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ff ~ ~ ARA_FR42G4 28 000235 | FCDhoFanAnttbeCrlooWmpooadnry ARRRG _ 342k Chambers Works PFOA Recycle Prior to start-upofthe PFOA Recycle process, baseline blood samples were collected on `fwuotrukreerssawmhploiwnoguclodubledabesscoimgpnaerteoddthteo rtehecybcalseeplrinoecelesvsealsn.diBtlsosoudppmoorntiotpoerriantgioinsscsonodtuhcatted as an industrial hygiene tool to evaluate the effectivenessofthe controls. Baseline samples of 42 workers were collected in 1999. Samples were analyzed as whole blood for PFOA by a contract laboratory `using gas chromatography with electron capture detector. This laboratory had been analyzing blood. samples for Washington Works for lsaebvoerraatloyreyapresr.soWnonrekleirnsvowlhvoedvwoilutnhtteheerePdFfOorA`rteesctyicngliinngcplrudoecdesosp.eraAtsoersc,omnedcrhoaunnidcosfand sampling was conducted in 2000 which included 30 people from the original 1999 group `and 34 newly assigned workers. DuPont analytical chemists found that in both the1999 `and2000 bloodmonitoringcampaigns, thelowestcalisb tanrdaa rdutseidbo ythne lab `was 100 ppb. PFOA was detected in many ofthe Chambers Works samples, but it could tnhoet1b9e9r9ealniadbl2y0q0u0anbtliofoieddmaotnciotnocreinntgractaimonpsailgesnsssthhaonw1e0d0rpespubl.tsA<l1lo0f0tphpeb.samples in both `This experience led DuPont to work with a different contract analytical laboratory on another method thatwouldbemore sensitive andprovide mores.cientificallyaccurateand reliabledataatthe low levelsinwhichwewereinterested. | December, 004 | Barbar. Davin,CI,CSP 000236 rH i g I2i% ia FsI i |= pm i :g : B| ers g Rk {1B iy EB 2 2 gas iPeiisicdiis Ee ~ ii iff) i is 5gg} 28iE 000237 J Totogieal Matrix DuPPonFtiCnOoBmlpoAaondy SeptCehmabmebre.rOsctWoobrekrs2002 Concaniation| Concentration (ug/ml) Units. [PFOA JSenm--s7te1| 1esluom [Operator | [PFOA [Serum [57204| 02o7lug [operator] 9 sowen o es ars] | [EmTe | [ProA sum [s7i62 | oooolugmi Dr Technion [[PPFFOOAA [[SSeerruumm 557718854[ |0o0.5cb2i5lluuggiimm |[TecThecnhniiccian] || [[PPFEOOAA [PFOA [SSS-- eeerrruuummm ss7 5r7e9e1i | | |--o 0.20 0s.0l28ulgug0.alugim iL Tochviier | [[PPFFOOAA [PFOA [[[SSSeeerrruuummm--Jo7[5517719195856| ||--.0.000088ollupggib/mm lp[[IgJ2LTTTeeoiccchhhnnniimciaionann]] [PFOA Serum 57196| 00643ugim 1 Toohnican] || [[PPFFOOAA [PFOA [SSSee5 errruuummm 7 51577221000|200000 0s5z068sellluugygigimmmi 81[JJLL0 TTTeooocohhhnniiicccaanan]] | [PFOA [Serum 06049 0oa8lugmi iLTechnician - no tot LO forresuslessthan i 5 limitof quantitationa 05 (0.050ugimi),75vi) PrepbyaBarrbaeradJ.NDaowsvone, m1CI7Hb,,2eC0S0rP4 000238 