Document ga5zE8pQQJmg9RY4MRdK7Vy0L

www.axysanalytical.com AXYS Axys Analytical Services Ltd 2045 Mills Road West SID N EY, BRITISH COLUMBIA, CANADA V8L 5X2 T E L 250-655-5800 FAX250-655-5811 www .axysanalytical.com AXYS Client No.: Client Address: 4673 Cardno ENTRIX 4295 Okemos Road, Suite 101 Okemos, MI, US, 48864 The AXYS contact for these data is Kalai Pillay. Page 1 of 49 www.axysanalytical.com BATCH SUMMARY Batch ID: WG39768 Analysis Type: Perfluorinated Organic Contract: Samples: L17838-1 L17838-2 L17838-3 L17838-4 BATCH MAKEUP 4673 Reference Tiss. TCR11-0039 MSF05D 120403 MSF11D 120403 MSF24D 120405 Date: 27-Apr-2012 Matrix Type: Tissue Blank: WG39768-101 Reference or Spike: WG39768-102 WG39768-104 WG39768-105 Duplicate: WG39768-103 Comments: 1. Data are not blank corrected. FQA-006 Rev. 2. 18-Jul-1994 Copyright AXYS Analytical Services Ltd February 1993 Page 2 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 1A PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. Reference Tiss. TCR11-0039 Sample Collection: N/A 3M - ALABAMA L17838-1 Matrix: TISSUE Sample Size: 2.00 g (wet) Sample Receipt Date: 19 -A p r- 2 0 1 2 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 00:32:37 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_157 S: 24 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G 157 S: 15 Concentration Units: ng/g (wet weight basis) This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPORTING LIMIT (RL)2 RETENTION TIME PFOS 7.16 1.00 (L) 8:17 (1) Where applicable, custom lab flags have been used on this report. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; Report Filename: PFC_FC_LC_PFOA_L17838-1_Form1A_FC2G_157S24_SJ1453688.html; Workgroup: WG39768; Design ID: 1722 ] Page 3 of 49 Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_L17838-1_Form1A_FC2G_157S24_SJ1453688.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 2 PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. Reference Tiss. TCR11-0039 Sample Collection: N/A 3M - ALABAMA L17838-1 Matrix: TISSUE Sample Size: 2.00 g (wet) Sample Receipt Date: 19-Apr-2012 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 00:32:37 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_157 S: 24 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G 157 S: 15 Concentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG1 SPIKE CONC. CONC. FOUND R(%) 2 RETENTION TIME 13C4-PFOS 36.0 31.5 87.6 8:17 CLEANUP STANDARD 13C8-PFOA 12.0 10.6 88.5 7:04 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_L17838-1_Form2_FC2G_157S24_SJ1453688.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_L17838-1_Form2_FC2G_157S24_SJ1453688.html) Page 4 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 1A PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. MSF05D 120403 Sample Collection: 03-Apr-2012 3M - ALABAMA L17838-2 (A) Matrix: TISSUE Sample Size: 2.11 g (wet) Sample Receipt Date: 19 -A p r- 2 0 1 2 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 0 1 :39:33 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_157 S: 28 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G 157 S: 15 Concentration Units: ng/g (wet weight basis) This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPORTING LIMIT (RL)2 RETENTION TIME PFOS 656 0.948(L) 8:17 (1) Where applicable, custom lab flags have been used on this report. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; Report Filename: PFC_FC_LC_PFOA_L17838-2_Form1A_FC2G_157S28_SJ1453692.html; Workgroup: WG39768; Design ID: 1722 ] Page 5 of 49 Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_L17838-2_Form1A_FC2G_157S28_SJ1453692.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 2 PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. MSF05D 120403 Sample Collection: 03-Apr-2012 3M - ALABAMA L17838-2 (A) Matrix: TISSUE Sample Size: 2.11 g (wet) Sample Receipt Date: 19-Apr-2012 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 0 1 :39:33 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_157 S: 28 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G 157 S: 15 Concentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG1 SPIKE CONC. CONC. FOUND R(%) 2 RETENTION TIME 13C4-PFOS 36.0 28.4 79.0 8:17 CLEANUP STANDARD 13C8-PFOA 12.0 9.77 81.5 7:06 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_L17838-2_Form2_FC2G_157S28_SJ1453692.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 - PFC_FC_LC_PFOA_L17838-2_Form2_FC2G_157S28_SJ1453692.html) Page 6 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 1A PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. MSF11D 120403 Sample Collection: 03-Apr-2012 3M - ALABAMA L17838-3 N (A) Matrix: TISSUE Sample Size: 2.15 g (wet) Sample Receipt Date: 19 -A p r- 2 0 1 2 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 16:11:38 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_158 S: 8 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: 5 Cal. Ver. Data Filename: FC2G 158 S: 4 Concentration Units: ng/g (wet weight basis) This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPORTING LIMIT (RL)2 RETENTION TIME PFOS D 3720 4.65 (L) 8:21 (1) Where applicable, custom lab flags have been used on this report; D = dilution data. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_L17838-3_Form1A_FC2G_158S8_SJ1453777.html; Workgroup: WG39768; Design ID: 1722 ] Page 7 of 49 Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_L17838-3_Form1A_FC2G_158S8_SJ1453777.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 2 PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. MSF11D 120403 Sample Collection: 03-Apr-2012 3M - ALABAMA L17838-3 N (A) Matrix: TISSUE Sample Size: 2.15 g (wet) Sample Receipt Date: 19-Apr-2012 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 16:11:38 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_158 S: 8 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: 5 Cal. Ver. Data Filename: FC2G 158 S: 4 Concentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG1 SPIKE CONC. CONC. FOUND R(%) 2 RETENTION TIME 13C4-PFOS D 36.0 20.4 56.5 8:21 CLEANUP STANDARD 13C8-PFOA D 12.0 8.90 74.2 7:06 (1) Where applicable, custom lab flags have been used on this report; D = dilution data. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_L17838-3_Form2_FC2G_158S8_SJ1453777.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_L17838-3_Form2_FC2G_158S8_SJ1453777.html) Page 8 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 1A PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. MSF24D 120405 Sample Collection: 05-Apr-2012 3M - ALABAMA L17838-4 Matrix: TISSUE Sample Size: 2.05 g (wet) Sample Receipt Date: 19 -A p r- 2 0 1 2 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 0 1 :22:47 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_157 S: 27 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G 157 S: 15 Concentration Units: ng/g (wet weight basis) This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPORTING LIMIT (RL)2 RETENTION TIME PFOS 537 0.976 (L) 8:17 (1) Where applicable, custom lab flags have been used on this report. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_L 17838-4_Form1 A_FC2G_157S27_SJ1453691.html; Workgroup: W G39768;DesignID: 1722 ] Page 9 of 49 Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_L17838-4_Form1A_FC2G_157S27_SJ1453691.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 2 PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. MSF24D 120405 Sample Collection: 05-Apr-2012 3M - ALABAMA L17838-4 Matrix: TISSUE Sample Size: 2.05 g (wet) Sample Receipt Date: 19-Apr-2012 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 0 1 :22:47 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_157 S: 27 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G 157 S: 15 Concentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG1 SPIKE CONC. CONC. FOUND R(%) 2 RETENTION TIME 13C4-PFOS 36.0 27.3 75.9 8:17 CLEANUP STANDARD 13C8-PFOA 12.0 10.8 90.3 7:06 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_L17838-4_Form2_FC2G_157S27_SJ1453691.html; Workgroup: WG39768; Design ID: 1722 ] Page 10 of 49 Page 1 of 1 (WG39768 - PFC_FC_LC_PFOA_L17838-4_Form2_FC2G_157S27_SJ1453691.