Document jBMvReYk0zeBVreBaDkBxeLXR

p0r* Approved 0MB fie. 4*-Rl 3S7 APprovil Expires: July 30, 1972 8.:. DEPABTOEHT Of 1*552 MATERIAL SAFETY DATA SHEET form No. OS1 Hiy, 1971 2i j 0 2. -" *---- A. SPCMXVLM 1---- I^L.1 LL-L-J ^ V -- - -------- _ _ U -A ------------------- --------1 UCT10M 1 g MONSANTO COMPANY ____________________________ M1U) Soil-: inn Nor^TlIlIfldbriFr^ouivVr^, St. Louia, Miaaocrl 63166 | . MlXT-\iT9__________ 1 M*ee aS itmwvmi I Aroeln- l?ti2 j `"ETftorlnated aromatic Mixture I l| ii _J 1 SECTION n S riaM. rl*VAfi*tV 4 MivtaM fUtwae) Cilil'T ixttT 4* rt4i.Lf eearaai um mr+ 44ton "~1 ~1 Vf<U lOivien *oe<Tfv(s Ots**f . MiTAujc cornua laii MVTA4 nuf OK CMI U/1 0TiM sjzTueci w tTHta leciat, a* wui I TUV SECTION HI PHYSICAL DATA MH.WC *o*t rvj _ f . 7 60 SB ------ -- 165-210*0 ] 4^oa MatrtT iaj4*ii Mecca-v,rv -i'f2,/25eC^ 3 SB rRrNvCOfWl \tMVOC<%ATTU nkt Irell iyP4Brieai UT| -------- m ___ kn.oit " 1. NAN W.1 . <1 SECTION IY FINE AND EXPLOSION HAZARD DATA D" CITiwQyitwi^ft m&A C.O.C. 196*C *m* 6tn - r-y r-< nr. --flrtl Sf.tr t--UatlliT!--12_ ripor or cases is possible: _______________________ lff^Jy^^^aTfsVrrbhlorldss and chlorine) can bs evolved In fires of this product. PRR 002794 A 0009407 WATER PCB-SD0000029164  /roclor 1221 SECTION V health HAZARO OATA :;oc Available - j>&01rrT:1 oIn the form of chloracnc, 3ysce^a::T~Trr^7^^ leads to nausea, vomiting, ToTS o: >.i*._ ft'wx ra * inn Pencvc ** ** from exnosura. ^^ Remove contaminated clothing. jr?~C--r, *L1 lt4l'-c Wj.w contact#*! arta with larpt amounts or wa:ir"lM Sfl,B n to physician. ami |T4tU SECTION VI REACTIVITY OATA luaeout Die owos.t.o oocn __ CO, ~4jA*OOUt 4f oecua mu *r oecua __ CO?, smoke, X soot, chlorides ar.d^jh'*< I ' SECTIQH VII SPILL OR LEAKK. PROCEDURES | > . m a m * > ^ *.i * i| Absorb on clav k >1 Mlw V * _. . a* ` "' :t material. ?lac in^j i drums. Bury in approved chemical landfill in accordance ui:--------`j I local and state peculations. 8p 4<UBurn114I rT an3approved incinerator in accordance with local and j state regulations. a i 5 .1 SECTION VIII SPECIAL PROTECTION INFORMATION iUpka'O** **uUC,C* *. oc" S'dretu of Mints approved recpirator for or nr. it Yes - for vapors C^ a arwTl . M*ea4*CM OtH - *- c.Ovii rubber tOw**'*** "f~ottc'.. ch,mlcli ecg^les 1 1 SECTION IX `ihk Jr 1 ' a S * a *y 1 ` L ^Avoid__skin and v fcn'.ict. | Avoid inhalation of vapors. > 0-C PHCawHOM SPECIAL PRECAUTIONS T . . _-- pea ocisci ; While the informtlcn and r ec onae nd a 11 on s set forth herein are to be accurate as of the date hereof. MONSANTO COMPANY MAKES WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE TV.-ah JAO:JiOH:J7C:WBP A 000940S WATER PCB-SD0000029165 # Monsanto material safety data OCCUPATIONAL CONTROL PROCEDURES Inhalation--Workplace exposure should be mamtainted balow m* OSHA ^w.hour , age Threshold Limn Value (TIVI. At room temperature*. me hazard of absent. Chemical cartridge reeoiretori or jh mas** oorov*d tar protection on*,Gs*es u_T'' rieoffimtad m me event of spills or tasks of hot fluid*. Thee# will provid* 9OO0 *oon * concentrations inown on me approval labels and me odor will give ampi# warning ,f itro,*ci,on ue t,, J? arnica. Self-contained breaming tooerttus mould ba worn wnan FCl's ara ancauni L* Threshold Limit Valua (TLVl---Chlorodioheoyl (42% chlorine) 1.0 mgreu.m. Chlorodipnerryl (54% cnionnel 0.5 mgicu.m. Sltin Contact--Avoid prolonged or repeated akin contact. Where amptoyaaa may coma into a wrtn PCI*a. protective clothing imoervioua PCI's mould ba wom. Glove*. boot*, ovarvioat ^ Co,>,ta apron* mat cover m* boot tops anould ba uaad wnan necessary. Thia protacttv* ouiom*n,n<S s'6"rr^ raguisrty inaoactad for