Document g9rJ6nO8yDepOjzDJa6g6DxN

AR 226 _ 0731 ACUTE TOXICITY TO AQUATIC INVERTEBRATES (ACARTIA TONSA) IESTSUBSTANCE 00 Identity: A mixture containing perfluorooctanesulfonate, which may also be referred to as PFOS, FC-95, or as a component of FC-203. (1- Octanesulfonic acid) (CAS # 2795-39-3). Remarks: The 3M production lot number was not noted. The test sample is FC-203. Current information indicates it is a mixture of 1.34% PFOS, 35% diethylene glycol butyl ether, 37.85% water, 20% ethylene glycol, 2.66 % Sultone foamer, 3% sodium octyl sulfate, 0.1% sodium lauryl sulfate, and 0.05% tolyltriazole. The following summary applies to a mixture with incompletely characterized concentrationsof impurities. Data may not accurately reflect toxicity of the fluorochemical component of the test sample. METHOD: Method: 1SO/DIS 14669-1997: Water quality -- Determination of acute lethal toxicity to marine copepods (Copepoda, Crustacea). Type: Acute static GLP: No Year completed: 2000 Species: Acartia tonsa Supplier: Test organisms cultivated from eggs, supplied by Marine Biological Laboratory, University of Copenhagen, Denmark. Analytical monitoring: Dissolved oxygen and pH Exposure period: 48-hours Test organism age: Large copepodites and adults Statistical method: LCs, values calculated by PROBIT analysis, National Swedish Environmental Protection Board (Version 2.3, 1990). Calculation of NOEC by single factor ANOVA followed by Bonferronis procedure. - Test conditions: Dilution water: Filtered natural seawater (34 ppt salinity) from an unpolluted site in Byfjord, Norway. Dilution water chemistry: Not given. Lighting: A daily photoperiod of 16 hours light and 8 hours dark was maintained throughout the testing period. Stock and test solution preparation: A 1003 mg/L primary stock solution was prepared by diluting 0.5017 grams of test sample in 1 liter of water. Aliquots were then added directly to water in test vessels to create test solutions. 000718 Remarks: There appears to be an error in the stock solution preparation information. Dilution of 0.5017 g of test substance in 1 Lof water will not give a stock solution of 1003 mg/L. Based on review of another report conducted by the same laboratory in the same period, the stock solution preparation information should be dilution of 0.5017 g of test substance in 0.5 mL of water to give a stock solution of 1003 mg/L. Exposure vessels: 28 mL rolled rim vials containing 25 mL of test solution Number of replicates: 4 Numberof organisms per replicate: 5 Number of concentrations: five plus a blank control Water chemistry during the study: pH range (0-48 hours): 8.18.1 (control exposure) 8.1-8.2(320 mg/L exposure)' - Temperature range: 20+ 1C Dissolved oxygen range (048 hours): 7.27.6 mglL (control exposure) 6.1-8.0 mg (320 mg/L exposure) * 320 mg/L (second highest concentration) exposure values used because the highest concentration resulted in total mortality by 24 hours R0 ESULTS OOO00 Nominal concentrations: Bk control, 10, 32, 100, 320, and 1003 mg/L. Element values: 24-hour LCso = 340 (260 - 460) mg/L 48-hour LCso = 200 (140 -- 270) mg/L. 48-hour NOEC = 100 mg/L Element values based on nominal concentrations Remarks: Testing was conducted on the mixture as described in the Test Substance Remarks field. The values reported apply to that mixture and not ~ the fluorochemical proportion alone. CONCLUSIONS The FC-203 48-hour LCs was determined to be 200 mg/L with a 95% confidence interval of 140 -- 270 mg/L. The 48-hour No Observed Effect Concentration (NOEC) was 100 mg/L Validity criteria fulfiled and reference substance in normal range. Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 000719 p0 ata0 Quau0 ty 0000000000 Reliability: Kiimisch ranking = 2. This study meets the criteria for quality testing. However, sample purity was not properly characterized and the study lacks analytical confirmation of the amountoffluorochemical proportion in the solution. REFERENCES 0000000 Test was conducted by RF Rogaland Research, of Stavanger, Norway at the request of 3M Norge, Lab reference number 99312-2, 2000. O-- THE-- R. -------------------------- Last changed: 6/27/00 000720 . 