Document g2pVz8QvLOjdYz3wEBDx3Gx4e
AR226-0335
VAPOR PRESSURE
TEST SUBSTANCE
Identity:
UN1-E4t6h4y,lpEeFrfOiSuoAr,ooEcttaPnOeSsAu,lfFo-n6am3i0d9e,;ormaFXy-1al2s.o
be (1-
referred
to
as
hOecpttaandeescualfflouonraom-iNd-ee,th1y,l1-,,2.C2,A3S,3.#4,441,551,5-,560,63,)7.7.8,8,8-
9Re9m%arbkasse:dMoatneriinaflorimsaatiwohnitsuepspolliied.d RbeypoSrptonsstoart'ess rtheaptressaenmtpalteivpeu.ritTyhies lot
number was not recorded.
M0 MEeTHmOoD00000000
GMeLtPho(dYI:N):OEYCeDs104, Dynamic Method
v
YReeamrarckosm:pleted: 1998
"TWhheilfeoltleoswtiinngg qtuesotteitfermo, mthteheaitresctonredpeonrstedrewscarsibuessetdheinopnllaycteesotf dweavtieartion:
ocuornd(eAnSsclerCobrepcoaruastieoonf)icouwrrmeenlttsicnigenptoiifnictokfntohweletdesgteiatenmd. uTndoerthsetabnedsitngo,f
tthaiksednefviraotmiotnheshteosutldrephoarvt)e.no effect on the outcome of this test." (Quote
RESULTS
V0.a0p4o7,r 0P.r1e4s2s,u0r.e2:38T,haendva0p.o3r95prPeas,surreesspeactti1v0e,ly20b,a2s5e,daonndt3h0eiCncwreearseing Dpreecsosmuproesrietgireosnsi(oynese/qunaot/iaomnb.iguous): Not noted dReecmraerakssi:n.g Tprheesseusrteimcaotnedditviaopnosrdpifrfeesrsbuyre2s0ftoor2t4he%.increasing and
conclusions The vapor pressure as determined with the dynamic method was raesgsruemsseidontoeqbueat0i.o1n4.2 Pa at 20C based on the increasing pressure
DATA QUALITY
006007
qRuealliiatbyiltietsyt:ingK.iimHioswcehverarn,kitnhge
= 2. 99%
This study purity may
meets not be
aclortrheectc,riTtehriea
for value
ewnaosuagshsidganteadpobiyntNs)M. R which is incomplete. Possible non-linear plot (not
REFERENCES
SDutluudtyh,coMnNd.ucted at the request of 3M Company by, AScl Corporation, OTHER SStu.bmPaiutlt,erM:inne3sMotCao,m5p5a1n3y3, Environmental Laboratory, P.O. Box 33331, Last changed: 5/16/00
006008
r! EAY.
ASSeSuRdeypIoD##054053-0.V0P4R5.0M1
oR NA
STUDYTITLE
Fx-~ (a .
Determinationof Vapor Pressure Curve by Dynamic Method for U1464 (ET POSA)
coe
DATASTANDARD
OECD Guideline 104, "Vapor Pressure Curve, Dynamic Method"
as
Mike Signorelli
Linda Christensen
`Phillip Marquis
STUDY COMPLETED November 6, 1998
TESTING FACILITY
EAnSvcilroCnomrepnotraaltiToens/tiAnSgclD-iDvuilsuitohn
:
4444 Airpark Boulevard
Duluth, MN 55811-5712
Tel. No. (218) 722-4040
STUDYIDENTIFICATION NUMBERS
:
AScl Study ID# 5030-045-01*
3M Company Environmental Technology and Safety Services
Sponsor Study ID# U1464
stTuhdiysisstkuedpyt roenpofritlecoatntAaSincsI-toDtEalTDof.26 pages. The raw data package (34 pages) supporting this
Sponsor Say ID# 14st
!
