Document dn15DyodbvDZzYmODjE6gL6qB

. AcPr^X TABLE OF CONTENTS List of Figures and Tables Part A: PERMITTING GUIDELINES A.l. Identification and Classification of Hazardous Waste - LL Inclusion of a Waste Within the Scope Of the System 1.2. Operational Threshold Definition for Category in Wastes 1.2.1. Ignitability 1.2.2. Corrosivity 1.2.3. Reactivity 1.2.4. Toxicity I.2.4.I. Threshold Toxicity Criteria 1.3. Special Test Protocols 1.3.1. Application of Tests 1.3.2. Leachate Extraction Procedure 1.3.3. Bioassay Procedure 1.3.4. Oral LD,^ for Humans L3.5. Albino Rabbit Skin Testing for Corrosivity and Irritability A.2. Monitoring Expectations 2.1. Scope of Analytical Requirements 2.1.1. Establishment of Baseliiie 2.1.2. Comprehensive Operational Analysis 2.1.3. Continuing Annual Operational0&a&$is<- 2.1.4. Quarterly Screening Analysis 2.1.5. Specific report on Departures from Norm 2.2. Description of Monitoring Systems 2.2.1. Groundwater M nitor Wells 2.2.2. Leachate Collection Monitoring Systems CCR 000037371 2.2.3. Surface Water Monitoring 2.2.4. Air Monitoring 2.2.5. Soil Monitoring Part B: PROGRAM ENFORCEMENT GUIDELINES B.l. Sampling Procedures; Chain ofCustody; Technical Standards; Collection 1.1. Recordkeeping and Reporting 1.2. Sampling Protocols L3. Planning the Scope of a Sampling Procedure L3.L Sampling Logistics L3.2. Safety in Drawing Samples fromHazardous Waste Containers L3.3. Sampling Devices L3.4. Preservation and Storage of Samples L3.5. Sample Integrity B.2. Analytical Citations 2.L General Laboratory Practices 2.2. Analytical Techniques 2.2.L Procedures for Organics Appendix A Appendix B-j 72 73 74 76 76 76 76 78 78 86 ffO 100 103 109 109 109 129 141 147 OCR 0000373T2 INTRODUCTION TABLE OF CONTENTS FAST C GENERAL C.i. Special Reporting C.2. General Waste Analysis C.3. General Inspection Requirements C.4. Personnel Training C.5. Preparedness end Prevention C.6. Contingency Plan and Emergency Procedures C.7. Operating Record C.8. Availability, Betention, Disposition of Records C.9. Quarterly Report C.10. Annual Report C.ll. Recordkeeping Instructions GROUND WATER MONITORING C.12. Applicability C.13. Ground Water Monitoring System C.14. Sampling and Analysis / I C.15. Preparation, Evaluation, and Response C.16. Recordkeeping and Reporting CLOSURE AND POST-CLOSURE C17 Applicability C.18. Closure Performance Standard C.19. Closure Plan; Amendment of Plan C.20. Time Allowed for Closure r C*21. Disposal or Decontamination of Equipment C.22. Certification of Closure 4 i 149 149 149 150 151 151 152 154 157 158 156 158 158 161 161 161 161 162 163 164 164 164 164 165 166 166 CCR 000037373 C.23 Post-Closure Use of Property; Period of Care C.24. Post-Closure Plan; Amendment of Plan C.25. Notice to Local Land Authority C*26* Notice in Deed to Property CLOSURE AND POST-CLOSURE FINANCIAL REQUIREMENTS C.27. Applicability C.28* Cost Estimate for Facility Closure C.29. Cost Estimate for Post-Closure Monitoring, Maintenance USE AND MANAGEMENT OF CONTAINERS C.30. Applicability C.31* Condition of Containers C.32. Compatibility of Waste With Container C.33* Management of Containers * TANKS C.34. Inspections C.35. Special Requirements, Ignitable or Resctives Wastes C.36. Applicability C.37. General Operating Requirements C.38. Waste Analysis and Trial Tests C.39* Inspections C.4Q. Closure C.41. Special Requirements, Ignitable or Reactive Wastes C.42. Special Requirements, Incompatible Wastes SURFACE IMPOUNDMENTS C.43. Applicability C*44. General Operating Requirements C45 * Containment System C.46. Waste Analysis and Trial Tests Wiuui. 166 167 168 168 168 168 168 169 169 169 169 169 169 170 170 170 170 170 170 170 171 171 171 171 171 171 172 172 CCR 000037374 C.47. Inspections C*48< Closure and Post-Closure C.49. Special Requirements, Ignltable or Reactive Waste C.SO. Special Requirements, Incompatible Wastes WASTE PILES C.51. Appllcablllty C.52. Protection From Wind C.53. Waste Analysis C.54. Containment C.55. Special Requirements, Ignltable or Reactive Waste C.56. Special Requirements, Incompatible Waste LAND TREATMENT C.57. Applicability C 38* General Operating Requirements C.59. Waste Analysis C.60. Food Chain Crops C.6I. Unsaturated Zone Monitoring C.62. Recordkeeping C.63. Closure and Post-Closure C.64. Special Requirements, Ignltable or Reactive Waste C.65. Special Requirements, Incompatible Waste LANDFILLS C * 68 Applicability C.67. General Operating Requirements C.68. Surveying and Recordkeeping X i : C.69. Closure and Post-Closure C.70. Special Requirements, Ignltable or Reactive Waste C.71. Special Requirements, Incompatible Waste -- 'TO'-A.yu- sbmb*Jti-'wiwnwijBWBaww"--ismmrmmmFBmt&si&XtoiSX 172 172 172 173 173 173 173 173 173 173 173 174 174 174 174 174 174 175 175 176 176 177 177 177 177 177 178 178 CCR 000037375 C.72. Special Requirements, Liquid Wastes Special Requirements, Containers INCINERATORS C.74. Applicability C.75. General Operating Requirements C.76. Waste Analysis C.77. Monitoring and Inspections C.78. Closure THERMAL TREATMENT C.79. Applicability C.80. General Operating Requirements C.81. Waste Analysis C.82. Monitoring and Inspections C.83* Closure C.84. Open Burning; Waste Explosives CHEMICAL, PHYSICAL, AND BIOLOGICAL TREATMENT C.85. Applicability C.86. General Operating Requirements C.87. Waste Analysis and Trial Tests C.88. Inspections C.89. Closure C.90. Special Requirements, Ignltable or Reactive Waste C.91. Special Requirements, Incompatible Wastes SECURITY C.92. Requirements for Sites 178 179 179 179 179 179 179 179 180 180 180 180 180 180 181 181 181 181 181 181 182 182 182 182 " 182 IIIIUHilLJ 1 - -JUP' CCR 000037376 l|*kUl.ll PNlLlliSi,"L> U. --JLU' 11 ,, LIST OF FIGURES AND TABLES Reactivity Hazards -- Table A-l Maximum Concentration of Contaminants for Characteristic of EP Toxicity -- Table A-IU Hazardous Constituents -- Table A-IV Summary of Data and Information Available from Selected References on Hazardous Substances -- Table A-VA Selected References on Toxicity Hazardous Materials -- Table A-VB Hazardous Wastes from Non-Specific Sources (Transferred from EPA Regulations Section 26L31) -- Table A-VI Hazardous Wastes from Specific Sources (Transferred from EPA Regulations Section 261.32) Acute Hazardous Wastes -- Table A-Vm Toxic Wastes -- Table A-IX Extraction Procedure -- Figure A-VIU Figure A-l Figure A-2 Figure A-3 Figure A-4 . Figure A-5 Figure A-6 Figure A-7 Analytical Report -- Table B-l Recommended Sampler Selection and Sample Number -- Table B-2 Recommended Containers, Preservatives, and Holding Times for Analytical Parameters -- Table B-3 Sampling Points for Waste Containers -- Table B-4 5 7 8 22 23 25 - 27 34 47 60 66 67 67 68 70 71 72 77 81 82 89 -111- CCR OOOQ37377 Table B-5 i able B-6 91 gg Hazardous Waste Site Equipment -- Table B-7 101 Table B-8 102 Field Inspection and Analysis Protocol -- Table B-9 104 Chain of Custody Receipt -- Table B-10 105 Sample Labeling Tag -- Table B-ll 107 Sample Seal -- Table B-12 107 Analytical Techniques -- Table B-21 112 Chemical Analysis Test Methods -- Table B-22 121 Analytical Characteristics of Organic Chemicals -- Table B-22-1 122 Analytical Characteristics of Inorganic Species -- Table B-22-2 127 Sample Preparation/Sample Introduction Techniques 128 Major Classes or Organic Compounds Considered -- Table B-23 iso Organic Compound Classes for which Methods are Presented -- Table B-24 131 EPA List of Priority Pollutants -- Table B-4.B 133 Tentative Monitoring Phase Methods -- Table B-25 135 Summary of Conditions for Purge and Trap Analyses -- Table B-26. 136 Summary of Methods for Semi-Volatile Organic Priority Pollutants -- Table B-27 Existing 304 (h) Methods -- Table B-28 137 139 Additional Methods Being Proposed as 304 (h) Methods -- Table B-29 140 CCR 0000373^8 HAZARDOUS WASTE MANAGEMENT PROGRAM ANALYTICAL OPERATING PROCEDURES MANUAL PART A: PERMITTING GUIDELINES A IDENTIFICATION AND CLASSIFICATION OF HAZARDOUS WASTE LL INCLUSION OF A WASTE WITHIN THE SCOPE OF THE SYSTEM A waste material is identified as potentially hazardous and is included within the permitting responsibility of the Louisiana program: (1) when it has been included in Categories I or D of Appendix A of the Rules and Regulations of the Louisiana Hazardous Waste Management Plan presented on May 30, 1979, or as may be amended, or (2) when an analysis of the waste would indicate that it exceeds thresholds designated below defining the "moderate hazard level of 2" for the criteria listed in Category m of those Regulations. L2. OPERATIONAL THRESHOLD DEFINITION FOR CATEGORY HI WASTES A waste material is determined to have exceeded the "moderate hazard level threshold" (level 2 in Appendix A, Category HI) if any of the following test responses are obtained: L2.L Ignitability: The threshold for a liquid waste being regulated as ignitable is designated to be a flashpoint of less than 140 F (60 C)~as determined in either of the two tests ASTM Std. D-93-79 or ASTM Std. D-3278-78. In the case of solid wastes, where these tests are not applicable, a waste must be included within the hazardous waste management system when there is no assurance that the waste is free from ignition (spontaneous or otherwise) -- under all the climatic and storage circumstances associated with an accredited non-hazardous landfill This provision however, does not apply to such waste materials as garbage derived from households and in general to refuse consisting entirely of paper products, masonry and scrap lumber when these are in no way contaminated with flammable fluids or other materials as are covered under the hereinafter listed criteria of corrosivity, reactivity or toxicity. 380 CC* 00 00*1 Ignitable gases and oxidizer chemicals as prescribed in 49 CFR 173.151 and 173.300 (U.S. Department of Transportation) are deemed prima fade to be over the ignitable threshhold. NOTE: ASTM Std. D-93-79 describes the Pensky-Martens Closed Cup Tester and ASTM Std. D-3278-78, the Setaflash Closed Tester. 1-2.2. Corrosivity and Irritability: The threshold for determining that a waste presents a moderate level corrosive hazard and is to be included in the program is defined by any of the fallowing: Cl) The pH of the waste measures less than or equal to 2.5 (acid) or greater than or equal to 12.5 (base) -- as measured with a pH meter test described in EPA-600/4-79-020, the "Manual of Methods fra* Chemical Analysis of Water and Wastes" (March, 1979), or (2) The waste corrodes steel (SAE grade 1020) at a rate greater than 0.250 inches per year at 130 F according to the procedure described in NACE Std. TM-01-69. (3) An albino rabbit patch test (Paragraph 1.3.5) for dermal corrosivity or irritability (which shall be invoked when the waste has not been characterized by prior analysis or experience with known constituent properties) showing that the waste would result in either (a) visible destruction or irreversible alterations (ulceration or necrosis) to the skin -- (corrosivity), or (b) a local inflammatory reaction carrying an empirical score of 5 or more -- (irritability). . 1.2.3. Reactivity: Wastes regulated under this category are those which simply by virtue of being commingled with other materials lead to adverse health or environ mental effects through heat generation, violent reaction, or release of toxic fumes of gases. While the level of hazard determination in this category is largely judgmental, the basic criteria for incompatibility described in Table A-I should not be violated in any disposal facility. Simple listing in Table A-I such as for group 4 A does not imply the material is hazardous per se except through its potential fra* reactivity. Explosives listed in 49 CFR 173.51, 173.53, and 173.88 are to be included in the hazardous wastes management system. 1.2.4. Toxicity: A potential toxicity hazard is deemed to exist for those wastes specifically listed n the Rules and Regulations (Table A-n), for those contained within CCR 000037381 the EPA Interim Primary Drinking Water Standards List (Table A-HI), for those in the EPA Hazardous Constituents List (Table A-IV), and for all those wastes containing substances with an oral LD&0 in humans less than or equal to 800 mg/kg. The generator's responsibility far characterization may be accomplished by analytical testing or by conscientious application of other well documented process knowledge. Whether or not the waste with this potential hazard is to be within the Hazardous Waste Management Program (i.e. is deemed to cross the "moderate'' toxicity hazard level of 2) is to be determined by the criteria of Section 1.2.4J applied to waste liquids and/or for extracts and residues drawn from solids and sludges. Preparation of leachate should follow the procedures described in Section 1.3.2. Attention is called to preemptive designation of the hazardous character of wastes cited in paragraph 1.2.5. L2.4.1. Threshold Toxicity Criteria; A waste containing a potentially toxic component (as defined in 1.2.4.) shall be presumed subject to regulation within the Hazardous Waste Management Plan except when the following criteria apply: L Acute Toxicity Thresholds The following conditions provide a basis for excluding wastes with subthreshold concentrations of potentially toxic materials from the Louisiana Hazardous Waste Management Program: A The aqueous fraction of the waste or its leachate (from the procedure of paragraph 1.3.2)exhibits an oral LD-0 toxicity far rats greater than or equal to 500 mg/kg (or a deemed Equivalent of 1220 mg/kg - for mice and 80 mg/kg for humans), and B. For those portions of the aggregate waste (when a solid or nonaqueous mixture) or the residue from the leachate extraction procedure of paragraph 1.3.2 -- which are in a state of aggregation less than or equal to 1mm (50 mesh), an oral LDS toxicity for rats^or'greater than or equal to 50 mg/kg is determined, and at C. The waste contains a concentration of less than 100 times the EPA primary drinking water standards in either its liquid phase or extract (such standards being listed as applicable in Table A-ni), and D. The concentration of those priority pollutants reasonably expected on process grounds (Table A-IV) yields a ratio sum as defined below of less than or equal to 0.2, i.e. in the event such ratio sum is greater than only 0.2, the bioassay protocol of Section L3.3 is conducted and yields a 96 hr. TLC-n greater or equal than 560 Q mg/L (Q represents the ratio of the weight of the raw wet waste to the dry weight.) NOTE: Sources for the aforementioned toxicity statistics are presented in Tables A-VA, and A-VB. H. Chronic Toxicity Guidelines for the characterization of chronic toxicity situations are being deferred until subsequent drafts of these guidelines are issued. They will likely involve tests for bioaccumulation (octanol/water partition coefficients and gross conversion efficiency tests --Weininger, D., University of Wisconsin dissertation, 1978) and for mutagenic activity. At present, potential hazard due to chronic toxicity is handled through the specific listing of wastes in Category I of the Rules and Regulations. 