Document eqQaMBrB157QawgJ8n18jwxm

(conoco) Interoffice Communication To Distribution Prom Tom Grumbles aw September 8, 1981 sublet HDPE MATERIAL SAFETY DATA SHEETS Enclosed are the final drafts for the HDPE Material Safety Data Sheets. These sheets will have the Conoco Chemicals product name, plant address and telephone numbers added when they are available. Very few changes were made on the first draft of the sheets. Please return any further comments you may have to me by September 28. Thomas G. Grumbles Distribution: Ken Mievre - PC Bill Groves - PC Dr. Massad - PC Larry Hubbard - Houston Bill Broddle -'PC Dr. Whetstone - PC Tom Williams - Houston Michele Malloy - Houston Susan Litzau - Houston. TIRAFT MATERIAL SAFETY DATA SHEET Conoco Chemicals 5 Greenway Plaza East P.O. Box 2197 Houston, Texas 77001 PRDDUi<^ID&h^iliAflDH^^T^ MANUFACTURER'S NAME Conoco Chemicals ADDRESS p 0 Box 2J97 . Houston, TX 77001. TRADENAME Conoco 1150 SYNONYMS High Density Polyethylene REGULAR TELEPHONE NO. EMERGENCY TELEPHONE NO. HAZARDOUSINGREDIENTST' BOILING POINT {F.} .VAPOR PRESURE(fimrH5'4 VAPOR DENSITY (AIR =- TV SOLUBILITY IN WATER N/A N/A N/A N/A SPECIFIC GRAVITY (HJ1 = D PERCENT VCLATILEBT VOLUME (%> EVAPORATION RATE f = ir MELTING POINT APPEARANCE AND ODOR Translucent Odorless Pellets MV mffEMT. I,l.cu.lm,- h--agSBSaai I I 111 Fill Tin '-."u. a): i =?>k11 r4 z'A u a i li mi ; a t f \} i- FLASH POINT (TEST METHOD) N/A AUTOIGNmON TEMPERATURE N/A 0.957q/cm^ N/A N/A 133 C w.yj.^agsas8saa EXTINGUISHING MEDIA SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION Water spray on dry chemical (Ammonium Phosphate Base) Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide^irritating fumes and smoke. Self-contained breathing apparatus should be CCR 000001838 HEflLmHAZnHEINFORMATION: FIRST AID EYES: if dust enters the eye, flush with large amounts of water. skin: N/A INHALATION: N/A INGESTION: Seek Medical Aid NATURE OF HAZARD PTES: This material is not expected to present a hazard to the eyes. ,, This material is not expected to present a hazard to the intact skin. sw": Molten resins will produce thermal burns. INHALATION: This material is not expected to present an inhalation hazard under normal use. This material is not expected to present an ingestion hazard. INGESTION: EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: CHRONIC OVEREXPOSURE: No adverse health effects are expectea to o'ccur witn exposure to this material. Irritation to the upper respiratory tract may occur with exposure to fumes or smokes produced when heating or burning polyethylene. THRESHOLD UNIIT VALUE (TLV) ACGIH: 10 mg/m^ nuisance dust TOXICITY DATA SX1N CONTACT: N/A EYEtONTACT: N/A INHALATION: N/A INGESTION: N/A CCR 000001839 vr ' V ; - ^ : CONDITIONS CONTRIBUTING TO INSTABILITY HEACiwirroimc^ INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZAROOUS DECOMPOSITION PRODUCTS Burning or heating to high**-temperatures weight composition products. may release irritating low molecular CONOmONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Will not occur.- SITIEOfflBHCPHaCEnUffiS^r-^' STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHWICALS N / A WASTE DISPOSAL METHQO May be disposed of in landfill regulations. in accordance with local, state or federal VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY in DETAIL): if dust is produced during handling of material an approved air-purifying respirator snould be used. EYE: Standard safety glasses or chemical goggles. * * GLOVES: General ly not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A CCR 000001840 L- .