Document gbX7Qb0vq440rJrQrGgKg5pNQ
MATERIAL SAFETY DATA SHEET
159
(Approved by U.S. Department of Labor as "essentially similar" to FORM OSHA-20)
r SECTION I IDENTIFICATION OF PRODUCT
MANUFACTURER'S NAMS
Tenneco Chemicals, Inc., organics & polymers division
EMERGENCY TELEPHONE NO.
609 386-9200
ADORESS
TURNER PLACE, P.0. BOX 365, PISCATAWAY, NEW JERSEY 08854
TRADE NAME ANO SYNONYMS
Tenneco PVC Copolymer Dispersion Resin 0565
CHEMICAL NAME ANO SYNONYMS
Vinylchloride - Vinyl Acetate Copolymer, VC/VAc Copolymer
CHEMICAL family
MOLECULAR FORMULA
Chlorohydrocarbon copolymer
{CH-CHC1). {CH9CH0C0CH->
MOL. w:
3 S'- OOj 00 9
SECTION II HAZARDOUS COMPONENTS OF MIXTURES
COMPONENT
THRESHOLD % limit *
VALUE
COMPONENT
Ithresmc % I LIMIT
1 VALUE
OSHA Standard 1910.93(.1017) on vinyl chloride sets a permissible exposure limit ol
1 ppm averaged over a3y 8 hour period and 5 ppm over any 15 minute period. On the basi
that polyvinyl chloride may contain and release small amounts of monomer, the Standard applies to the manufacture, reaction, packaging, repackaging, storage, handling, use or
transportation of PVC, but not to handling or use of "fabricated products", as defined, if not subject to processing sufficient in time or temperature to cause mass melting.
appearance and odor
SECTION III PHYSICAL DATA
White powder, faint ester odor.
BOI LING POINT (DEGREES FAHRENHEIT)
Not applicable
VAPOR PRESSURE (MM OF MERCURY)
Not applicable
VAPOR DENSITY (AIR - 1)
Not applicable
SOLUBILITY IN WATER
Negligible
MELTING POINT (DEGREES FAHRENHEIT)
Not applicable. ' Softens about 140-160F
SPECIFIC GRAVITY (WATER - 1)
1.4
PERCENT VOLATILE 1 BY WEIGHT)
Approx. 1% (MOISTURE)
evaporation rate
(BUTYL ACETATE - 1)
Not applicable
SECTION IV FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (SPECIFY METHOD)
iofoegrrwee.s_fnahremnhe.itil9__2_<_n
fire extinguishing media
Ignition
about
_,,_o_
735 F
Flammable limits (PERCENT BY VOLUME)
LOWER
UPPER
Not applicable
Water spray, carbon dioxide or dry chemical.
special fire fighting procedures
Water spray or fog may be helpful in reducing flame intensity and absorbing irritating fumes.
. . --. r\r% -mo
UNUSUAL fire and explosion hazards
NFPA lists ignition temperature of 1274F. for dust cloud. Produces combustible gases
above 570 F. Fire conditions produce hydrogen chloride, requiring protective equipmen
TEM0 143-
This information if furnished without wirunty, representation, inducement or license of any kind, except chat it u accurate to the best of Terntec
.... L . , -j v.w
n-i tr\ Kf nvnifatr and Tenneco Chemical* does not a mu ms any lets I
SECTION V HEALTH HAZARD DATA
threshold limit value
mr 'T'Trn tt - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -
efI^P^or overexposure None expected - Inert resin. See Section IX. Prolonged breathing of concentrated dust may be harmful. (Processing at high temperatures produces fumes irritating to eyes and respiratory tract requiring local exhaust.)
emergency and first aio procedures
Ordinary measures of personal hygiene. In case of exposure in hot processing move to fresh air, flush eyes with water.
SECTION VI REACTIVITY DATA
STABILITY
UNSTABLE STABLE
INCOMPATIBILITY (MaUriaU to avoid)
None in ordinary use.
conditions to avoid Normal processing temperature, about 350F, causes slow darkening and decomposition. Higher X heat increases rate and evolution of HC1.