1*2.5. Pre-emptive Designation in Hazardous Waste Status: Wastes listed in Tables A- VI, VII, vm and IX (corresponding roughly to Category I wastes of the Louisiana program Rules and Regulations) are expressly deemed hazardous and subject to regulation under this program. The program intent is in effect to supplement the list of Category I wastes originally presented in the May 30, 1979, Louisiana Rules and Regulations with the EPA derived lists presented in Tables A-VI through IX. -4- CCR 000037383  I & iw i TABLE A-I REACTIVITY HAZARDS (Materials in any subgroup A should not have contact with those in the corresponding subgroup B by reason of causing the indicated consequence.) Group 1 A Group 1B Acetylene sludge Alkaline caustic liquids Alkaline cleaner Alkaline corrosive liquids Alkaline corrosive battery fluid Caustic wastewater Lime sludge and other corrosive alklines V Lime wastewater ^Lime and water Spent caustic Acid sludge Acid and water Battery acid Chemical cleaners Electrolyte acid Etching acid liquid or solvent Liquid cleaning compounds . Pickling liquor and other corrosive acids \3pent acid Spent mixed acid Spent sulfuric acid Potential consequences: Heat generation, violent reaction Group 2 A Group 2 B Asbestos waste and other toxic wastes Beryllium wastes Unrinsed pesticide containers Waste pesticides Cleaning solvents ' Data processing liquid Obsolete explosives Petroleum waste Refinery waste Solvents Waste oil and other flammable and explosive wastes Potential consequences: Release of toxic substances in case of fire or explosion Group 3 A ^Aluminum Calcium Lithium Magnesium Potassium Sodium Zinc powder -and other reactive metals and metal hydrides Group 3 B Any waste in Group 1A or I B Potential consequences: Fire or explosion, generation of flammable hydrogen gas -5- CCR 000037384 \ucohols Water TABLE A-I (continued) Group 4 A Group 4 B Any concentrated waste in Groups 1A or 1B Calcium Lithium Metal hydrides Potassium Sodium so, ci, socl pa, ch, s, ci, and other water reactive wastes Potential consequences: Fire, explosion, or heat generation, generation of flammable or toxic gases Group 5 A Nu, Alcohols Aldehydes Halogenated hydrocarbons Nitrated hydrocarbons and other reactive organic compounds and solvents Hnsaturated hydrocarbons Group 5 B Concentrated Group 1 A and 1 B wastes Group 3 A wastes Potential consequences: Fire, explosion or solvent reaction Group 6 A Group 6 B Spent cyanide and sulfide solutions Group 1 B wastes Potential consequences: Generation of toxic hydrogen cyanide or hydrogen sulfide gas Group 7 A Group 7 B Chlorates and other strong oxidizers Chlorine Chlorides Chromic acid Hydrochlorides Nitrates Nitric acid fuming Perchlorates Permanganates Peroxides Acetic acid and other organic acids Concentrated mineral acids Group 2 B wastes Group 3 A wastes Group 5 A wastes and other flammable and combustible wastes Potential consequences: Fire, explosion, or violent reaction -6- CCR 000037385 TABLE A-JII Maximus Coaeehtration of Contaminants for Characteristic of X? Toxicity EPA Hazardous Vaste Number Contaminant Maximum Concentration (milligrams per llte) 0004 Arsenic ................................. 5.0 0005 Sari urn ........................................................................ 10 0.0 0006 Cadmium......................................................................... l.o 0007 Chromium....................................................................... 5.0 D008 Lead............................ 5.0 0009 Mercury......................................................................... 0.2 0010 Selenium....................................................................... 1.0 0011 Silver....................................... 5.0 D012 0013 0014 0015 0016 0017 Endrin (1,2,3,4,10,10-hcxaehloro-l 7-e poxy-1,4,4a,5,6,7,8,8a-octahydro-l 4-endo, endo-5,8-dlmethano naph thalene ................ ....................... ........................... 0.02 Lindane (1,2,3,4,5,6hexachlorocyclohexane, gamma isomer......................................................................... 0.4 Methoxychlor (1,1 ,l-Triehloro-2,2-bis [p-methoxyphenyl]ethane) . 10.0 Toxapbene (C^oHioClg, Technical chlorinated camphene, 67-69 percent chlorine)........................ ....................... 0.5 2,4-0, (2,4-Dichlorophenoxyacetic mcid).............................................................................. 10.0 2,4,5-TP Silvex (2,4,5- Trichlorophenoxypropionlc meld)........... 1.0 -7- jl CCR 000037386 -naSiei /J-JT HAZARDOUS COHS?ITU?fTS Acetaldehyde ( Ace ca zc) phenyloer eury Ace to nitrile 3 - ( aipha-Acs tonylbeazyl)-4hydroxycounaria and saxes 2-Acatylaminofluorene Acetyl chloride l-Aeetyl-2-thioure* Acrolein Acrylamide Acrylonlexile Aflacoxlna Aldrln Allyl alcohol Aluminum phosphide 4-Aminobiphenyl 6-Amino-1,1a,2,8,34,8b-hexahydTo- 8-(hydroxymethyl)-Sa-methoxy-5methylcarbamate axirino(2',3!:3,4) pyrrolo(l,2-a)ladole-4,7-dloae (ester) (Mitomycin C) 5-(Aminomethyl)-3-isoxazoloI 4-Amiaopyridin* Amit r o1e Antimony and compounds, S.O.S.* Ar amice Arsenic and compounds, N.Q.S. * The abbreviation tf.O.S signifies chose members of the general class "not otherwise specified" by name in this listing. CCH 0o3 TABLE A-IV ( ontinued) i ?S*Qlc.acid Arsenic peatoxlde Arsenic trioxide - - -. -Auramine Azaserine Bariua end compounds, N.O.S. Barium cyanide Beax[c]acridine Benz{a]anthracene Benzene Benzenearsonic acid Benxauethiol B-enxidine Benzo[a}anthracene Benzo[b]fluoranthene Benxo[j]fluoranthene Benzo[a]pyrene Benzotrichloride Benzyl chloride Beryllium and compounds, N.0S. Bit(2-chloroethoxy)aethane Bi3(2-chloroethyl) ether N,H-Bis(2-chloroethyl)-2-naphthylaoine Bia(2-ehloroisopropyl) ether Bie(chloroaethyl) ether Bts(2-ethylhexyl) phthalate Broaoaeetone Brooomethane CCR 000037388 -9- TABLE A-IV (continued) 4-Bromophenyl phenyl ether Brucine 2-Butaaone peroxide Butyl benzyl phthalate 2-see-Butyl-4,6-dinitrophenol (ONBP} Cadmium and compound*, N.O.S. Calclua chroaacc Calclua eyanld* Carbon disulfide Chloraabucll Chlordana (alpha and gamma isomers) Chlorinated benzenes, tt.O.S. Chlorinated ethane, S.O.S. Chlorinated aaphchaiene, S.O.S. Chlo-rlnacad phenol, S.O.S. Chloroacecaldehyde Chloroalkyl ethers p-Chloroaniline Chlorobenzene Chlorobenzilaee l*(p~Chlorobenzoyl)-5-nethoxy2-methyliadolc-3-acetic acid p-Chloro-a-ereeol l"Chloro2,3"epoxybutane 2-Chloroethyl vinyl ether ____________________ ___ Chloroform Chloromethane CCR 000037389 jPgjpa I* Mlill J ' J 'Hr?.- TABLE A-IV (continued) Chloromethyl methyl ether 2-Chlor.onaphthalene 2-Chlorophenol l-(o-Chlorophenyi)thiourea 3- Chloroproplonitrile alpha--Chlorotoluene Chlorotoluene, N.O.S. Chromium and compounds, 15.0.$. Chrysene Citrus red No. 2 Copper cyanide Creosote Crotonald-ehyde Cyanides (soluble salts and complexes), N.O.S. Cyanogen ^ Cyanogen bromide Cyanogen chloride Cycasln 2-Cyelohexyl-4,6-dlnitrophenol Cyclophosphamide -Daunomycln dod k ODE DDT Dial,late 0ibent[a,h]acridine -11- CCB. 000037390 f 'll r V. TABLE A-IV (continued) Dibeaz[a,j]acrldiaa Dibnnz[a,hJanthracene (Dibenzo[a,hj anthracene) 7H-Dibenso[c,3]carbaaola DIbenzo(a,]pyrana Dibenso[a,hJpyrane Dibenzo[a,ijpyrene 1.2-Dibroao~3-ehlotopropana 1.2-DIbronoechana 0lbrsaoaathane Di-n-butyl phchalaca Dlehlorobenzene, N.O.S. 3,3'-Dlehlorobcnzidine 1.1-Diehloroethane * 1.2- Diehleroethane traaa-1,2-Dichioroethena Oichloroethylene, N.O.S. 1.1-Diehloroechyiena Diehloromechane 2.4-Dichlorophenol 2,6-Dichlorophenol 2.4-DichloropbenoxyaeaCic acid (2,4-0) Dichloropropana Dichlorophenylarsine 1.2-Dichloropropana Dichloropropanol, N.O-.S. Dichloropropena, N.O.S. CCR 000037391 TABLE A-IV (continued) 1,3-Dichloropropeae Dieldrin Diepoxybutane Diethylaraine 0,0-Diethyl-s*(2-ethylthio)cthyl ester of phogporothioie acid 1,2-Diethylhydrazine 0,O-Diethyl-S-aethyleeter pbosphorodichioic acid 0,0-Diethylphoaphoric acid, 0-p-aitrophenyl eater Diethyl phthalate 0,0-Diethyl-0(2-pyrazioyl)phosphorothioate / Diethyletilbestrol Dihydrosafrole 3.1-Dihydrozy-alpha-CBechylaaiQoJaethyl benzyl alcohol Di-iaopropylfluorophosphate (DFP) Dinet boats 3,3Dimethoxybenzidiae p-Dlmethylaaiaoazobaazeaa 7,12-Diaetbylbeaz[a]aathracaae 3,3 '-Dimethylbenzidine Diaethylcarbamoyl ehloT4.de 1.1-Diaethylhydrazi-ae 1.2-Diaethylhydrazine 3.3-Diaathyl-l-(aethylthio)-2-butaaone0-((nethylaaino) carbonyl)oxias Dinethylaitrosaanine f) alpha .alpha-Diaethylphenethylaaine \ -IS- J J-f CCR 000037392 TABLE A-IV (continued) 2.4-Diaethyl phenol Dimethyl phthalate Dimethyl sulfate Diaitrobenzeae, K.O.S. 4.6-Diuitro-o-cresol and sales 2.4-Dinitrophenol 2.4-Dinitrotolueae 2.6-Dialerocoluene Di-a-oceyl phthalate l, 4-Dioxaae 1,2-Diphenylhydraxine Di-n-propylaltroeamine Diittlfocon 2.4-Diehiobiurat Eadosulfan Endrin and metabolites Eplehlorohydrln Ethyl cyanide Ethylene diamine Echyleaeblsdlthiocarbaaaee (E3DC) Ethyleneiaine Ethylene oxide Ethyleaethlourea Ethyl methaneaulfonate Fluoranthene G Fluorlna 2-Fluoroacetamide twilv-aST1 CCR 000037393 TABLE A-IV (continued) Fluoroacetic acid, sodium salt Fo raaldehyde Clycidylaldehyde Haloaethene, N.O.S. Heptachlor Heptachlor epoxide (alpha, beta, -and gamma isomers) Hexaehlorobenzene Hexaehlorobutadiene Bexachloroeyclohexaue (-all isomers) Hexachlorocyclopentadiene Hexaehloroethane 1,2,3,4,10,lO-Hexaehloro-1,4,4a,3,8,8a-hexahydro- 1,4:5,8-eado,endo-dinethanonaphchalene Hexaehlorophene Hexaehloropropens Hexaethyl tetraphosphate Hydrazine Hydrocyanic acid Hydrogen sulfide lndeno(l,3,3-c, d);pyrene Iodomethane Itocyanic acid, methyl -ester Isosafrole Kepone Lasioearplne Lead and compounds, N*0>S< Lead acetate ctft 00003-r^4 -15- v,: TABLE A-IV (continued) Lead phosphate Lead subacetate Maleic anhydride Malononicrila Malphalan Mercury and compounds, N.0.$. Mechapyrilene Hethomyl 2-Methylaziridiae j-Mathylcholanthrene 4,4 '-Methylene-bis-(2-ehloroenilin) Methyl ethyl- ketone (MEK) Methyl hydrasine 2-Methyllactonitrile Methyl methacrylate Methyl aethaaeeulfoaate . 2-Metby1-2-(methylthio)propionaldehyde- o-(methyl carbonyl) oxime a H-Methyl-H *-aitro-H-nierosguaaidiae Methyl perethion Methylthiouracil Mustard gas naphthalene 1,4-Haphthoouiaone l-Kaphthylemine Z-Maphehylamlne l-Haphthyi-2-chiourea Mickel and compounds, N.O.S>^ CCR 000037395 TABLE A-IV (continued) ii Nickel carbonyl, Nickel cyanide Nieocin* and sales Nitric ozid* p-iti troaniline Nitrob*azn t, K j Nitrogen dioxide Nltroga mustard and hydrochloride salt Nitrogen mustard N-oxid* -and hydrochloride salt Nitrogen peroxide Nitrogen tetroxlde Nitroglycerin* 4-Nitrophenol 4-Ni troqulnolin*-l-oxid* Nitrosamine, N.O.S. N-Nitrosodi-N-butylemlne N-Nitrosodiethanolamine N-Nitrosodieehylamin* N-Nitrosodim* thylaaine N-Nitrosodiphenylamine N-Nitrosodi--N-propylamine N-Nitroso-N-thylur*a N-Nitrosomethyletbylamin* N-Nitroso-N-m*thyiurea N-Nitroso-N-methylurethane N-Nicrojonethy1vinyl amine N-Ni tro'somo rp ho line 0000J,b -17 OCR A-IV (continued) --larir-iin-iV' in ? N-Nltrosonornicotine N-HitrosopiperidIn H-Hltrosopyrrolidine Mierioureola< 5-Hitro-o-toluidine Octeaethylpyrophosphotaside Oleyl alcohol condensed rich 2 aoles ethylene oxide Osaiua tetroxlde 7*0xabtcyclo{2.2.1]heptane-2,3-dicarboxyllc acid Paraehlon Pentachlorobenzene Pencachloroethane Pentaehloronltrobenzene (PCtfB) Pentaehlorophenol Phenacetin Phenol Phenyl dlehloroerslne Phenylaereury acetate N-P h e ny11 hloor ea Phosgene Phosphine Phosphorochloie acid, 0,0-'dlethyl ter, O-ester with benzene sulfonamide Phthallc acid esters, N.O.S. Phthallc anhydride Polychlorinated biphenyl, S.O.S. CCR 000037397 % i TABLE A-IV (continued) Potassium cyanide Potassium silver cyanide Pronaaide 1.2-Propanediol 1.3-Propane sultone Propionitrile Propylthiouracil 2-Propyn-l-ol Pryidin* Reaorpine Saccharin Safrole Selenious acid Selenium.end compounds, N.O.S. Selenium sulfide Selenourea Silver and compounds, N.O.S* Silver cyanide Sodium cyanide Streptocotoein Strontium sulfide Strychnine and malts 1,2,4,5-Tetrachlorobenxene 2,3,7,8-Tetrachlorodihenao-p-dioxin (TCDD) Tetrachloroethane, N.O.S. -19- CCR 000037398 TABLE A-IV (continued) t, 1,1,2-Tecrachloroethane 1,1,2,2-Tetrachloroethane Tecrachloroethene (Tetrachloroethylene) Tetrachloromcthane 2,3,4,6-Tetrachlorophenol Tetraethyldithiopyrophospbate Tetraethyl lead Tetraethylpyrophosphate Thallium and compounds, N.O.S. Thalllc oxide Thallium (I) acetate Thallium (X) carbonate Thallium (X) chloride Thallium (X) nitrate Thallium selenite Thallium (X) sulfate Thioacetamide Thlosemicarbazide Thiour ea Thiur am Toluene Toluene diamine o-Toluidine hydrochloride * Tolylene diisocyanate Toxaphene Trlbromomethane 1,2,4-Trichlorobenzene CCR 000037399 2L TABLE A-IV (continued) 1.1.1- Trichloroethmne 1.1.2- Trichloromthmn Trichloroethene (Trichloroethylene) Trichloromethmnethiol 2.4.5- Trichlorophnol 2.4.6- Trichlorophenol 2.4.5- Triehlorophanoxymcetlc meld (2,4,5-T) 2.4.5- Trichlorophenoxypropionie meld (2,4,5-TP) (Silvex) Trichloropropmne, K.O.S. 1.2.3- Trichloropropmnt 0,0,0-Trietbyl pbospborothiomt* Trlnitrobenzene Tri*(1-mxridinyl)phosphine sulfidm Tris(2,3-dlbreB0propyl) phosphate Trypmn blue Drmcil mustard Urethane Vanadie meld, ammonium male Vanadium pmneoxldm (dust) Vinyl chloride Vinylldmnm chloride Zinc cyanide Zinc phosphide 4OO OOOO31 CO?21- m\ Bef. No. taxicities* Aquatic toxl- citlee* (96-hour LCjO's) TABLE h V. SlfrlMAKY OF DATA AND INFORMATION AVAILABLE FNON SELECTED EEFIBENCES ON RAZABDOUS SUBSTANCES FlasaubUltlee Corroeivitlas, Irrita tion , and Sensi tization Exploaivltles, and Beac- t Wit lea Vapor Pressures TLV's Physical Da tab Trade Names and Synonyms 14 4- 44 24 - 4 4 - 4 4 4 - 3 4 4- - - - - - - - A + 4- - 4 -- - 4 4 - 54 - 4 4 4 4 4 4 4 iV--i- + - - 4 4 - -4 4 4-- - - - --4 4 s4 - - - - - 4 - 4 9- - 4 4 4 4 4 4 - 10 - - 4 4 4 - - - * - 11 - - 4 4 4 4 4 4 - 12 - - 4 4 4 - 4 4 4 13 - - 4 + 4 - - 4 4 1A - - 4 - 4 - - - 15 - - 4 - 4 - 4 4 - 16 - - 4 4 4 44-- 17 4- 4 4 4 4 444 18 - - 4 - - 4 4 4 4 19 - - - - - 4 - 4 - 20 4 4- - 4 - 4 4 4 4 21 4 4- - - - - - -- * 22 4- - 4 4 - 4 4 4 - (ixl other-MIPS!! dacniinnti) * Only reference* tdtich provide specific LDjq and LCso data are indie 1 ted may provide general toxicological information on Substances. Other references indicated ^ Physical state, boiling point, melting point, molecular weight, solubility, etc. TABLE A-VB SELECTED REFERENCES ON TOXICITY HAZARDOUS MATERIALS 1. U. S. Department of Health, Education, and Welfare, National Institute for Occupational Safety and Health, "Registry of Toxic Effects of Chemical Substances", June 1976, Rockville, Maryland. .2 Patty, F. A. Editor., "Industrial Hygiene and Toxicology", Vol. I and n. Interscience Publishers, 1963, New York, N.Y. 3. McKee, J. E. and H. W. Wolf, "Water Quality Criteria", 2nd Edition, 1963, Resource Agency of California, State Water Resources Control Board. 