Document jDyjkn7LKOw1ondqBa2noVBQ

' c 1no VI C nnp! vA-h: CHLORINE. LIQUID r t V <5 e: 12/04/36 Date Pointed: !0/14/87 sae: MSD: /'01122 mGREDIENTS: Dh lorlne Nitrogen oxide CAS# 007782-50-5 CAS# 010102-44-0 67. 0.27. This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). In addition, other =ubstances not 'Hazardous' per this OSHA Standard may be listed. Where proprietary ingredient shows, the identity may be made available as provided in this standard. "HvgicAL DATA: SOILING POINT: -29.3F (-340 'Ap =-r.-^=z. 02 pig <d 6SF, 20C -'AR DENSITY: 2.49 & 32F,0C GOu. IN WATEF:: o.73g/10Og H20 (a 200 3P. GRAVITY: i.47 @ 32F, OC; 53.2 psia hF'PEARANCE: Amber color; liquified gas vaporizes to greenish - yellow gas. ODOR: Pungent odor. under pressure; FIRE AND EXPLOSION HAZARD DATA: FLASH POINT: METHOD USED: None Not applicable FLAMMABLE LIMITS LFL: Not applicable UFL: Not applicable EXTINGUISHING MEDIA: Chlorine will react or cause reducing materials to burn without oxygen. Water is effective only as a cooling media to reduce the reaction rate, however, water should not be applied directly to the chlorine leak. Where practical attempts should be made to reduce the available reactants through the isolation of the reaction from the chemical supply. This should be attempted only by properly trained personnel using prescribed protective equipment. FIRE EXPLOSION HAZARDS: May react to cause fire and/or axpioiion upon contact with many organic compounds, ammonia, hydrogen, or many metals, and with all metals, including steel, .-levazec temperatures. r IRE-FIGHTING EQUIF'MENT: A positive pressure self-contained breathing apparatus for respiratory protection and protective i4".rued on Page 2) indicates a trademark of The Dow Chemical Company D0 p confidential CHLORINE. LIQUID cue : C3@: ane: 12/04/St Date Pointed: 1 0'14/87 age: MSD: 001122 'iiBRE- I ENTS: -hlorine Nitrogen oxide CAS# 007782-50-5 99.67. CAS# 010102-44-0 0.27. This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). In addition, other -uostances not 'Hazardous' per this OSHA Standard may be listed. Where proprietary ingredient shows, the identity nay be made available as provided in this standard. -`"SICAL DATA: SOILING POINT: -29.3F (-340 ap : rc: g . 92 ssiq 71 63F, 20C -AF' DENS I TV: 2.49 @ 32F,0C :-- i IN WmTEP : o. /3g/10Og H20 (a 20C IP. GRAVITY: i.47 @ 32F, OC; 53.2 psia hPFEARANCE: famber color; ligui + ied gas vaporizes to greenish - yellow gas. ODOR: Pungent odor. under pressure; IRE AND EXPLOSION HAZARD DATA: FLASH POINT: METHOD USED: None Not applicable rLAMMABLE LIMITS -FL: Not applicable NFL: Not applicable EXTINGUISHING MEDIA: Chlorine will react or cause reducing materials to burn without oxygen. Water is effective only as a cooling media to reduce the reaction rate, however, water should not be applied directly to the chlorine leak. Where practical attempts should be made to reduce the available reactants through the isolation of the reaction from the chemical supply. This should be attempted only by properly trained personnel using prescribed protective equipment. FIRE b. EXF'LOSION HAZARDS: May react to cause fire and/or 3';piosion upon contact with many organic compounds, ammonia, hydrogen, or many metals, and with all metals, including steel, . - -itvacec temperatures. FIRE-FIGHTING EQUIPMENT: A positive pressure self-contained breathing apparatus for respiratory protection and protective irued on Page 2) ndicates a trademark of The Dow Chemical Company ___ DO A 061223 CONFIDENTIAL L:-," NAME : DHLD"' I NE , I C*!J I D c"1 ve Dare: 12/04/86 Date Printed: 10/14/87 MSD: ''01122 -~T-.E AND EXPLOSION HAZARD DA i A: ' CONTINUtD/ clothing. REACTIVITY DATA: STABILITY: ^CONDITIONS TO AVOID) materials including chemicals. Avoid proximity to -flammable INCOMPATIBILITY: (SPECIFIC MATERIALS compounds, ammonia, hydrogen, moist metals. May react explosively with centinement. TO AVOID) Many