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?slch&r*d * Rgsg&rsh C&r.t&r Semester 9, 1969
D?NSZ 0? AP.CCI3R -
?. Hedges
PKCCC-
TO I. Wheeler - 2WE2S
General Policy
I Make the Govt., States and Universities prove their ca.se, , I tut avoid as much confrontation as possible. Comply and y/ | work with public officials to meet or~ exceed requirements ^ ahead of time. Adverse publicity and competition are
the real weapons.
Analytical fin Air 1 - Which Aroclors are present? Where?"]
for^Xfoclar U*t Water- w>i^h
}. Gove.
. (In Animals ^'interfere?
JAgencies
Keep track of how-ouch contamination - which sources.
Prove Bicharmful - let Govt, prove'its case, on case 'ey ease basis.
Monsanto Visit-Govt. Blolabs - in search of toxicological experiments and evidence vs. Aroclors to keep up with progress.
Monsanto Prove Bloharaless - Limited work at Ind. 31o-test -
"Safe" toxic level for
man
Rata
Seek evidence of Biodegra.-
mammals via Chickens
datlon
fish
pish
Question evidence against
" us.
Question shrimp toxicology
. especially ether toxic
chemicals.
.
If Aroclor bad, others
..
must be wofie.
Probable Outcome
We can prove some things are OK at low concentration. Give Monsanto same defense.
We can't defend vs, everything. Some animals or fish or insects will be harmed.
Aroclor degradation rate will be slow. Tough to defer.:,
.jiihst. '.l-Thar chlorination compounds will be worue ...
_u.:ur chlorine compounds.
"
Therefore we will have to restrict .uses and clean-up as muen ajL-we_san, starting immediately, a
WATER PCB-SD0000067155
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Tv.srefcre we will have to woric for alternate products in end use applications; for Aroclor production facilities.
Clean Do Aroclors and substitute oroducts where necessary and wheh~requireg, sefare i'Hreats of publicity ana competitive activity over whelm us.
Water Pollution seems to be first issue
Aroclcr product is refractive, will settle out on solids sewerage sludge - river bottoms, and apparently has a long li'e, Florida or Gulf Coast - Aroclor 1254 - Aroclor 1250 present Issue. 40-2CQ ppb - causing problem at Pensacola (Monsanto) in plant effluent-causing " with shrimp. - can't rislc shut-down of plant. - ' Federal and State can extrapolate to other plants in
, Gulf area. '
San Francisco - Aroclor 1254 and 1260
Reported Aroclor to be present in San Francisco Say.
Reported to be -thin egg shells in birds -
Lot of screaming -
Great Lakes
W&rf studies on DDT Aroclor 1254 will be found! Aroclor 1242 will be found?
Air Pollution - Possible spread - but less of an issue right now. Analytical woric more difficult.
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Doesn't sees to be an issue - except for food heat transfer
We don't believe Aroclor is being used as carrier for /
insecticide - sprayed around -
\7* i> ~
We are not positive but most uses are "closed" systems;! . ,*i.
or products used in solid plastics, or adhesives, or !
sealants.
'
u
OSW G14257
WATER PCB-SD0000067156
F. Fluids
product Hydraulic Fluids
Air Compressor Fluids Heat Transfer Capacitor Fluids Transformer Fluids
Possible Pollution by
Possible Pollutio-
Customers Plant Operation by Customers ?r-r'
Yes, leakage external
Yes, leakage external Yes, leakage external Yes, leakage from plant
- Scrap materials. No, Should be clean. Yes, Reworked trans
formers
Possible - See Johnson Motors Castings.
Leakage into produ: Leakage into produc In produet but elosec for end use4 In product but closed for end use4
* Capacitors can go to land fill dumps. ' Probably not burned, In A1 containers.
** Need to take care of Aroclor in discarded transformers, product could be drained and reworked. '
Probable Conclusions
Hydraulic Leakage
Produet could be caught at machines but will take a lot of clean-up work with customers. Will have to have replacement product - with less-sensitive components. Work from this base on clean-up to prevent more pollution problems.
