Document gd9kqRBEOX1pJmvnmwE2J6Oe

Eby SAR . CA 5. 4AE ne fanz it. y of Garfi.eld .FECEa S fcr t4ol1d3,Midd Av0e7026 2 0c-2 -2 RE ees REARTLS 5 SF pE oe L rm MICHAEL J. SFERRUZZO, C.P.W.M. CA BUREAU OF SAT DRINK Me4r 13) 546b -2200 To: Paul Smith From: Michael James Sferruzzo Garfield Water Superintendent Date: September 27, 2007 Subject: PFOA-PFOS Results Paul, here is the packet that I received from the lab. As per our telephone conversation .. Pedif Foi Michael James Sferruzzo Garfield Water Superintendent oer2sonsomors PWS ID NJ 0221001 SAMPLE POINT ID TP003015 Garfield Water Department Clieat Sample ID: GI KLWOUD PARK POMP STATION woe DTaotte-SaSammpplleed4.... : D0T9I/0065/003700-0080:140WDoartkeORredceexiv..e.:d:JE0A9/Z0N6I/A0A7 PrPreeppDBaattech..#.10+: 70295/51124/907 Aanaallyyssiies TDaitme.e.:. 0169:/4114/07 Dilution Factor: 1 Method. ~os DEN 10-0012 Matrix ATER `eeromseTen ron _ 0s0.e.0s04w20m5r RwearornTING mars 0o.l01s0 wwasnt. `1s3o6m1oapnrroen 1304 pros PrEeRcCoEvNT a52 RLaewciozsv.RY 0(50 -- 7200000) 8 DEP2.SDWB-000020 PWS ID NJ0221001 SAMPLE POINT ID TP003015 Garfield Water Department . Client Sample ID: G1 BUBIODBARKFONP STATIDOUNP me LDoatt-eSaSmupmlepl#e..d|..:: D073/I0050/30070-0080:140 WDoartke ORredceeriv.e.d...:: J0G9A/Z0N6I/A0E7 PPrreepp BDaatet..c.h ...:.: 07295/51124/907 AMaaaallyyssiiss DTaitee.l:: 1075:/1134/07 Dilution Pactor: 2 Method. ........ DEN -LC-0012 Matxix.........: WATER ePrAoRsETER ron R0e.s0u3u5r. loan RmERrORTING wars o0.l0o1i0s wwaesnt `1s3ucmesoaBnRrOs" 13ce vr05 RsaeccovaERY 535. Rpercoevyery ((5500 - 3200000 BIT erm -------------------- i i r--e--e--e--e---- 9 ey DEP2-SDWB-000021 PWS ID NJ0221001 `SAMPLE POINT ID TP003015 `SANPLE DUPLICATS FVALUTION REPORT C5lDieLnott-Staotmp4le...: DD7711006690330000-001 Work Order #...: JSGeAInNnLAeA -oSuP Matrix.......: WATER PrDaetpeDSaatmep.l.e.d.|..:+ 0099//0152//0077 08:40 RDeaatleysRiecaeiDvaetde.. .: 0099//0164//0077 rm gs DPirleuptiBoantchPac.t.o.r:: 17255149 Aoalysie Time..: 17:23 |Deane mPreosn EswueLre spmuspvLiIrCME wats 00..004209 ol0.o0s3s5 wawarftt moaiear Memon 211 ((00-2200)0 DbmEw -16u-c0o00122 `Ts3ucm4RoPoRAOTeR RECOVERY 303 pros RSEwCeOLVEER+Y_ RpoEpCLOIVoENRTYE_3 RECOVERY Lamrs a52 3565 s(o0 -- 220000)) 1 DEP2.SDWB-000022 ANALYTICAL REPORT SEVERN fomrTageR eknneeErtNsauTyet J -- STL -- PRONPFOS Analysis Lot#: D71060300 Michael Stermuzzo GGa4ra1fir3edlMd.aWantder0A7Dv0eep2t5. . Testamerca Denver oY hp ~PrGoajielctDeMRaunzazgoer September 24, 2007 DEP SOWB000023 Table Of Contents Standard Deliverables Report Contents pTeShrtesaCanofndhraiLrestdteernDdaenrdldihDveeeRreaglebrltCeposavacekrapsgge,eTahr rceopnosritderecd noemaple es llpages maid in hi Tobie of Contos ar etd + TaobfColnteents + Case Narrative + Executive