Document gDanyeV4M3XypoVaQR9mGJex9

PH EM GU ARO Safety Data Sheet This safe ty data sheet com plies w ith the requirem ents of: 2012 OSHA Hazard Communication Standard ( 29CFR 1910.1200) Product name CHEMGUARD 6% AFFF C606-MS-C 1. Identification 1.1. Product Identifier Product name CHEMGUARD 6% AFFF C606-MS-C 1.2. Other means of identification Product code Synonyms Chemical Family 770815 None No information available 1.3. Recommended use of the chemical and restrictions on use Recommended use Fire extinguishing agent Uses advised against Consumer use 1.4. Details of the Supplier of the Safetv Data Sheet Company Name Tyco Fire Protection Products One Stanton Street Marinette, Wl 54143-2542 Telephone: 715-735-7411 Contact point Product Stewardship at 1-715-735-7411 E-mail address psra@tycofp.com 1.5. Emeraencv Telephone Number Emergency telephone CHEMTREC 800-424-9300 or 703-527-3887 2. Hazards Identification Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Serious eye damage/eye irritation - Category 2 2.2. Label Elements Signal Word WARNING hazard statements Causes serious eye irritation <t> NX Precautionary Statements Prevention Wash face, hands and any exposed skin thoroughly after handling. Wear eye/face protection. Revision date 10-0ct-2015 Version 1 US00002436 Phembuaro Product code 770815 Product name CHEMGUARD6%/ AFFF C606-MS-C PAGE 2 / 8 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. 2.3. Hazards Not Otherwise Classified (HNOC) Not Applicable. 2.4. OTHER INFORMATION Unknown Acute Toxicity 3.5282% of the mixture consists of ingredient(s) of unknown toxicity 3. Composition/information on Ingredients 3.1. Mixture The following component(s) in this product are considered hazardous under applicable OSHA(USA) Chemical name Trade secret 2-(2-Butoxyethoxy)ethanol Laurylamidopropyl betaine Caprylcaprilyl glucoside CAS No Proprietary 112-34-5 4292-10-8 68515-73-1 weight-% 7 -13 5 -10 1- 5 1- 5 4. First aid measures 4.1. Description of first aid measures Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin contact Wash skin with soap and water. Get medical attention if irritation develops and persists. Inhalation Remove to fresh air. If breathing is difficult, give oxygen. (Get medical attention immediately if symptoms occur.). Ingestion Rinse mouth. Do not induce vomiting without medical advice. If swallowed, call a poison control center or physician immediately. 4.2. Most Important Symptoms and Effects. Both Acute and Delayed Symptoms No information available. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Note to physicians Treat symptomatically. 5. Fire-fighting measures 5.1. Suitable Extinguishing Media Product is extinguishing agent. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. 5.2. Unsuitable Extinguishing Media None. 5.3. Specific Hazards Arising from the Chemical None known. Hazardous Combustion Carbon oxides, Fluorinated oxides, Nitrogen oxides (NOx), Oxides of sulfur Products US00002437 Phembuaro Product code 770815 Product name CHEMGUARD6%/ AFFF C606-MS-C PAGE 3 / 8 5.4. Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. 5.5. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal Precautions Ensure adequate ventilation, especially in confined areas. For emergency responders Use personal protection recommended in Section 8. 6.2. Environmental Precautions Environmental Precautions Prevent further leakage or spillage if safe to do so. Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional Ecological Information. 6.3. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Pick up and transfer to properly labeled containers. 7. Handling and Storage 7.1. Precautions for Safe Handling Advice on safe handling Avoid contact with skin and eyes. Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible Materials Strong oxidizing agents. Strong acids. Strong bases. 