006009
) Sh
ASAeSlelSuRdepyor1tDI#43S0-3V0P..04R5.a0l1
Page 2
PTroactthiecebersetguolfatmiyonskn(o1)w.ledge, tis study was conducted in accordance with OECD Good Laboratory
ASC Study Director ~
Name (signed):.
i
8.
Namie (typed):
i
:
`SponsorSudy DF rast
; 006010
.
AASSeSuRuedpyorItDFAASOS3V0P-0.4R5.I0M1
Page3
STAOTFQE UALIMTYAESSUNRANTCE ps"rTeohfceleesdctuiurodenysoadfanttdahgewueriradewelrdieantveais.euwseTedhdetbyotyctpohenesdAouSfcctalutdhQiiutsassliptteuyrdfyAowsrsemureredafnfocolerloUthwniiestds,ttaoundaydstsauhrreselrtiehsptaeotdrstiainnsdtahaerndafcooclpuleorrwaaittniegng table.
ASel "StuTdoyyfIADpuFd5ei0t30f.or045.01
[rbot
TT em
DateReportMeadstaogSeundenytDirector and | .
am
[tov| Dwsaimsp| mtiaomee|
AScl's Quality Assurance Unit Auditor
Name (signed):
. W[6l5F
Name (ypedy0 AlanMoso0 l 000000
Sponsor Study IDF Udss
006011
.or
AAsSeelSuRedpyorItD##054053-0.V0P4.5R.I0M)
Pag4e
TAOFBCONLTENETS
COVERPAGE ett ieteeeheeeeeeeeeeee
CERTIFICATIONOF GOODLABORATORY PRACTICE COMPLIANCE ...... .......2
STATEMENTOF QUALITY ASSURANCE ............c.cooouinni.n..3.
TABLE OF CONTENTS . oii
eet eee eaean 4
10 INTRODUCTION... ..iiittite iia einaieaeaennannnnnn. 8
20 TESTMETHODS ..............cccouinianeniiniiiieiiii8i 3.0 TREATMENT OFRESULTS ...............c.coooeieoneiii.i1o0 ' 40 RESULTS ANDDISCUSSION ...................................10
5.0 CONCLUSIONS...
ieee eee 1]
6.0 DEVIATIONS FROM APPROVEDTEST PROTOCOL .................... 11
70 REPORTSIGNATURE............c.ccoueieinniensineen1n2
TABLE 1.
TABLE 2.
Toluene (Reference Item): Boiling Points (T) and Corresponding. Vapor Pressures (p) 2
Toluene (Reference Item): Boiling Points (T) and Corresponding Vapor Pressures (p)
at DecreasingPIESSUTE . . oy. vuueneenennnanennnnnnnnn..1.4
TABLE 3.
Toluene (Reference Item): Estimated Vapor Pressures (p) at Different Temperatures (T)Determinedfrom EQUation 1 ....................000uen...l.S
| TABLE 4. (TTo)luDeenteer(mRienfeedrenfcreomIEteQmU)A: UOENsti2ma.ted+V.a.po.r Pr+e.s.su4revs (ap)rateDnifsfernennt`Tnemnpnernatsur.e1s.6
SponsorSudy IDF U4s4
006012
.
Tableof Contents (cont.)
AAS501SRuedpyorItD410308350:.V0P4R5o.01
Pag5e
TABLES.
TABLE.
TABLE?7.
aRnadnEgEeCo-fLaVbaoproartoPrreysIsnutreerVcaolmupeasrifsoornTToelsuteinneg.PbryogthreamDsyna(4m) ic. M. e..th.o.d.f.r.om..O.E.C.D 17
ERTISPIIOGPSRACS(STUeTsEt
Item): +
+
Bot ilingePoei(nT)stanesdyCocrreespnonading
Vapor
Pressures(p)
at 18
ETPOSA (Test Item): Boiling Points (T) and Corresponding Vapor Pressures a
DecreasingPressure emer tt tt tater ett ra aa trasnrranas 19
TABLE 8. DEetTePrOmiSnAed(TfersotmItEeQm)U:AOENsti3ma- t.e.d+V.a.po.r ov uveieenen see Pressures (p) at Different Temperatures mM 20
TABLES.
