Document jJj3obrxnEXeQL8ZeX49nZ3k
.
YEE! F
RESEARCH
.
Attachment 2
A226~-~ 17764
Air Sampling Fluorochemical Report
|
DuPont Washington Works -- Air Sampling Program Round 2
[
Exygen Research Report No. L0001308
|~
Teastyineg LRaebsoeraarcthory
3058 Research Drive
|-
State College, PA 16801
{
Requester
-
|
Michael D Aucoin
BUaRrSleyCoMriplolraPtliaozna
|-
LaBnucialsdtienrg P2i7keRoanodmR1t216401
Wilmington, DE 19805
k
ALL DATA CONTAINED IN THIS REPORTWAS GENERATED BY EXYGEN RESEARCH
LEREset BiTeaon, usa
-
preter?
000082. gman,
Summary
Seven solid media samples were received by Centre Analytical Laboratories, Inc. (dba Exygen Research) (Exygen) from DuPont Corporation. The media represent samples of air collected on |" OVS tubes. Please see Table 1 for a completed listing of samples received and field air volumes
collected. Fm samples were analyzed for Perfluorooctanoic Acid (C8 Acid) using liquid chromatography |". /DemtaesrsmisnpaetcitornomoeftPreyrf(lLuCoMroSo)c.taTnhoiec mAectihdo(dPeFmOpAl)oyiendOiVs SenAtiitrlteudbe"sMebtyhLodCMoSf "An(aJlaysmiess fMiolrletrh,e
Exygen Research, February 17, 2003).
I" The OVS tubes were seprsted into thre factions fo specific forochenical analysis. | _. fFirrascttbioend Aof cXonAsiDstreedsionf atnhed ftihlteerP, UbaFckbiancgkinmgat.eriFarlacatnidonpClasctiocntraiinng.ed FtrhaectsieocnonBd cboendtaoifneXd AthDe
resin and PUF backing. Fractions A and B were extracted with 1 mL of methanol. Fraction C
| was not analyzed but saved for possible future analysis. Perfluorodecanoic Acid (C10 Acid)
was added as a surrogate spike to each fraction prior to extraction.
|" Instrument operating conditions can be found at the beginning of cach analytical run. Raw instrument data is given in Appendix A. Chain-of-custody information can be found in
| "Appendix B.
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
|
Page2007
000083
i Results Summary
-
|
SAairmpVloleudme1.
Cm8gAdci)d
r
-- AAS E28
I1r475
2<000000000077
r
n WIWK-A A-AMS12-ET2oC) --1475
1
00NA00
&
W[ah--Ase--8
1144668
WAANGE 20
ids
<00.000000907 NA
ASE2 Tr)
>
|
wWrANeSnE2
peaz
ooc0s
<Go0007
AISEC
1a
NA
|
A EUS E2 ow) Tee|
i
[ aA--28
1Ta43377
AA 20
ie
<Z0.o000r07 NA
AAS 2(os)
cw
|
WWWHAKAAGAMSESSEEE222408
11144a55566
<Z0G.oN000Ao00077
I"
AASS2 a)
---- T <cem |
wWkaaASESEE2"D
t1i42o2
<Zoo0a0o000r7
WWAWKAAAMSSSS-2E2TCo.
T CC 1w 422 os NA ]
|" om ronsvatget, toi ves oe om quasi ey eeoa fio doar ai
| . Ll. "<"is defined as not detected at or above the reported level.
2. Sample results have not been corrected for blank results or control spike recoveries.
| 3. Please note the following descriptions of the OVS sample tube fractions:
:|
FracAtion F[ForaecixoancDtescron
.
c8 o{ontcssoottbbeoaaddssaontvraactt (not analyzoc)
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Fuge 3or7
000084
I5
rf [
i
}5
[
41
r gE:
583
| CE3: E
[ if g[ E H5P
is
3
HN I"
g2s3 23
- 228 gPgl
?
I HEE
3
2 | 8
Im 2E58Epe
<a
I=
-
iEisE5ie38 |
iu32e3
582 |=
(23
F|gg4 giEsfsi} g[s3f g: Eis
=
g
Z
2Pi%
g=
:
Z
:3
;
000085
Surrogates
|
A surrogate spike (C10 Acid) was added to all OVS tubes to give a final concentration of 500 ppb in the extract.
Surrogate spike recoveries are given in the following table. There are no set criteria for surrogate spike
| recoveries. Advisory ranges are 75-125%.
I mmm -- 22
co
5
I WHKARMSLEZE
0
=
[| mess
2
%
|
WWICA-AMSS2 A
500
732
146
[| Bmemees | 3=1 a2 =13
| * Surrogate recovery outside of advisory range
; SS--------
000086
r r r
r
r | ean
sessazzezessege |
8% vvvv Vv vvvvvvvey
oz
H8 [TeIcVcIeEgLeEogTeTcToRgTocIeVEY
Slsarnsnseseze
= 22333033 JY Yce
-J
g
:
:;
il
2
::
i
000087
|" Example Calculation
For sample WWK-A-AMS2-E2 A C8 Acid,
=
[1340ng/ml 1000 L)]
of
C8
Acid
x
(1
mix )(1
ug/
1000ng)
x
(1
mg/
1000ug)
]
/
(C1468 L) x (1 m3 /
= 00009mg /m3
Signatures
|"
>
aul Connoly, LOMS Team Leader
| -~
7,
fohn M. Fiaherty, Viod President
| Otvertan MembersContin 0Data
I
James Miller
2125/0
Date
Ir)
Date
|i
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
freee
000088
r
)
E35 cooCfPEPEEEEEERLRNRELYELEIREELEESINoYo.
I
3
8 siggfgi28igi48igi28isi2i8 si88i%si2i8sigd9
558533553533539353835583533 8 FEEFrErsErFEEEfrairEEzag
[
z 55353825sg388s835855s8s5s8s8288888888
of SEEESESSSSESESSEsEsEEEssg
|"
3
.
52372853335505085228598]
r
7 g9888888858888aaaa585855
: <$s8o8 causnosnosnosnosan
|
LLi090N008YTYYINsTNeRg
2 |S BERa05050808333588888888
|-
$= |38 Fb32bT2hs3zi3=i3ss3=i32i32i32i32i3i3i3z5Si3Si23i32i33i32s22i28e28s95
2
ZELiSSSEEEEEEEEEEEEEEECSY
|
2
3222322333333333233%
2
223
|
Juve
000089
"
[
BSBgo 5t55E_i&2i23sT25i58st3S5i88st3_88i5 s38E88is2_ta%is3Ae3Es
3 8% 8% 8% 8% 8% 8F 8 %
~
$5]
to
co 22 53
BEBE RR:
83 33 ss 2g
00-00:00400:
r
% T0 TT TT TT RR ORR ORE ORR
Xx |
23sH so5sEsEo5s3z2o3s8s3s5g8s5s8s8s5s8seseassnasssy
Si SEEEIESEREEEEREEESSESERY
|
3 33383858885E snes,
S EEEEESTSIEEEEEEEEERzzcCC
I-
3g S<@ilOfcYeNocNevdsIocRnodcEnogcaaoEcaTg
|"
3
Ef
EER 0058088333885858888%
283333333333333233333299
IPIIESSISIISSISIiiiii
I~
3 EEEEEEEEEEEEEEEEEEEECYY
|"
Joo?
000090
.