8. Exposure Controls/Personal Protection_________________________________________________ 8.1. Control Parameters Exposure guidelines Chemical name Trade secret ACGIH TLV Ceiling: 100mg/m3 aerosol only OSHA PEL " NIOSH IDLH " 2-(2-Butoxyethoxy)ethanol TWA: 10 ppm inhalable fraction " " 112-34-5 and vapor ACGIH (American Conference of Governmental Industrial Hygienists) OSHA (Occupational Safety and Health Administration of the US Department of Labor) NIOSHIDLH Immediately Dangerous to Life or Health 8.2. Appropriate Engineering Controls Engineering controls Showers Eyewash stations Ventilation systems. US00002438 Phemcuard Product code 770815 / Product name CHEMGUARD 6% / AFFF C606-MS-C PAGE 4 / 8 8.3. Individual protection measures, such as personal protective eauioment Eye/Face Protection Avoid contact with eyes. Tight sealing safety goggles. Skin and Body Protection Wear protective gloves and protective clothing. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Ventilation Use local exhaust or general dilution ventilation to control exposure with applicable limits 8.4. General hvaiene considerations Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and Chemical Properties 9.1. Information on basic phvsical and chemical properties Physical State Odor odor threshold Liquid No data available No data available Color No data available Property PH Melting point/freezing point Boiling point / boiling range Flash Point Evaporation Rate flammability (solid, gas) Flammability limit in air Upper flammability limit: Lower flammability limit: Vapor Pressure Vapor Density Specific gravity Water Solubility Solubility in Other Solvents Partition coefficient Autoignition Temperature Decomposition Temperature Kinematic viscosity VALUES No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available Remarks Method 10. Stability and Reactivity 10.1. Chemical Stability Stable under recommended storage conditions. 10.2. Reactivity No data available 10.3. Possibility of hazardous reactions None under normal processing. US00002439 PH EM GU ARO Product code 770815 / Product name CHEMGUARD 6% / AFFF C606-MS-C PAGE 5 / 8 hazardous polymerization Hazardous polymerization does not occur. 10.4. Conditions to Avoid Extremes of temperature and direct sunlight. 10.5. Incompatible Materials Strong oxidizing agents. Strong acids. Strong bases. 10.6. Hazardous decomposition products Carbon oxides. Nitrogen oxides (NOx). Oxides of sulfur. Fluorinated oxides. 11. Toxicological Information_________________________ 11.1. Information on Likely Routes of Exposure Product information no data available INHALATION no data available. Eye Contact no data available. Skin contact no data available. INGESTION no data available. Acute Toxicity Chemical name Trade secret Oral LD50 = 4000 mg/kg (R a t) dermal LD50 = 9530 pL/kg ( Rabbit ) Inhalation LC50 " 2-(2-Butoxyethoxy)ethanol 112-34-5 Laurylamidopropyl betaine 4292-10-8 = 3384 mg/kg (R a t) > 2000 mg/kg ( Rat ) = 2700 mg/kg (R a bb it) " " " 11.2. Information on Toxicological Effects Symptoms No information available. 11.3. Delayed and immediate effects as well as chronic effects from short and long-term exposure sensitization No information available. Germ Cell Mutagenicity No information available carcinogenicity No information available. Reproductive Toxicity No information available. STOT - Single Exposure No information available. STOT - Repeated Exposure No information available. Target organ effects Central Nervous System, EYES, Respiratory System, skin. Aspiration Hazard No information available. 