4. Sittig, M., "Toxic Metals. Pollution Control and Worker Protection" 1976, Moyes Data Corporation, Park Ridge, N. J. 5. International Technical Information Institute, "Toxic and Hazardous Industrial Chemicals Manual", 1975, Tokoyo, Japan. .6 Widhols, M. Ed, "The Merck Index", 9th Edition, 1976, Merck A Co., Inc. Rahway, N. J. 7. Berg, G. L., Editor, "Farm Chemicals Handbook", 1976, Meister Publishing Co, Willoughley, Ohio. .8 American Conference of Governmental Industrial Hygienists, "Documentation of Threshhold Limit Values (TLV's)", 3rd Edition, 1971, Cincinnati, Ohio. 9. Steere, N. V., Editor, "Handbook of Laboratory Safety", 1967, The Chemical Rubber Co. Press Inc., Cleveland, Ohio. .10 U. S. Department of Transportation, "Code of Federal Regulations", Title 49, Parts 171 -177, September 27,1976, Federal Register, Washington, D.C. .11 Sax, N. L, "Dangerous Properties of Industrial Materials", 4th Edition, 1976, Van Nostrand Reinhold Co., New York, N. Y. (5th Edition, 1979). .12 Hawley, G., Editor, "The Condensed Chemical Dictionary", 9th Edition, 1977, Van Nostrand Reinhold Co., New York, N. Y. 13. National Fire Protection Association, "Hazardous Materials", 6th Edition, 1975, N.F.P.A., Boston, Mass. 14. Bretherick, L.,"Handbook of Reactive Chemical Hazards", 1975, Chemical Rubber Co. Press, Inc., Cleveland, Ohio. 15. Manufacturing Chemists Association "Guide for Safety in the Chemical Laboratory", 2nd Edition, 1972, Van Nostrand Reinhold Co., New York, N. Y. V r;"1 OCR 00003740Z TV Baskin, A.D., Editor, "Handling Guide far Potentially Hazardous Materials", 1974, Material Management and Safety, Inc., Niles, Illinois. U. S. Coast Guard, "CHRIS", Hazardous Chemical Data", Vol. I and n, 1974, CG-446-2, U. S. Department of Transportation, Washington, D.C. Chemical Rubber Co., "Handbook of Chemistry and Physics", 56th Edition, 1977, CRC Press Inc., Cleveland, Ohio. Perry 6c Chilton, Editors, "Chemical Engineers Handbook", 5th Edition, 1973r McGraw-Hfll Book Company, New York, N. Y. Verschueven, K., "Handbook of Environmental Data an Organic Chemicals", 1977, Van Nostrand Reinhold Co., New York, N, Y. National Academy of Sciences, "Water Quality Criteria", EP A-R3-73-033,. December 24, 1975. U. S. Department of Health, Education, and Welfare, National Institute for Occupational Safety and Health, "Criteria for a recommended standard....Occupational Exposure to Polychlorinated Biphenyls (PCB's)", "September 1977 (Other NIOSH criteria documents have been prepared on the materials listed on the next page). -24- 000037403 CCR Industry EPA Hazardous Haste Number Hazardous Haste T Hazard Code HAZARDOUS WASTES FROM NON-SPECIFIC SOURCT 3 ( TRANSFERRED FROM EPA REGULATIONS Section 261. H) CCR 0 0 0 0 3 7 4 0 4 Generic F001 F002 rtoi F003 F004 F005 F006 F007 The spent halogenated solvents used In degreasing, tetrachloroethylene, trichloroethylene, methylene chloride, 1,1,1-tricliloroethane, carbon tetrachloride, and the chlorinated fluorocarbons; and sludges from the recovery of these solvents In degreasing opera tions The spent halogenated solvents, tetrachloroethylene, methylene chloride, trichloroethylene, 1,1,1-trichloroethane, chlorobenzene, 1,1,2-trichloro-1,2,2trlfluoroethane, o-dichlorobenzene, trichlorofluoromcthane and the still bottoms from the recovery of these solvents The spent non-halogenated solvents, xylene, acetone, ethyl acetate* ethyl benzene, ethyl ether, n-butyl alcohol, cyclohexanone, and the still bottoms from the recovery of these solvents The spent non-halogenated solvents, cresols and cresyllc acid, nitrobenzene, and the still bottoms from the recovery of these solvents The spent non-halogenated solvents, methanol, toluene, methyl ethyl ketone, methyl isobutyl ketone, carbon disulf tde, isobutanol, pyridine and the still bottoms from the recovery of these solvents Hastewater treatment sludges from electroplating operations Spent plating bath solutions from electroplating operations (T) (T) (I) IT) ( l i T) IT) (n,r Industry EPA Hazardous Haste Number Hazardous Haste i Hazard Code 1| pooe | Plating bath sludges from the bottom of plating baths j (R,T 1 j from electroplating operations j 1 1\ 1\ 1 FQ09 | Spent stripping and cleaning bath solutions from j {R,TJ 1 11 1 FOlO 1 J1 j electroplating operations t j Quenching bath sludge from oil baths from metal heat j <H,T> j treating operations j 11 1I F011 | Spent solutions from salt bath pot cleaning from | (R,T> 1 | metal heat treating operations 11 t1 | 1| 1 F012 | Quenching wastewater treatment sludges from metal | (T) 1 j heat treating operations j 11 1 | to T 1 F013 1 | Flotation tailings from selective flotationfrom 1 mineral metals recovery operations |m | 11 1 | 1 F014 1 \1 1 F015 1 11 1 F0I6 | Cyanidation wastewater treatment tailing pond sedlmentj j from mineral metals recovery operations j 1 | Spent cyanide bath solutions from mineral metals 1 j 1 recovery operations | I Dewatered air pollution control scrubber sludges from j j coke ovens and blast furnaces | (T) (R*i*) (T) 11 1 o o 71 so<7i000 Industry Hood Preser vation EPA Hazardous Waste Humber Hazardous Waste Bottom sediment sludge from the treatment of waste- WaterS from wood preserving processes that use * creosote and/or pentachiorophenol I |Hazard i Code f 1---------I (T) I TABLE-A-'VH HAZARDOUS WASTES PROM SPECIFIC SOURCES (TRANSFERRED FROM EPA REGULATIONS Section 26U2) CCR 0 0 0 0 3 7 4 0 6 Inorganic Pigments Mi I Organic Chemicals KOI 2 Wastewater treatment sludge from the production of chrome yellow and orange pigments Wastewater treatment sludge from the production of molybdate orange pigments Wastewater treatment sludge from the production of zinc yellow pigments I (T) j ) ( (T) j I t (T) Wastewater treatment sludge from the production of chrome green pigments | (T> Wastewater treatment sludge from the production of chromi oxide green pigments {anhydrous and hydrated). (T) Wastewater treatment Sludge from the production Of iron blue pigments (T) Oven residue ftorn the production of chrome oxide green pigments___________________________________ ,, _______________ (T) Distillation bottoms from the production of acetalde hyde from ethylene (T) Distillation aide cuts from the production.of acetal- | (T>. dehyde from ethylene j Bottom stream from the wastewater stripper in the production of acrylonitrile <H,T) Still bottoms from the final purification of acrylonitrile in the production of acrylonitrile (T) 1! Industry| EPA Hazardous | - Waste Humber | ; Hazardous Waste t Hazard | Code 1l 1 , t ' r~ i K013 I , Bottom stream from the acetronItrile column In the 1 <H,T> 1 !, 1 i production of acrylonitrile 1 11 11 1 K014 | Bottom from the acetronltrile purification column 1 I'D 1 | in the production of acrylonitrile i> i 1a 1 K015 tI t Still bottoms from the distillation of benzyl chloride| (T) i1 i K016 | Heavy ends or distillation residues from the pro- im 1 | duct ion of carbon tetrachloride 1P i1 i i 1 K0L7 ) Heavy ends (still bottoms) from the purification 1 IT) I! 1 I ( column in the production of epichlcrohydrin | 1 1 i t KOI 8 | Heavy ends from fractionation in ethyl chloride 1 (T) 1 1 production I1 t1 1 1 1 K019 | Heavy ends from the distillation of ethylene I (T) \ I dichloride in ethylene dichloride production | 11 1 1 K020 11 t K021 | Heavy ends from the distillation of vinyl chloride | in vinyl chloride monomer production 11 | Aqueous spent antimony catalyst waste from fluoro- im i i (m 1 \J 1 methanes production 11 I ] 1 K022 | Distillation bottom tars from the production of t (T) 1a I jK 11 1 phenol/acetone from cumene i1 1 1 1 K 023 1 Distillation light ends from the production of f <T) 1 I K024 I phthalic anhydride from naphthalene i 1 1 | Distillation bottoms from the production of phthalic 1 (T) t 1 , , K025 I anhydride from naphthalene f Distillation bottoms from the production of nitro- 1 l1 t (T) 1 i t benzene by the nitration of benzene 1 CCR 0 0 0 0 3 7 4 0 7 \ ! * -2 9 - CCR 0 0 0 0 3 7 4 0 8 r Industry| EPA Hazardous j ( Waste Humber j < Hazardous Waste I Hazard | Code 11 1t ( l ! K026 |! j Stripping still tails from the production of methyl 1 (T> ff 11 1 | K027 1( t ! K028 t | ethyl pyridines i *- I Centrifuge residue from toluene dlisocyanate f production I Spent catalyst from the hydrochlorinator reactor in t (R,T) 1 (T) 1 |V i | Ifhe production of 1,1,1-trichloroethane t1 1 K029 | Waste from the product stream stripper in the 1 IT) 1 | production of 1,1,1-trichloroethane 11 11 1 K030 I Column bottoms or heavy ends from the combined pro- 1 (T> 1 I duetion of trichloroethylene and perchloroethyicnc 1 1 _T1_ - ' ---------------------------------------------------------------------------------------- Pesti cides 1 1 11 ( K031 | By-products salts generated in the production of MSMA 1 | and cacodylIc acid 1 (T) K032 1 11 t Wastewater treatment sludge from the production of | chlordane l1 1 IT) 1 K033 I Wastewater and scrub water from the chlorination of 1 (T) 1 I cyclopentadiene in the production of chlordane 11 1 K034 1 1 1 i K035 1 1V ! i ' K036 i iV t 1 1 K037 i 1 I Filter solids from the filtration of hexachloroI cyclopentadiene in the production of chlordane 1V | Wastewater treatment sludges generated in the proI duction of creosote j Still bottoms from toluene reclamation distillation | in!the production of disuifoton 1* ) Wastewater treatment sludges from the production of I of disiilfoton 1 (T) 1 IT) 1 IT) 1 tr) i t Industry Explosives J Petroleum Refining' 1 5 1 5; I EPA Hazardous Waste Humber , . K038 K039 i | | 1 1 | t 1i I t Hazardous Waste Wastewater from the washing and stripping of phorate production * Filter cake from the filtration of diethylphosphorodithoric acid in the production of phorate Hazard Code (T) (T) K040 K041 K042 K043 K044 K04S K046 K047 KO40 | 1 I l | I t1 | t I 1 | 1 "1 1 | \ I I I | ! | ! (1 t Wastewater treatment sludge from the production of , phorate Wastewater treatment sludge from the production of toxaphene Heavy ends or distillation residues from the distillation of tetrachlorobenzene in the production of 2,4* 5-T 2,6-Dlchlorophenoi waste from the production of 2,4-D ----------------------------------------------------------------------------------------------------------- Wastewater treatment sludges from the manufacturing and processing of explosives | Spent carbon from the treatment of wastewater contalninq explosives Wastewater treatment sludges from the manufacturing, formulation and loading of lead-based initiating compounds Pink/red water from TNT operations Dissolved air flotation {DAF) float from the petroleum refining industry 1 l 1 | | j i | t J | j (T) (T) (T) IT) {n) on (T) on (T) CCR 0 0 0 0 3 7 4 0 9 t I \ Industry ' i i EPA Hazardous | Haste Number | Hazardous Haste | Hazard Code 1 1 K049 ; K050 ; | Slop oil emulsion solids from the petroleum refining j i industry ( iV | j Heat exchanger bundle cleaning sludge from the petro-j j leum refining Industry | m (T) K051 ) K052 | API separator sludge from the petroleum refining | industry | ( Tank bottoms (leaded) from the petroleum refining 1 industry | (T) j j IT) j -3 1 - CCR 0 0 0 0 3 7 4 1 0 Leather Tanning Finishing K053 Chrome (blue) trimmings generated by the following | subcategories of the leather tanning and finishing | industry) hair pulp/chrome tan/retan/wet finish; hairt save/chrome tan/retan/wet finish} retan/wet finish) | no beamhouse; through-the-blue) and shearling | (T) K0S4 Chrome (blue) shavings generated by the following subcategories of the leather tanning and finishing industry) hair pulp/c hr online tan/retan/wet finish; hair save/chrome tan/retan/wet finish; retan/wet finish; no beamhouse; through-the blue; and shearling (T) K055 Buffing dust generated by the following subcate gories of the leather tanning and finishing industry: hair pulp/chrome tan/retan/wet finish; hair save/ chrome tan/retan/wet finish; retan/wet finish; no beamhouse; and through-the blue <T) K056 i l Sewer screenings generated by the following nubcategorles of the leather tanning and finishing industry) hair pulp/chrome tan/retan/wet finish; hair save/ chrome tan/retan/wet finish; retan/wet finish; no beamhouse; through-the-blue; and shear1Ing (T) iUi*. --h - i, it industry :' Vto3 I run and Steel ,i- ii 1 f s. ! qf I EPA Hazardous' Waste Humber : [ \ KQ57 * 1 )i f 1 K050 K0 59 K060 K061 K062 K063 * Hazardous Waste | Hazard I Code Wastewater treatment sludges generated by the l following subcategories of the leather tanning and finishing industry; hair pulp/chrome tan/retan/wet finish) hair save/chrome tan/retan/wet finish) retan/- wet finish) no beamhouse; through-the-blue and shearling (T) Wastewater treatment sludges generated by the following subcategories of the leather tanning and finishing industry: hair pulp/chrome tan/retan/wet finish) hair save/chrome tan/retan/wet finish) and through-the-blue 1 (R.T Wastewater treatment sludges generated by the following subcategory of the leather tanning and finishing industry: hair save/non-chrome tan/retan/ wet finish I (K) Ammonia still lime sludge from coking operations ' Emission control dust/sludgc from the electric furnace production of steel 1 <T> 1 (T) Spent pickle liquor from steel finishing operations 1 Sludge from lime treatment of spent pickle liquor from 1 steel finishing operations (C,T> (TJ OCR 0 0 0 0 3 7 4 1 1 Primary Copper K0S4 Primary Lf'ad KUfi 5 I I i I 1 Acid plant-blowdown slurry/sludge resulting from the 1 (T) thickening of blowdown slurry from primary copper production Surface impoundment solids contained in and dredged from sur face impoundments at primary lead smelting facilIties 1 CD 1 ------------------------ f~-------------------------- f Industry EPA Hazardous | Haste Humber j Hazardous Haste Hazard Code Primary Zinc ) K066 K067 Secondary Lead K06Q ICO 6 9 Sludge from treatment of process wastewater and/or acid plant blowdown from primary zinc production Electrolytic anode siimes/siudges from primary zinc i production i i Cadmium plant leachate residue (iron oxide) from i primary zinc production______________________________________ T I Emission control dust/siudge from secondary lead I smelting ________________ __________________________________ (T) j (. j (T) (T) CCR 0 0 0 0 3 7 4 1 2 i i \ \ \ i J TABLE A-Vffi ACUTE HAZARDOUS WASTES The following commercial chemical products or manufacturing chemical intermediates are identified as acute hazardous wastes when they are discarded or intended to be discarded. Included in the Louisiana system