organic or hot steel, and many some organics under HAZARDOUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POLYMERIZATION: Will not occur. ENVIRONMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS/LEAKS: Move unprotected personnel cross-wind to a clear area. Do not use water directly on a chlorine leak. A tog nozzle may be used to absorb gas. The leak should be isolated or controlled by trained personnel using prescribed protective equipment. DISPOSAL METHOD: Prior to disposal, the active chlorine must be reduced or destroyed. Chlorine may be absorbed in dilute solutions o-f caustic <NaOH) , soda ash (Na2C03) , or hydrated lime (Ca(OH)2). Caustic and soda ash solutions should contain approximately 3 pounds per gallon, lime 1 pound per gallon, -for i pound chlorine. Local, municipal or state authorities should be contacted -for disposal o-f resultant product. HEALTH HAZARD DATA: EYE: May cause severe irritation with corneal injury which may result in permanent impairment o-f vision, even blindness. SKIN CONTACT: Short single exposure may cause severe skin burns. 2KIN ABSORPTION: The dermal LD50 has not been determined. NGEETION: Ingestion is unlikely due to physical state. INHALATION: A single brie-f (minutes) inhalation exposure to easily attainable concentrations may cause serious adverse tinned on Page 3) Indicates a trademark o+ The Dow Chemical Company DO A 061224 CONFIDENTIAL V *1 -'rcouc" .CG5- jAME: THLC^INE, '..I HU ID c vc"1ve Date: 12/04/86 Date Printed: 10/14/87 - kJ .44 I ioe: MSD: :>011 22 -"EE ihND EXPLOSION inAZAFD DATA: '-CONTINUED;' clothing. REACTIVITY DATA: STABILITY: (CONDITIONS TO AVOID) materials including chemicals. Avoid proximity to flammable INCOMPATIBILITY: (SPECIFIC MATERIALS compounds, ammonia, hydrogen, moist metals. May react explosively with centinement. TO AVOID) Many organic or hot steel, and many some organics under -AZAFDQUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POLYMERIZATION: Will not occur. ENVIRONMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SF'ILLS/LEAKS: Move unprotected personnel cross-wind to a clear area. Do not use water directly on a ( chlorine leak. A fog nozzle may be used to absorb gas. The leak should be isolated or controlled by trained personnel using prescribed protective equipment. DISF'OSAL METHOD: Prior to disposal, the active chlorine must be reduced or destroyed. Chlorine may be absorbed in dilute solutions of caustic (NaOH), soda ash (Na2C03), or hydrated lime (Ca(OH)2). Caustic and soda ash solutions should contain approximately 3 pounds per gallon, lime 1 pound per gallon, for i pound chiorine. Local, municipal or state authorities should be contacted for disposal of resultant product. HEALTH HAZARD DATA: EYE: May cause severe irritation with corneal injury which may result in permanent impairment of vision, even blindness. 2k IN CONTACT: Short single exposure may cause severe skin burns. SKIN ABSORPTION: The dermal LD50 has not been determined. NGEETION: Ingestion is unlikely due to physical state. INHALATION: A single brief (minutes) inhalation exposure to c easily attainable concentrations may cause serious adverse finued on Page 3) 11- . Indicates a trademark of The Dow Chemical Company A 061225 CONFIDENTIAL ow c a ' , ir , ^ d 1 an a. . c6"-' Emertsencv rh^ne: d 3 7 --"t76 --"i^OO RGDUC7 NAME: 'HuORTNE, LIQUID :,'?fluc:': Cede: 1&295 Page: 7 :ctive Date: 12/04/86 Date Printed: 10/14/87 MSD: 001122 HEALTH nACARD DATA: (CONTINUED) effects, even death. Excessive irritation to upper respiratory lung injury. The LC50 -for mice ppm tor 1 hour. exposure may cause severe tract and lungs and may cause was 137 ppm and -for rats 293 SYSTEMIC v OTHER EFFECTS: Excessive exposure may cause liver, lung and kidney effects, severe irritation to upper respiratory tract and lungs, and lung injury. Excessive exposure to chlorine gas has been known to also cause erosion of tooth