Document gEEj3nNEvLy6LXqq9r5DLoNxV

m t- i \i / "^ STATE OF WEST VIRGINIA AIR POLLUTION CONTROL COMMISSION REGULATION XIII REGISTRATION OF AFFECTED SOITRCE(S)* <- . (Rirsuant to Section 3, Series XIII, and Chapter 1G-20-11B of the Code of West Virginia. ) INSTRUCTIONS: 1. Answer all questions. If certain questions are not applicable to your activity, please indicate NONE or NOT APPLICABLE. 2. Use the last 12 months of data available (e. g. , 1971 or July 1, 1971 to July 1, 1972). Specifiy period covered by Registration November I, I97l to November,I, 1972 3. If additional space is needed for answering any question, use additional sheets, following a similar format. 4. Return completed registration to: Registration - Series XIII West Virginia Air EolLution Control Commission 1558 Washington Street, East Charleston, West Virginia 25311 Section I. GENERAL: A. Name of organization: Union Carbide Corporation - Chemicals and Plastics Division B. Mailing address of organization: P. O.Bcx 8004 South Charleston, West Virginia 25303 C. Individual to contact regarding this registration: Name R. G. Li I ley______ Address Same as above T itle Environmental Protection Coordinator Phone 747-3169 D. Type of plant/unit (affected source)" being registered: Solvent Resin Unit E. Plant/Unit (affected source)" location: f*. Nearest Town South Charleston, W. Va. County Kanawha Directions to plant from nearest state road: Nnrth Fnst *See Regulation XIII, Sub-section 2.11. For the purposes of this Registration Form, the emission rate to be used to determine if a stationary source is an "affected source" in Sub-section 2. II (a-2) of Regulation XIII will be that emission rate of each pollutant which may bo emitted from all equipment at one location which together may bo considered to form a discrete manufacturing process unit. APCC-R-3-72 UCC 103423 F. Person completing form Charles Fry Section II. Date Completed January 22, 1973 AFFECTED SOURCE INFORMATION: Reviewed By: Bert Murray Bill Young A. On the attached "last Form" list all affected sources to be registered and all applicable air pollution control de vices. Also list all emission points to the atmosphere including emergency relief vents. Note' that each affected source, each control device and each emission point must have an I dentification Number. B. Construct on a separate sheet a sche matic line diagram showing these sources, their air pollution control de vices and atmospheric emission points in an understand able line sequence of operation. Show clearly which con trol device serves each source. Label the diagram with the Identification Numbers as well as descriptive words. C. Fill out an EMISSIONS POINTS DATA SHEET for all emission points on the list and diagram. Section III. CERTIFICATION: I hereby certify that all information in this registration and supplementary documents attached is true and correct to the best of my knowledge and that all reasonable efforts have been made to provide the most comprehensive information possible. SIGNED TITLE DATE APCC-R-3-72 UCC 103424 EMISSIONS POINTS DATA SHEET H/ <V' Identifi cation Number ^ of Emis sion Point to Atmos phere 1e List All Affected o Source(s) Vented Through this point * 6s b Ze 3e 6s 6s 4e 6s 5e 6s X fee 6s 7e 6s 8e 6s 9e 6s O Maximum Potential Emissions Maximum Actual Emissions (lbs/hr) With Control Device Applied i (lbs/hr) Height Gas Dimen of Exit Volume sions Point Through of Exit Above Exit Point Ground Point meters (meters! (ACFM) . 