Soluble in certain ketones and organic solvents.
HAZARDOUS DECOMPOSITION PRODUCTS
0
Thermal decomposition produces HC1, and CO and COj (above 570 F)
MAY OCCUR HAZARDOUS POLYMERIZATION
WILL NOT OCCUR
CONDITIONS to avoio
X 'None in ordinary use.
SECTION VII SPILL OR LEAK PROCEDURES
TO BE Taken in case material is released or spilled
Sweep up and remove to disposal container.
WASTE DISPOSAL METHOD
Bury in an approved landfill.
SECTION VIII SPECIAL PROTECTION INFORMATION
respiratory protection (Specify typai in case of concentrated dust, use Bureau of Mines approved
dust respirator (NIOBM TC-21C-132 or equivalent). See Sections II and IX.
VENTILATION
local exhaust
For hot processinz MEFCHoArNIoCrAdLi(nGaanrtryatt handling.
SPECIAL
Vent to elevated stack-
OTHER ,,,
,
Ventilate enclosed spaces.
PROTECTIVE gloves
Not ordinarily required
EYE PROTECTION
Safety glasses
other protective equipment None required for ordinary handling. For hot processing local exhaust, safety glasses and gloves are recommended.
SECTION IX SPECIAL PRECAUTIONS
precautions to be taken in handling and storing
^)SHA Standard 1910.93q (.1017) requires monitoring and other precautions in storage, handling and use of polyvinyl chloride, and also labeling of PVC "Contains Vinyl Chloride--Vinyl Chloride Is a CAncer-Suspect Agent."
New PVC resins with a low monomer content make it easier to operate below the OSHA actior
level of 0.5 ppm in a processor's work area, assuming normal conditions and ventilation,
simplifying compliance with some of the regulatory requirements. Further developments
nt realnfl and on regulations are pending.------------------------------------------------------tet; LUCK
DATE
ft/S/7S
NAME AND TITLE
T. R. AALTO. MANAGER, PRODUCT SAFETY SERVICES
SHEET NUMBER
159
MATERIAL SAFETY DATA SHEET
(Approved by U.S. Department of Labor as "essentially similar" to FORM OSHA-20)
wmtH 158
SECTION I IDENTIFICATION OF PRODUCT
MANUFACTURE M'S NAME
Tenneco Chemicals, Inc., organics & polymers division
EMERGENCY TELEPHONE NO.
609 386-9200 201 782-4011
ADDRESS
TURNER PLACE, P.0. BOX 365, PISCATAWAY, NEW JERSEY 08854
TRAOE NAME ANO SYNONYMS
314, 315, 382, 388, 389, 390, 391, 521 Tenneco PVC Copolymer Resin
CHEMICAL NAME AND SYNONYMS
Vinylchloride - Vinyl Acetate Copolymer, VC/VAc Copolymer
chemical family
Chlorohydrocarbon copolymer
MOLECULAR FORMULA
(CH-CHCl)' {CH CHOCOCH >
-__ l______
MOL. WT.
2,0 FOfi
SECTION II HAZARDOUS COMPONENTS OF MIXTURES
COMPONENT
THRESHOLD % LIMIT
value
COMPONENT
THRESHOL % LIMIT
VALUE
OSHA Standard 1910.93 (.1017) on vinyl chloride sets a permissible exposure limit of
1 ppm averaged over any 8 hour period and 5 ppm over any 15 minute period. On the basis
that polyvinyl chloride may contain and release small amounts of monomer, the Standard applies to the manufacture, reaction, packaging, repackaging, storage, handling, use or
transportation of PVC, but not to handling or use of ''fabricated products'), as defined, if not subject to processing sufficient in time or temperature to cause mass melting.
