Document gE220JeV420Mkx4QGD8XpQRBe

rca ANALYTICAL REPORT PFOAIPFOS Analysis Lots: Dect0284 Laura Vancho NewJ2e1r2seCyaArmegroicLaanneWater Delran,NJ 06075 TostAmerica Denver cPhreoljleectA.MaJnoahngsetron March 31,2008 958 Yow Set Anda COBY 3037360100 4203401717 ewwtsamarichncom DEP2.SDWE.000433 Table Of Contents Standard Deliverables Report Contents. S(StTothneadRanerpddDoaerrftdvCeoDrveoelbriepavpgeaecrikasagbceol.neTsisdserredaeninp5tegocroamlprplretttoef tihies s afpagesincicatod ntiTolofConlrsrmckkcsad) + Tableof Contents + Case Narrative + Executive Summar-y Detection Highlights. * Methods Summary + Method/Analyst Summary + Lot Sample Summary * Analytical Results + QC Data Association Summary + QC Results Chain-of-Custody Total Number of Pages [] Testanerica 1 DEPZ.SDWB-000434 CasDeBCN1a8r0r23a4tive TQeuxhcaeelptrteyisuoMlnatsnsuaiarnlec.lnuoAdtleeddrienbsteuhlloiwss.hreapvoertbheaevnefobuenedn troevmieeewtedalforrecqoumiprlemieanntcse owfitNhEtLheACLaabnordaatnoryy `oTrhisspornespoorrt.shDailllutniootn bfaectroerpsraodnudcfeodoeinxocleopsthianvfuellb, owietnhopurtovtihdeewdrointeenaacphprdoavtaalshoefetth1e laasbsoirsattoirny he interpretation of the rasufs. `TheSninoAarwraitvmearl sapanmdpRlleecsepeirpetsented in tris report were received at tha TestAmerica Denver taboratory at temperatures of 2.3C and 0.9C on March 18, 2008. No anomalies were observed during sample receipt. S`tAnaanldytaircadlsstandards were prepared using to ack form of the compound perfluorooctanci.c acid (PFOA). PFOS is a commrcial prepared and cortied soluon Perfluoro-n-{1,2,3,4-"C,Joctanoic acid was introduced at the extraction step and was used as IaPnnFtOrinSotd.eurcneadl asttatnhdeaorxdtrfoarctquoanntsitteaptiaonndofwaPsFOuAs.edPasearnfntlaumaolrstoan-da"1rCd-Jf{oocr1tqau,naan2ttei,stua3ltfi,oonn4aot-fe was `ESamxpletractandiAnaolysnis TDhenevesra'msplSeOsPprDeEsNe-nLtCed-0in01th2is report were analyzed for the target analytes by TestAmerica aFnord wiattieerxstaramcptleedsuasi2n5g0somlLd aplhiaqusoet eoxfleraaccthosntaemcphlreisquaecdwiftihedmewtihtahn1almcLoonfd6oNnHeCdIGs1ol8ution c`asratmrpildegesis. paEsascehd stahmropulgehistshpeickaertdrwiidtghe,tthhee nantaelmyatlesstaarnedaerldu,tperdiowrithoe4xtmrLactoifomne.tAhfatnoelr.thTehe final volume is brought to 5 mL using methanol and the extract is analyzed by LC/MS/MS. MetQChSeompldes `The Method Blank is processed reagent water spiked with surrogate andpreparedwith each mbaittchfoorft2h0estaargmetpanolafyetthesse.same matrix. Themethodblank was non-detatetchte reporting. Eleavcelhsbwaetrcoh wiistphrienpeasrteadblwiisthheLdacboonrtartolorIyiCo.ntrol Samples (LCS). The LCS recoveries for both AnT"ahRieAyNtiiNnctEaeYmlaWlCEosLtmLamn2eda8nrtdassrseoccoivaetreydfwoirth13QCC4bPaFtcOhS8w08a4s3b3e6l.owTthhoe coonwterrolcmonitrsolomrihitsn isnatemrpnlael P`sFtaOnSdarrdoshualvefnorohtyaetsabmepeine