Document e5vXNzBaorMZeYgmbXoyd4mEm
mn ROBERTV.GALANTE E S 3 escmtm ores 0e 7050
MEMO
FROM: Robert Galante DATE: 12-5-07
SUBJECT: Orange PFOS and PFOA
+Qo Uni3,ted Water
'
Sez
70: Betty Boros-Russo COPIES:
As discussed, here are the results. Let me know if you need anything else. Bob
E20
QCLaboratories UCD SACI XT Lol
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QC Laboratories
Analytical Report
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Tarn Mores
DEPZ.SDWB-000109
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oer?SoWB000110
TestAmeri2 ca
THE LEADERM4ENVIRONMENTALTESTING
AvALTIEAL eoRT
La4180we3
RECEIVED
WOEC -- 12 PM 2:34
oe
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PFOAIPFOS Analysis
ssn a0 aortas, Someren es
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Table Of Contents
Standard Deliverables
|
Report Contents
Total Number
of Pages
TShteCaonvedraLerttderDaenldithveeRerpaobrltCeoswrpagears consideredingral parsof his Sandor Dera package.Th report incomplete
[]
onaleposges indictend iTableofConaseenudse
Tableof Cantents + Case Narrative + Executive Summary - Detection Highlights
+ Methods Summary
+ Method/AnalystSummary Lot Sample Summary Analytical Results + QCData Association Summary
+ Chain-of-Custody
:
DEP2.SDWB-000112
!
Cas7e.2N6a0r2r9a4tive
| |
pTreesastcoAcnmoterarddiacninacehDewsnivrteeprtonrietzmweeatrsheoUdaSnsEaPnldyAzceaadlpepfdor.roivhDedipmaaeroatmhfeoatdcetsrorsissaatlnledad(nao5yni(c0haelsmweotarrhkeo.dpsTrhosovusmeamdmaporlnyeSspaacghe:
datasheet to assist in the interpretation of the results.
CaTothmaplrhleaasvnutelwsbirohloanltarebeoovnrilaeyowrteydtpfhroeortcsoaocmomlppslleiasnhcneatnwiyisherxetGpheoerpltiaoabnonrsdat1moer6ytdGaAbllKorGewCqupilraenmaenntdshoafvNeEfLoAuCn,d tAllbe
SPLlioemlaids(ehManDovLte)ebatenheadtnsNdhoronyv-iwDdeeitbgeohctctoc(onNmsDeic)diereerds.aulNtsDhaatvtehbeeMeDnLe.vaUluraitesd tdohwenr10ethneotMeedt.hoosduDlesteocrtion
This report shall not be reproduced excapt in ful, without the writen approval of the laboratory `TaSaomcpleeoolriingAnr1riivdaoolcpaunmrednctoeRendcoaslnamtphleeaancaloyatpilcaalnceelprsocecutrsr. Tshaempsalmepleecsewveerde1f0e2c6an0e7d,in good
condition at a temperature of 1.9C. No anom weraeel ncoiune ters ed during sample receipt.
|
S`(AtPnFaaOnlAdy)ai.rcadPssFaOnSdeIsrascowmamreerpcrieapalrpeodpuasriengdtnhedaccorfeordmsoofkutthoen.compound perfluorooctancic acd
Perfluoro-n{1,2,3,4-C.octancic acd was introduatctohde xtracton step andwasused as
an intemal standard for quantitation of PFOA. Perfluoro-1-(1,2,34-"CjJoctanalesulfonale was
|
PinRtOrSod.uced al the extraction step and was used as an internal standard for quantitation of
`TDSehanevmespral'mespElSxetOrpParDcetEsieNon-ntLeadCndi0nA0in1salAyrespiosrt was analyzed for the target anayt by TestAmerica
For water samples a 250 mi. aliquot of cach sample s acidfed with 1 mL of 6N HC) solton
i|
fsaciaannrmdatlptilvdtgeoieslsieu.xmptearEassacsctebehrddostuuagsrmhiptnolg0eusoi.lthisd5ip.pichkauearsdtsiienwdgiegxehmt,erttahhhceeatinnaoofnnleamtayaenilcdehsnshitaqeaunredeaxewrtidrhl,ahocpmtreswtiaihotnalora4nhloeylmxzlrce.aodcnotdfboiymnte.LitohnaMAendfoSlCt.1e.8hrTe he
MbTahlecehMeotfthQ2oC0dhSsBaalmmoapnplkledesissopfrioceesssaemdoremaagetn.t mii bo batches
Tlheermseptihkoedd wbiathnksuwtaosgnadotee lanedcptreapahreed 1weiptohreiancgh,
cEoancchanbiartacthioin lperveeplasroefdLwaibtohraatLoarbyoGroatnolrrylCSoantmrpolleSsawmeprleew(LiCiS).coTnhroelrHeicotvserfioesboafthtwbaotches.