DuPPonFtiCnOomopAoandy SepCtheambmebrerOsctWoobrekrs2002 Anaiyte| Biological | Subject [Concentration] Concentration Matrix (ug/ml) Units _[ns[sdoibgrment [sme oom em ------+--22----------- [[PPFFOOAA lSseenunm o[5a72t15| |0.0O610cluogimo--[f Eieu [cMeicg hiacniacmn|| [PFOA [Sem Joot3s | 0e2lugm [instMecham | C [PFOS A Serum {9815703601 0 --[Mechanic] 0 [[PPFFOOAA s[Seermum--JoeTotBa401| |b0otazrslluuggimmi [[iMnetchaMneichcani|c 2SY 7 -- || CT HMERNT T m on e --] ------------] | [[PPEFOOAA [[SSeernumn--obJ1oaata5t| | 0o0szusgliugmmi [[CAhroemaat--a]] [PSFOAoWA_eeN--sT T eum--os1tT ao r| o om sidlugim m ] " [UmiT= eohar] i CeCood TT o Tops om ms ] ~O : nt forresultsles 3sthan mmitorfquanStiteatioin(0.050eungh),25 m0 PrepbyaBarrbaeradJ.NDoavwesmobne,rCI1H7,,C20S0P4 000239 o : I i8 BEEF Enlil Bree ~ i An 2 Bo rH Ee COR HIHili nnli 000240 OPupFoOnAtnCoBpoaony 2004SecurCehaEmnvbieornsmWenotraklsTreaimont mxsex | cslv z4 or -- --= 1 -- --= -- ---- | 33] 3 =a ~> 2s%s|] 2 5 == | 11 | | [f[oAdiginer7710o8510.15305]4 = -- [[saixbev[57a1oo 5evs5asso = [e3s|]l | sre | or ||l TI [--iarac0] | [StaBov [3506] ~9 Barbara J. DDoewcsaomnb,oOrFs),,2o00n4 000241 * 1i5% SE 5E Een! L ze i ' mE | Bem] a | |Eee f| | = i . [B0 sf all : ! ;1iteRH i oo lSiEliii}ia h fiil 000242 CroPaurtnoenGsaBropooensnsy 2004 Nn Frnt I~ D | | I ~D [123 133) [a I 2--74] [Count [oa [do 63] C [Mar xT432o0s] 17.10] [StdBev[Ta05] 278] [23 [2 --| [03] [io I rrCrr -- [--1.30[Media|r [Tozfswape|v P--es--t-- bigo 000243 I88 8% ii 25 an 2 i ||a | i 5re | Bano iE i oh il n IEEENE HE 000244 DuPpFoOnAt CInoBmopnadny 2004 FonCehaPmEbOeArsReWcoyklse Operation C [aoea sfieo) ]| a ew o --r g esl a ---- = -- n I i smroez --] a i ml > ---- a | [a Av --3-- 5005--a0] = C[straBev|Tad0ss63000--se-- rseo] 2 | i E rer os n--| [[8Ts5o oolimeedian--| | ~B BaPrrboagraarJa.dDDoevcaoamnb,eCrO0,, 2C0o0P4 000245 J i5 En b= 1]EB rel 4i oA | Hg ET BY Eiggls | : Ei 000246 DuPPRoOnAtICnoBmlpoaondy 2Ch0a0m4beCrosntWroolrsks | |.| d | i JeJeane a -- T-- ea-- ] -- T a --a--] [O GT out T To ol1]71 CC[Mrea dian |--7.06]--i57|6 [saDov | ses 7 [CATontras| -- i ea e 4 m -- -- -- -- wfee--m [-- Tass-- 0ria--x|| --selsub] ~0 BaPrrebpaarraJe.dDDaowcsaomnb,eGrH0,, 2G0S0P4 0002477 N i Beefie [Er Rl EEB EE i > | Bm | =B: ea i lee BE Lo Ii111d ie Bld at 000248 | DPuFPOonAtICnoBmlpooadny 200C4hJaamcbkesornsLWaoborrkastory [Fochileia[n]--Superviaion | I rs5R -- --ocam v --rg) --ri7e-- -- 1-- D C CTo e -- -- es--I--;a --" r= CC 2 r GY CET 7 I-01 0 0 5) [ATTA Tass] I 2 I 271s| I [cr r I icrli e 53 I I I -- 7-- -- -- CE [ -- a --i--s 1o--| Cr fa saml a usIL | PSroopaerodDDeacveemb,e1r0, 2a0n04 I{ 000249