Document dn4QvXvO9Q06OOaenmMg9Zm65
_ + CBaigloennidaalrRYeepaorrst offor20th0e2Maannduf20a0c3ture ofAPFO DuPont Com--pFayaettneviylle Work
ARZ
Page old 1876
Biennial Report for the Manufacture of APFO Calendar Years of 2002 and 2003
DuPont Company -- Fayetteville Works
Naontdel:orTmhodeiifnicfaotrimoant.ion contained inthisdocumenitssubmitied voluntarily and may be subject tofuture revision
CONFBUI SINED SS INEFORN MATT IONIISREA DACL TED o"TfhiIsntreenptor(tLiOsI)sutbomSittetepdhepnurLs. uJaonhtntsoonc,omAmssiitsmteannttsAdmmaindiestbryatDourP,oUnStEiPnAa,Meanrtcithle1d4", V2o0l0u3n,taLretyter Actions to Evaluate and Control Emissions of Ammonium Perfluorooctanoate (APFO)" PbuergsiunannitngtoiAn dtdheenydeaurmaIfItIoerftphriosduLcOtLi,onprcoovmimsieonnc5e,sa, faancidlictyonmtainnuufiancgtufrorinfgivAePcFoOnsiescurteqiuviereydeatros, following, for the prior calendar year, report to EPA biennially the following information on a calendar year basis:
1. Annual production volume of APFO; 2. Emissions per facility (air, water, waste); 3. Summary reportofgroundwater monitoring results; 4. Summary reportof surface water monitoring results; 5. Workplace industrial hygiene monitoring; and 6. Summary data on employee blood monitoring results. "ATPhiFs Oreipsorttheprsouvbisdteasnctehepraobdouvceeidnfatortmhaetfiaocnilfitoyr,ctahleensduabrstyaenacresm2e0a0s2uraendd b20y03a.nalNytoitcealthtaetcwhnhiiqluees is the perfluorooctanoate anion (PFO), which is reported herein as perfluorooctanoic acid (PFOA).
General Facility Information
Company Name: ~~ E. I. du Pont de Nemours and Company
Site Location:
Site where APFO is manufactured: DuPont Company ~ Fayetteville Works 2Fa2y8e2tt8evNiClleH,iNgChwa2y838076-W7332
Confidential Business Information Redacted 2
Company Sanitized
CBiaclaennidaalrRYeepaorrstoffo20t0h2e Maannduf20a0c3tureof APFO DuPont Company ~ Fayetteville Works
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1. Annual production volume of APFO TprhoeduDcutiPoonntinCloatmep2a0n0y2. TFhaeyetftoelvliolwliengWotrabklse'shAoPwFsOthMeatnoutfalacptruordiuncgtioFancivloiltyumceomofmeAnPcFeOd for calendar years 2002 and 2003.
Calendar Year
"APFO Production
[ 2003 2 T| T (0 3 |
Soren | an ww | 2. Emissions per facility (air, water, waste);
TfahceilietsytiatmaFtaeydetqtueavnitlilteywoafsaidreteemrimsisnieodnsutsointgheenagtimnoeseprhienrgecaflrcoumlattihoensA.PFIOn amdadniutifoanc,tusrtiancgk
edestteicntgiopnelrifmiotr.medAnninua2l0ly03a
showed sample
oPfFtOheAsiatier's
esmuirsfsaicoenswattoerbdeislcehsasrgtehatno
the the
analytical Cape Fear
RquiavnetrifiiscaatniaolnyzleidmiftorofPFthOeA;anahloywtiecvaelr
mtehtahtomdo.nitTohreinwgasshtoewesmitshesiPonFsOAaretothbee
less than quantities
the of
PFOA, streams
otnraansdfreyrrbeadsifs,rotmhatthaereFeaysettitmeavtieldletoWhoarvkesbesieten.
present The
fionltlhoewivnagritoaubslesogliivdewsastthee
estimated emissions of PFOA to specific media from the Fayetteville Works during the
subject years:
eeeT 0
ET
323 b.
Note 1: tDhueesthoortthedulraatteisotnarotf-utpheof2t0h0e2ApPrFodOucMtainounfraucnt,urniongsuFrafcaicleitywaatnedr monitoring occurred in 2002.
NQ = less than the practical analytical quantification limit of 0.05 g/L
3. Summary report of groundwater monitoring results dInet2e0r0m2i,nethteheDumPoosnttpCroobmapbalenylo--caFtaiyoentstefvoirllteheWoartmkossppheerrfiocrmdeedpoasiirtidoinspeorfsiPoFnOmAodferloimngthtoe `ew manufacturing facility. New monitoring wells were installed in the surficial aquifer at
Confidential Business Information Redacted
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CBaielnennidaalrRYeepaorrst foofr2t0h0e2Maannduf2a0c03tureofAPFO DuPont Com--pFayaettneviylle Works
Page3ord
the two locations predicted by the modeling.