APPEARANCE AND ODOR
SECTION III PHYSICAL DATA
White powder, faint ester odor
BOILING POINT (DEGREES FAHRENHEIT)
Not applicable
VAPOR PRESSURE (MM. OF MERCURY)
Not applicable
VAPOR DENSITY (AIR - 1)
Not applicable
SOLUBILITY IN WATER
Negligible
\
melting point
(DEGREES FAHRENHEIT)
Not applicable. Softens about 140-160F
SPECIFIC GRAVITY (WATER * 1)
1.35 - 1.4
PERCENT VOLATILE (BY WEIGHT)
Approx. 1% (moisture)
EVAPORATION RATE (BUTYL ACETATE - 1)
Not applicable
SECTION IV FIRE ANO EXPLOSION HAZARD DATA
FLASH POINT (SPECIFY METHOD)
(DEGREES FAHRENHEIT)
Ignition about 735F
for PVC ?ASTM D-1929)
FIRE EXTINGUISHING MEDIA
flammable limits
(PERCENT 8Y VOLUME)
LOWER
UPPER
Not applicable
Water spray, carbon dioxide or dry chemical.
SPECIAL FIRE-FIGHTING PROCEDURES
Water spray or fog may be helpful in reducing flame intensity and absorbing irritating fumes.
UNUSUAL FIRE ANO EXPLOSION HAZARDS
NFPA lists ignition t mperature of 1274UF. for dust cloud. Produces combustible gases
above 570 F. Fire conditions produce hydrogen chloride, requiring protective equipment
TfiMO' 144-
This information if furnished Without warranty, representation, inducement or license of any kind, except that it is accurate to tfaa beta of Tenneco ^Tpnnwn Phemi<?aIm does not assume an* legal
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT value
sechqp ix-
Noneepf^rrs of overexposure expected - inert resin. See Section IX. Prolonged breathing of concentrated dust may be harmful. (Processing at high temperatures produces fumes irritating to eyes and respiratory tract requiring local exhaust.)
6MgRG6NCV AND FIRST AID PROCEDURES
Ordinary measures of personal hygiene. In case of exposure in hot processing move to fresh air, flush eyes with water.
c
SECTION VI REACTIVITY DATA
STABILITY
UNSTABLE STABLE
conditions to avoid Normal processing temperature, about 350 F, causes slow darkening and decomposition. Higher X heat increases rate and evolution of HC1.
1N COMPATI Bl LI T Y (MaUriait to avoid}
None in ordinary use. Soluble in certain ketones and organic solvents.
HAZARDOUS DECOMPOSITION PRODUCTS
Q
Thermal decomposition produces HC1,' and CO and CO2 (above 570 F)
HAZARDOUS
polymerization
MAY OCCUR WILL NOT OCCUR
conditions to avoid
X 'None in ordinary use.
t SECTION VII SPILL OR LEAK PROCEDURES
TO BE TAKEN IN CASE MATERIAL IS RELEA5EO OR SPILLED
Sweep up and remove to disposal container.
(
WASTE DISPOSAL METHOD
Bury in an approved landfill.
SECTION VIII SPECIAL PROTECTION INFORMATION
respiratory protection tspaafy typa) in case of concentrated dust, use Bureau of Mines approved
dust respirator (NIOBM TC-21C-132 or equivalent). See Sections II and IX.
VENTILATION
LOCAL EXHAUST
For hot processingt
MECHANICAL (Gtntral)'
...
For ordinary handling.
SPECIAL
Vent to elevated stack.
01^entilate enclosed spaces.
PROTECTIVE GLOVES
Not ordinarily required
EYE PROTECTION
Safety glasses
other protective equipment Hone required for ordinary handling. For hot processing local exhaust, safety glasses and gloves are recommended.
SECTION IX SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
OSHA Standard 1910.93^ (.1017) requires monitoring and other precautions in storage,
mandling and use of polyvinyl chloride, and also labeling of PVC "Contains Vinyl Chloride--Vinyl Chloride is a CAncer-Suspect Agent."
TENNECO. MATERIAL SAFETY DATA SHEET
(Approved by U.S. Department of Labor as "essentially simitar" to FORM OSHA-20)
157
SECTION I IDENTIFICATION OF PRODUCT
MANUFACTURER'S NAME
Tenneco Chemicals. Inc., organics & polymers division
EMERGENCY TELEPHONE NO.