DEP2.SDWB-000113
|
"ATnhaelyitnitceamlalCsotmamnednatrds:recofvore1r3Cy4 PFOS was below the lower contro mil in the method
ii
bdleatnekc,tiboontshfLorCSP'FsO,Sa,ndthaellstahmrpeleessamwpelreesrei-neQxtCrabcatecdhin73Q0C21b6a0t.chB7e3c0a8u0s5e6.theFosratmhpilsebsalhcahd, the
{
iblnatnekm,althsetalnodwacrodrnceecnotvreartyifoonrLC1S3,C4anPdFsOaSmpwlaesbLe2l47o8w6t6h3e-1loownelry.coBnotrtohlsmetistoifn rtehseulmlestahroed
reported.
`sTahmepmleetvhooldurmeeqsuuibrmeidttMeSd.IMTShDecaocucledpntoatblbeeLpCeSrfaonramleydtfeorreecfotvheerriebsatfcohr,wdouelefvoeilnssuifnfbicoitehnt
,
gbuaitdcehleisneps.rovide evidence that the laboratory is performing the method within acceptable
|
Noother anomalieswere observed.
.
I DEP2-SDWB-000114
JE EXESUC MMAU RY -T DetecI tionHV ighlE ights
anveren sevens sopserer owas ona
hmwioesn =
se SrEox en, cCohohtnma doemmoeewwwnn mo Im
BswErrion bbbmw iaseeasmns moe
jonIe w=
Cncoonmn Cha
oon oamhe
mWwEnn wi
b hmomm aiaE gcneen
|
fneoesrn
cw cchoeehoewmoolosol Iwwwmrbn mh pom Eean awnn
DEPz.SOWB.0011S
|
METHODS SUMMARY
pr26029
:
nRaETER
MAETyHTOIDCNL ePRmEoPDA.RATION
Lows us, veon,
DEN -12-0012
References:
ory oSpeevrearntinTgrenPtrocLeadbuorrea.tores, Denver, Facility Standard
DEP2.SDWB-000116.
METHOD / ANALYST SUMMARY
i
J--
i
seumersicas
nsrer
f5 r
om -ic-on12
sacuntine Bonners
onsen
|
References:
i
UE cSoemvmearnniofsronwtiosiasbtourrsetores, Desver, Fckiiey Standard
DEP SOWB-000117
SAMPLE SUMMARY Dameeass
HO 8 SANPLEN CLIENT SnipLs ID
bsawteeLep Tsnonee
395900m6, 000021 11224778866663312 9004 003 12786633
.
2100//2244//0077 0180::3300
10/24/07 10:30
wTooresc(si):rmsfo sde ne rid e lon ere Acin peta rig vk ftrsca ek.
eee
Roenps ebteenrset,stegi,re nowreeenpsdkf,cirr,, pin,gil.yes. te, prypreme,eiy,o ,ce ns,e, l, y egc,HE
DEP2.SDWB-000118
Laboratories
Client Sample 1: 124786631
i
mere.