254dia 6. 1 .5 Exit * Gas Temp erature <F) Ambient Exit Gas Velocity (meters / sec) . 005 . 076dia 27. 4 . 025dia 30.5 1 Ambient . 105 2 Ambient 1.89 . 076dia 30. 5 1 Ambient . 105 . 025dia 12. 2 2 Ambinet 1. 89 . 15 dia 13. 4 6 Ambient .160 . 15 dia 13. 4 6 70 . 160 1.219 x 1.219 1.219 x 1.219 30. 5 30. 5 9, 131 9, 131 120 2.9 120 2.9 ct' 1________________ ______ \ Oxi Other CO HC `NOx dants ^Specify) CO HC NOx /) 2.02 i .400' . 32 Acetone . 13 i.4 Acetonel!; Acetone. 2 . 12 Acetone 1 .0 4. 36 Isoprop . 5 Acetone 3 Isoprop 3 2 1.6 Acetone 1 1.5 14.4 Lsoprop 2 Acetone c 7 .84 lsoprop 2 4. 5 14. 4 Acetone ^ 7 Lsoprop 2 4. 5 _______ Oxi Other dants (Specify) Acetone 1. lsoprop 1. Acetone . 1 lsoprop . 7 1 Must correspond to number given on the Sjpction II "List Form". 2 List by identification number assigned as required on the Section II "List Form". 3 Emissions that could be emitted if air pollution control equipment was not working or is not installed. APCC-R-3-72 l UCC 103425 EMISSIONS POINTS DATA SHEET Identifi cation Number 1 of Emis sion Point to Atmosphc re lOe List All Affected o Sourcc(s)" Vented Through this point 1 6s lie 6s 12e 6s 13e 6s 14e 6s 15e 6s I6e 6s *> Maximum Potential Emissions^ (lbs/hr) Maximum Actual Emissions With Control Device Applied (lbs/hr) Height Gas Dimen of Exit Volume sions Point Through of Exit Above Exit Point Ground Point uneters (meters. (AC EM) 1.219 x 30. 5 1.219 9, 131 . 203dia 36. 6 1, 200 . J05dia 30. 5 650 Exit Gas T emperature (F) 120 Exit Gas Velocity (meters / sec) 2. 9 Ambient Ambient 17. 5 4. 2 CO .305dia 6. 1 5 80 .030 . 2 5 4dia 6. 1 4 80 . 037 . 254dia 6. 1 3 75 .028 . 33 dia | 20. 7 . 2 Ambient . 001 HC 14. 4 .4 .21 .2 19 7. 9 3.9 .8 .1 Oxi Other dants 'Spec ify) CO Acetone 97 Isoprop 24. 5 Acetone . 25 Isoprop . 1 Acetone . 5 Isoprop . 25 Acetone 10 Isoprop 1.5 Acetone 4 Isoprop . 3 Acetone 1.5 Isoprop . 3 no *x 9. 74 3. 943 1.847 .4 .02 Oxi Other dants (Spec ify) Acetone 3. 2 Isoprop . 24 Acetone 1. 5 Isoprop . 1 Acetone . 7 Isoprop . 1 1 Must correspond to number given on the Section II "List Form". 2 List by identification number assigned as required on the Section II "List Form", 3 Emissions that could be emitted if air pollution control equipment was not working or is not installed. APCC-R-3-72 UCC 103426 EMISSIONS POINTS DATA SHEET Identifi cation Number ^ of Emis sion. Point to Atmos phere 17e List All Affected Source(s) ^ Vented Through this point 6s 18e 6s ^ I 1> -*> 19e 6s 20e 6s 2 le 6s 22e 6s 23e 6s 24e 6s 25e 6s 26e 6s r> Maximum Potential Emissions' (lbs/hr) Maximum Actual Emissions With Control Device Applied (lbs/hr) Height Gas Dimen of Exit Volume sions Point Through of Exit Above Exit Point Ground Point 'meters (meters :< AC FAD .33 dia 20. 1 .2 Exit Gas T emperature <F) Amaient Exit Gas Velocity (meters 1 sec) . 001 CO .16 dia 6. 1 2 Ambient . 001 .076dia 20. 7 1.8 .20 dia 1.6 1. 8 80 Ambient . 180 V/ S'9 . 028 .10 dia . 025dia . 025dia . 05 dia . 25 dia Leak 16.2 1.6 7. 0 16. 1 6. 1 6.1 2 1 1 1 1 Seal Leak Ambient Ambient 70 Ambient Ambient 70 .011 " i. o -- . 940 . 940 r - ^ - *t *7 *7 J . 