609 386-9200
ADDRESS
TURNER PLACE, P.O. BOX 365, PISCATAWAY, NEW JERSEY 08854
trade name and synonyms TennecoPVC Dispersion Resin 1716, 1730, 1732, 1738, 1742, 1750, 1755, 1756, 1757
CHEMICAL name and synonyms
Poly(Vinyl Chloride), PVC
CHEMICAL FAMILY
Chlorohydrocarbon Polymer
MOLECULAR FORMULA
(CH,CHCl)n
MOL. WT,
SECTION II HAZARDOUS COMPONENTS OF MIXTURES
COMPONENT
threshold I % LIMIT
VALUE
COMPONENT
THflESMQL % LIMIT
VALUE
OSHA Standard 1910.93 (.1017) on vinyl chloride sets a permissible exposure limit of
1 ppm averaged over aSy 8 hour period and 5 ppm over any 15 minute period. On the basis
that polyvinyl chloride may contain and release small amounts of monomer, the Standard applies to the manufacture, reaction, packaging, repackaging, storage, handling, use or
transportation of PVC, but not to handling or use of "fabricated products", as defined, if not subject to processing sufficient in time or temperature to cause mass melting.
appearance and odor
White powder, Odorless.
BOILING POINT (DEGREES FAHRENHEIT)
Not applicable
VAPOR PRESSURE (MM. OF MERCURY)
Not applicable
VAPOR DENSITY (AIR - 1)
Not applicable
SOLUBILITY IN WATER
Negligible
SECTION III PHYSICAL DATA
ME lting point (DEGREES FAHRENHEIT)
Not applicable. Softens about 160-180F
SPECIFIC GRAVITY (WATER - 1)
1.4
percent volatile
I0Y WEIGHT)
Approximately 1%
EVAPORATION RATE (BUTYL ACETATE - 1)
Not applicable
(moisture)
SECTION IV FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (SPECIF Y METHOD)
---Or,
(degrees Fahrenheit)
-Ignition about 735 F
Auto ignition about 850F (ASTMD-1Q2Q1
fire extinguishing media
flammable limits
(PERCENT BY VOLUMEI
LOWER
UPPER
Not applicable
W..wawt*e-.r. spray, c--a--r--b--o--n----d, i1ox--i-d--e or dry chemical.
SPECIAL FIRE FIGHTING PROCEDURES
Water spray or fog may be helpful in reducing flame intensity and absorbing irritating fumes.
unusual FIRE AND explosion hazaros nFPA lists ignition temperatures of 752WF for layer
and 1220F for PVC dust cloud.
Produces,combustible gases
above 570 F. Fire conditions produce hydrogen chloride, requiring protective equipment.
--------------------------------------------------------------------------------------------------------------- ---------- TFNO '
on ,nao Thl1 in*ofm*tlon ,f furniahed without warranty, repretrntaliun. inducement or kcenae nf any kind, except that it isacninlr to the beet of Tenneco ,rt 90 2083 chimeiU' knowledc or obtain*) from source! believed by Tenneco Chemical! to be accurate, and Tenneco Chemical* doe* nm a\*ime .my lo*jl
SECTION V HEALTH HAZARD DATA
THHESMOLO LIMIT VALUE
EE SECTION LI None^ cts of overexposure expected - inert resin. See Section IX. Prolonged breathing of concentrated dust may be harmful. (Processing at high temperatures produces fumes irritating to eyes and respiratory tract requiring local exhaust.)
EMERGENCY ANO FIRST AIO PROCEDURES
Ordinary measures of personal hygiene. In case of exposure in hot processing move to fresh air, flush eyes with water.
'S,
SECTION VI REACTIVITY DATA
UNSTABLE STABILITY
STABLE
INCOMPATIBILITY (MattrlaU to avoid)
conditions to avoid Normal processing temperature, 350 F, causes slow darkening and decomposition. X heat increases rate and evolution of HC1.
