Document gpa0MQRnjgZYVj1k4LgboGKL

OxyChem, ^.'ZC[ - 02-Q>0 MATERIAL SAFETY DATA SHEET MSDS NUMBER : M7732 MSDS DATE : 01-25-91 PRODUCT NAME : FLUOROLUBI? FS 5 24 HOUR EMERGENCY PHONE: (716) 278-7021 I. PRODUCT IDENTIFICATION HMIS HAZARD RATINGS HEALTH HAZARD 0 FIRE HAZARD 0 REACTIVITY 1 Based on -the National Paint & Coatings Association HMIS rat Ing system. This pi oduct is not an OSHA Hazardous material as defined In 29 CFR 1910.1200. SARA/TITLE III HAZARD CATEGORIES (See Section X) Immediate (ACUTE) Health: NO Delayed (Chronic) Health: NO Fire Hazard: NO Reactive Hazard: NO Sudden Release of Pressure: NO MANUFACTURER'S: NAME AND ADDRESS Occidental Chemical Corporation Customer Service. Occidental Tower, P 0 Box 809050. Dallas. Texas 75380 Telephone (1-800-752-5151) CHEMICAL NAME: ChlorotrIfluoroethylene Polymer SYNONYMS/COMMON NAMES: Fluorolube Oil CHEMICAL FORMULA: X-(CF2-CFCL)n-Y DOT PROPER SHIPPING NAME: NA DOT HA1ARD CLASS: NA DOT I.D. NUMBER: NA DOT HAZARDOUS SUBSTANCE: NA II. HEALTH HAZARD INFORMATION CAS NUMBER:. 9002-83-9 EMERGENCY AND FIRST AID PROCEDURES EYES: IMMEDIATELY flush eyes with a directed stream of water for at least 15 minutes. Forcibly hold eyelids apart to ensure complete irrigation of all eye and lid tissue. GET MEDICAL ATTENTION IF IRRITATION OCCURS. SKIN: Wash with soap'and water. DO A 061604 CONFIDENTIAL CAS cn*ici i ifiitraet |rv)e n%tmomr *0 M* relevant inf n*t ln fewnd or net available Ml )|M Mrnittitl* tiMtura libit C0P Cerperate Capeture libit U 1CS1M Thratneid Unit *alua, Currant la* Chranic tff*ct Infernal i*n NA Nat applicable tMao*r**t The internet fan pretence* herarrp waft# net pwarentaad, vat prepare* by ceapetant ttcfmu* I par fennel an* It true an* accurate It the bet at egr tn#vteae AO waa ean T t . Of euAfAN f v, draft* 0* tMPltfO 10 MAOI ffCAfOINO laroBMANCt. fTtiiiirr. of orMCftwitf tni* infenutien it net intenee* te be allnelutive at ta the banner end eendtttent a* use. "ana ime an* ttortg* Other fact*'! may tnveive ether r additional safety ar partamanca cant l der at I ant. While OCCIDENTAL CHEMICAL MSDS NUMBER: M7732 PRODUCT NAME: FLUOROLUBE FS 5 Page 2 of 6 01-25-91 II. HEALTH HAZARD INFORMATION (Continued) INHALATION: Got person out of contaminated area to fresh air. INGESTION: NEVER give anything by mouth to an unconscious person. If swallowed. DO NOT INDUCE VOMITING. Give large quantities of water. (If available, give several glasses of milk.) If vomiting occurs spontaneously, keep airway clear and give more water. SEEK MEDICAL ATTENTION IMMEDIATELY. ROUTES OF EXPOSURE INHALATION: No effects expected. SKIN: No skin effects expected. EYE CONTACT: May cause mild Irritation. * INGESTION: Practically non-toxic. EFFECTS OF OVEREXPOSURE ACUTE: May cause mild eye Irritation. CHRONIC: None known. TOXICOLOGY DATA: Acute Oral Toxicity LD50 (rat) Acute Dermal Toxicity LD50 (rabbit) Primary Skin Irritation (rabbit) Primary Eye Irritation (rabbit) " * > 10 g/kg >5 g/kg Mild Reversible Irritation Very slight Reversible Conjunctival Irritation New material is relatively non-toxic. Material In service may become contaminated with toxic foreign substances. Exposure of laboratory rats to high concentratIons of a chiorotrifluoroethylone (CTFE) polymer by either oral or inhalation administration has resulted In the development 'Jof signs of liver toxicity. Based upon the outcome of studies In primates, the liver toxicity appears to be specific to rodents and therefore, not relevant to man. .___ 00 A 06160^ CONFTDFNTTAL OCCIDENTAL CHEMICAL MSDS NUMBER: M7732 PRODUCT NAME: FLUOROLUBE FS 5 III. INGREDIENTS ' Pago 3 of 6 01-25-91 ^ CAS NUMBER / NAME 9002839 Ethane, chlorotr1fluoro-. homopolymer EXPOSURE LIMITS PEL*Not Established * TLV-Not Established PERCENTAGE VOL WT COMMON NAMES: Listed On(List Legend Below): 19 23 100 100 See Sect Ion I I All components of this product that are required to Inventory are listed on the Inventory. Not listed as carcinogen - IARC, NTP, be on 0SHA the TSCA LIST LEGEND 19 PA REQUIREMENT- 3% OR GREATER IV. FIRE AND EXPLOSION DATA 23 NJ REQUIREMENT- 1% OR GREATER FLASH POINT: NA AUTO IGNITION TEMPERATURE: NA i FLAMMABLE LIMITS IN AIR, X BY VOLUME- UPPER: NA LOWER: NA EXTINGUISHING MEDIA: Use agent suitable for surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: In fire conditions, wear NIOSH/MSHA approved positive pressure self-contained breathing apparatus and full protective equipment. .UNUSUAL FIRE AND EXPLOSION HAZARD: Fluorolubes decompose and depolymerlze above 500F. . Decomposition products may be toxic and hazardous. Avoid friction or gal 1ing and contact with aluminum or magnesium parts. Friction or galling can cause localized areas of instantaneously high pressure and temperature which may result in localized detonation. See also Section VII. V. SPECIAL PROTECTION VENTILATION REQUIREMENTS: Genera 1 room ventilation