Summar-y Detection Highlights Methods Summary + Method/Analyst Summary + Lot Sample Summary + Analytical Results + QC Data Association Summary + Chain-of-Custody `Total Number of Pages [ 1 DEP2.SDW-000024 Case Narrative 71080300 TestAmerica Denver utilizes USEPA approved methods in all analytical work. The samples pinreascecnotreddanincethwisitrheptohretmweetrheodansailnydziecdatfeodr. thDeilputairoanmfeatcetrosrslaisntdedfoonottnhoetemseatrheodpsrosviudmemdaornyepaacghe datasheet to assist in the interpretation of the resus. The results relate only to the samples in this report and meet all requirements of NELAC. All data have been reviewed for compliance with the laboratory QA/QC plan and have found to be compliant with laboratory protocols with any exceptions noted below. Please note that Non-Detect (ND) results have been evaluated down to the Method Detection Limit (MDL) and should be considered ND at the MDL. Unless otherwise noted, results for solids have been dry weight corrected. This report shall not be reproduced except in full, without the written approvalofthe laboratory. `Sample Arrival and Receipt The following report contains the analytical results for one sample received 9/6/07, according to documented sample acceptance procedures. The sample was received in good condition at a tteemmppeerraattuurree,onfo18s.t9orCa.geAtletmhpoeurgahtutrhee shaamspbleeewnadsefrienceedivfeord tohuetsseidaenatlhyetepsr.efeNroreodt2he6raCnomalies were encountered during sample receipt. Standards `Analytical standards were prepared using the acid form of the compound perfluorooctaanciicd (PFOA). PFOS is a commercial prepared and certified solution. Perfluoro-n-{1,2,3,4-"C.Joctanoic acid was introduced at the extraction step and was used as aninternal standard for quaniitation of PFOA. Perfluoro-1-[1,2,3,4-"C,Joctanatesulfonate was. introduced at the extraction step and was used as an intemal standard for quantitation of PFOS. `Sample Extraction and The samples presented Analysis in Ihis report were analyzed for the target analyte by TestAmerica Denver's SOP DEN-LC-0012A. aFonrd wiatitseerxstaramcptleedsuasi2n5g0somlLid aplhiaqusoetoefxteraaccthiosnetmepclheniisquaeciwdiitfihemdewtihthan1olmLconofdi6tNionHeCdICso1l8ution cartridges. Each sample is spiked with the internal standard, prior to extraction. After the sfianmalplveolius mpeasissberdoutghhrotutgoh 5thmeLcasritrnigdgme,etthhaenaonlalayntdesthaereexetlruatcetd iws iatnha4lymzLedofbymeLtCh/aMnSol/.MS.The Method QC The Method Samples Blank is processed reagent water spiked with surrogate and prepared with cach batch of20samples of the same matrix. The method blank was non-detect for the target analytes al the reporting limits. 