defects and to anaura mat it is in dsan and satisfactory wonting eonditior/c*0"3 41 natad clothing, glovaa. ate., mould ba disposed of as praaenbad by regulations. SriUrs. Era Contag---Eye protscoon should ba uaad wnara mars is a possibility of liouid apiaah**. ingestion--tnoaation of m*aa material* is generally not a problam in industry. M ATERIAL SAFETY DATA M onSifltO PHYSIOLOGICAL EFFECTS SUMMARY: Stan Comag--Can ba absorbed through intaa akin. Local action on akin is aimilar to mat of common orgr* sotvams wna< comae leads to removal of natural fata and oils wtm subsequent drying and ersexing 3< bun. A potential exists for me contracting of ettioraen*. Eye Cornaa--The liquid products and their vaoors are moderately irritating to ays tissue*. ingestion--The acuta oral toxicitise of tha undihjtad compound* ara: natad. and 11.9 grrvkg for W% chlorinated "slightly toxic." rata--A56 gnvkg for 42% mien- Inhalation---Animal axpanmants of varying duration and at differ ant air concentrations snow that tar jim.i* exposure conditions, m* 55% cMonrvatad material produces mors liver injury man ma *2% ertionnstac material. Other--There are literature reoorts that PCX's can impair reproduction function in montaya. A study reoortsd m mj literature with famaia rata uaing Aroeior* 12*0 stated that A/odor 1250 caused liver cancers. Monsanto sponsored animal feeding studies of A/odor 1252.1255 and 1250. These com pounds, fad bom taxes of rats, did not produce cancers. Tho National Cancer institute performad a atudy in l*77-u*ingA/odori255wrtnDom saxaa of rets. NO ataasd trig the PCS. Arodor 1255 was not earonogemc under the condition* of tna* broaaaay. . Tha consistent flndhvg In animal studies with PCS'* is that they produca Irver injury tai^ashng prolonged ma reoastad sxpoaure by any routs, if tha exposure is of sufficient degree and duration. Uver injury >t produed first, and by ax&osures that ara leas than that alleged to causa cancer m rodents. Therefore, exposure ov ail routes should ba fcapt sufficiently low to pravem liver injury. FIRE PROTECTION INFORMATION Fire and Explosion--OMorodlpnenyle are assenoaiiy non-combuatibia compounds. They may dacomoosa i form CO. C0r HCl. phenol ice and aldanydaa under savers conditions such ta exposure to flame or not surfaces. No phosgene is formed. PR* 002017 X 0009410 WATER PCB-SD0000029166 M A II MIAI SAIT', t Y D A FA f ' i ! ! | : i j | j J I ; j Monsanto material safetv data3 ,,, RRE PROTECTION INFORMATION " " : fir* and Exptoaionr. PCBs art firs-rssistant compounds. They may decompose to form CO. CC?. ~Ci pntootica. awtnycts ana ome toxic comoustion products unaer severe conainons suen as txpesurt to flame or not surface*. ! ! 1 At tempeature* m tnt rang# of 600-650*C m tna presence at excess oxvgtn PC8s my form pofyentonnateo PiDenzofurans (PCDFs). Laooraiory studies uncer similar concitions navt atmonstrattc trial PCSa ao not prooocs poiycnionnatac cicencc-odioxins (PCDOs). ' PCS* in electrical tcuiomtnt have bttn reported to procuca Both emonnatte cicxirs (PCOOs) and furana (PCOFs) during hr* situation*. Tht* comoustion products -ay result all. or m part, from non-PC8 component* of th# aititctnc fiuias or ctner comouated m*t#nai*. Consult tn* equipment manufacture tor information regarding compoaioon of tn* aiet*ctnc fluids m eierrnr al apparatu*. ! Standard fir* hghting weanng apparel and s*ff<ontam#d breaming apparatus sncuid be worn wnen fighting firt* mat invotv* postal* exposure to chemical comoustion products. Firt fighting equipment snould 0* tnorougnfy d*an*d and decontammateo after uaa. If a PCS transforme is involved in a fir*-r*i*t*d incident. tn* owne of tn* transforme may 