicable Index: Non-applicable REACH: Non-applicable
Anionic hydrocarbon surfactant 6200710000 Directive 67/548/EC Xi: R36/38 Regulation 1272/2008 Eye Irrit. 2: H319; Skin Irrit. 2: H315 - Warning
Self-classified
m 0,1- <1%
!
CAS: 29385-43-1
Tolyltriazole
EC: 249-596-6 Index: Non-applicable
Directive 67/548/EC
REACH: 0 1 -2 1 1 9 9 7 9 0 8 1 -3 5 -X X ) : Regulation 1272/2008
N: R51/53; Xn: R22 Acute Tox. 4: H302; Aquatic Chronic 2: H411 - Warning
Self-classified
13111 0,1- <1%
CAS: 67-56-1
Methanol
EC: 200-659-6 Index: 603-001-00-X
Directive 67/548/EC
REACH :0 1 -2 1 1 9 4 3 3 3 0 7 ^ 4 -X X ) : Regulation 1272/2008
F: R11;T: R23/24/25, R39/23/24/25 Acute Tox. 3: H301+H311+H331; Flam. Liq. 2: H225; STOTSE 1: H370 - Danger
ATP CLPOO #> 4 T T k
<0,1 %
CAS: 111-77-3
2-(2-niethoxyethoxy)ethanol
EC: 203-906-6 Index: 603-107-00-6
Directive 67/548/EC Repr. Cat 3: R63
REACH: 01-211 9 4 7 5 1 0 0 -5 2 -XX) : Regulation 1272/2008 Repr. 2: H361d - Warning
To obtain more information on the risk of the substances consult sections 8, 11, 12 and 16.
ATP CLPOO
m <0,1 % &
4.1 Description of first aid measures:
The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct exposure to the chemical product or persistent discomfort, showing the MSDS of this product. By inhalation:
This product is not classified as dangerous through inhalation,however, it is recommended in case of intoxication symptoms to remove the person affected from the area of exposure, provide clean air and keep at rest. Request medical attention if symptoms persist. By skin contact:
This product is not classified as dangerous when in contact with the skin. However, in case of skin contact it is recommended to remove contaminated clothes and shoes, rinse the skin or shower the person affected if necessary thoroughly with cold water and neutral soap. In case of serious reaction consult a doctor. By eye contact:
Rinse eyes thoroughly with luke warm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the MSDS of the product. By consumption:
Do not induce vomiting, but if it does happen keep the head up to avoid inhalation. Keep the person affected at rest. Rinse out the mouth and throat, as they may have been affected during ingestion. 4.2 Most important symptoms and effects, both acute and delayed:
Date of compilation: 09/03/2015
- CONTINUED ON NEXT PAGE Version: 1
Page 2/12
US00006411
ICL Performance Products LP
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC
Phos-Chek 3% AFFF MilSpec - [AQUAFILM AF-3MS]
Acute and delayed effects are indicated in sections 2 and 11. 4.3 Indication of any immediate medical attention and special treatment needed:
Non-applicable
5.1 Extinguishing media:
Product is non-flammable under normal conditions of storage, manipulation and use, containing flammable substances. In the case of inflammation as a result of improper manipulation, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the Regulation on fire protection systems. IT IS NOT RECOMMENDED to use tap water as an extinguishing agent. 5.2 Special hazards arising from the substance or mixture:
As a result of combustion or thermal decomposition reactive subproducts are created that can become highly toxic and, consequently, can present a serious health risk. 5.3 Advice for firefighters:
Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment. Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance with Directive 89/654/EC. Additional provisions:
Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other emergencies. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible to inflamation, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an aqueous medium.
aTiDENTAL RELEASE M
6.1 Personal precautions, protective equipment and emergency procedures:
Isolate leaks provided that there is no additional risk for the people performing this task. Evacuate the area and keep out those without protection. Personal protection equipment must be used against potential contact with the spilt product (See section 8). Above all prevent the formation of any vapour-air flammable mixtures, through either ventilation or the use of an inertizing agent. Destroy any source of ignition. Eliminate electrostatic charges by interconnecting all the conductive surfaces on which static electricity could form, and also ensuring that all surfaces are connected to the ground. 6.2 Environmental precautions:
Avoid spillage into an aqueous medium as it contains substances potentially dangerous for this. Contain the product absorbed in hermetically sealed containers. In the case of serious spillage into an aqueous medium notify the relevant authority. 6.3 Methods and material for containment and cleaning up:
It is recommended:
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible absorbents. For any concern related to disposal consult section 13. 6.4 Reference to other sections:
See sections 8 and 13.