ETPOSA (Test Item): Estimated DeterminedfromEQUAtion 4 . ..
V. aoporoPre.susuereesu(np)eaet rDinff.erei nt Teemp. erat.ure.s (2T)0
TABLE 10. ETPOSA (Test Liem): Responsibilities, Signatures, and Initials ofKeyPersonnel
Tnvoinlthve Setudyd... .......... Ln
`
FIGURE 1.
FIGURE 2.
FIGURE 3.
FIGURE 4.
A Representative Plot of Log P (Pa) and 1/T (K) Toluene at Increasing Pressure . 23
A Representative Plot of Log P (Pa) and 1/T (K) Toluene at Decreasing Pressure . 24
PAIERSeSpUrIeCsento ativeo Plot ot f Log P (Pa) eee easel.25 and I/T (K) ET POSA atIncreasing
A Representative PlotofLog P (Pa) and 1/T (K) ET POSA at Decreasing Pressure 26
RAW DATAPACKAGE
APPENDIX A. APPENDIX B.
APPENDIX C.
APPENDIX D.
Approved Study Protocol #045-VP.P3M and `Amendments Test Item Information
Test Item Receipt and Usage
Raw Data Sheets
#
v
SpoSudny sD1oUtres
006013
\
AAScSSuRedpyorItD#0#45053:0V-P0.4R5S.0M1
Page 6
STUDY SYNOPSIS
"Title:
(DeEtTerPmOiSnaAt)ion of Vapor Pressure Curve by Dynamic Method for U1464
Test Method: ~~ Dynamic method as described in' AScl Protocol 045-VP.P3M
Key Findings:
1)
The estimated vapor pressures Pat 20C; and 0.239 Pa and
of the 0.293
test item, ET Pa at 25C.
POSA,
are
0.142
and
0.176
.
StudySponsor
Company:
3M Environmental Technology & Safety Services
935 Bush Avenue
BStu.ilPdaiunlg, 2M-i3nEn-e0s9ota 55133-3331
Study
Representative: Dr. Rich Purdy
|
Ecotoxicologist
Phone:
(612) 778-5379
|
Fax:
(612) 778-6176
:
Testitem
Trade Name: ET POSA. Lot/Batch Number: FCI2 from John Eberlin 3/12/98.
`Sponsor Study Identification Number: U1464
Molecular Formula: CyF;,SO,NCH,CH;
.
Chemical Abstract Service Registry#/Code#: TradeSecret
Physical Description: White waxy solid
Percent Purity (%
Representative.
active ingredient):
99%
Based
on
information
supplied
by
Sponsor's
Sponsor Study IDF Utd
006014
.
Stability Data: Stable at room temperature. Storage Conditions: Room temperature in darkness.
ASAeSlelSuRedpyorItDJ4O5403S0-.V0P45R.O0M1 Page 7
Company:
ASC Study Director: `Phone: Fax:
EAnSveilroCnomrepnotraaltiToens/tAiSncgl-DDiuvlisuitohn (AScl) 4444 Airpark Bivd Duluth, Minnesota 55811-5712
Linda Christensen (218) 722-4040 @18) 7222592
ReferenceItem
`Trade Name: Toluene. LovBatch Number: 8608KTMH. CAS Registry#/Code#: 108-88-3. Percent Purity: 99.9%. Source: Mallinckrodt. Date Container Opened: 4/3/98. Study Initiation Date: 3/30/98.
`Experimental Dates
: N
DVeatpeorrmiPnraestsiuorne.of
413198
4/8/98
.
LocationRawData and FinalReport
Certified copies completed, after
will be which,
archived a testing facility for the Sponsor will be contacted
ftiovedeyteearrmsinferofmurtthheerdadtiseptohsietsiotnudoyfiasll
records.