ANALYTICAL DATA REVIEW SHEET
}
I
LC/MS
Tawes Bo Mller
ve Vin
I
Analyst
Sigrature/Date
Tok _m_fihhenty
Reviewed by
ad milky'
gnature/Date
Shr
|
0090
000091
[oss con
[em sa Method and Injection Info Part:
~
Line Location SampleName
Method Inj SampleType InjVolume DataFile
_
_
1DSDuuuvaiiialln:sl SSMTDmio5a 0mkpeebneffCee8m d-d1ee0 ii11 oa cSanmsple
|
SSouviiasi TmoosaeEsn freadeo i1 acisn
|i
7S VVVUiiilRlaall6 E32 SSSBTohDtouEu1e0sm0e0cAepmipetbk mW FrRCeaE-dd1oo0 1baCcSaeilmmienble
- 13OVvViRiaIEh BmDoeeonbsoeeends Mmmaeeneciso o11 mSsamnmei
|
HivOoiVvEEE mmDeeennnaeads mMMadns bbi oosnnmmmnnn
- 1l17o9 VVViiAiR fDDooosbohhdooieaeddsle fmmeaaedciiooo 1 ssSaeemmmeeiilsee
23Bo oVVviRaliS RSShbeesno:nopPeehe RmMaeacdhsoo 11 smsaempellse
|
8BovVovEaaIlLS DmMoeebeonnsa:seammmeaesso 1onsomasmmnin
. Sf3e VvviiEaall: DmBeeRenmNeeedss mMRaaandsso 1o bosnm wmeins
|
[.
Dd2$9ovvVviiieaTlr:s92
Eo
S MSBSohlvaiResnR toeEmblsank
RrOrFeeCeBBdd-oE1oo0 1111acaSanimmpnsle
34 vial5 STD 750ppb
FC8-10 1 Calib
RoI 35 vial 6 SOTDM10E00NppEb RM FC8-10. 1LaCallib
-
.
-
Catibration part: | Line Location sapletame Method _ Callev Update SE Update RT Interval
|-
2SD$UUuVRRiaaIIllI}1
SSOVVAAsSS
0 Vil
SHSSEuVnD iSl
!
BUoHnLi
SSSSTDHhN50IopEpTeb SSIDD sDloootobmn boas SmBomm mme mSIiNnCE
FRmfC8ee-Ed1ad0 23i1 RRReeeddddod 37 Reio 1 RROeRiKWc 311 BMSab:7
Lass 11/20/03 4:31:48 ou smarter JR Vif
RRnheeepilmlascaee Avdmveeeenmrnadegnese Reise mens
oT
-
ARRevepelrbaecgaees mmAeevrreeerss
MMMeaEnngRne hMNeenrnnsa
mMenns NveEmm
oot 000092 rage 1 ot 2
[sera crane
r
[ r
I [
I I r r -
| I
I"
&,
I wane 11/20/03 asssets su misses 0 Tn
Ia .
;
.
i
oo -
. 0012 400093 suse zo
[
|
LC/MS SYSTEM AND OPERATING CONDITIONS
I1
Client: Dupont
EXYGEN STUDY: _L0001308 - =
Instrument: Hewlett-Packard 1100 LC/MSD (LC/MS 3)
-
API-ES Interface - Negative SIM mode
|
FNirtargomgeennt:or1:0 VLa/rmiianblaet; 3V0c0apC: 3500V
'
[
Computer:
Hewlett-Packard Kayak workstation
I"
Software:
Microsoft Windows NT 4.0
-
Agilent ChemStation Version A.08.03
-
|
HPLC Equipment: HP G1379A Solvent Degasser
HP G1311A Quaternary Pump
|
HP G1313A Autosampler
i:
HHPP GG11934166AA CMoSlDumn Thermostat
HPLC Column: Thermo Hypersil-Keystone Betasil C18, 30 x 2.0 mm x ym
-
Column Temp.: ~~ 35C
|
Mobile Phase (A): 2mM Ammonium acetate in OmniSolv Water
Mobile Phase (B): HPLC grade Methanol
Time
%A
%8
|
0.0
70
30
!
60
10
90
|~
1010..00
sT1o0p
sT9o0P
I~
TPootsatlTriumneti=m4em=in1.4 min.
|
Flow Rate:
0.3 mL/min
|
Injected Volume: 5 pL
["
Yn ~
!
Page 1012 uoi3 000094
I
I
~
fons monitored:
|
.
[
Analyte C8 Acid (PFOA)
10 Surrogate
lon (m/z) 369
469
Extraction Date: November 20, 2003
:
Analyst:
|
-
James R. Miller7 Veo
E30x5y8geRnesReesaeracrhc]Drive, State College, PA 16801
Phone: (814) 272-1039, FAX: (814) 231-1580
|i
-
-
.
1
--
Page20f2 0074
000095
[7 RInestdrueme:nt d: ernecruis3to 20030" 01946: API_ES NegatiCHv\e moHde P119C46TH0NE\EATUM NES \TONfage 1 of 3
I
aw/z G1e1o3.s01ba50.00.156 anw/z 4650916757Ba580.00.265 ane/a1511093935.98Bu550.00-56
|
io
is
ato
abs
1030 Jom
'
r | a" m/dzea1763303.o9u5 ma0x.65
A5'm1/0z022023323.B9w5 ma0x.76
bi) )
>
5
[
|
I" 1630 1635
0) 2235
E25e 501 peaks Base: 2233e .55 Abundancr e; 1021624 Raw,Gauss 0.3
| 100 1.
i
a|
-x
|
~Ed.
[RS
I" - aw
|
im]
| = ||
s00 1000
1500 2000
2500
a51/208hgf MdTueonlndes Re"l7ToAsbg3uond Isemoubamav/eyzs Iso AMebaiusnnod Iso 1RC2a26ti58o
10405 148800 239.01 1039.05 3434 23.01
21603333.3955 1040817020946 1577429..0956 21063344..9855 01767475962 3463..479
0015
000096
| iIandstrNuovmen1t2 6: 8:L4o7u:s10 2003/07 "ef6o1r946: API_ES NegatCiHve\noHdeEC19H46TEUNEMNAT\ONS1S.T\ONPage 2 of 3
[. [r
|-
.
[
Fragnentor
we]
| s
|
|
200{
"ls
Fragnent VAR WidthGain -120
SLLkeeinnmss2lz -642..100 MvWaiasdsstsOhGfOatfisfns.36V.V1AA5RR
Tris 176
|
OEpnoeirbgeyak 53.000
Gatn 2.0 gOupaodlokCnee 0.30106 |-
:
Vaevep 42000608 ASvaemrplaegses 18
stacus: Stepsize 0.10 ||
. {.
:
CChaapcnuCrar 1.0761 GDarsyinTgeGmaps 63.000
Gud Temp 99 eb bres 20
Sr mr
|
=
|
!
100
|
r "1
|
|-
A
s00
1000
1500
2000
2500
3000
I| ~
1M0a0s.s00 Se6t0t.i0n0g 30M0a0s.s00 S2e5t0t.i0n0g Wass Setting
|
|
00718
000097
|[InstrodumNoevn1t2 0: 8:l4o7u:s:10 2003 |. Widen Ofser
[~ 2|
|
40
r
-
[
-50
[100
oV6o1r346: API_ES NegatiCEv\e mHodsEC19H4STEONEM\KTNONE1S T\ONPage 3 of 3 Dynamic Parameter Ramp
|
.
{J
.:
500 1000
1500 2000 2500
3000
|
161b32a30s09s505 -S91e06t6.t.i00n00g 226M03a13s..s518 1S-0e16t0.6t.i00n00g 10M3a3s.s39 S-e1t0t6.i0n0g
| Hass ofeser
r
"
Synanic Paranater amp
I|
i
0.00
|
-1.00
|
I
|
|
2.00
LS
s00 1000
1500 2000
2500
3000
|- .