0* required to report tn* modem. Consult and follow approonat* federal. stata. and local regulations. --" REACTIVITY DATA________________ PCS* are vey staot*. fir*-f*si*tarrt compound*. HEALTH EFFECTS SUMMARY Skin Contacti PCS* can o aoaoro*d mrougn mtaa skm. Local action on sun is similar to mat of common organc *ofv*nts wne* comae; itads to removal of natural tats and oils witn suosepueit drying and cnoong of tn* skin. A potential exists tor tn* contracting of emoraen*. Eya Contact Th* liquid products and tn** vaoors ar* mooeatafy irntannq to *y* nssuts. Ingmetion: Th* acuts oral toacittaa at tn* undilut*d comoounds are: LO^ rat*--8.65 gm.kg for 42% emonnafd. and 11.9 gnvkg for 54% emonnateo--"siigntty toxic." - Inhalation: Animat experiment* of varying duration and at ditfeeit air cancelnations snow mat for smear txpoaur* conowon*. tn* 54% emormaud maieai products mort uve in jury than tn* 42% cf*onnat*d matanai. Other: The* ar* litsratur* reoorts that PCS* can uneair reoroductrv* functions m monseys. a study reported in tn* irteatur* with fenal* rats uamg Arooor' 1260 stated mat Arooor 1260 "v irrl live cancer. Monsanto soonsored ammai f**omg studi** of Aroctor 1242. 1254 and 1260. Th*** compounds. f*d to bom s*x** of rats, aid not oroouc* cancer Th* Nafione Cance insotuta p*rtorm*d a study m 1977 usmg Arodor 1254 with dotn him of r*tr NCI stat*d mat m* PCS. Arooor 1254. was not carcinogenic unde tn* conditions of mer p*oa**ay. m*wm .%crj Summary Corwnuetf On we*r Atgw PAR 00262** Polych'orlnated Biphenyls (PCBs) A 0009411 WATER PCB-SD0000029167 PACE 1 OF * Monsanto material safet/ data Standard rirw lighting waanng soparsl snd saif-contamad arsathmg sooaratus should Oa *orn wn#n fignung firs* mat involve poaaibJa axpoaura to cniorodipnanyit. Firs fighting aquipmant must s tnorougniy eiasnao *nd dacontammatad aftar um. PHYSICAL 0ATA TA8L1 I Prepaitlat of Soiactad Araaiort Colir IAPVIA) Physical star* Stability Dansity . iit>gai 25*0 , S pacific gravity to is.rc Oistillation rang# PC) Acidity mg KOHIg, maximum Firs point rci Viacoaity (ioo* iota -- moola od i r\*n 11.40 1.31-1.37 *-2r 3Z3-354 non# to boiling point 71-1 itn 100 mobtia oil inart 9*8 1.11-1.19 *-2r 275-320 .014 17g 31-41 izn 100 mobiia oil 10.58 1.27-1.2* *-2r 290-325 .014 231 44-81 1243 100 mobiia oil inft 11.50 1.30-13* *-2r 325-3*1 .015 non# to boiling point E2-82 1248 100 mobiia oil inart 12.04 1.40-1.41 s-r 340-375 .010 nona to boiling point 118-240 1284 100 vtacoui lCuid mart 12.52 12*0 150 Jtictv r*in inrr 13.50 1.48-1.50 *88* 388-3*0 - 155*1 58 *90* 385-420 .010 .014 nona to boiling point nona to ' soiling point 1400-2500 -- REACTIVITY DATA PCI's art vary stabia, flra-raanram compound*. Monsanto M ATER IAL SAFETY D A T A SPILL LEAK k DISPOSAL INFORMATION if PCI's iaak or art sptHsd. ma JoMmanng atop* ahould ba takan immadiatafy: AJI non ataarttiaf parsonnai ahouM laava ma Iaak or spill araa. Tha araa should ba adapuaaafy varttUatad to pravam ma accumulation of vapors. Tha soillrtaak should ba oontamad. Loaa to aawor syatama. navigsbla wsrcarwayt tnd-atraams should ba ptaxamad. SpMaftoaks should ba ramowd promptly by moans of absorptive matahal, such a sawdust. varmieuUta, dry sand, day. dirt or omac similar matanaia. or trappad and ramovad by pumping or otnar surtaOM maana (trap*, dhip pan*, trays. aseJ. Paraonnai antarlng ma soik or Iaak araa ahould b* (umtanad wrtti aporoprtata paraonal protactna aduipmant and doming aanaadad. Paraonnal trainad in ma amargancy procadura* and protactad againat m* attandant hazards should shut off souroaa of PCI's, daan up spills. control and repair laaka and ftgm Area In PCI area*. Alt wastaa and raaiduaa containing PCTa (a.