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G C / M S d e f a u l t file G 0 169 ::A4 MS data file header from : >G0169 Sample: 2UL UT-3115 Operator: GARY MS2 11/09/84 16:5 2 . Misc : SP2330 2 0 0 - 1/ 3 / 25O GT BT L#21 B T L #21 S y s . #: 1 MS model: 87 SW /H W rev.: CA ALS it : 8 Method file: SP2330 Tuning file: R P E I 01 No. of e x t r a records: 2 Source temp.: 250 Analyzer temp.: 265 T r a n s f e r line temp. : 2 6 5 -.--- * Chr Ctfiiat oor aph ic t em p ra tu re s : 2 0 0 . 2 5 0 . 0 . 0 . 0 . Chromt ographi c t imes , min. : 1 .0 25.0 6.6 0.0 0.0 C h r o m t ographic r at e , de g/ m in : 3.0 0.0 6.0 0.0 0.0 M/Z = 3 3 3 .S First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent sk im me d c o r r e c t e d area. Peak R. T. f irst m in . sc an max scan 1as t peak sc an wi dt h raw area corr. area corr. y. 1 12.244 245 250 257 o 12.44 245 250 257 12 63725 12 63725 41333 37763 100.00 91.36 M/Z = 331.9 First peak is b a s e l i n e drop c o r r e c t e d area. Seco nd peak is tangent s k im me d c o r r e c t e d area. P e ak * R.T. f ir s t m in . scan max sc an 1ast p e ak sc an w id t h raw area corr. area corr. * 1 12.244 24 6 256 256 12.244 246 250 256 10 54 3 7 6 10 54376 33996 31331 100.00 9 2 . 16 332/334 CALCULATION R-GlobaK 6) = .3225 n/" 32? g First peak is b a s e l i n e drop c o r r e c t e d area. Seco nd peak is ta ng en t s k i m m e d c o r r e c t e d area. P e*ak * R.T. fi rst min.. sc an max 1ast p e ak sc an - sc an w idt h r aw are a 1 12.264 246 251 257 2 12.264 246 251 257 11 46609 11 46 6 0 9 M/Z = 321.9 First pe ak is b a s e l i n e drop c orrec t ed area. Second peak is tangent s k i m m e d c o r r e c t e d area. Peak ft R.T. fi rst m in . sc an m ax sc an 1ast p e ak sc an wi dt h raw area 1 12.264 247 251 255 2 12.264 247 251 255 8 13966 8 13966 nnAcj^ c orr. area 30010 .26446 corr. y. 160.00 8 3 . 12 corri are' a 3630 2726 corr. * 100.00 89.97 Cl0961 S M/Z => 3 1 ?. 9 First, p e ak is b a s e l i n e drop corrected area. S e c o n d pe a k is t a n g e n t s k i m m e d c o r r e c t e d area. ak R. T. first max 1ast peak tf min. scan scan scan width raw area 1 -12.264 250 251 53 3 7490 2 12.264 250 251 253 3 7490 > Goi corr. area 2051 1985 corr. * 100.00 96,78 31-0/322 C R L C UL AT IOK R - Globali 1> = . 7 6 9 M/2 = 257.0 First peak is b a s e l i n e drop c o r r e c t e d area. S e c o n d peak is t a ng en t s k i m m e d c o r r e c t e d area. P ak # R.T. f irst min. sc an m ax sc an 1ast peak scan width raw area 1 12.264 250 251 252 2 7371 2 12.264 250 251 252 2 7371 c orr. area 2613 2512 corr. >: 100.00 9 6 . 13 <320 + 322)/<332 + 334) CALCULATION P-Gl obal < 3 ) = .0675 <328">/<332 + 334) CALCULATION R-GlobaK 3) = .3980 . V L ...i d - - -* T nrv^trc* C10962 o u* o ir> PJ \ co c0o5 U1 pj cso C\O T-l \ N -* I 1I o PJ Vo0 CO coo co PJ Cpu) CQO oPLJ CCCCMOOL O LI* u> Cl \ CO \ I CO CLPLOJ co \0 v co CO 1I In CO co 3 CO 33 cXI i) ' 05 *r '0 o CccOoo 05 CO CO jj I I co o co CO PI CO I- o I- I- H fH iji o Ci* oc* 11 vC* CO l 3 U 'o PPII CO t Ob* PJ CO I- T-i Li* US data file header from >G0 170 S amp 1e; 2UL. U T - 3 1 16 Operator: GRRY MS2 11/09x84 17: L7 Mfsc : SP2330 200-1/3x250 GT ETLK23BTLH23 Sys. #: 1 MS model; 87 SW/HU rev.; Cfi RLS # : 0 Method file: SP2330 Tuning file: RPEI01 Mo. of extra records: 2 Source temp.: 250 Analyzer temp. : 265 Transfe r line temp. : ? Chroma to gr ap hi c t em pe ra tu re s : 200. - 250. 0. 0. 0 C hir o m at o gr ap h ic times, min. : 1.0 25.0 O.0 0.0 0. C h r o m a t o g r aphi c rate, deg/min: 3.0 0.0 0.0 0.0 0. tU Z = 333. 9 First peak is baseline drop c o r r e c t e d area. S e c o n d peak is tangent skimmed corr ec te d area. Pe ak ft R. T. f irst min. scan max sc an 1ast peak sc an width raw area corr. area corr. y. 1 12.31G 251 256 261 2 12.310 251 256 261 10 54708 19 54708 41748 36103 100.00 86.48 n/z = 331.9 First peak is b as 1ine drop corrected area. Second p e'ak is tangnt skimmed coreected area. Pe ak # R. T. fi rst min. sc an max sc an 1as t p eak sc an width r aw area corr. area corr. y. 1 12.310 251 256 261 12.310 251 256 261 10 45680 32990 100.00 10 45688 28725 87.07 332/334 CALCULATION R - G l o b a l < 0> = .7962 M/Z = 327.9 First peak is ba se li ne drop c o r r e c t e d area. S e c o n d peak is tangent sk im me d c o r r e c t e d area. P e ak * R. T. first min. sc an max sc an 1ast peak sc an width raw ar 'a 1 12.330 2 12. 330 24 7 257 247 257 261 261 14 4 8 86 3 14 4 8S63 M/2 = 321.9 First peak is bas e line drop c o r r e c t e d ar ea. Sec ond peak is t ang ent skim me d c o r r e c t e d area. Peak # R. T. first m in . scan inax sc an 1ast pe ak scan width r aw area 1 0. 060 262 6 261 -1 0. 000 262 0 261 -1 - O N E ] L D H N l 1 A JS U B J E C T T O ?QriTtV'T*n /r* L nno 6.1. 0 0 c orr. ar e a 2 9 i'c>< 23488 c or9j,r. 100.00 78.91 c orr. area 1273 1273 corr. *4 100.00 100.00 C10964 s M/Z = Fi rs t pe ak is b a s e l i n e drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. R. T. Fi rst min. sc an max sc an 1ast peak sc an u i-dt h r aui area 0.000 0. O00 262 262 0 261 0 261 -1 -1 0 0 C Oil D corr. area 1252 1252 corr. vt 100.00 100,00 328/322 CALCULATION ' R - G l o b a l < 1> = .9835 M/Z = 257.0 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Pe ak # R.T. f irst m in . sc an fiax scan 1ast peak scan u idth raw area 1 0. 000 2 0.000 262 262 0 261 0 261 -1 -1 0 0 corr. area 1557 1557 corr. Ji 100.00 100.00 (320 + 322)/(332 +334) CALCULATION R--L 1o b a l ( 3 v = .03 33 (328')/(332 + 334) CALCULATION R - G 1 o b a l < 3) = .3981 L J C10965 F i l e > 0 0 1 7 1 333 .o M ,6 stillU LUL U T -31 17 :-:P2 330 2 0 0 - 1/ 3 2 5 0 C-T File File File >06171 321.6 6 ElITiU 2UL UT-3117 SP2330 200-1/3/250 GT File File c m `n ? i C10966 MS dti file header from > G 0 171 Sample: 2UL UT-3117 Operator: GARY MS2 11x09x84 17:37. Mise : SP2330 200-1x3x256 GT BTL#25 BTL#25 Sys. #: 1 MS model: 87- SUxHW rev.: Cfl ALS # : 0 Method file: SP2330 Tuning file: APEI01 Ho. of extra records: 2 Source temp.: 250 Analyzer temp.: 265 Transfer line temp. : 265*--'- * 'r Chromat ographi c temperatures : 200. 250. 0. 0. 0. Chrom atograph ic t imes f min. : 1.0 25. 0 0.0 0.0 0.0 Chromat ograph ic rat e , deg/min : 3.0 0.0 0.0 0.0 0.0 MxZ = 333.9 F irst pt ak is base 1ine drop corree t ed area. Second peak is tangent skimmed corrected area. Pcak # R T . fi rst min. scan m ax scan 1as t peak scan width raw area corr. area corr. V. 1 12.471 259 264 270 11 52682 35794 100.00 2 12.471 259 264 270 11 52602 30305 84.67 HxZ = 331.9 F irst peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. fi rst m in . sc an max sc an 1ast peak sc an width raw area corr. area corr. 1 12.471 261 254 270 2 12.471 261 264 270 9 43322 g 43322 29237 26222 106.00 89.53 332x334 CALCULATION R-Global< 0> = .8182 HxZ = 327.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Pe ak tt R.T. f irst min. scan m ax sc an 1ast peak fc an width raw area 1 12.491 266 265 271 2 12.491 25G 265 271 11 40316 11 40316 M/Z = 321.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Pe ak * R.T. f irst min. sc an max sc an 1ast peak sc an width raw area 1 12.511 263 266 270 2 12.511 263 256 270 7 11639 7 11639 Q f l D le v--r y * nn64 corr. area 25994 22617 corr. 160.00 87.01 corr. area 2651 2392 corr . 100.00 90.23 ,_ C10967 S M-'-'Z - SIS1.? First p ak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. fi rst min. sc an max scan 1ast peak sc an ui dth raw area 1 r 12.491 64 265 266 2 4832 2 12.491 64 65 266 2 4832 Gon I corr. area 1814 1689 corr. 108.30 93. 11 320/322 CALCULATION R-GlobalC 1) = .6843 M/Z = 257.0 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak tf R. T. fi rst rrtin . sc an max scan 1ast peak sc an width raw area 1 12.531 264 267 26S 4 9999 12.531 64 267 268 4 9999 corr. area 2243 22 corr. * 100.00 99.73 <32G + 322)/C332 +334) CALCULATION R - G 1o b a l < 3) - .0586 <3280/(332 + 334) CALCULATION R-Global< 3) = .3990 CONFIDENTIAL SUBJECT TO PROTECTIVE ORDER nn ^ 5 C10968 Fi 1* `r 1T 3 33 3 .0 - 334.6 lTiU 2 UL .2 5 0 3 / .48/.20 S P 2330 2 0 0 - 1/3/250 &T. . File >G'O173 321.6-322.8 aniu.iUL .2503/.48/.26 SP233Q 200-1/3/250 GT SU BJECT TO P R O T F C n v r r>or\iTT> C10969 MS dat a file header from : > G 0 173 Sample: 2UL .2503/.4S/.20 Operator: GARY MS2 1 l/09/84~l-7r5S~ Misc : SP2330 200-1/3/250 GT BTL#29BTL#29 Sys. #: 1 MS model : 87 SW/HW r e v . : CA ALS # : 8 Method file: SP233G Tuning file: APEIG1 Ho. of extr a records: Source temp.: 250 Analyzer temp.: 265 Tran sfer li ne temp. : Chromatographi c temperatures : 200. 250. 0. 0. 0. Chromat ograph ic t iKies, min. : 1.0 25.0 0.0 0. 0 0.0 Chiromatog r aph ic rate, deg/min: 3.0 0.0 0. 0 0.0 0.0 M/Z = 333.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R. T. f irst max last peak (iiin . scan scan sc an width rau area corr. area corr. 4 1 1G.936 178 1S8 205 27 95808 59655 100.00 2 10.936 178 188 205 27 95808 58062 97.33 M/Z = 331.9 F irs-t peak is baseline drop corrected area. Second peak is tan gent sk immed correc ted area. Peak * R. T. fi rst max 1ast p ak m in . scan sc an scan w idt h rau area corr. area corr. y. 1 10.936 1S3 188 200 17 691 85 45606 160.00 . 2 10.936 133 1SS 200 17 69185 43073 94.45 332/334 CALCULATION R - G l o b & K 0) = .7645 M/Z = 327.9 First peak is baseline drop corrected area. Sec ond peak is t argent s k i m m e d c o r r e c t e d area. Peak # R. T. first min. scan max sc an 1as- 1 peak scan width raw ar e a corr. area 1 10.956 183 189 203 28 69961 41921 2 10.956 183 189 203 20 69961 39711 M/2 = 321.9 Fi rst peak is base 1 ine drop c o r r e c t e d area. Second peak is t angent s k i m m e d c o r r e c t e d area* Peak # R.T. first min. sc an m sx s c an 1ast pe ak sc an wi dt h raw - area corr. are a 1 10.956 184 189 196 12 38607 22143 2 10.956 184 189 196 12 38067 20871 corr. yt 100.00 94.73 corr. 4 100.00 94.26 co n fid en tial SUBJECT TO PROTECTIVE n p ^ T 010970 S n/Z ~ 3_1__9_._9 Fi-rst pe a k is b a s e l i n e drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak R.T. f irst min. scan max sc an 1ast peak sc an u i*dth raw area 1 r, 10.956 184 189 201 2 1G.956 184 189 201 17 40214 17 40214 > rO |1 ^ corr. area 17842 16 966 corr, * 100.00 95.09 320/322 CALCULATION R - G 1o b a l < 15 = .8058 M/Z = 57.0 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Pe ak # R.T. f irst min. sc an max scan 1ast peak sc an width raw area 1 10.956 185 189 193 2 10.956 185 189 193 8 22858 8 22850 c orr. area 9396 8498 corr. 4 108.00 85.86 <320 + 322>/<332 +3345 CALCULATION R - G 1o b a l < 3) = .3799 <328'>/<332 + 334 5 CALCULATION R - G l o b a l ( 35 = .3964 TTPt SU BJECT TO PROTECTIVE ORnER. nnAp^ Cl0971 Fil 'G 0 174 3 33 .6 - 3 34 .6 m u 2U L 2.5 8 3 / .43 / .2 0 3 P2330 230-1 3/250..GT.. File 10 0 0 0 - i v e-f i i . I 1 1 1 1 1 1 > 1 1 1 1 1 ) 1 1 1 1 | < I ' ) I < i v-f-110.0 10.5 11.0 11.5 12.0 12.5 13.0 13.5 _1l4i.01 ' 1114i.5> i >115i.0 File > G 01 74 321.6-322.6 am u. SU L 2 .5 0 3 / .4 8 / . 