dietleersmsitnheadn; htheerreefpoorret,inngohcmor.rective action was necessary. The No other anomalies were noted. Testanerica 2 DEP2.SDWB-000435 EXECUTIVE SUMMARY - Detection Highlights Dacisozs PamnETER `RAMNEY POE 03/17/08 11:10 001 ePrroosn RANEY WELL #7 03/17/08 10:38 002 vPrroosn. RANEY WELL 1A 03/17/08 10:32 003 eEroYs RANEY WELL 28 03/17/08 10:38 008 ePrroos LAYTON POR 03/17/08 11:29 005 sroR, LAYTON WELL 4 03/17/08 11:35 007 eeroons. LATION WKLL 2 03/17/08 11:50 008 eProosn mEsor REPiOmaRrTING maes 0o.a0t0213 0o.l01s0 uue/gi 0o.l0s0233 0c.l0a1s0 uuge 00.0103013 0o.i0s0 uuga/L l0o.s0s503 0o.i01s0 uuss/un 0.08 001s ue 00..0013293 o0.l0i1s0 uuge//Ln 0o.o0:m 0o.l0o1i0s wuge/i wnEowmrorIpCAL DDEENN --11cc--00001122 eEwN --1Lcc--00001122 BDNB --L1cc--00001122 DDEBYY -"11c6--00001122 mi -1c-0012 ooBmN --11cc--00001122 oDEeY --11cc--00001122 Testanerica 3 DEP2-SDWB-000436 METHODS SUMMARY Decisozse eAmwETER aweuTnHsOrDroan Le/ws/ns, Bron References: oBY 10-0012 om SOpeevreartninTgrenPtrocLeadbuorrea.tores, Denver, Facility Standard MPERTEHPOADRATION TestAmerica N DEP2:SDWB-000437 METHOD / ANALYST SUMMARY Decisene vAEvmaHOrDic Aware DEN -1c-0012 Jaqueline Bonnett. References: oe Severn Trent Laboratores, Operating Procedure. Denver, Facility Standard f re 003601 Testanerica bl DEP2-SDWB-000438 SAMPLESUMMARY Dacisozse Wo + smiEs cLiENeswLE 1 XKIIRVA 000021 RRAANNNNEEYY WBoEBL.L #7 KKIICD 000043 RRAANNNNEEYY WWeELLLL 218A KKITRWMEG 000056 LLaAYYrToOnN WpoEmL.L 11 KKIRRWWT 000087 LLAAYYTTOONN WWEELLLL 24 Kwan 003 TRIP BLANK Tmoers)yoofbees er od 5 AX 1s err lr nin rd i es cht SE To 5 eifor liegppri,n ceev 4ewilyrwi aproofbb,oer si,... i, ye, Pl a, oyre, iseer,t c,h, ptt, cy,a DsMwE e tsuoe 0033//1177//0088 1110::1300 0033//1177//0088 1100::3302 0033//1177//0088 1111::2292 0033//1177//0088 1111::3550. 03/17/08 08:00 Testamerica DEP2-SDWB-000439 American ater Company Clieat sample 1: RAGE POR me DLoatt-eSaSmapmlepl4e.d.[..: D0S3C/I187/002834-1010:110WoDartkeORrdeecreiv.e.d...:: 0K3I/R1V8G/I0A8R PPrreepp Bpaattceh......:: 20038/42343/608 Dilution Factor: 1 MAanaallyyssiissDaTtiem.e.:.: 1063:/1280/08 Method.........: DEK -LC-0012 Matrix.........: WATER PerrosenErE ero R0e.s0o0u2r13 ol0ze LREaPOrRTING pass wen o0.l01s0 wg/au o0l.o0003210 su1R3RaocpArTEo. 1304 PROS REeECROCVaENRTY I"n% LRoErCzOsV.ERY ((5500 -- 2200007 1woPrR(es)ret eh aL _ Testanerica DEP2-SDWB-000440 American Water Company Clicat Sample TD: BARNEY WELL #7 wwe DLoatt-eSaSmapmlepl#e..d...:: D0I3C/I1870/20384-1000:238 DWaotrek ROercdeeirved.....:: 0K3I/R1K8A/L0A8A PPrreepp DBaatctheB.,..1..:: 80038/42343/608 RAonaallyyssiissDTaitmee....:: 1063:/3216/08 Dilution Factor: 1 Metbod.........: DEN -LC-0012 Matrix.........: WATER eProEsTER Pron R0e.s00o2u3r 3 0.040 RwEaRorRTING mars wo o0.i01s0 uugg//nn 00..0000301 s3ucRaRospArToSn 1304 Pros. REECROcVENETRY 5n RLeacrovsery ((5500 -- 720000)7 mores): EE -- Testanerica 8 DEP2-SDWB-000441 `American water Company Client Sample I: RAMEY WELL 1A wie DLaotte-saSmapmlepl4e..d...:: D0I3C/I1870/20384-1000:332 DWaotrek ROercdeeirved.....:: 0K3I/R1N8C/I0A8A PPrreeppDBaatte.c.h...