240 w ' i c. "7^. VhA Seal Leak IIC NOx d a nt s .8 .1 1. 5 1. 5 100 b 1.0 3. 2 .8 2.0 .2 10. 15 C A l Other Specify) CO Acetone 2 Acetone . 05 Acetone 2 Acetone 1.5 Acetone 1.0 Isoprop 1.0 Isoprop . 7 Acetone . 4 PC "AT . 02 .83 .5 20. 8 . 17 . 66 . 42 . 66 . 08 *x Oxi- Other dants (Specify) Acetone . 5 Acetone . 0! Acetone 1 Acetone . 6 Acetone . 3 Isoprop . 1 Isoprop . 3 UCC 103427 1 Must correspond to number given on the Section II "List Form . r 2 List by identification number assigned as required on the Section II "List Form". 3 Emissions that could be emitted if air pollution control equipment was not working or is not installed. APCC-R-3-72 EMISSIONS POINTS DATA SHEET Identifi cation Number ^ of Emis sion Point to Atmos phere 2 7e 28e 29e 30e 31e 32e 33e 34e 35e 36e 37e 38e . 39e 40e > 41e List All Affected Source(s) " Vented Through this point ' 6s 6s 6s 6s 6s 6s 6s 6s 6s 6s 6s 6s 6s 6s 6s O Maximum Potential Emissions (lbs/hr) Maximum Actual Emissions With Control Device Applied (lbs/hr) Height Gas Dimen of Exit Volume sions Point Through of Exit Above Exit Point Ground Point meters {meters] (AC FA I) Exit Gas T emperature (F) Exit Gas Velocitv (meters /sec) CO . 1016 . 076 . 1524 . 1524 . 0381 . 1016 . 1016 .0762 . 1524 . 0762 . 1524 . J016 Leaks . 1524 . 1016 2. 7) 19. 4) 2. 7) 21.4) 6) 19. 4) 2. 7) 19.4) 19. 4) 6. 1) 27 ) 27 ) 6. 4 27 ) 27 ) Emer gency reli sf devices that h ive not ac :ivated in ove r 5 years Seal Leak 70 Seal Leak Emergenc y relief ivices that have lot actival ed in 5 yea rs Oxi Other HC NOx dants 'Specify) CO 10.15 ^ 3 * oc /o /$r f? Acetone . 4 Oxi Cither IfC NOx dants (Specify) UCC 103428 1 Must correspond to number given on the Section II "List Form". 2 List by identification number assigned as required on the Section II "List Form". 3 Emissions that could be emitted if air pollution control equipment was not working or is not installed. APCC-R-3-72 Identification Number Is. 2s. 3s. 4s. 5s. 6s. 7s. 8s, 9s. 10s. 11s. 12s. 13s. 14s. 15s. 16s. 17s. 18s. Identification Number lc. 2c. 3c. 4c. 5c. 6c. 7c. 8c. 9c. 10c. 11c. 12c. 13c. 14c. 15c. 16c. 17c. 18c. Identification Number le. 2e. 3e. 4e. 5e. 6e. 7c. 8e. 9e. lOe. lie. 12e. 13c. 14c. 15e. 16e. 17e. 18e. SECTION II LIST FORM Affected Source Name No. 1 Solvent Resin Process Air Pollution Control Device (Type) BS 8c B Vent BS 8c B Vent BS 8c B Vent BS & B Vent BS & B Vent BS & B Vent BS & B Vent BS 8c B Vent BS 8c B Vent BS 8c B Vent BS 8c B Vent BS 8c B Vent * BS 8c B Vent BS Sc B Vent BS 8c B Vent BS & B Vent BS &c B Vent Motor valve pressure control Emission Point Storage tank vent ^ Vent scrubber tank vent ^ Centrifuge vent J , Storage tank vent ^ Mix tank vent v Slurry tank vent J Slurry tank vent Dryer discnarge Dryer discharge Dryer discharge Transfer system vent Product storage bin vent Solvent storage tank vent Solvent storage tank vent Solvent storage tank vent Column vent Column vent Storage tank vent UCC 103429 Identification Number Is. 2s. 3s. 4s. 5s. 6s. 7s. 8s. 9s. 10s. 11s. 12s. 13s. 14s. 15s. 16s. 17s. 18s. Identification Number lc. 2c. 3c. 4c. 5c. 6c. 7c. 8c. 9c. 10c. 11c. 12c. 13c. 14c. 15c. 16c. 17c. 18c. Identification Number 19e. 20e. 21 e. 22e. 23e. 24e. 25e. 26e. 27e. j 28e. j 29e. ) 30e. ) 31e. ) 32e. ) 33e. j 34e. ) 35e. \ 36e. J SECTION II LIST FORM Affected