4 fl \ Q RF watorema R2EEARER "FC-203 Light Water Brand AFFF" Toxicity tests Report RF-2000/002 Tab rt. ro: 5312:2 No.of pages: 31 Author: Ein Horve Gents): 3M Norge Version No. dae Vers. 1106.01 2000 Research Program: Sima: The following est results were obtained with "FC-203 Light Water Brand AFF": Todciy: Skeletonema costatum ~~ 72h EG, oon: 2 = Acar tonsa 48hLc, mon: 200 Corophium volutator 104LC, (mghg dry weight): >3060 The resus relate o the product as supplied by Novatech. Keywords: 1 Toxicity, Skeletonema costatum, Acartia tonsa, Corophium volutator n Topartof hi documentmaybarepodooedim ary for wARO parison wing bY FF FogaandResearch. TIsngaeyr LdiesecaorAndersen oKrarFeF-NeRotgiaalnadnd Resear 000721 993122 re CONTENTS: 1. PREFACE corns sms3 2. TEST FOR TOXICITYWITH SKELETONEMA COSTATUM cos & 3. TEST FOR TOXICITYWITH ACARTIATONSA corns: 10 4. TEST FOR TOXICITY WITH COROPHIUM VOLUTATOR sss 15 5. DATA SHEET(S).vcornrmmsmmmmmssssssssmmssssss2s0 000722 EN co PREFACE: NEocvoattoexcihc.oloTgihceaslatmepstlsewiesraecpoenrcfeonrtmreatdeotnha"tFGn-o2r0m3alLligyhtwiWlaltbeer BursaenddiAn FaF3"%isnoalugtrieone.menTteswtistwhere conducted in accordance with the "Harmonised Offshore Chemical Notification Format" (OSPARCOM 1995/SFT 1998). The project was carried out at RF - Rogaland Researchfor 3M Norge. All th tests were performed by RF - Miljolab. Study director was Senior Engineer Inger Lisa Andersen. The test results arepresented in separate sections. The results relate to theproduct as supplied by Novatech. This test report is issued by a laboratory accredited by Norwegian Accreditation (NA). eTqhueiapcmcernetdiatnatdiownorsktaitnegsptrhoactetdhuerleasbfoorrataollrythmeeettesst tmheetNhoAdsrecqounitraeimneendtsinctohnecearccnriendgitcaotmiopne.tence, Italso states that the laboratory has a satisfactory quality assurance system, which includes internal quality control schemes, participation in interlaboratory comparisons, and the use of certified reference materials and secondary reference materials. The testsperformed are covered by the accreditation. This test report may not be reproduced in anyform other than infull, without thepermission in writing by RF - Miljolab. 000723 TEST FOR TOXICITY Marine alga: Skeletonema costatum 000724 Sirsa" Te ii TEST REPORT GROWTH INHIBITION TEST WITH THE MARINE ALGA Skeletonema costatum QQlil ome RE ---- RESEARCH TEST SUBSTANCE: "FC-203 Light Water Brand AFF" TEST RESULT: - "The 72 hours ECs was calculated to 62 mg/l. `The test substance was supplied by Novatech, and the test results relate to this product. TEST DETAILS: METHOD: NS-EN ISO 10253, 1998: Water quality - Marine algal growth inhibition test with Skeletonema costatum and Phaeodactylum tricornutum. TEST ORGANISM: PREPARATIONS: Skeletonema costatum, strain NIVA BAC 1. A stock culture ofthe test organism is kept at RF - Rogaland Research. Natural seawater (salinity: 34 %:) fromanunpolluted site in Byfordwasused as basis for the growth medium. The water was filtered through a GF/C filter, and briefly heated to about 75C prior to use. The seawater was enriched with C`noumtrmiiesntssioancc.ording to ISO 10253, and recommendations from the Paris -- "Test `mg/l solutions were prepared was prepared by stirring from a 0.5008 stock solution. A sto gramsofthe product ck in solution of 500.8 1 litre of growth medium, Other concentrations were prepared from this stock solution. INCUBATION: Test cultures of 50 ml were incubated in 100 ml flat-bottomed flasks on an `orbital shaker, 3 replicates for each concentration. Test cultures were inocu- Tlahteetdetsotwabaosutr2un00u0ndceerllcso/mnltifnruoomusanlieghxtpo(n>en5t0iaulEl/ygmrosewki)ngfrionmocfulluuormecsucletunrte.~~ tubes of universal natural white type, at a temperature of20 + 2C. t`Thheetteessttfwlaassksruenacfhordaabyofuotr7g2rohwotuhrsm,eaansdurseumbesnatmsp.leAslgoalf5gmrolwwtehrweatsakmeenasfurroemd by fluorescence. pH measurements were performed as indicatoend data sheet. 