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f /VISA Data Sheet 08-01-02 Detectors, Reagents, and Accessories for Samplair" Pump and testing Kit. Using the Samplair Pump with appro priate tubes, filter paper and reagent kits, some 140 toxic gases, vapors, and mists in the threshold limit ranges can be detected. MSA detector tubes are regularly submitted for certification by National Institute for Occupational Safety and Health. The tubes which at the time this list was printed have been certi fied by NIOSH as meeting the require ments of 42 CFR Part 84 when used with these pumps, are indicated by ` NIOSH" and Testing & Certification number following the listed detectable hazard. The tubes are a direct-reading type. Those tubes calibrated for a single compound have the concentra tion scale printed on the tube for direct reading. Multiple-use tubes have a millimeter scale printed on the tube and concentrations are deter mined from a table supplied with the package. Tubes are supplied in packages of ten. Note: Shelf life of Detector Tubes and Reagent Kits, minimum of 30 months after packaging. For information on the Samplair Pump, Model A, see Data Sheet 08-02-02. Key Refers to Threshold Limit Values as established by the American Confer ence of Governmental Industrial Hygienists--1980. (TLVs refer to timeweighted-average concentrations for a 7- or 8-hr workday and 40-hr work week.) Threshold Limit Values are reviewed annually by the Conference. For current TLV data, contact: Secre tary-Treasurer, American Conference of Governmental Industrial Hygienists, P.O. Box 1937, Cincinnati, Ohio 45201. Interferences and temperature correction data shown on individual instruction sheets. Also order #81316 Package of Pre-Filter Discs to remove interfering H;S and SO; (if present). A pre-filter effectively absorbs these gases in concentrations up to 100 ppm. Also order #58238 Pinch Clamp (necessary to restrict contents of reactor tube). Also order #82389 Vial of Charcoal (required for filling filter retainer of Accessory Kit to protect Sampling Also for Universal Test r. Pump from reagent vapors and/or droplets). Order Sample Conditioning Kit #87028. When measuring CO content of flue gases or in presence of NOj in concentrations from 7 to 100 ppm, also order #73139 Gasorbent Refill (sufficient for 10 refills of Sample Conditioning Kit "prescrubber"). If remote sampling is desired, also order a sampling line of the desired length: #73067 Sampling Line, 10 ft long #73068 Sampling Line, 25 ft long #73069 Sampling Line, 50 ft long Note: when sampling point is remote from pump, detector tube should be placed in remote end of sampling line. If desired, a gas-sampling collecting kit is available for measuring the mercaptan content of a sample taken from a natural gas line. Order #454500 Gas-Sample Collecting Kit. Accessory Kit #87030 required for detecting Chromic Acid Mist, Decaborane, Diborane, Lead Dust/ Fume, and Pentaborane. Accessory Kit #87031 required for Arsine, Phosphine, and Stibine. Requires adapter (#467063) when using Samplair Pump. Flue Gas Test Kit #470321 is avail