SECTION 7
NG AND STORAGE
7.1 Precautions for safe handling:
A. - Precautions for safe manipulation
Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and cleanliness where dangerous products are used. B. - Technical recommendations for the prevention of fires and explosions
Avoid the evaporation of the product as it contains flammable substances, which could form flammable vapour/air mixtures in the presence of sources of ignition. Control sources of ignition (mobile phones, sparks,...) and transfer at slow speeds to avoid the creation of electrostatic charges. Avoid projections and pulverizations. Consult section 10 for conditions and materials that should be avoided.
Date of compilation: 09/03/2015
- CONTINUED ON NEXT PAGE Version: 1
Page 3/12
US00006412
ICL Performance Products LP
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC
Phos-Chek 3% AFFF MilSpec - [AQUAFILM AF-3MS]
C. - Technical recommendations to prevent ergonomic and toxicological risks
Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
D. - Technical recommendations to prevent environmental risks
It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3)
7.2 Conditions for safe storage, including any incompatibilities:
A. - Technical measures for storage
Minimum Temp.:
0 C
Maximun Temp.:
50 C
B. - General conditions for storage
Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5
7.3 Specific end use(s):
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product.
8.1
Control parameters: Substances whose occupational exposure limits have to be monitored in the work environment
: Methanol CAS: 67-56-1 EC: 200-659-6
DNEL (Workers):
Identification
TLVTWA TLV-STEL Year
Environmental limits 200 ppm 250 ppm 2014
Short exposure
Long exposure ;
i Identification
2-(2-butoxietoxi)etanoi CAS: 112-34-5 EC: 203-961-6
Non-ionic hydrocarbon surfactant 6607700000 CAS: Non-applicable ;EC: Non-applicable Anionic hydrocarbon surfactant 6201310000 CAS: Non-appiicabie EC: Non-applicable Anionic hydrocarbon surfactant 6608700000 CAS: Non-applicable EC: Non-applicable Tolyltriazole CAS: 29385-43-1 :EC: 249-596-6 Methanol ;CAS: 67-56-1 ;EC: 200-659-6 2-(2-methoxyethoxy)ethanol CAS: 111-77-3 EC: 203-906-6
DNEL (Population):
:
Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation
Systemic Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable 40 mg/kg 260 mg/m3 Non-applicable Non-applicable Non-applicable
! Local Non-applicable Non-applicable 101,2 mg/m3 Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable 260 mg/m3 Non-applicable Non-applicable Non-applicable
S yste m ic Non-applicable 20 mg/kg 67,5 mg/m3 Non-applicable 595000 mg/kg 420 mg/m3 Non-applicable 4060 mg/kg 285 mg/m3 Non-applicable 4060 mg/kg 285 mg/m3 Non-applicable 0,5 mg/kg 8,8 mg/m3 Non-applicable 40 mg/kg 260 mg/m3 Non-applicable 0,53 mg/kg 50,1 mg/m3
Local Non-applicable Non-applicable 67,5 mg/m3 Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable 260 mg/m3 Non-applicable Non-applicable Non-applicable
Date of compilation: 09/03/2015
- CONTINUED ON NEXT PAGE Version: 1
Page 4/12 US00006413
ICL Performance Products LP
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC
Phos-Chek 3% AFFF MilSpec - [AQUAFILM AF-3MS]
:
Identification
:
2-(2-butoxietoxi)etanol CAS: 112-34-5 EC: 203-961-6
Non-ionic hydrocarbon surfactant 6607700000 CAS: Non-applicable EC: Non-applicable
Anionic hydrocarbon surfactant 6201310000 CAS: Non-applicable EC: Non-applicable
Anionic hydrocarbon surfactant 6608700000 CAS: Non-applicable EC: Non-applicable
Tolyltriazole CAS: 29385-43-1 EC: 249-596-6
Methanol CAS: 67-56-1 EC: 200-659-6
2-(2-methoxyethoxy)ethanol CAS: 111-77-3 EC: 203-906-6