-r:HAZARD:CIASSIRCjSJIQW INFORMATION !MC0 HAZARD CLASS AMD NUMBS N/A US DOT CLASSIFICATION N/A UN NUMBER M/A EEC DANGEROUS SUBSTANCE CLASSIFICATION ADR CLASS NUMBER ea: special risks ano safety advice - CAS NUMBER 9002-88-4 :o USUAL SHIPPING CONTAINERS ^v TRANSPQEnflTIQN AND: STORAGE ELECTROSTATIC ACCUMULATION HAZARD STORAGETRANSPQRT pressure STORAGE TRANSPORT TEMPERATURE loading/unloading temperature - ; VISCOSITY AT LOAOING/UNLOAD1NG TEMPERATURE ' ` : " HANDLJNG. AND STORAGE MATERIALS AND. COATINGS suitable UNSUITABLE The acove aata is oased on testa ana exoenence whten Conoco oeiieves reiiaeie ana are suooited for informational ourcoses onty. Conoco disclaims any iiaoiiity for carnage or injury wnicn results hum tne use of the aoove aata ana nothing contained therein snail consorute a guar* antes. WARRANTY OF MERCHANTABILITY. or reoresentaoon (inducing freedom from patent Iiaoiiity) Oy Conoco with resoect to the caia. tne prooucr oescnoea. or tneir use for any soecfrc purpose. even if tnat ouroose is known to Conoco. CCR 000001841 DRAFT MATERIAL SAFETY DATA SHEET Conoco Chemicals 5 Greenway Plaza East P.O. Box 2197 Houston, Texas 77001 PRODUC^IDEKIIFICAnOKi NAME Conoco Chemicals REGULAR TELEPHONE NO. EMERGENCY TELEPHONE NO. ADDRESS P, 0. Box 2197 - Houston, TX 77001 TRADE NAME Conoco 1*070 SYNONYMS High Density Polyethylene .V * hazahoousinghedient^; 7 ^ r^ MATERIALOR:COMPONENT | HAZARD:DAW : L_ _ _ _ _ _ _ _ _ _ _ _ _ -I B0IUNG POINT ("F.J VAPOR -PRE5URE (mnr H*} VAPOR DENSITY (AIR t)- SOLUBILITY IN WATER APPEARANCE AND ODOR N/A N/A N/A N/A . SPECIFIC GRAVITY (HJL = 1) PERCENTVQLATILE- BY VOLUME (%) EVAPORATION RATE ( -=1) MELTING POINT Translucent Odorless Pellets 0.953g/cm3 N/A N/A 132 C i ivnm.'diMT-* FLASH POINT (TEST METHOD) N/A AUTDIGNIT10N TEMPERATURE N/A FLAMMABLE LIMITS IN AIR. % BY VOL LOWER N/A UPPER N/A EXTINGUISHING MEDIA Water spray on dry chemical (Ammonium Phosphate Base) SPECIAL RRE FiGHTING PROCEDURES UNUSUAL HRE AND EXPLOSION Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxideyirri tating fumes and smoke. Self-contained breathing apparatus should be wui n \1 enLei i iru luii f i ned space. 1 0000019A2 CCR FIRST AID EYES: HEALTHHAZARIIINFORMATION: If dust enters the eye, flush with large amounts of water. SKIN: N/A f INHALATION: N/A INGESTION: Seek Medical Aid MATURE OF HAZARD EYES: This material is not expected to present a hazard to the eyes. skin- This mater'*a^ is not expected to present a hazard to the intact skin. 5WN* Molten resins will produce thermal bums. INHALATION: This material is not expected to present an inhalation hazard under normal use. This material is not expected to present an ingestion hazard. INGESTION: EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: CHRONIC OVEREXPOSURE: No adverse health effects are expected to occur witn exposure to this material. Irritation to the upper respiratory tract may occur with exposure to fumes or smokes produced when heating or burning polyethylene. THRESHOLD LIMIT VALUE (TLV) ACGIH: 10 mg/m nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: N/A INHALATION: N/A INGESTION: N/A 1w CCR 00000X843 I CONDITIONS CONTRIBUTING TO INSTABILITY INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PRODUCTS Burning or heating to high'-temperatures may release irritating low molecular weight composition products. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Wi11 not occur. SPILLOffLEfllCPHQCEnUREStC-- ' STEPS TO BE TAKEN IP MATERIAL IS RELEASED OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHEMICALS N/A WASTE DISPOSAL METHOD May be disposed of in landfill in accordance with local, state or federal regulations. AiiiiliOI VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY in DETAIL): If dust is produced during handling of material an approved air-purifying respirator should be used. EYE: Standard safety glasses or chemical goggles. GLOVES:Generally