20 SP2330 280-1/3/258 GT CONFIDENTIAL SUBJECT TO PROTECTIVE ORDER*. * - -9 C10972 flS d a t a f i l e h e a d e r f r o m > G 0 1 7 4 Samp 1ej 2UL 2.503/. 48/. 20 Operator: GARY HS2 11/09/84 -!-3r Misc : SP2330 200-1/3/250 GT B T L # 4 1B T L 4 4 1 Sys, #: 1 MS model : 87 SW/HU r e v . : CA RLS # : 0 Method file: SP2330 Tuning file: R P E 101 Ho. of extra records: Source temp.: 250 Analyzer temp.: 265 Transfer 1ine temp. .Chrom at ograph ic temperat-ures : 200. 250. 0 . 0. 0 . Chromatographi c t im e s i min. : 1.0 25. 0 0.0 0.0 0.0 Chromat ographi c rate, deg/min: 3. O 0.0 0.0 0.0 0.0 1/Z = 333.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak * R. T. fi rst min. sc an max sc an 1ast peak sc an width raw area corr. area corr. * 1 12.552 260 268 278 18 98047 76015 100.00 12.552 260 268 278 18 98047 71083 93.51 M/Z = 331.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected are a. Peak # R. T. fi rst m it*i. sc an max scan 1ast peak sc an width raw area corr. area corr. * 1 12.552 260 268 285 25 92933 61233 100.00 2 12.552 260 268 285 25 92933 59658 97.43 332/334 CALCULATION R - G 1obalC 0> = .8055 M/Z = 327.9 First peak is baseline drop corrected area. Second peak is tan gent skimmed corrected area. Peak if R.T. fi rst min. sc an max sc an 1ast peak scan width raw ar e a 1 12.572 262 269 282 -20 81762 2 12.572 262 269 282 20 1762 M/Z = 321.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. f irst min. scan max sc an last peak scan width raw area 1 12.572 259 269 289 2 12.572 259 269 289 30 334113 30 334113 S H R IFYV T n Dornv/Turr corr. area 57102 54482 corr. `4 160.08 95.41 corr. area 298113 287268 corr, * 100.00 96.36 C10973 First peak is baseline drop cor rected area. Second peak is tangent skimmed corrected area. Peak * R. T. f irst min. scan max s can 1as t peak sc an u i-dth raw area 1 .-11|J f 258 269 2S4 2 12.572 258 269 284 26 248367 26 248367 >Qron'i corr. area 217141 206078 corr. * 100.00 94.91 320^'322 CALCULAT IOH R - G l o b a K 1) = .7284 IVZ = 257.0 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. tk R.T. first max 1ast peak min. sc an scan sc an ui dth rau area 1 12.572 259 269 285 2 12.572 259 269 285 26 156236 26 15 623 6 corr. area 119342 114285 corr. 100.00 95.76 <320 + 322)/<332 +334) CALCULATION R - G l o b a l < 3) = 3.7542 <328 y)/< 332 + 334) CALCULATION R - G 1o b a l < 3) = .3965 AA SUBJECT TO PROTECTIVE ORDER. nnr^>I G10974 File G O 175 333.5-234 . kniu. 2UL 25.03^ .43/.20 SP232Q 200-1/3/250 ...GT ... File GO 1 i:1.6-322. fftu UL 25.03/.48/.20 EP2330 200-1/3/250... GT.. CONFIDENTIAL SUBJECT TO PROTECTIVE ORDER. C10975 MS data file header from : >G0175 Sample: 2UL 25.03/.48/.20 Operator: GARY MS2 11/09/84 >8:39*-- Misc : SP2330 200-1/3/250 GT BTL#43BTL#43 Sys. #: 1 MS model: 87 SU/HW rev. : CA ALS 1* : 0 Method file: SP2330 Tuning filer RPEI01 No. of extra records: 2 Source temp.: 250 Analyzer temp.: 265 Transfer line temp. : 265---*- Chroma tographi c temperat ures : 200. 250. 0. 0. 0. Chromat ograph ic t im e s , min. : 1.0 25.0 0.0 0.0 0. 0 Chromatographi c rate, deg/min : 3.0 0.0 0.0 0.0 0.0 M/Z = 333. 9 F irst peak is baseline drop corrected area. Second peak is t argent skimmed corrected area. Peak # R. T. f irst min. scan max scan 1ast peak scan width raw area corr. area corr. * 1 12.754 272 278 281 2 12.754 272 278 281 9 58015 46495 100.00 9 58015 38048 81.83 M/Z = 331.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. f irst min. scan max sc an 1ast pe ak sc an width raw ar ea corr. area corr. ym 1 12.754 272 278 281 2 12.754 272 278 231 9 48899 9 43399 37883 30611 100.00 80.80 332/334 CALCULATION R-Giobal< 0> = .8148 M/2 9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. P eak '# R.T. f irst min. scan max scan 1as t peak sc an width raw area 1 12.774 273 279 282 2 12.774 273 279 282 9 58142 9 58142 M/Z = 321.9 F irst peak is baseline cJrop corrected area. Second peak is tangent skimmed corrected ar-ea Peak # R.T. fi rst min. sc an max sc an 1ast peak sc an width raw area 1 12.774 269 279 282 2 12.774 269 279 2S2 13 1736753 13 1736753 c orr, ar ea 46883 39143 corr. are a 1721712 1282312 corr. 4` 100.00 83.49 corr. '4 100.00 74.51 ,_ C10976 M/Z = 3 1 9 . 9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak * R. T. first min. scan max ' last peak scan scan width raw area 1 ^ 12.774 270 279 2S2 2 12.774 270 279 282 12 - 1267934 12 1267934 corr. area 1253342 948926 oI corr. y. 100.00 75.71 320/32 2 CALCULATION R-Global< 1) = .7280 tl/Z = 257. 0 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak R.T. fi rst min. scan max scan last peak scan width raw area 1 12.774 270 279 282 2 12.774 270 279 282 12 707015 12 707015 corr. area 691091 517709 corr. 'A 100.00 74,91 <320 + 32 2 )/ <332 +334) CfLCULRT ION R-Global< 3> = 35.2586 <323')/<332 + 334) CALCULATION R-Glo b a l < 3) = .3720 SUBJECT TO PROTECTIVE ORDER, C10977 li .; ir \ i i Le h i'*iTMr i " o n ; m 13 .(v,o ie : 2 U l nJ Ut/./ . 2 0 nisc 582330 200-1/3/250 Ooerator : kOt .BTLtfOS BL.V nb l 1.' 05/ 8 * ij. v;s. if i ri5 model: 97 5>4/HU rev. : CA Ai_y. * t) Hethod t u e : SP253G lun ina file: APtii No. o+ extra r-ecoras Source temp.= 2S0 Analyzer Te np. 0 Transfer Line temp. : (j Chropia t ograph ic temp er at ur es 0. Chromatographic t i n e s , nin. 0. 0 Chromatographic rate, deg/min : 0. 0 0. 0. 0 0. 0 0. 0. 0 0. 0 0. (i . 0 Q. o 0 o. a G. 0 \ 33 9 f i r s t peak is b a s e lin e droD c o rre c te d a re a . Second peak i s tan ge nt skimmed c o r r e c t e d a r e a . Pea k T K .1 . f i r s t min . scan max last scan . scan peak width raw area c orr . area corr . i 12.335 'j i 2 . 3 3 5 249 249 255 255 267 267 IS 4 2 8 0 7 9 18 428079 iW 1 5 i y 375528 i0 0 .0 0 93.4 5 !'t 3 a i 9 r ' r-?t peak i s b a s e l i n e drop co rre cte d area. Second peak i s tangent skimmed c o r r e c t e d a rea k . r . first min . sca n ma x scan last peak scan wl dt h raw area corn . area c or r 12.335 249 255 266 2. 33 5 2*+9 255 266 17 350343 30394* 10 0 . 0 0 17 350343 30 1986 ?/ . 78 .jZls .>34 i-AuCULAT ION R-GlobalC 0) = .SOYS n ~ 327 .7 first pea k is ba s e l i n e drop corrected area. Second peak is tangent skimmed corrected area. Peak =tf k .7. first min . s c a n ma x scan last peak scan width raw area i 12.355 ~_D 12.355 2S 0 250 256 256 267 267 17 40 9322 i 7 409322 ri Z ~ 5 2 1 . 9 f i r s t p e a k l s b a s e i i n e d r op c o r r e c t e d a r e a . Second pe a k i s tangent skimmed c o r r e c t e d area Peak * K .T . first min . scan max scan last peak scan width 1 12.355 251 256 269 j 12.355 251 256 2 6 ? w co n fid en tial 18 ' raw area 135239 135239 corr . area 36c 48> 3582i i c or r . 1DU . 00 97.74 corn . area 8 8 04 w* 87584 c or r . i l' 0 . 0 0 99.48 010978 n ' ^ iv V rir'sT p e a k is b a s e l i n e d r o p c o r r e c t e d area, becond peak is tangent sk i n n e d co rr ec te d area. Peak * k .T. first nin . scan na x scan last peak scan width raw area 1 12.355 2 i2.355 25 0 2S0 2S6 25 267 267 17 117128 i7 ii7i2t c or r . area 71755 69783 c or r . V 100.00 97.25 320/322 CALCULATION R - G l o b a 1 <. i> = .8150 n * L = 25 V .*) Frir c t peak is b a s e l i n e drop co rr e c t e d area. Second peak is tangent skinned corrected area. Peak * K .T . first nin. scan na x scan last peak scan width raw area 1 12.355 252 256 264 2 12.355 252 256 264 12 85928 12 85928 c orr . area 424 04 38954 c orr . 10 0 .0 0 91.86 *32U + 3 2 2 ) / (3o2 + 3 3 4 ) C A L C U L A T I O N R -Globali 3) - .2315 328''./* 32 + 334) C A L C U L A T I O N k - G l o b a l >! 3) - .5297 i jLflj SUBJECT TO PROTECTIVE ORDER C10979 Tile- > B 31 14 333 .-3 54 .3 /tuj.-'-L UT-304I SP2330 200-1^3^259 GT BT File > B 311 4 321.6-322.6 mu.^UL UT-3041 SP2330 2OO-l/3.'50 GT BT CONFIDENTIAL SUBJECT TO PROTTrm /r rtohcrs nnripyry G10980 i-i9- o i t i 1 j i.a n j a y r t r o n >83114 S a n l e iJL U - 3 0 4 1 Opera tor; KOY nS i i / 0 5 /id'4 1 :0 0 hi SC : S P 2 33 0 20 0- 1/3/250 GT BTL*3i BTL+31 Svs. : l rib n o d e l : 8 7 S W / H W r e v . C A A L S * : 0 Method file: SP2330 Toning file: APEI01 No. of extra records: 2 So uree t e n p . : 25 U Ana 1yisr tenp .= 0 Transfer line tenp . 0 Chronatographic tenperatures : 0 . Ch.r o n a t o g ra ph ic t m e s , nin . : 0 .0 C h r o n a t o g r a p h i c rate., deg/nin : 0 .0 0. 0.0 0 .0 0. 0.0 0.0 . 0.0 0.0 0. 0 .0 .0 rl'7. - 33 4.9 First p e a K is b a s e l i n e croo co rr ec te d area . Second peak is tangent skinnea correc te d area . Peak 4 ti .T . first ni n. scan nax scan last pea k scan w id th raw area c orr . area corr . X 1 12.354 250 256 268 2 2.354 25 256 268 8 242036 18 242U36 1976& 9295 10 0. 0 97.61 it' - 531.9 F m s t peak is baseline drop corrected a r e a . Second peak is tangent skinned corrected area. Peak 4 i< .T . f ir s t nin . scan nax scan last peak scan width raw area corr . area c or r . i 12.354 250 256 266 12.354 250 256 266 16 200080 i6 200080 160080 iS 69 12 10 0 0 98.02 532/334 CALCULA ION R-G'ioba 1 \ 0) = ii ~ ;-27" 9 .8099 CONFIDENTtat' Sa,ECTTCp^ ^ . Firr-t pPiK is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent sk in ne d co r r e c t e d area. Peak 4 K .T. first nin . scan na x scan last peak scan width raw area corr area c or r . 1 12.375 251 257 268 3 12.375 25i 257 268 17 23 3202 17 233202 it8 b /3 S38S9 i0 0 .0 0 97.60 A I - 3 2 1. 9 Firs t peak is ba se li ne dr1op cor rec ted area . Second peak is tangent skinned cor rec tea area . C10981 Peak K .T . first nin . scan na x scan last peak scan width raw area corr . area corr . A* 1 12.375 254 257 264 12.375 254 2S7 264 10 36043 10 36043 10543 9313 i0 0 . 88.33 P , / , -, 31^ * f i.r *:` p e a k is b a s e l i n e 'drop cor ree ted area . bee ond peak is tangent skinned c o r r e c t e d area. Peak * R .T . first r u n . scan na x scan last peak scan width raw area i i2.375 2 i 2_. 375 253 253 257 257 264 264 il 3 7 1 4 9 ii 37149 c or r . area 9308 8466 corn. /M i o .o u 90.95 320/322 CALCULATION R - G l o b a 1( i> _ .8829 n/2 " 257.0 ri r st peak is b a s e l i n e dro p c o r r e c t e d area . Second peak is tangent s k i n n e d c o r r e c t e d a r e a . Peak * i<.1 . first nin . scan na x scan last peak scan width raw area 1 12.375 2 12.375 252 252 257 257 260 260 8 35813 8 35813 corr . area 6421 6 1 2i corr . X 100.00 95.33 *320 + 322>/ (52 +,534) C A L C U L A T I O N R-GlobalC 3) = .0555 (328 ' '/ (332 + 334 ) C A L C U L A T I O N R-G o d a 1( 3; ~ .5263 SU BJECT TO PROTECTIVE ORDER. C10982 Pli* B 3 1 15 33 3 .6 -- 34 .6 Tiu .