2 DEP2-SDWB-000025. Each batch is prepared with a Laboratory Control Sample (LCS). The recoveries of two `concentration levels of Laboratory Control Samples were within control limits. The internal standard recovery for 13C4 PFOS in the mid-level LCS was below the lower control limit. No corrective action was necessary as the control limits for this intemal standard are stil being established. Analytical Comments The sample G1 ELMWOOD PARK PUMP STATION was analyzed in duplicate. The internal `standard it was in recovery control in for the 13C4 PFOS was below the lower control parent sample. No corrective action was limit in the necessary duplicate sample but as the control limits for this intemal standard are still being established. The RPD (relative percent difference) was outside control limits for the PFOS results. This may indicate some variability in this result. `The MSIMSD was performed on sample G1 ELMWOOD PARK PUMP STATION. The matrix spike and surrogate spike recoveries were in control. No other anomalies were observed. - 0s DEP2-SDWB-000026. EXECUTIVE SUMMARY - Detection Highlights D7x060300 enmawETER mESULT _ RpEmPaOrRtTING owts GL ELMWOOD PARK PUMP STATION 09/05/07 08:40 001 vros. 0.029 0.010 va/L PrOR 0.040 0.015 walt AwNeAmLoYnTICAL _ DEN -1C-0012 DEN -1C-0012 4 DEP2.SDWB-000027 METHODS SUMMARY 71050300 enRaETER. we/ws/us, pro References: ex Severn Trent Laboratores, Operating Procedure. Denver, MREBTLHYODTICAL DEN -1c-0012 Facility Standard MPERTEHPOADRATION 5s DEP2.SDWB-000028 METHOD / ANALYST SUMMARY 71060300 AuNeATLHYOTDICAL miaLyST DEN 1c 0012 Jaqueline Bonnett References: Dex Severn Trent Laboratores, Denver, Facility Standard Operating Procedure. AmALYST 003601 DEP2.SDWB-000029 SAMPLE SUMMARY 7060300 HO SAWPLEN CLIENT SAMPLE 1D J6AN 001 GI ELMWOOD PARK PUMP STATION NTOheTsEyS)d: eofoe pies ed ne rid oe lowes AD ina roa for ving vd unl sncae es. TRhen pfoortmultsienppcatr,rcieepin 0,orn doywehpboew .ocfooor,iy., ds,(8p, GR,0 Fi er proyectoert,ios, eg. snpLED sane bate Tine 09/05/07 08:40 2 DEP2-SDWB-000030 Garfield Water Department Client Sample ID: G1 KIMWOOD BARK PUMP STATION mic LDaotte-SaSammpplleed......:: D0I9I/00G50/30700-0080:140 WDaotrek ORercdeeirve.d....:: J0E9A/Z0N6/I0R7A PPrreepp DBaatet..c.h 4.. : 0792/51521/4097 AAnnaallyyssiiss DTaitme.e.:.: 0169:/4114/07 Dilution Factor: 1 Method.........: DEN -LC-0012 Matrix.........: WATER PARNETER Pprroos RESULT RLEPmORTING rs 00..002490 00.001150 uugg//LL s1u3CrsroGpArToE" 1304 pros PERCENT RE7COVERY s2 RECOVERY L(i50mit-s 2000 (50 - 200) - 0000000000008 DEP2-SDWB-000031 Garficld Water Department Client Sample ID: GI ELMWOOD PARK PUMP STATION DUP ec DLaotte-SSamapmlpele.d....:. D0791/00650/30070-0080:140 DWaotrek ROercdeeirved.....:: J0E9A/Z06N/I0A7B PPrreepp DBaattec..h......:.: 