not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A CCR 0000Q184-4 ^ :;.r i:'"HAZARD:CtASSIRCATIO^INFQRMATTQMi IMCS HAZARD CUSS ANO NUMB N/A US OOT CLASSIFICATION N/A UN NUMB N/A EEC DANGEROUS SUBSTANCE CLASSIFICATION > ADR CUSS NUMB EEC SPECIAL RISKS ANO SAFETY ADVICE - CAS NUMB 9002-88-4 : ;v:/. - USUAL SHIPPING CDNTAJNSS - STORAGE TRANSPORT TEMPERATURE THAMSPQRTATlOft AND STORAGE ELECTROSTATIC ACCUMULATION HAZARD STDRAGE/TRANSPORT PRESSURE LOAQING/UNLOAOING TEMPERATURE v ;: . VISCOSITY AT LOAQING/UNLOAOING TEMPERATURE ':: handling and storage materials and coatings. SUITABLE UNSUITABLE The acove caca is cum on tests arte exoenence which Conoco oe+ieves reiiac*e ano are succeed for informationaJ ourooses only. Conoco disclaims any (iaoi(y for 2amage or tntury whien results from me use of me above cata ano nothing contained therein snail constitute a guar antee. WARRANTY OF MERCHANTABILITY, or reoresentaoen (inducing freeoom from oatenc liaoiiiry) Oy Conoco with resoeci to the cats, me sroouc: oesenbed. or metr use for any soeerne ourpoae. even if mat guroose is known to Conoco- * CCR 000001845 DRAFT MATERIAL SAFETY DATA SHEET (conoco) Conoco Chemicals 5 Greenway Plaza East P.O. Box 2197 Houston, Texas 77001 PHDDUCTIDENTlFICflTIOMLr-.; MANUFACTURER'S NAME Conoco Chemicals REGULAR TELEPHONE NO. EMERGENCY TELEPHONE NO. ADDRESS P. 0. Box 2197 - Houston, TX 77001 TRADENAME Conoco DR 721 SYNONYMS High Density Polyethylene HAZARDOUS! INGREDIENTS' BOILING POINT VAPOR PRESUREjmnc Hg:) VAPOR DENSITY (AIR 1), SOLUBILITY IN WATER ODOR N/A N/A N/A N/A SPECIFIC GRAVITY (HJ1 =-1) PERCENT VOLATILE BY VOLUME (%) EVAPORATION RATE ( *ty MELTING POINT 0.964g/cm3 N/A N/A 136 C :ent Odoi si:! a1. s'1 m i w 111; a. t. u ^`sssaKaBlawgBBRSSBg FUSH POINT (TEST METHOD) N/A AUT0IGNIT10N TEMPERATURE N/A FLAMMA8LE LIMITS IN AIR. % BY VOL LOWER N/A UPPER N/A extinguishing: MEJIA Water spray on dry chemical (Ammonium Phosphate Base) SPECIAL RRE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide,irri tating fumes and smoke. Self-contained breathing apparatus should be WUl II if clllU! i ML LJI! f 1 llUli LpfiLE. i CCR 000001 fl4h FIRST AID ETCS: HEALmHflZflHfflNFOHIVIffnafC: If dust enters the eye, flush with large amounts of water. SKIN: N/A INHALATION: N/A ingestion: Seek Medical Aid MATURE OF HAZARD ETCS: This material is not expected to present a hazard to the eyes. This material is not expected to present a hazard to the intact skin. ' Molten resins will produce thermal burns. INHALATION: This material is not expected to present an inhalation hazard under normal use. ingestion* This material is not expected to present an ingestion hazard. EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: CHRONIC OVEREXPOSURE: No adverse health"effects are expected to occur with exposure to this material. Irritation to the upper respiratory tract may occur with exposure to fumes or smokes produced when heating or burning polyethylene. THRESHOLD LIMIT VALUE (TLV) ACGIH: 10 mg/m3 nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: N/A INHALATION: N/A INGESTION: N/A CCR 000001847 vr CONDITIONS CONTRIBUTING TO INSTABILITY REAcnvmrDAm-r INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PROOUCTS Burning or heating to higfrVtemperatures weight composition products. may release irritating low molecular CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Will not occur. * SPlLEOffLEBICPROCEDURE*^- STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHEMICALS N/A WASTE DISPOSAL METHOD May be disposed of in landfill regulations. in accordance with local, state or federal VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY IN DETAIL): If dust is produced during handling of material an approved air-purifying respirator should be used. EYE: Standard