116a3132s.7s3555
Set0t5in5g 0ls6
aMvaissse 2233.51
Set0t.i6n7g 10w3e3s.5 ose
Se0t.t6in6g
i|
yo:7
|
000098
MethodC: \HECHEI\1\METHODS\ 112003.
or
Calibration Table
i
[| --Cal--ib.--bata Wosifiad : sTcouersndaey, sJaemuaarny 08, 2004 2:45:39 pu
Saad on
Dona
[7 TRmbeeslr.l. RNeeotfnoeorrreeennrcceewwWiinindndodowoww:|i 55s...000000000 a3in
pooUnMcalEibRratEed PReakSs D| nSot reeported
* CPoarrsteicatl ACaLlibRreta.tiToinmes:: NYoe:s, onildyentfiorfieddenpteiatkisonarepearrescalibrated
| Gciruirggvhaenmoe
DIo sLoimmneeaarra
_. hAveralge i Revea niion mine! eFlsoastiensAAhverCaseHhorL730
| ; SrintCNooasrltmiablroaft`RipeoepncoerTtleinabifrstaetriaofntRseercawiiSitebhcriaanttiaiobnsreoqauncence:
1 tRheesusieqtusenocfe.EIioredonoveolwei.th(abnrdaicnkgevbirnegv:ious bracket)
[7 sSiigGnnaarl 211: wvioork 3de6s9., mBxrce--adcens. 7r.i6a0g.e7.
[Ret= timeELiC l C Moun,t Area , Amt/Area oRefoGrp Name
- 7237 1153 31305000...00000000000000 431...0006330a56433d0ee4ds 33313a46e71i09t00e00s03s3 iGo acid
3& 173050000.00000000000000 333.007i31s35877t00e633s b33.sd64s6gi9en7s65ee0ss3ss
6.005 2 153 151007005::000.000000000000 333..i30a07b08o04n87eeed3a 311.8.s57e60s41s80e08e33s 1 cio surrosace
|
N
&3 1305203500000....000000000000000000 5241....5035077373305301883406ee5555 1111.1ea67ds31i3i5z86si44eei0r-e3s3
|
5 1500.00000 7:36dses 13sisiess
Hore compound-specitic settings:
| coomosuntW:incdaowseta : From 7.064 min To 8.065 min
[|7 = ComTphoeuendW:incdio0w surrogate : From 7.808 min To 8.614 min
-
Seasun table
To
+210 Entries in tablers
| 200414 1/8/04 2:48:28 put 3mitierJ A
G08 gpoooguse : of 2
i:Hathod C:\HECHEM\1\METHODS\112003
! I [ea
||
| sooumo
oon]
Calibration Curves
=
s5
Js
SC801Aci3d69a,tBeIxCp.36R0T:7713.6027 37 7 | cFRooerrsmriuedlluaaaa:tliYoSynt":d=3.8maeDev+.ub: 106300.-9897826144
|XIbi ra1e20t9i33n23a80
- |[ 0 E10S 00 |
| me
[| {o70n0000
ms . [occ
| 300000 . rome L Iost
A5s
seemooo
cs1o0 su46rsr,ogBaitce-aa6t8e7x5p,46m.a7: 8.008 7 || RFcooerrsmriuedlluaaa:tlioySnt:d-. meDevs.b: 166507..9390893742
mb:: 20550733.5546958257
= x: Amount (ppb)
{|
1
-
,
| o0ae 1/0/08 20a8:28 ou sminier07 Hy
0079
000104. ; .:
Sage Sees 0 pes
I" sDaamtpalefilIenfo:(WCarr\mHPuCpHER\1\DATAVPCD00001.D
[SmfTeaihtopensowe
+ ia mu
ae mmTFEme
Jt Hi
HET
[7 ecr q,tweoE chownauhod +|{ErEeCnAacRton 1ETHODEAL1t20i03t1
|l- = a | Less analysis of perfluorcoctanoic acid.
Tecn
0
|
0
|
[7] wd
r=
1
sul1i
3
S
|
3H
|
3
i:
rl = | =2 MSD] 469,E4 IC=468.7:458.7 (FO006 0001 0) API-ES, Neg,SIM, Frag: Var
8
ma
I[I] | | w-==e bo coseI | | wo
|
mloo
rLj
i
compound
en
1
I
rou tno/et) RT.
Tas
||
7
Ta
Aven
sional
Thain ve, mee Tae
seen
Tn ok repre
--
Thu, 8. Jan. 2008 08:20:20 pm
. rage 1 of 1
000101
Sample Nane:STD 50 ppb
[~ Dsaatmap fleilIenfo:Co HRCHEII\ONTIVRCOO0002.D
1
p R Sm Gaam mare:E l1/e2
aryTBnEa Bk
sd::
V pr
iE ireetmsR ionan,nL on| E tmicii
emo 1B1200R3 1
Lo/ks anatysis of pertiuorooctanoie acid
[ere wo eessar
od
7228.ca.
|a -
[| ww
|
[| =
re
I [I wo
HST----
ES8En -- FRE-- D 9S 788 r : ----TT on oo
Flo
Flo 3000
|
|
ao
rl -wo
||
IL "' er
i
=
[omoms roms wr wm em
stan
Brea
Tan hen hen sas mesaea
Te Lee
-
| xooaia
Thu, 6. Jan. 2008 04:20:50 pm
ers 021
Page 1 of 1
000102
[" Ssaammppllee Nfaom:e:STM 100 ppb
1
[ pTaateastfiiolne bate ivaves swarm :C:\HPCHEM\1\DATA\FC000003.D
| Req operator: miller
VSiwalaivon. e:
23
~ DIinlsuttriumoennt JPCO0ALA
ITong.. vNeol.. ::
suli
| Acnqa.lysmiosthMeethod i+ Cs:e\nH-PtCoHwEM\I\METHODS\1120033
[a Changed : 1/8/04
02:46:06 pn
Lo/ms analysis of perfluorooctanoic acid.
![er 222- co. a||
| 4000:
I | 20
|
IN [|
|
1000]
[oe RE e of e a sie: CrT os a | |
"MSD 469,EIC-460.7:460.7(FOD00003D) AP NegE ,SIMS ,Frag, :Var
IL|
sm
0
roe
a0
||
|
| - 1000
r
I
i
Compound Amount (ng/ml) RT.
| ~e30ncSiuarogac 7787..9388
3T0a1345
"
Area Saeodnsoe
t
5
i
Signal
swedoi 436609,, Emiicc-e3s6e8.s7.:r3i6a9e.7s7
N A Eprrpeg------
-
| ecooara
Thu, 8. Jan. 2004 04:21:44 pm
0022 Page 1 of 1
000103
_ sarple tamersmD 250 ob
{ Sample Info:
1
Iectiemtie ANY ma : ' pata file :C:\HPCHEM\1\DATA\FC000004.D
I InjectionDate : 11/20/03 5:28:08 PM
Seq Line
a
I" -
p2denga,lvTsaieoshehoeeat |zCEeNenRro
emo 1t1200i3. i
|[7Less an:[ alysise of pers fivorocr ctanote acta.
:
12000
ed
| 10000-
I
Feed
| "00
|
I. J Fn
YE
SA TA SR
|
"MSD1469,EIC=468.7:469.7(FO000004.0) APNIeg,- SIME ,FrS ag:V,ar
|
i
|] om
|e
[7] ed
r 7a00
|
-
[|=
I.