enamel. No evidence has been found that chlorine is a carcinogen. Limited data suggests that chlorine is not teratogenic but may be slightly embryotoxic when administered at high doses in drinking water to pregnant rats. In animal studies, has been shown not to interfere with reproduct ion. Results of mutagenicity tests in animals have been negative. Has been shown to have mutagenic activity in bacteria. . FIRST AID: EYES: Immediate and continuous irrigation with flowing water for at least 70 minutes is imperative. Prompt medical consultation is essential. SKIN: Wash off in flowing water or shower. Remove contaminated clothing immediately and launder before reuse. INGESTION: No adverse effects anticipated by this route of exposure due to gaseous state. INHALATION: Remove to fresh air. If not breathing, give mouth-to-mouth resuscitation. If breathing is difficult, oxygen. Call a physician. give NOTE TO PHYSICIAN: If burn is present, treat as any thermal burn, after decontamination. Excellent warning properties .^ ... force rapid escape from chlorine gas; thus most inhalations are mild to moderate. If escape is not possible, ..exposure to high* concentrations for a very short time can result in dyspnea, hemoptysis and cyanosis with later complications being tracneooronchopneumonitis and pulmonary edema. Oxygen, intermittent positive pressure breathing and aerosolized droner.cai iators are of therapeutic value in the light to moderate inhalation. A severe inhalation should be hospitalized and treated as a respiratory emergency. Any chlorine inhalation in an individual with compromised pulmonary -4^ -r itinued on Page 4) n. Indicates a trademark of The Dow Chemical Company DO A 061226 CONFIDENTIAL V , .'Indiana. MI 'c6~T'1 ^^eraency Phone: 71 "76--<id-00 PRODUCT NAME: 'HuORTNE, LIQUID :>'cduc; Code: 16295 C c:tive Date: l2/04/86 Date Printed: 10/14/87 age! MSD: 001122 HcALiH nAIARD DATA: (CONTINUED) effects, even death. Excessive irrmtion co upper respiratory lung injury. The LC50 -for mice ppm tor 1 hour. exposure may cause severe tract and lungs and may cause was 137 ppm and -for rats 293 SYSTEMIC fy OTHER EFFECTS: Excessive exposure may cause liver, lung and kidney effects, severe irritation to upper respiratory tract and lungs, and lung injury. Excessive exposure to chlorine gas has been known to also cause erosion of tooth enamel. Mo evidence has been found that chlorine is a carcinogen. Limited data suggests that chlorine is not teratogenic but may be slightly embryotoxic when administered at high doses in drinking water to pregnant rats. In animal studies, has been shown not to interfere with reproduct ion. Results of mutagenicity tests in animals have been negative. Has been shown to have mutagenic activity in bacteria. 1 'i.T- - ~T. FIRST AID: EYES: Immediate and continuous irrigation with flowing water for C at least 70 minutes is imperative. is essential. Prompt medical consultation SKIN: Mash off in flowing water or shower. Remove contaminated clothing immediately and launder before reuse. INGESTION: No adverse effects anticipated by this route of exposure due to gaseous state. INHALATION: Remove to fresh air. If not breathing, give mouth-to-mouth resuscitation. If breathing is difficult, oxygen. Call a physician. .. give NOTE TO PHYSICIAN: If burn is present, treat as any thermal burn, after decontamination. Excellent warning properties force rapid escape from chlorine gas; thus most inhalations are mild to moderate. If escape is not- possible,.