ITnhe20m0o3n,itthoeriFnagyetitnevvoillvleedWtohrektswsoitneebwelgyaninasntnalulaeld mwoenliltsodreisncgroibfetdheabgorvoeu,ndawnadteirncflourdPedFOtwAo existing monitoring wells.
GlervoeulnsdowfatPeFrOAm.oniintotrheintgwoconndeuwctweedllisnaJnadnutaheryexainsdtinMgarweclhl 2a0t0t3hesOhlodweBdionsoluqdugaentLiafgiaobolne
(SMU-01, of PFOA
SWM-02, above the
aqnudanMtiWfi-ca1tiorenspleicmtiitvelayt).theTheexsiestmionngitwoerllingloecvaetnetds
did indicate upgradient
levels of the
Nafion Common Sump.
gForloluonwdiwnagtedrismcounsistioornisngwiwtahstheexpNaonrdtehdCtaoroilnicnlaudDeivtihsreieonexoifstWiangstweelMlsandaogwenmgernadti,enttheo2f0t0h4e
Ninaf2i0o03n, aCnodmtmhoenthSreuemapboarveea-.meTnhteio2n0e0d4dmoownnigtroardiinegnrteswuelltslswesrheowveirdtuPalFlyOiAdecnotniccaelnttroatthioosnes
of 0.303 PFOA is
pg/L, 1.530 a resultof a
pg/L, and 0.123 historical release
pg/L respectively. originating from the
It is believed that the detected Nafion manufacturing area's
common process wastewater sump. That source has been eliminated from the site.
`The following table shows the groundwater monitoring analytical results for 2003 and 2004:
`Confidential Business Information Redacted
CBaielnennidaalrRYeepaorrst offor2t0h0e2Maanndu2f0a0c3tureofAPFO DuPont Company - Fayetteville Works
Pagedofd
(SMaomnpilteorNiangmeWell Description)
`MoDnaittoering
PFOA ug
(SNMeUw-0w1ell on River Pump Road;
0013/72277/0033
East of APFO Facility)
02/04/04
(SNMeUw-0w2ell at Construction Gate entrance; Southwest |[ 0327o 03 |Tp __<<oos 0101||
of APFO Facility
0204/04
(MEWx-is1tSing well a1 Od Biosludge Lagoon SWMU by 0O12s8/o03
00s |
Central WWTP; SouthofAPFO Facility)
0327/03
22/0404
(NEAxiFst!ing well upgradientof Nafion Common [032702003|00006 68 s|
Sump; SoutheastofAPFO Facility)
[opis [oo
o2o40a 0062|
N(EAxFi-st0i2ng well downgradient of Nafion Common 020404
0303
Sump: Southeast ofAPFQ Faciliy
(NEAxiFs-ti0ng well downgradientofNafion Common 0204004
1530
Sump: Southeast of APFO Facil
(NEAxFis-t0i4ng well downgradientofNafion Common 020404
0123
Sump; Southeast of APFO Facility
4. Summary report of surface water monitoring results
As for
reported in Item 1 above, the PFOA in the site's surface
DuPont Company water discharge to
-- Fayetteville Works annually monitors the Cape Fear River. The monitoring
conducted in both 2003 and 2004 shows the
the analytical method, or less than 0.0 g/L.
PFOA to be less than the quantification
No surface water monitoring occurred
limit of
in 2002
due to the late start-up of the APFO Manufacturing Facility and the short duration of the
2002 production run.
5. Workplace industrial hygiene monitoring
The DuPont Company -- Fayetteville Works began workplace monitoring for PFOA with the
start up of the APFO Manufacrtyurarienag mFoanciiltiotrysitnha2t0s0a2m.plTehdethweorbukiplldaicneg maiornistpoarcienfgorintw2e0l0v2e
and 2003 consisted of stationa (12) continuous hours. These
sampled
locations
are.
limited
access
restricted
areas
in
which
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. CBaiglaennidaalrRYeepaorrst offor20th0e2Maannduf2a0c03tureofAPFO DuPont Company -- Fayetteville Works
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personnel wear reported in the
both respiratory following table
and are
dermal personnel the 12-hour time
protection. weighted
The analytical average (TWA)
results PFOA
concentration values.
Minimum| Maximum| Average
[vo20r02 |pAree alPzh[r | omp_ les|| _ 0(0mmg0/4 e8mrT | e m0g./02m4']
(mg/m |
0.017
Twa [10s| oo |ox | ooo]
mg/m' = milligrams per cubic meter
6. Summary data on employee blood monitoring results
At the DuPont measured since
Company 2002. A
s--umFmayaertytevoiflrleesuWlotrskosf,embploloodyeseesrwuimthleivdeelnstioffiedPFAOPAFOhaevxepobseuerne
potential in 2002 and 2003 is presented in the table below. The entire data setofblood
concentrations is available upon request.
Minimum Maximum
Average
oameples! ppm)
ppm
ppm)
[Zoe| 17 | ood | oo Toor |
C2005| 44[0008| 2280
ppm = partspermillion
Confidential Business Information Redacted