07295/51124/907 AAnnaallyyssiics DTaitne.e.:.: 0197/:1134/07 Dilution Factor: 1 Method.........: DEN -1C-0012 Matrix.........: WATER FPrAoRsNMETER PFOA R0E.S03U5LT 0.01 RuEPmORTING gars 00.001150 uuga//Ln `TSaucRsRorGAoTaE 1304 pros PERCENT `5R9ECOVERY 36 RECOVERY r(sio n-e 2000 (so - 200) NOTE(S) + 9 DEP2.SDWB-000032 SAMPLES 001 QC DATA ASSOCIATION SUMMARY 71060300 Sample Preparation and Analysis Control Numbers wATRIX ANMAETLHYOTDICAL WATER DEN -Lc-0012 BLAETACCHH # BRAETPCH 728549 ms RUNE 7255093 10 DEP2-SDWB-000033 METHOD BLANK REPORT oe CMlBieLnott-SLaotmpl#e...#:: DRIIITO1G200300000-143 Work Order f...: JGLXDLAA Analysis Date..: 09/14/07 PPrreepp BDaattec.h..#......:: 70295/51124/097 Dilution Factor: 1 PARAMETER PPrFoOsA REsuLT. RLEMPOTRTING uwrts mww 00.001105 uuga/lL surRoGATE. 113334 PPrFOOSA rREERCCOEVNETRY 6552 RLEaCmOeVsERY ((5500 -- 220000)) wwe. Matrix.........: WATER hnalysis Time..: 15:53 DveETNHO-DLC-0012 DEN -1C-0012 1 DEP2-SDWB-000034 LABORATORY CONTROL SAMPLE EVALUXTION REPORT moc CLlCiSenLtot-LSoatmp#l.e.f.:: DRI71I10200300000-145 Work Order #...: JELYDIAC Prep Date......: 09/12/07 Analysis Date..: 09/14/07 PDrielputBiaotnchFact.o.r.:: 71255189 Analysis Tine.: 16:09 Matrix.........: WATER PPrAoRnAMETER eros RPEECROCVEENRTY 1005 RLIEMCIOTVSERY ((309 -- 113200)0 MDEETNHO-D10-0012 DEN -1c-0012 `1S3UcRsROpGrAoTAE _ _ 130s FOS PREECROCVEENRTY 5ass RLEICMOIVTESR_Y _ ((5500 -- 220000)) CNOoTtEo(Sn)ve+rome oreenn 1 od oo10 1li es 12 DEP2-SDWB-000035 LABORATORY CONTROL SAMPLE DATA REPORT ie Client Lot #...: DII060300 Work Order ...: JELIDIAC PLrCeSpDLaott-eS.a.m.p.l.e.d:: R0791/11220/00700-149 Analysis Date..: 09/14/07 PDrielputBiaontcFhact.o.r.:: 17255149 Analysis Time:. 16:09 Matrix.........: WATER PPrAoRnAETER Pros spike 0M.2o00T 0.200 MEASURED w0.o217u og/zt.s 0.101 waft. eERCENT 1R0E9COVERY MDERTHO-D1.C-0012 0 DEN 16-0032 `TSaUcRsROGpArToEn. 13c4 pros RpEaCrOcVaNETRY ais. RLEmCMOIVTESRY ((5500 -- 2200000) CNOaTnEe(Ss)seperroong 0s fscd + Soocepee dcoolr -------------------- DEP2-SDWB-000036 LABORATORY CONTROL SAMPLE EVALUNTION RERORT mec CLlCiSenTtot-LSoatmp#l.e.d.:: DRI7I1O1G200300000-145 Work Order f...: JELXDIAD PPrreepp BDaattec.h..#......:: 7092/51521/4097 AAnnaallyyssiiss TDaitmee....:: 1069:/2154/07 Dilution Factor: 1 Matrix.........: WATER rPAoRnAMETER eros RPEECROCVEENTRY 110s3 RLIEMCIOTVSERY ((3790 -- 113200)) DMEETNHO-D1c-0017 DEN -Lc-0012 s13cu4 mBRFRoTE 134 pros PERERCCOEVNETRY s5o RLEICMOIVTESRY ((5500 -- 220000)7 NoTE(S) Colon vepermet oerin ld oofrs nd es 1 DEP2-SDWB-000037 LABORATORY CONTROL, SAMPLE DITA REPORT mic Client Lot #...: DII0G0300 Work Order f...: JELXDIAD LPCrSepLDoatt-eS.a.m.p.l.e.d:: R079T/1122/000700-149 Analysis Date..: 09/14/07 DPirleuptBioantcFhact.o.r.:: 17255149 hoalysis Time:. 