DLaotte-SaSammpplleed#......:: 1D0I/I2246/002794-0090:130 WDoartkeORredceeriv#.e.d..: J109/02K6G/L0A7A Matrix.........: WATER
rep Date....: 10/29/07 Boalysis Date..: 11/01/07
! DPirleuptBiaotnchFac#t.o.r.:: 17302160
Analysis Time..: 18:38
Method... DEN -1C-0012
`reonnva.ngTER pros | sau3rcReoeorAoTEn. 134 pros
R0e.s02o7LT 0.0097 3 RpERCCORVNETRY 7ae
RuepmoRTING wus 0.010 wat 0010 ug/n RoEaCrOVsERY ((5500 -- 2200000)
o+STeEo(p5a) merry oekd Fe _
DEP2.SDWB-000119
Qc Laboratories
Client Sample I: 124786631
mie
DLaotte-SSaammpplleed......:: D10I/02246/002794-0090:130 WDoartke ORredceexiv.e.d...:: J1O0/K2G6I/A0A7
pPrreeppDBaattec.h.......:: 71310/80085/607 nAnaallyyssiios TDiamtee.::. 1161:/3019/07
Dilution Factor: 1
Method... DEN -1C-0012
Matrix.........: WATER
[T Fronr . ros
Resvir
LREaPOrRTING ours
0o.o0n20
00.00110 wwaalnt
`1su3maRooPaTRsO: 1304 PROS.
ERERCcOaVNERTY a8ss.
RpErCeOnVeEyRY ((5500 -- 2200007)
Bom (s) pr ------------
DEP2.SDWB-000120
Qc Laboratories
Clieat Sample 1: 124786632
pie
DLaotte-sSaammpplleed8......: 1D0I/J2246/002794-1000:230 WDoartke ORredceeixveKd......: J190O/K2L6/I0M7A
PPrreeppDBaattec.h.........: 1702/02291/6007 Ahnaaallyyseiiss TDaitme.e:: 1181:/5041/07
Dilution Factor: 1
Method. ........: DEN -1C-0012
Matrix.........: WATER
eA=RANSTER
oo
m0.s06u1r
ors
oon
RmEPrORTING wars 00.0000 uggn/
1su3R4soPcRAOTNE 134 P05
`sRErCcOVERY w"o.
LRocworvsk:Ry (G5o0 -- 220000))
HSoTeEg(aS) ey te et rt
-
|
DEP2.SDWB-000121
y
[--
|
Client cumple 1: 124706632
!
on
iRELoeoeet1-nSpaSmeapelnmeneea .re.l.rh: DTTE IooJra2a6err0eo2rr94-T0o0r2so WmTooorkntOmrodeereoem#.ke.e..: JJT9aOroKiLnIhgAaR Matrix.........: WATER
Bre
I --.
i -- =
wbx ee oa saas rns
p=
Ts m=
mNmE
mgIonye --po_mes-y
HE
Z
nT
: mEn.om
Dep Sows 000122
oc taoratories Client sample : LasrsGes-3
mie BDLeaoectpe-DSSaaemteppellesed....: |1 11D00I//I322586//00027780-10001320 WBbaoaatrlekveROireedceeDriev8v.ee.dr.::: J1110O//02G86U//00A77 Matebx.........: WATER || rDeielputbioan tpaceiedrt 1omeo masiyels Time. 1300
Method... bE -ic-oui2
srooansne s2fm6essopoorronss orzoe).a
soeroer aon sSm5sccmoeusray "
LsSmoovtorartoie uorrens BE apsrcosvme GGoo Zo5n0
DEP2.SDWB.000123
ac Laboratories
Client Sample T: 124786633
mene
LDoatt-eSaSmapmlpele..d...:: D1703/22640/20974-1000:310 WDoartke ORredceeriv.e.d...:: J109/02K6M/A0A7
PPrreepp DBaattceh.#.....:: 71310/80045/607 Annaallyyssiias TDaitmee..:.: 1117/:0035/07
Dilution Pactor: 1
Method.........: DEN -1C-0012
Mateix.........: WATER
rporwneTER eos
s0e.s0u63r olo12
wREaPOrRTING wars co.0o10 wuogn
`sumnooATS.
|
23C4 PFOA,
i
13c4 FOS
RpEECROcVEENRTY.