None in ordinary use. Soluble in certain ketones and organic solvents.
HAZARDOUS DECOMPOSITION PRODUCTS
Thermal decomposition produces HC1, and CO and CO- (above 570 F)
about Higher
MAY OCCUR HAZARDOUS
POLYMERIZATION WILL NOT OCCUR
conditions to avoio
X None in ordinary use.
SECTION VII SPILL OR LEAK PROCEDURES
S TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Sweep up and remove to disposal container.
WASTE DISPOSAL METHOD
Bury in an approved landfill.
c
SECTION VIII SPECIAL PROTECTION INFORMATION
respiratory protection (Specify tym) in case of concentrated dust, use Bureau of Mines approved
dust respirator (NIOBM TC-21C-132 or equivalent). See Sections II and IX.
ventilation
local exhaust
For hot processing MEFCHoArNIoCArdLJiGneanryrol),han,d,li.ng.
SPECIAL
Vent to elevated stack.
OT$!ntilate enclosed spaces.
protective gloves
Not ordinarily required
EYE PROTECTION
Safety glasses
other protective equipment None required for ordinary handling. For hot processing local exhaust, safety glasses and gloves are recommended.
SECTION IX SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING ANO STORING
OSHA Standard 1910.93^ (.1017) requires monitoring and other precautions in storage,
mandling and use of polyvinyl chloride, and also labeling of PVC "Contains Vinyl hloride--Vinyl Chloride is a CAncer-Suspect Agent."
New PVC resins with a low monomer content make it easier to operate below the OSHA actioi
level of 0.5 ppm in a processor's work area, assuming normal conditions and ventilation,
simplifying compliance with some of the regulatory requirements. Further developments
nron resins and on regulations are pending. _____________________________________
teho
OATH
6/5/75
NAME AND TITLE
T. R. AALTO, MANAGER, PRODUCT SAFETY SERVICES
SHEET NUMBER
157
LTENNECOJ MATERIAL SAFETY DATA SHEET
(Approved by U.S. Department of Labor as "essentially similar" to FORM OSHA-20i
156
SECTION I IDENTIFICATION OF PRODUCT
' ' 3* .
MANUFACTURER'S NAME
Tenneco Chemicals, Inc., organics & polymers division
EMERGENCY TELEPHONE NO.
609 386-9200 713 479-3411
AOORESS
TURNER PLACE, P.0. BOX 365, PISCATAWAY, NEW JERSEY 08854
TRADE NAME ANO SYNONYMS Tenneco PVC Resin 175.200-2. 225. 225 PG. 250. 250-3. 10R. 501
CHEMICAL NAME AND SYNONYMS
Poly(Vinyl Chloride), PVC Homopolymer
CHEMICAL FAMILY
Chlorohydrocarbon Polymer
MOLECULAR FORMULA
(CH2CHCl)n
MOL. WT
SECTION II HAZARDOUS COMPONENTS OF MIXTURES
COMPONENT
OSHA Standard 1910.93
(.1017)
THRESHOLD % LIMIT
VALUE
on vinyl chloride
sets
COMPONENT
a permissible
exposure
threshol
% LIMIT VALUE
limit of
1 ppm averaged over any 8 hour period and 5 ppm over any 15 minute period. On the basis
that polyvinyl chloride may contain and release small amounts of monomer, the Standard applies to the manufacture, reaction, packaging, repackaging, storage, handling, use or
transportation of PVC, but not to handling or use of "fabricated products", as defined, if not subject to processing sufficient in time or temperature to cause mass melting.
APPEARANCE AND ODOR
White powder, odorless
BOILING POINT (DEGREES FAHRENHEIT)
Not applicable
VAPOR PRESSURE (MM OF MERCURY)
Not applicable
VAPOR DENSITY (AIR - 1)
Not applicable
SOLUBILITY IN WATER
Negligible
SECTION III PHYSICAL DATA
MELTING POINT (DEGREES FAHRENHEIT)
Not applicable. Softens about 160-180F.