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 1A PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. Lab Blank Sample Collection: N/A N/A WG39768-101 Matrix: TISSUE Sample Size: 2.00 g Sample Receipt Date: N/A Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 24-Apr-2012 Time: 23:59:06 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_157 S: 22 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G _157 S: 15 Concentration Units: ng/g This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPORTING LIMIT (RL)2 RETENTION TIME PFOS U 1.00 (L) (1) W here applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-101_Form1A_FC2G_157S22_SJ1453684.html; Workgroup: WG39768; Design ID: 1722 ] Page 11 of 49 Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_WG39768-101_Form1A_FC2G_157S22_SJ1453684.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 2 PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. Lab Blank Sample Collection: N/A N/A WG39768-101 Matrix: TISSUE Sample Size: 2.00 g Sample Receipt Date: N/A Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 24-Apr-2012 Time: 23:59:06 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_157 S: 22 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G 157 S: 15 Concentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG1 SPIKE CONC. CONC. FOUND R(%) 2 RETENTION TIME 13C4-PFOS 36.0 33.2 92.3 8:17 CLEANUP STANDARD 13C8-PFOA 12.0 11.2 93.7 7:04 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-101_Form2_FC2G_157S22_SJ1453684.html; Workgroup: WG39768; Design ID: 1722 ] Page 12 of 49 Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_WG39768-101_Form2_FC2G_157S22_SJ1453684.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 8A PERFLUORINATED ORGANICS ONGOING PRECISION AND RECOVERY (OPR) AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Lab Sample I.D.: W G 39768-102 Matrix: TISSUE Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 24-Apr-2012 Time: 22:51:55 Column ID: C18MS Extract Volume (uL): 4000 OPR Data Filename: FC2G_157 S: 18 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G 157 S: 15 ALL CONCENTRATIONS REPORTED ON THIS FORM ARE CONCENTRATIONS IN EXTRACT, BASED O N A 1 m L EXTRACT VOLUME. COMPOUND LAB FLAG 1 SPIKE CONC. (ng/mL) CONC. FOUND (ng/mL) % RECOVERY RETENTION TIME PFOS 80.0 87.1 109 8:17 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ These pages are part of a larger report that may contain inform ation necessary for full data evaluation. Results reported relate only to the sample tested. For Axys Internal Use Only [ XSL Template: FC-Form8A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-102_Form8A_SJ1453676.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 - PFC_FC_LC_PFOA_WG39768-102_Form8A_SJ1453676.html) Page 13 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 8B PERFLUORINATED ORGANICS ONGOING PRECISION AND RECOVERY (OPR) AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Lab Sample I.D.: W G 39768-102 Matrix: TISSUE Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 24-Apr-2012 Time: 22:51:55 Column ID: C18MS Extract Volume (uL): 4000 OPR Data Filename: FC2G_157 S: 18 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G 157 S: 15 ALL CONCENTRATIONS REPORTED ON THIS FORM ARE CONCENTRATIONS IN EXTRACT, BASED O N A 1 m L EXTRACT VOLUME. LABELED COMPOUND LAB FLAG 1 SPIKE CONC. (ng/mL) CONC. FOUND (ng/mL) % RECOVERY RETENTION TIME 13C4-PFOS 36.0 29.0 80.5 8:17 CLEANUP STANDARD 13C8-PFOA 12.0 11.2 93.3 7:04 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ These pages are part of a larger report that may contain inform ation necessary for full data evaluation. Results reported relate only to the sample tested. For Axys Internal Use Only [ XSL Template: FC-Form8B.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-102_Form8B_SJ1453676.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 - PFC_FC_LC_PFOA_WG39768-102_Form8B_SJ1453676.html) Page 14 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 1A PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. MSF11D 120403 (Duplicate) Sample Collection: 03-Apr-2012 3M - ALABAMA WG39768-103 N (DUP L17838-3) Matrix: TISSUE Sample Size: 2.07 g (wet) Sample Receipt Date: 19 -A p r- 2 0 1 2 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 16:28:24 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_158 S: 9 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: 5 Cal. Ver. Data Filename: FC2G _158 S: 4 Concentration Units: ng/g (wet weight basis) This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPORTING LIMIT (RL)2 RETENTION TIME PFOS D 3510 4.83 (L) 8:21 (1) Where applicable, custom lab flags have been used on this report; D = dilution data. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-103_Form1A_FC2G_158S9_SJ1453778.html; Workgroup: WG39768; Design ID: 1722 ] Page 15 of 49 Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_WG39768-103_Form1A_FC2G_158S9_SJ1453778.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 2 PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. MSF11D 120403 (Duplicate) Sample Collection: 03-Apr-2012 3M - ALABAMA WG39768-103 N (DUP L17838-3) Matrix: TISSUE Sample Size: 2.07 g (wet) Sample Receipt Date: 19-Apr-2012 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 16:28:24 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_158 S: 9 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: 5 Cal. Ver. Data Filename: FC2G _158 S: 4 Concentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG1 SPIKE CONC. CONC. FOUND R(%) 2 RETENTION TIME 13C4-PFOS D 36.0 25.9 72.0 8:21 CLEANUP STANDARD 13C8-PFOA D 12.0 10.7 89.2 7:06 (1) Where applicable, custom lab flags have been used on this report; D = dilution data. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-103_Form2_FC2G_158S9_SJ1453778.html; Workgroup: WG39768; Design ID: 1722 ] Page 16 of 49 Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_WG39768-103_Form2_FC2G_158S9_SJ1453778.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 1A PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. MSF05D 120403 (MS) Sample Collection: 03-Apr-2012 3M - ALABAMA W G39768-104 (MS) Matrix: TISSUE Sample Size: 2.01 g (wet) Sample Receipt Date: 19 -A p r- 2 0 1 2 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 01:56:19 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_157 S: 29 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G _157 S: 15 Concentration Units: ng/g (wet weight basis) This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPORTING LIMIT (RL)2 RETENTION TIME PFOS 670 0.995 (L) 8:17 (1) Where applicable, custom lab flags have been used on this report. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-104_Form1A_FC2G_157S29_SJ1453693.html; Workgroup: WG39768; Design ID: 1722 ] Page 17 of 49 Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_WG39768-104_Form1A_FC2G_157S29_SJ1453693.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 2 PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. MSF05D 120403 (MS) Sample Collection: 03-Apr-2012 3M - ALABAMA W G39768-104 (MS) Matrix: TISSUE Sample Size: 2.01 g (wet) Sample Receipt Date: 19-Apr-2012 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 01:56:19 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_157 S: 29 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G _157 S: 15 Concentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG1 SPIKE CONC. CONC. FOUND R(%) 2 RETENTION TIME 13C4-PFOS 36.0 35.4 98.2 8:17 CLEANUP STANDARD 13C8-PFOA 12.0 11.0 91.3 7:06 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-104_Form2_FC2G_157S29_SJ1453693.html; Workgroup: WG39768; Design ID: 1722 ] Page 18 of 49 Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_WG39768-104_Form2_FC2G_157S29_SJ1453693.