able for reducing sample temperature (max. 1000 F) to less than 125 F. Detector, Reagents, Accessories for Universal Tester and Samplair Pumps and Testing Kits DENOTES TRADENAME ( >TLV FIGURES IN PARENTHESES ARE 1980 PROPOSED Detectable Hazard Measurable Range (PPM) 1980 ACGIH TLVs (PPM) Pkgcrf Detector Tubes Box of Reagent Filter Kit Papers Required ; Pyrolyzer Interferences Acetaldehyde 25-1000 100 93963 Turpentine, other Aldehydes Acetic Acid 0-50 10 460022 SO, Acetone NIOSH (TC-84-54) 125 - 6500 (750) 460423 Ethanol Acetonitrile 10-200 40 91624 460325 HaS, Halogen, Nitrogen & Hydrocarbon Compounds Acetylene 3-600 82802 Ammonia, H,S, CO, Hydrocarbons Acrylonitrile 1-150 (2) 91624 460325 H,S, Halogen, Nitrogen & Hydrocarbon Compounds Ammonia NIOSH (TC-84-034) 10-400 5-1600 25 92115 25 460103 Acid gases & other Amines Acid gases & other Amines n-Amyl alcohol (pentanol 1) 25 - 2000 95097 Other Alcohols sec-Amyl alcohol (pentanol 2) 25-2000 95097 Other Alcohols tert.-Amyl alcohol (2 methyl-butanol 2) 25-2000 95097 Other Alcohols n-Amyl mercaptan (pentanethioi -1) 0.5-100 454206 HjS 3M 115072 Data Sheet 08-01-02 DENOTES TRADENAME < >TLV FIGURES IN PARENTHESES ARE 19S0 PROPOSED Detectable Hazard Measurable Range (PPM) 1980 ACGIH TLVs (PPM) Pkgof Detector Tubes Reagent Kit Box of Filter Papers Required Pyrolyzer (?) Interferences Arsine 0.025-1.0 0 05 81101 81220 Stibine, Phosphine Benzene 5-200 0-150 10 93074 10 467050 Aromatic, Aliphatic Hydrocarbons Aromatic, Aliphatic Hydrocarbons Bromine 5-175 01 82399 H;S. NHs, NO,. Ethylene. Halides Bromobenzene (Mono) 10-800 93074 Aromatic, Ahphatic Hydrocarbons Butadiene (1.3-butadiene) 100 -4000 1000 93962 2-Butoxyethanol (butyl Cellosolve1) 30 -900 (25) 95097 Other Alcohols n-Butyl alcohol (butanol 1) 50 - 4000 50 95097 Other Alcohols sec-Butyl alcohol (butanol 2) tert -Butyl alcohol (2 methyl propanol 2) 50 -4000 100-1000 (100) 100 95097 95097 Other Alcohols Other Alcohols n-Butylamine Butyl mercaptan (butanethiol-1) 2-100 0.5-100 5 92115 05 454206 Acid gases HsS tert-Butyl mercaptan (2-methyl propanethiol-2) 0.5-100 454206 HsS Carbon dioxide NIOSH (TC-84-025) 200-120,000 5000 85976 Carbon disulfide 0-100 10 463527 NBS Color Change Carbon monoxide 1NIOSH (TC-84-067) 10-1000 5 - 3000 0 - 3000 50 47134 50 91229 50 465519 NOs, Ethylene, Acetylene Hydrogen, HsS, Acetylene Hydrogen, HjS, Acetylene uaroon tetracniortae Chlorine NIOSH (TC-84-042) 10-200 0-70 0.5-100 0.1-25 (5) 88536 (5) 460548 1 82399 1 460225 460325 460325 Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens HsS, NH3, NOs, Ethylene, Halides HsS, NHa, NOs, Ethylene, Halides Chlorine dioxide 0.05-16 0 1 82399 HsS, NHj, NOs, Ethylene, Halides tnioroDenzene (MonocmoroDenzenej 10-200 10-800 75 85834 75 93074 Other Halogen Compounds & Halogens Aromatic, Aliphatic Hydrocarbons (jnioroDromometnane 50-400 25-500 200 85834 200 88536 460325 Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens 1-Chloro-l, l-di(luoroethane (Genetran" 142B) 100 -4000 100 - 2500 i 88536 92030 460325 460325 Other Halogen Compounds & Halogens HNOa, Hydrocarbons i Chlorodifluoromethane (Freon1,22) Chloroform (trichloromethane) 200 -2000 25-400 1000 10 88536 88536 460325 460325 Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens | 1-Chloro-l-nitropropane j Chloropentafluoroethane (Freon^ 115) 2-75 200 - 2000 (2) 91624 88536 460325 460325 HsS, Halogen, Nitrogen & Hydrocarbon Compounds Other Halogen Compounds & Halogens tmorotrmuorometnane (i-reorr u) 250 - 2500 200 - 3500 88536 92030 460325 460325 Other Halogen Compounds & Halogens HNOj, Hydrocarbons Chromic acid mist 0 05-1.4 mg/m3 01 79014 79010 Cumene Cyanogen 0-1000 2-100 50 460422 10 91624 460325 Butyl Mercaptan & Unsaturated Hydrocarbons HsS, Halogen, Nitrogen & Hydrocarbon Compounds Cyclohexanol 25-1000 50 95097 Other Alcohols Cyclohexylamine Decaborane CD 5-100 0.01-1.0 10 0 05 92115 82099 82388 Acid gases Hydrazine, UDMH, HsS Diborane CD 1,2-Pibromoethane (ethylene diDromiae) 0.1-3.0 10-200 5-100 0.1 20 88536 20 85834 82099 82388 460325 Hydrazine, UDMH, HsS Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens 0-Dichlorobenzene Dichloroditluoromethane (Freon1' 12) 10-200 25 - 3000 50 1000 85834 88536 460325 Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens 1,1-Dichloroethane 1,2-Dichloroethane L*cmoroetftyiene(UJH^j Uichloroethyiene (trans.-l.Z) Dichloroethylether 1.1-Dichloro-l-nitroethane Dichlorotetrafluoroethane (Freon- 114) 25-400 25-400 10-300 100 - 500 50 - 400 25-1000 5-75 2-75 200 - 2000 200 10 200 200 200 200 5 2 1000 85834 85834 85834 88536 85834 92030 85834 91624 88536 460325 460325 460325 460325 Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens Other Halogen Compounds 8 Halogens Other Halogen Compounds S Halogens Other Halogen Compounds & Halogens HNOs, Hydrocarbons Other Halogen Compounds & Halogens HsS, Halogen, Nitrogen & Hydrocarbon Compounds Other Halogen Compounds & Halogens Diethylamine 10-200 3 92115 j_ _ _ _ _ _ _ _ _ _ _ Acid gases 115073 DENOTES TRADENAME ( )TLV FIGURES IN PARENTHESES ARE 1980 PROPOSED Detectable Hazard Measurable Range (PPM) Diethyl sulfate Dimethyl acetamide 5-50 5-80 Dimethylamine Dimethylformamide Dimethyl sulfate Dimethyl sulfoxide Di-n-propylamine 2-Ethoxyethanol Ethyl alcohol (ethanol) Ethylamine Ethyl benzene Ethyl bromide Ethyl Chloride Ethylene Ethylene dichlonde 1,2-Dichloroethane NIOSH (TC-84-058) Ethylemmine Ethyl mercaptan N-Ethylmorpholine Fluorotnchloromethane (Freon* 11) 5-100 5-150 1-50 10-250 5-100 50-1000 200-10,000 10-300 10-500 25 - 400 100 - 2000 100 - 2000 0.5-100 25-450 0-600 2-100 0 5-100 5-100 250 - 2000 250 - 2000 Formaldehyde Furfuryl alcohol Hexane Hydrazine 1-100 25-500 25 - 5000 0 5-40 Hydrogen chloride 0-300 2-170 Hydrogen cyanide Hydrogen fluoride NIOSH (TC-84-022) Hydrogen sulfide---------------------------------- Isoamyl alcohol (2 methyl-butanol 4) Isobutyl alcohol (2 methyl propanol) 0-80 0-25 1-1000 10-2000 50-1000 50 - 4000 Isopropylamme Lead Dust/Fume > Mercury, except alkyl Methacrylonitrile Methyl alcohol (methanol) Methylamine Methyl bromide Methyl chloride Methyl chloroform (1,1,1-tnchloroethane Methylcyclohexanol Methylene chloride (dichloromethane) 5-100 0.05-6 3 mg/m3 0.05-2.0 mg/m3 10-80 