PNEC:
:
Identification
:
2-(2-butoxietoxi)etanol CAS: 112-34-5 EC: 203-961-6
Non-ionic hydrocarbon surfactant 6607700000 CAS: Non-appiicabie EC: Non-applicable
Anionic hydrocarbon surfactant 6201310000 CAS: Non-appiicabie EC: Non-applicable
Anionic hydrocarbon surfactant 6608700000 CAS: Non-applicable EC: Non-applicable
Tolyltriazole :CAS: 29385-43-1 :EC: 249-596-6
Methanol CAS: 67-56-1 EC: 200-659-6
2-(2-methoxyethoxy)ethanol CAS: 111-77-3 EC: 203-906-6
8.2 Exposure controls:
Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation Oral Dermal Inhalation
Short exposure
Systemic
Local
Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable 0,25 mg/kg Non-applicable Non-applicable 8 mg/kg 8 mg/kg 50 mg/m3 Non-applicable Non-applicable Non-applicable
Non-applicable Non-applicable 50,6 m g/m 3 Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable 50 m g/m 3 Non-applicable Non-applicable Non-applicable
Long exposure
Systemic
Local
1,25 mg/kg 10 mg/kg 34 mg/m3 35,7 mg/kg 357000 mg/kg 124 mg/m 3 24 mg/kg 2440 mg/kg 85 mg/m3 24 mg/kg 2440 mg/kg 85 mg/m3 0,25 mg/kg 0,25 mg/kg 4,4 mg/m3 8 mg/kg 8 mg/kg 50 m g/m 3 1,5 mg/kg 0,27 mg/kg 25 mg/m3
Non-applicable Non-applicable 34 mg/m3 Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable 50 mg/m3 Non-applicable Non-applicable Non-applicable
STP Soil Interm itten t Oral STP Soil Interm itten t Oral STP Soil Interm itten t Oral STP Soil Interm itten t Oral Sj p
Soil Interm itten t Oral STP Soil Interm itten t Oral STP Soil Interm itten t Oral
200 mg/L 0,4 mg/kg 3,9 mg/L 56 g/kg 560 mg/L 0,654 mg/kg 0,27 mg/L 111,11 g/kg 1,35 mg/L 0,2445 mg/kg 0,086 mg/L Non-applicable 1,35 mg/L 0,22 mg/kg Non-applicable Non-applicable 39,4 mg/L 0,0024 mg/kg 0,086 mg/L Non-applicable 100 mg/L 23,5 mg/kg 1540 mg/L Non-applicable 10000 mg/L 2,44 mg/kg 12 mg/L 90 g/kg
Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) Fresh water Marine water Sediment (Fresh water) Sediment (Marine water) Fresh water Marine water Sediment (Fresh water) Sediment (Marine water)
1 mg/L 0,1 mg/L 4 mg/kg 0,4 mg/kg 0,176 mg/L 0,0176 mg/L 1,516 mg/kg 0,152 mg/kg 0,095 mg/L 0,0095 mg/L 1,5 mg/kg 0,15 mg/kg 0,1357 mg/L 0,01357 mg/L 1,5 mg/kg 0,15 mg/kg 0,008 mg/L 0,008 mg/L 0,0025 mg/kg 0,0025 mg/kg 154 mg/L 15,4 mg/L 570,4 mg/kg Non-applicable 12 mg/L 1,2 mg/L 44,4 mg/kg 0,44 mg/kg
Date of compilation: 09/03/2015
- CONTINUED ON NEXT PAGE V ersio n:!
Page 5/12
US00006414
ICL Performance Products LP
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC
Phos-Chek 3% AFFF MilSpec - [AQUAFILM AF-3MS]
A. - General security and hygiene measures in the work place
If product is used at the concentration dosing conditions specified in the relevant instructions for use (section 15), personal protective equipment described in section 8.2 for UNDILUTED products will not be required.
Safe handling recommendations for undiluted product: As a preventative measure it is recommended to use basic Personal Protection Equipment, with the corresponding ""CE marking"" in accordance with Directive 89/686/EC. For more information on Personal Protection Equipment (storage, use, cleaning, maintenance, class of protection,...) consult the information leaflet provided by the manufacturer. For more infomation see subsection 7.1. All information contained herein is a recommendation which needs some specification from the labour risk prevention services as it is not known whether the company has additional measures at its disposal. B. - Respiratory protection
The use of protection equipment will be necessary if a mist forms or if the professional exposure limits are exceeded.