I
7
7
7
Compo rmomt gims AT. Aven
signa
|. ~
| sonoae
or
S22 End ofReport ++
ha, 6.an. 008 04:22:30pm
A
TT
0023
meio
000104
[= SSaammppllee NIanfmoe::STD 500 ppb
Data file :C:\HECHEM\L\DATA\FCO00005.D
|[= cInqjeocpteiroantoDra:te m: i11l/l20e/r03 5:43:40 BM
vSieaqlLNiom.e :
~ DInislturtuimoennt t+ rpeovata
nInij.. vNeol..
|| aca, Methoa : cs-10.m
= AansatlysCihsaMnegtheodd:: C1:/\8/H0E4CHEM\L\METHODS\10122:04063:.0}6 pm
- | Lesus analysis of perfluorooctanoic acid.
-T HSDT 69,ECE 7 APTES,Neg SW,FragVar
of = a 20000.
10000
1 Ts4 sul1
||
ro FM
I. ~
WSO 469,EIC=465.146a 97 (FORO) APNoFg, ESW,FrSaEgTiV,ar Ta
asus
8017 C10 Surogat
I
Ted
2500
[7]
[I 15000
Fl ond
IS | |sompons_ ome wazrms wx. 1 sewn 5
|
|
sigma mi
| 2810acSiuderogar 553227..3922
87..021471 218989643607 MMSDDLI 436699,, EBIICC-=436688..77::436699..77
y= | 2co0ata
"End of meport ter Thu, 8. Jan. 2004 04:23:18 pm
rage 1 of 1
000105
sarole Hane: 750 pod
I
= Injection Date : 11/205/:509:320 PM
SeqLin:e
5
! wo
7.220. Ca.
iro
|f
on
| - | 10000
|
[| [mrtvomm
r--e-----em
[7] om
|
-
ri l =
1
- on
-fl
;
T
:
:
A
sigma
[10 Gurren 753765 TEE New es: mous riaee
1 | PC00414
+++Endof Report +++
Thu, 8. Jan. 2004
04:24:04 pm.
TTT 0025
Page 1 of 1
0001
arpto anni 1300 51
|" InjeDac te:t1i1/o20/n03 6:30:33 BM
Seq Line:
8
| Acq Operator : jmiller
Vial No. i
7
dubs foesGe
Ha
E
a.
is "
I 40000.
"
[[7] somo
wo
IN
| po
mrs st iue n
| ---
[1] -on
|
[-| wpoe
[| --.
{ropes moe tomar ww, owen
sna
| .0 Surrogat 1444.38
8.026 787916 MSDL 469, EIC-168.7:369.7
| cosas
Cnof mepore vee
hu, 8. gan. 2004 04:25:1pm9
se totl 000107
=
Sample
Sample
NIanmfeo::Solvent.
blank
)
Data file iC: \HPCHEM\I\DNTA\ZC000009.D
|" Injection Date : 11/20/03 6:46:01BM
Seq Line :
5
|
-
DATicftqeuccOinpoeenrnastor
|i: HBjCmoiolalnesr
vnmioalevNeo..
su9l2:
|
AADcnaqa.alyMsCeihtsahnMogedetdhod
+| FC1C:/B\8-R01P80O.HMEM\1\NETHODS\51214260.00318.
pn
| orms anatyats of pertiuococtanote acta
r STO E53 TR6FEO8 ODT APNaESWSF Vir
>
I
| 20
om
[ow
ro
|=
I" 180
r NT AE HT FOe E TES.NaS Fg Vr =
i 260
rl ==}
| aodel
ie
1903
[7] =
~ wo
7
7
spot soo gtr x een
[a8 AEcid y 0.00
a0.t00e0 06
-
siomnt pe M1 SDL 369, EHICe-3n68.a7:n369.7
A TE ot Repent or --
scours
Thu, o. gan. 2008 04:26:06 pm
nage rocy 000108
- smampile teame:sou0tion-22
1
Data lle LC: \HPCCHhamaBtorI\L1DV271IS6\A\370D560\ARE0T0001N0
| ST nieectinone epeta 1|a 1Ruaveres ensmn Comme
Hnsm eaihiinL e
sd52i
|I EEEEL Ee
HE
1 tems anata of porelsorosctanoie seid.
HIN -- [HT BTTHORAaCn-ca 5
[| ee
jo
[| = won!
[lo aw
[l=
.
RE
TE TTCEO
|
ICrT o cI iseEa ai_-- d oh
|
r=wo
[7] oo
[oo
- [I
I
coment mount Gos)
BSehbo T33E:3E2
|
|
xn i res i signal TTaOiRnE wmeEa mEeea76sd
1"conse
I reer TT 0029
hu 8. gm. 0s 02:18:12 0m va1sofe1
000109
Sample Namo:0001308-23
~ sample Info:
1
Data file iC: \HECHEN\I\DKTA\Chemstor\Li337379\A3T3312\7C000011.D
[ FSpmsrreereoiofnnbeuatadEa idiesades nesm seuwa latee
fii:
on
[ses ected.
if
senso
mv
sad
[MoE diyeiE s Method | CX \RCHEN1\KET1H1E2O0D63SS.\on
Lo/MS analysis of perfiuorocctanoic acid.
[
TR EGTR RENTON -
2F varCOcRTonPVSEW Fi,r
[ 2000
Tl oe
| ed [---
[l=
]
|
|
Le gate. crt i |
"MSD 469,EIC=488.7:469.7 (CHEMSTOR\I13373A7G9T312FC0000T1.0) API-ES,Neg,SIM, Frag: Var
[I --
[7] NE mi
| |
| | on
|
5
l=
r
--_--
z
I
7
compound amount tngreid RT. aves
= signal
28Lo"AcSiidrvopac4385.1968:
SAMMI 7.227
30300
MSD 369,
mEmeINd EIC=368.7:369.7
-
-
1| ecooars
TT Repere naT :
0033
Thu, 8. Jam. 2006 03:12:27 pm
sage 1 of 1
000110
[saE mple E Name:10001308-1
)
Data File +0: HPCHENVI\or1D3ATTHMIVA\TTCSOSh\FeEOmUOeOIEt
[emeaemrann ifJas ens J tives 4
a r igsat l mo
RTB} sul
I pr
Eog, EtesLted ne
|| SSonAwtoensoEnh. oe
LHS analysts of pertluorooctanote acid.
[ Nw -- LL
or
|0
[ ~ |=o
|i
Flo=
|-
|-
"MSD 469, 5 EIC=468.7:469.7 (CHEMSTORN i1337644\A376064s1 ch 120] e APeNIog,- s SIME,FrS ag:V,ar
[[| p= p-oi
80G210 S1uro.ga
I | -- | 20000-
| .5000 j
I
IE
|t
3
2
4 oy Ps
si8gnat
rT
I BS
| scooeze
**+ End of Report
TT
Te. 8. den. 2008 07:13:07 pm
0031 rage 1 of 1
000111
[Emm
.
OO. A,
|" eInjiectnioneDsate Lp : 11/20/03 7:48:16 PM SegqheLiene :
b1d3
[ [7 SseqE. oerEots w |+rT enrtou mn moEr ct wars sty of pereTuseosSanAS a
[ree aS
I 2=0]
I|| = | wd | woi
|| J|
|
|
180-
| | so rmsas;
em 7
ET ; ----7 ---- ro cron
I | oorm]
|
[I ho
|-
||
r
.200
1
:
I
BT
sional
Shea om
Too
ont Sea eae737
TT TEndof Report see
|
0032
000112
| Sample Info:
A
| IInpjemctiioonDbnautae :+ 10 1/20/03 8:03:50 BM
{ vrmon. ros
--_ 1
i Seq Line :
1i4
[
TT OS Ro
= [| owr=]
||
[=
| oo
|
#0:
7219.C8.