safety glasses or chemical goggles. GLOVES: General ly not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A 00 OOO C.C* 41 y 3 H ft I a IMCO HAZARD CLASS ANO NUMBS N/A UN NUMBS M/A HAZARD: CUSSlHCOTOff INFORMATION- US DOT CLASSIFICATION N/A SC DANGEROUS SUBSTANCE CLASSIFICATION ADR CLASS NUM8ER SC SPECIAL RISKS ANO SAFrTf ADVICE CAS NUMBS 9002-88-4 USUAL SHIPPING CONTAINERS STORAGE TRANSPORT TEMPERATURE TRANSPORTATION AND- STORAGE ELECTROSTATIC ACCUMULATION HAZARD STORAGE/TRANSPORT PRESSURE LOADtN&UNLOADiNG TEMPERATURE VISCOSITY AT 10A0ING/UNL0AQING TEMPERATURE HANDLING: AND STORAGE MATERIALS AND COATINGS SUITABLE UNSUITABLE The acove data is cased on tests ana exoenence wnicn Conoco oeiieves reiiaoie and are succtied for informational ourocses only. Conoco disoaims any Iiaoiiity for camage or injury wnicn results from trie use of the aOove aata and notmng contained therein snail constitute a guar* ante*. WARRANTY Gf MEPCHANTA8IUTY. or representation (including freedom from oatent iiaoiiity) oy Conoco witn resoect to the cata. the product aescnoea. or their use tor any soeafic purpose, even if mat purpose is known to Conoco. * CCR 000001849 DRAFT MATERIAL SAFETY DATA SHEET Conoco Chemicals S Greenway Plaza East P.O. Box 2197 Houston, Texas 77001 MANUFACTURER'S NAME rConoco Chemica,ls ADDRESS p c TRADE NAME Box 2197 - Houston, TX 77001 Conoco TO 10 SYNONYMS High Density Polyethylene REGULAR TELEPHONE NO. EMERGENCY TELEPHONE NO. HAZAHDOUSINGREDienS^i: BOILING-POINT (F.) VAPOR-PRESURE(mnrHg.) VAPOR DENSITY (AIR =* T) SOLUBILITY IN WATER APPEARANCE AND ODOR N/A N/A N/A N/A SPECIFIC GRAVITY (HJ = 1) nERCEMT VOLATILE BY V0tUME(%) EVAPORATION RATE { - IV METING POINT Translucent Odorless Pellets 0.950g/cm^ N/A N/A 130 C ll" " FLASH POINT (TEST METHOD) N/A .11.11111 ALif.d'fmi ~ AUTOiGNITTON TEMPERATURE ;;rr:',-d N/A FLAMMABLE LIMITS IN AIR. To BY VOL J LOWER N/A UPPEH N/A EXTINGUISHING MEDIA Water spray on dry chemical (Ammonium Phosphate Base) SPECIAL FIRE RGHT1NG PROCEDURES UNUSUAL FIRE ANO EXPLOSION Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide,irri tating fumes and smoke. Self-contained breathing apoaratus should be ^ 1 ` ---- CCR 000001850 CONDITIONS CONTRIBUTING TO INSTABILITY INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZAROOUS DECOMPOSITION PROOUCTS Burning or heating to high'.temperatures may release irritating low molecular weight composition products. CONOmONS CONTRIBUTING TO HAZAROOUS POLYMERIZATION Will not occur.- vie SPlUIQlTLEIUCFRQCEDURES^r STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHEMICALS N/A WASTE DISPOSAL METHOD May be disposed of in landfill in accordance with local, state or federal regulations. VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT respiratory (SPECIFY in detail): If dust is produced during handling of material an approved air-purifying respirator should be used. eye Standard safety glasses or chemical goggles. d GLOVES:Generally not required unless handling hot or molten resins. N/AOTHER CLOTHING ANO EQUIPMENT: CCR 000001852 'i- : ^.rxv- HAZARD^ CLASSIFICATION^INFORMATION IMCQ HAZARD CUSS ANO NUMBER US DOT CLASSIFICATION N/A N/A UN NUMBER N/A EEC DANGEROUS SUBSTANCE CLASSIFICATION >" ADR CUSS NUMBER SC SPECIAL RISKS AND SAFETY ADVICE CAS NUMBER 9002-88-4 USUAL SHIPPING CONTAINERS STORAGE TRANSPORT TEMPERATURE TRANSPOETTATlOfiAND: STORAGE ELECTROSTATIC ACCUMULATION HAZARD STORAGE/TRANSPORT PRESSURE LOAQING/UNLOADING TEMPERATURE viscosm at ldaoing/unloading temperature : HANDLING. AND STORAGE MATERIALS AND COATINGS SUITABLE UNSUITABLE The acova aata is sasea on tesa ana exoenenee whicn Conoco oeiieves reiiacte ana are succtied for imarmaoonat ourooses only. Conoco cadaims any liaoiiify for carnage or intury which results from me use of me aoove oata ano nothing contained therein snail constitute a guar* antee. WARRANTY CF MERCHANTABILITY, or reoresentanon (inciuotng freeoom from patent tiaciiiryj by Conoco with resoect to tne oata. me oroauct aescnbea. or their use for any soscmc cursose. even if mat purpose is known to Conoco. 