also are off-specification material that would otherwise have been merchandized as these materials, containers or inner liners having been in contact with these materials and not suitably cleaned, or residue, contaminated soil, water or debris resulting from a spill of these products. HAZARDOUS WASTE HUMBER SUBSTANCE * F001 ;P002 F003 FQQ4 ?005 F006 1080 see P038 1081 see P057 (Acetate)phenylaercury see P092 Acetone cyanohydrin sec P069 3-(alpha-Acetonylbenzyl)-4-hydroxycouaarin and salts 1~Acetyl-2-thiourea Acrolein Agarin see P007 Agrosan GN 3 see P092 Aldicarb see ?069 Aldlfen see ?04g Aldrin - -- --- Algimycin see ?092 Allyl alcohol Aluminum phosphide (R) A1VIT see P037 t The Agency included chose trade names of which it was aware; an omission of a trade naae does not imply that the omitted' material is not hazardous. The material is hazardous if it is listed under its generic name. -34- CCR 000037413 P007 ?008 P009 9010 POU F0L2 >013 P01& >015 P016 F017 P018 TABLE A-VIII (Continued) Aainoethylene set P054 5-(Attinochyl}-3-isoxa*olol 4-Aainopyrldia Aaaoaiua setavansdace set F119 Assoalurt picrate (&) AHTIMDCIN WER see PC92 AKTUEULT see P073 AQ12A1B0L see P088 ABETIT see P020 Arsenic acid Arsenic peneojclde Arsenic crioxidt Athroobin see P001 AVIIS.OL sec F0Q8 Azirldene sec P054 AZOFOS sjse P061 Axopbos see P061 BASIC see 9072 Bsrias cyanide BASEKITZ see 9020 BCME see F016 AenzeneChiol Benzoepin see P050 Veryllioe dose Jls(ehlorcneehyl) ether BLAIUN-M see >071 Broaoaeecone Brucine -25- CCR 000037414 P019 P020 P021 P022 P023 P024 P023 P026 P027 P028 FQ29 P030 P031 P032 P033 TABLE A-VIE (Continued) 2-Bi canone peroxide BUFEN see P092 Butaphene see P020 2-sec-Bucyl-4,6-dinitropheno1 Calcium cyanide CALDON see P020 Carbon disulfide CERESAN see P092 CERESAN UNIVERSAL sec P092 CHE BOX GENERAL see P020 CHE BOX P.E. see ?020 CaEM-TOL see P090 Chloroaeecaldehyde p-Chloroaniline 1-- ( p--Chlorobeasoyl)-5"*mathoxy2-ethylindole3-acetic acid l-(o-Chlorophenyl)thiourea 3-Chloropropionltrile alpha-Chlorotoluene Copper cyanide CRETOX see P108 Coumadin see P001 Coumafea see P001 Cyanides Cyanogen Cyanogen bromide Cyanogen chloride Cyclodan see P030 CCR 003 7*lS -36- PC34 P035 P036 ?037 P038 P039 P040 P041 ?042 P043 P044 P045 PQ46 P047 P048 TABLE A-Vm (Continued) 2-Cyciohaxyl-4,6-dinitropheaol D--CON see U001 DE7HM0E see F001 DETENEL it< P001 DPP see P043 2.4-Dichlorophenoxyacetie add (2,4-0) Dichlorophenylarsine Dicyanogen sea P031 Dieldrln DIELUt.EC sae P037 Diechylsrsine 0,0-Dichyl-S-(2-(ethylchio)ethyl)ester of phoephorochioic acid 0,0-Diethyl-0-(2-pyrszinyl) phosphorochioace 0,0-Diechyl phosphoric acid, O-p-nitrophenyl aster 3.4-Dihydroxy-alpha-< metbylamiao)- methyl benzyl alcohol Di-iso-propylfluorophosphata DIMETATE sas P044 1,4:5,8-Dimethanonaphthaleae, 1,2,3,4,10,10- haxachloro-1,4,4a 5,8,Se-hexahydro ando,aodo sea P060 Dlmethoace 3.3-Dimethy1-1-(methylthio)-2-butanone-O[(aachylaaino)carbooylj oxime alpha,alpha-Dimachylphanethylamiae Dinitrocyclohexylphenol sea P034 4,6-Dinitro-o-creaol and salts 2.4-Diaitrophanol DZNOSES sae P020 37- CCR 000037416 F049 P050 P051 P052 P053 P054 P055 P056 P057 P058 TABLE A-vm (Continued) DINOSEBE see P02Q Qisulfoeon see P039 2,4-Dithio'oiurec DNBP see' P020 DOLCO MOUSE CEREAL see P108DOW GENERAL 3ee P020 DOW GENERAL WEED KILLER see P020 DOW SELECTIVE WEED KILLER see P020 DOWICIDE G see P090 DYAHACIDE see P092 EASTERN STATES DCOCIDE see POOL ELGETOL see ?O20 Eadosuliaa Eadria .Epiaephriae see P042 Sthylcyaaide Ethyleaediamine Zthyleaeimiae FASCO FASCRAT POWDER see POOL IEKHA see P091 Ferric cyanide Fluorine 2-Fluoroseeeamide FluoroacfcCie acid, sodium sale FOLODOL-SO see P0T1 POLODOL M see P071 POSFtrWO W SO see P07I CCR 00003 7417 P059 P060 P061 P062 P063 P064 TABLE A-vm (Continued) FRAIOL se* P056 Fuloinatt of aereury set P063 FUUGITQX OR ssc P092 FPSSOF see P057 . GALLOTQX see P092 GLOPBOS see P071 GERUTQX see P020 Heptsehlor 1.2,3,4 *10,10*4exaehio co^l,4,4,5,8,8e-hexehydro1 f 4:5,S**endo, endo-dimeth*aooaphths.lene , , ,1,4,5,6 7 7-*Hex*ehloro-eyclie-5-norboraene-2 3-diaethanol sulfite see P050 Bexeehloropropene Bexaethyl tecrspbospbsce HOSTiQUICK set P092 HOSTAQUHC see P092 * Bydrasoaethant see P068 Hydrocyanic acid ILLQXOL see P037 21TO0CI* see P023 Indonethacin set P025 IKSECTOPHEITC set PO30 Iso-drla see P060 Isocyenlc ecld, eettayl ester XILOSES ett P020 XOP-THIODAN set PO50 XVIK-KIL see PI08 TWIXSAN set P092 XUMADIR set P001 3B- 00003^8 GC* P065 P066 P067 P068 P069 P070 P071 TABLE A-Vm (Continued) K:f P? ARIN see P001 LZYTOSAN see P092 LIQOIPHENE see P092 MALIK see PO50 MAREVAN see POOl MAR-FRIN see POOl MARTIN'D MAR-PRIN see POOl MAVERAN see POOl KEGATOX see P005 Mercury fulminate MEKSOLITE see P092 METACID 50 see P071 METAPOS see P071 METAPHOR see P071 METAPHOS see P071 METASOL 30 see P092 Methomyl 2- Methylaairidiaa METHTL-E 605 see P071 Methyl hydrazine Methyl isocyanate see P064 2- Methyllactonitrile 2-Methyl-2-(methylthio)propioualdehyde- o-(eethylcarbonyl) oxine METHYL MIRON sec P042 Methyl parathion ME IRON see P071 MOLE DEATH see P108 ' -40- OCR 000037419 P072 P073 PQ74 P075 P076 P077 P078 P079 P080 P081 P082 P083 7084 P085 7086 7087 7088 TABLE A-VHI (Continued) MOUSE-SOTS see ?108 MOUSE-RID see PI08 MOUSE-T0X see PI08 MUSCIMOL see F007 1--Naphttayl-2-thiouree Nickel carbonyl Nickel cyanide Nleocine and sales Nitric oxide p-Nitroaniline Nitrogen dioxide Nitrogen peroxide Nitrogen tetroxide Nitroglycerine (R) N-Nitrosodlaethylaolne N-Nitrosodiphenylamine N-Nitrosomethylvinylanine NUMERATE see P092 i OCTALOX see P037 Octaaethylpyropbosphoramidc OCTAN see P092 Oleyl alcohol condensed with 2 moles ethylene oxide OWPA see 7085 OHPACXDE see P085 OMPAX see 7085 Osmium tetroxide 7-Oxabicyclo[2.2.1]heptane-2, 3-diearhoxylic scid Cc 000037420 P089 P090 P091 P092 P093 C' P094 TABLE A-VIII (Continued) PAtfIVARrIN see ?00l PAN OR.AM 0-31 see P037 PANTHERIME see P007 PANWAR7IN see P001 Parechlon PC? see P090 PENNCAP-M see P0 71 PENOXYL CARSON N see P048 Pantaehloropheaol Pentaehloropheaate see P090 PSNTA-KILL see P090 PSNTASOL see P090 PI NT?AS. see ?090 PER.MXCXOE see PQ90 PSRMAGDARD see P090 FERMAICX see P090 PIE MITE see P090 PERTOX see P090 PESTOX III see P085 PHENMAD see P092 PRENOTAN see P020 Phenyl dichloroarsine Phenyl mercaptan see P014 Phenylmercury acetate N-Phenylthiourea PHILIPS 1861. see P008 PEIX see F092 Phorate -42- CCR 000037421 P095 P096 ?057 P098 P099 PI 00 -pioi P102 TABLE A-VIII (Continued) Phosgene Phosphine Phosphorothioic acid, 0,0-dimethyl ester, 0-ester vith X.S-dimetnyl benzene sulfonamide Phosphorochioic acid 0,0-dlaethyl-O(p-nitrophenyl) ester see P071 PIED PIPES. MOOSE SEES see P108 Potassium cyanide Potassium silver cyanide PREMSNGE see P020 l,2-Propanediol Propargyl alcohol see ?102 Proplooitrile 2-Propyn-l-ol PS0THR.0KADIN See P001 QOICZSAM see 7092 QCIHTOI see ?037 SAT AND MICE BAIT see P001 EAI-A-WAT see 7001 EAI-B-C0N see 7001 EAZ-O-CIDE #2 see P001 BAT-CUA3LD see P001 EAI-EXIL see P001 EAT-hlX see P001 EAIS-N0-M0EE see 7001 EAT-OU see P001 LAZ0B.EE see P001 J. ', EAITUNAL sec POOl o0003^^22 OCR -43- P103 P104 P105 P106 P107 P108 TABLE A-VIII (Continued) RAT-TROL see P001 RO-DETH see P001 RO-DEX see P108 2.0SEX see P001 ROUGH & READY MOUSE MIX see POOl SANASEED see P108 SANTOBRITE see P090 SANTOPHEN see P090 SANTOPHEN 20 see P090 SCHRADAH see P085 Selenouree Sliver cyanide SMITE see P105 SPARIC see P020 SPOR-KIL see P092 SPRAY-TROL BRAND RODEN-TROL see F001 SPURGE see P020 Sodium szide Sodium couasdin see POOl Sodium cyanide Sodium fluoroacetaee see P056 SODIUM WARFARIN see POOl S0L7A&IN see POOl S0L70BLACK BB see P048 S0L70BLACK SB see P046 Strontium sulfide Strychnine and salts SUBTEX see P020 -44- . CCR 000037423 P109 P110 P1U P112 P113 P11A P115 P116 P117 TABLE A-Vm (Continued) STSTAW see P033 TAG FUNGICIDE see P092 TSKKAISA see P071 TEMZC see P070 TEMXK see P070 TERM-I-IR.OL see P090 Tetraethyldlthiopyrophosphste Teerseehyl lesd TeersechylpyrophosphsEe Tetrend, troaethsne Tetrapbosphoric acid, hexseehyl ester see P062 TETROSULFDR BIACE PB see P048 TETEOStJLPHDR PBR see P048 Thallic oxide Tballulm peroxide see PI13 Thai11us selenite Thallium (I) sulfate THIFOR see P092 THIMUL see T092 TE10DAN see P050 THIOFOR see P050 THXQMUL see P050 THIONgX see P050 THIOPHENIT see P071 Thloseolcarbazide Thiosulfan tlonel see P030 Thlurea -45- CCR 000037424 PI 18 PUS PI 20 P121 P122 TABLE A-VIII (Continued) THOMPSON'S WOOD 71 see PC90 TXOVIL see P050 Trichloromechaaecbiol TVTlf LIGHT HAT AWAY see P001 OSAP RH-8' see P06 9 OSAF EK-4890 see P002 Vaaadie acid, ammonium salt Vanadium pencoxlde VOFATOT see P071 WANADO see PL20 WAHCOD2HN see P001 WARFARIN SODIUM see P001 WARFICIDE see P001 WOFOTOX see P072 TANOCK see P057 YASOKNOCK see P058 ZIARNIK see P092 Zlac cyanide Zinc phosphide (H,T) ZOOCOOMA&IN see P001 -46- ---V-* 000037425 CCR TABLE A-IX TOXIC WASTES The commercial chemical products or manufacturing chemical intermediates are identified as toxic wastes when they are discarded or intended to be discarded. Included in the Louisiana system also are off-specification material that would otherwise have been merchandized as these materials, containers of inner liners having been in contact with these materials and not suitably cleaned, or residue, contaminated soil, water or debris resulting from a spill of these products. Their particularly toxic nature will impact considerations of the treatment of even small quantities. HAZARDOUS WASTE NUMBER 0001 0002 0003 U004 0005 U006 0007 SUBSTANCE * AAF see U005 Acetaldehyde Ace.tone (I) Acetonitrile (I,T) Acetophenone 2-Acetylaainoflourene Acetyl chloride (C, Acrylamide U008 U009 Acetylene tetrachloride see U209 Acetylene trichloride tee U228 Acrylic acid (I) Acrylonitrile AE&OTBSNE TT see U226 3-Aaino-5-(p-acetaaidophenyl)-lH-l,2,4triazole, hydrate see 0011 6-Aaino-lia,2,8,8a,Sb-hexahydro8-(bydroxyae thyl)8-me ehory-5aethylcarbaaate azirino(2 ', 3 ': 3,4 ) PT^rolof1,2-a)lndole-4, 7-dlone (ester) t The Agency Included those tr.ade neaes of which it was aware; an oaission of a trade naae does not imply that it is not hazardous. The material is hazardous if it is listed under its generic naae. OCR 000037426 0011 0012 0013 0014 0013 0016 0017 0018 0019 0020 0021 0022 0023 0024 0025 0026 0027 0028 0029 0030 0031 0032 c 0033 TABLE A-IX (Continued) Amitrole Aniline (I) Asbestos Auramine Azaserlne Ben*[c]acridine Benzal chloride Benz[a]anthracene Benzene Benzenesnlfonyl chloride (C,R) Benzidine 1,2-3en*lsochla*olin-3-otie, 1, l-dioxlde see 0202 Benzo[a]anthracene see 0018 Benzo[a]pyrene Benzotrichloride (C,R,T) Bis(2-chloroe thoxy)me thane Bis(2-chlocoethyl) ether N,N-Bis(2-chloroethyl)-2-naphthylamine Bis(2-chloroisopropyi) ether Bis(2-ethylhexyl) phchalate Bromomethane 4-Bromophenyl phenyl ether n-Butyl alcohol (I) Calcium chromate Carbolic acid see 0188 Carbon tetrachloride see 0211 Carbonyl fluoride -48- 00003?^27 cc* 0034 0035 17036 0037 U038 17039 U040 0041 004 2 0043 0044 U04S 004 6 004 7 004 8 004 9 0030 0051 U052 0053 0054 005-5 0056_ U057 0058 TABLE A-IX (Continued) Chloral Chlorambucil Chlordane Chlorobenzene Chiorobenzilate p-Chioro-a-cre sol Chiorodibronooctbane 1- Chloro-2,3-epoxypropaae CHLOROETKEifE KU see 0226 Chloroethyl vinyl ether Chlorocehene Chloroform (I,T) Chloromechane (I,T) Chloromethyl methyl ether 2-- Chioronaphthalene 2-Chlorophenol 4-Chioro--o--toluidine hydrochloride Chrysene C.I. 23060 see 0073 Cresote Creeds Cro tonaldehyde Cresylic acid Cumene Cyanomethane see 0003 Cyclohexane (1) ~ Cyclohexanone (I) Cyclophosphamide CCR 00003T4Z8 -49- 0059 U060 0061 0062 0063 0064 0065 0066 0067 0068 0069 0070 0072 0073 U074 0075 0076 0077 0078 007 9 0080 . 0081 "0*2 TABLE A-IX (Continued) Dauaomycin ODD DDT Diallace Dibenz[a,h]anthracene Dibanzo[a,h]anthracene see 0063 Dlbanzo[a,1]pyrene Dibromoehloronathane 1.2-Dibroao-3-ehloropropane 1.2-Dibroaoethaae Dlbronomethane Di-n-butyl phchalata 1.2-Dichlorobenzene 1.3-D1chlorobenzene 1.4-Dichlorobenzene 3,3 '-D'ichlorobenzidiae 1.4-Dichloro-2-butene 3,3'-Diehloro-4,4'-diaai/no biphenyl see 0073 Diehlorodifluoroaethane 1.1-Diehioroe thane 1.2-Dlchloroethane 1,l-Dichioroe thylane 1,2-trana-Dichloroethylene Diehiorosethane Dlchloromechylbenzane tec 0017 2.4-Dlehlorophenol 2,6-Diehiorophenol 00003^29 cefc -50-  - r C0S3 0084 0085 0086 0087 0088 0089 no 90 0091 0092 0093 0094 0095 0096 0097 0098 0099 0100 0101 0102 0103 0104 0105 0106 0107 .0108 0109 TABLE A-K (Continued) 1,2-Diehioropropane 1,3-Diehloropropene Diepoxybutane (I,T) 1,2-Diechylhydra*ina 0,0-Diet hy1-S-oethy1 eater of phosphorodithioie acid Diethyl phthalate Diethylstilbeatrol Dihydroaafrole 3,3'-Dtaethoxybaaiidina Diaechylsaina (I) p~Dlse tbylaalaoaao benzene 7,12~Dlaechylbeaz[e]anthrecene 3 >3'-Dimethyl benzidine alpha,alpha-Diaethylbenzylhydroperoxide (R) Dinethyicarbanoyl chloride l>l-Diaathylhydraxine 1,2-Dine chylhydrazina .4 Diaethylnieroeoaaine 2,4-Diaethylphenol Diaethyl phthalate Dimethyl sulfate 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Diaitrotoluene Oi-n-oetyl phthalate. 14-Dioxane 1,2-DiphenyIhydrazina ` - .