[I] |L| =oow=o V7 e T t T er | | v
"MSO 469,EIC=468.7:469.7 (CHEMSTOR\ 1337966\A381760\FC000014.0) ~ APNI og,-SIME ,FrS ag:V,ar
| | aon
[on
| I
. re
1
7
T
|
compres amos gs nr. aves
p=
I TTT sad of Report ven
|| acooess
hu, 8. dan. 2008 03:16:0p7m
TTT
0033oaks
000113
Sample Nae 10001308-5
[ Sample Info:
1
[|J" Eso Inrjtecie tiioonDnate :EH: 1h1aN/2n0E/e03 8:19:26 PM Twm Seq eeLEine :
[r " sNca.EE wocnotsee +| zE enroveo nm
1s5 uilz:
r w]
I'l w=
lL iIL:L.h
[|] =
r 20.
rl =
|
||
|
T a RSTB O A ETA pTt SN SFereBE aon
[1
[7] on
| 10000
|
|
,
-
s 1 a T
3
[amos ems sag ie ern
signal
|
[=
T+ End of Reportees
ho 5. dan. 2008 03:24:58 pm
oT
rage 1 of 1
000114
[ESammple Name:L0001308-7
1
Data file :C:\HECHEM\I\DATA\Chenstor\11338314\A387648\FC000016.D.
OT [| InAIjcenqcsOttpierorunatmDoeartn~et::: Pj1mCiO1l0l4/e1r208/:305:308 Bi
~ pilution
il
vSieaqlLimon.e Imnjl. vNeol..
[ LAansatlysCihsaMnegtheodd:: C1:/\8H/0F4CHEM\I\METHODS\10122:0450:33.91 pn
LC/MS analysis of perfluorooctancic acid.
-
WSO353EIG<36873857 (CHEN TORIESTAU iTdRO] AVES:
:
b1i6j
i:
sul1
NoSW, Frage Var
[] ==
[
| 2000
|
|| |
|=
Fo. 3 I : 5 |
"MSD 469, EIC=468.7:469.7 (CHEMSTOR\I 1338314A387648\FCO00AP0E1S6,.N0eg),SIM,Frag:Var
J wm 1
[1]
son 2000
[| =0
[7] oe
T0000
8018C10Sur 1
[
|
|
I 000o.l
|
- opment ome ows vx. i
| Seio"acSuirdrogat s1s3e3.90.a98
78.0203148 438565239699
`
w5 o
wSeDDIl 436699,. BBIICC--346688..77::346633..77
_ | ecooere
"+ EndofReport+ Thu, 6. Jam. 2004 03:15:51 pm
TTT
0035 Page 1 of 1
000115
[_sSeammplee Nmaitmoe::10001308-8
1
Data file :C:\HECHEM\1\DATA\Chemstor\11338477\A390656\FC000017.D
AIcnajeOcpteiroantoDarte +: j11u/i2l0l/e0r3 8:50:40 BM
vSieaqlLiNon.e ::
117
| pIintsuteruimoennt iPlCO041
mnj.i vNoe.l.
sul1
| Ahncga,lysMiesthoMdethod |+ sCc:a\-HrP0C.HuEM\L\METHODS\1120043
| eLarsetsCwhaangtetds of e1/s8t/i04orsscanec ac0c2.:45:39 pn
| - 10 ;a
7350 CHEN TORT5347
vaso7.07ca APLES, eg STFagVar
[p=
a
I "| -
|
00
I] w
i
| wif
| . HS 58,EXG=488374697 CHENSTOR ISBTGRGESSFGOo030T7.0) AP a,3 ST W.FrS a Var Po
| an
|
oe
[| wo
|
|
I" 10000.
|
n|e 5000
||
| copmns ome w2 orms wx4 . wen ss 0s sana
| SioaiSudrrogar a0b.s0.0op
87.021820 7226483157 SMDSDII 346699,, 2B1ICC--346688..77::346699..77
TTT
a of meport +e
| coosrs
Th, 8. Jan. 2004 03:17:16 pm
TTT 0036
Page 1 of 1
000116
Sarple Nane:L001308-10
I Sample Info:
1
"Data file :C:\HPCHEM\1\DATA\Chemstor\11338658\A393600\FC000018.D
[[7dIencjeictmiaontDeate :| i11n/d2i0e/s03 9:06:20
hseq etine:
18
[7 nSnoig,veavosrheomeethod Cr| eEaSnSceAtPoML\WETH1A O12D003S.\4
|. |
r 0000.
pd i
|
rl 0000
oon
=
|
ol
[7 . s ore oes2 s cmaron4 c 6 so8sc mi
[|7]| ao
soon an | 25000] I" 1w5o0s00]
8015+C10 Sumogat
| y5000-
| cpm roo war wr. meen
sional
["08 AcSidhon Shee 1266.20
Ti 7.244 fms 460236 mmMSD1 369, medmand EIC=368.7:369.7
|
| ==ssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssEssEEs
----
The, 8. dan. 2008 03:26:01 pm
rage orn 000117
--
ve Fite. EE TTAA BTACOS
r ee Injection Date ae : 11/20/03 9:21:59 PM
ra Seq Line
129
IE rRom EsorrS e r| Eevns sayBoA
|[RTC
|
Mw
SE
Tan cn
i
--
i
I~ 00.
!r[| l oI w> i a To 3 | |
"MSD1469, EIC=488.7:469.7 (CHEMSTOR\11338818\A395840FC000019.0) API-ES,Neg, SIM,Frag:Var
| 2000
I--
[| ew
[|
I
wn
m-o
T
comes roe wor xx we
Il
: FE si
-
| rmccccssssssssssssssssssscszssssssssssssssssssssssssssssssssssssssssssssss
~
| cooars
Thu, 8. Jan. 2004 03:19:17 pm
00338
Page 1 of 1
000118
|" _ SSaemrpplee Nnakmoe::STD 500 pob
:
! Data file :C:\HPCHEM\1\DATA\Chemstor\11339001\A398848\FC000020.D
hTIenodjaecoceptaiemoernnattoDrate |:+ B1mc1io/l02li0et/ra03 ~ Dilation i
9:37:33 2M
h SSeoq e eLi,ne : oven
sw201i
I Anaiyais Method | C:\MPCHEM\1\METHODS\1120043
rE
RT
02.4503 om
L/S analysts of perflucrocctanoic acid.
|-
ST EC<08873697CRESTORTROT HEIGFCETRo0o3 n07 APiE,SSH F.arar
I
|
[ ao
ao
|
Pe
|
-
|
SDT85 8831607CHENSTORT ROOT RECINE0 BT PTES, iog, SW. Fa VTir a
po.
som: eee
[=
[||| ww-t
I =on
||
|
|
|
~o
1
I
:
| compound _mmowne carr nr. aves
signa
| "610aScuirdrogat 554426..6138
78..020388 229045666140 MWSSDDII 346699., EEIICC--346688..77::436699..77
r
Tiinaof mepore tee
| eeonsrs
Thu, 8. Jan. 2006 03:20:06 pm
Page 1 of 1
000119
[saE rple E tame:Solvent blank
:
pata File <0: HRCHEHLL\ONTR\Chemstor\ LL335162\MOLSA\RCHO0021.
[[ Sfmonemeetcmuimiempnaetee :cTfR2i0e0e0 seer me mmEnaei eEO ad2%:
|I SET eaa | ErnoEmob1Ws1208Y\3.