SponsorStudy IDK 14s
006015
.:
ASAeSlelSRuedporItD44054053-0V-P04R5I0M1
Page 8
1.0 INTRODUCTION
hCahzeamridcs.al Tshubestaasnsceesssmiennttroodfuceendviirnotonmtehnetaelnvfiartoenamnedntefpfreecsteontf tpohteesnetisaulbsdtiasnpcoessalisanrdequriereendtrbyy
various governmental agencies. pressure of a substance. In this
Accordingly, one of the experiment, the test item
tests is to determine the vapor boiling point is determined at
a
desired pressure and then vapor pressure and boiling point are correlated.
`The vapor pressure oaf indicates the probability
substance is an environmentally relevant property because (1) of phase transition, volatilization (liquid/gas) or sublimation
it
:
(solid/gas), behavior of
of a chemical, chemicals, (3)
(2) it helps substantiate predictions chemical vapor pressure and water
regarding solubility
the environmental allow for the
calculation of chemical volatility `whether photochemically induced
from an aqueous degradation can
solution, and be determined
(4) in
it is useful in deciding the homogenous gas
phase or in an absorbed phase (OECD 1993).
2.0 TESTMETHODS
2.1 Glassware. All glassware employed were cleaned before use by performing the following:
n "Washed in hot detergent water and rinsed three times with warm tap water.
2)
Immersed in 10% HNO, acid bath and then rinsed with deionized water.
3
Rinsed three times each with acetone followed by hexane.
All glassware identification.
used
were
labeled
with
the
relevant
information
required
for
proper
22
Testitem. Thetest item,
were received at AScl on
ET POSA,
March 27,
material safety
1998. The test
data
item
sheets,
was in
and
one
gcelratsisfibcoattteleofanadnalwyassis
isttoermedisatdersocroimbetdemeaprelriaetruirne
in darkness this report.
as In
received. this test,
All relevant information about 13.39 g of test item was used.
the
test
2.3
ReifnfeorremnactieoInteabmo.utRtehaegerneftegrrenacdee
toluene was used item is described
as a reference chemical. earlier in this report. In
All this
relevant test, 35 ml
of
:
reference chemical was used.
2.4 TestApparatus. The test system consisted of:
n
5-L Ballast bulb to vary pressure in double-neck distillation flask.
Sponsor Study IDK 1464
006016
`
AASSecSuRedpyorItD #O5A0S3-0V0P.4R5.O0M1
Page 9
2) Closed-tube mercury manometer to measure pressure.
3)
100-m double-neck distillation flask.
4. Cinentthiegdriasdteiltlahteironmofmleatske.r, + 0.2C, with one hole rubber stopper to fit
5) Reflux condenser.
0) Heating element.
:
7 Vacuum pump.
8) Aspirator.
9 Boiling stones.
10) Nitrogen cylinder.
25 DandertefeererncemoitfieVmnaspwaoarstPraesisfsooulrlneo.ws:The procedure to determine the vapor pressures of test
n
Pthliarcdedthtehfelaistkemvoilnudmoeu,blaen-dneacdkdedidsttihlrleaetiotno
flask four
at a volume about boiling stones.
one-
I)
Flanged test system together and in the system was adjusted using
purged it vacuum.
with
nitrogen.
The pressure
3)
Heated that is,
the item gradually until when a constant boiling
temperature temperature
equilibrium was found.
was
reached,
4
At @n
this point, C).
recorded
total
pressure
(in
mm
Hg)
and
boiling
point
T
5) Fnoerwattotlaelasptrefsisveurdeisffaenrdentbopirleisnsguproeisn,tisnwcrheeanseedqupirleisbsruiraewaenrde rreecaocrhdeedd.
.
6
To obtain the second set pressure was lowered.
of
data,
recorded
total
pressure
and
boiling
point
as
the
Sponsor SudyY IDI Lass
006017
.