4 CCR 000001853 DRAFT MATERIAL SAFETY DATA SHEET conoco Conoco Chemicals 5 Greenway Plaza East Houston, Texas 77001 MANUFACTURER'S NAME rConoco Chem. icals ADDRESS p G TRADE NAME Box 2197 - Houston, TX 77001 Conoco 2010 SYNONYMS High Density Polyethylene REGULAR TELEPHONE NO. EMERGENCY TELEPHONE NO. hazardous:ingredients? BOILING POINT (F.) VAPOR DENSITY (AIR -- 1)* SOLUBILITY IN-WATER APPEARANCEANO ODOR N/A SPECIFIC GRAVITY (HJ1 = 1} N/A N/A EVAPORATION RATE ( -1) MELTING POINT Translucent Odorless Pellets 0.960g/cm3 N/A N/A 134 C FLASH POINT (TEST METHOD} N/A AUTOIGNITION TEMPERATURE N/A FLAMMABLE LIMITS IN AIR. % BY VOL. * LOWER N/A UPPER N/A EXTINGUISHING MEDIA Water spray on dry chemical (Ammonium Phosphate Base) SPECIAL RRE RGHT1NG PROCEDURES UNUSUAL FIRE Awn FYPi.nsinN Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide,irri tating fumes and smoke. Self-contained breathing apparatus should be wu iii i I en LB! I IIU Cwl'l 1. i icu S pdLC . CCR 000001854 EYES: If dust enters the eye* flush with large amounts of water. SKIN: N/A INHALATION: N/A INGESTION: Seek Medical Aid NATURE OF HAZARD EYES: This material is not expected to present a hazard to the eyes. This material is not expected to present a hazard to the intact skin. ' Molten resins will produce thermal burns. inhalation: This material is not expected to present an inhalation hazard under normal use. This material is not expected to present an ingestion hazard. INGESTION: EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: CHRONIC OVEREXPOSURE: No adverse health effects are expecxeo to occur wren exposure to this material. Irritation to the upper respiratory tract may occur with exposure to fumes or smokes produced when heating or burning polyethylene. THRESHOLD UMIT VALUE (TLV) 3 ' ACGIH: 10 mg/m nuisance dust TOXICITY DATA SX1N CONTACT: N/A EYEtONTACT: n/A INHALATION: N/A INGESTION: N/A CCR 000001855 CONOmONS CONTRIBUTING TO INSTABILITY INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSmON PRODUCTS Burning or heating to high'-temperatures may release irritating low molecular weight composition products. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Will not occur.- STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHEMICALS N/A WASTE DISPOSAL METHOD May be disposed of in landfill in accordance with local* state or federal regulations. VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY IN DETAIL): If dust is produced during handling of material an approved ai r-puri tying respirator should be used. EYE: Standard safety glasses or chemical goggles. * GLOVES:Generally not required unless handling hot or molten resins. OTHER CLOTHING ANO EQUIPMENT: N/A CCR 000001856 IMCO HAZARD CUSS ANO NUMB N/A UN NUMBER n/a HAZARD:CUSSiRCAnOff INFORMATION* US DOT CUSSIRCATION N/A EEC DANGEROUS SUBSTANCE CLASSIFICATION ' ADR CUSS NUMB ESC SPECIAL RISXS ANO SAFETY ADVICE " CAS NUMB 9002-38-4 .' USUAL SHIPPtNG CDNTAiNS STORAGE TRANSPORT TEMPERATURE ELECTROSTATIC ACCUMULATION HAZARD STORAGE-TRANSPORT PRESSURE L0ADING/UNL0A0ING TEMPERATURE r. VISCOSITY AT L0AD1NG/UNL0A0ING TEMPERATURE 1 HANDUN6.AND STORAGE MATERIALS AND. COATINGS SUITABLE UNSUITABLE The acove cata is cased on tests ana exoenence which Conoco oeiieves rwiaoie and are suociied for informational ourooses only. Conoco disclaims any liaojiity for damage or injury wmcn results from the use of the aoove oata ana nothing contained (herein snail constitute a guar* antae. WARRANTY