SPECIFIC GRAVITY (WATER = 1)
1.4
PERCENT VOLATILE (BY WEIGHT)
Approx. 1Z (Moisture)
EVAPORATION RATE (BUTYL ACETATE - 1)
Not applicable
SECTION IV FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (SPECIFY METHOD
A(duetgor-eiegsnFiathiornenhaebito) ut
Ocrtolgnltlon about 850 fa$tm
735
F
FIRE EXTINGUISHING MEDIA
flammable limits
(PERCENT BY VOLUME)
LOWER
UPPER
Not applicable
Water spray, carbon dioxide or dry chemical.
SPECIAL FIRE FIGHTING PROCEDURES
Water spray or fog may be helpful in reducing flame intensity and absorbing irritating fumes.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Q
NFPA lists ignition temperatures of 752 F for layer and 1220 F for PVC dust cloud.
Produces combustible gases above 570F,. .
....
hire conditions produce hydrogen chloride, requiring protective equipment.
Thu information it tumilhed without warranty. repreicnUtion. inducement or Ecmjt of any kind, except that it u jcXrj^Juj tlw^brt of Tenneco
*rm 90 2083 Chemical** knowledge Or obtained from source* believed by Tenneco Chemicals to be accurate, and Tenneco Chemicals does not assume any legal
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE
PEE SECTION II ----------------------------------------------------------------------------------------------------------------------------------------
ects of overexposure None expected - inert resin. See Section IX. Prolonged breathing of concentrated dust may be harmful. (Processing at high temperatures produces fumes irritating to eyes and respiratory tract requiring local exhaust.)_______ _________________
EMERGENCY ANO FIRST AID PROCEDURES
Ordinary measures of personal hygiene. In case of exposure in hot processing move to fresh air, flush eyes with water.
\
't
C
SECTION VI REACTIVITY DATA
STABILITY
UNSTABLE STABLE
INCOMPATIBILITY (Material* to avoid)
None in ordinary use.
Normalconditions to avoid processing temperature, about 350F, causes slow darkening and decomposition. Higher X heat increases rate and evolution of HC1.
Soluble in certain ketones and organic solvents.
HAZARDOUS DECOMPOSITION PRODUCTS
Q
Thermal decomposition produces HC1, and CO and C02 (above 570 F)
MAY OCCUR HAZAROOUS POLYMERIZATION
WILL NOT OCCUR
CONDITIONS TO AVOIO
X None in ordinary use.
SECTION VII SPILL OR LEAK PROCEDURES
PS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Sweep up and remove to disposal container.
WASTE DISPOSAL METHOD
Bury in an approved landfill.
(
SECTION VIII SPECIAL PROTECTION INFORMATION
respiratory protection (Specify type) In case of concentrated dust, use Bureau of Mines approved
dust respirator (NIOBM TC-21C-132 or equivalent). See Sections II and IX.
VENTILATION
local exhaust
For hot processing MECFHoArNIoCArdL i(nGeanreyral) mhandling.
SPECIAL
Vent to elevated stack.___________________
Ventilate enclosed spaces.
protective gloves
Not ordinarily required
EYE PROTECTION
Safety glasses
other protective equipment None required for ordinary handling. For hot processing local exhaust, safety glasses and gloves are recomnended.
SECTION IX SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING ANO STORING
OSHA Standard 1910.93^ (.1017) requires monitoring and other precautions in storage, b handling and use of polyvinyl chloride, and also labeling of PVC "Contains Vinyl ^ Chloride--Vinyl Chloride is a CAncer-Suspect Agent."
New PVC resins with a low monomer content make it easier to operate below the OSHA action level of 0.5 ppm in a processor's work area, assuming normal conditions and ventilation, simplifying compliance with some of the regulatory requirements. Further
(
OATE
6/5/75
NAME ANO TITLE
T. R. AALTO, MANAGER, PRODUCT SAFETY SERVICES
1 BNU 14y
SHEET NUMBER
156