000725 F L9a9b3r1e2f2ro Page 60/31 DATA ANALYSIS: CALCULATIONS: vGerroswutshtirmaet,esawsedreesccrailbceudlaitnedNSby-ElNog linear regression 180 10253. on biomass (fluorescence) ECs: Tcohneceinnthriabtitioornoy fefafperctodounctthegigvrionwgth5o0f%Skreeldeucttoinoenmoafcgorsotwatthumraitsee(xEpCrses)s.edTahsisthe etfhfeecctomcponucteenrtrpartoigonraamnmdethTeO9X5E%DcOondfeivdeenlcoepeldimbiyt wVeKrIe (cDalecnumlaartke)d,byastshuemuisnegoaf rloagtairointshimnihcibniotrimnaglgrdioswttrhibruattieon1o0f%daatan.d 9T0h%e (pEr.oCgiroaamnmdeE.aClosoo)c-alculate concen- NOEC: CfaacltcourlaAtNioOn VofANfOoEllCow(eNdobyObBsoenrfveerdroEnfifsecptroCcoendcuernterfaotriocno)mpisardionngeebaychsingleconcentration mean with the control mean. TESTRESULTS: COMMENTS: VALIDATION: Table 1. EC and NOEC values obtained with Skeletonema costatum. Testsubstance EC ECo EC FBrCa2nd03AFLiFght Water 13 (83-18) 6 (8-89) >100 NoEC: 3 eVVaallrueesstirnedrieccaitenoiccoeancaeddm,bryaNthiOeoEncsCogmaprieuncgalp1er0uo%lgtr3ea0bm%ymaeunsTdiOn9N0tEh%DecnOiobm(ipVtuKit,oenrDoepfnrmgoargrorkw)ai.mhmarenaedG.r9a5Up%nhciPosnafdiinIdmenlnic.ae3.0. dTuhreinrgeswulhtisacrhethbeasgerdowotnhgirsocwotnhsirdaetersedfotrotbheeetxipmoenesnptainal0 i-n7t2heb,cotnhterpoelrciuoldtures (see growth curves). Tcehlel dveanlisdiittyyicnrcirteeraisaedgibvyenaifnactthoerotefstmporroetotchoalnar1e6fiunlftihleletde,stinpetrhiatodthe control v(acroyrrbeyspmoonrdientghtaona1g,0rouwnitthsrdautreionfgmtohreetetsthaannd0,t9h4e"7)2, thhoeurcsonttersotlrpesHultdsidwintoht _ 3,5-dichlorophenol was in the range normally found. LSaabm.plreef.rneoc.eived.: Test period: Report date: 993122 20.09.99 04.07.1099 06.01.2000 AL Near Elin Horve Engineer Analytical technician HHoy " SeniAorgeReMsoelavrecrhsmScyientist Quality Assurance Enclosed: Data sheets T Tom r aber hn indul,ywittthehy peosisueioten idn wrbiyteinbyeg Rn-EMfillea.n (V0. The pm SE ' 7 000726 piri: Page ross PRIMARY DATA: Growth inhibition test with Skeletonema costatum Lab.rt: 993122 Test substance: "FC-203 Light Water Brand AFFF" Start date: 04.10.99 Conc. unit: mg Measurement: The biomass was measuredbyfluorescence; values in fluorescence units 04.1038] 05.1089] 06.1080] 07.1089] |Grraotwe | Carte atsotHar|atoennd Concentration | 1405| 0925 | 1030 | 10:40 | |day-1| tain| oftest| oftest 00 o01n5 || oossos || s729 || ssso || || 22134| [oosses 00 ooiw || oosee || s8a || as7t |||| 22027 0o0sse 00 ooaz || oosr2|| 6713 || as8s ||| 2[20260|| o10s0s0 00332 0o1ias || o0s7e7 aos || 22330|| 11.00000 0s oa | oss 7 243 | 09% 11 oota | [oosze |[ 1112 || e20s |||| 22431 ||oossesse| as 1 ote | oss | 83 | e|| 213] oses 3322 ooimea || oosses || 781 220152|| 00g80870 32 012 | 05 | es 217| 0560 100 oosae || oossss || s4s4 || 4e8s | | 212729| |0o90s7s4s as 10 ots | os | 75 | es || 200 |osn 004m3|| a5s3 128085|| 00939520 0s | 36 179| 0870 101000 0010|| o0o1s8 || 0013 || 10335||| [oosos |oser 100 oe | oe | 021 | 13 || ose |omme -- Reference substance0(13a5d|ichiooraorph|en) 18 | 42 | [739 [08% 9 o01166 || ooe4ss || vvaass || a239 ||| 1[11199| 1lo0s0e0s Mean val0ves: 0312 1302 1200 (Referencesubst oasa | o[0s8 || 1&0 | | es || | 2[3s20romo -- ootiss || 007s || 07 || sess 221310|| 00959%7 ooims || ooas || 47 || 3so | [125008 |oossees| ao | or | 0 | 4 039| 0317 | Teresa 0.5|05|16| 95 |[326[1000] swaannnawnoirsge romaly 6)0072 7 Liosresne Pagesorsit TGeRstOsWubTstHanCceU:RV"EFGS::200GLrioghwttWhaitnehiBbriatnidonAtFeFsFt with [U-- Skeletonema costatum le |e al i| ] i i 1{ e on I anion ls cuhlo| emew il| 3 $1 ! Te = OF aniopem ia 1 mgt ii.' i fo Fontan " 32 mg I5s!i i| fo I ansmpen 3 `|LA] 10 mgt 2i 34 i 2.49 Zw = 5) tot raton (ours) i7Ly 100 mg! is e y 3 a rs " RK ors 3 of7 32 mgt 4i 34 i1 _ HE) @7 s est craton (ours) i. 000728 Labrefno. 9312-2 Pagevo3s Inhibition of the growth of Skeletonema costatum itn: ag/L (FC-203 Light Water Brand AFFF) Experinental data: cFoCn-2c0e3ntrLiagthitonWaitner Brand AFFF Growth rate Iinnhpiebricteinotn cCoonnttrrooll 12 CCoonnttrrooll 34 CCoonnttrrooll 56 Control mean : 00..3322 0.32 11..0000 1.00 33..2200 3.20 1100..0000 10.00 3322..0000 32.00 101000..0000 100.00 22.0349 -- 22.10279 - -: 2.210280 -- 2.19 220.3320 00.00 2.3 oo 22.03861 00.00 2.13 2.8 22..0152 63.35 2.17 10 21.1272% 108.003 209 as 12..8065 156.51 1179 183 00..0605 10200..03 - 0.52 76.3 STATISTICAL PARAMETERS CALCULATED FROM CONTINUOUS RESPONSES 5 doses and 11 responses have been used during calculations. : EECc50:: EC 50 i 1631..3935 283.00 9555 %% ccoonnffiiddeennccee lliimmiittss :: (( 95 % confidence limits : ( 488..2295 .