--IJL U T - 342 2 P 2330 2 0 0 - 1/3/253 GT BT File >E 3 115 321.6-322.6 amu.2UL UT-3042 SP2330 200-1/3/250 GT BT confidential SUBJECT TO PROTECTIVE ORDER, nnr^ 80 C10983 n S *.ia t :a i i le h e a d e r t r o n >Bi i5 fannie: 2UL UT-3042 Operator ; ROY rIS ii/05/34 hisc SP233Q 200-1/3/250 GT BTL*33 BTL*33 bos. t : i NS nodel t 87 SU/HW rev : CA ALS $ : 0 Method file: SP2330 Tuning f ile = APEIOi No . of extra ree oras- S o u r c e t e n p . ! 250 A n a l y z e r t e m p .: 0 Transfer line tenp . i Chromatographic temperatures 0. C K r o n a t o a r a p h i c t i m e s , m i n . : 0 .0 C h r o m a t o g r a p h i c rate, deg/min = 0 .0 0. 0.0 . 0 .0 0. a .0 o .o 0. 0.0 o .o 0 O.i a. M/ Z = 3 3 3 . ? First pea k is b a s e l i n e arop corrected area. S econd peak is tangent skinned c o r r ected area. Peak R .T. first min . scan 1 12.354 3 12.354 250 250 Ma x last scan scan 256 266 2S 266 peak width 16 16 raw area 154401 15440 i corr . area 115793 i13657 cor"/n . i0 0 .00 98.16 ri/I - 331. ? First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent skinned c o r r e c t e d area. Peak * ft .T. first min . scan na x scan last peak scan width raw area corr . area corr . A 1 12.354 250 256 265 d. 12.354 250 256 265 15 128678 15 i23678 91898 9 0413 l0 0 .0 0 98 .38 332/334 CALCULATION R - G l oba 1 ( 0) =r .7 9 3 6 h/Z ~ 32/.9 First peak is b a s e l i n e SUBJECT TO PD.-..-P-T1..' `t l ^ " V'lcv.ii/a ORDER. drop corrected area . Second peak is tangent skinned co r r e c t e d area . Peak * K.T. first min . scan na x scan last peak scan width raw area corn . area corr* . X 1 12.375 "3 12. 3 7 5 H/I = 32i.9 252 252- 257 257 265 265 13 147887 113554 i 0 0 .0 0 13 i47887 109524 96.45 First peak i s Daselin e drop corrected area . Second peak is tangent skinned cor r e c t e d area Pea k # ft .T. first min . scan i 12.375 "3 1 2 . 3 7 5 253 253 ma x scan 257 257 last peak scan width 262 262 9 9 raw area 367975 367975 corr . are a 331687 31343? corr- . /* ( 10 0, 00 94.50 n/ 3 j. / .V Fi r s t p e a k is b a s e l i n e droo corrected area. Second peak is tangent skinned corr ec te d area. Pea k * K .T . f irs t n i n . scan nax scan last peak scan width raw area 1 12.375 3 12.375 253 253 257 257 262 262 9 305215 9 305215 P 3 3 ! 5 corr . area 271699 257753 corr. X 10 0. 00 94.87 520/322 CALCULATION R - G I o b a 1 < i) = .8191 ri/2 = 2 5 7 . 0 First peak is baseline drop corrected area. Second peak is tangent skinned corrected area. Peak * K .T. f i r s t nin . scan 1 12.375 2 12.375 254 254 nax scan 257 257 last scan 262 262 peak width a 3 raw area 195226 9S226 corr . area 157882 150626 corr . X 100.00 95.4 0 (320 + 322)/<332 +334) CALCULATION R - G i o b a K 3) = 2.9052 .323*') / ( 3 3 2 + 334) C A L C U L A T I O N R -Glo b a l i 3) - .5324 `'-l 4 j.*&O r i l A 1 SUBJECT TO PaOTECTVE ORDER. C l I'1O C ' ' C10985 333 . - S 3*. amu.-UL U T -3043 P 2330 2 0 0 - 1/ 3 -'50 ST File >B3116 321.6-322.6 amu.SUL UT-3043 SP2330 200-1/3/250 GT BT d 100000H 50000-3 O-P 10.0 _____ ___ .s" 11`.0 __A ________ r 1 1 ' ' 'I ' ' 11.5 12.0 13.0 OPOG*? J-.S. -i CBJECT TO PROTECTIVE ORDER. 13.5 14.0 14.5 1S.0 C10986 Fi r s t p e a k is b a s e l i n e drop corrected area. S e c o n d p e a k is tangent s k i n n e d c o r r e c t e d area. Peak $ K.T. first nin . scan i 12.37S 2 2.37S 254 254 na x scan 257 257 last scan 262 262 peak wid th e 8 raw area 646915 646915 c or.r . area 598907 575623 corn. Z i 0 0 .0 0 96.11 `.'20/322 C A L C U L A T I O N R - G I o b a l C i) = .8303 rl/ii - 2 5 7 . 0 First peaK is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent skinned c o r r e c t e d area. Peak * R.T. first n m . scan na x scan last peak scan width raw area 1 12.375 2 12.375 254 254 257 257 262 262 8 374852 8 374852 corr . area 318020 311824 corr . / 10 0. 00 98.05 '320 + 3 2 2 ) / < 3 3 2 +334) C A L C U L A T I O N R - C l o b a 1< 3) = 4.327 32a-* > / ( 3 3 2 + 334) C A L C U L A T I O N R - G l o b a l i 3) = .5085 ^ SUBJECT TO PROTECTIVE ORDER* 0085 C10988 Ot* SU BJECT TO PROTECTIVE ORDER. t) ro <3 <3 <33 G< G* IO v W 33 Wo W CO >1< -u 10 u V 'V l l w wco ow 0) M c>_ J ____1--- 1- ro - .- L 1 L i_ l_ ro >-- . . Oi' eri CtoO l ro 1-. ,-1.1 rcro cn ] <-i=r ro CO *- --* L. to. r cn i M 0.1. <r--o0> CO !-* CO CO. 10 01 >-- 4 *. \ CO r\o cn -u cn- Oij w cn ro I '}S cn WQ ro o4* 4* It to CO CO ro \ CO r cn r> w t :. g t a f 1 J e b e a d e r t'ron * > B 3 1 1 7 `- a r . o J e : 2U L U V -3044 O p e r a t o r ROY M i s e : &P2330 200- 1/ 3/250 GT B T L *37 B T L *37 ri-5 11/05/34 2=00 Svs. #: t MS n o d e l = 87 S U / H U r e v : CA A LS t- : 0 M e t h o d f i l e : S P 2330 T u n i n g f i l e : APEIQ1 No . of extra records- 2 S o u r c e t e m p . ; 250 A n a l v i e r t e n p .= 0 T r ansf er line tenp . : 0 Chronatographic tenperatures C t y o n a t o g r a p h ic tines, n i n . : Chronatographic rate, deg/nin* . 0 .0 0 .0 0. 0.0 0.0 0. 0.0 0.0 0. 0 . 0 .0 0. 0 .0 0 ,0 h/3 " 333.9 First peak is baseline drop corrected area. Second peak is tangent s k i n n e d c o r r e c t e d area. Pea k t hi.T. f i r s t nin . scan nax last peak scan scan width raw area c orr . area corr . X 1 12.35S 2 2.355 250 250 256 256 266 266 16 229668 190628 10 0.0 0 16 229668 1 8 5 9 S 6 9/ .55 ri/Z - 33 i 9 r ir s t peak ls b a s e l i n e dr od cor retted area . Second1 peak is tangent skinned corrected area. Peak * K .T. f i r s t nin . scan na x scan last p ea k scan w id th raw area corr . area c orr . A i 12.355 250 256 264 "J i 2 .355 250 256 264 i4 191754 1S5214 100.00 14 191754 150629 9 7 .05 332/54 CALCULATION R - G l o b a l i 0) - ,8142 ri* i*_5*/'? First peak is b a s e l i n e dro p c o r r e c t e d area .S U B J E C T Second peak is t a n g e n t s k i n n e d c o r r e c t e d area. Peak * R .T. f i r s t nin . scan na x scan la s t scan peak w id th raw area corr . area corr* . X i 12.375 51 257 265 14 226639 179165 i 0 . 00 2 12.375 251 257 2 6 5 - 14 226639 i 72774 96.43 ri/Z = 3 2 .9 First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent skinned c o r r e c t e d area. Peak * K.T. fir s t nin . scan na x scan la s t scan peak width raw area 1 12.375 254 257 262 2 12.375 254 257 262 8 154102 8 154102 C10990 corr area 120374 117538 corr' y / \t \'\ 100.00 97.64 first peak is ba se li ne drop co r r e c t e d area. S e c o n d p e a k is tangent s k i n n e d c o r r e c t e d ar ea . Peak # H .T. first nin . scan nax scan last peak scan width raw area 1 12.375 '254 257 262 2 12.375 254 257 262 8 130072 8 130072 c orr . area 97976 96132 corr . X 10 0 .0 0 98.12 320/322 CALCULATION R - G l o b a l C 1) .6139 ri/Z = 2 5 7 . 0 f irst p e a k is b a s e l i n e dr op c o r r e c t e d area . Second peak is tangent skinned c o r r e c t e d area. Peak K .T . f i r s t n i n . scan i 12.375 2 12.375 254 254 nax scan 257 257 last scan 263 263 peak width 9 9 raw area 101154 101154 corr . area 55704 54903 corn . X 10 .0 0 98.56 !30 + 3 2 2 ) / < 3 3 2 + 334) C A L C U L A I ION R - G l o b a 1( 3) = .6314 <328' >/ < 3 3 2 + 334) C A L C U L A T I O N R -Globale 3) - .5 i4 9 SU B JECT TO PROTECTIVE ORDER. */'o q C10991 F lie > B 31 13 3 3 3 . 6 - 3 4 . 6 i mu . 2UL U T - 3 0 4 5 LP233G 200-1 '3^250 GT ST File >33113 321.6-322.6 aii.ij.2UL UT-3045 SP2330 200-1/3^250 GT BT 4O00- 20000" File V-Sw^ 0- T-- i-- i-- r--i-- |-- i-- i-- .-- i-- |-- !-- i-- i-- i-- --i-- n -- i-- i-- .-- i-- i-- i-- |-- i-- r 10.0 10.5 11.0 11.5 12. 12.5 > B 3 1 13 319.6-320.6 amu.SUL UT-3045 13.0 .-....,,A------- i 1 i 1 1 rt--r--i--i--|--i--r 13.5 14.0 14.5 3P2330 200-1^3/250 GT 15.0 BT J W * . --* SUBJECT TO PROTECTIVE ORDER. C10992 ni:, (i3 T 3 ri. J.e n e acier t'ron : > B 5 i 8 Sanle; UL 01-31145 Operator: ROY rIS 11/05/84 2 hite : SP2330 2U-1/3/250 GT &TL#39 BTL43? Svs. : X rfS n o d e l 87 S W / H U r e v . ; CA A L S = ; 0 hethod file: SP2330 Tuning file: APEIO No. uf extra records 2 S o u r c e t e n p .: 250 A n a l y z e r tenp . 0 Transfer line tenp, (1 Uhronatographic tenpera tures 0. C l\r onato g r a p h i c r i e s , nin. : 0 .0 C h r o n a t o a r a p h i c rate, d e g / n i n 0 .0 0. 0.0 0.0 0. 0.0 0.0 0. u .o 0 .0 0. 0 .0 0 .0 r l / -- iU J . 9 First peak is baseline drop corrected area. Second peak is tangent skinned corrected area. Peak * K .T. first nin . scan na x scan last peak scan width raw area i 12.355 251 256 267 2 12.355 25i 256 267 16 195019 16 195019 c orr . area 153195 150411 corr . X 10 0 .0 0 98.18 ri/Z = 331.9 First peak ;is baselin e dr op corree ted area . Sec ond peak is tangent skinned c o r r e c t e d area. Peak T R .T . f ir s t n m . scan na x scan last peak scan width raw area i 12.355 252 256. 267 2 2.355 252 256 _0 / 15 162092 15 62092 corr . area 12&212 12322? corr. 100,00 97.63 332/334 CALCULAI ION -Globali 0) = .8239 n y *V *= .j 7/. Qy ^ 'i1; - -- -- --- i < First peak is baseline drop corrected area. Se c o n d peak is tan g e n t s k i n n e d corr ec ted a r e a . : lu IAL V JS.CTVE ORDER. Peak R.T. first n i n . scan na x scan last peak scan width raw area corr. area corr . 1 12.375 251 257 265 2 12.375 251 257 265 14 187228 147034 10 0. 0 0 14 197223 i 4 ocio 2 97.69 H/Z - 321.9 First peak :is b a s e l i n e drop c o r r e c t e d area . Second peak is tangent skinned corr ec ted area . Peak t R.T. first n i n . scan na x scan last peak scan width raw area i 12.375 254 257 262 2 12.375 254 257 262 8 168687 6 168687 C1Q993 corr. area 143415 i35535 corr . /A 100.00 94.51 First peak is ba se li ne drop co rrected area. Second peak is tangent skinned co rr ec te d area. Peak * U.T. first nin . scan na x scan last peak scan width raw area 1 12.375 41 2 . 3 7 5 254 254 257 257 262 262 8 140123 3 140123 c or r . area 114939 109047 corr . /. 100.00 94.87 320/322 CALCULATION R-Globali i> = .8014 ri/3 2 5 7 . 0 n r s t peak is b a s e l i n e drop corrected area. Second peak is tangent skinned corrected area. Peak * Ft .T. f i r s t nin . scan nax scan last peak scan width raw area 1 12.375 2 i2.37S 254 254 257 257 262 262 8 98062 8 98062 corr. area 64206 62230 corr . 7. i 0 0 .0 0 96.92 (320 t 322>/<322 +334) CALCULATION R - G l o b a H 3) - .9247 .320')/(332 + 334) CALCULATION R - G l o b a 1( 3) - .5216 'j ... *,,____.- SUBJECT TO PROTECTIVE ORDER. C10994 S660T0 o O w u hi hr^ V/-L j_^j2 iai - n>% / n rfc* ia o s s ^s m -o o s osssds ss *.yst *soo *i m s * r,UJ^ msz-m9sz ex isa < * n j ia ss--'yx-0 0 s osssds o s M s t - '/ s o o M "ins'nu,li 9 * s s - 9 * & xs xia< * i j a o s s ^s m -oos 0&tds s */st? /s 00 i nns`n,iJ ? *SS-9'XSS tXXSa< *l?J 0 'iSX . .S.M X 0 *M 3 * X ' X 3 *S X O 'SX 3 'XX 8 ' XX -1-- * ` 1 1 * _ * t <- ._l__L if S 'OX 'X * i * `-f-g 00003 0OOO X ia 03S// X-DOS eSSSdS O S '/3t?'s Z W X *102" nure 9' SSS-9' S &X X3< *T J ia OSS/M-OOS 0SdS OS *-'8fr*^SO M T n S ' r"J1i 9 'S - 9 M S S 8 XX 3 C * I TJ ,it' o a a f l i-3 n a d e r f r o n ; >B 3 1 i 9 iijMn l.e : 2 U L i .002/.