16:25 Matrix.........: WATER `pPrAoRAnMETER Pros smeroxer oo.l0o2z000 MoEAwSUtRED 00..00223006 wuug/sL waft PREERCCOEVNETRY METHOD 110s3 DDEENN --11cC--00001122 `TSiUcReROGpAEToEA. 13c4 pros PERCENT R0ECOVERY s0 RECOVERY (L5i0mIT- S2000 (50 - 200) CNOTbE(Ss) +prior fore s_g 0 _ cea 15 DEP2-SDWB-000038 MATRIX SPIKE SAMPLE EVALUATION REPORT nec MLSot-LSoatm-pSlaempl#e...:: DDIIXT0000330000-001 Work Order #...: JEANIAC DParteep SDaamptleed.......:: 0099//1025//0077 08:40 ADantaelysRiesceiDavteed....:: 0095//0164//0077 Prep Batch ...: 7255139 Dilution Factor: 1 Mateix.........: WATER PARMETER Prroons PREECROCVEENRTY 103 r 130s e PFOA 1304 PROS NoTE(S)+ Cis prone lor Tn v0 Fo rr RLEmCMOIVTESRY 039 -- 115200)) vERCENT RE6COVERY 58 ed veTHOD DDEENN --LLCC--00001122 RECOVERY L(5o0t-s300) (50 - 200) -------------------------------- DEP2-SDWB-000039 MATRIX SPIKE SAMPLE DATA REPORT we LKoStlSoatm-pSlaempl#e.... DD7T1I00600330000-001 Work Order ...: JEAZNIAC DParteep SDaatmep.l.e.d......: 0055//0152//0077 03:40 DAnaatleysRiesceDiavteed...: 0035//0164//0077 DPirleuptpioantcFhacit.o.r.: 71 255149 Matrix.........c WNTER sbraon e bros sSaucmhmoaparToen Tics pros noms): JSawnoeNLTe wserx_s mMeersotwo wits 00.002450 00..115955 00..226005 uvga/nL sReerccoavneRy soe Rreecnovceery weTaon 9103 bbenn 115c--000m327 RLeacuorveery . (00 -- 2260007) _-- un DEP2.SDWB-000040 SAMPLE DUPLICATE EVALUATION REPORT nec CSlDieLnott-TSoatmpl.e..#:: DDI7I1006600330000-001 Date Sampled...: 03/05/07 08:40 PPrreepp DBaatcthe.#.....:: 0792/51521/3097 Dilution Factor: 1 Work Order 4...: JJE6AANnImAAAE Date Received..: 09/06/07 AAnnaallyyssiiss DTaitmee....:: 0179:/1134/07 --SDWUPP Matrix.......: WATER MS Run oot PPrAoRsMETER pron SRAEMSPULLET 0.0.00240 DRUEPSLUILCTATE UNITS 0.00.30548 wvaalllu ReD_ RELDIMIT METHOD 2115 ((00--2200)) DDEENN --LLc0--000011z7 TS3UcRaROGPAFTOEA RECOVERY 23c4 FOS RSEACMOPVLEERY _ RDEUCBOLVIECRAYTE_% RECOVERY LIMITS s72 3569 ((500 -- 220000)) 18 DEP2-SDWB-000041 61 3 (I Ho COFRLTTS } i r rr rr r | SF Fe -- 1 adCII: rrr A | BE rrr rrrrrr ERY DET prBE=E | |S3 Bl: || mH m HsB--EE--S--I 1a N HEENRSY |e ETT e TT of| SS3.hE9e4Yd8 SE EEE EE B3 EEhk SLEiNeS | CE E EE 0 A _ QiSE C cr o i SU i F She 3sf EE i S L = FEE E EE RA aS|S i: 3 x Ee i of 3 i is3) of |1 | IgyEalddla, Ji|iin 2B8 1S3YE eFirfaans BERGE HH SSS% <8E:hSpEaht | 3 | a 11H ai a 3 Iii:e LD3Sp 3 aIol1Ea91||5E a it S 3 i HElk vee?owe000042 i|= 3i 3 g 2 | i i i;S S ; a H ih _ | S -- a = H fi E 2 AE 2 l 3} Ww I 3 ; ; = r i 5i N 2) \E'f ri T 4} ga: di of i Foe: fh ie t y g : i i o i : s | = | s 1 | HiH 0 q Hr ! yl o ii a 3, i I;Hn Ji i J a t g Oo h l Hh i : 3 5 i l 3 i E S$ 14 d i 53 d 2J i gl ] o0 aJ ls i i | = 012 , Ho i aUs is 8 iiH 8 Ji f 13 5 13 i Ho Fi i SL o a us