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 1A PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. MSF05D 120403 (MSD) Sample Collection: 03-Apr-2012 3M - ALABAMA WG39768-105 (MSD) Matrix: TISSUE Sample Size: 2.11 g (wet) Sample Receipt Date: 19 -A p r- 2 0 1 2 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 02:13:05 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_157 S: 30 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G _157 S: 15 Concentration Units: ng/g (wet weight basis) This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPORTING LIMIT (RL)2 RETENTION TIME PFOS 653 0.948 (L) 8:17 (1) Where applicable, custom lab flags have been used on this report. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-105_Form1A_FC2G_157S30_SJ1453694.html; Workgroup: WG39768; Design ID: 1722 ] Page 19 of 49 Page 1 of 1 (WG39768 - PFC_FC_LC_PFOA_WG39768-105_Form1A_FC2G_157S30_SJ1453694.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 2 PERFLUORINATED ORGANICS ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Project No. Lab Sample I.D.: CLIENT SAMPLE NO. MSF05D 120403 (MSD) Sample Collection: 03-Apr-2012 3M - ALABAMA WG39768-105 (MSD) Matrix: TISSUE Sample Size: 2.11 g (wet) Sample Receipt Date: 19-Apr-2012 Initial Calibration Date: 24-Apr-2012 Extraction Date: 23-Apr-2012 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 Time: 02:13:05 Column ID: C18MS Extract Volume (uL): 4000 Sample Data Filename: FC2G_157 S: 30 Injection Volume (uL): 15 Blank Data Filename: FC2G _157 S: 22 Dilution Factor: N/A Cal. Ver. Data Filename: FC2G _157 S: 15 Concentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG1 SPIKE CONC. CONC. FOUND R(%) 2 RETENTION TIME 13C4-PFOS 36.0 37.1 103 8:17 CLEANUP STANDARD 13C8-PFOA 12.0 10.9 91.1 7:04 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFC_FC_LC_PFOA_WG39768-105_Form2_FC2G_157S30_SJ1453694.html; Workgroup: WG39768; Design ID: 1722 ] Page 20 of 49 Page 1 of 1 (WG39768 -PFC_FC_LC_PFOA_WG39768-105_Form2_FC2G_157S30_SJ1453694.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 3A PERFLUORINATED ORGANICS INITIAL CALIBRATION PERCENT RECOVERIES AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial Calibration Date: 24-Apr-2012 CS0 Data Filename: CS1 Data Filename: FC2G _157 S: 4 FC2G _157 S: 5 Instrument ID: LC MS/MS CS2 Data Filename: FC2G _157 S: 6 LC Column ID: C18MS CS3 Data Filename: FC2G _157 S: 7 CS4 Data Filename: FC2G _157 S: 8 CS5 Data Filename: FC2G _157 S: 9 CS6 Data Filename: FC2G _157 S: 10 CS7 Data Filename: FC2G _157 S: 11 CS8 Data Filename: N/A COMPOUND PFOS LAB FLAG1 CS0 104 CS1 91.9 CS2 86.4 PERCENT RECOVERY (%) CS3 CS4 CS5 105 99.5 112 CS6 101 CS7 99.7 CS8 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Kristina Coleman______ For Axys Internal Use Only [ XSL Template: FC-Form3A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA_FC_LC_24-Apr-2012_FC2G__Form3A_GS45507.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 -PFOA_FC_LC_24-Apr-2012_FC2G__Form3A_GS45507.html) Page 21 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 3B PERFLUORINATED ORGANICS INITIAL CALIBRATION PERCENT RECOVERIES AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial Calibration Date: 24-Apr-2012 CS0 Data Filename: CS1 Data Filename: FC2G _157 S: 4 FC2G _157 S: 5 Instrument ID: LC MS/MS CS2 Data Filename: FC2G _157 S: 6 LC Column ID: C18MS CS3 Data Filename: FC2G _157 S: 7 CS4 Data Filename: FC2G _157 S: 8 CS5 Data Filename: FC2G _157 S: 9 CS6 Data Filename: FC2G _157 S: 10 CS7 Data Filename: FC2G _157 S: 11 CS8 Data Filename: N/A LABELED COMPOUND 13C4-PFOS CLEAN-UP STANDARD 13C8-PFOA LAB FLAG1 CS0 103 101 CS1 82.4 99.6 PERCENT RECOVERIES (%) CS2 CS3 CS4 CS5 CS6 92.7 86.9 104 103 111 94.3 98.3 101 98.9 103 CS7 117 104 CS8 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Kristina Coleman______ For Axys Internal Use Only [ XSL Template: FC-Form3B.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA_FC_LC_24-Apr-2012_FC2G__Form3B_GS45507.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 -PFOA_FC_LC_24-Apr-2012_FC2G__Form3B_GS45507.html) Page 22 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 3C PERFLUORINATED ORGANICS INITIAL CALIBRATION RETENTION TIMES AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial Calibration Date: 24-Apr-2012 CS0 Data Filename: CS1 Data Filename: FC2G _157 S: 4 FC2G _157 S: 5 Instrument ID: LC MS/MS CS2 Data Filename: FC2G _157 S: 6 LC Column ID: C18MS CS3 Data Filename: FC2G _157 S: 7 CS4 Data Filename: FC2G _157 S: 8 CS5 Data Filename: FC2G _157 S: 9 CS6 Data Filename: FC2G _157 S: 10 CS7 Data Filename: FC2G _157 S: 11 CS8 Data Filename: N/A COMPOUND PFOS LAB FLAG1 CS0 8:17 CS1 8:17 CS2 8:17 RETENTION TIMES CS3 CS4 CS5 8:17 8:17 8:17 CS6 8:17 CS7 8:17 CS8 MEAN RT 8:17 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Kristina Coleman______ For Axys Internal Use Only [ XSL Template: FC-Form3C.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA_FC_LC_24-Apr-2012_FC2G__Form3C_GS45507.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 -PFOA_FC_LC_24-Apr-2012_FC2G__Form3C_GS45507.html) Page 23 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 3D PERFLUORINATED ORGANICS INITIAL CALIBRATION RETENTION TIMES AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial Calibration Date: 24-Apr-2012 CS0 Data Filename: CS1 Data Filename: FC2G _157 S: 4 FC2G _157 S: 5 Instrument ID: LC MS/MS CS2 Data Filename: FC2G _157 S: 6 LC Column ID: C18MS CS3 Data Filename: FC2G _157 S: 7 CS4 Data Filename: FC2G _157 S: 8 CS5 Data Filename: FC2G _157 S: 9 CS6 Data Filename: FC2G _157 S: 10 CS7 Data Filename: FC2G _157 S: 11 CS8 Data Filename: N/A LABELED COMPOUND 13C4-PFOS CLEAN-UP STANDARD 13C8-PFOA LAB FLAG1 RETENTION TIMES CS0 CS1 CS2 CS3 CS4 CS5 CS6 CS7 8:17 8:17 8:17 8:17 8:21 8:17 8:17 8:17 CS8 MEAN RT 8:18 7:04 7:04 7:04 7:04 7:04 7:04 7:04 7:04 7:04 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Kristina Coleman______ For Axys Internal Use Only [ XSL Template: FC-Form3D.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA_FC_LC_24-Apr-2012_FC2G__Form3D_GS45507.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 -PFOA_FC_LC_24-Apr-2012_FC2G__Form3D_GS45507.html) Page 24 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 4A PERFLUORINATED ORGANICS CALIBRATION VERIFICATION AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial Calibration Date: 24-Apr-2012 VER Data Filename: FC2G _157 S: 15 Instrument ID: LC MS/MS Analysis Date: 24-Apr-2012 LC Column ID: C18MS Analysis Time: 2 2 :0 1 :37 COMPOUND PFOS LAB FLAG1 RETENTION TIME 8:17 EXPECTED CONC. (ng) 80.0 CONC. FOUND (ng) 86.8 RECOVERY (%) 108 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form4A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA _FC_LC_FC2GJ57S15_Form4A_SJ1453671.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 -PFOA_FC_LC_FC2G_157S15__Form4A_SJ1453671.html) Page 25 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 4B PERFLUORINATED ORGANICS CALIBRATION VERIFICATION AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial Calibration Date: 24-Apr-2012 VER Data Filename: FC2G _157 S: 15 Instrument ID: LC MS/MS Analysis Date: 24-Apr-2012 LC Column ID: C18MS Analysis Time: 2 2 :0 1 :37 LABELED COMPOUND 13C4-PFOS CLEANUP STANDARD 13C8-PFOA LAB FLAG 1 RETENTION TIME 8:17 EXPECTED CONC. (ng) 36.0 CONC.FOUND (ng) 36.0 R E C O V E R Y (%) 100 7:06 12.0 12.1 101 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form4B.