Document embY8Kp9qb66L3g2m3BdbNa6e
DATE: 28 January 1980
IN TURN:
DATE RECEIVE)
APPROVED INITIALS DATE
*F. F. EHRICH
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*J. C. WATTS
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A. M. KAPLAN, CRD - HASKELL LAB
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V. F. STAFFORD, CDP - B-10262
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J. S. THa CKRAK, CDP - B-17202
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APPROVAL REQUEST
' ' MATERIAL SAFETY DATA SHEET
Please approve the attached material. Any comments may be indicated in the te*t and initialed.
TITLE OF PIECE: Material Safety Data Sheet for _
ZINC YELLOW: Y-539-D '
TYPE (OBJECTIVE): New MSDS 'i : aliiiiiiii
(*) Those whose names follow the asterisk (*) above certify that the product and performance claims contained in subject material are accurate and that the files of the Chemical, Dyes and pigments Department contain data to support the claims. They further certify that any claims attributed to non-DuPont sources are Consistent with our knowledge and experience.
EPT/ilc 9/5/79
MATERIAL SAFETY DATA SHEET
IDENTIFICATION
Nam ZINC - POTASSIUM BASIC CHROMATE Y-539-D
Synonyms1. -.Pigment Yellow 36:1_ C.T. NO. chemiOai family Inorganic hexaVslent
ZZaei
Chromium Salt
CAS Name chromic Acid, Potassium Zinc Sait. CAS Registry No. 1344-37-2
Hydrate * _ I'D- Nos./Codes _N,iGg_Aees-s -Ho. GB~305GO0Q
Manufacturer/Qistributor
Product Information and Emergency Phone
Address
E. I. DU PONT DE NEMOURS CO. INC.
302-774-2421
WXUMXNCTON, DE 19898
Transportation Emergency Phone
HAZARDOUS COMPONENTS
800-424-9300
Material(s)
Approximate %
-Zinc-Po-tnoaium
A;
PHYSICAL. DATA
Soiling Point, 760 mm Hg
Melting Point
Specific Gravity 3.39
Vapor Pressure
Vapor Density
Solubility in HzO Soluble
% Volatiles byAtafc wt. 0.3 - Q.5 (+ 6.5% combine<tvaporation Rate (Butyl Acetate 1) waterl
Form
Appearance
Color
` Odor
pH Information 5.5 - 6.0
FIRi AND EXPLOSION DATA
Octanol/Water Partition Coefficient
TfW riJKtsonlyto the specific mxtarialdasignitad taH^nartd doe* not relate to use in combination withanyotharmaterjalorin any process. the
infortraUon ael forthhereinis tumlshedff^ot charge andiabased on technical datathrt Du Pombelievesto be reliabie. lt Is ta^ pam dlscrattonand rtafc.Slhbecondlttana ofuMereoutskta our control, wamaite no wamntia,0xptmorImpllad, and aasume no liabilityin connectionwithany useof this Information. Nothing herein iato be laktn aa a license to operate under or a recommendation to infflngi *ny patent*.
DUP050075142
N42350.01
HAZARDOUS REACTIVITY
Instability Stable
Incompatibility
Oecompositior Polymerization
|ot__a5cyr^ Will not occur,
re Svu ''tyfWUAJL,
HEALTH HAZARD INFORMATION
^^
Exposure Limits OSHA 8-hour t^afe weighted average (TWA) is 100 ug/m^ (as =fcr). ACGIB
TLV-TWA is 50
(a^Cr), with a paragraph A2 notation (Industrial Substances
Suspect of, Caxcinoeenic Potential for Man). -`OSHA/NICS'II 3CF"fc,uu al^Itmueiillately o^.
,
M|f' cguse canCey^jifirifi fim^undjaale*; -Sympteoi)^-*.... Has.*! and gogpina-twry
'HrttfTlriv *fytt "7ftrj cmtijurifttlvi
1 ret,
In caaS" "Of' c8ul^tSS^^ate4^rSrOT^
eaalnophiliyy - lcidneyri'(lvnr'"da'aage.
minutes. Call a Physician. Flush skin with water. If swallowed, induce vomiting immediately by giving 2 glasses of water and sticking finger down throat. Call a Physician. Never give anything by mouth to an unconsicous person.
PROTECTION INFORMATION
Ventilation Use only with adequate ventilation and dust containment to reduce air
concentrations to permissible exposure limits. Personal Protective Equipment
If exposure limits are exceeded, use OSHA- permissible respiratory equipment.
Other
such as high efficiency particulate respirator, air supplied respirator, etc.
DISPOSAL PROCEDURES Aquatic Toxicity Spill, Leak or Release Do not sweep.
Vacuum and Vet scrub.
Waste Disposal Comply with federal, state and local regulations. If approved, may be removed to licensed land disposal area or drained to chemical sewer.
SHIPPING PRECAUTIONS Transportation Not regulated as a hazardous material by Dept, of Transportation.
Shipping Containers Bags Storage Conditions Protect packages from breakage.
REFERENCES AND ADDITIONAL INFORMATION
Avoid contact with eyes, skin and clothing.
Wash thorough!ly after handling.
Change clothes after work if they may be contaminated; wash contaminated clothing
before re-use.