emlssion. plus local exhaust at points of SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY: Respiration protect ion is not required under normal use. EYE: Wear safety glasses with side shields (ANSI 87.1) GLOVES: Wear Impervious gloves. k DO A 061606 CONFIDENTIAL OCCIDENTAL CHEMICAL MSDS NUMBER: M7732 PRODUCT NAME: FLUOROLUBE FS 5 , Page 4 of 6 01-25-91 VI. PHYSICAL DATA BOILING POINT 0 760 mm Hq: Decomposes above 500F FREEZING POINT: -7515F <-6010C> VAPOR PRESSURE: 2.2nrn Hg 0 200F SPECIFIC GRAVITY (H20- 1) : SOLUBILITY IN H2O X BY WT: 1.87 at 100F Insoluble VAPOR DENSITY (Air-1): NA APPEARANCE AND ODOR: Clear, colorless oil pH r NA VII. REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY: Fluorolube has been known to detonate when used on aluminum fittings. Detonation can occur when Fluorolube Is allowed to contact aluminum in confined spaces under heavy loads or high pressure. This reaction will only occur when aluminum Is free of Its oxide coating. Friction, galling, or seizure can remove the oxide coating and expose fresh aluminium. The same type of reactions may occur with magnesium. Therefore, do not use Fluorolube for the lubrication of aluminum or magnesium parts. INCOMPATIBILITY: Reacts violently with sodium, potassium, fluorine. liquid chlorine trlfluoride. Do lubrication of aluminum or magnesium. amines. llpuid not use for HAZARDOUS DECOMPOSITION PRODUCTS: Decomposes when heated above 500F releasing hazardous decomposition products Including hydrogen fluoride, hydrogen chloride, chlorotrifluoroethylone and other toxic organic fluorine compounds. VIII. HANDLING AND STORAGE HANDLING AND STORAGE PRECAUTIONS: ' Keep containers tightly sealed to avoid contamination. Avoid conditions of galling or friction with aluminum or magnesium parts Including container closures. DO NOT REUSE THIS CONTAINER. Product residues may remain In this container. ' All labeled precautions MUST be observed. Dispose of container In a manner meeting government regulations. PRODUCT DISPOSAL. Product should be completely removed from this container. Material that cannot be used or chemically reprocessed should be disposed of In a manner meeting government regulatIons. DO A 061607 CONFIDENTIAL OCCIDENTAL CHEMICAL MSDS NUMBER: M7732 PRODUCT NAME: FLUOROLUBE FS 5 IX. ENVIRONMENTAL PROCEDURES s?' * Page 5 of 6 01-25-91 ^ 'Ax STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Wipe upFluorolube Oils or take up with absorbent material and place In marked containers for reclamation or disposal. WASTE DISPOSAL METHOD: Incinerate .In equipment designed to handle hydrogen chloride and hydrogen fluoride as products of combustion or submit to an approved chemical disposal service for disposal In accordance with government regulations. X. ADDITIONAL INFORMATION Fluorolube oils are not listed by chemical name or trade name nor Included In a general category as being regulated or listed as a substance In various acts or publications of Government agencies and Internatlonal organizations recognized as authorities In Identifying materials as actual, potential or suspected threats to human health and safety or the environment. Fluorolube Is a registered Trademark of Occidental Chemical Corporation. No exposure limits have been established for Fluorolube oils. This product Is not an OSHA hazardous material as defined In 29 CFR 1910.1200. To aid our customers In complying with regulatory requirements, SARA Title III hazard categories for this product are Indicated In Section I. If the word "YES" appears next to any category, this product may be reportable by you under the requirements of 40 CFR Part 370. Please consult those regulations for details. XL PREPARATION INFORMATION For additional Non-Emergency health, safety, or environmental Informat ion telephone (7 16) 286-3081, or write to> Occidental Chemical Corporation Product Stewardship Department Suite 400 360 Rainbow Boulevard South Niagara Falls, NY 14302 For Emergencies: 24 HOUR EMERGENCY PHONE: (716) 278-7021 This MSDS replaces MSDS No. M7732 dated 5/5/89. DO A 061608 C0NFIDFNTIAL OCCIDENTAL CHEMICAL MSDS NUMBER: M7732 PRODUCT NAME: FLUOROLUBE FS 5 ' Page 6 of 6-c 01-25-9 1^ - 4. WARNING LABEL INFORMATION Occidental Chemical Corporation ' Electrochemicals & Specialty Products Dallas, Texas 75062 In case of CHEMICAL EMERGENCIES - Call (716) 278-7021 (24 hours) This product Is not an OSHA hazardous material as defined In . 29 CFR 1910.1200. SIGNAL WORD: CAUTION STATEMENT OF HAZARDS: DO NOT USE FOR LUBRICATION OF . MAY CAUSE MILD EYE IRRITATION ALUMINUM OR MAGNESIUM PARTS INFORMATION REQUIRED BY FEDERAL, STATE OR LOCAL REGULATIONS: This product contains: CAS# NAME i 9002839 Ethene, oh1orotr1f1uoro-, homopolymer . HMIS RATING SYSTEM: HEALTH 0 FLAMMABILITY 0 REACTIVITY 1 FOR INDUSTRIAL USE ONLY For further informat Ion, Request OCC MSDS. LABEL 011M7732 DO A 061609 CONFTDFNTTAI