ASAeSlelSuRedpyorItDJ40540S-3V0P-.04R5O0M1
Page 10
3.0 TREATOFMRE ESN ULT TS
F`mourlteiapclyhindgattaheseotbwsietrhvetdestmialnldimreetfeerremnecrecuirteymsp,retsostuarlepwreistshur1e33w.a3.s
converted to Pa unit by Similarly, the boiling
`opfoitnotta(lT)prwesassurceon(vPear)tevds.to(I/TK) bfyroamddtihnegi2n7d3iv.i1d5uatlodtahteaosbestserwveerderCegbroeislsiendg tpooidnetv.elTohpethleog
`ivtaepmorweprreessduerteercmuirnveeds aftor1e0acCh, i2t0em.C,V2a5poCr,parnedss3ur0esCfoursitnhge atpepstroiptreimataendlintehaerrreefgerreenscsei.on
`equations.
4.0 RESANU DDIL SCUT SSIS ON
RefeItreme:Tnolcueene
The
and
observed data obtained for
2, respectively for toluene.
iTnchreeacsailncgulaantdeddercergeraessisinogntchuerpvreesssfurroematrheesphlootwtnedincuTravbelse,s
1
Figures 1 and 2, are:
Increasing pressure:
logp = 1027-1994 IT) (1) r=-099,n=5
Decreasing pressure:
:
logp = 10352023 (IFT) (2)
r=-099,n=5
`eTshteimtawtoeddvataaposrelpsraersesusriemsilaatr1a0n,d20h,av2e5,coarrnedla3t0ionCcaoreeffliicsiteendtsingrTeaabtleerst3haann0d.4995f.or tThheetwo
toluene data sels. dynamic method
Table 5 lists the range of vapor from interlaboratory comparisons
pressure (4).
values
determined
by
the
:
The toluene vapor pressures interlaboratory comparisons.
determined from equation 1 are within The values determined from equation
the ranges listed for 2 are slightly lower
the at 10
and 20C.
established
The vapor pressure for
in the protocol (2.93.1
toluene at 20C (2.8 X
X 10 Pa). The vapor
10 Pa)
pressure
is lower than the criterion
for toluene at 10C
`(p1ro.bXl6em1o0ccuPrar)edis wliotwherthtehasnysttheemcarsitterhieopnrsetsastuerdeiwnarsefdeecrreenacs4eed.(1.T7o-1.g8etXth1e0t3olPuae)n.e tAo boil
as the pressure was `whether this would
decreased, more have affected the
boiling chips temperature
were added and pressure
to the item. It measurements.
is
not
clear
SponsorStudyIDF L464
006018
ASAeSlelStRuedpyorItD44O540S3-0V-P0.4R5O0M1
Page 11
pTrhoeviedxepedraitmaenctoamlpadreasbiglne ptoretsheanttreedphoertreedfoinr both increasing and decreasing pressures.
dreefteerremnicnein4g.
vTaphoerrpergersessusrieoncucruvrevsesaaprpeealrisnetaor
for
TI estteETmPO:SA
The and
7o,bsreerspveecdtidvaetlay.obtTahienecdalfcourlaitnecdreraesgirnegssainodn
dceucrrveeassifnrgomthtehperepslsoutreed
are shown curves of
in log
Tables p vs
6
(UT), Figures 3 and 4 are:
.
Increasing pressure:
rlo=g -p 0=9192,.6n4-=39554 (1/T) 3) Decreasing pressure:
rlo=pg-0= 9127.4n5-=35871 (IIT) @) `The estimated vapor pressures at 10, 20, 25, and 30C are listed in Tables 8 and 9 for the cteosntdiittieomn.s dTihfeferesbtyim2a0tetdov2a4poprerpcreensts.ures for the increasing and decreasing pressure 5.0 CONCLUSIONS
a`cTchuerpatlea,cesmteenatdyoftetmhpeertahteurrmeommeetaesrurienmtehnetsa.ppaTrhaetusplparcoevmeednttoofbethpeivtohtearlmionmeesttearblfiosrhitnhge test
aiptpermowxiamsatdieflfyeroennet tihnacnh tahbaotvoeftthhee bruebfbelrienngceteisttemi.temThine tthheecromlolmeecttieorn wfalasskp.lacTehde
thermometer for the reference item was placed in the neck of the collection flask.