C. - Specific protection for the hands
Pictogram
PPE ;
Labelling
CEN Standard ;
Remarks
:
Chemical protective gloves
Mandatory hand protection
D.- Ocular and facial protection
Pictogram
PPE :
t, _ .............
Labelling
Mandatory face protection
E.- Bodily protection
Panoramic glasses against liquid splash
Pictogram
PPE :
Labelling
EN 374-1:2003 EN 374-3:2003/AC:2006 EN 420:2003+A l: 2009
Replace the gloves at any sign of deterioration.
CEN Standard :
EN 166:2001 EN 172:1994/A1:200Q EN 172:1994/A2:2001
EN ISO 4007:2012
Remarks
Clean daily and disinfect periodically according to the m an u factu rer's instructions. Use if there is a
risk of splashing.
CEN Standard :
Remarks
W ork clothing
EN ISO 13688:2013
For professional use only.
Anti-slip work shoes
EN ISO 20347:2012 EN ISO 20344:2011
None
F.- Additional emergency measures
Emergency measure
Standards
Emergency measure
Standards
Emergency shower
ANSI Z358-1 ISO 3864-1:2002
Eyewash stations
DIN 12 899 ISO 3864-1:2002
Environmental exposure controls:
In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage of both the product and its container. For additional information see subsection 7.1.D
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties: For complete information see the product datasheet. Appearance: Physical state at 20 C: Liquid
*Not relevant due to the nature of the product, not providing information property of its hazards.
- CONTINUED ON NEXT PAGE -
Date of compilation: 09/03/2015
Version: 1
Page 6/12
US00006415
GL Performance Products IP
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC
Phos-Chek 3% AFFF MilSpec - [AQUAFILM AF-3MS]
Appearance: Color:
Transparent Yellowish
Odor:
Characteristic
Volatility:
Boiling point at atmospheric pressure:
Non-applicable *
Vapour pressure at 20 C: Vapour pressure at 50 C: Evaporation rate at 20 C: Product description: Density at 20 C: Relative density at 20 C: Dynamic viscosity at 20 C:
Non-appiicabie * Non-applicable * Non-applicable *
1000 - 1040 kg/m3 Non-appiicabie * 4 cP
Kinematic viscosity at 20 C: Kinematic viscosity at 40 C: Concentration: pH: Vapour density at 20 C:
Non-applicable * Non-appiicabie * Non-applicable * 7 - 8,5 Non-applicable *
Partition coefficient n-octanol/water 20 C: Solubility in water at 20 C: Solubility property: Decomposition temperature: Melting point/freezing point:
Non-applicable * Non-applicable * Highly water-soluble Non-applicable * Non-appiicabie *
Flammability:
Flash Point: Autoignition temperature: Lower flammability limit: Upper flammability limit: 9.2 Other information:
Non Flammable (>60 C) Non-applicable * Non-applicable * Non-appiicabie *
Surface tension at 20 C: Refraction index:
Non-applicable * 1,367
*Not relevant due to the nature of the product, not providing information property of its hazards.
SECT!
10.1 Reactivity: No hazardous reactions are expected if the following technical instructions storage of chemicals. See section 7.
10.2 Chemical stability: Chemically stable under the conditions of storage, handling and use.
10.3 Possibility of hazardous reactions: Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected
10.4 Conditions to avoid: Applicable for handling and storage at room temperature:
Shock and friction i Not applicable
Contact with air Not applicable
Increase in tem perature Precaution
Sunlight Avoid direct impact
H u m idity Not applicable
10.5 Incompatible materials:
: Acids ; Not applicable
W ater Not applicable
Combustive materials Avoid direct impact
Combustible materials Avoid direct impact
Others Not applicable
- CONTINUED ON NEXT PAGE
Date of compilation: 09/03/2015
Version: 1
Page 7/12
US00006416
ICL Performance Products LP
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC
Phos-Chek 3% AFFF MilSpec - [AQUAFILM AF-3MS]
10.6 Hazardous decomposition products:
See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (C02), carbon monoxide and other organic compounds.
