Document g2x0xveXbQYbM7BBg2JkMYyNJ

06-May-S9 Conoco material S-atety Data Sheet Page 1 MATERIAL IDENTIFICATION NUMBER NAME GASC W<b6 Sour Condensate CHEMICAL FAMILY i TRADE NAMES AND SYNONYMS Casinghead Gasoline Natural Gasoline 0541 Petroleum : Hydrocarbon CAS NUMBER Mixture; See Regulatory Information NFPA RATING Health: 1 Flammability: 3 Reactivity: 0 WHMIS CLASSIFICATION This is a WHMIS controlled material. See Regulatory Information. MANUFACTURER/DISTRIBUTOR: Conoco, Inc. P.O. Box 2197 Houston, TX 77252 GENERAL INFORMATION PHONE 1 -(713)293-5550 TRANSPORTATION EMERGENCY PHONE 1-(800)424-9300 MEDICAL EMERGENCY PHONE 1-(BOO)441-3637 ****+*******************+************************+***************+***'**** OSHA HAZARD DETERMINATION Hazardous Ingredients CAS Number Hydrocarbons (Aromatic & Paraffinic) Benzene (wt.'Z) Hydrogen Sulfide Mixture 71-43-2 7783-06-4 ,= 502 o .1-1 1 - io;c Hazardous Physical Properties: Class IA Flammable Liquid - NFPA 30-1987. The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to the Regulatory Information Section of this MSDS for federal and state regulatory information. *****************************************************hh***************-**-*- PHYSICAL DATA Boiling Point Vapor Pressure Vapor Density V. Volatiles Solubility in Water dor Form Color Specific Gravity 80-700 deg F 200-500 mm Hg at 68 deg F > 1 (Air - 1.0) Variable Insoluble Sulfur Liquid Dark (H2Q=1) 0.8 MCD 000023351 06-May"3? Conoco Material Safety Data Sheet hage 2 MSDS No: GhSlO'I^c HAZARDOUS REACTIVITY Instability : Stable. Hazardous Decomposition Products: Carbon monoiade and oxides of sulfur may be formed. Conditions to Avoid: Oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur FIRE AND EXPLOSION DATA Flash Point : -50 deg F Method : PMCC Flammable Limits in Air, X by Vol LEL : 1 UEl : 10 FIRE AND EXPLOSION HAZARDS Class IA Flammable Liquid (NFPA). EXTINGUISHING MEDIA Dry Chemical. C02. Foam. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from areas of potential ignition. Unusual Fire and Explosion Hazards: Highly Flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protect ion. ***********#***#**#**************-*****************************-** HEALTH HAZARD INFORMATION Primary Routes of Exposure/Entry: Skin, Inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: A few studies have indicated that workers exposed to high concentrations of benzene have a slightly many years higher Oo-May-89 Conoco Material Safety Data Sheet Page 3 MSDS No: bAScOOoS < HEALTH HAZARD INFORMATION - CONTINUED) incidence of leukemia. Benzene can also be toxic to the blood and blood-forming tissues. s t ud les w ith m ice or r a ts h av e shown t h at some petro leum d 1 St ill at es ha ve cause d eit he r damag e o r tumors of t he k i dn eys 0 r t urn ors of t h e li ve r. How e V e r, kidney eff ects w e re no t seen in s im i 1 a r s t ud les inv o 1 V in g guinea pi gs. dogs o r m on k ey s, A Iso , the s ign if 1C:ance 0 f th e liver turn ors in rodents is highly speculative. Mouse skin painting studies have shown that petroleum middle distillates (boiling range of 100-700 deg F; naphtha, jet fuel, diesel fuel, kerosene, etc.) can cause skin cancer when repeatedly applied and never washed from the animal's skin. The relative significance of this to human health is uncertain since the petroleum distillates were not washed from the skin and resulting skin effects (irritation, cell damage, etc.) may play a role in the tumorigenic response. A few studies have shown that washing the animal's skin with soap and water between treatments greatly reduces the carcinogenic effect of some petroleum oils. The product contains petroleum hydrocarbons which may cause irritation to eyes, skin and lungs after prolonged or repeated exposure. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness and other nervous system effects; greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness or convulsions. Hydrogen sulfide can be irritating at low concentrations to the eyes, skin and lungs. At higher concentrations, loss of ability to smell hydrogen sulfide, respiratory paralysis and death may occur. Carcinogenicity The following components are listed by IARC, NTP, QSHA, or ACGIh as carcinogens. A 'P' indicates a Proposed Carcinogen. Chemical IAR NTP usm Ai Benzene (IARC - Category 1) x DuPont controls the following chemicals as potential carcinogens : Benzene (IARC - Category 1) Exposure Limits for Sour Condensate MCD 000023353 06-May-89 Conoco Material bafety Data Sheet Page 4 MSDS No: GASCOv-bb (HEALTH HAZARD INFORMATION - CONTINUED; TLV ** (ACGIH) s None Established PEL (OSHA) : None Established Other : Exposure Limit for Petroleum Distillate PEL: 400 ppm, 1600 mg/m3 Other Applicable Exposure Limits: Exposure Limits for Benzene (wt.X) AEL * TLV *-* PEL (DuPont): 1 ppm 5 ppm - (ACGIH) : 10 ppm, (OSHA) : 1 ppm 5 ppm 0.5 ppm 3 & 12 Hr. TWA 15 Min. TWA 30 mg/m3 (A2) - 8 Hr. TWA - (Short term exposure - Action level limit) Exposure Limits for Hydrogen Sulfide AEL * (DuPont) TLV ** (ACGIH) PEL (OSHA) 10 ppm - 3 & 12 Hr. TWA 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 10 ppm, 14 mg/m3 STEL 15 ppm, 21 mg/m3 * AEL is DuPont's Acceptable Exposure Limit. ** TLV is a registered trademark. Safety Precautions Do not breathe vapor or mist. Avoid contact with eyes, skin, or clothing. **************************************************************-****-*-*-**-* FIRST AID SKIN CONTACT In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. EVE CONTACT In case of contact, immediately flush eyes with plenty of water tor at least 15 minutes. Call a physician. INGESTION If swallowed, do not induce vomiting. Give large quantities :t water. Never give anything by mouth to an unconscious parser. . <il a physician. INHALATION: Because hydrogen sulfide can cause death, rescuers must wear positive pressure full facepiece, self-contained or suppiied-air NIOSH approved respirators before attempting the rescue, if hydrogen sulfide is present. Remove victim to fresh air immediately. If breathing stops, being artificial resuscitation. Keep MCD 000023354 06-May-89 Conoco Material Safety Data Sheet Page t< MSDS No: GASCOOofe {FIRST AID - CONTINUED) victim warm and at rest. Seek medical attention. NOTES TO PHYSICIAN Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. ********************+*+***************************** *********-*** ***--* *** PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilation: General mechanical ventilation normally adequate but use local exhaust where necessary to maintain exposures below acceptable limits. Personal Protective Equipment Respiratory Protection: Select appropriate NIQSH-approved respiratory protection where necessary to maintain exposure below acceptable limits in the Health Hazard Section. Proper respirator selection should be determined by adequately trained personnel and based on the contaminant^), the degree of potential exposure and published respirator protection factors. Protective Gloves: Should be worn when any potential exists for skin contact. NBR or neoprene recommended. Eye Protection: Goggles or face shield for spray/mists or if splashing is probable. Other Protective Equipment: Coveralls with long sleeves if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUT I before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. All sparks, flames and ignition sources must be restricted from the area. Contain spill immediately in smallest possidle area. Recover as much of the product as possible by such methods as vacuuming, followed by recovering residual fluids by using absorbent materials. Nonrecoverable product, contaminated soil, debris and otnmaterials should be placed in proper containers for ultm r* disposal. Avoid washing, draining or directing material MCD 000023355 06-May-89 Conoco Material Safety Data Sheet Page s MSBS No: Gh&U UU 6ib (SPILL, LEAK AND DISPOSAL INFORMATION - CONTINUED) storm or sanitary sewers. Waotw Disposal Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. Recycle as much of the recoverable product as possible. *************+*********+***#*#**********+******************#'-#*a-**-***-*-* SHIPPING INFORMATION DOT Proper Shipping Name Gasoline Hazard Class UN/NA No. DOT Label(s) DOT Placard IATA/IMQ Proper Shipping Name Natural gasoline Hazard Class UN No. IMO/ICAQ Label Packaging Group : Flammable liquid : UN 1203 : Flammable liquid : Flammable : 3 (IMO 3.1 ) : UN 1257 : Flammable liquid : II *******************************-**-*********** ********** *************** STORAGE CONDITIONS f Store in accordance with National Fire Protection Assn regulations. Acute: Chronics Fire s Reactivity; Pressures Yes Yes Yes No No REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 261 and 302 The material contains the following hazardous substance which, when released in quantities equal to or exceeding the Reportable Quantity, triggers National Response Center notification requirements. Hazardous Substance Not Applicable Reportable Quantity SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, TITLE. Ill - SECTIONS 302, 304, 311, 312, 313 MCD 000023356 06-May-8? Conoco Material Safety Data Sheet Page 7 M3DS No: 13ASC0O6* (REGULATORY INFORMATION - CONTINUED) SECTION 302/304 - Extremely Hazardous Substances, 40 355 The material contains extremely hazardous substances at greater than 1.0*/ concentration as listed below; it is possible that this material may contain other extremely hazardous substances at a lower concentration. CFR Extremely Hazardous Substances: Hydrogen Sulfide Threshold Planning Quantity: 500 lbs of H2S Reportable Quantity: 100 lbs of H2S Concentration: 1-10'/ SECTION 311/312 ** MSDS and Chemical Inventory Reporting Requirements, 40 CFR 370 The material should be reported under the following EPA hazard categories: x Immediate (Acute Health Hazard) x Delayed (Chronic Health Hazard) x Fire Sudden Release of Pressure Reactive Not Applicable Notes See the Hazard Determination Section for the concentration of any ingredients classified as hazardous by QSHA. SECTION 313 - List of Toxic Chemicals, 40 CFR 372 The material contains the following chemical(s) at a level of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and is subject to toxic chemical release reporting requirements. Toxic Chemical Benzene CAS # 71-43-2 Approx. Concentration (Upper Bound) r/ TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 The material is a mixture as defined by TSCA. The chemical ingredients in this material are in the Section 8(b) Chemical Substance Inventory and/or are otherwise in compliance with TSCA. In the case of ingredients obtained from other manufacturers, Conoco relies on the assurance of responsible third parties in providing this statement. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal MCD 000023357 06-May-S9 Conoco Material Safety Data Sheet- Page 8 MSiJS Not GhbL'.'Oui (REGULATORY INFORMATION - CONTINUED) regulations; however, it could be considered hazardous if it meets criteria for being toxic, corrosive, lgmtable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, regulations 40 CFR 262, 263, 264 and 26S may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15, 40 CFR 116 The material contains the following ingredient(s) which is consideredhazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline HAZARDOUS MATERIALS TRANSPORTATION ACT, 49 CFR 172 The material contains the following ingredient(s) which considered hazardous if spilled while being transported commerce. Ingredient Reportable Quantity Not Applicable is in FOREIGN REGULATION CANADIAN HAZARDOUS PRODUCTS ACT (WHMIS) The material is a WHMIS Controlled Product Canadian MSDS is available. and a STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 19S6 ("PROPOSITION 65") The material contains ingredient(s) known to the State of California to cause cancer, birth defects or other reproductive harm. Read and follow label directions and use care when handling or using all petroleum products. Ingredients Benz ene PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT To the best of our knowledge the material is not sold or produced in Pennsylvania. Please notify us at the telephone number noted below if the material results in Pennsylvania commerce. MOD 000023358 06-May-89 Conoco Material Safety Data Sheet Page 9 MSDS No: GASCOOdo The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, ir good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THt MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS 89/05/06 Env. & Qcc. Health Conoco Inc. PQ Box 2197 Houston, TX 77252 713-293-5550 Services ,,0009