|.:: 8030/82443/3068 Dilution Factor: 1 `AAooaallyyssiiss DTaitem.e.:: 0236/:4246/08 Method.........: DEN -LC-0012 Matrix.........: WATER er3rnETER ron R0e.s0o0u6r1 3 0.083 RmEaROrRTING mars Go0i0s wwooms w0.0e03n0 0.0021 `1so3m4RoaPaRTOsR: 1304 PROS eERERCCOaVENRTY. aa RLeocaorrvsery ((5500 -- 220000)7 soT(s) ee Testanerica s DEP2.SDWB-000442 Averican Water Company Clicat sample TD: RwGEY WiLL 28 wee DLaotte-gSamapmleple..d...:: 0D3E/C1I78/002834-1000:438 WDoartekORredceerive4d.....:: 0K3I/R1W8D/I0A8A PPrreepp Bpaatcthe#....1..:: 60038/42343/608 Dilution Factor: 1 MAonaallyyssiissTDiamtee...:: 0137/:1216/08 Metbod.........: DEN -1C-0012 Matrbx.........: WATER oPrAosmETER ron n0e.s0u0u6r0 7 0.050 RmEaPOrRTING moms won o0l.o0i1s0 wwga/nn 00..00003310 1s3u0R4RoPGRAOTRE 134 pros PREERCCOEVNETRY a 2 RLEaCrOVsERY ((5500 -- 220000 woSTeEm(asn):ry md ee _ Beatre. oh tom. TestAmerica 10 DEP2.SDWB-000443 American Mater Company Client Sample TD: LAYTON OE we DZoatt-eSaSmapmlepl#e..dl..:: 0D3I/C1I70/002834-1010:529WDoartkeORredceerlved.....:: 0K3I/R1W8E/L0M8A PPrreepp BDaatcthe#.......:: 0630/842343/608 Dilution Factor: 1 nMoaallyyssiios DTaimtee....:: 1073:/2246/08 Method.........: DEN -16-0012 Matrix.........: WATER `rPoRsMETER ero. R3esour 0.083 RaERrORTING wars wn 0o.0s10 augi/nh 0..00002301 1s3u0R4RoopArToEn 1304 pros. ReEesCcOaVnEtRY aas LREaCrOsV.ERY ((5500 -- 220000)) Testanerica 1 DEP2-SDWB-000444 American ater Company Client Sample ID: LAYTON WELL 11 me DToatt-eSSasammpplleed#......:: D0S3C/I187/002834-1010:622 DWaotrek ROercdeeirve4d...... K03I/R1W8G/I0A8X PPrreepp DBaatcthe#....1..:: 0830/82443/3068 Dilution Factor: 1 A`Nnoaallyyssiiss TDiamet.e:.: 0273:/3276/08 Method.........: DEN -1c-0012 Matrix... WATER ePraonsETER ron reouiz RaEproRTING mass woo w 0o.i01s0 uugg//Lt 00..00007301 `1s3u0R4RopGraToEn 1304 pros eBEERccoEvNETRY 27n RLEcaovsERY ((5500 -- 7200007 TestAnerica 12 DEP2.SDWB-000445 American ater Company Client Sample ID: LAYTON WELL 4 wc DLoatt-eSaSammpplleed#......:: 0D3I/C1I78/002834-1010:735WoDartkeORredceerived.....:: K0I3R/W18I/L0A8A PPrreepp BDaattec.h........:: 80038/42343/608 AAnnaallyyssiiss TDaitse.e.:.: 1073:/5206/08 Dilution pactor: 1 Method.........: DEN -LC-0032 Matrix.........: WATER rPorsm.nGTER roa R0e.s0o0u2r95 oom nREaPOrRTING mars won c0.o01s0 wwga/nn 00.o0o03n0 `Ts3ucmeRoapartosn 1304 ROS ReErCrOVcEaRrY 55 oReacrovsery ((5500 - 7007 200 noE(s) Testanerica 13 DEP2.SDWB-000446 American water Company Client sample I: LAYTON WELL 2 wc DLaotte-saSsapmlpel4e..d...:: D03S/C1I78/002834-1010:850 bWaotrek ORredceeirved.....:: 0K3I/R1W8K/I0A8A PPrreepp Bpaatcthe#....