-18/. 20 Wise SP2330 200-1/3/250 Operator: ROY B T L $ 0 5 BTL-tf 5 MS i i/ 05 / }34 2 4 3 5us. $- i nS nodel: 07 SW/HW r e y . : CA ALS * : 0 Method file: SP2330 Tuning file; APEI01 No. of extra records- 2 S ource terip. : 250 Analyzer temp.: 0 Transfer line tenp . 0 C h r o n a t o g r a p h i c t e n p e r a t ures : 0. Ch-r o n a t o g r a p h i c tines., nin. 0 .0 Chronatographic rate, deg/nin: 0.0 0. 0.0 0 .0 0. 0.0 0 .0 . 0.0 0 .0 0. 0 .0 0 .0 H/Z = 333.9 First peak is b a seline drop c o r r ected area. Second peak is tangent skinned co r r e c t e d area. Peak * R.T. first nin . scan 1 12.334 2 12.334 251 251 nax * last scan scan 255 2S5 264 264 peak width 13 13 raw area 420210 420210 c orr . area 389543 381242 corr . 'L 100.00 97.87 M / Z - 3 3 i .9 F irst peak is b a s e l i n e dr op cor r e c t e d area . Second peak is tangent skinned cor re c t e d area . Peak * K .T . first n i n . scan na x scan last peak scan width raw area corr . area corr . 7. i 12.334 250 255 265 2 12.334 250 255 265 15 355362 317997 100.00 15 355362 311667 ? 8.01 332/334 CALCULATION R - G l o b a H 0) - .8163 CCr.'T"-- h '/ = 527.9 SUBJECT TO p 7 n iZ L 'i 2 WOTtCiTVE ORDER. First peak is base l i n e drop c o r r e c t e d area. Second pea k is tangent skinned cor ree ted area. Peak * R.T. first nin . scan na x scan last pea k scan width raw area corr. area c or r 1 12.355 2 12.355 252 252 256 256 266 266 14 4 2 4 0 6 1 3 8 8 9 3 5 i 0 0 .JO0 14 4 2 4 0 6 i 5 8 0 4 9 3 <;>7 p.k M/7, - 3 2 1 . 9 F ip s t peak is b a s e l i n e drop corr ec ted area . Second peak is T angent s k i n n e d c o r r e c t e d ar ea . r.1 0496 Peak * k ,T . f irst nin . scan 1 12.375 n 12.375 252 252 nax scan 257 257 last peak scan uid th 266 266 14 14 raw area 774861 774861 corr. area 739973 726127 corr . f 100.00 98.13 First peak is b a s e l i n e drop co rr ec te d area. Second peak is tangent skinned co r r e c t e d area. Peak . * R .I . first nin . scan na x scan last peak scan width raw area i 12.375 2 12.- 3 7 5 250 250 257 257 266 266 16 644133 16 644133 c orr . area 602389 587541 c orr . 7. 100.00 97.54 JS0/322 CALCULATION -Global 1 ) = .8141 ri/Z - 2 5 7 . 0 First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent skinned c o r r e c t e d area. Pea k t K .T. f irst nin . scan na x scan last peak scan width raw area 1 12.375 2 12.375 251 251 257 257 26S 265 14 3 6 9 0 6 1 14 369061 c orr . area 321167 3H374 corr . % i0 0 .0 0 96.95 (320 + 322)/(332 +334) CALCULATION R - G l o b a 1( 3) = 1.8972 <328'>/(332 + 334) CALCULATION U - G l o b a K 3) = ,5403 n r.r. o * s u b j e c t t o p r o t e c T/E ORDER. C10997 f H O *u A) CHm> n II1 o AJ D m 'Ai L J 10 3* (CSf' 1* I' it* V W to rGio ttoo I tttooo <7* iffiu.SUL UT-304 STPB.SP2330 130-1-'7/275 O M* O CO CO CD Ct W W W IO o till. Gi u 1 1 1X J Qi Ltn tn 10 w. r<n to. to tn +*_ U_ tn tn . CD l1 ro -t. w to ito tr Q -V- -- i-- l--i-- Li l_j_X Gi ' t1o0 -0 O' I to ICOO O' Gi I- ro c tn .r c H fO _ 1m 9to - - O' *-+ . tn M_ G J_ CO H n to CO to " TJ O ro ,to . to 4*_ CO M1 \ \ tn * ro * -'j tn M tn _ w v wtH-o ro Gi to <0 -- *- _ O' tn tIo to *-* ro 0* G i* W lr - tn - - I io tio - * O' ^ IO. tn to_ CO H D W h-* CTO7 to tn ro ttoo u w 1 Gi I c* \ -\-sI tn (O -o tn cn. w h) 4- ijl Q G> c> L_l--L_l i l t , Li_l wio ro O' tio to r O' tno c* T> ro too -i to oi *3 -ile h e a d e r i r o n >B3120 a- 2 U L U T - 3 0 4 6 Oper a t o r ; ROY' NS i 1 / 0 5 / 0 4 3:iJ5 ' S1AB.SP233U 180-1/7/275 BTL#5iBTL*5i t: l MS n o d e l : 87 SLJ/HW rev.-. CA A L S * = 0 hod file; SP233Q Tuning file: APEIOi No. of extra records; 2 :e tenp.-- 2 5 0 A n a l y z e r tenp..' 0 Transfer line tenp. U Chromatographic tenperatures 0. Ctir o n a t o g r a p h i c t i n e s , n i n . 0 .0 Chromatographic r a t e ; d e g / n i n : 0.0 0. 0 .0 .0 * 0. 0 .0 0 . 0. 0 .0 0 .0 0. 0 .0 0 .(J 333.9 t peak is baseline drop corrected area, d peak is tangent skinned corrected area. H.T . first nin . scan nax ` last peak scan scan width. raw area corr . area corr . 71 .2.376 2.376 `2 5 2 252 257 257 266 266 14 2 1 4 3 7 4 1 7 7 S 9 6 i0U .00 i4 2143 7 4 172948 97.38 331.9 t peak is baseline drop corrected area, id p e a k is t a n g e n t s k i n n e d c o r r e c t e d a r e a . fc .T. f i r s t nin . scan na x scan last peak scan width raw area corr. area corr. % 12.376 i 2 .376 252 252 257 257 264 264 12 175550 12 175550 143702 139508 100.00 97.08 - 0 * ,34 C A L C U L A T I O N obal( 0) = .8092 = 327.9 s u b je c t to protective it p e a k is b a s e l i n e dro p c o r r e c t e d area, nd peak is tangent skinned corrected area. AT roefl Fi .T . f i r s t nin . scan nax scan last peak scan width raw area corr . area corr. / 12.396 253 258 265 12.396 253 258 265 12 204100 12 204100 169708 165892 100 .0 0 97.75 321.9 p e a k :is b a s e l i n e drop c o r r e c t e d are a . 1 peak is tangent skinned corrected a r e a . R.T. first nin . scan na x scan last peak scan width raw area 1 2 . 3 9 6 2 5 3 2S8 26 4 11 4 9 0 0 3 1 2 . 3 9 6 253 258 264 ii 490 03 C10999 corr. area corr. _ _ % Ocq6 2059Q 18626 100.00 90.46 TOOTTO 8600 dz e i d s 'sais fr0-in Tic nure ' S r - i ' S S S t3< e n j 3 S Z T 3" I~Q c T O d 3 *3 t1 S fr0-lfl "ins'nui 9 `0 - 9 ' 6 T STS< *IJ 33 SZ3/3v-QSt 0*dS'alS *0-in n n r 'nuj 9 ` - 9 ` 3 iisa< * i j 0 S T S *M 0 frI 3 ` I 0 ` 1 3 *c T TM 0 S T 3*11 Q-*T1_I- 1 *5_*0l_Ti_ 0 '0 1 -t-fi '~Tt -00003 010 0 t" os szs^e^t-osi essra*atus 0\S S \ M 0 `M S *.I 0*.T fr0-lfi i r \ Z , r "u* ?* 333-9* Z3 IcS< *I!J S VS I 0\Sl 3 '.U O M I 1 3**011i- 0*.l -00003 03 s z /'S/i - s t esasds'sbis f r 0 - m m ' n41 9 * c - 9 M L000Ofr T313C^TTJ O: S Z S - S ' 1 - 0 3 I 0 T d : * 3 y 1 -S ot-in m r ' n '"i ?*-?* i i s s ; i nS daTa i'll h e a a e r f r o m >B3i2i Sample: 2UL UT-3047 Ooerator KUY riS li/0b/84 Mise : S T A B .S P 2 3 3 0 1 8 0 - / 3 / 2 7 5 SCC B T L * 5 3 B T L + 5 3 5ys , 1 hS nodel: 87 SU/HU rev.: CA ALS * : 0 h e t h o d file: S P 2 3 3 Q Tuning file : AP E I O i No. of extra records* S o u r c e temp.: 250 A n a l y z e r t e n p .: 0 T r a n s f e r lin e temp. : Chromatographic temperatures = Chromatographic tines, n i n . Chromatographic rate, deg/min : o o 0. 0 .0 0. 0.0 U .0 0. 0.0 0 .0 0. 0 .0 0.0 0. 0.0 0 .0 li/Z 3 3 3 . 9 First peak is b a seline drop cor r e c t e d area. Second peak is tangent skimmed corrected area. PeaK # R .T. f i r s t m m . scan ma x scan last peak scan width raw area corr . area c orr . Vtm i i2.355 OC-- 2 . 3 5 S 252 252 256 256 265 265 13 168497 135802 100.00 13 1 6 8 4 9 7 1 3 1 9 2 1 97 .i4 H / 2 - 3 3 i .9 F i r s t p e a k is b a s e l i n e dr op c o r r e c t e d a r e a . S e c o n d 1 p e a k isi tang e n t s k i m m e d c o r r e c t e d a r e a . Peak * k.T. first min . scan i 12.355 2 12.355 252 252 ma x scan 256 256 last peak scan width 266 266 14 14 raw area 148241 148241 c orr . area 113409 110994 c or r . i oo. bo 97.87 332/334 CALCULATION R - G l o b a 1< 0) - .8351 h/2 - 327.9 **" - Fri.r s t p e a k is b a s e l i n e drop c o r r e c t e d area. Second pea k is tangent skimmed corrected area. Pea k * k.T. first min . scan ma x scan last peak scan width raw area 1 12.375 2 12.375 252 252 257 257 266 266 14 174775 14 174775 h/ z = 3 2 1 . 9 r ir s t peak is base l i n e droo c o r r e c t e d area . Se c o n d peak is tangent s k i m m e d c o r r e c t e d a r e a . Peak * K.T. first min . scan ma x scan last peak scan width raw area 1 12.375 L,D 1 2 . 3 7 5 253 2S3 257 257 268 268 15 551083 15 551083 " ---- __ ~-- ' .... ` 'T' V_ corr . area corr . % 137633 134434 100.00 97.63 C11002 c orr . area 512623 5 0 148 0 cor r . % 100.00 97.91 rt/2 Ji9 .9 First peak is baseline drop corrected area. Second peak is tangent skinned corrected area. Peak * R .T . f i rst nin . scan na x scan last peak scan wid th raw area 1 12.395 O Lm 12.395 252 252 258 258 269 269 17 4 5 6 5 9 0 17 456590 c orr . area 414889 405853 corr . X 100.00 97.82 20/322 CALCULATION R - G l o b a 1( 1) = .8093 h/Z = 2S7.0 First peak is baseline drop corrected area. S econd peak is tangent skinned corrected area. Peak # R.T. first nin . scan na x scan last peak scan width raw area 1 12.395 2 12.395 252 252 258 258 269 269 17 292443 17 292443 c orr . area 218527 216334 c orr . 7. 10 0.00 99.00 (320 + 322 >/(332 +334) CALCULATION R - G I o b a l ( 3) = 3.7218 >:328' > / < 3 3 2 + 334 ) C A L C U L A T I O N R - G l o b a l ( 3) = .5338 (- C11003 Fila, . 33 122 32 3 .-5 24 .i mu.-'-'L UT -3 04 3 3T B .3 P 2 3 2 3 lS0-l/*3,'2rS SC F i l e >3122 3 2 1 .6 - 3 2 2 .6 amu.2UL UT-3948 STAB.SP2330 180-1^3^275 SC Ub-'L*^i <0 r . T v i U u u . C11004 ri4 d 3 T8 t i l e h e a d e r t'ron >B 3 1 2 2 Semole : SUL Ur-3048 O p e r a t o r -* KU Y lib hisc STAB.3P2330 130-1/3/275 SCC BTLtSS BTLiSS ii/05/84 Sus. if: t HS rtodel : 87 S W / H U rev.: CA A L S * : 0 Method file: SP2330 Tuning file; APEIOi No. of extra records- S o u r c e temp . 250 A n a l y z e r temp . - 0 Transfer line temp. 3 =45 Chromatographic temperatures 0. Chromatoaraphic times, min. s 0 . Chromatographic rate, dea/min: o o o o 0. 0 .0 0 .0 . 0 .0 0 .0 0. 0 .0 0. 0 .0 o o h/Z = 333.9 first peak is baseline drop corrected area. Second peak is tangent skimmed c o r r e c t e d area. Peak k .T. f i r s t min . scan max * last pea k scan scan width raw area corr . area corr . % i 12.355 2 2.355 252 252 256 256 268 268 16 i9 2 609 153953 i 0 0 .0 0 16 926G9 15Q769 97.93 H/Z - 331.9 F i r s t p e a k is b a s e l i n e dr op c o r r e c t e d are a . S e c o n d p e a k is; t a n g e n t s k i m m e d c o r r e c t e d a r e a . Peak * H .T . f i r s t min . scan max scan last peak scan width raw area c orr . area corr . / i 12.355 2 12.355 252 252 256 256 266 266 159404 1 2 4 2 9 2 i 0 .0 i4 159404 121688 97.90 332/33-** C A L C U L A T IN R - G l o b a 1( 0; - .8073 ri/2 - 3 2 7 .V SUB. first peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak V R .T . f i r s t min . scan max scan last peak scan width raw area i 12.375 252 257 267 2 2.375 252 257 267. 15 189083 15 189033 rl/Z = 3 2 i . 9 First peak is b a s e l i n e drop cor r e c t e d area. Second peak is t angent s kimmed c o r r e c t e d area. Peak * R .T. f i r s t min . scan ma x scan last peak scan width raw area i 1 2 . 3 9 5 2 5 2 25 8 26 3 ii 3 6 7 7 5 2 1 2 . 3 9 5 2 5 2 258 263 ii 3 6 7 7 5 i A LI``-i-"r--vVr-L C: corr. area 149133 145133 corr. 7i 100.00 97.31 corr . area corr . 9 7 9 2 10 0. 0 8934 91.24 C11005 ' n/ {. - j19.9 First peak is baseline drop corrected area. Second peak is tangent skinned corrected area. Peak + R .1 . f i r s t nin . scan nax scan last peak scan width r au area 1 12.395 2 12.395 255 255 258 258 262 262 7 25072 7 25072 i7 0 12 . 