|.. 186.95 .. 1883..4160)) 562.40) _= Coefficient of determination :0.763 000729 L9a3b1r2ef2ro page 100/31 TEST FOR TOXICITY Marine herbivore: Acartia tonsa 000730 93122 RE TEST REPORT ACUTE TOXICITY TEST WITH THE MARINE COPEPOD Acartia tonsa QA paLrde RREOSGEAALRACNHD TEST SUBSTANCE: "FC-203 Light Water Brand AFF" TEST RESULT: : `The 48 hours LCs was calculated to 200 mg/l. `The test substance was supplied by Novatech, and the test results relate to this product. TEST DETAILS: i METHOD: 1toISmOa/rDiInSe1c4o6p6e9po-d1s99(7C:opWeaptoedra,quCarluisttya-ceDae)t.ermination of acute lethal toxicity TEST ORGANISM: Acartia fonsa (Dana), supplied by the Marine Biological Laboratory, University of Copenhagen. (CULTIVATION: The test organisms were supplied as eggs, and were cultivated in accordance with the "Paris Commission - Ring Test Protocol" (VKI). Large copepodites and adults were used in the test. PREPARATIONS: INCUBATION: Natural seawater (salinity: 34 %o) from an unpolluted sitein Byfjord was used parsiboarstios ufsoer.the dilution water. Thewaterwas filtered through a GF/C filter = Test solutions were prepared froma stock solution. A stock solutionof1003 `mg/l was prepared by stirring 0.5017 grams of the product in1 litreofdilution water. Other concentrations were prepared from this stock solution. The test was run in glass containers (28 ml rolled rim vials) each containing 25mlof test solution and 5 animals, 4 replicates for each concentration. The_ 2vi0al1s weCr.e kpepHt aunnddeorxyag1e6nb/m8ehasluigrhetm/edanrtkspwheorteoppeerrifoodramtead taesmipnedriactautreed of on the data sheet. 000731 Lsawbarigzirzo. rege sin DATA ANALYSIS: (CALCULATIONS: NOEC: Tahperoedfufcetctloetnhatlhetsu5r0vi%vaolfotfheActaersttiaanitmoanlssa (iLs Cesx)p.resTsheed casomtbheinceondcmeonrttraaltiitoyn of per test concentration were used for calculation. The 24 hours and 48 hours LCs values and the 95% confidence limit were calculated by using the standard procedure PROBIT Analysis, National Swedish Environmental Protection Board(Version 2.3, 1990). This programme also calculate test concentrations lethal to 10% and 90%ofthe test animals. CfaacltcourlaAtiNoOnoVfANfOoEllCow(eNdobOybBsoenrfveerrdoEnfifsecptroCcoendcuernetrfaotricoon)mpias rdionnge ebaychsingle- concentration mean with the control mean. TESTRESULTS: "VALIDATION: Table1. LC carta tonsa and OR a NOEC values obtained with "FC-203Light 24 hours oreo Water BrandAFFF". sthous Co 160 (84-220) 76 (2-110) Len 340 260-460) 200 (140-270) Lon 40 (530-1400) 510 Gs0- 1100) No Voaes :eny s TC. 302 dPan 55aloyanfweer ei4a54l7oadee dUcntis.nNg1OaVar0leEsaalreuCed ty hecamp prgromme GraphPnSad 30. oTxhyegveanlicdointcyecnrtirteartiiaognaivtetnhienetnhde otefstthpertoetsotcwolasagrreefautlefritllheda,ninortheaqtutahle1d0i4ssmogl/vle,d tLhCespeorfce3n,t5a-gdeicmholrotraolpihteynionlt(hreefceornetnrcoel)s wwaass ilnestshethraanng1e0n%o,ramnadlltyhefo4u8ndh.ours Lab. ref. no: `Sample received.: `RTeepstorpterdiaotde:: 993122 20.09.99 060-60.80.11.02.09090 Nee Elin Horve Analyt[iEcnaglinteeecrhnician Liter Kits ey Age Molversmyr. SeniQouralRietsyeaArscshurSacnicenetist Encloserd:eDsatea syheetHs airy Seedeody Norwegian eon (VA_ ). The_ repa_ y nb_ pro-- d en A bot io emeiion inwringby RE - MAUD. 000732 wili2 PRIMARY DATA: Acute toxicity test with Acartia tonsa Testsubstance: "FC-203 Light Water Brand AFFF" SLatba.rtrdeatt:e: Measurement: HT | Concentration 1 (mg) |{ cool | { {1 | 100 { 0s6e.a1r02929 Numobfdeeard Tol | -- specimen number |pr.vessel 24hours | Specimen| preonc.| A GC E | A CE B DF | B DF | 000010 || 555|000 5 0 000 1 555 5 555212 5 2 nn 48 hours ACE Tow |B DF | 1 0[100001 001 1 201 1 7 |344 1 55 55 555 5 i 1| i Toa| | I 1 | | i I { | Reference substance (3.5dichiorophenol): eee 020 1 tome 100 15 The result withthe reference substance is within the range normaly found. 000733 bos12:2 - Test substance: *FC-203 Light Water Brand AFF" LaSbta.rtrdatt:e: 0s6m.1z0.e1999 | wweT we] Measurements of oxygen andpH. | conconvation | Omgen pH omg | omen | [on (mon) . 