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RESIDUAL VCM ANALYSIS TEXAS CITY VINYL RESIN PRODUCTION
NOVLM11ER, 1975
DEC 5 1975 R N WHEELER JR.
Author; Supervisor: Date:
R. M. Arnold G. F. Tacquard December 1, 1975
Attached in Table I is a summary of the residual VCM levels in suspension vinyl resin production during the month of November. Essentially all QSAN-7 production averaged less than 10 ppm residual VCM. A slight increase in residual VCM of QSQH-7 compared with October production was noted. Individual bin and blend data for each suspension resin produced during the reporting
period are shown in Tables II-VII.
Also shov/n in Tables VIII and IX are residual VCM levels of VYNW
and solvent vinyl resin production for the month. Two VYHH`bins
and one V.MCH bin were re-blended to achieve < 1 ppm residual .VCM
during.the months
'
/kw ; Attachments
RESINS LABORATORIES UNION CARBIDE CORPORATION CHEMICALS AND PLASTICS DIVISION
TEXAS CITY PLANT
Vice
TABIL I SUMMARY OF VCM ANALYSIS OF SUSPENSION VINYL RESINS
NOVEMBER, 1975
Resin Type
QSAN-7 QSQH-7 VSJE-10
VCM, ppm
Bin Blend
15 8
48 30
1125-
724
% Blends < 10 ppm
90 25
o
% VCM Reduction from Blending
47 38 36 .
ucc
044999
TABLE II
QSAN-7 BLEND ANALYSIS FOR VCM CONTENT
Blend Number
B-6427 B-6428 B-6429 B-6430 B-6431 B-6432 B-6433 B-6434 B-6435 B-6436 8-6437 B-6438 B-6439 B-6440 B-6441 B-6642 B-6443 8-6444
B-6445 B-6446 B-6447 B-6448 B-6449 B-6450 B-6451 B-6452 B-6453 B-6454
B-6455 B-6456 B-6457 B-6459 B-6460 B-6461 B-6462 B-6463 B-6464 B-6465 B-6467
B-6468 B-6469
. '
VCM, PPm
147 2 3 1 5
13 48
1 7 3 2 4 1 3 3 1 2 2 2 3 1 1 1 1 .5 1 8 4 4 2 2 4 3 5 1 11 3 3 8 3 10
UCC 045000
TABLE III QSQH-7 BLEND ANALYSIS FOR VCM CONTENT
NOVEMBER, 1975
end Number
B-994 B-995 B-996 B-997 B-998 B-999 B-1000 B-1001 B-1002 B-1003 B-1004 B-1005
yM,_RPjn
21 23 15 16 69 29 9
6 5 23 120 21
ucc
045001
TABLE IV
VSJE-10 BLEND ANALYSIS FOR VCM CONTENT
NOVEMBER, 1975
Blend Number
B-804
B-805 B-806 B-807 B-808 B-809 B-810 B-812 B-815 B-816 B-817 B-818 B-821 B-822 B-823 B-824 B-825
B-826 . B-827 . . B-828
B-829 B-830 B-831 B-832
.
VCM, ppm
131 611 848 352 574 363 694
228 148 537 1076 411 898 1285 1026 370 2149 -1584 '
1402 . 308 .