DATE:
EDUP050075143
ZIKC YELLOW Y-539-D
HEALTH HAZARD INFORMATION Statements are not supported by toxicity Information and are
submitted subject to Haskell Lab approval. L. P. THOMAS
LPT:DID
DUP050075144
N42350.02
CONTAINS ZINC CHROMATE
WARNING! HARMFUL DUST
ma y ^Ir r it at e 's k in a n d e y es ,
AVOID BREATHING DUST. USE ONLY WITHIN GUST CONCENTRA TION wIMIT PRESCRIBED BY OCCUPATIONAL-- SAFETY AND HEALTH ADMINISTRATION (29 CFR 1910.1000, AIR CONTAMI
NANTS). AVOID ' CONTACT WITH
SKIN, EYES AND CLOTHING. >VA3H THOROUGHLY AFTER HANDLING. IN CASE OF EYE CONTACT, FLUSH WITH PLENTY OF LATER FOR AT LEAST IS MINUTES, CALL A PHYSICIAN. FLUSH SKIN WITH WATER.
.... 'jn1""" I 1 *' " 1 '! . 'L ' i """'
HISCAN CONTAINS ASAMPLE
'H-tttm
ZINC YELLOW
PIOMENTS
Y*$39~D PS-83a09
rl>lMT*0 IH U, *. A.
E. I. DU Po n t d e Ne mo u r s & Co. (In c .)
Pigments Department
Wilmington* Delaware
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l d i t y* i ' ; I V
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if
~ < ! *
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35
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DUP050075145
N42350.03
I.S. BEfllTHENT OF UBOR
S' > T s
xs
& Health Administration
MATERIAL SAFETY DATA SHEET
SECTION 1
MANUFACTURERS NAME
"
"~
' ~"
EMERGENCY T|LEPHONENO
B. I. Du Pont de Nemours & Co.-Pigments Dept.
(302) 774-1000
"arket`"street'**Wlmlflgton, Delaware 19998
CHEMICAL NAME AND SYNONYMS
Smc Chromate
zTnDr^isr39-D
cm? ffiiromate
77955 - Pig.Yellow 36
SECTION II HAZARDOUS INGREDIENTS
PAINTS. PRtSCRVATlVES. ft SOLVENTS
V
pig men t s 2inc /..........................30.8
Chromium.....................23.5 Potassium____________. . .
VEHICLE
TLV (Unit.)
ALLOYS AND METALLIC COATINGS
See
BASE METAL
Sec. ALLOYS . 9.1__V____
METALLIC COATINGS
SOLVENTS
ad d it iv es
"o In W" .....it l i
"'iri '
FILLER METAC PLUS COATING OR CORE FLUX OTHERS
HAZARDOUS MIXTURES OP OTHER LIQUIDS. SOLIDS. OR CASES
TLV * (Unit*)
%
TLV (Unit.)
BOILING POINT (F.|
.
SECTION III
VAPOR PRESSURE lenmHs.l VAPOR DENSITY IAIN" 11
SOLUBILITY IN WATER
^r~~- 2 g./l.
a p p e ar a n c e a n d o o o r Dry powder - None
PHYSICAL DATA
SPECIFIC GRAVITY IHjO" tl
PERCENT VOLATILE-----BY VOLUME 1%)
EVAPORATION RATE 1 ' 11
.
.
--------
SECTION IV FINE AND EXPLOSION HAZARD DATA
FLASH POINT (Method usedl
FLAMMABLE LIMITS
EXTINGUISHING MEDIA
Water
SPECIAL EIRE LIGHTING PROCEDURES
None
Lei
UNUSUAL EIRE AND EXPLOSION HAlAFtOS
3.50
Uel
NOTICE FROM DU PONT
The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process.
DUP050075146
N42350.04
, SECTION. V HEALTH HAZARD DATA
t h r e s h o l d l imit v a h
time-wexgbted average limit for chromab
is A mg.gcr.JLO. g\ibic,,metera..aa....CrOHy..cited .ip 2, _EB.
t ticit or o v er ex po s u r e jjgy cause dermatitis - may irritate skin, eyes,
:nts nasal
passages and respiratory tract* Harmful dust for recent informa-
fciafr <?,p
i see June .1.3# 177 h... Istier.. from Dry Color.
Manufacturers' Association/ attached.
: Av13 breathing dust. Avoid contact with skin eyes and clothing. In case of eye contact:, flush with, plenty of water f&r at least 15 ftin.i call a physiciant flush skin with watef -----------
STABILITY
unst abl e
SECTION VI REACTIVITY DATA
CONDITIONS TO AVOIO
STABLE INCOMPATABIUTV (Matt'iah to Ovoid)
h a z a r d o u s d e c o mp o s it io n p r o d u c t s
HAZARDOUS POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
CONDITIONS TO AVOIO
X
\
SECTION VII SPILL OR LEAK PROCEDURES
"stirs tb BE TAKEN INCASE mWr UL IS AtUASe'o Oft SPILLIO Avoid breathing dust. Clean up - Use protective equipment - See special protection information (below)
WASTE 'DISPOSAL METHOD In accordance with Local, State and Federal regulations,
SECTION VIII SPECIAL PROTECTION INFORMATION
|
w s p w a t o iw p r o t e c t io n f5pw/r rp;
having NIOSH/MESA approval No. TC--21i!
.91.. TX-2.3C,,are.sug.qasiia4
VENTILATION
LOCAL EXHAUST yeg
SPECIAL
MECHANICAL (Ctnrtal) yes
OTHER
PROTECTIVE GLOVES
Yes
o t h er pr o t ec t iv e eq u ipmen t clothing
EYE PROTECTION
Yes - Glasses
SECTION IX
p r e c a u t io n s TO M t a x e n in h a n d u n c ANp s t o r in o
SPECIAL PRECAUTIONS store in clean , dry area - avoid
_________________________
breathing dust.
o t h er pr ec au t io n s ^gjj thoroughly before eating. Keep away from food
products-.
DUP050075147