2) - ) -! = = 1]i T+ -- | [eeTT Referencesubstance(35dichiorophendl): ___ _ _ 000734 93122" - TEST FOR TOXICITY Marine Amphipode: Corophium volutator 000735 Labret Page 160/31 T_ EST REPORT ACUTE TOXICITY SEDIMENT TEST WITH THE MARINE AMPHIPOD Corophium volutator QQ i RF l d2aBm ROSALAND RESEARCH TEST SUBSTANCE: "FC-203 Light Water Brand AFF" TEST RESULT: - `The 10d LCso was calculated to >3060 mg kg" dry weight sediment. `The test substance was supplied by Novatech, and the test results relate to this product. `TEST DETAILS: METHOD: TAoSxiTcMityE1T3e6st7s-9w0i,thStMaanrdianredaGnudidEestFuoarriCnoenSdeudcitmienntgs.10 day Static Sediment TEST ORGANISM: Corophium volutator, from an unpolluted site near Trondheim. CULTIVATION: aTehreatteedstsoeragwaantiesrmast w1e5rCe.suAppslmiaeldlasamaoduulnttso(f4n-a8tmurmalisnesaiwzee)eadnwdawseurseehdeflodrin feeding. PREPARATION: NSattauvraanlgesreawwaasteurs(esdalfionritdyi:lu3t4io%n)wafterro.m aSneduinmpoelnltuctoeldlesictteedinatByafnjuonrpdoelnlouuttesdidsiete awnaaslyusseeddffoorroprrgeapnaircincgontteestntseadnidmepnrtosp.orTtihoensseildtifmoernetaicshatemsut.ddy sand and was _ dEaacmhptsesetdciomnecnetnitnraatpiloanstwiacsbupcrkeepta.re2d0b0ymaldodfinsgetahweatperrodwuacst aindd6e0d0angrdatmhseof 1 4bu0c0kemtl woafssesahwaakteenrfwoas3rahdoduersd.toTehaechs,edainmdetnhtewbaesakdeirvsidweedreinatcortahtreedeobveearkers, tnihgehdt.am1p0 saendiimmaelnstwwearse athneanlyrsaenddfoomrlwyasteelrecctoendtefnotr,eaancdhablleackoenrc.enAtrastaimopnlsearoef. calculated as mg kg" sediment dry weight. -- INCUBATION: sTehdeimteesntt,waaspp.ru4n0i0n mgllaosfssceoanwtaaitneerrsan(d60100maln)imeaalcsh,c3onrteapilinciantges20f0orgeoafchtest concentration. The beakers were kept under continuous aeration ata tiendmipceartaetduorenotfhe1d5a+ta1shCe.etpH and oxygen measurements were performed as 000736 3i 993122 - } Hl DATA ANALYSIS: : CALCULATIONS: The effect on the survival of Corophiu volutator is expressed as the concen- tration ofa product lethal to 50% of the test animals (LCs). The combined vmoarltuaelaitnydptehret9es5t%cocnocnefnitdreantcieonliwmeirteauesecdalfcourlactaelcdublaytiuosni.ngTthhee s1t0adnadyarLdCso 3 PROBIT Analysis, National Swedish Environmental Protection Board (Version 2 23,1990). This programme also calculate test concentrations lethal to 10% and B 90%ofthe test animals. i NOEC: Calculation of NOEC (No Observed Effect Concentration) is done by single- E factor ANOVA followed by Bonferronis procedure for comparing each ; concentration mean with the control mean. 4 TESTRESULTS: Table 1. LC and NOEC values obtained with "FC-203 Light Water BrandAFFF" & Corophiam volutator 10 eas 3 1co >3060 i 1Ca >3060 : Co >3060 &1 NTOEC:o TT Tt ne 30m6g0 en &x GVraaplheprased icnSlit 3e0abyPROBI ans. NOErCe caby ehecou mptee profdane 3 VALIDATION: The validity criteria given in the test protocol are fulfilled, in that the dissolved oxygen concentration at the endofthe test was greater than or equal to 60 %, 44 tFhleuoprearncteennteag(eremfoerrteanlciet)ywiansthien ctohnetrraonlsgewenorremlaelslsythfaonun1d.5%Thanedsaedtiemstenwtituhsed is found to be within accepted limits for organic content and silt fraction. 3 Table 2. Characteristics otfh sediment used for testing -- | Organic conteat (4) Siltfraction (4) 1 01 0s 1 LSaabm.plreef.renco.e:ived.: 29090391.2929 QElien HoVrvoe n TAogee MMolovierssmsyry ~ Test period: 0313.12.99 Engineer Senior Research Scientist 3 Report date: 06.01.2000 Analytical technician Quality Assurance 3 Enclosed: Data sheets TThoismoetshterretpohratnsinuFuell,dwbhyu3tahbeopretiesornefndwroiynNgorbwyegRiFan- MAcocrbeaon (VA). The report may nt be eprdosed many 000737 993122 i PRIMARY DATA: Acute toxicity test with Corophium volutator 4 Testsubstance: "FC-203Light Water Brand AFF" 3 3 StLaabr.t rdea.t:e: 90933.1122:829 : Measurement: Numobfdeeard ra | I Number of NUMBER OF DEAD | number | pr.vessel 5days 10days | Goncentration |Specimen| A C E | A CE ACE (mo dry weight)| prconc. | 8 D F | 8 F | Tow | 8 D F| Tol i t| 1100 1100 1100 A ee Taleo 000000 Pee] | i| l [{ ow |oo | cnr 3060 10 10 10 ee | l 2 Referencesubstance (tuorarthene): _ :i Loo --|ow | t-ee | e- ls] 7 i| 83 `The result with the reference substance is within therangenormallyfound. -- { i 000738 [ow [ewe] | concenvaion [Omen oH Oyen pH | Omen pH (mg/kg dry weight) (%) : (%) = (%) - [or To wo wie Ce[Tv ewe e] 11 1] EET 2 000739 ssi % Page 00r31 DATA SHEETS -- 3 000740 SLattresfro: Pege21 oft ) EMS-DATASLAD (selse-, Milie og ixmermacasacavies] SSorkeunmaennesrac. 