I serns smatrasa of pesttussonssancte acie.
| EE
a
[| Z= [- IR0S7i
| a]
|| =
|" wd
|
|
SOT488,E6468 4687 CHEN TORY 338
[| =
|
7.238 C8.
AOSHAFOO0021 0A] PVoEg, SSW,Fi,Var
| we
I ---
[1] =
| comport sen warn wr
iyeee
BTaEn
Lid|
|
een
oan
uant gae me ene ne ag
co0414
a pent TTT
0040
Thu, 8. Jan. 2004
03:20:53 pm
Page 1 of 1
000120
Sample Name:L0001308-13
= Sample Info:
1
"bata file :C:\HECHEM\1\DATA\Chemstor\11339324\A404096\FC000022.D
HTIoonnajoeorcoptneieronanstoDrate :|+ SI1om1oi/0d2ai0te/sr03 10:08:33 BM HySeqaeLie.ne
gies i
Wve
| AhTeneaas,ltyCswhioastnngMoeeadthod &|+ Cr1:c/a8H-/Et0C4oH.EuN\1\METHODS\101222040530,38 pm
: 22a3 su
r
"WSO369,EIC=368.7:369.7 (CF
RT 1330324A4DIOIBFCO00022.0) APIES,Nog, SIM,Frag:Var |.
[| v0e
f|
[| oeI
om
[7] =
= | I" ==
7222-08,
I
SOT 5,EG 3ETCHEHTORS: RS RRFG7 Ro3c070) APTSTog: SWF Vr
| -som
8002. 010 Surg 1
||
| om
i
- ao
||
| 15000
ao
|!
!I~ oEd
[-orp
Sia
moore waIrms nr. : meen 3 J3
ols
Tana hen ses, siease nae
-
| acooara
ied ot Report san
Thu, 8. Jan. 2004 03:22:14 pm
Tem
004i
Page 1 of 1
000121
[mn
.
|I" AIcnqjoecpteiroantoDrate :: m11i/l2l0e/r03 10:24:08PX
vSieaqlLiNon.e :
2223
bre
1
------------ ---- ----------r
ol
w
[1] |
-
|
|
250.
II~|| . =|) =" ners |
"MSD1469, EIC=468.7:469.7 (CHEMSTOR1 1330485\A406464\FC000023.0) APNegI,S- IM,EFraSg:V,ar
[7] of
| 10000
ne. 2 5000.
| comport roe
| 28(0AcSiudrrogat04.0030.03
grr
wx.
08..000002
een
20 23526
|
signet
MMSSDD1 436699,, EEIICC-=436688..77::436699..77 -
NB
["coosze
"etEnd of Report er
ted
0042
sage ot 1
000122
Sarple Tame-L0001308-16
[ Sample Info:
1
Data file SC: \HPCHEM\L\DATA\Chemator\ LL33364T\MO940B\FC000024.D
DihTeuT e l NTVn ATR TH TA TE Tweae tela n?
He Hh
BE
sul
[seq
Lda
se otoiat it +|
rT CeoacetoE m LS$0. 055
on
[m TT CREOSPCraR PES SF | |e
[1
|
2000
[Mw
r=
I EE ETOT SA
r
[=
| ww
or
lo
-
2
4
3neSiiogae $a5n7
TTRiE Ehale
|
anorSFGTraFtiEenNS For
|
5
p=
RwenId vEe, HmiEenI. 7RiaeSn.d
= | scooars
[LE a Thu, 5. Jan. 2000 03:24:08 pm
0043 Page 1 ot 1
000123
a FT ----
:
bata File :C:\HPCHEN\L\NTA\Chenstor\ 11399761\AALISOR\RCO00025.D
|"
ipr srll Injection Date
Acq Operator
i: 11/20/03
: jmiller
10:55:20 PM
I Hoye o garme aewmsatt hod | sOSFieavmbeoaein LETHO1e120D0S3.S
[7 ems ane of poceisorosseante sc.
I TR TR CRETSaaER
|
roewl
wnee Seq Line :
Vial No. :
su22l454
on
RASNgPSEFSr
||A
IA w
rare.ca
I| =
r=
Fl ae | [|
rn 2 rsa ssor rr}versosra e8s
sor. croton
IHl --- ||
Il
[7]
I
|
I - oo
| .orpoms ome warm. 1
Frese
Tan
| 10 Surrogat 436.81
8.000
een
en
240538
1
1
po
sioner
in ve, ces wT
MSD1 469, EIC=468.7:469.7
| Tr -- | susssssssssssesssssssssssssssssssssssssssssssssssssssssassmsssassssmsasans
| evonse
0044
he, 8. gan. 2008 03:27:25 pm
A
000124
Sc arplek Nane:L0001308-19
.
NT --
I rdSoimpmp eesnne ae n |ET inNiit Sler I ET eweeeee
%x:
mm
Hho ed
|JAE vcq. Mrete haod | EFAEC8m Y-10.M eeerh
[sos mates of perersomossansc cia.
-
ES ITR TT
! =o
[a
[|
I wn
ra.00
Foe
Ee J
progiadn
[| |
|=
10000]
||
| Acopoma
soos wo7rms wm 1 een
ET
Tare
|
|
1
w7om =
we es Bene 760
| eoonna
Ipent
a
045
Tha, 6. can. 2006 03:37:42 pm
Page 1 ot 1
000125
[rsarapie Nane:10001308-20
:
Data file 1C:\WRCHEN\I\DNTAChanstor\ L1F3993T\ALTESIVECDONUZ7.D
sencteieocrnonDare Has"
fjAavneeess 1
mises
[mmserEviane l HE
suzl%
[1rSieirqraatwloesretvdaaagnets |+rESeNasRSonsWED 1H1200E3 3
[| serms smatyais of pestrsorsectaneic sci,
r EER
or seesvgswFv
w [lw
[|=J [w=
r= [es | 150. =
sreem manasks
sore. oo
[7] mod
[ | wo
|
|
|
=
|
| soo.
Fo. : 1 C 7 p
| emptor warn raven
signal
He
Sa
rr
oT
[--
"++ Endof Reporit+
The 6. Jan. 2008 03:30:71 pm
TTT
046 meiot
000126
[saE rple E Nane:sTD 500 ppb
:
Data file 1c:HRCHEH\L\DA1T1MAOA\O\CMZh0GeDRm\RsCOt00o01rS.\D
_
P seiiamn eDateIl{I JiaseI Br i
hmee T
2:
mL sul
[7 stoi. va oetrosm.ethod r| eEaastononWEmODS\1B1200R3, on
[7] ~ an A TT CRESTOR
rtR e E SF
[|: Joos| |
i= | o125n00.
Il 7500
| so00-
|.
r
|
|
1 omen
BA
|
|
1
|
CHET oOESRF FTES i oi orev
[ | a0
som
[7] oo
|
|
I!
[ srooms ms w2t ww a een 6
=
[0 rSiearene R34e15n2 TGEET Bhaene mwenisse, mmeeee Traea7
|
|" conse
Thu, 8. Jan. 2000
u047
03:39:13 pm
sage 1 of 1
000127
Sanpto aso:Sotvent Blank I" sDaatmapleEilIenfo:CI \IBCCHhEorI11N3401137\\A42S3616A\EaERBEN> 1 | El Injectionpate 11/20/03 11:57:31BM SHeqmLime i 293
I fr
E A nce, mR ovensen
+
rEestpo srono s iB2n 00A .