[..:: 80038/4234/3068 `ARaolaylyssitss TDiamet.e.:.: 2003:/0238/08 Dilution Factor: 1 Method.........: DEN -1C-0012 Matrix........: WATER PhmvETER rroosn. R0e.so0u0r15 oom LREoPaOrRTING ours wn o0.l0o1i0s wuga/n 00.0000210 `1s3um4RoPoRTOE 134 PROS oTs(s) P`ERRBCcEoNvRTy a& `LBocrorveERY ((5500 -- 220000)) Testanerica 1 DEP2-SDWB-000447 American Mater Company Client sample I: TRIP BLANC DLoatt-eSSamapmlpele#d.....:.: 0D3E/C1I7S/002834-0080:900 Work Date Order B...: Received..: KIRWNLAA 03/18/08 PPrreepp BDaatcthe......:: 80038/6243/3068 AAnnaallyyssiissDTatiem.e.:.: 1063:/1266/08 Dilution Factor: 1 Metbod.........: DEN -LC-0012 Matrix... WATER PPrroes nTER Pro Rwesour w RwEaPOrRTING gars we 0o.0s10 gug//tL 00..00003220 3su0RaRoGparToEn. 1304 Pro ~rREeRccoEvNETRy oa2 RLaacrovsimy ((5500 -- 7200007 Testanerica 1s DEP2.SDWB-000448 QC DATA ASSOCIATION SUMMARY Dacisoase Sample Preparation and Analysis Control Wbers sues wre mmaowrsrica on wm om -te-ooiz 002 wm om e002 03 wm baw seco cr wm om icon: 0s wm om sconz 0s warm om com: 07 wa ox -1c-om2 0s mmm om scomz 00 warm om seoms mmoeorns mmeeens wo now aoaaze sosarse sosarse sonazse sonnze soars soni sosarsa sone sosanss sosanse sonaase sone sosarse sosanse soease sore sonia Testanerica hd DEP2.SDWB-000449 C5 lLoti-Lsoeatmpfnl.e.t.:: DAinlaultyisoins FDaatcet.o.r:: = aaneETER eros s1u3RcssoaParTosn: 1304 pros son, BLK REPORT mc DRI8CCI2S4O0203060-336 WorkOrder #...:KNMSIMA 03/20/08 PPrreepp DBaattec.h........:: 08038/42343/603 1 Resour RuavroRTING pars w5 o0.0o15 uugg/u Rseecsocveenry a LReocaonvsery (t5o0 -- 2200007) Mabrix.........: WATER Analysis Time..: 15:00 wDEeNmo1n-012 DEN -Lcoouz nosrt hos ed 708 oe TestAmerica 1 DEP2-SDWB-000450 LABORATORY CONTROL SANPLE EVALUATION REPORT me C1l0iSenLtot-LSoatmp8l.e.d.:: DRI8CCI20600203040-336 Work Order #...: KINSIAC PPrreepp DBaattec.h..#......:: 0830/82443/3068 AAonaallyyssiiss TDiamtee....:: 0135/:2130/08 Dilution Factor: 1 Matrix.........: WATER perhomnETER Pros PREERCCOEVNETRY o50 RLEmCuOIVzEsRY ((3790 -- 112300)) EDmTx O16-0013 pa -1c-0012 2su2m4souParToe". 1304 PROS emeenccoevveTry a2 RLemcaotvsery ((5500 -- 220000)) Cnuotr(iss)weert tr sin vo norsodA ipe descotames Testanerica 18 DEP2-SDWB-000451 LABORNTORY CONTROL SAWPL DATA. REZORT me C1l5ienLtotT-oStampi.e.t.:: DRSICC2I40O0O020-236 Work Order #...: KIANSIAC PPrreepp Dmaattec.h........:: 09030/42303/600 Ahaaaallyyssiiss DTaitmee....:. 0135/1230/08 Dilution Packer: 1 Matrix.........: WATER vm roosn ower sme m0e0w sme moemw wwoats mssaccoawrmy m Dew 16m -0073o Wie os wow De "16-0012 sToauctmomparrosn Tick pros mmcocvmmzy a5 rf ome). T ---- Rocesmn ---- rLaocaonvsasy GGoo -- 220000)) Testanerica 1 DEP2.SDWB-000452 LABORATORY CONTROL SANPL RVALUATION RESORT ee CC8lLoitL-oeStam#np.l.et.d:: DRS8CC128400203000-336WorkOr#.d ..:e KINSr IAD PPrreepp BDaattec.h..