11.1 Information on toxicological effects:
No experimental information is available on the product itself in relation to the toxicological properties. When performing the danger classification on corrosive or irritant effects the recommendations included in section 3.2.5 of Annex VI of Directive 67/548/EC, in paragraphs b) and c) of section 3 of article 6 of Directive 1999/45/EC and in section 3.2.3.3.5. of Annex I of CLP Regulation were taken into account. Contains glycols. With possibility of effects that are hazardous to the health, it is recommended not to breathe the vapours for long periods of time. Dangerous health implications:
In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure limits, it may result in adverse effects on health depending on the means of exposure: A.- Ingestion:
Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for consumption. For more information see section 3. B- Inhalation:
Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for inhalation. For more information see section 3. C- Contact with the skin and the eyes:
Produces eye damage after contact.
D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):
Based on available data, the classification criteria are not met, however it does contain substances classified as dangerous for this effect. For more information see section 3. E- Sensitizing effects:
Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous with sensibilizing effects. For more information see section 3. F- Specific target organ toxicity (STOT)-time exposure:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. G- Specific target organ toxicity (STOT)-repeated exposure:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. H- Aspiration hazard:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3. Other information:
Non-applicable
Specific toxicology information on the substances:
: Identification Anionic hydrocarbon surfactant 6201310000 CAS: Non-appiicabie EC: Non-applicable Methanol CAS: 67-56-1 EC: 200-659-6 2-(2-methoxyethoxy)ethanol CAS: 111-77-3 EC: 203-906-6
LD50 oral LD50 dermal LC50 inhalation LD50 oral LD50 dermal LC50 inhalation LD50 oral LD50 dermal LC50 inhalation
Acute toxicity 580 mg/kg Non-applicable Non-applicable 100 mg/kg 300 mg/kg 3 mg/L (4 h) 7128 mg/kg 9404 mg/kg Non-applicable
Genus Rat
Rat Rabbit
Rat Rat Rabbit
Date of compilation: 09/03/2015
- CONTINUED ON NEXT PAGE Version: 1
Page 8/12
US00006417
ICL Performance Products LP
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC
Phos-Chek 3% AFFF MilSpec - [AQUAFILM AF-3MS]
The experimental information related to the ecotoxicological properties of the product itself is not available 12.1 Toxicity:
12.2
Identification 2-(2-butoxietoxi)etanol CAS: 112-34-5 EC: 203-961-6 Non-ionic hydrocarbon surfactant 6607700000 CAS: Non-applicable EC: Non-applicable Anionic hydrocarbon surfactant 6201310000 CAS: Non-applicable EC: Non-applicable Tolyltriazole CAS: 29385-43-1 EC: 249-596-6 Methanol CAS: 67-56-1 EC: 200-659-6 2-(2 -m eth oxye th oxy)eth an ol CAS: 111-77-3 EC: 203-906-6
Persistence and degradability:
LC50 EC50 EC50 LC50 EC50 EC50 LC50 EC50 EC50 LC50 EC50 EC50 LC50 EC50 EC50 LC50 EC50 EC50
Acute toxicity 1300 mg/L (96 h) 2850 mg/L (24 h) 53 m g/L (192 h) 126 m g/L (96 h) 151 m g/L (48 h) 27 m g/L (72 h) 177 m g/L (96 h) Non-applicable 21,5 mg/L (72 h) 55 m g/L (96 h) 9 mg/L (48 h) 75 mg/L (72 h) 15400 mg/L (96 h) 12000 mg/L (96 h) 530 m g / L (168 h) 5741 mg/L (96 h) 1192 mg/L (48 h) Non-applicable
Specie Lepomis macrochirus
Daphnia magna Microcystis aeruginosa
Brachydanio rerio Acartia tonsa
Scenedesmus subspicatus Brachydanio rerio
Genus Fish
Crustacean Alga Fish
Crustacean Alga Fish