2 corr . area 7138 6875 corr. X 100.00 96.32 320/322 CALCULATION R - G l o b a 1( i) = .7290 il/Z = 2 5 7 . 0 First peak is baseline drop corrected area. Second peak is tangent skinned corrected area. Pea k * H .T. f i r s t nin . scan nax scan last pea k scan width r aw area 1 12.395 2 12.395 256 256 258 258 262 262 6 27295 6 27295 corr . area 5905 5848 corr . X 100.00 99.03 <320 + 322)/<332 +334; CALCULATION R - G l o b a l ( 3) = .0608 ' <328'>/<332 + 334) CALCULATION rt-Global< 3) = .5357 SUBJECT \ M k el +\ C11006 F i l e > 8 3 1 5 3 3 33 . if*- 3 3 4 . 6 a my , 2UL U T - 3 0 4 9 2T P B . 2P 2 3 30 2 0 0 - 1 / 3 / 2 5 0 R MH File >83123 327.6-323.6 amu.2UL UT-3049 STAB .3P2330 2OO-1/3/250 RIJN File >83123 321.6-322.6 amu.^UL UT-3049 STA8.SP2330 2O0-1/3/250 RUN ' _ J l A 10.0 10.5 1 1 1`.0 1 l'.S 12.0 12*. 5 13.0 13.5 14.0 14.5 15.0 -- f SUBJECT TO PROTECTIVE ORDER, C11007 ni:> <ia tj f ].J,e h e -3d e r tr on = 1b j 1 2 j janpie: 2 U L U l - i 0 4 9 O p e r a t o r : ftQY MS hisc : STAB.SP2320 20Q-1/3/250 RUN BTL+5 7 B T L 4 57 il/OS/84 4:05 Cys, t MS nodel- 87 S W / H U r e u . ; CA A L S i : 0 Method file: SP2330 T u n i n g file; A P S I O i No. of e xtra records: 2 Source tenp.: 250 Analyzer t e n p . 0 Transfer line tenp 0 Chromatographic temperatures 0. Ch.romatographic times , Min . 0 . Chromatographic rate> d e g / n i n : 0.0 0. 0.0 0.0 . 0.0 0 . 0. 0 .0 0 .0 0. 0 .0 0 .0 ri/>I = 3 3 3 . 9 First peak is b a s e l i n e drop corrected area . Second peak is tangent skinned cor r e c t e d a rea . Peak * ft .T . f i r s t nin . scan i 12.354 2 12.354 250 250 na x scan 256 256 last peak scan width 2 72 272 22 22 r aw area 206564 206564 corr . area 151916 149012 c orr . /u 100.00 98. i.)9 n/j. - 3 o i . 9 First peak is b a s e l i n e drop cor r e c t e d area . Second peak is tangent s k i nned c o r r e c t e d area. Peak # ft .7 . f lr s t nin . scan i 12.354 ? 12.354 246 246 max scan 256 256 last scan 267 267 peak width 21 21 raw area i7 3 3 1 0 1733 0 corr . area 125136 119791 corr . / 1 U 0 .0 95.73 332/534 CALCULATIUN R-C-lobalC ) = .8237 n/'i - 3 2 7 . 9 First peaK is b a s e l i n e drop cor r e c t e d area . Second peak is tangent skinned co r r e c t e d area. '" ' "''~5 ' SCuJc.CT 70 ppQTTr-T-- . 7 Peak * ft .1. f i r s t nin . scan na x scan .last p e a k scan width raw area c orr . area c orr . ~i i 12.375 2 12.375 253 253 257 257 265 265 12 1 7 7 4 8 5 1 4 5 4 5 7 10 (1.00 12 177435 141251 97.11 1/7. - 32 i .9 First pea k :is b a s e l i n e d r o p c o r r e c t e d area, Sec onci peak is t a n g e n t s k i n n e d c o r r e c t e d a r e a . Peak * ft .T. first nin . scan na x scan last peak scan width raw area C11008 corr. area kJ \}j / . corr. 7. i 1 2 . 3 7 5 2 5 3 25 7 264 ii 3 6 0 0 3 ? 1 2 . 3 7 5 253 257 264 ii 3 6 0 0 3 8151 7634 100.00 93.66 ri/ - 3 i'? ,V r r*s t p g a k is b a s e l i n e drop c o r r e c t e d area . becond peak is tangent s k i n n e d c o r r e c t e d area. Peak t R .T . f i r s t nin . scan nax scan last peak scan width raw area 1 1 2 . 3 7 5 254 257 265 ii 34404 2 1 2 . 3 7 5 254 2 5 7 265 11 34404 7 5 3 i? 3 c orr . area 7014 6865 corr . / 100.00 97.88 320/322 CALCULATION ft-Global( 1) = .8605 h/Z - 257.0 n r s T peak is bas e l i n e dr op c o rrected area . Second peak is tangent skinned c o r r e c t e d area . Peak # K.T. first n i n . scan na x scan last peak scan width raw area 1 12.536 261 265 272 11 42210 2 12.536 261 265 272 11 42210 corr . area 4040 3300 c orr . X a o .o a 81.88 *320 + 322)/!332 +34) CALCULAT ION R - G l o b a l C 3) - .0547 <28' )/(332 + 334) CALCULATION ft-GlobaK 3) = .5248 \1 ^r-rr~3*"c. L*:i.D-- rL ii nr/yr*- 's y, C11009 File '33124 33 . 4 .6 EiiTiU UL U T - 3 0 5 0 T m B .3 P 2 3 3 3 2 0 0 - 1/ 3-' 2 S 0 R U N File >33124 1 . 6 - 3 2 2 . 6 iffiu 2UL U T - 3 OSO S T f l B P 2 3 3 0 2 0 0 - 1 ^ 3 ^ 2 5 0 RUN '!*1f -, I i,L* h g t"`r 1 r n n a nu 1 * i| 11T j 5 0 Oper .u o r H0 Y OS i. i / u b . i-* hx sc S T A B . S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN B TL frS?BTL*5? 5vs . fr; l nS n o d e l : 8/ S U / H U reu . CA AL S fr '.) hethod fiie: SP2230 Tuning fiie- AFLIOi Nu. of extra recortis Source tenp.: 2S0 Analvzer te n p . 0 Transfer line te n p . U Chronatographic tenperatures C h r o n a t o a r ap h ic t i n e s . nin . Chr ona t o g r a p h i c rate. deg / n i n 1: 0. 0 .0 0.0 0. 0 .0 0 .0 0. 0 .0 0 .0 0. 0 .0 .0 0 0 .U 0 . ri/'3- 3 3 3 . ? * r ir s t peak i s b a s e l i n e dr op c o r r e c t e d area . S e cond peak is tan g e n t s k i n n e d c o r r e c t e d a r e a . Peak * i 2 ,R .1 . f ir s t / tun . scan 12.368 12.368 255 255 na x last peak scan . scan width 26 0 26 0 272 272 17 17 raw area 191246 191246 nSZ - 331.9 First peak is b a s e l i n e dr o d corr ec ted area . Second peak is tangent s kinned c o r r e c t e d area . C O!rr . area 148933 145 779 Ly t 1*TM corr . /y 10 0. 0 7 .88 Peak 1 k.T. first run . scan i 12.368 d, 1 2 . 3 6 8 254 54 na x scan 260 260 last peak scan w id th .2 ^ 1 271 17 7 raw area 163470 163470 c orr . area 122432 i 19 i 17 corr . 1 0 0.00 <?"/ *2<.) 332/334 CALCULATION R - G i o b a i ( ) " .8221 ri/ /: - :?./ SUBj z TO First peak is baseline drop corrected area. Second peak is tangent skinned c o r rected area. Peak \ h! .T . f i r s t nin . scan na x scan last peak scan width raw area corr. area corr. 1 12.389 257 261 268 2 12.389 257 261 268 11 1 7 7 3 6 b 1 4 5 6 8 7 10 0. 00 11 1 7 7 3 6 6 14*1511 97.2 0 ilZ - 321.9 F irs t peak i s 'b a s e l i n e dr op cor r e c t e d area . Second peak is tangent s k inned c o r r e c t e d ar ea Peak *- k .T. f i r s t nin . scan na x scan last peak scan width raw area l i c or r i area corr . X 1 12.389 256 261 269 2 12.389 256 261 269 13 46073 13 46073 13833 13027 100 0 0 94.17 C11011 rl '>: " 7-i" 9 H peak is b-iseiine drop co rr ec te d area . Sec ond peak is tangent s k i n n e d c o r r e c t e d area. R .T . f ir s t nin . scan na x scan last peak scan width raw area 12.389 258 261 267 12.389 258 261 267 9 34662 9 34662 '7 ;^ 3 |*2 '4 c orr . area 11163 10803 corr . /h 100.00 96.78 "20/322 CALCULATION R - G l o b a l ( 1) = .8070 rit/, = 257. o First peak is baseline drop corrected area. Second peak is tangent skinned corrected area. Peak * R .1 . f i r s t nin . scan na x scan last pea k scan width raw area 1 1 2 . 3 3 9 257 261 267 10 4 6 1 5 4 2 . 12. j>3 V 25 7 261 2 67 iU 46i 54 c or r . area 10304 i02 09 corr . V i00 00 99.08 <320 + 22)/(32 +330) CALCULATION R - G l o b a l < 3) - .0921 32S-')/(332 + 33*4) C A L C U L A T I O N R - G l o b a l < 3; - .5360 SU BJECT TO ,-j ii^L 1r. L/ ^ " Et- o, C11012 Fil* > 31 2 5 33 3.6-3 3 4 .6 =niu .2UL 1 .02/. 4 3 / . 20 SP2338 2 0 0 - 1/3/250 GT ST File >3125 3 2 1 . 6- 32 2. 6 a m u , 2UL 10.02/. 43/. 20 S P 23 3 0 2OO-1/3/250 GT BT CUOI 3 h-> d a T a t i l e h e a d e r f r o n >B32b S a n p l e = 2U L i(J .02/. 48 / .20 (Jperator j ROY hisc : P2330 2 0-1/3/250 GT BTL417 BTL*17 rfS 11/05/34 Sys. i hS-nodel: 87 SU/HU reu.i CA ALS * 0 H e t h o d filei S P 2 3 3 0 T u n i n g file: AP E I O i No. of extra r e c o r d v S o u r c e tenp.: 2 4 8 A n a l y z e r t e n p .: 0 Transfer line tenp. Chronatographic tenperatures = 0 . Chronatographic tines, n i n . 0 .0 Ch-ronat ographic rate, deg/nin 0.0 0. 0.0 0.0 0. 0 .0 0.0 0. 0.0 0 .0 0. 0 .0 0 .0 H/'I - 3 3 3 . 9 First peak is baseline drop corrected area. Second peak is tangenT skinned c o r r e c t e d area. Pea k * R.T. first nin . scan na x scan last pea k scan width raw area c orr . area corr . X 1 12.375 2 12.37b 250 250 257 257 268 268 18 4245 7 B 3 8 0 4 0 6 i 0 0 .0 Q 18 424578 376518 98.98 tt/Z = 3 3 1 . 9 First peak is b a s e l i n e drop c o r r e c t e d area. Second peak is tangent skinned c o r r e c t e d area. Peak i- R.T. first nin . scan i 12.375 2 12.375 252 252 na x scan 257 257 last scan 267 267 peak width raw area 15 352807 15 352807 corr . area 314857 3 1 i8i2 corr. X i 0 0 .0 0 99.03 332/334 CALCULATION R - G 1 oba 1( 0) - .8277 nV./ - 3 2 7 . 9 First peaK is baseline drop corrected a r e a . Second peak is tangent skinned co r r e c t e d a r e a . Pea k R.T. first nin . scan nax scan last peak s c a n w id t'h raw area i 12.395 12.395 250 250 258 2S8 268 268- * i8 18 522373 522373 ri/Z 32i .9 First peak is baseline drop corrected area. Second peak is tangent skinned c o r r e c t e d area. Peak * K .T . f i r s t nin . scan 1 12.395 2 12.395 252 2S2 na x scan 258 258 last scan 270 270 peak width raw area 18 7572890 T f r 7172890 ^ii corr. area 47514 468535 corr . /** 10 0.0 0 9 3 . 6i C11014 corr . area 7529474 7443425' corr. % 100.00 98.86 F i r s t Dea k is b a s e l i n e drop c o r r e c t e d area. S e c o n d p e a k is ta n g e n t skin ne d c o r r e c t e d area. Pea k * R .T. f i r s t nin . scan na x scan last peak scan width raw area 1 12.415 253 259 274 2 12.. 4 IS 2 5 3 259 274 21 6226951 21 6226951 corr . area 6175942 6118413 corr . /. 100.00 99.07 320/322 CALCULATION R - G l o b a l < i) = .8 2 0 2 h/2 = 257.0 f i rst peak is b a s e l i n e drop cor rected area . Second peak is tangent skinned corrected area . Peak I. K.T. first nin . scan na x scan last peak scan width raw area i 12.415 *3 1 2 . 4 1 5 253 253 259 259 279 279 26 ` 26 3075655 3075655 corr. area 2991051 29686 0 corr . X 1.0 0.00 99.25 <'520 + 3 2 2 ) / < 3 3 2 + 334) C A L C U L A T I O N R - G l o b a ( 3) = 19.7126 <320')/<332 + 334) CALCULATION R - G i o b a l i 3) = .58S9 011015 F i l e > 3 1 2 6 3 3 3 . 6 - 3 3 4 . 6 aniu . 2 U L U T - 3 0 5 1 S T A B .SP2330 200-1/3/250 RUN File >3126 321.6-322.6 itru.SUL UT-3051 S T A B .SP2330 200-1/3/250 RUN I TU3JECT TO ?R C11016 n c.. nata rii h e a d e r f r o n ; >fc(3i2o Sanple: 2UL UT-3Q5 Operator: ROY MS 1 1 / 0 S / 4 S iO M i 5C : STAB.SP2330 200-1/3/250 RUN BTL*63BTL*63 S v s . *: i MS Model: 87 SU/HU rev.: CA ALS * : 0 Method file: SP2330 Tuning file; APEIOi No. of extra records- 2 Source tenp. 2S0 Analyzer ten p . 0 Transfer line tenp. - 0 Chronatographic tenperatures 0. Chi* ona t o a r a p h i c t i n e s ; n i n . : 0 .(1 C h r o n a t o a r a p h i c rate, d e g / n i n : 0 .0 0. 0.0 0 .0 0. 0 .0 0 .0 0. 0 .0 0 .0 0. Q.. 0 .0 r)/Z = 3 3 3 . 9 First peak is b a seline drop cor r e c t e d area. Second peak is t a ngent s k i n n e d c o r r e c t e d area. Pea k * 1:.T . f i r s t nin . scan na X scan last peak scan width raw area corr . area c orr . 7. i 12.355 2 12.353 251 251 256 25b 265 265 14 1 3 4 2 6 8 i4 134268 100360 95915 100.00 95.57 ri/ Z - 3 ^ i . 9 First peak is baseline drop cor rected area . Se c o n d p e a k is; t a n g e n t s k i n n e d c o r r e c t e d area. Pea K * K .T. f i r s t nin . scan na X scan last peak s c a n wid th raw area corr. area corr . V i 12.375 253 257 267 D 12.375 253 257 267 14 1 2 0 9 2 6 i4 120926 837 0Q 82496 10 0 . 