#......:: 0830/82443/3068 AAnnaallyysoilss DTaitne.e.:.: 0153:/2266/08 Dilution Factor: 1 Matxix.........: WATER PETER erroosa. _ EPEcRoCvEENRTY RELCuOtVsERY smo os01 G(303--152000) DDEw 1106--00001172 s2u3mcse oPaRTOs 1304 PROS Cwoor(ns)vspr es to rok nb re i ReERccovNeTny "55 ReLcpoavsaRY ((5500 -- 220000) Testanerica * DEP2-SDWB-000453 LABORMTORY CONTROL SAMPLE DATA REPORT mc CLClSienLtotL-oSatmp#l.e.d.:: DR38CC128400203040-336 Work Order ...: KIHSIAD PPrreepp BDaattec.h..4......:: 08038/42343/608 AAnnaallyyssiiss DTaitee...:: 03/26/08 15:26 Dilution Pactor: 1 Matrix.........: WATER PeArRoAMETER. vrs smeomwes swmaostmRED murs emBeRcCoEvNeTR.y wemion 60.2020000 0o.l0o2a0s2n waaftr o1s00 DEN -1.6-0012 DBs -1c-0012 s33u0R4RoaparTso. 1304 pros PEmERcCoEvNsTRY 5a5 RLeuctovsaRY ((5500 -- 220000)) CmloTiEn(se) psirte 5 rod rt re i redet re Testanerica 21 DEP2-SDWB-000454 MATRIX SPIKE SAMPLZ EVALMTION REPORT prc LM5ot-LSoatm-pSalmeplA.e..:: DDBECC1I8800221354-001 Mork Onder #...: KIRNTIAC DParteep SDaatmep.l.e.d......:: 0033//1274//0088 09:30 DMnaatleysRiecseiDvaetd.e..: 0033//1268//0098 DPirleuptBiaotnchFa#c.t.o.r:: 81084336 Matrix.........: WATER ronovnETER Pros s13u0R4RoGpArToEn. 1304 PROS wloirsn(sw:)e or irerin pmcrs etvs RPeEcRoCvEmNRTy i"n 708 ol RLEmCrOtVsERY 0Gs -- 113200)) ReEmCROcVEENTRY 0% a MDEmTxHO1D.5-0012 Dmx 1-002 `LRaECrOVsERY ((5500 -- 220000)0 Testanerica 22 DEP2-SDWB-000455 WATRIX SPIKE SANPLR DATA REPORT pc L5ot-LSota-mSpalmepl#.e..:: DDIICC1I8S00221354-001 Work Order ...: KIANTIAC DParteep DSaamptleed....l..:s 0033//1274//0088 09:30 DAnaatleysRiecseiDvaetde.....: 0033//1288//0098 DPirleuptBiaotnchFac#t.o.r.:: 81084336 Matrix.........: WATER ro= noesm.ETER su13mcRaoopArToEn. 1304 pros mCornes)s:r pretwheeoe ipi decr epa, MSAOMUPNLTE ASMPEIKE MMEOAUSNRTD UNITS 00..00005640 00..220000 00..118938 uwagf/tL. `pREaCcOVaERrY 0a et ds RpEeCROcVaENRTY METHOD o5 DomEy 1166--00001122 pRrEicmoevyRY ((5500 -- 220000)0 Testamerica 23 DEP2-SDWB-000456 `SAMPLE DUPLICATE EVALATION REPORT ve C5lDiLeontt-SLoatmpl#.e..#:: DDSECC1I8S00221354-001 WorkOrder #...: KRIRNNAD SDMUPP Matrix.......: WATER DParteep SDaamtpel.e.d.....:: 0033//1274//0088 09:30 DAnaatleysRiecseiDvaetd.e..: 0033//2188//0088 ' Rm bs PrDielputBiaotnchFa#c.t.o.r:: 81084336 oalysis ime.: 16:05 PernomnmTER vros sRpEiseisr _ mpueesuuzrca_rs gwts 00.0000650433 0o.o0o073I uugg//Lu Rep m1e7n L(0m-o2r0) vbmwe-LCm-001o2 n 10 (0-20) De -ic-o012 `1S3U4RROPGARTOE RECOVERY. o1T3R04(S)PROS SCwOeVLEERY+ o& RDuERCLOIVCEARTYE t ray RE(C50OVER-Y2L00I)MITS (so - 200_) Cuswepert nin m4efre cde Testanerica 2 DEP2-SDWB-000457 1sT FET IR i i R\ IiE HOE a2 LLL iE il | E1ep1EiEE | i.iRE iE f:e 13 ! BIETR oefi3l | '0F pi fMli]E 3 bha a0.%x RJ|| i Fr E pe e om--e i Li:3 iJECe EoE e oi'd HdeEr -- kHH TT eH H-- E-- ---- -- HH | 2 | i|n p | =} | 7 25 XBaenrnoerx S4h1ee1t0 feeney_patri. cia_a -------------------- UserName feeney patricia a DEP SOWB-00045H