Pseudokirchneriella subcapitata Cypronodon variegatus Daphnia galeata
Pseudokirchneriella subcapitata Lepomis macrochirus Nitrocra spinipes Microcystis aeruginosa Pimephales promelas Daphnia magna
Alga Fish Crustacean Alga Fish Crustacean Alga Fish Crustacean
: Identification 2-(2-butoxietoxi)etanol CAS: 112-34-5 EC: 203-961-6 Non-ionic hydrocarbon surfactant 6607700000 CAS: Non-appiicabie EC: Non-applicable Anionic hydrocarbon surfactant 6201310000 CAS: Non-applicable EC: Non-applicable Tolyltriazole CAS: 29385-43-1 EC: 249-596-6 Methanol CAS: 67-56-1 EC: 200-659-6 :2-(2-methoxyethoxy)ethanol CAS: 111-77-3 EC: 203-906-6
Bioaccumulative potential:
i
Degradability
BOD5 COD
0.25 g 02/g 2.08 g 02/g
BOD5/COD
0.12
BOD5 COD
Non-applicable Non-applicable
BOD5/COD
Non-applicable
BOD5
Non-applicable
COD
Non-applicable
BOD5/COD
Non-applicable
BOD5 COD
Non-applicable Non-applicable
BOD5/COD
Non-applicable
BOD5 COD
Non-applicable 1.42 g 02/g
BOD5/COD
Non-applicable
BOD5 COD
Non-applicable Non-applicable
BOD5/COD
0.07
Concentration Period % Biodegradable Concentration Period % Biodegradable Concentration Period % Biodegradable Concentration Period % Biodegradable Concentration Period % Biodegradable Concentration Period % Biodegradable
Biodegradability
:
100 mg/L 28 days
92 %
Non-applicable 28 days
100 %
2 mg/L
30 days
98 %
100 mg/L 28 days
4%
100 mg/L 14 days
92 %
Non-applicable 28 days
100 %
12.4
2-(2-butoxietoxi)etanoi CAS: 112-34-5 EC: 203-961-6
Methanol CAS: 67-56-1 EC: 200-659-6 2-(2-methoxyethoxy)ethanol CAS: 111-77-3 EC: 203-906-6
Mobility in soil:
Identification
BCF Pow Log Potential BCF Pow Log Potential BCF Pow Log Potential
Bioaccumulation potential 0,46 0,56 Low 3 0,77 Low 3 -1,18 Low
:
Date of compilation: 09/03/2015
- CONTINUED ON NEXT PAGE Version: 1
Page 9/12
US00006418
ICL Performance Products LP
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC
Phos-Chek 3% AFFF MilSpec - [AQUAFILM AF-3MS]
Identification
2-(2-butoxietoxi)etanol CAS: 112-34-5 EC: 203-961-6
Non-ionic hydrocarbon surfactant 6607700000 CAS: Non-applicable EC: Non-applicable
Anionic hydrocarbon surfactant 6201310000 CAS: Non-applicable EC: Non-applicable
Tolyltriazole CAS: 29385-43-1 EC: 249-596-6
Methanol CAS: 67-56-1 EC: 200-659-6
12.5
2-(2-methoxyethoxy)ethanol CAS: 111-77-3 EC: 203-906-6
Results of PBT and vPvB assessment:
Non-applicable
12.6 Other adverse effects:
Not described
Absorption/desorption
Koc Conclusion
48 Very High
Surface tension
33950 N/m (25 C)
Koc Conclusion
50 Very High
Surface tension
Non-applicable
Koc Conclusion Surface tension
150 Very High 33200 N/m (24 C)
Koc Conclusion
90 Very High
Surface tension
Non-applicable
Koc Conclusion
Non-applicable Non-applicable
Surface tension
23550 N/m (25 C)
Koc 1
Conclusion Surface tension
Very High 35900 N/m (25 C)
Henry Dry soil Moist soil Henry Dry soil Moist soil Henry Dry soil Moist soil Henry Dry soil Moist soil Henry Dry soil Moist soil Henry Dry soil Moist soil
Volatility 7,2E-9 Pa,m 3/mol No No l,2 E -8 Pa,m 3/mol No No l,06 E -2 P a 'm 3/mol Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable Non-applicable l,621E-6 Pa-m Vm ol Non-applicable No
: DISPOSAL CONSIDERATE
13.1 Waste treatment methods:
Code
Description
Waste class (Directive 2008/98/EC)
16 05 08* Discarded organic chem icals consisting of or containing dangerous substances
Waste management (disposal and evaluation):
Dangerous
Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex 2 (Directive 2008/98/EC). As under 15 01 (2000/532/EC) of the code and in case the container has been in direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue. We do not recommended disposal down the drain. See paragraph 6.2.