1002-/3108/0907 SUkriseivcees ue: 0131//1111//9388 sviedresion 1 Lase 06.0o0o | TBe4l5e-fdoant:abl6a3de8s4 7e5x 0u0sa/sbTeeildeeftaxa:v 6w3iljaeoavidsel5i8ngen ved IH Norge A/S. | 1 IDINTITIXASION AV RIMIRALIE 06 ANSTARLTS Fra. | faporsors a Norse A/S FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FoR Setezaesjionsnouanemrees., Produkrasisteres 22's5 13 00 Telefon, Giftinformesjonsseatralen: - re E---------- Informasjon on enkeltkonponentes, fazesysbol(es) og risikosecninger srormuav asm vmesosaer | 2p-(2-30ToKs:zT0=KTASNYO)L / [Et Ttiatasness % I a 1a-Fiazaetsyomrboles/zisikosetninges: Xi; R136 Faresymboles/sisikosesainger: xn; R122 109-211 "20 :i RSFELwSUETOTSRRIALsACKVY:LOORpVGeEATNReIFRSLGKAIETNEIFAELRUEIOVREKISETNOIPKFAELRIER Tpreaadsee smeeccrreerr Toads secret [ ros Ikke biome -- 5 3 viKTIGsTs FanswoneTan. & 00741 i_s-- Page 220031 FS-203 LIGHT vatER BRAND AqUEOUS Fron FORKING FORK : Vikeigree skadevinminger HetsetXaezne:Lzsicere synens og huden. . .| Sixkeshess LPiT mstserSsreeesrisievtait. i1 4 FORSTEHJELPSTILTAK. = !I| | -- SnlKeIdLetsnsaeraek:s synene mad sikelige sender vam. Koncake dese iHDi i meRSe1mns2eeeiehudteegnermad =ixalise messder vann. Evi irrisessonen vecvaras, | eaerias"onsnysspirno,mes cppsads, being vadiomende bert fra || pSihssztoenceisiiinssnsgkilden. Sots for frisk left. Svis syapsomens vedvacer, | TitaSKoendstivasekiltgntanklga:pgearsuonniedila.tnaGc1t.alFreeaknaolelSbireemkonninpgeesrmkaunth41seeenciEd emetdst0s . | Ema ves mammerenian. ZonesPrbordaumkmisetsuknoxingoitaibdrdaemtmselokkingsaidiel. ) ! Tike eqns brammslukningsaiddes - i Eesponecingszistko ved bream i - IN Forbrenningsprodukter ved brann: 5317s Lab.refrno.: Page23of 31 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM TILIA VED UTizerkes: uTeLies. PessonSleigveernveetsimleiseitkcaukn:der andre puskser & deste BMS-datablades. | TilteokSVnebznsviseoddirelbteeu:zzmeienolddmsecihvkdzmaeeanc:t..eruitPSaslellaieisl.pslpe:rSsepvsiglrleinsesenasmleegusnmeitdodpepbleshuaomrlicdd.edrelDsmeaekcdkt.ttiolRke.nmgediorer ||: FleniSnegpuanvkekje1m3,ikeFliiecranvienagllasv Kjemikalisaviell. i 7 HANDTERING OG OPPBIVARING. SesinBWshetlsieeklkrelefrolraglresegiseknkieidrioeomrpc.phbdeeLvraagrihievnsogr:vepsrodsuekmtseercaikearn uknodmemre 9kgonetsatket med Gelsius. Lasres ved temperatures over 8 seeder selsive. seid | beholderen test lukket rir produktet ikke er i bruk. | Utozenelige materiales: : vensitCaospseovna:s ensellzsien sh et godt ventilest sied. | Sikkeshesstileak for & forhindre brasn: : SStikkkkeesrIhhkeeectbssrtteiinllnetbaaakkr.ffoorr && ffoorrhhiinnddrreeekstsaptliosskjoenl:ekssisitess i Forholdszegler ved bru: SpHoropolkddeunkeimoabgsallkfaaanszjieizngeeyktdieentxgtomflpuookrnkdeerrts.iankgeRsepyfrkoeirdnuurgkeinfesornribnuKdgatn:avS.Uansmdoemers:kibaorneukpouaorvneelle1rh |t| - - i stabilitet og reaktiviter, skadelige dekomponenter. i1 gi| ] 8exsrowmammaskovnooras penser vim, TTT 000743 a page 200731 { i 99312-2 8 /: Fo-203 Lous waren snap aquEous Tix FomkING FoR i oyeverUna:ngh & 4 dep, vernebiller med vsepnrtaiyteerl.ler sike i oynene. Druk teste Hhneve3r:nu:k agnece vernehanskes av hens tkusaessig mesesiale ved ahndbnedfzaelreisn:g sBvusyplrgoudmumkis.es. Vernenansker av folgende meteriale(s) AnnesUnhnusddvezhnudeknonnthahkaecvern: Andedzestsvern: . U2Svynpnegl(dusf)eifngnooircnukdzjieenngnssaaiAvnngdelerudfzz{ebtlatrrsebvteeirmdnas:taecrnhioaasllfveam.raesnkBeasveemlregtdespfdiletnkeornasvmenfotorlagsejnodneen orsaniske damper og vaskeformise partikles: A/P2SL. SvelsiDnegt:nh ikke spises, drikkes eller roykes under erbeid med . phreonddueknteete.xteVraskhinudtsseartitnegoomgrdfeorr sgpriusnidnigg. med sipe og vann. Vask || awsefa#lvsisveunttsiuigansijnogns:vensilusjon ikke ex tilstrexkelis, nd egnes I