100-10,000 10-100 10-100 2.5-90 10-100 25-1000 100 - 700 25-800 100 - 2000 0 - 3000 100-1000 50 - 2000 Methyl isobutyl carbmol Methyl mercaptan 25-1000 05-100 Monomethyl hydrazine Nitric oxide NIOSH (TC-84-059) Nitrogen dioxide NIOSH (TC-84-040) Nitroethane 0 5-50 1-150 0-30 10-300 1980 ACGIH TLVs (PPM) & Pkgof Detector Tubes Reagent Kit Box erf Filter Papers Required Pyrolyzer Interferences 95300 10 91624 460325 H;S, Halogen, Nitrogen & Hydrocarbon Compounds 10 92115 Acid gases 10 91624 460325 HjS, Halogen, Nitrogen & Hydrocarbon Compounds 0.1 95300 95739 460325 SO;, Organic Sulfur Compounds 92115 Acid gases (50) 1000 95097 95097 Other Alcohols Other Alcohols 10 92115 Acid gases 100 200 1000 463202 85834 85834 Aromatic, Aliphatic Hydrocarbons Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens 1000 92030 82802 460325 HNO,, Hydrocarbons NH3i HjS, CO, Hydrocarbons 10 92030 10 461863 460325 HNOj, Hydrocarbons Other Halogen Compounds & Halogens 0.5 92115 0.5 454206 CD Acid gases HsS 5 92115 Acid gases 1000 88536 460325 Other Halogen Compounds & Halogens 1000 2 92030 93963 460325 HNOj, Hydrocarbons Turpentine, other Aldehydes 10 95097 Other Alcohols 50 463838 Aliphatic and some Aromatic Hydrocarbons 0 1 460425 5 91636 5 466612 Acid gases & other Amines HNOj HNOj 10 93262 Ammonia, HZS 3 462019 10 460058 10 463875 SO; SO; 100 95097 Other Alcohols 50 95097 Other Alcohols 5 92115 Acid gases 0.15 mg/m3 78399 78693 0 05 mg/m3 83089 91624 460325 H;S, Halogen, Nitrogen & Hydrocarbon Compounds 200 95097 Other Alcohols 10 92115 Acid gases (5) 85834 (5) 462135 Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens (5) (50) 350 88536 92030 88536 460325 460325 460325 Other Halogen Compounds & Halogens HNOj, Hydrocarbons Other Halogen Compounds & Halogens 50 95097 Other Alcohols (100) 85834 Other Halogen Compounds & Halogens (100) (100) (100) 462516 88536 92030 460325 460325 Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens HNOj, Hydrocarbons 25 95097 0.5 454206 Other Alcohols H;S 0.2 460425 Acid gases & other Amines 25 (3) 100 460424 83099 91624 460325 H;S & Halogens H,S. Halides H;S, Halogen, Nitrogen & Hydrocarbon Compounds 3M115074 DENOTES TRADENAME ( >TLV FIGURES IN PARENTHESES ABE 19fl0 PROPOSED Detectable Hazard Measurable Range (PPM) Nitromethane 5-300 1-Nitropropane 2-100 2-Nitropropane 5-150 Ozone 0.05-5.0 Pentaborane 001 -- 1.0 25-350 Perchloroethylene NIOSH (TC-84-065) 0-800 25-400 Phosgene (carbonyl chloride) 0.1-10 Phosphine 0.025-1.0 Propyl alcohol (propanol-1) 100-10,000 iso-Propyl alcohol (propanol-2) 100-10,000 n-Propyl mercaptan (propanethiol-1) 0.5-100 n-Propyl nitrate 10-100 Propylene 1-400 Propylene dichlonde (1,2-dichloropropane) 25-250 25-500 Propylene imine 2-300 Pyridine 2-50 Stibme 0.025-1.0 Styrene, monomer (phenylethylene) 0-500 Sulfur dioxide NIOSH (TC-84-046) 1-400 1,1,2,2-Tetrabromoethane 2-50 1,1,2,2-Tetrachloroethane 2-50 1,1,3,3-Tetrachloropropene 5-100 luiuentMiuiuoi/ NIOSH (TC-84-057) 12.5-700 10-800 1,1,2-Trichloroethane (beta) 25-700 50 - 500 50 - 600 Trichloroethylene NIOSH (TC-84-055) 25 - 600 25-400 1,2,3-Trichloropropane 10-500 