3 57
RLuacorvsERY
(50 - 200) (50 - 200)
|
DEP2.SDWB-000124
QC DATA ASSOCIATION SUMMARY Drsacoase
Sample Preparation and Analysis Control Numbers
i
sums mm memmwroren, mmaoris mwoers usm
wr mhmmmm oomm n-ee-oootns
2Ta0o2w106s0e
02 wWmr oomm sicconos
0TA2o2so6s0e
ws mmmmm oomm ziocoamn
072303006506
DEPZ.SDWB-000125
METHOD BLANK REPORT
mic
MClBieLnott-TSoakmp#l.e..4:: DR709226500209040-160 Work Order 4... JSAM Analysts Date..: 11/01/07 pprreeppDBaattec.h..#......:: 71300/22156/007 Dilution Factor: 1
Mateix.........: WATER Analysis Tive..: 17:01
reaosnnETER Pros
swssuur w
LREipaorRTING wars .o01o0 uagl/ll
women-o10-0012 DEN -1c-0012
s1u3RssogFnOTRE. | ous
eeRcET R@ECOVERY 3.
RperceovyERY ((s5o0 -- 220000))
|1 Csoambe)s:rr ls ming tofre cid | +Srga ney ee tco s.
DEP2.SDWB-000126
METHOD BLANK REPORT
mre
MC2lieLnott-LSoatmpl.e..#:: DR7T9K206400209040-056 Work Order ...: KAMRVIAA Analysis Date..: 11/03/07 PPrreepp DBaattec.h........:: 71310/80045/607 Dilution Factor: 1
PeraoannETER bros
mesuur
LReopaorRTING wars
ww
00.001100 uugg//LL
sumsosaTs 1T33c043 Pperoons.
REeCROcVaENRTY. 6a.
Rpercoevyery ((5500 -- 20000))
nCoors):ve rors fo in rdom ro i +Sareeerry esd vs.
Waerix.........: WATER Analysis Time..: 16:54
owemmio1n6-0012 BN -1c-0012
DEP2.SDWB-000127
LABORNTORY CONTROL. SAMPLE EVALUATION REPORT
mie
|i CLlCiSenLtott-Soarmpwl.e.d.:. R0270022650020900-160 Work Order ...: 393ATIAC pPrreepp BDaattee.n..#......:: 71300/22196/007 oAuaallyyssiiss TDiavtee....:: 1171:/1071/07
Dilution Factor: 1
Matrix... WATER
: | eeAoRnnsTER
pros
RpeacRocvEeNrTy 202022
RLEoCaOTVsERY G(3o9--1123000)
DeEoW n-1e003 DEN -1c-0012
`asucRssoaPnRTOEA i 1304 PROS
rEBsRcCoRvNeTsy a0.
RpeucosvERY ((5500 -- 220000)
Cooreesn)pee te gd 9 Fr ed 40 des pris.
1
DEP2.SDWB-000128
LABORMTORY CONTROL, SAMPLE DATA RERORT
me
C1l0i5eoLtot-LSoatmpl.e.f.l:: RD130225600020904-160WorkOrder #...: JSIATIAC Pprreepp DBaattceh..#.......:: 71300/22196/007 Booaallyyssiios DTaitme.e..:: 1171:/1071/07 Dilution Factor: 1
Matrix.........: WATER
PerroRnETER eros
wspiorew MEnAoSuURrED wats RPeacRocvEeNRTY MemHoD 00..220000 00..220053 vaafrt 01022 DDann 1106--00001172
s3u0RssoaParToE | en oes
RpEarccoaERY &a0
RLEmCMOrVmEsRY ((5500 -- 2200001)
| [merormos:---------- t pr aese--cr os--tpr--ic----"
DEP2.SDWB-000129
LABORNTORY CONTROL SAMPLE BVALUNTION REPORT
moc
.