[1 R ims-amatysis of peT xtioroscransic acid. F 9 SF
|-
20:
|
20
| wr
NS
[oe
|
2"MSD 468,EIC=458.7:(4C6H9E.MS7TOR\11340137A4236161FC000020.0)
| | wo
[=
|=
Il 180.
APNogI, S- IM,EFraSg: V,ar
a
sigma
-
| coos
TTT EndofReport +o
Thu, 8. Jan. 2004 03:40:19 pm
TT
ub43 Page 1 of 1
000128
| Ssaanmppllee NIanfmoe::STD 50 ppb i Data file :C:\HECHEM\1\DATA\FC000030.D
[| AIcmqecOtpieornatoDrate :: 1j1m/i2l1l/e0r3 12:13:02 a Instrument : covata
vSieaql LNoi. ne nj. No.
I"_ Dsielnutimoanvvos +iisencznn
m3. vel.
I LAansatlyCshiasnMgeetdhod : C1:/\8/H0E4CHEM\I\METHODS\10122:0460:30.61 pm
LC/MS analysis of perfluorooctanoic acid.
I
SDT 355 EG-35873507 (FOO000000) AP Neg,SI W.FiS rVar
||
72. Co
--
i
|] =
| I.
|i
I~ so
1 301 sul1
i
[7] wo I iNSDOTT 48583 E1OC--4i5588 74486597((OFCoRoBRoEIDBDy] 50
I "-3
I 1500
1000
[| = oUsspminto wows amI r ame. 7
| 8"lo"AcSiudrrogac 1270..5775
870.020474
AAPeYsEStN,eog, SW,Fr
en
2290431259
Vgare
&
mi
80G010su7rog.ate
|
1
siz na
SSDDII 436699,, EEI1CC--436688..77::346699..77
TTT || cooara
Endof Repweoe rt
TT
Thu, 8. Jan. 2008
0049
04:33:53 pm
Page 1 of 1
000129
=
||" AIcnqjeocpteiroantoDrate i: sm11i/l2l1e/r03
[7 req. wortoa + ren-tom
.
12:28:34 AM vSieaqlL No. ime: 312
Et--
|
recs
[ "0
j
I w-n]
|
i"
|I
I
|
--oSR-- S
FR
=
1NUS
; Sh co--se -- |
|" =8000 |
-| -
I
| .
| sommes rar. en
wont
~
i| xco0a1a
TT
ena ot report wee
Thu, 8. Jan. 2004 04:38:25 pm
oT
wlbla Page 1 of 1
000130
SJ l Data file AC: \HPOHII\IAI\RCO00ISR.D
[| TM ATerdioespteiroantboarte:s JTmiaidteer ima BR
:
T Via wor T 3
HRA
sul
Aeivais veenod | Eon 1 weo11D200S3 30
OT --
- TTR FE ERSRE
U1 ae
720-8
[7] on
wo
I.
I "000.
| om
Fo.
[|
ren es ses
!
||J
80G010 S7uro.gat
I] en
|
| | ood
|-
I=
| dd
|
|
| corps ses tater ren
signat
Sen ra Taw iver mee ae, Eiceses Tie
~
| C0414
Thu, 8. Jan. 2004 04:38:54 pm
0051
Page 1 of 1
n00131
| SSaammmpliee Nzaakmoe::STMD 500 ppb
1
Data file :C:\HPCHEM\I\DATA\FCO00033.D
I seq seers + sesso | AIIcnnqsjteOrcputmeieronanttoD r a :: 1t 2m1Ci/ol2o1lae /er0ra3 12:59:38AM.
vSieaqlLKion.e : mi. Nel:
33i 1
.. Dilution
i
mil vel. :
EE
I ALnaasltysCihsanMgeetdhod :: C1:/\8H/0P4CHEM\L\HETHODS\10122:04063:.016 pm 10/4 analysis of pertluorooctanoic acid.
-
HOT ECT
FES:Nog, SFWir.Voarxy
| || so
10000
|" i |e
I.
|.
SOY458EIC-468 274687 (FCODORD] :APES. eg SWe FraVr h Tm
| aso
00100 u8rg-e
I
a
|
[7] sow0
| vend
[7] wed
|
| | om
i.
o 0 z I i
| somes swe wars
meen
signs
| 8"10"AcSiurdrogac s53d80.7775
871.020388 229032280845 uMsSbDlI 436699,, BEIICC--436688..77::436699..77
|
| 00414
CTT
endof Reportsav
Thu, 8. Jan. 2004 04:39:29 pm
TT
u052
Page 1 of 1
000132
Sanple Nane:STD 750 ppb
In Sample Info:
|" ESeosmteis d| i pe "Data file :C: \HPCHEM\1\DATA\FC000034.D
ene pak
[7 iseg amesheednon | setsrseoats wEmmons\112003.0
LHS analysis of perfluoraoctanois acid.
| ~ or EET 0
-.L roa.co
[[|1 om
on
-
| | 10000
Bl wl
[I
||
somo
24
"MSD1 469, EiC=468.7:460.7 (FC000034.0) API-ES, Neg, SIM,
wore.s
Frag: Var
cross
I] aw
|
1
TT 3
8me
NIl i. r wn
. I~EE
28 Acid
780.73
|
a
7.238
288762
6
si8gnal mi
MSD1 369, EIC=368.7:369.7
| | coonsa
J pra he, 8. dan. 2008 04:29:59 pm
we
U053 sage 108 2
000133
[_. SSaimpele sNekmae::STTM 1000 ppb
Data file :C:\HCHEM\1\DATA\FC000035.D
I req, menos + senso r AITcnnqgjterOcutpmieeonnrtDaattoer:: Cj1m10i/4l2l11e/4r03
~ Dilution
ir
1:30:48 AX
SveiqaLliNnoe. : Iinjl. vNeoll. |i
[ LAansatlysCihsangMeedthod : C1:/\8/H0E4CHEM\1\NETHODS\10122:0460:30.61 pm LC/MS analysis of perfluorooctanoic acid
-
WSDTI6 ECT
sanco
APeEg,SSW.F,iTg oVar
| | om
|
r he
2000
|
[ | 1500
| oom
Hn |
sao
|-
HST459, E0488z74697(FORGEEBS EY IAPTaSgS,W Fag ar
PE
| eno
| owed
: 35s su1
|
|
N
:
|
[| 10000
oli
| -compo ome coz m
| "810"AcSiudrrogat 11003334..7102
xx. T
871.020335
en
334748122655
J
5
si3gma
MmSsDDIl 346699,, EEIICc--346688..77:.346699..77
_ [
[ ceonea
+++ 2nd of Report ter
Thu, 8. Jan. 2006 04:40:31 pm
EE uib4a
Page 1 of 1
000134
[a Sample Name:57> 1500 pp
.
Data file -Co\HRCHEN\1\DATA\Chemstor\1336955\A3673360R2000036.
= oF eTchteCimoensp bate Tl miIeBET
[ EnCT ei
w!g
J[sEaegtEweomEnTeascnon |+ SSrlcesat10t0en wmmons\11B20E03S,0
L715 anaiysis of pexeluorcoctanic acid.