981 ' * 542
577 387
:
UCC 045002
TABLE V QSAN-7 BIN ANALYSIS FOR VCM CONTENT
NOVEMBER, 1975
Bin Number
409 411
415 405 403 411 406
408 412 409 411
412 415 405 414 - 406 402 408 414
409 411 402 409 412 405 408 415 414 412 402 405 408 405 409 402
Date VCH, ppm
11-1 11-2 11-2 11-3 11-3 11-4 11-4 11-4 11-4 11-5 11-5 11-6 11-6 11-6
11-6 11-7 11-7
' 11-8
11-9 11-9
11-12 11-13 11-12 11-13 11-13 11-24 11-14 11-14
11-15 11-15 11-16 11-16 11-16 11-16. 11-17
18 44
28 60 60 33 15 21 11 18
8 3 15 10 14 4 7 4 2 14
93- . 12
8 14
1 13
9 13 13
6 5 4 6 4
5
Bin Number
403 405 415 414 412 402 408 415 405 403 409 406 409 415 408 405 414 408 403 .402 406 412 415 411 409 412 406 411 415 408' 414 403 402 411
Date VCM, pf
11-17 11-18 11-18
11-18 11-19 11-19
11-19 11-20 11-20 11-20 11-21
11-21 11-22 11-22 11-22 11-23
11-24 11-25 11-23 11-23 11-24
11-25
11-25 11-26 ' 11-26 11-27 11-27 11-27 11-28 11-28 11-29
11-29 11-30 11-29
1 4
3 10 13 16
5 35 31 25
19 22 12
7
4 9 10
20 3
.5
8. 16
6 8 6 9 5 12 12 71 35 4 5 4
UCC ,,
045003
TABLE VI QSQH-7 BIN ANALYSIS FOR VCM CONTENT
NOVEMBER , 1975
Bin Number 703 706 704 707 703 707 706 702
Date 11-1 11-2 11-3 11-2 11-4 11-3 11-5 11-5
VCM, ppm 46 59 31 100 30 45 15 55
045004
TABLE VII VSOE-IO BIN ANALYSIS FOR VCM CONTENT
NOVEMBER, 1975
n Number
701 707 703 706 709 703 706 709 701 707 705 702 709 707 709 702 706 705 707 701 701 707 704 702 705 ' 706 702 709 705 701 704 702 704 706 701 706 707 704 701 707 701 704 702 703
Date
11-6 11-6 11-7 11-7 11-8 11-8 11-9 11-9 11-11
n-n
11-13 11-12 11-12 11-18 11-18 11-15 11-14 11-16 11-16 11-17 11-20 11-20 11-20 11-21 . 11-21. 11-23 11-22 11-23 11-24 11-23 11-23 11-24 11-25 11-24 11-25 11-25 11-26 11-27 11-27 11-28 11-29 11-28 11-29 11-29
VCM, ppm
913 1029 1164
715 671 806 486 1050 1160
61
1771 500 695
1623 1692 1646
620 1443 1179 428 1098 2844
737 1644 1497 1025 1186
900 1897 2101 1736
951 1223
918 518 920 926 959 628 1734 1338 1277 795 976
045005
TABLE VIII VYNW BLEND ANALYSIS FOR VCM CONTENT
Blend Number B-3892 B-3893 B-3894 B-3896 B-3897
VCM, ppm 1.5 1.0 3.4 4.8 35
UCC 045006
TABLE IX RESIDUAL VCM ANALYSIS OF SOLVENT VINYL RESINS
NOVEMBER, 1975
VYHH
in No.
VCM, ppm
52 ND
32 ND 44 0.3 41 ND 34 TR
51 TR 33 ND 42 TR
43 TR 61 0.4 44 0.4 62 0.4
32 0.2 31 0.2 62 0.8
51 ND 34 - 0.4 63 ND 83 TR
33 ND 31 ND 61 TR 52 TR
53 ND 62 0.3 41 0.8
i
VMCH
Bin No.
VCM, ppm
73 ND 83 ND 74 0.3 84 0.3 71 TR
72 TR 73 TR 82 TR 72 ND 81 0.2 74 0.3
VYNS
Bin No.
VCM, pi
23 0.6 11 ND 12 ND 14 ND
Note:
Trace ND
<0.2 ppm Non-Detectable
IJCC 045007
DISTRIBUTION
TEXAS CITY
Dr. J. C. Chaty/D. R. Montgomery Mr. M. E. Eisenhour Mr. R. L. Frantz Mr. J. t. Hockersmith/W. C. Roeh Mr. F. L. Johnson Mr. K. E. Ross Mr. R. W. Sesler
BOUND BROOK
Mr, T. F. Archer Mr. E. Bell Mr. R. G. Davis
NEW YORK OFFICE
Mr. G. P. Bigelow Mr. A. E. Donaldson Mr. J. B. Hollingsworth Mr. G. T. Scott Dr. T. T. Szabo
SOUTH CHARLESTON PLANT
C. E, Fry M. E. Griffith R. N. Wheeler
TECH CENTER
Dr. 0. 0. Brezinski
i if
04 i