Source Name Air Pollution Control Device (Type) Emission Point Still condenser accumulator vent t/ Monomer storage tank vent Still condenser accumulator vent Solvent storage tank vent Still condenser accumulator vent t-' Still condenser accumulator vent ^ Solvent storage tank vent Reactor agitator shaft seal leaks Emergency relief devices UCC 103430 No. 2 Solvent Resin System Solvent Recovery UCC 103431 Identification Number Is. 2s. 3s. 4s. 5s. 6s. 7s. 8s. 9s. 10s. 11s. 12s. 13s. 14s. 15s. 16s. 17s. 18s, Identification Number lc. 2c. 3c. 4c. 5c. 6c. 7c. 8c. 9c. 10c. 11c. 12c. 13c. 14c. 15c. 16c. 17c. 18c. Identification Number 37e.) 38e.) 39e. 40e. ) 41e.) SECTION II LIST FORM Affected Source Name Air Pollution Control Device (Type) Emission Point Emergency relief devices Reactor agitator shaft seal leaks Emergency relief devices UCC 103432 No. 1 Solvent Resin System 6s 36e 37e 18c 38e 1c 1c 2c 3c UCC 103433 Recove ry EMISSIONS POINTS DATA SHEET ,-Tt Identifi cation Number 1 of Emis sion Point to Atmos phere 1e List All Affected Source(s) " Vented Through this point 1 7s 2e 7s 3e 7s 4e 7s 5e / 6e 7s 7s 7e 7s 8e 7s 9e 7s lOe 7s o Maximum Potential Emissions" (lbs/hr) Maximum Actual Emissions With Control Device Applied (lbs/ hr) Height Gas Dimen of Exit Volume sions Point Through of Exit Above Exit Point Ground Point meters! (meters! (ACFAD ,051 dia 2.5 2 Exit Gas T emperature (F) 60 Exit Gas Velocitv (meters /sec) . 466 10 2 dia 25. 0 4 Ambient . 233 051 dia 9-0 .01 Ambient .002 051 dia 10. 0 2 Ambient . 466 254 dia 6. 1 5 Ambient . 047 037 dia 30. 5 1.2 Ambient . 497 037 dia 30. 5 2. 0 Ambient . 860 037 dia 30. 5 2. 0 Ambient . 860 203 dia 13. 5 .1 Ambient .001 203 dia 13. 5 .1 75 . 001 CO HC Oxi- 1 Other dants Specify) CO MeAc 16 MeOh.4 MeAc 20i } MeOh 30 MeAc . 1 MeOh .0 2 MeAc 1. 3 MeOh.8 MeAc 3, 3 Me Oh 1. 3 MeAc 20 . 0 MeOh 5. 3 MeAc 5. 3 MeOh 1. 3 MeAc 10 MeOh . 2 MeAc 12 ) MeOh 72 MeAc 12 ) MeOh 72 Oxi Other IIC Nx dants (Specify) MeAc 8. 0 MeOh 2. 0 MeAl.3 MeOh . 1 MeAc 2.0 MeOh . 5 MeAc 2.0 MeOh 1.0 MeAc 2.0 MeOh 1.0 1 Must correspond to number given on the Section II "List Form". 2 List by identification number assigned as required on the Section II "List Form". . 3 Emissions that could be emitted if air pollution control equipment was not working or is not installed. AFCC-R-3-72 MeOh - Methanol MeAc - Methyl Acetate UCC 103434 EMISSIONS POINTS DATA SHEET Identifi cation Number ^ of Emis sion Point to Atmos phere lie List All Affected 2 Source(s) Vented Througli this point 1 7s 12e 7s 13e 7s 14e 7s 15e 7s 16e 7s 17e 7s 18e 7s 19e 7s Maximum Potential Emissions (lbs/ hr) Maximum Actual Emissions With Control Device Applied (lbs/hr) Height Gas Dimen of Exit Volume Exit sions Point Through Gas Exit Gas of Exit Above Exit T e nip - Velocitv Point Ground Point meters! {meters! (AC FAI) erature (meters <F) / sec) Oxi Other Oxi Other CO HC NOx dants Specify ) CO HC NOx dants (Specify) . 356dia . 356dia - 356dia . 356dia . 356dia - 203dia . 305dia .51 dia .51 dia 34. 0 34. 0 35.0 35. 0 35. 0 36. 5 30. 5 6. 1 6.1 5, 000 5, 000 5, 000 5, 000 7, 000 750 650 4 4 90 90 no no 95 Ambient Ambient Ambient Ambient 23. 6 23. 6 24. 7 24. 7 33. 3 10. 9 4. 20 . 009 . 009 Me Oh i: 15 Me Ac C-A( >0 MeAc 5( '0 Me Oh i: 5 Me Oh li . 5 MeAc 7f MeAc 7! Me Oh 2' ' MeAc sd Me Oh 3 MeAc . 