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA _FC_LC_FC2GJ57S15_Form4B_SJ1453671.html; Workgroup: WG39768; DesignID: 1722 ] Page 1 of 1 (WG39768 -PFOA_FC_LC_FC2G_157S15__Form4B_SJ1453671.html) Page 26 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 4A PERFLUORINATED ORGANICS CALIBRATION VERIFICATION AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial Calibration Date: 24-Apr-2012 VER Data Filename: FC2G _158 S: 4 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 LC Column ID: C18MS Analysis Time: 15:04:34 COMPOUND PFOS LAB FLAG1 RETENTION TIME 8:17 EXPECTED CONC. (ng) 80.0 CONC. FOUND (ng) 81.1 RECOVERY (%) 101 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form4A.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; Report Filename: PFOA_FC_LC_FC2G_158S4__Form4A_SJ1453773.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 -PFOA_FC_LC_FC2G_158S4__Form4A_SJ1453773.html) Page 27 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 4B PERFLUORINATED ORGANICS CALIBRATION VERIFICATION AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial Calibration Date: 24-Apr-2012 VER Data Filename: FC2G _158 S: 4 Instrument ID: LC MS/MS Analysis Date: 25-Apr-2012 LC Column ID: C18MS Analysis Time: 15:04:34 LABELED COMPOUND 13C4-PFOS CLEANUP STANDARD 13C8-PFOA LAB FLAG 1 RETENTION TIME 8:21 EXPECTED CONC. (ng) 36.0 CONC.FOUND (ng) 28.3 RECOVERY (%) 78.6 7:06 12.0 11.8 98.3 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ For Axys Internal Use Only [ XSL Template: FC-Form4B.xsl; Created: 27-Apr-2012 14:59:50; Application: XMLTransformer-1.12.13; ReportFilename: PFOA_FC_LC_FC2G_158S4__Form4B_SJ1453773.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 -PFOA_FC_LC_FC2G_158S4__Form4B_SJ1453773.html) Page 28 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 PERFLUORINATED ORGANICS ANALYSIS REPORT RELATIVE PERCENT DIFFERENCE AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. Contract No.: 4673 Client ID: MSF11D 120403 Concentration Units: 3M - ALABAMA ng/g (wet weight basis) COMPOUND PFOS L17838-3 (A)_______ LAB FLAG1 CONC. FOUND D 3720 WG39768-103 LAB FLAG 1 CONC. FOUND D 3510 MEAN 3620 RELATIVE PERCENT DIFFERENCE 5.77 (1) Where applicable, custom lab flags have been used on this report; D = dilution data. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ These pages are part o f a larger report that may contain inform ation necessary for full data evaluation. Results reported relate only to the sample tested. For Axys Internal Use Only [ XSL Template: RPD.xsl; Created: 27-Apr-2012 15:00:24; Application: XMLTransformer-1.12.13; ReportFilename: RPD_FC_LC_PFOA-RPD_WG39768-103_L17838-3_.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 - RPD_FC_LC_PFOA-RPD_WG39768-103_L17838-3_.html) Page 29 of 49 www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Contract No.: 4673 Form 8C PERFLUORINATED ORGANICS MATRIX SPIKE (MS) ANALYSIS REPORT Project No. Lab Sample I.D.: Matrix: TISSUE Sample Size: Extraction Date: 23-Apr-2012 Initial Calibration Date: Analysis Date: 25-Apr-2012 Time: 01:56:19 Instrument ID: Extract Volume (uL): 4000 Column ID: Injection Volume (uL): 15 MS Data Filename: Dilution Factor: N/A Blank Data Filename: Cal. Ver. Data Filename: CLIENT SAMPLE NO. MSF05D 120403 (MS) Sample Collection: 03-Apr-2012 3M - ALABAMA W G39768-104 (MS) 2.01 g (wet) 24-Apr-2012 LC MS/MS C18MS FC2G_157 S: 29 FC2G _157 S: 22 FC2G 157 S: 15 ALL CONCENTRATIONS REPORTED ON THIS FORM ARE CONCENTRATIONS ON SAMPLE SIZE BASIS COMPOUND PFOS LAB FLAG1 ION ABUND. RATIO N/A SPIKE CONC (ng/g) 39.8 SAMPLE LAB FLAG 1 SAMPLE CONC (ng/g) 656 CONC. FOUND (ng/g) 670 MS R% 2 36.4 REL % DIFF (1) Where applicable, custom lab flags have been used on this report. (2) R% = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ These pages are part of a larger report that may contain inform ation necessary for full data evaluation. Results reported relate only to the sample tested. For Axys Internal Use Only [ XSL Template: MS.xsl; Created: 27-Apr-2012 15:00:16; Application: XMLTransformer-1.12.13; Report Filename: MS_FC_LC_PFOA-MS-MSD_WG39768-104_L17838-2_Form8C.html; Workgroup: WG39768; Design ID: 1722 ] Page 30 of 49 Page 1 of 1 (WG39768 - MS_FC_LC_PFOA-MS-MSD_WG39768-104_L17838-2_Form8C.html) www.axysanalytical.com AXYS METHOD MLA-043 Rev 8 Form 8E PERFLUORINATED ORGANICS MATRIX SPIKE DUPLICATE (MSD) ANALYSIS REPORT AXYS ANALYTICAL SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. Contract No.: 4673 Lab Sample I.D.: Matrix: TISSUE Sample Size: Extraction Date: 23-Apr-2012 Initial Calibration Date: Analysis Date: 25-Apr-2012 Time: 02:13:05 Instrument ID: Extract Volume (uL): 4000 Column ID: Injection Volume (uL): 15 MSD Data Filename: Dilution Factor: N/A Blank Data Filename: Cal. Ver. Data Filename: CLIENT SAMPLE NO. MSF05D 120403 (MSD) Sample Collection: 03-Apr-2012 3M - ALABAMA W G39768-105 (MSD) 2.11 g (wet) 24-Apr-2012 LC MS/MS C18MS FC2G_157 S: 30 FC2G _157 S: 22 FC2G 157 S: 15 ALL CONCENTRATIONS REPORTED ON THIS FORM ARE CONCENTRATIONS ON SAMPLE SIZE BASIS COMPOUND PFOS LAB FLAG1 ION ABUND. RATIO N/A SPIKE CONC (ng/g) 37.9 SAMPLE LAB FLAG 1 SAMPLE CONC (ng/g) 656 CONC. FOUND (ng/g) 653 MSD R% 2 REL % DIFF (1) Where applicable, custom lab flags have been used on this report. (2) R% = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 com pliant quality assurance processes. Signed:____________ Bryan Alonzo______ These pages are part of a larger report that may contain inform ation necessary for full data evaluation. Results reported relate only to the sample tested. For Axys Internal Use Only [ XSL Template: MS.xsl; Created: 27-Apr-2012 15:00:16; Application: XMLTransformer-1.12.13; Report Filename: MS_FC_LC_PFOA-MS-MSD_WG39768-105_L17838-2_Form8E.html; Workgroup: WG39768; Design ID: 1722 ] Page 1 of 1 (WG39768 - MS_FC_LC_PFOA-MS-MSD_WG39768-105_L17838-2_Form8E.html) Page 31 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. Table 1a NELAP Accreditation Held by AXYS Analytical Services Ltd. for Chlorinated Dioxins/Furans, Chlorinated Pesticides, PCBs and PAHs Matrix Codes for Table 1a NPW = Non-Potable Water DrW = Drinking Water S = Solid T = Tissue Accreditation Method Codes and Explanation for Table 1 Code Accreditation Certificate Applicable AXYS Method and Description No. Method Reference 1 EPA 1613B MLA-017, performance based implementation of EPA1613B (GC/HRMS) 2 EPA 8290 MLA-017, performance based implementation of EPA 8290 (Gc /HRMS) 3 AXYS MLA-017 MLA-017, performance based implementation of EPA 1613B, 8290 (GC/HRMS) 4 EPA 608 MLA-007, performance based implementation of EPA 608 (GC/ECD) 5 EPA 8270C or 8270D MLA-007, performance based modification of 8270C/D (GC/LRMS) 6 EPA8081Aor8081B MLA-007, performance based implementation of EPA 8081A/B (GC/ECD) 7 EPA 1668A MLA-010, performance based implementation of EPA 1668A (GC/HRMS) 8 SM 6630B MLA-007, performance based implementation of SM 18-20 6630B (GC/ECD) 9 EPA 1625B MLA-021, performance based modification of EPA 1625B (GC/LRMS) 11 EPA 625 MLA-007, performance based modification of EPA 625 (g C/LRMS) 20 EPA 8270C or 8270D MLA-021, performance based modification of EPA 8270C/D (GC/LRMS) TABLE 1 PCDD/F - Polychlorinated Dioxins and Furans Dioxins Dioxins and Dibenzofurans 1,2,3,4,6,7,8-HpCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF 1,2,3,4,7,8-HxCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDD ACC-101 Rev 06, 29-Jun-2011 New York State D epartm ent of Health Lab ID 11674 NELAP Primary NP W S California D epartm ent of Public Health Lab ID 01138CA NELAP Secondary NP W S 1 2 12 12 12 12 12 12 State of Florida D ep artm en t of Health Lab ID E871007 NELAP Primary Dr. NP WW S T 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 State of New Jersey Department of E n viro n m en tal Protection Lab ID CANA005 NELAP Secondary Dr. NP WW S T 12 2 12 2 12 2 12 2 12 2 12 2 Page 1 of 18 Page 32 of 49 www.axysanalytical.com TABLE 1 1,2,3,6,7,8-HxCDF 1,2,3,7,8,9-HxCDD 1,2,3,7,8,9-HxCDF 1,2,3,7,8-PeCDD 1,2,3,7,8-PeCDF 