^exposure to hig>V concentrations for a very short time can result in dyspnea, hemoptysis and cyanosis with later complications being tracheooronchopneumonitis and pulmonary edema. Oxygen, intermittent positive pressure breathing and aerosolized droncr.odi 1 ators are of therapeutic value in the light to moderate inhalation. A severe inhalation should be hospitalized and treated as a respiratory emergency. Any chlorine inhalation in an individual with compromised pulmonary c inued on Page 4) ndicates a trademark of The Dow Chemical Company 00 A 061227 CONFIDENTIAL V 1 .Dew Chemical J.S.A. y|: m \ an d. "'ll Eitsf'cancv -'hone: ^l-7--636--t1"fl-,''0 ' 1 -`'oduct Zeds*. PRODUCT NAME: CHLORINE, -iCLJID c >ctive Date: 12/04/86 Date Printed: 10/14/87 :6295 -age: A MSD: 001122 PIRST AID: (CONTINUED) function (CORD) should be regarded as a severe inhalation and a respiratory emergency. 3. HANDLING PRECAUTIONS: EXPOSURE GUIDELINE (S): ACGIH TLV is 1 ppm TWA; the STEL is 3 ppm. The OSHA PEL is 1 ppm ceiling. VENTILATION: Control airborne concentrations below the exposure guideline. Use only with adequate ventilation. Local exhaust ventilation may be necessary -for some operations. Lethal concentrations may exist in areas with poor ventilation. RESPIRATORY PROTECTION: Atmospheric levels should be maintained Deiow the exposure guideline. When respiratory protection is required for certain operations, use an approved air-purifying respirator. SKIN PROTECTION: Use protective clothing impervious to this material. Selection of specific items such as gloves, boots, apron, or full-body suit will depend on operation. Safety shower should be located in immediate work area. Remove con taminated clothing immediately and launder before reuse. EYE PROTECTION: Use chemical goggles. If vapor exposure causes eye irritation, use a positive pressure full-face respirator. , Eye wash fountain should be located in immediate work area. 9 ADDITIONAL INFORMATION: - SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: No attempt should be made to handle or store chlorine without complete review of the chlorine manual, available from the Chlorine Institute, Inc., New York. r" a MSDS STATUS: Revised 2, 3, 5, 6, 7, and 8. 4 -i is 3?. >s Indicates a trademark of The Dow Chemical Company Information Herein Is Given In Good Faith, But No Warranty, 'ess Or Implied, Is Made. Consult The Dow Chemical Company Further Information. *--3 -y vjrr DO A 061228 CONFIDENTIAL V ew cal . 2. A. z ar,fD / J Emergency hc:na: ^ i"7--636-- PRODUCT NAME: CHLORINE, -lOLJID ;,,'oduct Code: 16295 :-age: 4 active Date: 12/04/86 Date Printed: 10/14/87 MSD: 001122 -IRS7 AID: (CONTINUED) function (CORD) should be regarded as a severe inhalation and a respiratory emergency. 3. HANDLING PRECAUTIONS: EXPOSURE GUIDELINE(S): ACGIH TLV is 1 ppm TWA; the STEL is 3 ppm. The OSHA PEL is 1 ppm ceiling. VENTILATION: Control airborne concentrations below the exposure guideline. Use only with adequate ventilation. Local exhaust ventilation may be necessary -for some operations. Lethal concentrations may exist in areas with poor ventilation. RESPIRATORY PROTECTION: Atmospheric levels should be maintained oeiow the exposure guideline. When respiratory protection is required -for certain operations, use an approved air--pur i-fy ing respirator. SKIN PROTECTION: Use protective clothing impervious to this material. Selection o-f specific items such as gloves, boots, apron, or full-body suit will depend on operation. Safety shower should be located in immediate work area. Remove con taminated clothing immediately and launder before reuse. EYE PROTECTION: Use chemical goggles. If vapor exposure causes eye irritation, use a positive pressure full-face respirator. Eye wash fountain should be located in immediate work area. ADDITIONAL INFORMATION: SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: No attempt should be made to handle or store chlorine without complete review of the chlorine manual, available frpm the Chlorine Institute, Inc., New York. T, a V MSDS STATUS: Revised 2, 3, 5, 6,r7, and 8. :<T ____jfr *jrv o-'r-V--,- ( Indicates a trademark of The Dow Chemical Company Information Herein Is Given In Good Faith, But No Warranty, fc.x, ress Or Implied, Is Made. Consult The Dow Chemical Company For Further Information. A 061229 CONFIDENTIAL