I] - | ag a -- = oS
I an (I
|= | i hi!
|
--- 7 7 3 I |- | "I
"MSD 469,EIC=488.7:469.7(CHEN TOR 13369851A367536C000036 5) APIES, Neg,SIM,Frag:Var
17] owmn! eso. 105m | | wom
|
| | i 40000-
|
[7] | an
|
-I Too. eg
omprund Shen
mous ares nn Sa
ees es
stant wan a em ie
|
:
[QS
RS hepa TIT Thu, 6. dan. 2008 03:30002 pe
oss rage 1 of 1
000135
E
I
eno
3058 Research Drive
State College, PA 16801
RESEARCH
Phone: 814-272-1039
Fax: 814-231-1580
[_ eLoSPrgruiobgnemeit#t:esdurBoy:ce
LP0O00001D340180 > 1,418 Michael. Aucoin
~ SLtoagtunsT:yps: UnIrmomceediivteedRecoefSiampplets
[7 sDittaorSet:art T111412003 84319AM
Dus Date 1172872003
I" RReecceeiivveedd BDya:te: A1M1/M1E4/R2M00A3N, MARK
~ SLapbreelad Sample:
[7 Frofct Tiere qu
PLoa gin Notes:
_CoomMotss:
[7 fer cue
tliDat Condition Packa
Promenz
Package sCunoaonnss Czenamrruoemmasd
| cComoanmoers c7r2o0swon p14
[CCooommm ae er772250
GoCaormamosss------r75255-
| PiceCoconhtsooeeesaessBIS772290
|[7 GGaomoens 11220s
CCooreonnsio----r7a20e
|" CmCooaeotseaasio------7r2a0z
Loess 120
{i CeCooevesneenssse----FR17T2200-
|" CGCoooomemmsea
vTaags 120
J
contooveerrioe OOvveerr oOvveerr Over oOvtvheeerrr oovveerr Oovveerr Oobveerr OOvbeerr oOOvtvheeerrr onveerr pOveedr
CCGooonnnfffooorrrmmmCCSOaOmCCp:lSea:mple: Gonform Request:
|ShCoinptpaeDirners Temp. Contol/ Temporst
83600re3v8e200702
r&r
prosNenoanteive
vig. Lot
NNoonnee
NNoonnee
None
NNNooOnnNeEe
NNoonvee
NNoonnee
NNNooonnneee
None
NNNoOonNrEee NNoonnee NNoonnee
TTTrrruueee: True
Direction HandledBy EreRcevenHARK
woo
I(mMisceaanroous | te
tLoignnainootes
Dusen = icoc
0056
Report VersioPn:agNeo1v01135.2003 451PM
re
000139
[IRIN
-
}
|
mmememn `Sample ID
00013080001
oCxE Matrix GAS|
cTiema Fraction
OVSTubes
Lmmoe Em ee
IG SS T SGiAmTe 93 SA
ee
m Lm O SSeR poentanen
LuLoS meodnsms 5DUS S2 vomevireeern
[[* L mLoocormsseE esmssere~ [mae
GG9Ga2tEs OGOVrSReTuvTbees SS
I SB T S Si
Samples
Sample
MWEONMSEMrKsSED ~~ WWK-A-AMSFBLK-E2A wmMeeemmoeos i evwmsraes e Twneeal myes eweesesascs wane oAarWWsaKAmAmsMSoeS-eEsmSS~ ouwmans
OO
Date SamDapte l Receeivded
hEedreniaA.tSell leaamen Ne C section
1/1312003
DateDue
Eiwmammse 1172872003
Tn e l soee
polll
fmicrelle=e
Lpielel
ae om
nc n l em 11132008 11/28/2003
n WwEs o a me
Login.mt
Page 20f5
0057
000137 (HITHNTE
= Bottles
[7 Looot308-0001
_ CootCgoar29t1aiOnmeerrNONE
Method
1L0001308-0002
r| consCsosnotraoimneerrnone
Method
[7~ L00013c0o8s-0a0s03
ore
CootdE3t Omer NONE
[" Looo130s-0004
|i coCrotntoamimneirnone
Method
L0001308-0005
| Co166C3o3nt/aOinrerINONE
Method
| 1L0001308-0006
r C0016CEo3n4taOinrerNONE
Method
L0001308-0007
CoConotarOitnhGeerr/aNOSNE
Method
1 -L00013c0o8-i00n08
eos
00156387Over / NONE
| Looo1308-0009
Container
Method
| C0019837/ Other NONE.
10001308-0010
| CootdCaoanataOimneerrNONE
Method
| "L0001308-0011
I 0016C8o3n8t7aGienerr NONE 10001308-0012
| Coane
| -Longwianomtos
Method
Method ul5o3
Report VersiPona:gNoov30131.52003 4:51PM
Instance: Ro072755
oco128 [jffRENNI
I wiomrone none
r L0001308-0013
CoContoaOivneetrr/NOeNE
f L0001308-0014
[~ C001C9o8n4t2a/Oithneerr NONE
1L0001308-0015
| 0019C8o4n3t1aOinerr NONE
|" ooot1308-0016
[| coCorntoainneer ne
1L0001308-0017
|i cooCronstaoimneerrnone
[Lonorsescota
cCoontanOimneetrr NOaNE
| L0001308-0019
Container
| CO016847 1 Other / NONE _L0001308-0020
| CootCeoenetaaionverr NONE
| "Looot30s-0021 | cmsmCoanrtaoinneerncne
L0001308-0022
[7 popootnaaOnameerrsNnON)E
| ~~L0001308-0023
i Container
| L0001308-0024
|" - conCoantaninermone
| - 1inanons
| ton
Method
Method
Method
Method Method
Method Method
Method
Method
Method
Method
Method 059
Report Version Nov 13.2000 4:51PM
rents
Instance: Ro072755
0c<139 [HRI
NN
" i r r r r [
I I
|
I
| |
| tLiopnamtn
loon
u06d
Report VersionP:agNeovS0113.52003 4:51PM cIcnsteansce:4e [IRMo0I72N755IN
- 3 Nb 2
Fr|
LE NEE
EEEEREE|S
|E E Flot A
Eps H
gl N
CoE
Oo
A3:TWN Eam||
EEPieeEieCiEiEe EEEEERlEglE1eRI2m
|
2
|[s:0
Z>|[HTaR|E[PeebenHlE (T34) RAElo
Ee
i=tff
"B
3 :
i: m
Sah alii aL Poles]
gm eee r
LR
O
gf vo
JR (uERmEnRnRniEsS
FE & El
H| L
i:sF
HEE
ike TT
RANE
3
r
ANLNiEl
Cee|Egw 8 | Qi 8 23 o EMEG
-
iN bE>|
&
BEEFETRER
Ei N
L z E|
fli: d
Bie gii: g
3
.
Re IHG r| iEENEERLEyL
oBe OER H
21 3 S :
Bi: Ss
i
`lig
'
32
rr
-
[een
Rk
=THR
es
ig B
cBE liiH Flite
i1hp B
o T H T r : 4f,iHE
3 38
G # E | Hom T
HIF &
UUs! 00014
Exygen |
rePrgovReneRaeclh,
o
[
Sample "Condition UponReceipt? Form
|
- ph 1 ey
Protocol #_
Tool) Seo tn
[
Exygen Study #
Mo (Jes
DeTin Reed --ah fils
Condition of Samples
Abe in
Temporary Storage Location
Dow, LS
|
Initials & Date
pH- 7)lo
Waybill #
FILS ge 2207
Comments:
teeitiog for rd ade _alyly
|
-
Vay 24,2003
|
Q:WORDprocess Jogi SampleCondiononReceipt doc
06s
amen,
000142.
conn
-
fg (HLT
Br
ng
i et To per iii
je T8385
i
EER b4EA Ri E IEEEfigE A[C 4l18 E Ii
Sig 5 2a BEL
i leg
1] A gh | spflat F2473) . i7 "A|
Cr RSH AE GE |I]oj B|WoEISLa0EyL 2EEgEa = n=| , | T 3 Ses 24] 4 HE i h= e
| &S| 2SAAAAT 1|3e34lo== d
|B
Ball dR =
000143