agvdoendriktnjiielsnattszjaodznnidveseidizkneosrtamscevseasmnopgk/boeennlsyletetnresske.osajtSoronorelgnlsefrohroslpcdriealsyssruelenlkdekeserlietghnkbee.falte Adn. normer for foruzensning { arbeidsasmosfaze, Februar 1936: VAN A(m7e7c3k2n-i1n8g5e)s: Ingen sca. norm. 2-(2-3UT-tOiRnSeYrSsTOvReSrYe)i-SpoTmA:NOL35 / (DIZTYLINGLYKOLNONOSUTYLEZER) (112-34-5) A(nImnegxeknninnogzesrk: aAdnm.erinkozamn)s.k grenseverdi anbefalt av produsenten. - 1,2-ET8A-NtiDnIeOsLs (v1e0s7e-i21p1o)m: - (stew) T8a-ktvineerzdsi pveear:e:25mo/m(ae:sp1)0 (stv) | Takvezdi ng/ml: - (dang) SYNISTAnImSeKzEknDiEnTgEeRsG:ENTIEnRgen(Tardaad.e Sneocmr.et) FLUORAAnLmKeYrLknOiVnEgReFrL:ATEIAngKeTnIVEadaS.TOnFoFrEmR. (Trade Secret) RESTER8-AtVineOrRsGANvIeSrKdEi mFLgU/OmR:KIE0N,I1KALGIrEeRn,se(vTerraddie Saemcbreefta)lt av 3M. ; 000744 Sits wuo.rej.no. Page 25 of 31 7-303 Liu wacen saan aquEouS Ez rome rons Pramepunie: setvancennetisnes: ---- te cetensos suspen coo. i10.3emtg)(ratistens Dasprecshes: cTeot111 (arent) rectors Tirkeise oxseniske fosbindetees (1): =ae37.0 51 SCAG Kebintere Viskositet: Lo Ikke kjent : = Tozhatd som skal msi: sasaziater som ska smnghes fartio$Ree9zo3sCp0ouatueenlnatiknasgss4ocro0tduikXsoeetrnosondaiuckksiadm.eyessnosBentoluceeird.iCGhieEiAgTn douemper, wtIhF forventes ikke & representere noen risiko. 000745 L5a9b3r1e2f2ro. Pa26gofe31 FC-203 LIGHT WATER BRAND AQUEOUS FIL FORMING FOAM SeabilSittebeislso.g rTeesalkissiviptoelcy:merisesjon vil ikke forekomme. 11 0PPLYSNINGER OW HELSZFARE. sezektHeirldoyonyee:izzitasjon: synpioner kan vare rodhes, hevelse, smerter og czer. EefekzHeirldhuhda:dizzitasjon (etser langvarig eller gfenc|ast kontaks): symptoner kaa vare rodhet, hevelse og kloe. zefekt=enreniknenlktadionvge:zeksponering son overstiger anbefalte adainistrative nommer, ken fore til: 2esihveicr,knisnogvaiagvhes:e,ntmzaanlngelrevnedseysktoeomredti:nassjyomrpsteovmaeer, kennedvsaastee hodepine, zSeecvkiasjsocnlsoesvhsees,. siezes tale, svimmelhe: og i ekstreme tilfeller sIvrezligt,asjhoonsti(negveoglunyfstivnegi.er): symptomer kan vare sirhet i nese og zefekzDeyrzefsovrelsgeikngu:tfors med orgeniske fluorkjentkalier, son finnes i Gmeesntgelenpdreoduskptpeess,ittv,isesrlovehfeftektsearmtsoefmfelketveerrfosrosmcyprhrveilrskeerr, nveeukriotleopg,i, bhueklssoeyeetst,ekbiiensyzfeoromgenhneemastkoelsogfir.a Deektspofnoerreilnigggeorverifnogrenorkgjaennitseke vfeliuloerdknjienngi.kalies nbz de brukes som forutsate og i henhold til = Svelging kan. fore til: Pihvuziiznkenningogavrynsyssmeenset:ers.ymptomer kan vare redusert urinmengde, blod A Akosmpmiezrasjnoednspineluunnognenie.(LEunngeablemsiennnneellisgebrssoanksktyilldetsilsattanfdreenmmeexdlegener oRpopsktaesto.p)p: blsoydmpoigomel:unkgaenbetvaernenelhsosetisnogn, kpaunstveavraensLkievrs,trugeinsdpei.ng, Informasjon om allessi, ovesfolsomhet: Keettfrenkallende esenskapes: . . 000746 . Lasbwriesnso: page27631 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORKING FON Arvestotsskadelise sgenskepers Reproduksjonssadelige egenskaper: . Andre skadevirkninges, heise: Eftorersepsyumrselv.edrorende produktets giftighet er tilgjengelig pk Dfelsutoerkypernoidkuakltieers,insnoemhomlduelriseennseklalnersbfsleorreberoerssan0i3skleagres over lengre is, encen son utgangeneleylet sller som i krovpen Snjeednbtraytttneinsgkssaptoontetzeirng(emre.reDbeotlizftoerreyl;igzoeFrKeinngeankkikmjielnteeresMelvseedeffekier SfoAr mdeennberuskkeesr sforam efokrsupsosneetrtinga3ovierhfeonriolodrgaeniliskveellfeldunoirnkgj.emikalier VSFaeosnreeerkepolnuisbesleinsbeerfatovlksonizdigenanngiesn1k3e7o0g fAulrnuedcneserk.sjoepnouitiskaasleiipoeinrdeesmiiobslolmoogdieatshkeetiidlsetudredeniesharav Sone irneidere viser ingen sacelise ebfextens 12 orsiteniicen on Weiierass. PezsiDsestesnes/pirooldougkitsekt ninendeanrsyihdaerrheecns eller flere organiske millujooreksjen(ipkeerlsiiessenstoem).meligens ikke 6x nedoryibere og forbliz { AniseNeskdahdyesvbiarzkhneirnges, miljer - c2o0c0 200 22(00chdceaamggieecrarsls/cO(ox3nyigoec=nhe1Dm,e0i0mc.aenld)Oxy=ge1n,1Degm/ga:nd) = 11 57g; Aevasisk gifeighess pSrtoasteilssks)9)6 =tin7e5s0smL/Cl:S for fisk (Fathead minnow (Pimephales Stacisk 36 tines 50 for fisk (Rainbow trout (Oncorhyncus ~ oStkaciiesk) 43= 1c3i0n0ersn/LtC;BO for daphnia (Water flea (Daphnia magna)) = S1t60a0timssk/18 (t13i0n0e-s210L0CS0m;3/1A1n;tipode 1100 mg/d (340-1300 271); (Scud (Gammarus fasciatus) = v48igsciinneizcsa)C=504,7 mZga/slser(n10O-y3s34terAg/s1m)b;ro-larvae (Crassostrea i 2489/1tim(e1r7s00-C35600,5 Cmogmsmiro:n mammichos (Fundulus heceroclitus) = 2500 000747. pSrats page280131 FC-203 LIGHT WATER BRAND AQUEOUS FI FORMING FORK 5T(I2C06(02-R7,e250s,p5im-zotarrsaiyjf;oen,nylAecetsizvaaztoeldivsalkuidogreid=)>S1e0s00vimgs/tle: ingen ensymhenning for konsentrasjoner opp Sil 1000 mg/l. SorS for aviallshindsesing ihe. gieldende forskeifcer. 