Air. Compressor Fluids
Hydraulic Fluids '
Must expect "shrimp" experiments. West Florida State, to be "alf*6d" sometime soon; next few months.
This will lead to bad publicity and competitive action vs. all Pydrauls.
We will have to try to confine to Aroclor 125^ and Aroclor 1260.
OSH G142SS
WATER PCB-SD0000067157
'Je will have to take action before that time.
Gulf Coast -
Action w. Richard Gallon/ Richard
Be able to replace Aroclor 1254 and Aroclor 1260 in Pydraul AC and 625 la 2 month's time before Mov. 15, 1969.
Have trial product in hands of Gulf Coast accounts and distributor before Dec. 15.
Pallon
Suggest possible buy .of "all phosphate" ester from Pood Machinery, Use this as one trial fluid MCS___ for insurance.
Richard/ ,
Suggest possible substitution of Aroclor 5442 for Aroclor 1254 in hydraulic and compressor blends. E. Wheeler Judges lower order of toxicity and solubility for 5442 series. Have to test product in pump test for deposits.
Pallon/ Suggest field trials of our own all-phosphate Richard ester.
Pallon/ Kuhn/ Kountz
Work with large customers to clean-up streams. Bring in Plndett as mfg. partner in the recycle business. Get money out of recycle operations.
Inland-Waterways-
`./heeler/ Be close enough to Great Lakes studies to Judge Richard situation. Are there animals which are being
' affected by the concentrations found?
1 Richard
Be prepared to replace-Aroclor 1254 and Aroclor 1260 in 4 months in hydraulic fluids and in air compreasor fluids.
r
Richard Be prepared to replace all Aroclor 1242 or 124P .
in 6 months in hydraulic fluids. This means *
' replacement of Pydraul 312 series, and control
of sale of Aroclor 1248 to other hydraulic
accounts such as Cities Service and Mobil.
Heat Transfer
os* 014259
Fallon/ Roush/ Kountz
Systems will have some leakage depending strongly on engineering and maintenance. Heed to work with customers or. clean-up.
Pallon/
Roush
Need to replace PR especially In food or sensitive
product areas
the product is tfettina
into water. See Jish washer compounds. See
letter E. Wheeler to ?, Pallon.
We have possible rep cement producti 1,. Themir Them!;... cc,
WATER PCB-SD0000067158
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Actlan
Kuhn
Kuhn/ Fallon
Try to assure adequate production a? Theroir.ol So in face of decreased Aroclor production, Ha and terphenyl supply nay become short. Switch customers to Theralnol 55
or Therainol 66 ahead of pollution problems in customers plant. Work with customers on plant and dumping practices. Plndett already set up to rework. Need to make them a manufacturing ant. We get sale of recycle-rework fluid.
Capacitor Capacitor plants have re-
Flulds
purification and recycle
systems but up to 53* of
product can be lost by
poor plant producers and
off-quality material.
Mkt. Benlgn.ua/
Bryant
5J 0f production could be
Eng, -(Counts/ ^ lb*/7*"*
a bl
Mfglodges p10o8ll8utfioorn twhe atyrepetroyring now
to guard against.
Capacitor products
Enclosed in A1 or stainless steel for 5 to 25 year period. Will ultimately have to dispose of capaci tor products.
Hecommend we try to save this product for a time.
Action Eng,,TSEPlant Pol lution Con trol Hodges/ Kountz
Monsanto must start to work with capacitor people to clean up plant practices. We have set^ip to accept material for rework Into hydraulic fluid but this relocation Is not a satis factory solution. Material must be reworked to electri cal grade or destroyed, whichever is more economical Must start now to get con trol of off-grade material.
Recommend replacement of future Arocler business with other products. Save 2 years.