2 5 Me Oh . 1 MeAc E Me Oh . 2 MeAc 2E Me Oh 1C MeAc 2E Me Oh 1C MeAc 160 Me Oh 40 MeOh 40 MeAc 15 Me Oh 7 MeAc 5 Me Oh 3 MeAc 5.0 MeOh 2.0 MeAc 5. 0 MeOh 2. 0 1 Must correspond to number given on the Section II "List Form". 2 List by identification number assigned as required on the Section II "List Form". 3 Emissions that could be emitted if air pollution control equipment was not working or is not installed. APCC-R-3-72 UCC 103435 EMISSIONS POINTS DATA SHEET Identifi cation Number^ of Emis sion Point to Atmos phere 20e List All Affected Source(s) ^ Vented Through this point 1 7s 21e 7s 22e 7s 23e 7s 24e 7s 25e 7s 26e 7s 21 e 7s 28e 7s 29e 7s 30e 7s 31e 7s O Maximum Potential Emissions" (lbs / hr) Maximum Actual Emissions With Control Device Applied (lbs / hr) Height Gas Dimen of Exit Volume sions Point Through of Exit Above Exit Point Ground Point meters (meters! (Acni) . 037dia 7. 0 2. 5 . 05 ldia 20. 7 1 . 152dia 6.0 2 , 152dia 6. 0 2 . 037dia 29.0 2, 600 . 102dia 10. 0 280 .0762 . 0508 . 1524 . 1016 . 1016 . 1524 4 4 2 6 2. 7 19.4 Exit Gas Exit Gas T emp- Velocity erature (meters <F) 1 sec) Oxi CO IIC NOx dants Ambient 1.035 Ambient .240 Ambient . 052 Ambient . .052 100 1136 Ambient 16. 3 Ambient) Ambient) Ambient) Ambient) Ambient) Ambient) Emergi ncy re Lief device s that h< Lve not activatf d in o\ er 5 ye irs Other Spec lfy) CO Me Ac 2< Me Oh 3 MeAc . 1 Me Oh 6. 0 MeAc 4. 0 Me Oh lJ 0 MeAc 0 Me Oh 3. 0 MeAc 1( Me Oh 5 MeAc . c Me Oh * 1 01 TIC Oxi dants Other (Specify) MeAc 1.5 MeOh . 3 MeAc 1.0 MeOh.5 x 1 Must correspond to number given on the Section II "List Form". 2 List by identification number assigned as required on the Section II "List Form". 3 Emissions that could be emitted if air pollution control equipment was not working or is not installed. APCC-R-3-72 UCC 103436 Identification Number Is. 2s. 3s. 4s. 5s. 6s. 7s. 8s. 9s. 10s. 11s. 12s. 13s. 14s. 15s. 16s. 17s. 18s. Identification Number lc. 2c. 3c. 4c. 5c. 6c. 7c. 8c. 9c. 10c. 11c. 12c. 13c. 14c. 15c. 16c. 17c. 18c. Identification Number le. 2e. 3e. 4e. 5e. 6e. 7e. 8e. 9c. lOe. lie. 12c. 13c. 14c. 15e. 16e. I7e. 18e. SECTION II LIST FORM Affected Source Name No. 2 Solvent Resin Process Air Pollution Control Device (Type) Condenser Condenser Condenser Condenser BS & B BS & B BS & B BS & B BS k B BS & B Motor Valve BS & B BS & B BS & B BS & B Emission Point Slurry Tank Vent Dissolver Vent Reactor Vent Reactor Vent Storage Tank Vent Centrifuge Vent Tank Vent Mix Tank Vent Slurry Tank Vert Slurry Tank Vent Dryer Discharge Dryer Discharge Dryer Discharge Dryer Discharge Dryer Discharge Transfer System Vent Storage Bin (Product) Vent Solvent Storage Tank Vent UCC 103437 Identification Number Is. 2s. 3s. 4s. 5s. 6s. 7s. 8s. 9s. 10s. 11s. 12s. 13s. 14s. 15s. 16s. 17s. 18s. Identification Number lc. 2c. 3c. 4c. 5c. 6c. 7c. 8c. 9c. 10c. 11c. 12c. 13c. 14c. 15c. 16c. 17c. 18c. Identification Number 19e. 20e. 21e. 22e. 23e. 24e. 25e. 26e.) lie.) 28e.) 29e.) 30e.) 31e.) SECTION II LIST FORM Affected Source Name Air Pollution Control Device (Type) Emission Point Solvent Storage Tank Vent Still Condenser Accumulator Vent Still Condenser Accumulator Vent Solvent Storage Tank Vent Solvent Storage Tank Vent Vacuum Jet Discharge Vacuum Jet Vent Emergency relief device r UCC 103438