13 EISRNING AV KIEHIALTEAVALL, MezodFeSorptetsfaiokarsl-afvjieealrllnlei.rngLbeeahvveenrkdjleaimvnifgkaasllalineltaeivslfsaelnflo:roffsesnecsiiisyiessto:edrksj.ent innsamier, aHUsONbVDeDEfKRaAGlTTtEIeGGOOsRRvEEat00i77s:g0r6Au:VpFpAAevLreL:alFlRAfrOaRGAPNSIDSKEavZRc0eSsZeSaSsEoRt.ier, spe, zEAeXn-skioodreing0s7ai06die0r3,! os sodertut. HdeelsoigneenkesrjtoensemrisdalneisrkeosleKsoesmmiodsiieir,, vaskevasker Avtallstotfrummer: 7151 Orsanisk aviell sed halogen. Soestelle komporentes: inaeholder flovsforbindelser, 14 orRLrsuIGER on TransRORT, Poreklasse: sitter: bokstavs mezgnunmes: -- numer: ter0kiesse: Doc-ktasie: 0-side: Eason. i | reac: - a co - - - - - . 000748 La93b1r2e.p2ro. Page 29131 FC-203 LIGHT WATER BRAND AQUEOUS FILX FORMING FOAM ovrigeTkokeppltyrsannisnpgoerst:aslis gods. 15 OPPLYSNINGER OM LOVER 0G FORSKAIFTZR. Meskeetikese: SyaboHlEeLrS)E:SKADELIG (Xn) . Inneh2o-l(d2e-sb:uzoksyesoksy) -ezanol 35 -. Scylengiykol 208 ResetnFianrgleirs:ved svelging. Ken irritere oynene og huden. S-setnUinnnggeds:innkading av dems/sproycesike. Unngh kontakt med huden og omyennednee.s Fvie:namaong skcoonfzfaekc: ilegsey.nenZec;serskyhluldkosnttzaakkes, grvuansdkismedmedsivseoroeg veelnlne.s Veesdikestvteelng.ingK,unkotnitlakitndluesgterioenlglebrnudks.ogIkvkiesbedreengnaestbehtoilldebzreank som medisinsk uistyr eller legemiddel. i-gru0p0pe: Korr. yrkeshyg. luftbehov: ovrigeOvecnpnpleyvsnntiengmeerckoimngmeecrkebeatsiekretttpehn:tidligere merkefo:rskrifter og vil | vianriedle&rtfiidnneerpshtapcrteosdukatverfoelngentdied mfercekmionvge,r. sMoemckeizngbeanservtilpb reviderte merkeforskrifier av januar 1938. Symbol: Ingen Innenolder: 2-(2-3utoksyetoksy)-ecanol, 1,2-etandiol UKennngkirkzointteazektsmyendenehudoegnhuodgene.yneUnnen.ghFAirnnbmnadninsgtoafvfetdamip/esypnreoney;sessikkyel.l "|" ssttorfafksphgruhnuddeing, mvedasksetsorestmreenksgdemredvasntnoreogmeknogndtearktsilpegee.ogFivzamm.anVed svelging, drikk to glass vann og kontakt lege uniddelbart. t00i-grupse: 000749 La9b9r3ef1n3o.: Page 300/31 FC-203 LIGHT WATER BRAND AQUEOUS FIL FORMING FOMN SpesieS1l.ilkekFeozrlhsoekveetrisfdcoagtoabmbelseucdseamcfmboeerlisdfeearlrssleigeogkdjiesmtirkiabluiseiron av Helse-, Milje- og 32.. FFoorrsskkeeiiffst oomm Kkllaassssiiffiisseerriinngg, kan medfoe miljotases ongecmkeisnkginAgva.v afvarSltigoeffkjseonmikelies. 54.. 6 fFoorrsskkrriiffee see oonn sspteosfiiaklaarvtioatiesk.. I || mRmmmRmemeS nsilen n oD TaD DsEeTImPaUiInNeCToOnRBsROKeERsS SISNeRSmRMeSnT 0aGn EeLiSnEe. AnvendFeillsaecsaonnnseinddeer:skumkonsentret for slukking av brann i hydsokasboner. !| ViktigDsatteeblkeidldef(as) 3MveGdenuetraarlbeOifdfeilcseesn, avSt.AMS7-asdle,cebMliamdmeets:eca, USA. | AzsakBHeMtlSiel-dadoptepetdbaalbsalecartdioenrsgs:korrifreeavsi,derfte.ssTaitlepasiseatuanyre m1e9r90k,e-Zeoeg: Zqne opplysainger: || acIevnefldoyerstmnteiesnjgpoernsoednuokgoidebsedsetutetnedeorpHoHfnSa-osdmnaeitlnaegblaafdonergtnhoelneddx.siZrnhiheksviheio:yldbbeuutkiloavfviprhreionddnutixevsraeirrsepnedsneom || pIrkokedukesxetisianksovmebrinmeesdjondemsetde ex brukezens ansvar, aAnMdSr-edatparboldaudketce,r eellllees esmohmvemreciaonrneerm bpercokseosv | | 000750 SLa3br1e3t Fogestofst FO-203 LGET WATER BRAND AQUEOUS FIIN FORMING PORK i !| roroenoe sroduKesa pmxxzs av DETTE AMS-DATABLADET: [I -- + x3uMrn-A00T0E8-022-127P-r03oduBxrsainonnslukningss Fp + r-0008-0059-5 | F3MigLhitgihntg WFoaatme,r 73%-A20F3F,F10F0i0reL || aH Toons. | + F3XiFg-hL0ti0ig0nh8gt-0W0Fa7out0ne-,r5 7308-2a0r3E,r 3m0i0re1. ||| 3M ID-nr. + XF3H7is-Lt0u0ii0gn8hg-00WF6oaa9tm-e,8r 37%6-2A0E3,F Fi2r0e1 i }{ . || |i | | | . |! || | | | | | shy . 000751 .