-~'r?rrr*rxr-"? ^vr..t it\'?i*'** -51- CCR 000037430 GILO U1U Gil 2 U113 0114 UU3 G116 0117 0118 0119 0120 0121 0122 0123 0124 0125 0126 0127 0128 0129 0130 0131 .0132 0133 TABLE A-IX (Continued) D1propylaaiae (I) Di-n-propylnitrosasine EBOC see 0114 1,4-Epoxybutane see 0213 Ethyl tceUCt (X) Ethyl acrylate (I) Sthylenebisdithiocarbanate Ethylene oxide (I,T) Ethylene thiourea Ethyl ether (IfT) Ethylaetheorylate Ethyl aethanesulfonatt Ethylnltrlle see 0003 Fireaaster T23P see 0235 Fluoranthene Fluorotrlchloconethane Fo raaldehyde Foraic acid (C,T) Furan (I) Furfural (I) Glycldylaldehyde Hexachloroben2ene Hexachlorobutadiene Eexachlorocyclohexane Bexaehlorocyclopentadlene Hexachloroethane Hexachlorophene Hydrazine (H,T) -52- CCR 000037431 0134 U13 5 013 6 U137 0138 0139 0140 0141 0142 0143 0144 U145 0146 014 7 0148 0149 0150 0151 0152 0153 0154 U15S 0156 TABLE A-IX (Continued) Hydrofluoric acid (C,T) Hydrogen sulfide Hydroxybenzene see 0188 Hydroxydiaethyl arsine oxide 4,4(laldocarbonyl)bis(N,N-diaethyl)aniline see 0014 Indeno(l,2,3-ed)pyrene lodome thane Iron Dextran Isobutyl alcohol Isosafrole Kepone Laslocarpine Lead acetate Lead phosphate Lead subacetate Maleic anhydride Maleic hydraside Maloaouitrile MEK Peroxide see 0160 Melphalan Mercury Methaerylonltrlle Me thanethiol Methanol Methapyrllenc Methyl alcohol set 0154 Methyl chlorocarbonate -53- - OCR 000037432 0157 0158 0159 0160 0161 0162 0163 0164 0165 0166 0167 0168 0169 0170 0171 0172 0173 0174 0175 0176 0177 0178 TABLE A-K (Continued) Methyl chloroform see 0226 3-Methyleholanthrene Methyl chlorofotaact see 0156 4,4 Methylene-bis-(2-chloroaailine) Methyl ethyl ketone (MEK) (X,T) Methyl ethyl ketone peroxide (2.) Methyl Iodide see 0138 Methyl lsobutyl ketone Methyl methecrylete (2,T) 8-Methyl-N'-nitro-H-nltrososuaaidiae Methylthlourecil Mitomycin C see 0010 Naphthalene 1,4-Haphthoquinone 1-Haphthylamine 2-Naphthylamine Nitrobenzene (I,T) Nitrobeazol see 0169 4-81trophenol 2-81tropropane (X) 8-81trosod1-n-butylamine 8-81trosodleehaaolamina 8-81trosodiethylamine 8-81troeodl-n-propylamine 8-81troso-a-eebylurea 5-Sltroso-n-aethylurea 8-81 tros'o-a-me thy lur ethane -S4- CCR 0003-'-,> 0179 ai8o 8181 01 82 01 83 VI84 0185 0186 0187 0188 0189 0190 0191 m 92 0193 0194 0196 0197 0200 0201 0202 0203 0204 0205 TABLE A-IX (Continued) N-iiicroso piperidine N-Nitrosopyrrolidine 5-Niero-o-toluidine Paraldehyde PCN8 see 0185 Peaeachlorobensene Pentaehloroethane Peaeachloronitrobemeoe 1.3- Pentadiena (1) Pare see 0210 Perehlorathylene see 0210 Pheaaceeln Phenol Phosphorous sulfide (2) Phthallc anhydride 2-Plcoline Pronaaide 1.3- Propane aultoae n-Propylanlne (1) Pyridine Quinones fteserpine Resorcinol Saccharin Safrole Selenlous -acid Selenium sulfide (2,T) Silver see 0233 -55- C 0003'' C2Q6 0207 0208 0209 0210 0211 0212 0213 0214 0215 0216 0217 0218 0219 0220 0221 0222 0223 0224 0225 0226 0227 0228 0229 TABLE A-IX (Continued) S trept02ococtn 2.4.5-T see 0232 1.2.4.5- Tetreehlorobenzene 1.1.1.2- Tetreehloroe thane 1.1.2.2- Tetrachloroe thane Tetreehloroethene Teeraehloroethylene see 0210 Tetrechlorooethane 2.3.4.6- Teerschlorophenol Tetrahydrofurau (I) Thallium (1) acetate Thallium (I) carbonate _ Thallium (I) chloride Thallium (I) nitrate Thioacetaaide Thiourea Toluene Toluenediaaine o-Toluidine hydrochloride Tolylene diisocyanate Toxaphene 2.4.5-T? see 0233 Tribroaoaethane 1.1.1-Trlchloroethane 1.1.2-Triehloroethane Trichloroethane Trichloroethylene see 0228 Trie hlo rof luor one thane- -56- O0 0^ 0230 17231 0232 0233 0234 023 5 023 6 023 7 0238 023 9 TABLE A-IX (Continued) 2.4.5-Trlchloropheno 2.4.6-Triehlorophenol 2,4 , 3-Trlchl.orophenoxyacecic acid 2,4,5-Trlchlorophenoxyproptonic acid alpha, alpha, alpha- Trlchlorotoluene saa 0023 TR1-CLZNE ae 0228 Trlsitrobanzenc (R,T) Trl*(2,3-dlbroeopcopyl)phosphate Trypan blue Uracil mustard Urethane Vinyl chloride tea 0043 Vlnylldana chloride see 0078 Xylene -57- 000037A36 OCR L3. SPECIAL TEST PROTOCOLS L3.L Application of Tests; The toxicity threshold criteria defined in Section L2. must be applied to the waste's liquid fraction j o leachate derived from the contained solids, and to residual solids from such a leachate procedure. The procedure outlined in the following section or its equivalent is to be used in obtaining the leachate. 1*3.2. Leachate Extraction Procedure: One hundred grams of subject waste (finely ground to less than 40 mesh) are to be agitated with 2 liters of extract wash solution for 24 hours at 25 C in a closed system. The nature of the extract wash solution is to be designated by class as follows with the extract solution subjected to the toxicity and corrosivity determinations prescribed by Section L2. A single leachate solution will be satisfactory based on the specified setting for the waste's disposal. Class A; For Biologically Active Organic Wastes -- Test to be performed as prescribed by EPA in the Federal Register (December 18, 1978, page 58957) Appendix I here. Applicable where sanitary landfill disposal is possible. Class B; For Inorganic Wastes -- Test to be performed with one of six leaching solutions prepared with deionized water or 0.5 M NaCl and at pH of 5 (HNOg), 7, or 9 (NaOH), depending on specified disposal setting. I Class C: For Non-Biologieally Active Organic Wastes -- Provisional placement is made into Class A pending develppment of a hum ate extract procedure. The matrix of Table A-Vm recapitulates this choice of extract solutions. L3.3. Bioassay Procedure; Bioassay testing shall follow the aquatic 96-hour TLC5Q protocol on fathead minnows and/cr bluegills for freshwater settings or on Atlantic Croaker (Micropegon undulatis) and/or the Spot (Leiostomus xanthurus) for brackish or marine systems. (Species substitution may be made with the concurrence of Department staff.) The appropriate procedures are as described in "Standard Methods for the Examination of Water and Wastewater, Part 800 (14th Edition). The waste is to be diluted to concentrations described in Standard Methods and the determination made for whether half of the subject fish expire in the 96-hour test period. Generally, a static test will be acceptable unless special properties of the waste necessitate a continuous flow bioasay. Far solids, slurries not entirely soluble in water, suspensions or emulsions, the waste should be examined as a waste extract as prescribed in Section L3.2. L3.4. Data on Oral LD50 for Humans; The LD5Q value for a substance is the amount of the substance in milligrams per kilogram of body weight of the test subj ct which would kill 50% of a population of such subjects. 000037437 For humans, the LDj.q value can be estimated from the LD50 value for oral exposure to rats. Where a value for the rat is not available, mouse oral LD5{} data may be employed. Where an appropriate LD5Q value for the rat or mouse is listed in NIOSH (National Institute for Occupational Safety and Health) 1978 Registry of Toxic Effects of Chemical Substances, this value may be used without validation. If other values are used, they must be supported by specific and verified laboratory reports. The appropriate conversion factors to use in estimating human LD50,g are 0.16 for the rat and 0.066 for the mouse. Thus human LDg0 equals 0J6 rat LDg0 or 0.066 mouse LD5{J. As an example, tetraethylenepentamine has a listed oral rat LD&0 of 3990 mg/kg. Thus, the human LD50 equals 3990 times 0J6, or 638 mg/kg, which is less than the 800 mg/kg limit. 1.3.5. Albino Rabbit Skin Testing for Corrosivity and Irritability; A. Corrosivity to Skin 1. Corrosion to the skin is measured by patch-test technique on the intact skin of the albino rabbit, clipped free of hair. A minimum of six subjects are to be used in this test. 2. Introduce under a square cloth patch, such as surgical gauze measuring 1 inch by 1 inch and two single layers thick, 0.5 milliliter (in the case of liquids) or 0.5 gram (in the case of solids and semisolids) of the substance to be tested. 3. Immobilize the animals, with patches secured in place by adhesive tape. 4. Wrap the entire trunk of each animal with an impervious material, such as rubberized doth, for the 4 hour period of expsoure. This material is to aid in maintaining the test patches in position and retards the evaporation of volatile substances. It is not applied for the purpose of occlusion. 5. After 4 hours of exposure, the patches are to be removed and resulting reactions are to be evaluated for corrosion. 6. Readings are again to be made at least at the end of a total of 48 hours (44 hours after the first reading). 7. Corrosion will be considered to have resulted if the substance in contact with the rabbit skin has caused destruction or irreversible alteration of the tissue. Tissue destruction is considered to have occurred if, at any of the readings, there is ulceration or necrosis. -59- CCR 000037^38 6 t ^ 00 Tissue destruction does not include merely sloughing of the epidermis, or erythema, edema, or Assuring. B. Irritability to Skin The irritability testing procedure is taken from Title 16, Chapter H -- Consumer Product Safety Commission: Primary irritation to the skin is measured by a patch-test technique on the abraded and intact skin of the albino rabbit, clipped free of hair. A minimum of six subjects are used in abraded and intact skin tests. Introduce under a square patch, such as surgical gauze measuring 1 inch by 1 inch and two single layers thick, 0.5 milliliter tin the case of liquids) or 0.5 gram tin the case of solids and semisoitids) of the test substance. Dissolve solids in an appropriate solvent and apply the solution as for liquids. The animals are immobilized with patches secured in place by adhesive tape. The entire trunk of the animal is then wrapped with an impervious material, such as rubberized cloth, for the 24-hour period of exposure. This material aids in maintaining the test patches in position and retards the evaporation of volatile substances. After 24 hours of exposure, the patches are removed and the resulting reactions are evaluated on the basis of the designated values in the following table: Skin Reaction Value 1 Erythema and eschar formation: . No erythema 0 Very slight erythema (barely perceptible) 1 Well-defined erythema 2 Moderate to severe erythema .3 Severe erythema (beet redness) to slight eschar formations (injuries in depth) 4 Edema formation: No edema 0 Very slight edema (barely perceptible) 1 Slight edema (edges of area well-defined by definite raising) 2 Moderate edema (raised approximately 1 millimerer) 3 Severe edema (raised more than 1 millimeter and extending beyond the area of exposure) 4 Ct* * The "value1* recorded for each reading is the average value of the six or mare animals nbject to the test. Readings are again made at the end of a total of 72 hours (48 hours after the first reading). An equal number of exposures are made on areas of skin that have been previously abraded. The abrasions are minor incisions through the stratum comeum, but not sufficiently deep to disturb the derma or to produce bleeding. Evaluate the reactions of the abraded skin at 24 hours and 72 hours, as described in this paragraph. Add the values for erythema and eschar formation at 24 hours and at 72 hours for intact skin to the values on abraded skin at 24 hours and at 72 hours (four values). The total of the eight values is divided by four to give the primary irritation score; for example: Skin reaction Exposure tl (hours) Evaluacion value Erythaaa and eschar formation: Intact akin................................ <**........................................................... Abraded skin...................................................... to.............................................................. 24 72 24 72 Subtotal...................................................... 2 1 3 2 S Iatact.skia................................................... to......................................................... ^toadad Ala................................................. to.......................... 24 72 24 72 Subtotal Ideal... 0 1 1 2 4 12 Thus, the prlaary irritation score la 12*4-3. -62- CCR 000037441 A.2. MONITORING EXPECTATIONS 1. SCOPE OF ANALYTICAL REQUIREMENTS Monitoring expectations for each disposal facility will include the following: A. Baseline establishment B. Initial comprehensive operational analysis C. Continuing annual operational analysis D. Quarterly screening analysis 2. L1. Establishment of Baseline: In order to establish baseline levels, samples from monitoring wells and leachate collection systems should be analyzed and interpreted on a comprehensive basis prior to treatment, storage, or disposal of any hazardous waste at each new facility. This baseline analysis should include the determinations far parameters designated during the permit review procedure. Comparable sampling and analysis should be conducted for existing facilities prior to award of an unconditional permit and within fifteen months of the effective date of the Louisiana Hazardous Waste Management Plan Rules and Regulations...an order to establish the baseline for these facilities. Sampling procedures and the leachate and groundwater analyses should be consistent with the guidelines presented in this document. Baseline levels for groundwater and leachate quality (reflecting seasonal variability as appropriate) should he established through comprehensive analysis on a quarterly basis for a period of at least one year. Less frequent sampling for the baseline should be planned only when there is a firm basis for not anticipating significant seasonal groundwater quality changes. 2.1.2. Comprehensive Operational Analyses: The comprehensive operational analyses should include the identification of the presence and level of the pertinent parameters for waste liquids, extracts, and permitted solids from the following list. A guideline on relevant analyses for the various industry classes is provided in Appendix A: (a) specific conductivity, mho/cm at 25 C (b) temperature, C (field and laboratory) (e) pH (d) total dissolved solids, mg/liter CCR 000037442 (e) t tal suspended solids, mg/liter (f) total settleable solids, mg/liter (g) dissolved organic carbon (DOC), mg/liter (h) total chlorinated hydrocarbons, mg/liter (i) phenolic compounds (as phenol), mg/liter (J) metals: antimony, mg/liter arsenic, mg/liter barium, mg/liter beryllium, mg/liter cadmium, mg/liter chromium, mg/liter copper, mg/liter ircn,mg/liter lead, mg/liter magnesium, mg/liter manganese, mg/liter "~ mercury, mg/liter nickel, mg/liter selenium, mg/liter silver, mg/liter thalium, mg/liter vanadium, mg/liter zinc, mg/liter (k) ammonia (as N), mg/liter Q) chlorides, mg/liter (m) cyanide, mg/liter (n) fluoride, mg/liter (o) nitrate, mg/liter (p) phosphate, total mg/liter (r) ortho-phosphate (as P), mg/liter is) organic contaminant scanning (volatile, base neutrals, add extracts) by Oas Chromatography -64- CCft 000037443 2.1.3. Continuing Annual Operational Analysis: The comprehensive operational analysis will be conducted annually and its scope may be reduced by the Secretary after baseline establishment so as to eliminate any compounds consistently not found in the waste handled at the facility. Sample collection and analysis are to be in accordance with Part B of these guidelines. 2.1.4. Quarterly Screening Analysis; Confirmatory screening analyses (for quarterly reports) will be required to demonstrate that operation is proceeding in a consistent fashion with what has appeared in the comprehensive analysis. The scope of the quarterly analyses will be agreed upon at permit issuance. As a guide a minimum analysis shall quantify the following parameters: (a) specific conductivity, roho/cm at 25 C (b) temperature, C (field and laboratory) (c) total dissolved solids (TDS), mg/liter (d) chloride, mg/liter (e) pH (f) dissolved organic carbon, mg/liter (g) total organic carbon (TOC) (h) two principle metals or other designated parameters (ones found in the largest quantities or which best serve as indicators), as designated by the State, in mg/liter. 2.1.5. Specific renort on departures from norm. When monitoring shows that the concentration of a chemical species has increased above baseline levels by a statistically significant amount, i.e., as indicated for example by the Student's single- tailed test at the 95% confidence level (Appendix B), the facility owner/operator must: (a) notify the Louisiana Department of Natural Resources within 48 hours by telephone and in writing within 7 days, (b) undertake confirmatory analyses (c) determine the cause of the increase, e.g, the result of a spill, a design failure, an improper operating procedure, etc. and initiate corrective action, ' (d) determine the extent of the groundwater contamination. 