0 93.56 j32/CALCULATION f-Gi oba 1 < 0 ) ri/Z -= 3 2 7 . 9 .834 0 <Uil. sua,';- -- First peak is b a s e l i n e .drop cor rec t ed area . Second peak is tangent skinned cor rec ted area. "" - -- * --3 . 7 7 A, Peak * k.T. first n i n . scan na X scan last peak scan width raw area corr. area corr . X 1 12.396 253 258 266 2 12.396 253 258 266 13 138628 104724 100.00 13 i38628 0357 9 6 . 76 ri/ Z = 3 2 1 . 9 First peal< is b a s e l i n e dro p c o r r e c t e d area . Second peak is tan g e n t s k i n n e d c o r r e c t e d area. Peak t k.T. first n i n . scan na X scan last peak scan width raw area C11017 corr . area * corr. V / 1 12.396 253 258 268 15 74495 3635 0 100.00 2 12.396 253 258 268 15 74495 35420 97.44 n *'*Z =: 5 1 S'.? Fi rs t peak is baseline? drop c o r r e c t e d area. Second peak is tangent s k i n n e d c o r r e c t e d area. Peak * K.T. first nin . scan na x scan last peak scan width raw area i 12.396 253 258 266 13 61532 4'D* 1 2 . 3 9 6 25 3 2 5 8 2 6 6 13 6 1 5 3 2 0 ? i ?- ( j ; c orr . area 27704 27576 corr . - 100.00 9V .25 '20/322 CALCULATION R " G 1 o b a 1< i) - .7643 rt/Z = 2 5 / . 0 First p e a k is baseline drop corrected area. Second peak is tangent s k inned c o r r e c t e d area. Peak * K.T. first nin . scan na x scan last peak scan width r aw area 1 12.396 2 12.396 253 253 258 258 264 264 11 5 4 1 2 8 11 5 4 1 2 8 corr . area corr. V 1742i 100.00 15303 e7.84 (320 + 22;/(332 +334) CALCULATION R-GJLobalC 3) = .3464 (328')/<332 + 334) CALCULATION R -GIobal( 3) - .5672 /x/-I ^ C11O10 '-331 4 .6 clFTiU SUL UT-3052 >P2330 200-1/3/250 RUN 3T 15/84 5=2 1 a : 1* 0 0. 0.0 0.0 rr . X 1.00 .03 > >3127 321.6-322. amu.SUL UT-3052 SP2330 200-1/3/250 RUN BT rr . Z .0 0 .16 CUOIO- /' .00 04 .i r. .00 85 &ri//. - 3 l V . 9 First peak is b a s e l i n e drop corrected area. Second peak is Tangent skinned c o r r ected area. Peak # k .T. f i r s t nin . scan nax scan last peak scan width raw area 1 1 2 . 3 9 5 2 5 5 258 266 ii 8 8 4 7 9 2 12,, 3 9 5 2 5 5 2 S 8 266 ii 8 8 4 7 9 t -/3 3''2_~7 c orr . area 59021 58328 corr . /. i 0 0 .0 0 98.83 320/322 CALCULATION R - G l o b a 1< i) = .793? rl/'/l = 2 5 7 . 0 First peak is baseline drop corrected area. Second peak is tangent skinned c o r r ected area. Peak * H .T. f i r s t nin . scan nax scan last peak scan width raw area 1 12.395 2 12.395 252 252 258 2SU 265 265 13 13 77888 77888 corr . area 34156 33506 corr . 7. 100.00 98.10 (320 + 322)/< 332 +334) CALCULATION R ' G l o b a K 3) = .4940 (328 *)/(332 + 334) CALCULATION R - G l o b a l ( Z) - .5416 a ^n (Si C11021 File >3128 333.6-334.6 amu.2UL UT-30S3 SP2330 200-1/3/2E0 RUN BT File >3128 321.6-322.6 a m u .2 U L .UT-3G53 SP2330 200-l/'3/250 RUN BT C11022 MS data file header from : >B3128 Sample: 2UL UT-3053 Operator: ROY MS 11/05/84 .5:49. flisc s SP2338 200-1/3/250 RUN BTL#67 BTL#67 Sys. #: 1 MS model : 87 SW/HW rev. t CR ALS # : 0 Method file: SP2330 Tuning file: APEI01 No. of extra records: 2 Source temp.: 250 Analyzer temp.: 0 Transfer line temp. : 0 Chromatographic temperatures : 0. 0. 0. 0. 0. Chromat ograph ic times, min. : 0.0 0.0 0.0 0.0 0.0 Chromatograph:c rate, deg/min: 0.0 0.0 0. 0 0. 0 0. 0 M/Z = 333.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. fi rst min. scan max scan 1ast peak scan ui dth raw area corr. area corr. 7. 1 12.355 250 256 266 2 12.355 250 256 266 16 208609 16 208609 166849 162753 100.00 97.55 M/Z = 331.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. f irst min. sc an max sc an 1ast peak scan width raw area corr. area corr. *4 1 12.355 248 256 268 12.355 24S 256 268 20 191713 137753 100.00 20 191713 135873 98.64 332/334 CALCULATION R - G l o b a l < 0) = .8256 M/Z = 327.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R. T. fi rst min. scan max sc an 1ast peak sc an width raw area 1 12.375 252 257 267 12.375 252 257 267 15 20S4 63 15 20S43 M/Z = 321.9 First peak is baseline drop corrected area. Second peak is t angent skimmed corrected area. Peak # R. T. f irst min. sc an max sc an 1ast peak sc an width raw area 1 12.375 255 257 260 5 22714 ____ 2_ 12.375 255 257 260 5 22714 "7 n r* CR. corr. area 164288 162443 corr. ym 100.00 9S.88 corr. area 7064 7046 corr. V. 180.00 99. 75 C11023 S M/Z = 319.9 F i r s t p e a k is' b a s e l i n e drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R.T. f irst min. scan max sc an last peak sc an width raw area -1 .12.375 251 . 257 264 13 42215 2 12.375 251 257 264 13 42215 ^ B 3i^S> c orr. area 8896 8636 corr. z. 180.00 97.08 320/322 CALCULATION R - G l o b a K 1) = 1.2593 M/Z = 257.0 First peak is baseline drop corrected area. Second peak is t angent skimmed corrected area. P eak # R.T. f irst min. scan max scan 1ast peak scan width raw area 1 12.375 252 257 263 11 46064 2 12.375 252 257 263 11 46064 corr. area 8719 8526 corr. V. 100.00 97.79 <320 + 322>/(332 +334) CALCULATION R-Global< 3) = .6524 < 3 2 8 0 / 0 3 2 + 334) CALCULATION R - G l o b a l < 3) = .5391 nn12 C11024 F i 1* > E 3 1 2 9 3 3 3 . 6 - 3 3 4 . 6 a,n.u.2UL U T - 3 0 5 4 SP2330 200-1/3/250 RWH T File >33129 4 0 0 0-1 321.6-322.6 amu.2UL UT-3054 V--j ''.-- 2O00H SF2330 200-1/3/250 RUM BT File 0- t-- t-- n -- j-- :-- i-- n -- |-- !-- i-- i-- -- |-- i-- n -- i-- j-- i-- i-- i-- i-- j-- i-- i-- i-- r~]-- i-- i-- i-- r p n -- i-- n "j-- i-- i-i- r -- i-- i-- i-- r-- j 10.0 1'0`.5" 11.0' 11".5 1'2`.0` 12.5^ 13.0 13.5 14.0 14.5 15.0 >33129 319.6-320.6 amu.SUL UT-3054 SP2330 200-1/3/250 RUM BT MS data file header from >B3129 Sam pi * i 2UL UT -3054 Operator : ROV MS 11/05/84 Mise l SP2330 200-1/3^250 RUM BTLK69 BTL#69 Sys. #i 1 MS model ! 87 SU/HU rev. : CA FILS * : 0 Method file: SP2330 Tuning file: APEI01 Mo. of extra records: ; Sourc e te m p .: 250 Analyzer temp .i 0 Transfer line temp. : -Chromatographi c temperat ures : 0 0. 0. 0 m 0. Chromatograph!c t imes , min. : 0. 0 0. 0 0.0 0. 0 0.0 Chromatographi c rat e , deg/m in : 0. 0 0.0 0.0 0. 0 0.0 M/Z * 333.9 First peak is baseline drop corrected are a. Second peak is tangent skimmed corrected area. Peak # R.T. fi rst min. scan max scan 1ast peak scan width raw area corr. area c o ry.r . 1 12.355 252 256 270 2 12.355 252 256 270 18 186388 142756 100.00 18 186388 139030 97. 39 M/Z = 331.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Pe ak # R.T. fi rst min. scan max sc an 1ast peak scan width raw area corr. area corr. * - 1 12.355 252 256 268 2 12.355 252 256 268 16 155143 117207 100.00 16 155143 113935 97.21 332/334 CALCULATION R - G 1o b a l < 0) = .8210 M/Z = 327.9 First peak is baseline drop corrected .area. Second peak is tangent skimmed corrected area. Peak # R.T. first min. sc an max sc an last peak sc an width raw area corr. area 1 12.375 245 257 269 2 12.375 245 257 269 24 204193 132505 24 204193 132193 M/Z = 321.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. first min. scan max scan last pe ak scan width - raw area corr, area 1 12.395 255 258 262 2 12.395 255 258 262 w '''N.w''J, \j t--*W>ci J ... T ft i . ci ?o ^rT T r\ oorrnrr-nvc n o n m 7 26293 7 26293 7995 7288 - * W G11026 corr. y. 100.00 99.76 corr. V. 130.00 91.16 M/2 = 319.9 First peak is b a s e l i n e drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak tt R. T. first min. scan max scan 1as t peak scan u idt h rau area 1 r12.395 254 258 271 2 '12.395 254 258 271 17 50718 17 50710 > 0 3 12. 9 corr. area 9468 9417 corr. 100.00 99.46 32&/S22 CALCULATION R-Global< 1> = 1.1842 M/2 = 257.0 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. fi rst min. scan max sc an 1ast peak scan width raw area 1 0.000 2 0. 000 272 272 0 271 0 271 -1 -1 0 0 corr. area 3897 3897 corr. y. 100.00 100.00 <320 + 322)/<332 +334) CALCULATION R-Glo b a l < 3) = .0672 <32S')/<232 + 334) CALCULATION R-Glo b a l < 3) = .5094 ` I-- i O E ORDER. A^ A - * 'tj C11027 File >B3130 3 33.6 4.6 amu .2UL UT -3 05 5 3P2330 200-1/3/250 RUN BT File > E 3 130 321 .6 - 3 2 2 . 6 iniu UL U T - 3 0 5 5 SP2330 20G-1/3/250 RUN BT C11028 MS data file header from >B3130 Sample: 2UL UT-3055 Operator: ROY MS 11/05/84 6: Mise : SP2330 200-1/3/250 RUN BTL#71 BTL#71 Sys. #: 1 MS model: 87 SU/HU rev .: Cfl ALS : 0 Method file: SP2330 Tuning file: APE 101 No. of extra records: 2 Source temp.: 250 Analyzer temp.: 0 Transfer line temp. : 0 Chromat ographi c temperatures : 0. ^Chromatographic t imes , min. : 0.0 Chromat ographic rate, deg/min: 0.0 0. 0. 0.0 ' 0.0 0.0 0.0 0. 0. 0. 0 0.0 0.0 0.0 M/Z = 333.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak it R. T. fi rst min. scan max sc an 1ast peak scan width raw area c orr. area corr. % 1 12.375 251 257 269 2 12.375 251 257 269 18 199421 18 199421 152945 149318 100.00 97. 63 M/Z = 331.9 `First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak it R. T. f irst min. scan max sc an 1ast peak sc an u idt h raw area corr. area corr. * 1 12.375 251 257 268 2 12.375 251 257 268 17 169442 127707 100.00 17 169442 124009 97. 10 332/334 CALCULATION R-Glo b a l ( 0) = .6350 M/Z = 327.9 F irst peak iis b a s e 1ine drop corrected area. Second peak ii s t ange nt skimmed corrected area. Peak R. T. fi rst min. scan max scan 1ast peak sc an width raw area 1 12.395 252 258 269 2 12.395 252 258 269 17 207888 17 207880 M/Z = 321.9 First peak is baseline drop corrected area, Second peak is tangent skimmed corrected area. Peak * R. T. f irst m in . sc an max sc an 1ast sc an 12.395 253 258 274 12.395 253 258 274 -------;. \T * SUBJECT TO P i . i t i . ORDER. peak width 21 21 raw area 670010 670010 . c orr. area 159787 155741 corr. ar e a 6ie539 607489 corr. k 100.00 97.47 corr. 100.00 98.20 C11029 s M/2 = 315.9 First peak is b a s e l i n e drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak H R.T. f irst min. scan max sc an 1ast peak scan u idt h raw area 1 ,12.395 252 258 268 2 12.355 252 258 268 16 554384 16 554384 7 8 3 i3 o corr. area 513920 580472 c orr. * 100.06 97.38 320/322 CALCULATION R-GlobalC 1) = .8309 M/2 = 257.0 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. P eak # R.T. fi rst min. sc an max sc an 1ast peak scan ui dt h raw area 1 12.395 251 253 271 2 12.395 251 253 271 20 364735 20 364735 corr. area 290935 285515 corr. * 180.60 98. 14 <320 + 322) / C332 +334) CALCULATION R - G 1o b a l < 3) = 4.0351 <328')/<332 + 334) CALCULATION R-Glo b a l < 3) = .5495 .i SUBJECT Tn-J IT C11030 File >3131 33 3 . 6 - 3 3 4 .6 am u .2UL .2504/ ,43 / .20 SP23 30 20 G- 1 / 3 / 2 5 0 GT BT F i l e - >B 3 1 3 1 3 2 1 . 6 - 3 2 2 . 6 a m u . 2 U L . 2 5 0 4 / . 4 3 / . 2 3 S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 GT BT C11031 MS data file header from >B3131 Sample: 2UL .2504/.48/.20 Operator: ROY MS 11/05/84" 6:52 * Mise : SP2330 200-1/3/250 GT BTL#29 BTL#29 Sys. 4: 1 MS model: 87 SU/HU rev.: Cfi ALS # : 0 Method'file: SP2330 Tuning file: APEI01 No. of extra records: 2 Source temp.: 248 Analyzer temp.: 0 Transfer line temp. ; 0 Chromat ograph ic temperatures : 0, 0. 