Regulations related to waste management:
In accordance with Annex II of Regulation (EC) n1907/2006 (REACH) the community or state provisions related to waste management are stated
Community legislation: Directive 2008/98/EC, 2000/532/EC: Commission Decision of 3 May 2000
--a
This product is not regulated for transport (ADR/RID,IMDG,IATA)
SECTION 15: REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture: Candidate substances for authorisation under the Regulation (EC) 1907/2006 (REACH): Non-applicable Regulation (EC) 1005/2009, about substances that deplete the ozone layer: Non-applicable Active substances for which a decision of non-inclusion onto Annex I (Regulation (EU) No 528/2012): Non-applicable Regulation (EC) 649/2012, in relation to the import and export of hazardous chemical products: Non-applicable Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII, REACH):
Date of compilation: 09/03/2015
- CONTINUED ON NEXT PAGE Version: 1
Page 10/12
US00006419
ICL Performance Products LP
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC
Phos-Chek 3% AFFF MilSpec - [AQUAFILM AF-3MS]
Non-applicable
Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local circumstances in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this product. Relevant instructions for use:
This product is intended for the production of foam for fire extinguishing purposes. It should be diluted at 3% in water and used with appropriate foam-generating equipment. Other legislation:
Non-applicable
15.2 Chemical safety assessment:
The supplier has not carried out evaluation of chemical safety.
Legislation related to safety data sheets:
This safety data sheet has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of Regulation (EC) N 1907/2006 (Regulation (EC) N 453/2010)
Modifications related to the previous security card which concerns the ways of managing risks. :
Non-applicable
Text of R-phrases considered in section 3:
The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the individual components which appear in section 3
Directive 67/548/EC and Directive 1999/45/EC:
R ll: Highly flammable R22: Harmful if swallowed R23/24/25: Toxic by inhalation, in contact with skin and if swallowed R36: Irritating to eyes R36/38: Irritating to eyes and skin R38: Irritating to skin R39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed R41: Risk of serious damage to eyes R43: May cause sensitisation by skin contact R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R63: Possible risk of harm to the unborn child
CLP Regulation (EC) n 1272/2008:
Acute Tox. 3: H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled Acute Tox. 4: H302 - Harmful if swallowed Aquatic Chronic 2: H411 - Toxic to aquatic life with long lasting effects Aquatic Chronic 3: H412 - Harmful to aquatic life with long lasting effects Eye Dam. 1: H318 - Causes serious eye damage Eye Irrit. 2: H319 - Causes serious eye irritation Flam. Liq. 2: H225 - Highly flammable liquid and vapour Repr. 2: H361d - Suspected of damaging the unborn child. Skin Irrit. 2: H315 - Causes skin irritation Skin Sens. 1: H317 - May cause an allergic skin reaction STOT SE 1: H370 - Causes damage to organs
Advice related to training:
Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
http://esis.jrc.ec.europa.eu http://echa.europa.eu http://eur-lex.europa.eu
Abbreviations and acronyms:
Date of compilation: 09/03/2015
- CONTINUED ON NEXT PAGE Version: 1
Page 11/12 US00006420
ICL Performance Products LP
Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC
Phos-Chek 3% AFFF MilSpec - [AQUAFILM AF-3MS]
- ADR: European agreement concerning the international carriage of dangerous goods by road -IMDG: International maritime dangerous goods code -IATA: International Air Transport Association -ICAO: International Civil Aviation Organisation -COD: Chemical Oxygen Demand -BOD5: 5-day biochemical oxygen demand -BCF: Bioconcentration factor -LD50: Lethal Dose 50 -CL50: Lethal Concentration 50 -EC50: Effective concentration 50 -Log-POW: Octanol-water partition coefficient -Koc: Partition coefficient of organic carbon
The information contained in this security data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its accuracy. This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users of this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the manipulation, storage, use and disposal of chemical products. The information on this security data sheet only refers to this product, which should not be used for needs other than those specified.
- END OF SAFETY DATA SHEET -
Date of compilation: 09/03/2015
V ersio n:!
Page 12/12
US00006421