2.2. DESCRIPTION OF MONITORING SYSTEMS Monitoring syst ms prescribed in the Hazardous Waste Management Program include those for = Groundwater, Leachate, Surface Water, Air and SoiL Nominal expectations for each of these follow. CCR 00003744A 2.24. Groundwater Monitor Wells; Evaluation of pollutant build-up in groundwater, and migration patterns within and beneath the disposal site and in the surrounding area require several strategically located stations with samples concurrently collected and analyzed. The appropriate number of sampling points will be directed by the expected variability in each parameter and the degree of monitoring accuracy desired. Sampling point distribution and procedures will depend on the geologic, hydrologic, and chemical complexities likely to be encountered. Under ideal conditions, where the underlying earth materials are fairly homogeneous, impermeable, and uniformly sloping in one direction, four sampling points are recommended. Three of these points should be equally spaced on a line through the center of the disposal area (for relatively small areas) and extending from the area of highest water table elevation to the lowest water table elevation on the property (see Figure A-l) with the center well located downgradient positioned immediately adjacent to the active portion of the facility. Larger disposal areas will require additional point/wells for adequate sampling as determined by State staff. The wells should be located to intercept contamination at the earliest possible occurrence. Wells locations and completion depths must be selected to assure that probable contaminant flow paths are monitored. Figure A-l OCR 00003T* disposal area figure At2 \A. i ;' M" 446 -67' CC^ qO00^ In many cases earth materials may not be homogenous and flow pt hs of groundwater through any given profile may be complex. The upper and oasal surfaces of intervening strata may be warped in such a manner so as to influence the direction of groundwater flow and resultant vertical migration patterns of leachate movement (see Figure A-2). In many existing land disposal sites, only the lower, more permeable portions of the unconsolidated earth material above bedrock are tapped by monitoring wells, even though overlying water-bearing zones are known to be present. Under these conditions (see Figure A-3) a major portion of groundwater pollution derived from the disposal sites may flow undetected through these overlying beds to some nearby natural or man-made drainage course. A similar situation can occur in areas underlain by only one primary water-bearing zone if too few monitoring wells are installed, or if wells installed tap only the uppermost part of the zone of saturation. In situations where more than one watercarrying stratum is present in the earth material section, each individual water bearing unit should be monitored by properly spaced, 3-station lines (see Figure A-4). Wells may be constructed to draw samples from a single depth only if it can be demonstrated that it is the depth where contamination is likely to occur. Figure A-4 -68- 00003l`*'>7 CCR All monitor wells should be cased and the annular space between the "monitor zone" (zone of saturation) and the surface should be completely backfilled or plugged with impermeable material in order to prevent percolation ef surface water into the well bore and to prevent inter-aquifer water exchange. Well opening at the surface should have a removeable cap to provide access and to prevent entrance of rainfall or stormwater run-off. Well casing should be of sufficient diameter so as to permit use of a submersible pump for obtaining samples for analysis, if desirable, but portable pumps may also be used to obtain samples. When practical, the well should be pumped to remove the volume of liquid initially contained in the well prior to obtaining a sample for analysis. See Figure A-5 for the typical monitor well detail. 2.2.2. Leachate Collection Monitoring Systems; A leachate collection monitoring system should be installed beneath any pit, pond, or other facility receiving hazardous waste which employs an earthen or artificial liner as an impervious barrier. Accept able leachate collection monitoring/collection systems include, but are not limited to the following basic designs: L "Simple Leachate Collection" - This system consists of a gravity flow drainfield installed under the waste disposal facility liner. This design is recommended for use under the following circumstances: a. when liquid, semi-solid, or teachable solid wastes are placed in a lined pit excavated into a relatively thick, unsaturated, homogenous layer, of low permeability soil; and b. when a minimum of ten feet of relatively impermeable soil separates the.pottom of the disposal facility from the groundwater table at its highest seasonal fluctuation (see Figure A-6). 2. "Compound Leachate Collection" - This system consists of a gravity flow -- drainfield installed under the waste disposal facility liner and above a secondary installed liner. This design is recommended for use under the ` following circumstances: a. when liquid, semi-liquid, or teachable solid wastes are placed in. a lined pit excavated into relatively permeable soils; and b. when less than ten feet of relatively impermeable soil separates The--------- ---- bottom of the disposal facility from the groundwater table at its highest seasonal fluctuation (see Figure A-tf). 11 if Atrqi. -69- oooo^*8 CC* Fi9U1* A-5 - MONITOR WELL (Not to scale) -70 c<> 3. "Suction Manometers" - This system consists of a network of porous "stones" connected by hoses/tubing to a vacuum pump. The porous "stones" or suction manometers are normally installed along the sides and under the bottom of the waste disposal facility liner. This type of system can be used in a variety of situations but works best when installed in relatively permeable unsaturated soil immediately a<$acent to the disposal facility's bottom and/or sides. The suction manometer system functions primarily as a leak detection device and is generally superior to monitor wells for early detection of leachates escaping from a disposal facility. One drawback to this type of system is that it is somewhat limited with respect to the volume of leachate that could actually be collected for treatment or return to the disposal facility in the event of a leak of significant volume. CCR 000037^50 Sampling should be effected at the low point in each gystem described above and all systems should be designed to ensure that leachate from all contents will percolate to the low point. Provision for pumping out collected leachate must be made. Leachate collection systems should be monitored for quantity and quality of leachate produced on a routine basis as defined in the following section. The leachate should be either treated to acceptable quality for discharge in accordance with effluent discharge permit limitations disposed of by another method, or recycled to the facility producing the leachate. *' ' A leachate monitoring is not needed if the facility owner/operator can demonstrate that an alternative monitoring technique will detect leaks as effectively as a leachate monitoring system. It is recommended, however, that where geologic and hydrologic conditions warrant it, disposal sites accepting "hazardous wastes" employ both groundwater monitor wells and leachate collection systems in order to minimize the chance of pollutants as rapidly as possible in the event that they are leached from the disposal facility. Under no circumstances should a monitoring/leachate collection system be used in lieu of a proper lining where it has been established that a lining is necesary to protect the ground and surface waters in the vicinity of the disposal site. 2.2.3. Surface Water Monitoring: Surface water monitoring is required as a routing c mponent f a total monitoring network. The proximity of a disposal site to surface water and drainage patterns will determine the degree of surface water monitoring necessary. -72- 00003lft51 CC* Selection f surfa e water sampling stations, equipment, and procedures should follow a methodical approach similar to that described for groundwater monitoring. Each surface water monitoring item should be evaluated in terms of compatibility or possible contamination with the constituents to be analyzed. Surface sampling stations should be located in areas which represent the greatest potential for contamination. These points can be determined after examining the pathways available for leachates to enter a surface water body. Consideration should also be given to selecting stations which can provide consistent samples throughout the monitoring program. Flow patterns and seasonal variations should be addressed when applicable. Sampling equipment and procedures can range from continuous or intermediate automated samplers to manual collection. Manual sampling is aim st always considered to be adequate. Indicator parameters and analytical methods used for surface water samples should be consistent with selected procedures for groundwater sample testing. The effects of surface water mixing and interference with contaminants should be considered. 2.2.4. Air Monitoring; Installed, or available portable air monitoring devices are required at all sites involving: incineration, landfill, or treatment facilities. An installed air monitoring system (triangular grid) with continuous recording is required at all commercial sites. Sampling devices should be located in whatever direction structures exist. Typically, sampling devices may be located near the property boundary and off-site on the landfill side of structures in pathways most susceptible to gas migration. The generation and rate of gas movement within disposal sites may also require monitoring. Samples should be taken the same time water samples are taken. . More specific guidelines for air monitoring are currently under preparation. ) OOOOil1*52 -7S- OCR IT -l . T7 .5. Soil Monitoring; Soil monitoring is required for landfarm disposal sites. (a) background soil conditions should be determined by taking one soil core per acre in the area to be treated. The depth of the soil core should be three (3) times the depth of the zone of incorportion or 30 centimeters (12 inches), whichever is greater. The bottom one-third of the soil core should be quantitatively analyzed for those constituents known or expected to be in the waste which make it hazardous. At new facilities, soil cores sh uld be taken and analyzed prior to beginning opertion. At existing facilities, background soil cores should be taken and analyzed within six months after the effective date of the Louisiana Hazardous Waste Management J?lan Rules and Regulations. (b) soil conditions in the treated area of the landfarm should be determined by taking one soil core per acre semi-annually. The depth of the soil core should be three (3) times the depth of the zone of incorporation or 30 centimeters (12 inches), whichever is greater. The bottom one-third of the soil ewe should be quantitatively analyzed for those constituents in the waste which make it hazardous. NOTE; Soil monitoring may be conducted by taking less than one soil core per acre and/or by monitoring less frequently than semi-annually, provided the owner/operator can demonstrate to the Department that hazardous constituents, especially heavy metals, will be detected before vertically migrating a distance that exceeds three (3) times the depth of the zone of incorporation or 30 centimeters (12 inches), whichever is greater. (c) If soil monitoring shows that the concentration of a hazardous constituent in the bottom one-third of the soil core has significantly exceeded the background levels, the owner/operator should: (i) notify the Louisiana Department of Natural Resources within seven (7) days;(ii) (ii) determine, by soil monitoring, the area extent of vertical contaminant migration in the soil; and discontinue all landfarming in the contaminated area, as determin d in (ii), until corrective measures can be taken. ooo031 -75- PART B: PROGRAM ENFORCEMENT GUIDELINES This section presents a summary of sampling and analytical procedures deemed by the Department to be acceptable in the conduct of The Louisiana Hazardous Wastes Management Program. Specific attention is also given to documentation and record maintenance responsibilities. These notes reflect the objectives of the Department of Natural Resources' staff and should be used as a point of departure in requests for consideration of alternative good procedures and practices. They are addressed to Department staff, industrial personnel and service laboratories. B.l. SAMPLING PROCEDURES; CHAIN OF CUSTODY; TECHNICAL STANDARDS; COLLECTION LI. Recordkeeping and Reporting; Operators of facilities shall forward two copies of the monitoring data specified in Section 2.1, Part A, of these guidelines to the Louisiana Department of Natural Resources, Office of Environmental Affairs, Baton Rouge 70804 (attention of Enforcement Section, Hazardous Wastes Division). A uniform tabular format should be followed in which samples from each location are described on the horizonal axis with parameter concentrations for each presented on the vertical axis. Those parameters exceeding background standards are to be prominently noted. Table B-l illustrates this format. Permanent logs should be kept indicating the date, time, method, water level, and other pertinent conditions existing at the time of sampling in the addition to statistics presented in required reports. Operators of facilities should retain records of monitoring activities and results, including all original strip chart recordings for instrumentation, calibration and maintenance of records for a minimum of 3 years. 