Based 25C,
on the increasing pressure and 30C were 0.047 Pa,
regression 0.142 Pa,
equation, 0.239 Pa,
tahnedv0a.p3o9r5prPeas,surreesspeactti1ve0lyC.,
20C,
6.0 DEVFRI OMAA PPRT OVEDI TESO TPRN OTOS COL
"The deviation which occurred while conducting this study is:
ny `Wbheiclaueseteostfilngowtesmtelittienmg, ptohienatirofcotnhedetnessteritweam.s used in place of water condenser
`SponsorStudy IDF U1464
006019
AASSeelSuRdepyor1tD44O5A0S3-0V-P0R45I0M1
Page 12
`To no
etfhfeecbtesotnotfheouorutcucrormeentosfcitehnistitfeisct.knowledge
and
understanding,
this
deviation
should
have
7.0 REPORTSIGNATURE
Name (signed).
Name (typed):Linda Christensen
: (1/6/98
_
:
TReasbploens1i0b.ilities, signatures, initials, and names of key personn. el involved in this study are in
80 REFERENCES
1
Organization for Economic Cooperation and Development (OECD), 1993. OECD
Guidelines for Testing of Chemicals. OECD Publication Information Center,
`Washington, DC.
2)
Shoemaker, D.P. and C.W. Garland. 1962. Experiments in Physical chemistry.
McGraw-HillBook Co., pp. 162-163.
3) EOrngvainrioznamteinont DfoirreEctcoornaotem,icChCeomoipcearlastiGornoaunpdaDnedveMlaonpamgeenmten(tOECCoDm)m,itt1e9e97.. OECD NSeurmiebseorn1.PriOncEipClDesPorfinGcoipoldesLoabnorGaotoodryLaPbraocrtaitcoeryanPdraCcotimcpel.iance Monitoring.
`SponsorSwdy IDF 146s
006020
v
.
AAseSeSuRedpyorItDRFS53V0P0.45R.O01M
Page 13
TABLE." PTroelsuseunrees(R(epf)eartenIcnecrIetaesmi)n:g PBroeislsiunrge.Points (T) and Corresponding Vapor
[=n[vo [owe|70|row [ren | |Mewsitows
-
[
oOwbsrereveid TTemopemratmurne
--1
C o | T |e e se m T|w eno|e n wss]|[_oomoms|s| o [ oom oomn Te e5s0 ||woone ee |oaowwon ||
Sponsor SudyIDI U14es
006021
:
AScl Report #045-VP.RIM
Page 14
`TABLE 2.
PTroelsuseunrees(R(ep)feartenDceecrIetaesmi)n:g BPorielsisnugrePoints (T) and Corresponding Vapor
[ [=r [ emT T [vo or1e wo m n [we]| ||[ [ e wT wsee [Tm n eaoome wnT [wasmone | |e e wweeeenes ||oooomo wween]||
L 2 1 ew 1Ser| 0 | suis |oom |
rer
008022
.
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Page 15
TABLE3. T`Toelmupeenreat(uRreefser(eTn)ceDeItteerm)m:ineEsdtfirmaotmeEdqVuaatpioornP1ressures (p) at Different
to
} woo
[| VeorPeemeen | [ VeVappoorrPPrresosurme (GmamHigl) ) |
[ oxwe
|
Spontor Sudy IDJ U1des
006023
.
ASAeSlelSuRdepyorItD44054053-0V-P0.4R50a1M
Page 16
[e eee TT ree TABLE 4. `TToelmupeenreat(uRreefser(eTn)ceDeItteerm)m:ineEsdtfirmoatmeEdqVuaatpioornP2ressures (p) at Different
`Sponsor Study IDF tds
006! 024
oe '
Fe ASel Report #045-VP.RIM
Page 17
CeTerme] TABLE 5.