0. 0. 0. Chrom at ograph ic times, min. : 0.0 0.0 0.0 0. 0 0.0 Chromat ographi c rate, deg/min: 0,0 0. 0 0.0 0.0 ' 0. 0 - M/Z = 333.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak ft R. T. fi rst min. scan max sc an 1ast peak scan width raw area corr. area corr. * 1 12.376 250 257 270 2 12.376 250 257 270 20 524902 470402 100.00 20 524902 461832 98. 18 11/2 = 331.9 F irst peak is b a s e 1ine 1drop corrected area. Sec ond peak is tangent skimmed corrected area. Peak 4 R. T. fi rst min. scan 1 12.376 2 12.376 252 252 max sc an 257 257 1ast peak sc an width 271 19 271 19 raw area 433748 433748 corr. area 384082 379313 corr. * 1G0.00 98.76 *- 332/334 CALCULATION R-Glo b a l < 0) = .8165 M/Z = 327.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R. T. first min. scan max scan 1ast peak scan width raw area 1 12.396 252 258 271 2 12.396 252 258 271 19 55G359 19 550359 M/Z = 321.9 F irst peak is baseline drop corrected area. Sec ond peak is tangent skimmed corrected area. Peak 4 R. T. fi rst m in . sc an max scan 1ast pe ak scan width raw area 1 12.396 2 12.396 252 258 275 252 258 275 - -- "--r \ T --.nc Q T O P R O T E C T ; * = SUBJECT 23 303091 23 303091 ftri* v < > corr. area 492295 484552 corr. A 180.60 98.43 - _ corr. area corr. 'A 246281 241037 100.00 97.87 C11032 *" M/Z = 319.9 First peak is b a s e l i n e drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak R. T. f irst min. scan max sc an 1ast peak scan u idt h raw area 1 * 12.396 25 253 274 2 12,396 253 258 274 24 275452 24 275452 Q3) 3 corr. area 214564 212416 corn. 7. 100.00 99. 03 320/322 CALCULATION R - G 1o b a l < 1) = .8712 M/Z = 257.0 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. first min. scan max scan 1ast peak sc an width raw area 1 12.396 253 258 269 16 174909 2 12.396 253 258 269 - 16 174909 c orr. area 116653 112437 corr. W 100.00 96.39 <320 + 322)/< 332 +334) CALCULATION R-Global< 3) = .5393 <328")/<332 + 334) CALCULATION R - G l o b a U 3) = .5735 CC? c " f T W i V " 1`' :XL _jz_.r-L 70 C11033 Fi le- >3132 333.6-334.6 &ihu.2UL UT-3056 SP2330 260-1/3/250 RUN ET File >3132 321.5-322.6 amu.2UL UT-3056 SP2336 260-1/3/250 RUN ET ic .-_ra. ; e ''(Pacer fr en ; >33* 2 '-'Tiple: 2'L'L *J:- :=05t* l"v,e r a t o r : ROY Mise : SP233G 200-1/3/ 0 RWh"~ 3Ti_-75 B T l Sy. - * * MS mode 1 : 87 $*/ HW r e v .:: CA Method file: SP2330 uning fiie: A^EIO' Source temp.: 250 Analyzer temo,: 0 '/ 0 5 / 3 4 ho. of extra records: 2 Transfer line temp. : 0 temperatures : Q. 0. 0. 0. n < 1 1m e s . min. : 0.0 0.0 0.0 0.0. oTo rate, deg/nin: O.C 0.0 0.0 0.0 G.C y./2 * 333.9 r iTSZ peak ease im e crop corrected area. Second peak is tangent sKinmeG corrected area. Peak F R .T . min. irsi scan max scan :as t Peak scan (J1C tM rau ar ea cor:. area corr . a 1 12.375 252 257 270 2 12.375 252 257 270 18 203827 48 203827 '55' :9 152275 i00.CC 98.17 :V Z - Ow TI C l - i r s t ce arc rase m e croc corrected area. Second pea* is tangent skimmed correctec area. -eak - R. '. f i rs t m m . scan ' 12.375 2 12.275 250 250 max scan 257 257 last p e ak scan u id m 2? fi 270 20 20 rau area 180^*2 `809*2 co rr * S-T 1Z*K -tZ~-1 *26722 corr, /; 1 0 0 . OP 97.09 14 232/334 CALCULA TIj .N R - G 1ocal ( 0 ) - M/Z = 327.3 -irst peak :s easel m e dr o p cor rectec area. Second peak is tangent skimmed cor rectec area. Peak f R.T. min. I 12.395 2 12.395 - irst scan 252 252 max scan 258 258 last scati 27G 270 p eak uictn 1^.!'COO/ rau area Pi'_LOl--J.DO^OO-Q_<tO^jcr:.J M/Z = 22:.9 -irsi peak is easel ine drc d cor rectec =r e a . Second peak is tangent skimmed cor rectec area. Peak * R.T. f irst min. scan max scan r n 7 -r""tS -J ' is** " * *A ' SUBJECT TO PROTECTIVE last oea< scan u idth ' ^ O O Q 3 2- r~ j ar-- a CO TT ar ea 700*3 '63337 cor r . A 100,00 36.23 corr . area corr. j (/> V. e: Ivj*.1 i',i 'oI ' :m t (i * M- i Cf . I'l (> li n P3 -5 0 C11036 r*j fO f\i O-*CO (>lJ1?<LnO r-Ojltr/l cnofl ron.*or*nj CO i*n ICl\TjjirrO_jl "'j--j oo(onor<ooon UD LO oj -j no co u> Cu'iJoO \f Oo CZ f U 1 UJ M ./ L * ."i -1rs: pea* is oaseline crop corrected area. Second Pea; is tangent skimmed corrected area. -eax ~ 7 R.T. min. 12.41 5 12.415 T 1 rs t scan 256 256 max scan 259 259 iast scan 2o8 268 peak width o 12 rau area 10070 40070 13 Z . cor: . area 8990 9492 corr. X 100.00 O/i .Z10 12 0/ 32 2 C A l C'JLA :ION R-ioca:( ') = .7598 '1/2 = 257.0 r i r s t oeai is D aseiir.e drop co rre c te d area. Second peaK i s tangent skimmed c o r r e c t e d a r e a . 3 ea< *, 2 R .T . first riti. scan '2.4": 5 2.A'5 25^ 254 max scan 258 259 last scan 269 266 sesie width * T raw area 54Q4 54041 corr. ar ea 7787553 corr/ /< 00. OC 97.07 (220 - 322)/(322 +334) CALCULATION R-GiODai( 3) = .0729 (722' >/<222 * 334 > C4l CULAIN n - G l o calf 3) = .5949 riT; 134 C11037 R ile >53133 3 4 . 6 alTMJ 2 UL U T - 3 0 5 7 S P 2 3 3 0 2 O 0 - 1 / 3 / 2 5 O RUM T f i l e >3133 3 2 1 .6 - 3 2 2 .6 amu.SUL UT-3057 2006- >v S P 2 3 3 0 2 0 0 - 1 / 3 / 2 5 0 RUN E T -Jy-v U i 1 ` ---------- --------) > - l ` ` ` l i t i i | ! r--r i i i i i i i ` ' h -- i | i-- n -- 1-- \-- :-- i t t | -- r r r r p -I i i i i 10.0 10.5 11 .0 11.5 12.0 12.5 13.0 1 3.5 14.0 14. 5 15.0 3133 3 1 3 .6 - 3 2 6 .6 amu.2UL UT-3057 S P 2 3 3 0 2 O O - 1 / 3 / 2 5 0 RUN E T Wa .'EJECT* TO-- > i _ V *rJ */*i--t .-ki-'Wl'C 0013! C11038 MS data file header from > B 3 133 Sample: 2UL UT-3057 Operator: ROY MS 11/05/84 Mise : SP2330 200-1/3/250 RUN BTL#77 BTLK77 Sys. #: 1 MS model : 87- SU/HW reo : CR ALS # : 0 Method f i 1e: SP2330 Tuning file: APEI01 No.' of extra records: Source temp.: 248 finalyzer t e m p . ; 0 Transfer 1ine temp. : C h r o m a t o g r a p h ic te mperatures : 0. 0. 0. 0. 0. ^ Chroma to gr ap hi c t im e s , min. : 0.0 0.0 0.0 0.0 0. 0 C h r o m a t o g r a p h ic rate, deg/min: 0. 0 0.0 0.0 0.0 0.0 7:34 M/Z = 333.9 First peak is baseline drop corrected area. Second peak is tangent sk immed corrected area. Peak R. T. fi rst m in . scan m ax sc an 1as t peak sc an width rau area corr. area c orr. sm 1 12.415 253 259 271 2 12.415 253 259 271 18 310151 18 310151 260291 253343 100.00 97.33 M/Z = 331.9 * First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. P eak # R.T. f irst min. sc an max scan 1ast `peak scan width rau area corr. area corr. 1 12.415 2 12.415 251 259 c*S 1 259 272 272 21 277458 221556 100.00 21 277458 ` 215392 97.22 332/334 CfiLCULRTI ON R - G 1ob a l < 0) = .8512 M/Z = 327.9 F irst pe ak is b ase 1ine drop corrected area. Sec ond p e ak is tang ent skimmed corrected area. ** Peak * R.T. fi rst min. sc an max scan 1ast peak sc an width raw area c orr. area 1 12.435 254 260 273 2 12.435 254 268 273 19 3455 i6 286445 19 345516 280070 M/Z = 321.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. eak R.T. f irst m ax 1ast peak 4 fuin . scan sc an sc an u idth raw area 1 12.435 2 12.435 'W . . -- ! ) 255 260 264 255 260 264 Q 30993 9 30993 . - *i '-i-- 1 001 H6 r*" t"~-^7;VF O R D E R . corr. area 7215 4888 corr. * 100.00 97. 77 corr. 108.00 67.75 G11039 S rvz = 319,9 Fi rs t peak is b a s e l i n e drop corrected area. S e c o n d peak is ta ng en t s k i m m e d c o r r e c t e d area. Peak # R.T. first min. scan max scan 1as t peak scan ui'dt h r aw area 1 r-12. 476 255 262 268 13 41741 2 12.476 255 262 268 13 41741 ^3(33 com. area 7967 7830 corr. 100.00 98.28 320/322 CALCULATION R - G 1o b a l < 1) = 1.1042 M/Z = 257.0 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. fi rst min. scan max sc an 1ast peak scan width raw area 1 0.000 2 0.000 269 269 0 268 0 268 -1 -1 0 0 com. area 4058 4058 com. *4 100.00 100.00 <320 + 322 >/<332 +334) CALCULATION R - G l o b a l < 3> = .0315 C323'>/<332 + 334 > CALCULATION R-Glo b a l < 3> = .5943 001 .v -,W .A . --. II 1 ' J ' 'V -c t p /e e s c C11040 File >E3134 4.6 amu.2UL UT-3058 SP2330 206-1/3/250 RUN ET File >E 3 134 321.6-322.6 m u . UL UT-3058 SP2339 200-1/3/250 RUN BT SUBJECT X C11041 MS data file header from > B 3 134 Sample: 2UL UT-3G58 Operator: ROY MS 11/65/84, 7:54 Mi sc : SP2330 200-1/3/250 RUN BTL#79 BTL#79 Sys. i : 1 MS model: 87 SU/HU rev.: CA ALS * : 0 Method file: SP2330 Tuning file: APEI01 No. of extra records: 2 Source temp.: 250 Rnalyser temp.: 0 Transfer line temp. : 0 " rChromt ographi c temperat ures : 0. 0. 0. 0. 0. Ch rom at ograp h ic times, min. : 0.6 6.0 0.0 0.0 0.0 Chromatographic rat e, deg/mi n : 0.0 0. 0 0.0 0.0 0.0 M/Z = 333.9 First peak is baseline drop corrected ar ea Second peak is tangent sk immed correc ted area. Peak # R.T. f irst min. sc an max sc an last peak scan width raw area corr. area corr, *4 1 12.386 247 257 269 2 12.386 247 257 269 22 311507 251975 100.06 22 311507 244627 97.08 M/Z = 331.9 Fi rst peak is baseline drop corrected area. Second peak is tarigent skimmed corrected area. Peak # R.T. f irst min. sc an max sc an 1ast peak sc an width raw area corr. area corr. V. 1 12.386 231 257 269 12386 251 257 269 18 256725 212445 100.00 18 256725 204543 96.28 332/334 CALCULATION R - G l o b a l < 0) = .8431 M/Z = 327.9 First peak is base 1ine drop1 correc ted area. Sec ond peak is t ang ent skimmed corrected ar ea . Peak # R.T. f irst min. scan max sc an 1as t peak scan width raw area 1 12.466 251 258 267 2 12.406 251 253 267 16 310916 16 310916 M/Z = 321.9 First peak is base 1in e drop corr seted area. Second peak is tang ent skimmed corr ec ted area. Peak 4 R.T. fi rst min. sc an m ax sc an 1ast peak scan width raw area 1 12.406 255 253 261 2 12.406 255 258 261 6 6 0^4 24773 24773 C\ '? ;~rr t -' ''i"-- 7 ---. ** . corr. area 253116 248116 corr. % 100.00 96. 13 corr. area 9185 7025 corr. 10.00 76.48 G11042 MxZ = 319.9 First peak is b a s e l i n e drop corrected area. Se c o n d peak is ta ng en t s k im m e d c o r r e c t e d area. Peak tt R. T. fi rst min. scan max sc an 1ast peak sc an width raw area 1 ,12.466 254 258 267 13 42683 *2 12.406 254 258 267 13 42683 7 3 3 1 3<f corr. area 8272 7979 corr. 7. 100.00 96.46 320x322 CALCULATION R - G l o b a U 1) = .9006 MxZ = 257.0 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R. T. first min. sc an max scan 1ast peak scan width raw area 1 6.000 2 0.000 257 257 0 256 0 256 -1 -1 0 0 corr. area 4558 4558 corr. y 100.00 100.00 <320 + 322)/<332 +334> CALCULATION R-G 1o b a 1< 3) = .0376 <32S')x<332 + 334) CALCULATION R - G l o b a l < 3) = .5556 C11043 File >3135 333.6 --3 34.6 aitiu .3UL UT 3059 SP2330 200-1/3/25 RUN BT File >3135 321.5-322.6 amu.SUL UT-3059 SP2330 200-1/3/250 RUN BT m 5 ! !5. '\r C11044 MS dit a file header from > B 3 135 Sample: 2UL UT-3059 Operator: ROY MS 11/05/84 Mise : SP2330 200-1/3/250 RUN BTL#81 BTL#81 Sys. #: 1 MS model 87 SU/HU rev'. : Cfi fiLS # : 8 #Method filei SP2330 Tuning file: fiPE101 No. of extra records: Source temp,: 248 finalyzer te m p . : 0 Tran sf er 1 ine temp. : 8 cChrornat ograph ic temperatures : 0. 