*
Action
Monsanto must help plant clean up of customer plaits cwc&ntation, coalescing, adsorption, dis posal of ad-c.-be.-.o or recycle of adsorbents. Monsanto badly needs "toow-how" for clean-up. Monsanto should seek Govt. contract -'money for clean-up research, (See MRC R. Binning, D. Nelson)
q$h 014260
WATER PCB-SD0000067159
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Transformers
Action Senignua/ Bryant
Transformer Plant can operate in a clean, efficient manner with recycle of off-grade Aroclor. Should advise disposal of filter element materials so as to minimize chance of water pollution. Incinerate or dispose. Reworked transformers pose a threat if the Aroclor is dumped into a water stream.
product transformers can remain clsie.; ano exposure for 2= yShould try to resair. business by clear.-no by education of custoners.
* i1 l<*t
Action Senlgnus/ Bryant
Should try to minimize chance of dumping ''old" fluid by reworking and by educating co. shops and collecting product for rework or disposal.
Dalton is set up in England to rework electrical grade fluid.
Kuhn/ICountz Findett?
Heed rework facility here + disposal scheme.
Monsanto Plants
The Dept, of Interior and/or State authorities could
monitor plant outfall and find ppa of chlorinated biphenyls
at Krunmrich or Anniston anytime they choose to do so.
This would shut us down depending on what plants or animals
^ they choose to find harmed,
.
Action - Take steps to see that every precaution Is taken
to prevent Aroclor entering water streams. Try
1
to reduce to ppb level.
.
? .Hodges-Seek a Oort, contract on adsorption and incineration
TSD cycles - MRC.
Engrg.-
'
Kountz Take samples of streams and river water and mud
evidence for before and after clean-up. Samples
can be stored for further analysis if we car.11
keep up current with analytical determinations.
Apply Monsanto ei*n-up methods to customer plant u;; i..: ii'.j pi'oascure*.
OSM 01^261
WATER PCB-SD0000067160
Action 2.-vers. i Mrg, Xountz arid Kuhn
Evaluate liquid incinerators vs. solids handling incinerators for disposing of Aroclor and pentachlorophenol wastes. 1 estimate Aroclor disposal at 1-W lbs/year, exclusive of cleaning up river bottoms or outfall bottoms.
Hydraulics 2056 of tff lbs
Heat Transfer 1056 of 2ff lbs
Capacitors
of 20fT
Transformers 556 of 15JT
8O0,CC0 lbs 200.000 lbs 1,000,000 lbs 750.000 lbs
2,750,000 lbs
Central Eng. & Mfg TSD
Kountz & Kuhn
Set up an incinerator to handle Aroclor dis-\ t j ur-~
posal - preferably one which will handle
\ -r* .
solids such as muds - slurries as well as
,L
liquids. Have In operation within 12 months. / 1
Ideally have incinerators available different '
sections for disposal.
/
Possible help from MRC
Chronic Toxicity Studies - ind. Bio-Test
Wheeler Keller Ind .Bio-
Test
Continue studies to establish TEA type limits
of toxicity on Aroclor 1242, Aroclor 1254
and Aroclor 1260.
`
Rework with R. Xsller-S. Tucker the number
of samples which are to be analyzed
for Aroclor In tissue. Try to see if
Aroclors are ehanged metabollcally. Dees
concentration level off, decline If feeding
is stopped?
,"
, ' Institute studies against the most limiting biological parameters. If shrimp are the most limiting species for Aroclor levels of toxicity, then we will have to have biological studies on these species to con firm or deny adverse findings.
DSM 014262
WATER PCB-SD0000067161
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Blodegradation Studies
Sec up rate of biodegradation studies with Inorganic Dlv.
on Aroclor 1242 vs. Aroclor 1254
;
Aroclor
vs. Aroclor 5460
Swisher Chlorinated diphenyl ether
Chlorinated paraffin vs. chlorinated naphthalene
Chlorobromo Aroclors 1242 and 1248
Baxter Contact Baxter and Lidgett at KtX regularly for results on Lldgett Aroclor degradation. They are reported to be moving on MCL laboratory experiments.
Establish contact with chicropheno1 degradation studies
of Cellu-Chem Croup.
-
WER:os
W. R. Richard
OSU 014243 WATER PCB-SD0000067162