2,3,4,6,7,8-HxCDF 2,3,4,7,8-PeCDF 2,3,7,8-TCDD 2,3,7,8-TCDF OCDD OCDF Total TCDD Total TCDF Total PeCDD Total PeCDF Total HxCDD Total HxCDF Total HpCDD Total HpCDF PCBs - Polychlorinated biphenyls PCB 1 2-Chlorobiphenyl PCB 3 4-Chlorobiphenyl PCB 4 2,2'-Dichlorobiphenyl PCB 5 2,3-Dichlorobiphenyl PCB 15 4,4'-Dichlorobiphenyl PCB 18 2,2',5-Trichlorobiphenyl PCB 19 2,2',6-Trichlorobiphenyl PCB 31 2,4',5-Trichlorobiphenyl PCB 37 3,4,4'-Trichlorobiphenyl PCB 44 2,2',3,5'-Tetrachlorobiphenyl PCB 52 2,2',5,5'-Tetrachlorobiphenyl PCB 54 2,2',6,6'-Tetrachlorobiphenyl PCB 66 2,3',4,4'-Tetrachlorobiphenyl PCB 77 3,3',4,4'-Tetrachlorobiphenyl PCB 81 3,4,4',5-Tetrachlorobiphenyl PCB 87 2,2',3,4,5'-Pentachlorobiphenyl ACC-101 Rev 06, 29-Jun-2011 AXYS Analytical Services Ltd. New York State D epartm ent of Health Lab ID 11674 NELAP Primary NP W S 1 California D epartm ent of Public Health Lab ID 01138CA NELAP Secondary NP W S 12 12 12 12 12 12 12 12 12 12 12 1 1 1 1 1 1 1 1 State of Florida D epartm ent of Health Lab ID E871007 NELAP Primary Dr. NP WW S T 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2 , 3 1, 2, 3 1, 2, 3 1, 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 State of New Jersey Department of E n viro n m en tal Protection Lab ID CANA005 NELAP Secondary Dr. NP WW 1 1 1 1 1 1 1 1 1 1 1 S 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 T 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 Page 2 of 18 Page 33 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 1 PCB 101 PCB 104 PCB 105 PCB 109 PCB 114 PCB 118 PCB 123 PCB 124 PCB 126 PCB 138 PCB 141 PCB 151 PCB 153 PCB 155 PCB 156 PCB 157 PCB 167 PCB 169 PCB 170 PCB 180 PCB 183 PCB 187 PCB 188 PCB 189 PCB 202 PCB 205 PCB 206 PCB 208 PCB 209 Aroclor 1260 Aroclor 1254 Aroclor 1221 Aroclor 1232 Aroclor 1248 Aroclor 1016 Aroclor 1242 2,2',4,5,5'-Pentachlorobiphenyl 2,2',4,6,6'-Pentachlorobiphenyl 2,3,3',4,4'-Pentachlorobiphenyl 2,3,3',4,6-Pentachlorobiphenyl 2,3,4,4',5-Pentachlorobiphenyl 2,3',4,4',5-Pentachlorobiphenyl 2,3',4,4',5'-Pentachlorobiphenyl 2,3',4',5,5'-Pentachlorobiphenyl 3,3',4,4',5-Pentachlorobiphenyl 2,2',3,4,4',5'-Hexachlorobiphenyl 2,2',3,4,5,5'-Hexachlorobiphenyl 2,2',3,5,5',6-Hexachlorobiphenyl 2,2',4,4',5,5'-Hexachlorobiphenyl 2,2',4,4',6,6'-Hexachlorobiphenyl 2,3,3',4,4',5-Hexachlorobiphenyl 2,3,3',4,4',5'-Hexachlorobiphenyl 2,3',4,4',5,5'-Hexachlorobiphenyl 3,3',4,4',5,5'-Hexachlorobiphenyl 2,2',3,3',4,4',5-Heptachlorobiphenyl 2,2',3,4,4',5,5'-Heptachlorobiphenyl 2,2',3,4,4',5',6-Heptachlorobiphenyl 2,2',3,4',5,5',6-Heptachlorobiphenyl 2,2',3,4',5,6,6'-Heptachlorobiphenyl 2,3,3',4,4',5,5'-Heptachlorobiphenyl 2,2',3,3',5,5',6,6'-Octachlorobiphenyl 2,3,3',4,4',5,5',6-Octachlorobiphenyl 2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl 2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl Decachlorobiphenyl New York State D epartm ent of Health Lab ID 11674 NELAP Primary NP W S 77 77 77 77 77 77 77 California D epartm ent of Public Health Lab ID 01138CA NELAP Secondary NP W S 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7, 11 7, 11 7, 11 7, 11 7, 11 7, 11 7, 11 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 5, 7 5, 7 5, 7 5, 7 5, 7 5, 7 5, 7 11 11 11 11 11 11 11 5 5 5 5 5 5 5 State of Florida D epartm ent of Health Lab ID E871007 NELAP Primary Dr. NP WW S T ACC-101 Rev 06, 29-Jun-2011 State of New Jersey Department of E n viro n m en tal Protection Lab ID CANA005 NELAP Secondary Dr. NP WW 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 S 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 T Page 3 of 18 Page 34 of 49 www.axysanalytical.com TABLE 1 Pesticides 4,4'-DDD 4,4'-DDE 4,4'-DDT Aldrin Alpha-HCH Beta-HCH cis-Chlordane (alpha-Chlordane) Chlordane, technical Delta-HCH Dieldrin Endosulphan I Endosulphan II Endosulphan sulphate Endrin Endrin aldehyde trans-Chlordane (gamma-Chlordane) Gamma-HCH (Lindane) Heptachlor Heptachlor epoxide Hexachlorobenzene Methoxychlor Mi rex PAH Anthracene Pyrene Benzo[ghilperylene Indeno[1,2,3-cdlpyrene Benzo[blfluoranthene Fluoranthene Benzo[klfluoranthene Acenaphthylene Chrysene Benzo[a]pyrene Dibenz[ahlanthracene Benz[alanthracene ACC-101 Rev 06, 29-Jun-2011 AXYS Analytical Services Ltd. New York State D epartm ent of Health Lab ID 11674 NELAP Primary NP W S California D epartm ent of Public Health Lab ID 01138CA NELAP Secondary NP W S State of Florida D epartm ent of Health Lab ID E871007 NELAP Primary Dr. NP WW S T 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 55 5, 11 5 11 5 11 5 11 5 4646 4646 4646 4646 4646 4646 55 11 5 11 5 11 5 11 5 4646 9595 4,8 6 8 6 5 State of New Jersey Department of E n viro n m en tal Protection Lab ID CANA005 NELAP Secondary Dr. NP WW S T 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 Page 4 of 18 Page 35 of 49 www.axysanalytical.com TABLE 1 Acenaphthene Phenanthrene Fluorene Naphthalene AXYS Analytical Services Ltd. New York State D epartm ent of Health Lab ID 11674 NELAP P rim a ry NP W S 9 20 9 20 9 20 9 20 California D epartm ent of Public Health Lab ID 01138CA NELAP Secondary NP W S 9 20 9 20 9 20 9 20 State of Florida D epartm ent of Health Lab ID E871007 NELAP Primary Dr. NP WW S T State of New Jersey Department of E n viro n m en tal Protection Lab ID C AN A005 NELAP Secondary Dr. NP WW S T ACC-101 Rev 06, 29-Jun-2011 Page 5 of 18 Page 36 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. Matrix Codes for Table 1b NPW = Non-Potable Water DrW = Drinking Water S = Solid T = Tissue Table 1b NELAP Accreditation Held by AXYS Analytical Services Ltd. for Perfluorinated Organic Compounds Accreditation Method Codes and Explanation for Table 1b Code Accreditation Certificate Applicable AXYS Method and Description No. Method Reference 12 AXYS MLA-041 13 AXYS MLA-043 14 AXYS MLA-060 MLA-041, laboratory performance based method (LC/MS-MS) MLA-043, laboratory performance based method (LC/MS-MS) MLA-060, laboratory performance based method (LC/MS-MS) TABLE 1 State of Florida D epartm ent of Health Lab ID E871007 NELAP Primary Dr. NP WW S T Minnesota Department of Health Lab ID 232-999-430 NELAP Primary! Dr. NP WW S T State of New Jersey Department of E n viro n m en tal Protection Lab ID CANA005 NELAP Secondary Dr. NP WW S T PFC - Perfluorinated Organic Compounds Perfluorobutanoate (PFBA) Note Perfluoropentanoate (PFPeA) Note Perfluorohexanoate (PFHxA) Note Perfluoroheptanoate (PFHpA) Note Perfluorooctanoate (PFOA) Nte Perfluorononanoate (PFNA) Note Perfluorodecanoate (PFDA) Note Perfluoroundecanoate (PFUnA) N ote N Perfluorododecanoate (PFDoA) N ote N Perfluorobutanesulfonate (PFBS) Perfluorohexanesulfonate (PFHxS) Perfluorooctanesulfonate (PFOS) Perfluorooctane sulfonamide (PFOSA) 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 Note: Accreditations by Minnesota Department of Health and New Jersey Department of Environmental Protection are against the corresponding acid form of the anion shown. ACC-101 Rev 06, 29-Jun-2011 Page 6 o f 18 Page 37 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. Table 2: Canadian and US State Specific Accreditation Held by AXYS Analytical Services Ltd. Matrix Codes for Table 2 NP W = Non-Potable Water Dr. W = Drinking Water W = Aqueous S = Solid T = Tissue Accreditation Method Codes and Explanation for Table 2 Code Accreditation Certificate No. Method Reference Applicable AXYS Method and Description 1 EPA 1613 3 AXYS MLA-017 7 EPA 1668A 10 AXYS MLA-007 12 AXYS MLA-041 13 AXYS MLA-043 14 AXYS MLA-060 15 AXYS MLA-010 16 AXYS MLA-028 17 AXYS MLA-033 18 AXYS MLA-021 19 AXYS MLA-075 MLA-017 Performance based implementation of EPA 1613B (GC/HRMS) MLA-017 Performance based implementation of EPA 1613B (g C/HRMs ) MLA-010 Performance based implementation of EPA 1668A (GC/HRMs ) MLA-007, Performance based modification of EPA 8270C/D, 8081A/B (GC/LRMS and GC/ECD) MLA-041 Laboratory performance based method (LC/MS-MS) MLA-043 Laboratory performance based method (LC/MS-MS) MLA-060 Laboratory performance based method (LC/MS-MS) MLA-010 Performance based implementation of EPA 1668A (GC/HRMS) MLA-028 Laboratory performance based method (GC/HRMS) MLA-033 Performance based implementation of EPA 1614 (Gc /HRMS) MLA-021 Performance based modification of EPA 8270C/D (GC/LRMS) MLA-075 Performance based implementation of EPA 1694 (LC/MS-MS) TABLE 2 PCDD/F - Polychlorinated Dioxins and Furans 1,2,3,4,6,7,8-HpCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF 1,2,3,4,7,8-HxCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDD 1,2,3,6,7,8-HxCDF 1,2,3,7,8,9-HxCDD 1,2,3,7,8,9-HxCDF 1,2,3,7,8-PeCDD 1,2,3,7,8-PeCDF 2,3,4,6,7,8-HxCDF 2,3,4,7,8-PeCDF 2,3,7,8-TCDD 2,3,7,8-TCDF OCDD OCDF Total TCDD Total TCDF Total PeCDD Total PeCDF Total HxCDD ACC-101 Rev 06, 29-Jun-2011 Canadian Association for Laboratory Accreditation (CALA) Accreditation No.: A 2637 W S Pulp T 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 3333 W ashington State D epartm ent of Ecology Lab. ID: C404 NP S W 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 Page 7 of 18 Page 38 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 2 Total HxCDF Total HpCDD Total HpCDF Total PCDD Total PCDF Total PCDD + PCDF PCBs - Polychlorinated biphenyls PCB 1 2-Chlorobiphenyl PCB 2 3-Chlorobiphenyl PCB 3 4-Chlorobiphenyl PCB 4 2,2'-Dichlorobiphenyl PCB 5 2,3-Dichlorobiphenyl PCB 6 2,3'-Dichlorobiphenyl PCB 7 2,4-Dichlorobiphenyl PCB 8 2,4'-Dichlorobiphenyl PCB 8/5 PCB 9 2,5-Dichlorobiphenyl PCB 10 2,6-Dichlorobiphenyl PCB 11 3,3'-Dichlorobiphenyl PCB 12 3,4-Dichlorobiphenyl PCB 13 3,4'-Dichlorobiphenyl PCB 14 3,5-Dichlorobiphenyl PCB 15 4,4'-Dichlorobiphenyl PCB 16 2,2',3-T richlorobiphenyl PCB 16/32 PCB 17 2,2',4-T richlorobiphenyl PCB 18 2,2',5-Trichlorobiphenyl PCB 19 2,2',6-T richlorobiphenyl PCB 20 2,3,3'-T richlorobiphenyl PCB 21 2,3,4-T richlorobiphenyl PCB 22 2,3,4'-T richlorobiphenyl PCB 23 2,3,5-T richlorobiphenyl PCB 24 2,3,6-T richlorobiphenyl PCB 24/27 PCB 25 2,3',4-T richlorobiphenyl PCB 26 2,3',5-Trichlorobiphenyl PCB 27 2,3',6-T richlorobiphenyl PCB 28 2,4,4'-T richlorobiphenyl PCB 29 2,4,5-T richlorobiphenyl PCB 30 2,4,6-T richlorobiphenyl PCB 31 2,4',5-Trichlorobiphenyl PCB 32 2,4',6-T richlorobiphenyl PCB 33 2,3',4'-T richlorobiphenyl PCB 33/20/21 PCB 34 2,3',5'-T richlorobiphenyl PCB 35 3,3',4-T richlorobiphenyl PCB 36 3,3',5-T richlorobiphenyl PCB 37 3,4,4'-T richlorobiphenyl PCB 38 3,4,5-T richlorobiphenyl PCB 39 3,4',5-T richlorobiphenyl PCB 40 2,2',3,3'-Tetrachlorobiphenyl PCB 41 2,2',3,4-Tetrachlorobiphenyl PCB 41/71/64/68 ACC-101 Rev 06, 29-Jun-2011 Canadian Association for Laboratory Accreditation (CALA) Accreditation No.: A 2637 W S Pulp T W ashington State D epartm ent of Ecology Lab. ID: C404 NP S W 11 11 11 11 11 11 15 15 15 15 15 15 15 15 10 15 15 15 15 15 15 10, 15 15 10 10, 15 10, 15 10, 15 15 15 10, 15 15 15 10 10, 15 10, 15 15 10, 15 15 15 10, 15 15 15 18 15 15 15 15 15 15 10, 15 15 10 15 15 15 15 15 15 15 15 10 15 15 15 15 15 15 10, 15 15 10 10, 15 10, 15 10, 15 15 15 10, 15 15 15 10 10, 15 10, 15 15 10, 15 15 15 10, 15 15 15 10 15 15 15 15 15 15 10, 15 15 10 15 15 15 15 15 15 15 15 10 15 15 15 15 15 15 10, 15 15 10 10, 15 10, 15 10, 15 15 15 10, 15 15 15 10 10, 15 10, 15 15 10, 15 15 15 10, 15 15 15 10 15 15 15 15 15 15 10, 15 15 10 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 Page 8 of 18 Page 39 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 2 PCB 42 PCB 42/59 PCB 43 PCB 44 PCB 45 PCB 46 PCB 47 PCB 47/48/75 PCB 48 PCB 49 PCB 49/43 PCB 50 PCB 51 PCB 52 PCB 52/73 PCB 53 PCB 54 PCB 55 PCB 56 PCB 56/60 PCB 57 PCB 58 PCB 59 PCB 60 PCB 61 PCB 62 PCB 63 PCB 64 PCB 65 PCB 66 PCB 66/80 PCB 67 PCB 68 PCB 69 PCB 70 PCB 70/76 PCB 71 PCB 72 PCB 73 PCB 74 PCB 74/61 PCB 75 PCB 76 PCB 77 PCB 78 PCB 79 PCB 80 PCB 81 PCB 82 PCB 83 PCB 83/108 PCB 84 PCB 85 PCB 85/120 2,2',3,4'-Tetrachlorobiphenyl 2,2',3,5-Tetrachlorobiphenyl 2,2',3,5'-Tetrachlorobiphenyl 2,2',3,6-Tetrachlorobiphenyl 2,2',3,6'-Tetrachlorobiphenyl 2,2',4,4'-Tetrachlorobiphenyl 2,2',4,5-Tetrachlorobiphenyl 2,2',4,5'-Tetrachlorobiphenyl 2,2',4,6-Tetrachlorobiphenyl 2,2',4,6'-Tetrachlorobiphenyl 2,2',5,5'-Tetrachlorobiphenyl 2,2',5,6'-Tetrachlorobiphenyl 2,2',6,6'-Tetrachlorobiphenyl 2,3,3',4-Tetrachlorobiphenyl 2,3,3',4'-Tetrachlorobiphenyl 2,3,3',5-Tetrachlorobiphenyl 2,3,3',5'-Tetrachlorobiphenyl 2,3,3',6-Tetrachlorobiphenyl 2,3,4,4'-Tetrachlorobiphenyl 2,3,4,5-Tetrachlorobiphenyl 2,3,4,6-Tetrachlorobiphenyl 2,3,4',5-Tetrachlorobiphenyl 2,3,4',6-Tetrachlorobiphenyl 2,3,5,6-Tetrachlorobiphenyl 2,3',4,4'-Tetrachlorobiphenyl 2,3',4,5-Tetrachlorobiphenyl 2,3',4,5'-Tetrachlorobiphenyl 2,3',4,6-Tetrachlorobiphenyl 2,3',4',5-Tetrachlorobiphenyl 2,3',4',6-Tetrachlorobiphenyl 2,3',5,5'-Tetrachlorobiphenyl 2,3',5',6-Tetrachlorobiphenyl 2,4,4',5-Tetrachlorobiphenyl 2,4,4',6-Tetrachlorobiphenyl 2,3',4',5'-Tetrachlorobiphenyl 3,3',4,4'-Tetrachlorobiphenyl 3,3',4,5-Tetrachlorobiphenyl 3,3',4,5'-Tetrachlorobiphenyl 3,3',5,5'-Tetrachlorobiphenyl 3,4,4',5-Tetrachlorobiphenyl 2,2',3,3',4-Pentachlorobiphenyl 2,2',3,3',5-Pentachlorobiphenyl 2,2',3,3',6-Pentachlorobiphenyl 2,2',3,4,4'-Pentachlorobiphenyl ACC-101 Rev 06, 29-Jun-2011 Canadian Association for Laboratory Accreditation (CALA) Accreditation No.: A 2637 W 15 10 15 10, 15 10, 15 10, 15 15 10 15 15 10 15 15 15 10 15 15 15 15 10 15 15 15 15 15 15 15 15 15 15 10 15 15 15 15 10 15 15 15 15 10 15 15 10, 15 15 15 15 15 15 15 10 10, 15 15 10 S 15 10 15 10, 15 10, 15 10, 15 15 10 15 15 10 15 15 15 10 15 15 15 15 10 15 15 15 15 15 15 15 15 15 15 10 15 15 15 15 10 15 15 15 15 10 15 15 10, 15 15 15 15 15 15 15 10 10, 15 15 10 Pulp T 15 10 15 10, 15 10, 15 10, 15 15 10 15 15 10 15 15 15 10 15 15 15 15 10 15 15 15 15 15 15 15 15 15 15 10 15 15 15 15 10 15 15 15 15 10 15 15 10, 15 15 15 15 15 15 15 10 10, 15 15 10 W ashington State D epartm ent of Ecology Lab. ID: C404 NP S W 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 Page 9 of 18 Page 40 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 2 PCB 86 2,2',3,4,5-Pentachlorobiphenyl PCB 87 2,2',3,4,5'-Pentachlorobiphenyl PCB 87/115/116 PCB 88 2,2',3,4,6-Pentachlorobiphenyl PCB 89 2,2',3,4,6'-Pentachlorobiphenyl PCB 90 2,2',3,4',5-Pentachlorobiphenyl PCB 91 2,2',3,4',6-Pentachlorobiphenyl PCB 92 2,2',3,5,5'-Pentachlorobiphenyl PCB 93 2,2',3,5,6-Pentachlorobiphenyl PCB 94 2,2',3,5,6'-Pentachlorobiphenyl PCB 95 2,2',3,5',6-Pentachlorobiphenyl PCB 95/93 PCB 96 2,2',3,6,6'-Pentachlorobiphenyl PCB 97 2,2',3,4',5'-Pentachlorobiphenyl PCB 97/86 PCB 98 2,2',3,4',6'-Pentachlorobiphenyl PCB 99 2,2',4,4',5-Pentachlorobiphenyl PCB 100 2,2',4,4',6-Pentachlorobiphenyl PCB 101 2,2',4,5,5'-Pentachlorobiphenyl PCB 101/90/89 PCB 102 2,2',4,5,6'-Pentachlorobiphenyl PCB 103 2,2',4,5',6-Pentachlorobiphenyl PCB 104 2,2',4,6,6'-Pentachlorobiphenyl PCB 105 2,3,3',4,4'-Pentachlorobiphenyl PCB 105/127 PCB 106 2,3,3',4,5-Pentachlorobiphenyl PCB 107 2,3,3',4',5-Pentachlorobiphenyl PCB 107/109 PCB 108 2,3,3',4,5'-Pentachlorobiphenyl PCB 109 2,3,3',4,6-Pentachlorobiphenyl PCB 110 2,3,3',4',6-Pentachlorobiphenyl PCB 111 2,3,3',5,5'-Pentachlorobiphenyl PCB 112 2,3,3',5,6-Pentachlorobiphenyl PCB 113 2,3,3',5',6-Pentachlorobiphenyl PCB 114 2,3,4,4',5-Pentachlorobiphenyl PCB 115 2,3,4,4',6-Pentachlorobiphenyl PCB 116 2,3,4,5,6-Pentachlorobiphenyl PCB 117 2,3,4',5,6-Pentachlorobiphenyl PCB 118 2,3',4,4',5-Pentachlorobiphenyl PCB 118/116 PCB 119 2,3',4,4',6-Pentachlorobiphenyl PCB 120 2,3',4,5,5'-Pentachlorobiphenyl PCB 121 2,3',4,5',6-Pentachlorobiphenyl PCB 122 2,3,3',4',5'-Pentachlorobiphenyl PCB 123 2,3',4,4',5'-Pentachlorobiphenyl PCB 124 2,3',4',5,5'-Pentachlorobiphenyl PCB 125 2,3',4',5',6-Pentachlorobiphenyl PCB 126 3,3',4,4',5-Pentachlorobiphenyl PCB 127 3,3',4,5,5'-Pentachlorobiphenyl PCB 128 2,2',3,3',4,4'-Hexachlorobiphenyl PCB 129 