1.2. SAMPLING PROTOCOLS Effective program enforcement depends upon access to reliable scientific evidence of the environmental effects of disposal operations. There will be even more need for sampling and testing in those cases when the history of the site is not completely documented. The analytical procedures of Part B-2 of these guidelines can yield results which are only as reliable as the manner of sampling from the site and great care must be taken in collecting and caring for such samples between the field and the laboratory. Because of the time and expense associated with the sampling process, sp dal care should be taken to: -76- 000037^56 CCR ANALYTICAL REPORT TABLE B-l Service to: Address: ,, Attention: _________ Title-___________________ Grab O Sample Type: Comp O Date Collected Ml Date Collected (21______ Preserved: Time: Time: Yes No Date Received Collected Ry Time: Brought in: EML Client G SAMPLE NO. 1 EML # end Source: File No. Report No. Invoice Nn. net* ___ P.O. No..RPD_____ MISCELLANEOUS CHARGES: 1. Total Milas at __ c/mila 2. Labor Time at /hr. 3. Shipping Charges (bus).................... .. Logged In By:Comments:. EML #and Source: SAMPLE NO. 2 PARAMETER t Pg. Ref. Cone. lbs. per bey Date Btyun icidity 273 .Ikilimty. Bicartionati 278 Carbonate 278 -Total 278 '.ollform-Fecel 937 Tout 935 real Strep 942 k 005 543 P- ,-iiride SdD 304 SSO inidc, T, rv (MGD) 361 luoridei 391 lardnen 202 Jitrogfn-Ammonia -Kjeldahl IBS 175 -Nitrate 427 -Nitrite 434 -Organic 437 Total )il & Grease 515 H 460 henolt hosph*tes-Totil 574 481 Ortho 481 lolidi-T otal 95 Total Din. 94 Total Sum- 92 -Volatile Din. 96 volatile Susp. 95 -Fixed Diet. 95 Fixed Susp. 95 pccific Cond. 71 ulfur-Sulfetc 496 Sulfide ,505 Sulfite 508 INTU) 532 132 148 Tune Begun Dm Com pleted Tune Com pleted Analyst Cone. lbs. per dey Date Begun Time Begun Date Com pleted - , Time Com pleted Analys - n- nn003T45f L.'-n.-------- i:l: 1 . X. Plan the sampling procedure before initiating it, 2. Avoid contamination and deterioration of the samples once obtained, and 3. Protect the integrity of the samples both technically and legally so as to assure their being truly representative of the actual site conditions. Guidelines are accordingly presented now for Planning the Scope of a Sampling Procedure, for Technical Standard for Sample Gathering, and for the Management of Chain-of-Custody including an outline of the requisite supporting records. Supplemen tary guidelines are also presented in EPA 600/2-80-018 (January, 1980), "Samplers and Sampling Procedures far Hazardous Waste Streams." 1.3. PLANNING THE SCOPE OF A SAMPLING PROCEDURE Efficient collection of a reliable set of samples can be supported by the following planning procedure to be accomplished and documented before proceeding to the site: 1. Careful definition of location, access and regional geography. 2. Assembly of a roster of responsible personnel at site, preliminary contact established with them and identification of other resource persons and records. 3. Collection and review of relevant state agency records (active permits) and identification of agents with earlier site experience. 1.3.1. SAMPLING LOGISTICS 1. Number of Samples To Be Taken; The number of samples naturally depends on the information desired. When gathering evidence for possible legal rae, duplicate samples are usually collected. At least two identical samples are desirable: one sample is given to the company or organization responsible for the wastes; the second sample is submitted to the state laboratory far analysis. Subdividing a waste sample at the site is not recommended. A laboratory environment is desirable to avoid contamination and to insure personnel safety. The sample, representative of the main body of waste, must be adequate in size for all needs including laboratory analyses or splitting with other organizations. For most hazardous waste sites a sample should be collected in a 2 1/2 gallon glass container, properly prepared using a teflon seal. One 2 1/2 gallon sample is gen rally sufficient for a variety of laboratory analyses. Table B-2. lists the recommended number of samples for different types of wastes. If only one parameter (such as Phenol) is to be analyzed, Table B-3. should be consulted for the proper container and sample size. -78- CCR 000037458 AH sample containers should be filled to overflowing before capping to reduce the loss of volatile components and to reduce possible oxidation. 2. Container Wash Procedures; It is critical that sampling containers and their caps be clean. The EPA Handbook for Analytical Quality Control in Water and Wastewater Laboratories (EPA 600/4-79-019) gives special instructions for the cleaning of bottles to be used far organic analysis. The bottles should be rinsed successively with; 1. Chromic acid cleaning solution 2. Tap water 3. Distilled water 4. Several rinses of redistilled solvent such as methylene chloride, ac tone, hexane, petroleum ether, and chloroform. Any solvents used in the analytical extraction should be used to prerinse the collection container. Top liners are cleaned in the same manner as collection bottles and-stored in a sealed container. Bottle caps are washed with detergent, then tap water, distilled water, and solvent. j ' 3. Type of Sample: Grab or Composite; A grab sample is one taken from only one point at one particular time. Widemouth sampling jars are preferred to facilitate rapid collection; the sample volume depends on analytical work to follow. Grab samples are required if parameters such as dissolved gases, residual chlorine, sulfides, or pH are to be analyzed. These require immediate preservation and sealing in accordance with Table B-3. A composite sample is a mixture of individual samples collected "over time" or "over space". A composite can be very useful if care is taken to make sure the sample is representative of the entire waste. In all compositing, special attention must be given to the possibility of mixing incompatible substances. (Table A-l. lists incompatible wastes and the results of mixing.) If a "flow" is involved the sampling should be proportional to the flow rate, A good ratio is one milliliter sample for each gallon per minute of flow. Automatic liquid samplers are available which composite samples on the basis of flow or time. ___ A mixture of samples taken at approximately the same time from different joints-is -----an integrated-composite. Sample: Composite-Flow; Sample aliquots are proportional to waste flow. -79- CCR 000037459 Composite-Time: Fixed sample aliquots collected at predetermined fixed intervals. Integrated: Fixed sample aliquots collected from different points at approxima tely the same time. AH details on the compositing technique used should be noted at the time of collection. The holding times given in Table B-3. should be observed. The holding time begins when the first aliquot of a composite sample is collected. The compositing time should not exceed the time available before analysis should be initiated. The overall composite volume should be sufficient for the analytical work required. A grab sample is preferred when: L The waste characteristics are relatively constant throughout the entire lot. For such wastes, an occasional grab sample is adequate rather than a lengthy complex sampling program. 2. The waste does not flow continuously such as intermittently dry discharge outlets or well-mixed samples from dumped contaminated process tanks. A grab sample is sufficient to determine the characteristics of the hazardous wastes. 3. A composite sample may obscure extreme variables in the waste. A classic example is pH variation. A composited sample may be neutral but individual grab samples exhibit a wide range of pH's. 4. Incompatible hazardous wastes are known present. 4. Selection of Sampler: Hazardous wastes are usually complex, multiphasic mixtures, f liquids, semi-solids, sludges, or solids. The liquid and semi-solid mixtures vary greatly in viscosity, corrosivity, volatibility, explosivity, or flammability. The solid wastes can range from powders and granules to large blocks or lumps. The wastes are contained in drums, barrels, sacks, bins, vacuum trucks, ponds, and other containers. No single type of sampler can, therefore, be used to collect representative samplesjjf. the different types of wastes. Table B-2. lists most waste types and the corresponding sampler to be used. A description of each sampler and its utilization is given in Section 1.3.3. of this guide. -30- TABLE B-2. RECOMMENDED SAMPLER SELECTION AND SAMPLE NUMBER Waste Type Liquids, sludges, and slurries in drums, vacuum trucks, barrels, and similar containers Liquids and sludges in ponds, pits, or lagoons Powdered or granular solids in bags, drums, barrels, and similar containers Dry wastes in shallow con tainers and suface soil Waste piles Soil deeper than 8 cm Sampler No. of Samples Limitations Coliwasa 1 Not for containers > l.S m deep a) Plastic 1 Not for wastes containing ketones, nitrobenzene, dimethyiformamide, mesityl oxide, or tetrahydrofuran. b) Glass Not for wastes containing hydrofluoric acid and concentrated alkali solutions. Pond sanpler 1 composite (surface, mid dle, near bottom) Cannot be used to collect samples beyond 3.5 m. Dip and retrieve sampler slowly to avoid bending the handle. a) Grain 1 composite sampler (3-5 points) Limited application for-- -..... sampling moist and sticky solids and when the diameter of the solids is greater than 0.6 cm. b) Sample 1 composite trier (3-5 points) May incur difficulty in retaining core sample of. very dry granular materials during sampling. Trowel or scoop 2-20 points Nay composite Not applicable to sampling deeper than 8 cm. Difficult to obtain reproducible mass of samples. Waste pile,. 2-20 points sample? con*oslfee Not applicable to sampling solid wastes with dimensions greater than h the diameter of the sampling tube. Soil auger Does not collect undisturbed core sample. Wastes in storage tanks Weighted 1 composite bottle sampler (surface, middle, near bottom) -81- Difficult to use on stony or rocky or very wet soil. May be difficult to use on very viscous liquids. CCR 000037461 TAKE B-3. RECOMMENDED CONTAINERS, PRESERVATIVES, AND HOLDING TIMES FC l ANALYTICAL PARAMETERS* Measurement Priority Pollutants Asbestos Volative Organics Physical Properties Color Conductance Hardness Odor pH Residue Filterable Non* Filterable Total Volatile Settleable Matter Temperature Turbidity Metals Dissolved Suspended Total VoL Req. (ml) Container01 Preservative 2% gal. G Cool, 4C .1 1 100 ml. p None G(serum vile) Cool, 4C 50 100 100 200 25 P.G P.G P.G G only P.G 100 100 100 100 1000 1000 100 P.G P.G P.G P.G P.G P.G P.G 200 P.G 200 100 P.G Cool, 4*C Cool, 4*C Cool, 4*C HNO3 to pH <2 Cool, 4*C Det on site Cool, 4*C Cool, 4*C Cool, 4*C Cool, 4*C None Req. DeU on site Cool, 4*C Filter on site HNO3 to pH <2 Filter on site HNO3 to pH <2 -82- Holding Time0* 24 hours 24 hours 24 Hrs. 24 Hrs.w 6 Mos. ,w 24 Hrs. 6 Hn. 7 Days 7 Days 7 Days 7 Days 24 Hrs. No Holding 7 Days 6 Mos.'" 6 Mos. 6 Mos.'" 7^62 CC* OOOO^ Measurement Mercury Dissolved TABLE B-3. (Continued) VoL Req. (ml) Container Preservative O1 0 P.G Filter on site HN03 to pH <2 Total 100 P.G HNOj to pH <2 Inorganics, Non-Metallic Acidity 100 Alkalinity 100 Bromide 100 Chloride 30 Chlorine 200 Cyanides 500 P.G P.G f,g P.G P.G P.G Fluoride Iodide Nitrogen Ammonia 300 P.G 100 P.G 400 P.G Kjeldahl Total 500 P.G Nitrate plus Nitrite 100 P.G Nitrate Nitrite 100 P.G 50 P.G None Req Cool, 4*C Cool 4*C None Req. Det. on site Cool 4*C NaOH to pH 12 None Req. Cool 4*C Cool,4*C HjS04 to pH <2 Cool 4*C HjSO< to pH <2 Cool 4*C HjS04 to pH <2 Cool 4*C Cool 4*C -83- Holding TuncTM 38 Days (Glass) 13 Days (Hard Plastic) 38 Days (Glass) 13 Days (Hard Plastic) 24 Hrs. 24 Hrs. 24 Hrs. 7 Days No Holding 24 Hrs.7 7 Days 24 Hrs. 24 Hrs. 24 Hrs.w 24 Hrs.**' 24 Hrs. 48 Hrs. 0000311*63 Measurement Dissolved Oxygen Probe Winkler Phosphorus Ortho phosphate, Dissolved Hydrolyzable Total Total, Dissolved Silica Sulfate Sulfide Sulfite Organics BOD COD Oil & Grease Organic carbon Phenolics MBAS TABLE B-3. (Continued) VoL Req. (ml) ContainerTM Preservative Holding TimeTM 300 G only 300 G only Det. on site Fix on site No Holding 4-8 Hours 30 P.G 50 P.G SO P.G so P.G 50 P only 50 P.G 500 P.G 50 P.G Filter on site Cool 4*C Cool, 4*C HjS04 to pH <2 Cool, rc HjS04 to pH <2 Filter on site Cool 4-C HjS04 to pH <2 Cool. 4*C Cool 4-C 2 ml zinc acetate DeL on site 24 Hrs. 24 His/** 24 Hrs.w 24 Hn.m 7 Days 7 Days 24 Hrs. No Holding 1000 so 1000 25 500 P.G P.G G only P.G G only 250 P.G Cool 4*C HjS04 to pH<2 Cool, 4*C HjS04 or HQ to pH <2 Cool 4-C HjS04 or HQ to pH <2 Cool 4-C H,P04 to pH <4 I.0 g CuSO*/! Cool 4*C 24 Hrs. 7 Days'*' 24 Hrs. 24 Hrs. 24 Hrs. 24 His. --84-- \iVbu \0^,0* -.0* TABLE B-3. (Conti neud) . Measurement Voi Req. (ml) Container*" Preservative Holding Timew NTA 50 P,G Cool, 4*C 24 Hrs. 1. More specific instructions for preservation and sampling are found with each procedure as detailed in this manual. A general discussion on sampling water and industrial wastewater may be found in ASTM, Part 31, p. 72-82 (1976) Method D-3370. 2. Plastic (P) or Glass (G). For metals, polyethylene with a polypropylene cap (no liner) is preferred. 3. It should be pointed out that holding times listed above are recommended for properly preserved samples based on currently available data. It is recognized that for some sample types, extension of these times may be possible while for other types, these times may be too long. Where shipping regulations prevent the use of the proper preservation technique or the holding time is exceeded, such as the case of a 24-hour composite, the final reported data for these samples should indicate the specific variance 4. If the sample is stabilized by cooling, it should be warmed to 25*C for reading, or temperature correction made and results reported at 25'C. 5. Where HNOj cannot be used because of shipping restrictions, the sample may be initially preserved by icing and immediately shipped to the laboratory. Upon receipt in the laboratory, the sample must be acidified to a pH <2 with HNOj (normally 3 ml 1:1 HNOj/Iiter is sufficient). At the time of analysis, the sample container should be thoroughly rinsed with 1:1 HNOj and the washings added to the sample (volume correction may be required). 6. Data obtained from National Enforcement Investigations Center-Denver, Colorado, support a four-week holding time for this parameter in Sewerage Systems. (SIC4952). Adapted from the EPA "Recommendation for Sampling and Preservation of Samples According to Measurement" 1.3.2. Safety in Drawing Samples from Hazardois Waste Containers: The fcdl wing detailed procedures are recommended for sampling the various types of hazardous wastes in different types of containers: L Sampling a Drum The EPA has recommended that drums should not be opened unnecessarily until completely safe methods have been developed and tested. Current research is being conducted.in the use of remote opening devices. Drums containing liquid wastes can be under pressure or vacuum. A bulging <frum usually indicates that it is under high pressure and should not be sampled until the pressure can be safely relieved. A heavily corroded or rusted drum can readily rupture and spill its contents when disturbed and should only be sampled with extreme caution. Opening the bung of a frum can produce a spark that might detonate an explosive gas mixture in the drum. These situations are difficult to predict. The use of full protective sampling equipment cannot be over-emphasized when sampling a drum. When the EPA publishes recommended safe procedures for sampling drums, this sampling guide will be updated. 