OP WSRCHANTABIUTY. or reoresentaoon {including freedom from patent liaoiiity) Oy Conoco with resoea to the oatau the product oescnoed. or their use for any soecrfie aumose. even if that purpose is known rp Conoco. CCS 00ia5? DRAFT MATERIAL SAFETY DATA SHEET conoco Conoco Chemicals 5 Greenway Plaza East P.O. Box2197 Houston, Texas 77001 _ .............. FLASH POINT (TEST METHOD) N/A AUT0IGNTT70N TEMPERATURE N/A FLAMMABLE LIMITS IN AIR. % BY VOL LOWER N/A UPPER N/A extinguishing: MEDIA Water spray on dry chemical (Ammonium Phosphate Base) SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide,irri tating fumes and smoke. Self-contained breathing apparatus should be .vuru--if eiiidimy LJiifiiieu S(jaLS.------------------------------------------------------------------------------------------------ CCR 00000185 8 FIRST AID EYES: If dust enters the eye, flush with large amounts of water. SKIN: N/A INHALATION: N/A INGESTION: Seek Medical Aid MATURE OF HAZARD EYES: This material is not expected to present a hazard to the eyes. This material is not expected to present a hazard to the intact skin. SH ' Molten resins will produce thermal burns. INHALATION: This material is not expected to present an inhalation hazard under normal use. This material is not expected to present an ingestion hazard. INGESTION: EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: CHRONIC OVEREXPOSURE No adverse health effects are expectea-to occur witn exposure to this material. Irritation to the upper respiratory tract may occur with exposure to fumes or smokes produced when heating or burning polyethylei THRESHOLD LIMIT VALUE (TLV) ACGIH: 10 mg/m^ nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: N/A INHALATION: N/A INGESTION: N/A 000001B59 CCR CONDITIONS CONTRIBUTING TO INSTABILITY INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZAROOUS DECOMPOSITION PROOUCTS Burning or heating to high*'temperatures weight composition products. may release irritating low molecular CONDITIONS CONTRIBUTING TQ HAZARDOUS POLYMERIZATION Will not occur. * - VIC 'Ht1* SPimOffLEAiCPHOCEDUHk^^JS-', ^ STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHEMICALS N/A WASTE DISPOSAL METHOD May be disposed of in landfill regulations. in accordance with local, state or federal VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY IN DETAIL1: If dust is produced during handling of material an approved air-purifying respirator should be used. EYE: Standard safety glasses or chemical goggles. GLOVES:Generally not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A HAZARD: CtASSIRCATlOWINFOHIVIATIOM ^ 1MC0 HAZARD CLASS AND NUMBER N/A UN NUMBER N/A ADR CUSS NUMBER US DOT CLASSIFICATION N/A EEC DANGEROUS SUBSTANCE CLASSIFICATION *- EEC SPECIAL RISKS AND SAFETY ADVICE -CAS NUMBER 9002-88-4 : ;; V ,v. USUAL SHIPPING CONTAINERS T STORAGE TRANSPORT TEMPERATURE IHANSP0EfTATI0Pi AND: STORAGE ELECTROSTATIC ACCUMULATION HAZARD STORAGE/TRANSPORT PRESSURE L0ADING/UNLCAOING TEMPERATURE VISCOSITY AT LOADING/UNLOADING TEMPERATURE ..... ` ' I HANDUNa AND STORAGE NIATHB1ALS AND-COATINGS. SUITABLE | UNSUITABLE : * The acove cata is Oased on tears anc axoenence wmcn Conoco oeiievea reiiaoie anc are suociied for mToimaoonai ourcoses only. Conoco disclaims any liaoiiity tor Carnage or tniury whicn results from the use of the aoove data and norning contained therein snail consotute a guar antee. WARRANTY OF MERCHANTABILITY, or reoresemation (inciuaing freeoom from patent liaoiiiryj Oy Conoco wicn resoect to the data, trie oroouct sescnoed. or tnwr use for any soecrfic purpose, even if that ournose is known to Conoco. OOOOOXS61 CCR DRAFT MATERIAL SAFETY DATA SHEET (conoco) Conoco Chemicals 5 Greenway Plaza East P.O. Box 2197 Houston, Texas 77001 mpiucpo^ MANUFACTURER'S