2,2',3,3',4,5-Hexachlorobiphenyl PCB 130 2,2',3,3',4,5'-Hexachlorobiphenyl PCB 131 2,2',3,3',4,6-Hexachlorobiphenyl PCB 131/142 ACC-101 Rev 06, 29-Jun-2011 Canadian Association for Laboratory Accreditation (CALA) Accreditation No.: A 2637 W 15 15 10 15 15 15 10, 15 15 15 15 15 10 15 15 10 15 10, 15 15 15 10 15 15 15 15 10 15 15 10 15 15 10, 15 15 15 15 10, 15 15 15 15 15 10 15 15 15 15 15 15 15 10, 15 15 10, 15 10, 15 10, 15 15 10 S 15 15 10 15 15 15 10, 15 15 15 15 15 10 15 15 10 15 10, 15 15 15 10 15 15 15 15 10 15 15 10 15 15 10, 15 15 15 15 10, 15 15 15 15 15 10 15 15 15 15 15 15 15 10, 15 15 10, 15 10, 15 10, 15 15 10 Pulp T 15 15 10 15 15 15 10, 15 15 15 15 15 10 15 15 10 15 10, 15 15 15 10 15 15 15 15 10 15 15 10 15 15 10, 15 15 15 15 10, 15 15 15 15 15 10 15 15 15 15 15 15 15 10, 15 15 10, 15 10, 15 10, 15 15 10 W ashington State D epartm ent of Ecology Lab. ID: C404 NP S W 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 Page 10 of 18 Page 41 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 2 PCB 132 2,2',3,3',4,6'-Hexachlorobiphenyl PCB 133 2,2',3,3',5,5'-Hexachlorobiphenyl PCB 134 2,2',3,3',5,6-Hexachlorobiphenyl PCB 134/143 PCB 135 2,2',3,3',5,6'-Hexachlorobiphenyl PCB 136 2,2',3,3',6,6'-Hexachlorobiphenyl PCB 137 2,2',3,4,4',5-Hexachlorobiphenyl PCB 138 2,2',3,4,4',5'-Hexachlorobiphenyl PCB 138/163/164 PCB 139 2,2',3,4,4',6-Hexachlorobiphenyl PCB 140 2,2',3,4,4',6'-Hexachlorobiphenyl PCB 141 2,2',3,4,5,5'-Hexachlorobiphenyl PCB 142 2,2',3,4,5,6-Hexachlorobiphenyl PCB 143 2,2',3,4,5,6'-Hexachlorobiphenyl PCB 144 2,2',3,4,5',6-Hexachlorobiphenyl PCB 144/135 PCB 145 2,2',3,4,6,6'-Hexachlorobiphenyl PCB 146 2,2',3,4',5,5'-Hexachlorobiphenyl PCB 147 2,2',3,4',5,6-Hexachlorobiphenyl PCB 148 2,2',3,4',5,6'-Hexachlorobiphenyl PCB 149 2,2',3,4',5',6-Hexachlorobiphenyl PCB 149/139 PCB 150 2,2',3,4',6,6'-Hexachlorobiphenyl PCB 151 2,2',3,5,5',6-Hexachlorobiphenyl PCB 152 2,2',3,5,6,6'-Hexachlorobiphenyl PCB 153 2,2',4,4',5,5'-Hexachlorobiphenyl PCB 154 2,2',4,4',5,6'-Hexachlorobiphenyl PCB 155 2,2',4,4',6,6'-Hexachlorobiphenyl PCB 156 2,3,3',4,4',5-Hexachlorobiphenyl PCB 157 2,3,3',4,4',5'-Hexachlorobiphenyl PCB 158 2,3,3',4,4',6-Hexachlorobiphenyl PCB 158/160 PCB 159 2,3,3',4,5,5'-Hexachlorobiphenyl PCB 160 2,3,3',4,5,6-Hexachlorobiphenyl PCB 161 2,3,3',4,5',6-Hexachlorobiphenyl PCB 162 2,3,3',4',5,5'-Hexachlorobiphenyl PCB 163 2,3,3',4',5,6-Hexachlorobiphenyl PCB 164 2,3,3',4',5',6-Hexachlorobiphenyl PCB 165 2,3,3',5,5',6-Hexachlorobiphenyl PCB 166 2,3,4,4',5,6-Hexachlorobiphenyl PCB 167 2,3',4,4',5,5'-Hexachlorobiphenyl PCB 168 2,3',4,4',5',6-Hexachlorobiphenyl PCB 169 3,3',4,4',5,5'-Hexachlorobiphenyl PCB 170 2,2',3,3',4,4',5-Heptachlorobiphenyl PCB 170/190 PCB 171 2,2',3,3',4,4',6-Heptachlorobiphenyl PCB 172 2,2',3,3',4,5,5'-Heptachlorobiphenyl PCB 172/192 PCB 173 2,2',3,3',4,5,6-Heptachlorobiphenyl PCB 174 2,2',3,3',4,5,6'-Heptachlorobiphenyl PCB 174/181 PCB 175 2,2',3,3',4,5',6-Heptachlorobiphenyl PCB 176 2,2',3,3',4,6,6'-Heptachlorobiphenyl PCB 177 2,2',3,3',4,5',6'-Heptachlorobiphenyl ACC-101 Rev 06, 29-Jun-2011 Canadian Association for Laboratory Accreditation (CALA) Accreditation No.: A 2637 W 15 15 15 10 15 10, 15 10, 15 15 10 15 15 10, 15 15 15 15 10 15 10, 15 15 15 15 10 15 10, 15 15 10, 15 15 15 10, 15 10, 15 15 10 15 15 15 15 15 15 15 15 15 15 10, 15 15 10 10, 15 15 10 15 15 10 10, 15 10, 15 10, 15 S 15 15 15 10 15 10, 15 10, 15 15 10 15 15 10, 15 15 15 15 10 15 10, 15 15 15 15 10 15 10, 15 15 10, 15 15 15 10, 15 10, 15 15 10 15 15 15 15 15 15 15 15 15 15 10, 15 15 10 10, 15 15 10 15 15 10 10, 15 10, 15 10, 15 Pulp T 15 15 15 10 15 10, 15 10, 15 15 10 15 15 10, 15 15 15 15 10 15 10, 15 15 15 15 10 15 10, 15 15 10, 15 15 15 10, 15 10, 15 15 10 15 15 15 15 15 15 15 15 15 15 10, 15 15 10 10, 15 15 10 15 15 10 10, 15 10, 15 10, 15 W ashington State D epartm ent of Ecology Lab. ID: C404 NP S W 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 Page 11 of 18 Page 42 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 2 PCB 178 2,2',3,3',5,5',6-Heptachlorobiphenyl PCB 179 2,2',3,3',5,6,6'-Heptachlorobiphenyl PCB 180 2,2',3,4,4',5,5'-Heptachlorobiphenyl PCB 181 2,2',3,4,4',5,6-Heptachlorobiphenyl PCB 182 2,2',3,4,4',5,6'-Heptachlorobiphenyl PCB 183 2,2',3,4,4',5',6-Heptachlorobiphenyl PCB 184 2,2',3,4,4',6,6'-Heptachlorobiphenyl PCB 185 2,2',3,4,5,5',6-Heptachlorobiphenyl PCB 186 2,2',3,4,5,6,6'-Heptachlorobiphenyl PCB 187 2,2',3,4',5,5',6-Heptachlorobiphenyl PCB 187/182 PCB 188 2,2',3,4',5,6,6'-Heptachlorobiphenyl PCB 189 2,3,3',4,4',5,5'-Heptachlorobiphenyl PCB 190 2,3,3',4,4',5,6-Heptachlorobiphenyl PCB 191 2,3,3',4,4',5',6-Heptachlorobiphenyl PCB 192 2,3,3',4,5,5',6-Heptachlorobiphenyl PCB 193 2,3,3',4',5,5',6-Heptachlorobiphenyl PCB 194 2,2',3,3',4,4',5,5'-Octachlorobiphenyl PCB 195 2,2',3,3',4,4',5,6-Octachlorobiphenyl PCB 196 2,2',3,3',4,4',5,6'-Octachlorobiphenyl PCB 196/203 PCB 197 2,2',3,3',4,4',6,6'-Octachlorobiphenyl PCB 198 2,2',3,3',4,5,5',6-Octachlorobiphenyl PCB 199 2,2',3,3',4,5,5',6'-Octachlorobiphenyl PCB 200 2,2',3,3',4,5,6,6'-Octachlorobiphenyl PCB 201 2,2',3,3',4,5',6,6'-Octachlorobiphenyl PCB 202 2,2',3,3',5,5',6,6'-Octachlorobiphenyl PCB 203 2,2',3,4,4',5,5',6-Octachlorobiphenyl PCB 204 2,2',3,4,4',5,6,6'-Octachlorobiphenyl PCB 205 2,3,3',4,4',5,5',6-Octachlorobiphenyl PCB 206 2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl PCB 207 2,2',3,3',4,4',5,6,6'-Nonachlorobiphenyl PCB 208 2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl PCB 209 Decachlorobiphenyl Total Monochlorobiphenyls Total Dichlorobiphenyls Total Trichlorobiphenyls Total Tetrachlorobiphenyls Total Pentachlorobiphenyls Total Hexachlorobiphenyls Total Heptachlorobiphenyls Total Octachlorobiphenyls Total Nonachlorobiphenyls Total Decachlorobiphenyls Total Polychlorinated biphenyls Aroclors Aroclor 1260 Aroclor 1254 Aroclor 1268 Aroclor 1221 Aroclor 1232 Aroclor 1248 Aroclor 1016 ACC-101 Rev 06, 29-Jun-2011 Canadian Association for Laboratory Accreditation (CALA) Accreditation No.: A 2637 W 10, 15 10, 15 10, 15 15 15 10, 15 15 10, 15 15 15 10 15 10, 15 15 10, 15 15 10, 15 10, 15 10, 15 15 10 10, 15 10, 15 10, 15 15 10, 15 15 15 15 10, 15 10, 15 10, 15 10, 15 10, 15 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10 10 S 10, 15 10, 15 10, 15 15 15 10, 15 15 10, 15 15 15 10 15 10, 15 15 10, 15 15 10, 15 10, 15 10, 15 15 10 10, 15 10, 15 10, 15 15 10, 15 15 15 15 10, 15 10, 15 10, 15 10, 15 10, 15 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10 10 Pulp T 10, 15 10, 15 10, 15 15 15 10, 15 15 10, 15 15 15 10 15 10, 15 15 10, 15 15 10, 15 10, 15 10, 15 15 10 10, 15 10, 15 10, 15 15 10, 15 15 15 15 10, 15 10, 15 10, 15 10, 15 10, 15 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 10 10 W ashington State D epartm ent of Ecology Lab. ID: C404 NP S W 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 7 10 10 10 10 10 10 10 10 10 10 10 10 10 7 10 7 10 10 7 10 7 10 7 7 7 7 7 7 7 7 Page 12 of 18 Page 43 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 2 Aroclor 1242 Aroclor 1242/1016 Pesticides 2,4'-DDD 2,4'-DDE 2,4'-DDT 4,4'-DDD 4,4'-DDE 4,4'-DDT Aldrin Alpha-HCH Beta-HCH cis-Chlordane (alpha-Chlordane) cis-Nonachlor Delta-HCH Dieldrin Endosulphan I Endosulphan II Endosulphan sulphate Endrin Endrin aldehyde Endrin ketone Gamma-HCH (Lindane) Heptachlor Heptachlor epoxide Hexachlorobenzene Hexachlorobutadiene Methoxychlor Mirex Oxychlordane Toxaphene trans-Chlordane (gamma-Chlordane) trans-Nonachlor BDE - Brominated Diphenylethers BDE 7 2,4-dibromodiphenylether BDE 8 2,4'-dibromodiphenylether BDE 10 2,6-dibromodiphenylether BDE 11 3,3'-dibromodiphenylether BDE 12 3,4-dibromodiphenylether BDE 13 3,4'-dibromodiphenylether BDE 15 4,4'-dibromodiphenylether BDE 17 2,2',4-tribromodiphenylether BDE 25 2,3',4-tribromodiphenylether BDE 28 2,4,4'-tribromodiphenylether BDE 30 2,4,6-tribromodiphenylether BDE-33 