Document ganvZXE2xj43q119g019obwNe

Material Safety Data Sheet Emergency Medical Telephone (800) 441-3637 (conoco) CRUDE OIL (SOUR) I. MATERIAL IDENTIFICATION Name Crude Oil (Sour) CAS Registry Number Mixture; See Section XI Chemical Family Petroleum Hydrocarbons Transportation Emergency Phone 1-(800) 424-9300 (Chemtrec) II. OSHA HAZARD DETERMINATION The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for federal and state regulatory information. Hazardous Ingredients Hydrocarbons (Aromatic & Paraffinic) Benzene Hydrogen Sulfide CAS Registry Number Mixture 71-43-2 7783-06-4 Concentration > 90% 0.1 - 2 wt % <1% Hazardous Physical Properties Class IA Flammable Liquid - NFPA 30-1987. III. PHYSICAL DATA Appearance and Odor Usually black or green liquid; Aromatic or sulfide odor Specific Gravity (H20 = 1) 0.71 - 1.1 Boiling Point/Range 50 - >1100F Evaporation Rate (Ether = 1.0) Variable Vapor Pressure (mmHg) @ 68*F 100 - 800 (Variable) IV. REACTIVITY DATA Stable: X Unstable: Hazardous Decomposition Materials: Normal combustion forms carbon dioxide; incomplete combustion may form carbon monoxide: Conditions to Avoids Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. MlSCOOlO/March 1989 1 MCD 000023466 Conoco Inc., P.O. Box 2197, Houston, TX 77252 General Information No. (713) 293-5550 V. FIRE AND EXPLOSION HAZARD DATA < 1 UEL: 10 Flash Point: Less Than Ambient (Variable! Flash point is variable; handle and store in accordance with NFPA procedures. Could be hazardous as Class IA Flammable Liquid - NFPA 30*1987. Extinguishing Media: Use dry chemical, C02, foam. Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from areas of potential ignition. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association (NFPA* Classification Health 1 Fire 3 Reactivity 0 VI. TRANSPORTATION AND STORAGE HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 Storage Conditions: Store in accordance with National Fire Protection Association regulations. Shipping Information: DOT: Flash Point < HXPF Proper Shipping Name: Crude Oil, Petroleum Hazard Class: Flammable Liquid UN/NA No.: UN 1267 DOT Label(s): Flammable Liquid DOT Placard: Flammable IATA/IMCh Flash Point < 73*F Proper Shipping Name: Petroleum Crude Oil Hazard Class: 3 (3.2 1MO) UN No.: UN 1267 Flash Point &109T Crude Oil, Petroleum Combustible Liquid UN 1267 None Combustible Flash Point *73*F Petroleum Crude Oil 3 (33 IMO) UN 1267 VII. HEALTH HAZARD INFORMATION Exposure Limits for Crude Oil (Sour) PEL: None Established TLV: None Established Exposure Limits for Petroleum Distillates PEL: 400 ppm: 1600 mg/m3 TWA Exposure Limits fog Benzene PEL: 1 ppm - 8 Hr. TWA 5 ppm - fShort-Term Exposure Limits 0.5 ppm - Action Level TLV: 10 ppm - 30 mg/m3 Du Pont AEL: 1 ppm - 8 A 12 Hr. TWA 5 ppm - 15 Min. TWA Exposure Limits for Hydrogen Sulfide PEL: 10 pom. 14 mg/m3 STEL 15 ppm. 21 me/m3 TLV: 10 ppm. 14 mg/m3 STEL 15 ppm. 21 mg/m3 Du Pont AEL: 10 ppm - 8 A 12 Hr. TWA MISCOOlO/March 1989 2 MCD 000023467 Primary Routes of Exposure/Entry: Inhalation, Skin. Signs and Symptoms of Expostire/Medical Conditions Aggravated by Exposure: Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs or monkeys. Also, the significance of the liver tumors in rodents is highly speculative. Mouse skin painting studies have shown that some crude oils caused a low incidence of tumors. However, these studies involved repeated exposure of shaved skin which was never washed free of test material. The product contains petroleum hydrocarbons which may cause irritation to the eyes, skin and lungs after prolonged or repeated exposure. Extreme overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness or convulsions. This product may contain hydrogen sulfide which is irritating at low concentrations to the eyes, skin and lungs. At higher concentrations, loss of ability to smell hydrogen sulfide, respiratory paralysis and death may occur. A few studies have indicated that workers exposed many years to high concentrations of benzene have a slightly higher incidence of leukemia. Benzene can also be toxic to the blood and blood-forming tissues. Listed as Carcinogen or Potential Carcinogen by: Benzene NTP Yes IARC Category 1 OSHA Yes VIII. EMERGENCY AND FIRST AID INFORMATION Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cali physician. Skin: In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. Inhalation: Remove victim to fresh air immediately. If breathing stops, begin artificial resuscitation. Keep victim warm and at rest. Seek medical attention. Because hydrogen sulfide can cause death, if it is present, rescuers must review Respiratory Protection in Section X of this MSDS before attempting rescue. Ingestion: If swallowed, do not induce vomiting. Give targe quantities of water. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physician: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. IX. SPILL, LEAK AND DISPOSAL INFORMATION In Case of Spill or Leak: Contain spill immediately in smallest possible area. Recover as much of the product as possible by mechanical means, followed by recovering residual fluids by using absorbent materials. Nonrecoverable product, contaminated soil, debris and other materials should be placed in proper containers for ultimate disponL Avoid washing, draining or directing material to storm or sanitary sewers. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method: Recycle as much of the recoverable product as possible. Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. MISCOOlO/March 1989 3 MCD 000023468 X PRECAUTIONARY MEASURES Respiratory Protection: Type C respiratory protection such as airline respirator with full facepiece and an escape bottle. A SCBA with full facepiece may also be used. Respirators should be utilized in any situation where hydrogen sulfide may reach significant concentrations (e.g., confined spaces) or in unusual circumstances described in Section V. Respirators must be used in the pressure-demand, positive-pressure or continuous-flow mode (refer to Hydrogen Sulfide Material Safety Data Sheet). Ventilation: Mechanical ventilation. Necessary if significant amount of hydrogen sulfide may be present or when working in confined space. Protective Gloves: Neoprene or NBR gloves should be worn to protea against chronic skin contact. Eye Protection: Safety glasses with side shields and/or face shield where splashing is present. Other Protective Equipment: Coveralls if splashing is present XI. REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 261 and 302 The material contains the following hazardous substance which, when released in quantities equal to or exceeding the Reportable Quantity, triggers National Response Center notification requirements. Hazardous Substance Not Applicable Reportable Quantity SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, TITLE in SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances (40 CFR 355) The material contains extremely hazardous substances at greater than 1.0% concentration as listed below; it is possible that this material may contain other extremely hazardous substances at a lower concentration. Extremely Hazardous Substances: Hydrogen Sulfide Threshold Planning Quantity: 500 lbs of H Reportable Quantity: 100 lbs of HjS Concentration: < 1.0% SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The material should be reported under the following EPA hazard categories: x Immediate (Acute) Health Hazard x Delayed (Chronic) Health Hazard x Fire __ Sudden Release of Pressure __ Reactive __ Not Applicable NOTE: See Section Q for the concentration of any ingredients classified as hazardous by OSHA SECTION 313 - List of Toxic Chemicals (40 CFR 372) The material contains the following chemical(s) at a level of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and is subject to toxic chemical release reporting requirements. Toxic Chemical Benzene CAS Registry Number 71-43-2 Approx. Concentration (Upper Bound) 2.0% MISCOOlO/March 1989 4 MCD 000023469 TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is a mixture as defined by TSCA. The chemical ingredients in this material are in Section 8(b) Chemical Substance Inventory and/or are otherwise in compliance with TSCA. In the case of ingredients obtained from other manufacturers, Conoco relies on the assurance of responsible third parties in providing this statement RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous if it meets criteria for being toxic, corrosive, ignitable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste. Regulations 40 CFR 262, 263, 264 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15, 40 CFR 116 The material contains the following ingredient(s) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline. HAZARDOUS MATERIALS TRANSPORTATION ACT, 49 CFR 172 The material contains the following ingredient(s) which is considered hazardous if spilled while being transported in commerce. Ingredient Not Applicable Reportable Quantity FOREIGN REGULATION CANADIAN HAZARDOUS PRODUCTS ACT (WHMIS) The material is a WHMIS Controlled Product and a Canadian MSDS is available. STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 ("PROPOSITION 65*) The material contains ingredients) known to the State of California to cause cancer, birth defects or other reproductive harm. Read and follow label directions and use care when handling or using all petroleum products. Ingredient Benzene PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT To the our knowledge the material is not sold or produced in Pennsylvania. Please notify us at th^ldepbone number noted below if the material results in Pennsylvania commerce. MSDS Code: MlJliftO DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT: 3/89 - Replaces MSDS dated 1/89 Environmental and Occupational Health Services MSDS Analyst Conoco Inc. (713) 293-5550 MISCOOlO/March 1989 5 MCD 000023470 The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufacturers. In these instances, Conoco, in good faith relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MER CHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. MISCOOlO/March 1989 6 (conoco) MCD 000023471