C1l0i5enLtot-TSoatmp4l.e.f.:: DR7I3226900209040-160 Work Oxdex ...: JSITIRD PPrreeppDBaattec.h.......:: 17300/22196/007 AAnaaallyyssiiss DTaitme.e.:.: 1171:/3031/07 Dilution Factor: 1
Matxix.........: WATER
eEnnvETER Pros sTuaRcRsoGparToSn. 134 PROS
mPeEcRoCvEeNrTy 120087
LREeCtOVsERY 0(9--113200)) PcERoCvENeTy aa0
memwio-n1C0012 _ DEN -1c-0032 RLErCOtVsERY. G(5500 -- 2200000)
Coorka(isn) eredwhaoi 7 rn rs i _ [re ------
DEP2.SDWB-000130
LABORATORY CONTROL, SAMPLE DATA REPORT.
sone
LCClSieLnott-LSoatmp#i.e.d.:: DR77932265002090%0-160 Work Order ...: JS3ATIAD rPreeppbBaattec.h r.o..s: 073/02291/6007 BAomaallyysiiss TDaitme.e..:: 1171:/3031/07 Dilution Factor: 1
Mateix.........c WATER
PEAoEnTER Pros
soeorwer wEaAusoUmRTED ores ReEaRccoEvNsTR.Y wemon o0l.o0220000 0o.l0o2a1i5s wwaallt. 110087 DDEENN 1160--00001122
sTuoRcRaooparToEn. 1304 PROS
sEcRovceErTy 0a.
RLmewcromvsery ((5500 -- 2200001)
onobTE(os) cred ho doy 2 tore ce J+ r -- e-- s ueeco rols.
DEP2.SDWB-000131
mtce i -
J
EJRE EE ww
it
| o-- ia m
LABORATORY CONTROL SAMPLE DATA REPORT
C1l0i5enLtotL-oStamp4l.e.d.s: DRI7X20640020900-056 Work Order K...: KNERVIAC PPrreepp DBaattec.h.s4,...:..: 1713/00840/5067 `Ahnoaallyysoiis TDaitme.e.:.: 1151:/2009/07 Dilution Factor: 1
Mateix.........} WATER
FeraoRnneETER eros
smeroer 00..220000
HwERoSUrRED 0o.a5n0
aouLts p=
ReERccoEvNETRY ETHOD 1005 DDiaoys -_11Cc--00001122
sTu3RcmeoaraoTEn 1204 PROS
`ReeEcRocvaeNTr.y 7=
RLaEmceorvsERY ((5500 -- 2200007)
wotmeins)ee rt io ig7 Sk ee cp
re cd
a
DEP2.SDWB-000133
LABORATORY CONTROL SAMPLE EVALUATION REPORT
wie
| Client rors... 0260298 Work Order f...: KNIRVIRD || PLroSepoDta-tSee.m.p.l.e.n.:: R173K/00440/00700-056 Aealysis Date..: 11/09/07
pDrielputBiaotnchFact.o.r.:: 17308056 aalysie Time.: 15:26
Mateix.........: WATER
|to bpeaa se i ews
sPsEcRoCvEeNRTy 108s0
RpECaOVsERY G(90 -- 112500))
mMEWTHO1D-002 DEN 16-0012
i `suRRoaaTE 33c4 ROR 1304 pr0S
sPEcRoCvEsNsTy 7a0e
`LRaevcionveery. ((5500 -- 2200000)
Cnhorte(os)re ret for oni 049 fre ed p iri--nr--ec--e--p--v--T----
i
DEP2.SDWB-000134
LABORATORY CONTROL, SAMPLE DATA REPORT
|
merc
LCClSieLnott-LSoatmpl.e.d.:: DR7JK206400209080-056 Work Order ...: KARVIAD PPrreeppBDaattceh..-......:: 1713/00840/5067 RAonaallyyssiiss DTaites..e|:: 1115/:0236/07 Dilution Factor: 1
Matxix.........: WATER
' PARETER 1 PPeroons.
msoewreer MEoAmSeUrRED ITs emeEcRoCvEeNRTy eraoD 00.0022000 00..012m0m0 vaaf/t 2800 DDEEN 1100-0001122
`TsaucrsouparTosn. 134 PROS
Emrsccaonv.y a7e
`iRsmcoavsRy ((5500 - +2200001)
foeres).
TE
= rendecesycn pieendct i.
DEP2.SDWB-000135