2',3,4-tribromodiphenylether BDE 35 3,3',4-tribromodiphenylether BDE 37 3,4,4'-tribromodiphenylether BDE 47 2,2',4,4'-tetrabromodiphenylether BDE 49 2,2',4,5'-tetrabromodiphenylether BDE 66 2,3',4,4'-tetrabromodiphenylether BDE 75 2,4,4',6-tetrabromodiphenylether ACC-101 Rev 06, 29-Jun-2011 Canadian Association for Laboratory Accreditation (CALA) Accreditation No.: A 2637 W S Pulp T 10 10 10 W ashington State D epartm ent of Ecology Lab. ID: C404 NP S W 77 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10 10, 16 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 16 10, 16 10, 16 10, 16 10 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 16 10, 16 10, 16 10, 16 10, 16 10, 16 16 10, 16 10, 16 10, 16 10 10, 16 10, 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 Page 13 of 18 Page 44 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 2 BDE 77 BDE 85 BDE 99 BDE 100 BDE 105 BDE 116 BDE 119 BDE 126 BDE 140 BDE 153 BDE 154 BDE 155 BDE 166 BDE 181 BDE-183 BDE 190 BDE 206 BDE 207 BDE 208 BDE 209 3,3',4,4'-tetrabromodiphenylether 2,2',3,4,4'-pentabromodiphenylether 2,2',4,4',5-pentabromodiphenylether 2,2',4,4',6-pentabromodiphenylether 2,3,3',4,4'-pentabromodiphenylether 2,3,4,5,6-pentabromodiphenylether 2,3',4,4',6-pentabromodiphenylether 3,3',4,4',5-pentabromodiphenylether 2,2',3,4,4',6'-hexabromodiphenylether 2,2',4,4',5,5'-hexabromodiphenylether 2,2',4,4',5',6-hexabromodiphenylether 2,2',4,4',6,6'-hexabromodiphenylether 2,3,4,4',5,6-hexabromodiphenylether 2,2',3,4,4',5,6-heptabromodiphenylether 2,2',3,4,4',5',6-heptabromodiphenylether 2,3,3',4,4',5,6-heptabromodiphenylether 2,2',3,3',4,4',5,5',6-nonabromodiphenylether 2,2',3,3',4,4',5,6,6'-nonabromodiphenylether 2,2',3,3',4,5,5',6,6'-nonabromodiphenylether Decabromodiphenylether PFC - Perfluorinated Organic Compounds Perfluorobutanoate (PFBA) Perfluoropentanoate (PFPeA) Perfluorohexanoate (PFHxA) Perfluoroheptanoate (PFHpA) Perfluorooctanoate (PFOA) Perfluorononanoate (PFNA) Perfluorodecanoate (PFDA) Perfluoroundecanoate (PFUnA) Perfluorododecanoate (PFDoA) Perfluorobutanesulfonate (PFBS) Perfluorohexanesulfonate (PFHxS) Perfluorooctanesulfonate (PFOS) Perfluorooctane sulfonamide (PFOSA) PAH Anthracene Pyrene Benzo[ghi]perylene Benzo[e]pyrene Indeno[1,2,3-cd]pyrene Perylene Benzo[b]fluoranthene Fluoranthene Benzo[k]fluoranthene Acenaphthylene Chrysene Benzo[a]pyrene Dibenz[ah]anthracene Benz[a]anthracene Acenaphthene Phenanthrene Fluorene ACC-101 Rev 06, 29-Jun-2011 Canadian Association for Laboratory Accreditation (CALA) Accreditation No.: A 2637 W S Pulp T 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 W ashington State D epartm ent of Ecology Lab. ID: C404 NP S W 14 12 14 12 14 12 14 12 14 12 14 12 14 12 14 12 14 12 14 12 14 12 14 12 14 12 13 13 13 13 13 13 13 13 13 13 13 13 13 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 Page 14 of 18 Page 45 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 2 Naphthalene PPCP (Pharmaceutical and Personal Care Products) Acetaminophen Azithromycin Caffeine Carbadox Carbamazepine Cefotaxime Ciprofloxacin Clarithromycin Clinafloxacin Cloxacillin Dehydronifedipine Digoxigenin Digoxin Diltiazem 1,7-Dimethylxanthine Diphenhydramine Enrofloxacin Erythromycin Flumequine Fluoxetine Lincomycin Lomefloxacin Miconazole Norfloxacin Norgestimate Ofloxacin Ormetoprim Oxacillin Oxolinic acid Penicillin G Penicillin V Roxithromycin Sarafloxacin Sulfachloropyridazine Sulfadiazine Sulfadimethoxine Sulfamerazine Sulfamethazine Sulfamethizole Sulfamethoxazole Sulfanilamide Sulfathiazole Thiabendazole Trimethoprim Tylosin Virginiamycin Anhydrochlortetracycline (ACTC) Anhydrotetracycline (ATC) Chlortetracycline (CTC) Demeclocycline ACC-101 Rev 06, 29-Jun-2011 Canadian Association for Laboratory Accreditation (CALA) Accreditation No.: A 2637 W S Pulp T 18 18 W ashington State D epartm ent of Ecology Lab. ID: C404 NP S W 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 Page 15 of 18 Page 46 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 2 Doxycycline 4-Epianhydrochlortetracycline (EACTC) 4-Epianhydrotetracycline (EATC) 4-Epichlortetracycline (ECTC) 4-Epioxytetracycline (EOTC) 4-Epitetracycline (ETC) Isochlortetracycline (ICTC) Minocycline Oxytetracycline (OTC) Tetracycline (TC) Bisphenol A Furosemide Gemfibrozil Glipizide Glyburide Hydrochlorothiazide 2-hydroxy-ibuprofen Ibuprofen Naproxen Triclocarban Triclosan Warfarin Albuterol Amphetamine Atenolol Atorvastatin Cimetidine Clonidine Codeine Cotinine Enalapril Hydrocodone Metformin Oxycodone Ranitidine Triamterene Alprazolam Amitriptyline Amlodipine Benzoylecgonine Benztropine Betamethasone Cocaine DEET (N,N-diethyl-m-toluamide) Desmethyldiltiazem Diazepam Fluocinonide Fluticasone propionate Hydrocortisone 10-hydroxy-amitriptyline Meprobamate ACC-101 Rev 06, 29-Jun-2011 Canadian Association for Laboratory Accreditation (CALA) Accreditation No.: A 2637 W S Pulp T 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 W ashington State D epartm ent of Ecology Lab. ID: C404 NP S W 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 Page 16 of 18 Page 47 of 49 www.axysanalytical.com TABLE 2 Methylprednisolone Metoprolol Norfluoxetine Norverapamil Paroxetine Prednisolone Prednisone Promethazine Propoxyphene Propranolol Sertraline Simvastatin Theophylline Trenbolone Trenbolone acetate Valsaran Verapamil AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Accreditation No.: A 2637 W S Pulp T 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 W ashington State D epartm ent of Ecology Lab. ID: C404 NP S W Table 1 and Table 2 - Explanation of Terms Used: NELAP = National Environmental Laboratory Accreditation Program Non-potable water = water not fit for consumption without treatment as it may contain pollutants, contaminants, minerals or infective agents. Surface water, ground water, rainwater, effluents as well as any other non-drinking water sources are included in this category. Solid = environmental solid sample. Soil, sediment, biosolids, hazardous waste, mixed phase samples with significant solids content are included in this category. Performance based implementation = methodology follows that of the method reference but modifications deemed by AXYS as minor 1may apply, results meet method reference data quality standard. Performance based modification = modifications deemed by AXYS as significant2 have been made to method reference protocol, results meet method reference accuracy standard. The suitability of the methodology for any method prescriptive applications should be assessed based on the modifications made and the specific work requirements. Performance based method = an in-house AXYS method, published method reference not applicable. GC/LRMS = gas chromatography, low resolution mass spectrometry detection. GC/HRMS = gas chromatography, high resolution mass spectrometry detection. GC/ECD = gas chromatography, electron capture detection. LC/MS-MS = liquid chromatography, mass spectrometry-mass spectrometry detection. ACC-101 Rev 06, 29-Jun-2011 Page 17 of 18 Page 48 of 49 www.axysanalytical.com AXYS Analytical Services Ltd. Note 1: Performance Based Implementation - Examples of Minor Modifications - use of additional isotopically labeled references - adjustment of calibration range - adjustment of clean-up technique - use of a different extraction of same general type (example soxhlet vs soxhlet Dean Stark) - addition of matrix type using same principles (example addition of tissue matrix using same detection principle and similar extraction type) Note 2: Performance Based Modification - Examples of Significant Modifications - different acquisition conditions using same detection principle (example MS SIM vs. full scan) - different internal control limits while meeting method reference accuracy standard ACC-101 Rev 06, 29-Jun-2011 Page 18 of 18 Page 49 of 49