NAME Conoco Chemicals ADDRESS P. 0. Box 2197 - Houston, TX 77001 TRADE NAME Conoco 2003 SYNONYMS High Density Polyethylene REGULAR TELEPHONE NO. EMERGENCY TELEPHONE NO. HAZARDOUS INGREDIENTS' ;'' MTT^rsgg*s^^ 80IUNG POINT (F.) VAPQR.PRESURE(mni Hg;) VAPOR DENSITY (AIR -- 1) SOLUBILITY IN WATERAPPEARANCE AND ODOR N/A N/A N/A N/A 1 hh'w-gaBga^isgl SPECIFIC GRAVITY (H.a = 1| "| 0.957q/on3 PERCENT VOLATILE _____________ BY VOLUME (%> EVAPORATION RATE f = 11 MELTING POINT N/A N/A 134 C Translucent Odorless Pellets EXTINGUISHING MEDIA SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION N/A | Water spray on dry chemical (Ammonium Phosphate Base) Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide,irrirating fumes and smoke. Self-contained breathing apparatus should be ooooo 1&&2. CX* FIRST AID EYES: If dust enters the eye, flush with large amounts of water. SKIN: N/A INHALATION: N/A INGESTION: Seek Medical Aid NATURE OF HAZARD EYES: This material is not expected to present a hazard to the eyes. This material is not expected to present a hazard to the intact skin. * Molten resins will produce thermal burns. INHALATION: This material is not expected to present an inhalation hazard under normal use. This material is not expected to present an ingestion hazard. INGESTION: EFFECTS OF OVEREXPOSURE; ACUTE OVEREXPOSURE No adverse health effects are expected to occur wren .exposure to this material. Irritation to the upper respiratory tract may occur with exposure to fumes or smokes produced when heating or burning polyethylens. CHRONIC OVEREXPOSURE: THRESHOLD LIMIT VALUE (TLV) ACGIH: 10 mg/m nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtDNTACT: n/A INHALATION: N/A INGESTION: N/A CCR 000001863 VT ~ CONDITIONS CONTRIBUTING TO INSTABILITY HEflanvmrDflmr? INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PRODUCTS Burning or heating to high'-temperatures weight composition products. may release irritating low molecular CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Will not occur.* STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHEMICALS N/A WASTE DISPOSAL METHOD May be disposed of in landfill in accordance with local, state or federal regulations. VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY IN DETAIL): If dust is produced during handling of material an approved air-purifying respirator should be used. EYE: Standard safety glasses or chemical goggles. GLOVES:Generally not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A CCR 000001864 ^ -.-77;- HAZARD: CIASSJRtrATIQrf INFORMATION IMCO HAZARD CLASS ANO NUMBER N/A US DOT CLASS1BCATT0N N/A UN NUMBER N/A | EEC DANGEROUS SUBSTANCE CLASSIFICATION > ' ADR CLASS NUMBER SC special risks ano safety advice - CAS NUMBER 9002-88-4 : ---Tr - USUAL SHIPPING CONTAINERS ^ tv- THANSPGOTATJQN ANO. STORAGE ELECTROSTATIC ACCUMULATION HAZARD STORAG&TRAN5POHT PRESSURE storage TRANSPORT TEMPERATURE LQAQ1NG/UNLQADING TEMPERATURE VISCOSITY AT LOADING/UNLOADING TEMPERATURE ' 7` 7 HANDLING AND STORAGE MATERIALS ANa COATINGS SUITABLE UNSUITABLE : The acove aata is aasea on tests ana experience wnicn Conoco owieves reiiacie ano are succiiec for informaoonai purposes oniy. Conoco discaims any liability for damage or injury wnicn results from tne use of cne aoove data ana notnmg contained tnerem snail constitute a guar antee. WARRANTY OF MERCHANTABILITY, or reoresentacon fincucing freedom rrom patent liaoiiicy) by Conoco wim resoect to tne cata. tne orcaucr aescnbec, or tnetr use for any soecrfic purpose, even if cnat ouroose is known to Conoco. CCR 000001365 " DRAFT MATERIAL SAFETY DATA SHEET Conoco Chemicals 5 Greenway Plaza East P.O. Box 2197 Houston, Texas 77001 MANUFACTURER'S NAME rConoco rCuhem. ica,ls AOORESS p Q TRADE NAME Box 2197 - Houston, TX 77001 Conoco 3001 SYNONYMS High Density Polyethylene REGULAR TELEPHONE NO. , EMERGENCY TELEPHONE NO. HAZARDOUS:INGREDIENTS | 11 fS-r- - . -|TT. VT `7a; --^*.