11.4. Numerical Measures of Toxicity - Product information The following values are calculated based on chapter 3.1 of the GHS document mg/kg 12. Ecological Information 12.1. ecotoxicitv 0.9206% of the mixture consists of components(s) of unknown hazards to the aquatic environment_________________ | Chemical name | Algae/aquatic plants | Fish | Crustacea US00002440 PHEM G UARO Product code 770815 Product name CHEMGUARD6%/ AFFF C606-MS-C PAGE 6 / 8 Ethylene Glycol 107-21 -1 2-(2-Butoxyethoxy)ethanol 112-34-5 2-Methyl-2,4-pentanediol 107-41-5 t-Butanol 75-65-0 Polyethylene Glycol 25322-68-3 Sodium chloride 7647-14-5 4,4'-bis-(sulfostyryl)-biphenyl disodium salt 27344-41-8 EC50 96 h 6500 - 13000 mg/L Pseudokirchneriella subcapitata EC50 96 h > 100 mg/L Desmodesmus subspicatus EC50 72 h > 1000 mg/L Desmodesmus subspicatus " EC50 72 h = 10 mg/L Desmodesmus subspicatus EC50 96 h 10.0-11.0 mg/L Desmodesmus subspicatus LC50 96 h = 41000 mg/L Oncorhynchus mykiss LC50 96 h 1 4 -1 8 mL/L Oncorhynchus mykiss static LC50 96 h = 27540 mg/L Lepomis macrochirus static LC50 96 h = 40761 mg/L Oncorhynchus mykiss static LC50 96 h 40000 60000 mg/L Pimephales promelas static LC50 96 h = 16000 mg/L Poecilia reticulata static LC50 96 h = 1300 mg/L Lepomis macrochirus static LC50 96 h 10500- 11000 mg/L Pimephales promelas flow-through LC50 96 h = 10000 mg/L Lepomis macrochirus static LC50 96 h = 8690 mg/L Pimephales promelas flow-through LC50 96 h = 10700 mg/L Pimephales promelas static LC50 96 h 6130-6700 mg/L Pimephales promelas flow-through LC50 24 h > 5000 mg/L Carassius auratus LC50 96 h 5560 - 6080 mg/L Lepomis macrochirus flow-through LC50 96 h = 12946 mg/L Lepomis macrochirus static LC50 96 h 6020 - 7070 mg/L Pimephales promelas static LC50 96 h = 7050 mg/L Pimephales promelas semi-static LC50 96 h 6420 - 6700 mg/L Pimephales promelas static LC50 96 h 4747 - 7824 mg/L Oncorhynchus mykiss flow-through LC50 96 h = 76 mg/L Brachydanio rerio static EC50 48 h = 46300 mg/L Daphnia magna EC50 24 h = 2850 mg/L Daphnia magna EC50 48 h > 100 mg/L Daphnia magna EC50 48 h 2700 - 3700 mg/L Daphnia magna EC50 48 h = 933 mg/L Daphnia magna EC50 48 h 4607 - 6577 mg/L Daphnia magna Static " EC50 48 h = 1000 mg/L Daphnia magna EC50 48 h 340.7 - 469.2 mg/L Daphnia magna Static EC50 48 h = 1000 mg/L Daphnia magna 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulation No information available. Chemical name Trade secret Partition coefficient -1.93 12.4. Other Adverse Effects No information available 13. Disposal Considerations 13.1. Waste Treatment Methods Disposal of wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Do not reuse container. US00002441 PH EM GU ARO Product code 770815 / Product name CHEMGUARD 6% / AFFF C606-MS-C PAGE 7 / 8 14. Transport Information DOT TDG MEX ICAO (air) IATA IMDG NOT REGULATED NOT REGULATED NOT REGULATED NOT REGULATED NOT REGULATED NOT REGULATED 15. Regulatory Information 15.1. International Inventories TSCA DSL/NDSL ENCS IECSC KECL PICCS AICS Complies Does not comply Does not comply Does not comply Does not comply Does not comply Does not comply Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances 15.2. US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical name Ethylene Glycol -107-21-1 2-(2-Butoxyethoxy)ethanol -112-34-5 SARA 311/312 Hazard Categories Acute Health Hazard Chronic health hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard SARA 313 - Threshold Values % 1.0 1.0 No No No No No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) US00002442 PH EM GU ARO Product code 770815 / Product name CHEMGUARD 6% / AFFF C606-MS-C PAGE 8 / 8 Chemical name Trade secret Hazardous Substances RQs 5000 lb 15.3. US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Riqht-to-Know Regulations CERCLA/SARA RQ " Reportable Quantity (RQ) RQ 5000 lb final RQ RQ 2270 kg final RQ Chemical name Ethylene Glycol 107-21 -1 2-(2-Butoxyethoxy)ethanol 112-34-5 New Jersey X X Massachusetts X " Pennsylvania X X 16. Other information, including date of preparation of the last revision NFPA HMIS Health Hazards 2 Health Hazards 2 flammability 0 flammability 0 Instability 0 Physical Hazards 0 Physical and chemical properties Personal Protection X Revision date 10-0ct-2015 Revision note No information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet US00002443