Document e12XY914GDDnG2yDDbyNQYKJe
Tenneco Polymers
A Tenneco Company
MATERIAL SAFETY DATA
NUMBER
(Approved by U.S. Department o( Labor as "essentially similar" to FORM OSHA-20)
SECTION I IDENTIFICATION OF PRODUCT
MAIJIICAPTIlOFfi'C n>tiC
TENNECO POLYMERS, INC., RESEARCH & DEVELOPMENT
EMERGENCY TELEPHONE NO.
609-386-9200 713-479-3411
ADDRESS
RIVER ROAD, P.0. BOX 129, FLEMINGTON, NEW JERSEY 08822
TRAOE NAME AND SYNONYMS TENNECO PVC RESIN 185, 190, 195, 200, 225, 225F, 225PG.
CHEMICAL NAME ANO SYNONYMS
POLY(VINYL CHLORIDE), PVC H0M0P0LYMER
CHEMICAL FAMILY
CHL0R0HYDR0CARB0N POLYMER
225SG. 250. 250-3.
MOLECULAR FORMULA
(CH2CHCl)n
501.
530.
540
MOL. WT.
SECTION II HAZARDOUS COMPONENTS OF MIXTURES
COMPONENT
THRESHOLD /. LIMIT
value
COMPONENT
THRESHOLD
Vo LIMIT
VALUE
(UNITS!
(UNITS!
0SHA Standard 1910.93q(.1017) on vinyl chloride sets a permissible exposure limit of
lppm averaged over any 8 hr period and 5ppm over any 15 min period. Oh the basis that
polyvinyl chloride may contain and release small amounts of monomer, the Standard
applies to the manufacture, reactipn, .packaging, repackaging, storage, handling, use or transportation of PVC, but not to handling Or use of "fabricated products , as defined, if not subiect to Processing sufficient in fimp nr f.pmppratnrp tn rancp macc mpltTng-__
APPEARANCE AND ODOR
White powder, odorless
BOILING POINT (DEGREES FAHRENHEIT)
Not applicable
VAPOR PRESSURE (MM. OF MERCURY)
Not applicable
vapor oesity
(AIR * 1)
Not applicable
SOLUBILITY IN WATER
Negligible
SECTION III PHYSICAL DATA
(oiGTREEs,FAHRENHEiT) Not applicable Softens about 160 - 180F
SPECIFIC GRAVITY (WATER 1)
1.4
PERCENT VOLATILE (BY WEIGHT)
Approx. 1% (Moisture)
EVAPORATION RATE (butylacetate = i|
Not applicable
.
SECTION IV FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (SPECIFY METHOD)
Ignition
about
735F
autOi flammable limits (PERCENT BY VOLUME)
LOWER
850 F (ASTM D-1929)___________ I
Not applicable
FIRE EXTINGUISHING MEDIA
Water spray, carbon dioxide or dry chemical.
SPECIAL FIRE FIGHTING PROCEDURES
Water spray or fog may "be helpful in reducing flame'intensity'and absorbing' irritating fumes.
UPPER
unusual fire and explosion hazards NFPA lists ignition temperatures of 725F for layer and 1220F' for PVC dust cloud. Produces combustible gases above 570F. Fire conditions produce lydrogen chloride, requiring protective equipment.
This information is furnished without warranty, representation. Inducement or license oi any kind. except that M is accurate to the best of Tenneco Polymers knowledge or
obtained from sources believed by Tenneco Polymers to be accurate and Tenneco Polymers does not assume any legal responsibitlv tor use or reliance upon same.
Customers ere encouraged to conduct ineir own tests Belora using any product read its label
CTLO 32077
TPOL 25 4A3
THRESHOLD LIMIT VALUE
See Section II
SECTION V HEALTH HAZARO DATA -------------------------- f--'-----------------------
effects or overexposure None expected - inert resin. See Section IX. Prolonged breathing of concentrated dust may be harmful. (Processing at high temperatures produces fumes irritating to eyes and respiratory tract requiring local exhaust).
EMERGENCY ANO FIRST AID PROCEDURES
Ordinary measures of personal hygiene.
In case of exposure in hot processing move to fresh air. flush eyes with water.
SECTION VI REACTIVITY DATA
STABILITY
UNSTABLE STABLE
Normalconditions to avoio processing temperature, about
X
350F, causes slow darkening and decomposition. Higher heat increases rate and evolution of HC1.
INCOMPATIBILITY (Materials to avoid)
None in ordinary use. Soluble in certain ketones and organic solvents.
HAZARDOUS DECOMPOSITION PRODUCTS
Thermal decomposition produces HC1, and CO and CO? (above 570F).
HAZARDOUS POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
CONDITIONS TO AVOID
X None in ordinary use.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Sweep up and remove to disposal container.
WASTE DISPOSAL METHOD
Bury in an approved landfill.
SECTION VIII SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTEC1noN iscwciiytype) In case of concentrated dust, use Bureau of Mines approved dust respirator !NI0BM TC-21C-132 or equivalent). See Sections II and IX:
VENTILATION
local exhaust
For not processing. MFEoCrHAoNICrdALi.n(Gaenreyral) ,han,d l.ing.
eEnLto elevated stack. flenlilate enclosed spaces.
PROTECTIVE GLOVES
EYE PROTECTION
Not ordinarily required.
Safety glasses.
other protective eouipment None required tor ordinary handling. For hot processing
exhaust, safety glasses and gloves are recommended.
local
SECTION IX SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING OSHA Standard 1910.93q(.1017) requires monitoring and other precautions in storage, handling and use of polyvinyl chloride, and also labeling of PVC "Contains Vinyl Chloride-Vinyl Chloride is a Cancer-Suspect Agent". New PVC resins with_a low monomer content make it easier to operate below the-OSHA action-level of 0.5ppm in a processor's work area, assuming normal conditions and ventilation, simplifying compliance with some of the regulatory requirements. Further developments (L>-n resins and on regulations are pending.
DATE
5/30/84
NAME AND TITLE
D. GOODMAN, PRODUCT REGULATIONS
SHEET NUf/QER
156
cTL032078
TPOL 2b 4/83