Range of Vapor Pressure Values for Toluene by the Dynamic Method from `OECD and EEC-Laboratory Intercomparison Testing Programs "@
ry
006025
.
A156uRyopar HoSsE RoM
Page 18
TABLE 6.
ET POSA (Test Item): Boiling points (T) and Corresponding Vapor Pressures (p) at Rising Pressure
ormTToem] [ome T ooTipo | reo [ vom | wen |
fm
LmTe me [ee | ewan |
||
| [o vT
ow
woew
Te|ws|ws
|weowr | wween || eweoss
| oom |
| |oomoann ||
Spoor Sy IDF Utes
006026
mi
Page 19
TABLE 7.
ET POSA (Test Item): Boiling points (T) and Corresponding Vapor Pressures
(p) at Decreasing Pressure
[~ owObe envedn Pree
[O "Obr servei d Tempeo rature n]1
[o " s | mame [[| [ e wae ww[ s |[w wwo oo[|e [aewsse[ i|||oooommm || 1 C Ts oToow oemw | wonee | wwness |oowwnn|]
reer i
006027
ASAeSlelStRuedpyorItD44O5I0S30V-P0.4R5O0M1 Page 20
TABLES. TEeTmpPeOrSatAur(eTses(tTI)teDme)t:erEmsitniemdatferdomVaEpqouartPiroenss3ures (p) at Different t -- o T I o E--E -- [ -- Va Pop e ano i r
Equatio3n -- Log Pa = 12.64:3954 (11)
`Example Calaulation
:
Log Pa = 12.64-3954 (1/T)
10C = 283.15
Log Pa = 12.64-3956 (1283.15)
Log Pa = 12.64-13.9643
.
Log Pa = 1.3263
.
Pa = lav Log (1.3243)
Pam 0.007
For mmHg = 0153..350=04.367X 107
`Sponsor Study IDF U1464
:
006028
.
SAllSuRedpyorIt1#0540350p04R530M1
Page 21
TABLES. = ETeTmPpeOrSatAur(eTses(tTI)tDeme)t:erEmsitniemdatferdomVaEpqouartPiroenss4ures (7) at Differeat
IT VaporPoss mi)
s T m e e e ] | vem exe
Equuion 4 = Log Pa = 12.45.3871 (1m)
Sponsor Study DW Usa
006029
.- :
Pepper AScl Report #045-VP RIM
Page 22
TABLE 10.
ET POSA (Test Item): Responsibilities, Signatures, and Initials ofKey Personnel Involved in the Study
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Page23
Figure 1. A Representative Plot of Log p (Pa) and 1/T (K) for Toluene at Increasing Pressure
425
4.20
4.15
4.10
405
=4.00 S395
3.90
385
3.80
375
| 000300 000305 000310 000315 000320 000325 0.00330
8
1T(K)
: Se sy 00 vie
.
.
STa R
Figure 2. A Representative Plot of Log p (Pa) and 1/T (K) for Toluene at
|
Decreasing Pressure
j
4.40
|
4.30
& 4.20 3=2d4.10
4.00
3.90
X
"
3.80
g
0.00295
&
i--
0.00300
0.00305
0.00310
IT (K)
0.00315
0.00320
0.00325
JJsepreorsyrei Pages
Figure 3. A Representative Plot of Log p (Pa) and 1/T (K) for ET POSA at Increasing Pressure
4.15
410
>
405
Q
4.00
a 305
<
83%
385
.
3.80
375
370
g 0002140 0.002160 0.002180 0.002200 0.002220 0.002240 0.002260
g
"
IT, K
{ P--
.
fsorherotosaimri
Page26
Figure 4. A Representative Plot of Log p (Pa) and 1/T (K) for ET POSA at Decreasing Pressure
420
|
4.15
4.10
4.05
T& 4.00
38S 395
3.90
3.85
3.80
@ 375
8
0.00214
2g
; mn st08vyi
#
0.00216
.
,
:
0.00218
0.0022
170)
0.00222
.
3 0.00224