1,1,2-Tnchloro-1,2,2-triftuoroethane (Freon*113) 100 - 2000 100-4000 Triethylamine Trifluoromonobromomethane (Freon* 13B1) 5-100 100 -4000 Trimethylamine Unsymmetrical Dimethylhydrazine 5-200 0.5-50 25-250 Vinyl chloride (chloroethylene) 0-100 100 -2000 Vinylidene chloride 10-300 Vinyl pyridine 1-100 Xylene (o-, m-, p-isomers) 10-500 Xylene 10-800 1980 ACGIH TLVs (PPM) 100 (15) 25 0.1 0 005 50 50 50 0.1 03 200 400 25 75 75 2 5 0.1 (50) 2 1 100 100 10 10 (50) (50) (50) 50 1000 1000 25 Pkgof Detector Tubes 91624 91624 91624 93865 85834 460467 88536 89890 *" 95097 95097 454206 91624 82802 85834 92030 92115 91624 ` '" ' ' 461781 92623 85834 85834 85834 461371 93074 85834 88536 85834 460328 88536 85834 88536 92030 92115 Box of Reagent Filter Required Kit Papers Pyroiyzer Interferences 460325 H:S, Halogen, Nitrogen & Hydrocarbon Compounds 460325 H;S, Halogen, Nitrogen & Hydrocarbon Compounds 460325 H;S, Halogen, Nitrogen & Hydrocarbon Compounds NO,. SO, 82099 82388 Hydrazine, UDMH. H,S Other Halogen Compounds & Halogen Other Halogen Compounds & Halogen 460325 Other Halogen Compounds & Halogen 81101 81220 460325 460325 81101 " 81220 460325 Arsine, Stibine Other Alcohols Other Alcohols H,S H,S, Halogen, Nitrogen & Hydrocarbon Compounds NH3, H2S, CO, Hydrocarbons Other Halogen Compounds & Halogens HNOj, Hydrocarbons Acid gases H,S. Halogen, Nitrogen & Hydrocarbon Compounds Arsine, Phosphine 460325 460325 460325 460325 Acetic Acid Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens Aromatic, Aliphatic Hydrocarbons Aromatic. Aliphatic Hydrocarbons Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens Other Halogen Compounds & Halogens HN03, Hydrocarbons Acid gases 1000 88536 460325 Other Halogen Compounds & Halogens 92115 0.5 460425 5 85834 5 462534 5 92030 10 85834 91624 100 463201 100 93074 460325 460325 Acid gases Acid gases & other Amines Other Halogen Compounds & Halogens HNOj, Hydrocarbons HN03i Hydrocarbons Other Halogen Compounds & Halogens HaS. Halogen, Nitrogen & Hydrocarbon Compounds Aromatic. Aliphatic Hydrocarbons | Aromatic, Aliphatic Hydrocarbons Note: This Data Sheet contains a general description of certain detectors, reagents and accessories for use with the Universal TesterTM and Samplair Pumps from MSA and includes a list of representative hazards that can be detected; however, under no circum stances should the products be used except by qualified, trained personnel and not until the instructions, labels, or other literature accompanying them have been carefully read and understood and the precautions therein set forth followed Only they contain the complete and detailed information concerning these products. 600 Penn Center Boulevard MSA Pittsburgh, Pa. 15235 USA Phone (412) 273-5000 Telex 812453 Worldwide service: Branch offices throughout the United States. Subsidiaries in: Amsterdam Barcelona Berlin Calcutta Glasgow Johannesburg Lima Mexico City Milan Ndola Paris Salisbury Santiago Sao Paulo Singapore Sydney Tokyo Toronto. Representatives in principal cities throughout the world Data Sheet 08-01-02 (Part No 994098) Printed m u S A 8111 (L) 3M 115075