*.. wiping dotha. adaerbant matariai. uaad diaooaaeia oro tacttvs giovaa. doming. me.) ahould ba eoilactad. piacad in prooar eomamtars. mamad and disooaad of in ma mannar praacribad by &A regulations (40 CFR 711). Various fadarai and stasa regulation* may raouira raoomng of PCI spills. Consult your srtomay or appropnata raguiartory official* for information raiaong to soiH reporting. PRK 002*i8 A 0009413 WATER PCB-SD0000029168 Monsanto St. Louis - Gaasral Offic* .... Uarch 17, 1969 ......... ... TO TO REGIONAL WATER QUALITY CONTROL BOARD Thair Uttar to you of March. 7 from Mr. Frad H. DUrkar : 3-H. S. Bergen - HBERG ^ About Aroclor used ia tha dieUctric area, we respond to itame ind 7 of Mr. OUrktr'a lattar as follow*: S, 6, 4) The solubility of Aroclor la tap w&tar at 25* C. i a* follows: Product Solubility la Water Aroclor 1242 203 t 10 ppm Aroclor 1249 106 t 14 ppm l Aroclor 1254 50 t 2 ppm Although tha solubility of Aroclor 1260 has aot baaa d*tarmiaad tha above data cartaialy serves to ladicata xbm mors highly chloriaatad Aroclor* such as 1260 ar* tha Uast solubla ia watar. Aeeordiagly, It Is quita reasonable to say that tha solubility of Aroclor 1260 ia watar would ba significantly lowar than 50 ppm. 5) Aroclor 1242 aad a small amount of Aroclor 1254 ars usad la ha rma tic ally saalad capacitors. Tha harm* tically saalad can construction is of aluminum, mild steal, aad staialass staaL Thasa capacitors era usad 1mbaddad ia asphalt la fluorascant lighting systama. Thay ar* usad for powar factor correction oa utility liaas. Thay are also usad as motor ra capacitors for air conditioning tystam*. Attached are tha specifications for Aroclors 1242, 1254, 1249, aad 1260, which describes tha physical properties of thasa materials. Aroclor 1260, sad to a Ussar axteat Aroclors 1242 aad 1254, are used as components in transformer fluids of tha askaral type. Ia gaaaraL the amount of Aroclor usad ia tha trans formers fluid ranges from 45 parcaat to 60 pereaat. PRR 004669 " i, A 0009415 WATER PCB-SD0000029169 H. S. Bergen, -2- March IT, 1969 On the West Cout La 1968, about 300, 000 pounds of Aroclor i contained in tha transformer askarel fluid used in that region to mutt trtaifarmi ri. These askarel truiforauri are also hermetically sealed, non-breathing apparatus. Very little of tha fluid is used to replace ipent fluid. Askarsl transformar failure that would require replacement of tha fluid is vary rare. Tor example, tha Edison Electric Institute found that tha incident of auch failure ia in tha raafa of 0. 05 percent. 6) No Aroclor capacitor* art mad* on tha Wait Coast. Traaaformar maaufacrur#r on tha Waat Coaat who hwi9ia Aroclor containing fluid include: Federal Pacific - Saata Clara, CaXonia Hill UagBatica - Radwood City, California H. K. Portar - Salim oat, California Sierra Transformer - Radwood City, California Spokana Transformer - Spokane, Washington 7) .' In tha aormal use of capacitor or transformer fluid / containing Aroclor, Monsanto advises tha capacitor transformer manufacturers to avoid breathing vapors that would be emitted from the fluid if it were heated to elevated temperatures. Monsanto also advises the user of the fluids to avoid continu ous contact with tha skin. If clothing becomes saturated* the workman is advised to launder it before wearing it again. If there has been spillage an the sldn* it should be removed by washing with soap and star. Normal* ordinary good housekseping practice is recommended. Normal ttration of the fluid as done in the electrical industry has not presented health hasard provided that ordinary normal cleanliness ia followed. PAR 00^870 A 0009416 WATER PCB-SD0000029170