0. 0. 0. 0. Chromatographi c times, min. : 0.0 0. 0 0.0 0. 0 0.0 Chr om atographi c rate, deg/min: 0.0 0.0 0. 0 0.0 0.0 M/Z = 333.9 First peak is baseline drop corrected area. Second peak is-tangent skimmed corrected area. Peak * R. T. fi rst min. scan max scan 1ast peak scan u idt h rau area corr. area corr. *4 1 12.372 252 259 268 2 12.372 252 259 268 16 238576 198816 100.00 16 238576 190088 96. 00 M/Z = 331.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak 4 R. T. f irst min. scan m ax. 1ast peak sc an sc an width rau area corr. area corr. % 1 12.372 250 259 273 2 12.372 250 259 273 23 223423 166153 100.00 23 223423 161334 97. 10 332/334 CftLCULftTI ON R-Global< 0) = .8391 M/Z = 327.9 F irst peak is base 1ine drop corrected an ea . Second peak is tang ent ski mmed cor rect ed area. Peak # i- f irst min. scan max sc an 1as t peak sc an ui dt h rau area 1 12.393 255 260 271 2 12.393 255 260 271 16 258380 16 253300 M/Z = 323.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. R. T. fi rst m ax 1as t peak # m in . sc an sc an sc an width rau area 1 12.393 255 260 271 2. -12.39-3. 255 260 271 ' V** - 16 46945 16 46945 > 0014: c orr. area 212636 207076 corr. V, 100.00 97.39 corr, at*ea 7441 6353 corr. /% 100.00 35. 33 G11045 M/Z - 319.9 F i r s t p e a k i s. b a s e l i n e drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak tt R.T. f irst min. scan max scan 1ast peak sc an u i-dt h r au area 1 t12,393 258 260 265 2 12.393 253 260 265 7 23683 7 23883 >3I3S corr. area 5359 5282 corr. * 100.00 98.56 328/322 CALCULATION R - G l o b a K 1) = .7202 M/Z = 257.0 First peak is baseline drop corrected area. Second peak is. tangent skimmed corrected area. Peak # R.T. fi rst min. scan m ax sc an 1ast peak scan u idth rau area 1 0.000 2 0.000 266 266 0 265 0 265 -1 -1 0 0 corr. area 3787 3787 corr. 100.00 100.00 <320 + 322)/< 332 +334) CALCULATION R - G l o b a l < 3) = .351 <329')/<332 + 334) CALCULATION R - G l o b a l < 3) = .5837 I *' 4-5 C11046 F i l e >E3136 333.6-334.6 amu.2UL UT-3073 SP2330 20O-1/3/250 RUN BT File > B 3 136 321.6-322.6 a m u .^UL UT-3073 SP2330 200-1/3/250 RUN BT 2G00- II -Ksfi\*S'f'i*-- -- VV''-- 'VA1 0_ , 1 T ^ t 10.0 10.5 1111I.01 1~,~1l1l.51 1 1112l.01 1 1112l.51 File >33136 257.7 amu.SUL UT-3073 | I |'f - .! ^ . , . , | , I | 13.0 13.5 14.0 14.5 15 0 SP2330 206-1/3/250 RUN BT C11047 MS d a t a file h e a d e r f r o m 36: > B 3 1 Sample: 2UL UT-3073 Operator: ROY MS 11/05/84 8: Mise : SP233 200-1/3/250 RUN BTL#83 BTL#83 Sys>. #: 1 MS model: 87 SW/HW rev.: Cfl RLS # : 0 Method file: SP2330 Tuning file: APE101 No. of extra records: 2 Source temp.: 248 Analyzer temp.: 0 Transfer line temp. : 0 Chromatographi c temperatures : 0. 0. 0. 0. 0. Chromatographi c times, min. : 0.0 0.0 0. 0 0.0 0.0 Chromat ographi c rate, deg/min: 0.0 0. 0 0.0 0.0 0.0 M/Z = 333.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R. T. first ruin . scan max sc an 1ast peak scan wi dth rau area corr. area corr. * 1 12.379 251 25S 271 2 12.379 251 258 271 20 281696 232916 100.00 20 281696 228696 98. 19 M/Z = 331.9 First peak is b a s e l ine drop corrected area. Second peak is tangent sk immed corrected area. Peak * R. T. f irst min. scan max sc an 1ast peak sc an width raw area corr. area corr. 7. 1 12.379 248 258 270 2 12.379 243 258 270 22 246911 22 246911 193055 186488 100.00 96. 60 332/334 CALCULATION R-Global< 0) = .8289 M/Z = 327.9 First pe ak is basel ine drop corree ted ar ea . Sec ond peak is t an ge nt sk im m e d ,corree ted area. Peak # R. T. f irst m in . scan max scan 1ast peak scan width raw area m * corr. area 1 12.399 247 259 270 2 12.399 247 253 270 23 297042 33677 23 297042 224943 M/Z = 321.9 F irst peak is basel ine drop cor reeled ar'ra > Sec ond peak is tange nt skimmed corrected area. Peak R.T. first min. sc an max sc an 1ast peak sc an w idth raw area corr. area 1 12.399 257 259 261 2 12.399 257 259 261. 4 4 noi..ib 14562 14562 4314 3716 it-1 70 PSOTCnVE ORDER, corr. 7 100.00 96.26 corr. " 100.00 86.14 C11048 S M/Z = 319.9 First peak is b.aseline drop corrected area. Se c o n d peak is ta ng en t sk im me d c o r r e c t e d area. Peak R. T. fi rst min. scan max scan 1ast peak sc an width raw area 1 ,r 12.399 2 12.399 2*<5e*2 259 259 263 268 16 44997 16 44997 ^ B3i3C? corr. area 4901 4605 corr. * 100.00 93.96 320^322 CALCULATION R-GlobalCl) = 1.1361 IVZ = 257.0 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak * R.T. f irst min. scan max scan 1ast peak scan width raw area 1 0.000 2 0 000 269 269 0 263 -1 0 268 . -1 0 0 corn. area 3688 3688 corr. * 100.00 100.00 C320 + 322) ^ <332 +334) CALCULATION R-GlobalC 3) = .0216 C32S')/'C332 + 334) CALCULATION R-GlobalC 3) = .5485 on* *o C11049 File >B31 333.6-334.6 amu.^UL 2 .564/.43/.20 S P 23 30 2 O 6 - 1 / 3 / 2 5 0 GT ET File >3137 321.6-322.6 amu-.UL 2.564/. 43/ .28 3F2330 260-1/3/250 GT BT nS data file header from > B 3 137 Sample: 2UL 2.504/.48/.20 Operator: ROY MS 11/05/84 Misc : SP2330 200-1/3/250 CT BTL#41 BTL#4l Sys. #: 1 MS model: 87 SW/HU rev.: Cfl flLS # : 0 Method file: SP2330 Tuning file: RPEI01 Source temp.: 248 finalyzer t e m p . : 0 Ho. of extra records: Transfer line temp. e ?Chromatograph!c temperaturei : 0. 0. 0. 0. 0. Chromatographi c t imes, min. : 0.0 0. 0 0.0 0.0 0.0 Chrom atdgraph ic rat e , deg/mi n: 0.0 0. 0 0.0 0.0 0.0 M/Z = 333.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. first min. scan m ax scan 1ast peak scan width raw area corr. area corr. 1 12.374 252 257 272 2 12.374 252 257 272 20 512301 464061 100.00 20 512301 457901 98.67 M^Z = 331.9 First peak is base 1ine drop corrected area. Second peak is tangent skimmed corrected area. Peak # R. T. fi rst min. scan max sCan 1ast peak scan width raw area corr, area corr. 5i 1 12.374 247 257 270 12.374 247 .cw*1"17 270 23 430776 375231 100.00 23 430776 367744 98.00 332/334 CfiLCULfiTIOH R - G 1obal< 0) = 8086 M/Z = 327.9 F irst peak is b a s e 1ine drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. f irst min. scan max scan 1ast peak scan w idth raw area 1 12.394 253 258 271 2 12.394 253 258 271 18 520261 18 520261 M/2 = 321,9 F irst peak is baseline drop corrected ar ea. Second peak is tangent. sk immed correct ed at*'ea . Pe ak ft P. T. first min. scan m ax s c an 1ast peak sc an w idth raw aI*a 1 12.394 246 258 271 12.394 246 258 271 25 227S243 25 2278243 Q c orr. area 471769 466036 corr. * 100.00 98. 78 corr. at*e a corr. 2214793 2174668 100.00 98. 19 C11051 M^Z - 319.9 First peak is baseli ne drop corrected area. Second peak is tangent skimmed corrected area. Peak R .T. fi rst min. scan max sc an 1ast peak scan u idt h rau area 1 * 12.394 249 258 272 2 12.394 249 258 272 23 1874580 23 1874580 >3313 7 corr. area 1818966 1791136 corr. * 100.00 98.47 320x322 CfiLCULATION R-Global< 1> = .8213 M/Z = 257.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. fi rst min. scan max sc an 1ast peak scan width raw area 1 12.394 250 258 273 2 12.394 250 253 273 23 1050625 23 1050625 corr. area 965341 955163 corr. Ji 100.00 98.95 <320 + 322)/(332 +334) CfiLCULfTION R - G 1ob a l < 3) = 4,8061 <323')s<332 + 334 ) CALCULATION R-Glo b a l < 3> = .5384 00149 SUBJECT. TO p r o t e c t iv e o r d er . C11052 F i l e > 3 1 3 3 3 3 3 . 6-33*4.6 a m u .2 U L 2 5 . 0 4 / . 4 8 / . 2 0 S P 2 3 3 6 2 6 0 - 1 / 3 / 2 5 0 GT ET File >3138 321.6-332.6 am u .2UL 25.04/. 48/ .20 SP2330 200-1/3/250 GT -BT SUBJECT TO PROTECTIVE ORDER. ^ C11053 MS data file header from : >B3138 Sample: 2UL 25.04/.48/.20 Operator: ROY ns 11/85/84 ' : 15 Misc : SP2330 288-1/3/258 GT BTL443 BTL443 Sys. #: 1 US model: 87 SIJ/HW rev.: CA RLS # : 0 Method file: SP2330 ` Tuning file: RPEI01 No. of extra records: 2 Source temp.: 250 Analyzer temp.:- 8 Transfer line temp. : 0 Chromatographi c temperatures .: 0. 0. 0. 0. 0. Chromatographic times, min. : 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 M/Z = 333.8 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak t R.T. f irst min. scan max* 1as t peak scan scan u idt h rau area corr. area corr. * 1 12.402 245 260 268 2 12.402 245 260 268 23 594999 538235 100.00 23 594999 527287 97. 97 M/Z =* 331.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak it R.T. f irst min. scan max sc an 1ast peak sc an w idt h raw area corr. area corr. y. 1 12.402 250 268 275 2 12.402 250 260 275 25 496056 436156 100.00 25 496656 432081 99.07 332/334 CALCULATION R - G l o b a l < 0) = .8103 M/Z = 327.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. first min. scan max scan 1as t peak sc an width rau area corr. area corr. 4 1 12.422 252 261 273 2 12.422 252 261 273 21 819857 767294 100.80 21 819857 759377 98.97 M/Z = 321.9 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak 4 R.T. f irst min. scan max sc an 1ast peak scan width rau area corr. are a corr. '4 1 12.422 252 261 270 2 12.422 252 261 276 18 25792552 25748143 18 25792552 25407972 108.06 98.68 Si-/ ,, SUBJECT TO PPS.T." j .\ * ** it twHm vi ---'- st t G11054 = 319.9 First peak is b a se li ne drop corrected area. S e c o n d peak is t a n g e n t s k i m m e d c o r r e c t e d area. Peak # R.T. fi rst min. scan max' 1ast peak scan scan width raw area corr. area 1 rl2.442 249 262 272 2' 12.44-2 249 262 272 23 21171796 21112984 23 21171796 20842836 ^55/3^ corr. 100.00 98.72 320^322 CALCULATION R - G 1o b a l ( 1> = .8200 M-'Z * 257.0 First peak is baseline drop corrected area. Second peak is tangent skimmed corrected area. Peak # R.T. fi rst min. scan max sc an 1ast peak scan width rau area corr. area 1 12.442 250 262 274 2 12.442 250 262 274 24 11339390 11262638 24 11339390 11137286 corr. * 100.00 98.89 C320 + 322 )s'(332 +3345 CALCULATION R - G 1o b a l < 3) = 48.G927 <328'>/(332 + 334 > CftLCULRTI ON R-Glo b a l < 3) = .5496 fr^ -- ------------ tU'u __ -,K.L SUBJECT TO PROTECTIVE ORDER. C, * ' C11055 <9 333 .- 334 . .fii'j.BBECSNE .v^fVv\`/tv,' w v,'vv,V- -- * SP2330 2 0 G - 1/3/258 RUN BT i i t i i i "i1r r 7 i "t "i "i T H "i i p n n i .0 10.5 11.0 11.5 12.0 12.5 39 331 .6-332.$" amu.PODEXfiNE r r t T T T T r f r r r r i ' n --i--i--j 13.0 1133..55 14.0 14.5 15..0 SF2330 200-1/3/250 RUN BT i- 0 . 0 ' 1 0 . 5 1 ' U . 8 r r i V . 5 ' 1 1 2 . 0 ' ' 1 2 . 5 1 3 , 0 13 ."5 1 4 . 0 ^ M . S ' I S . 0 139 3 2 1 . 0 - 3 2 2 . 6 fiiu . DOBECflNE 1 SP2330 200-1/3/250 RUN BT O1^ -i 1 r r p T <--i--i-- --1-1 y m --1--p - i - 1--1-- - i - t - i -t y t i--r r y r~r r r f r 1--1--1--|- 1 10.0 1.5 11.0 11.5 12. 12.5 13.0 13.5 14.0 14,5 -r--, 15.0 3139 319.6-320.6 s m u .BGDECAME SP2338 200-1/3/250 RUN BT 2273264 t^L ' 2^ -- OHru^r^ '5 fJi ^ 2.JI J 57 3