^^3 J ! ^ <s (H M a i f ^ f^ - 11 -11" wjjpmep BOIUNG POINT (F.) I ,' __ ____ _________ _________________ ILCA_______________ VAPOR-PRESUREdmn Hg;) N/A VAPOR DENSITY (AIR N/A SPECIFIC GRAVITY (HJ1. = 1} PERCENTVOLATILE BY VOLUME (%} EVAPORATION: RATE f = ir SOLUBILITY IN WATER APPEARANCE AND ODOR N/A 1 11 METING POINT " ......... Translucent Odorless Pellets 0.950g/cm3 N/A N/A 130 C -.. . , i FLASH POINT (TEST METHOO) N/A FLAMMABLE UMITS IN AIR. % BY VOL AUTDIGNITIONTEMPERATURE j LOWER N/A N/A UPPEB | N/A EXTINGUISHING MEDIA SPECIALRHE FIGHTING PROCEDURES Water spray on dry chemical (Ammonium Phosphate Base) Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide,irri tating fumes and smoke. Self-contained breathing apparatus should be wc FIRST AID EYES: HEAIIKHAZARIEINFaHMAnOH^; If dust enters the eye, flush with large amounts of water. SKIN: N/A INHALATION: N/A INGESTION: Seek Medical Aid NATURE OF HAZARD EYES: This material is not expected to present a hazard to the eyes. This material is not expected to present a hazard to the intact skin. SKW- Molten resins will produce thermal bums. INHALATION: This material is not expected to present an inhalation hazard under normal use. . This material is not expected to present an ingestion hazard. INGESTION: EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: CHRONIC OVEREXPOSURE: No adverse health-- effects are expected to occur witn exposure to this material. Irritation to the upper respiratory tract may occur with exposure to fumes or smokes produced when heating or burning polyethylene THRESHOLD LIMIT VALUE (TLV) ACGIH: 10 mg/m^ nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: N/A INHALATION: N/A INGESTION: N/A CCR 000001B67 CONDITIONS CONTRIBUTING TO INSTABILITY INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PRODUCTS Burning or heating to high'-temperatures weight composition products. may release irritating low molecular CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Will not occur. SPItEDKLEniCPHOCEnUREStS' STEPS TO BE TAKEN IF MATERIAL JS RELEASED OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHEMICALS N/A WASTE DISPOSAL METHOD May be disposed of in landfill regulations. in accordance with local, state or federal VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFYIN DETAIL): If dust is produced during handling of material an approved air-purifying respirator should be used. EYt Standard safety glasses or chemical goggles. GLOVES: Generally not required unless handling hot or molten resins. OTHER CLOTHING ANO EQUIPMENT: N/A 000001B68 CCR IMCO HAZARD CLASS ANO NUMBS N/A UN NUMBER N/A HAZARD: CLASSIFICATION INFORMATION' US DOT CLASSIFICATION N/A EEC DANGEROUS SUBSTANCE CLASSIFICATION ** AOR CUSS NUMBER EC SPECIAL RISKS ANO SAFETY ADVICE ^, ' CAS NUMBER 9002-38-4 USUAL SHIPPING CONTAINERS : TRANSPORTATION. AND: STORAGE ELECTROSTATIC ACCUMULATION HAZARD STORAGE/TRANSPORT PRESSURE STORAGE TRANSPORT TEMPERATURE U3A0ING/UNU3A01NG TEMPERATURE VISCOSITY AT LOAOiNG/UNLOADING TEMPERATURE HANDLING AND STORAGE MATERIALS AND. COATINGS- SUITABLE UNSUITABLE The acove cata is oasec on teats anc exoenencs wnten Conoco oeiieves reiiaoie anc are succiied lor informational ourooses omy. Conoco disclaims any liaoiiity for carnage or injury whtcn results from the use of the aoove oata ano nothing contained therein shall constitute a guar* antes. WARRANTY OR MERCHANTABILITY, or representation (including freedom from patent liaoiiity) Py Conoco with reseed to the data, the proouc: oesenbed. or thetr use for any soecnc purpose, even if that ouroose is known to Conoco. CCR 000001869