2. Sampling a Vacuum Truck In sampling a vacuum truck, the collector must climb onto the truck and walk along a narrow catwalk. In some trucks, one must climb access rungs to the tank hatch. These situations present problems to the sample collector who must wear protective sampling gear. Preferably, two persons should perform the sampling: one person will do the actual sampling, and the other stands ready with the sample container to aid in any problems. Sampling should be conducted only when a breeze is present to disperse any concentration of gases. The sample collector positions himself to collect samples only after the truck driver has opened the tank hatch. The tank is usually under pressure or vacuum, and the driver should open the hatch slowly to release pressure or to break the vacuum. The following instructions are recommended. 1. Let the truck driver vent the tank prior to opening the hatch of a tank under positive pressure. 2. Using protective sampling gear, assume a stable stance on the tank catwalk or access rung to the hatch. 3. Collect a sample through the hatch opening with a Coliwasa. 4. If the tank truck is not horizontal, take one additional sample from the rear and the front clean-out hatches and combine all three samples in th same sample container.5 4 5. When necessary, carefully take a sediment sampl from the tank through the drain spigot. -86- _ . .... . 000 03^ , ct* a 3. Sampling Barrels, Fiberdrums, Cans, Bags, or Sacks Containing Powder or Granular Waste The proper protective respirator, in addition to other protective gear, must be worn when sampling dry powdered or granular wastes. These wastes tend to generate airborne particles when the containers are disturbed. The containers must be opened slowly. The barrels, fiber<i*ums, and cans should be positioned upright. If possible", sample the sacks or bags in the position in which they are found. Standing sacks or bags upright might cause them to rupture. Collect a composite sample from the container with a grain sampler or sampler trier. 4. Sampling a Pond Storage or evaporation ponds for hazardous wastes vary greatly in size. It is difficult to collect representative samples from the large ponds without incurring great expense and assuming excessive risks. Any samples desired beyond 3.5 meters from the bank may require the use of a boat, which is very risky, or the use of a crane. The information desired must be weighed against the risk and expense in collecting the samples. See Tables B-l. and B-4. for number and locations of sampling points. 5. Sampling Soil The standard techniques of soil sampling are numerous. The procedures outlined below are adapted from these techniques. The procedures are consistent with hazardous waste management objectives of collecting soil samples to determine the residue level in the soil. There are elaborate, statistically designed patterns for sampling soil. If a large area is to be sampled the statistical approach should be used to obtain the most representative sample. If one desires to use these patterns, a good statistics book should be consulted. In the following procedures, soil samples are taken in a grid pattern over the entire site to ensure a uniform coverage of the site. 1. Divide the area into an imaginary grid, 1 grid for each sample to be collected. 2. Sample each grid and combine the samples into one composite sample. 3. To 8 cm deep, collect samples with a scoop. 4. To sample beyond 8 cm deep, collect samples with a soil auger. 6. Sampling Waste Piles Waste piles can range from a small heap to a large aggregate of wastes. The wastes are predominantly solids and can be a mixture of powders, granules, and chunks 1 inch -87- cca 000037^7 (2.5 cm in diameter or larger. A number of core samples have to be taken at (Afferent angles and composited in order to obtain a sample which, in analysis, will give average values far the hazardous components in the waste pile. L Determine the sampling points. 2. Collect a composite sample with a waste pile sampler. 7. Sampling a Storage Tank The collection of liquid samplers in storage tanks is extensively discussed in the ASTM Procedures. The procedure used here is adapted from one of the ASTM methods. Sampling a storage tank requires manual dexterity. Usually it requires climbing to the top of the tank through a narrow vertical or spiral stairway while wearing protective equipment and carrying sampling paraphernalia. At least two persons must perform the sampling; one to collect the actual samples and the other to stand back, usually at the head of the stairway, to assist or to call for help in case of problems. The sample collectors must be accompanied by a representative of the company who must open the sampling access, usually on the tank roof. The tank should not be opened in a "no wind" condition. Fumes can collect to toxic levels around the sample access point. 1. Collect one sample each from the upper, middle, and lower sections of the tank contents with a weighted bottle sampler. 2. Combine the samples in one container and submit it as a composite sample. 3. The sampling bottle should be replaced with a clean bottle far each sample site. -88- ooOo*1 Table B-4. SAMPLING POINTS FOR WASTE CONTAINERS Container Sampling Point Drum, bung on one end* Withdraw sample through the bung opening. Drum, bung on side* Lay drum on side with bung up. Withdraw sample through the bung opening. Barrel, fiberdrurn, buckets, sacks, bags Withdraw samples through the top of barrel, fiberdrums, buckets, and similar containers. Withdraw samples through fill openings of bags and sacks. Sample through the center of the containers and to different points diagonally opposite the point of entry. Vacuum truck and similar containers Withdraw sample through open hatch. Sampl all other hatches. Pond, pit, or lagoon Divide surface area into an imaginary grid.a Take three samples if possible; one at the surface, one at mid-depth, and one near the bottom. Repeat the sampling at each grid over the entire pond or site. Waste pile Withdraw samples through at least three differ nt points near the top of the pile to points diagonally opposite the point of entry. Storage tank Sample from the top through the sampling hole. Withdraw three samples; one at the top, one at mid depth, and one near the bottom. Soil Divide the surface area into an imaginary grid.a Sample each grid. * THE EPA STATES THAT DRUMS ARE NOT TO BE OPENED EXCEPT BY REMOTE DEVICES. a The number of grids is determined by the desired number of samples to be collected which when combined should give a representative sample of the wastes. CL9- 1.3.3. Sampling Devices L Solid Waste Samplers There are a number of available tools used in sampling solid substances. The most suitable for sampling solid hazardous wastes are the grain sampler, sampling trier, and the trowel or scoop. a. Grain Sampler; The grain sampler, Figure B-5., consists of two slotted telescoping tubes, usually made of brass or stainless steel. The outer tube has a conical pointed tip on one end which permits the sampler to penetrate the m atrial being sampled. The sampler is opened and closed by rotating the inner tube. Grain samplers are generally 61 to 100 cm long 1.27 to 2.54 cm in diameter. They may be purchased from laboratory supply houses. Utilization: The grain sampler is used for sampling powdered or granular waste materials in bags, flberdrums, sacks or similar containers. This sampler is most useful when the solids are no greater than 0.6 cm (i) in diameter. Procedure; L While in the closed position, insert the sampler into the granular or powdered waste from a point near a top edge or comer, through the center, to a point diagonally opposite the point of entry. 2. Rotate the inner tube of the sampler into the open position. 3. Wiggle the sampler a few times to allow materials to enter the open slots. 4. Place the sampler in the dosed position and withdraw. 5. Place the sampler in a horizontal position with the slots facing upward. 6. Rotate and slide the outer tube out from the inner tube. 7. Transfer the collected sample in the inner tube into a suitable container. 8. Collect two or more core samples at different points and combine the samples in the same container. 9. Cap the sample container; attach label and seel; record in field log book; and complete sample analysis request sheet and chain-ofcustody record. 10. Clean, or store the sampler in plastic bag for subsequent cleaning. 11. Deliver the sample to the laboratory for analysis. -90- oO'0^1*no f n^ Jr. -^l _> r-?l Zl VO OI fMW. W (Si 1.27-2.54 ~>| j<- Grain Sampler Or> -p ooo ooJ l ! 1.27-2.5/i cre (^-l") Sample Trier wr-- 4: b. Sampling Trier: A typical sampling trier is a long tube with a slot that extends almost its entire length. The tip and edges of the tube slot are sharpened to allow the trier to cut a core of the material to be sampled when rotated after insertion into the material. Sampling triers are usually made of stainless steel with wooden handles. They are about 61 to 100 cm long and L27 to 2.54 cm in diameter. A sampling trier can be purchased from laboratory supply houses. Utilization; The trier's use is similar to that of a grain sampler as discussed above. It is preferred when the powdered or granular material to be sampled is moist or sticky. In addition, the sample trier can be used to obtain soft or loosened soil samples up to a depth of 60 cm as outlined below. Procedure; 1. Insert the trier into the waste material at a 0 to 45 angle from horizontal. This orientation minimizes the spillage of sample from the sampler. 2. Rotate the trier once or twice in order to cut a core of material. 3. Slowly withdraw the trier making sure that the slot is facing upward. 4. Transfer the sample into a suitable container with the aid of a spatula and/or brush. 5. Repeat the sampling at different points two or more times and combine the samples in the sample container. 6. Cap the sample container; attach the label and seal; record in field log book; and complete sample analysis request sheet and chain-ofcustody record.7 8 7. Wipe the sampler dean, or store it in a plastic bag for subsequent deaning. 8. Deliver the sample to the laboratory for analysis. c. Trowd or Scoop; A garden-variety trowel looks like a small shovel. The blade is usually about 7 X 13 cm with a sharp tip. The laboratory scoop is similar to the trowel, except that the blade is usually mare curved and has a dosed upper end to permit the containment of material. Scoops come in different sizes and makes. Stainless steel or polypropylene scoops with 7 X 15 cm blades are preferred. A trowd can be bought from hardware stores; the scoop can be bought from laboratory supply houses. -92- i Utilization: An ordinary zinc-plated garden trowel can be used in some cases to sample dr, granular or powdered materials in bins or other shallow containers. The laboratory scoop, however, is superior. It is usually made of a corrosive-resistant material, thus lessening the probability of sample contamination. The trowel or scoop can also be used in collecting top surface soil samples. Procedure: L At regular intervals take small equal portions of sample from the surface or near the surface of the material. 2. Combine the samples in a suitable container. 3. Cap the container; attach the label and seal; record in field log book; and complete sample analysis request sheet and chain-of-custody record. 4. Deliver the sample to the laboratory for analysis. d. Soil Auger; The auger consists of a hard, metal, central shaft and sharpened spiral blades. When the tool is rotated clockwise by its wooden T-handle, it cuts the soil as it moves forward and discharges mast of the loose soil upward. The cutting'diameter is about 5 cm. The overall length is about 1 m (40 inches) with graduations every 15.2 cm (6 inches); the length can be increased to 2 m. This tool can be purchased from hardware or farm implement stores. Utilization: The auger is particularly useful in collecting soil samples at depths greater than 8 cm. This sampler destroys the structure of cohesive soil and does not distinguish between samples collected near the surface or at greater depths. It is not recommended, therefore, when an undisturbed soil sample is desired. Procedure: 1 Select the sampling point and remove unnecessary rocks, twigs, and other non-soil materials. 2. Install the sampler's wooden T-handle in its socket. 3. Bore a hole through the middle of an aluminum pie pan large enough to allow the blades of the auger to pass through. The pan will be used to catch the sample brought to the surface by the auger. 4. Spot the pan against the select d sampling point.* *93- ,0^I1*,13 5. Begin augering through the hole in the pan until the desired sampling depth is reached. 6. Pull back the auger and transfer the sample collected in the catch pan and sample adhering to the auger to a suitable container. Spoon out the rest of the loosened sample with a sample trior. 7. Repeat the sampling at different points and combine the samples in the same container as in Step 6. 8. Cap the sample container; attach label and seal; record in field log book; and complete sample analysis request sheet and chain-ofcustody record. 9. Brush-off and wipe the sampler clean, or store it in a plastic bag for subsequent cleaning. 10. Deliver the sample to the laboratory far analysis. 2. Liquid Samplers Among the most common liquid samplers- are the pond sampler, the weighted bottle sampler, the wastewater pump, and the Coliwasa. Some of these samplers may be fabricated and some may be purchased from various scientific/ supply houses. a. Pond Sampler; The pond sampler consists of an iadjustable damp attached to the end of a 2 or 3 piece telescoping aluminum tube which serves as the handle. The damp is used to secure a sampling beaker. The sampler is not commercially available, but it is easily and inexpensivdy fabricated. The tubes can be readily purchased from most hardware or swimming pool supply stores. The adjustable damp and sampling beaker can be obtained . from most laboratory supply houses. The suggested materials required to fabricate the sampler are as follows: *4- CCR 000037474 BASIC PARTS OF A POND SAMPLER Quantity Item Supplier & Approximate Cost . 1 Clamp, adjustable, 6.4 to 8.9 cm (2i to 3i") for 250 to 600 ml beakers Laboratory supply houses $7.00 1 Tube, aluminum, heavy duty, tdescoping extends 2.5 to 4.5 m with joint cam locking mechanism. Pde diameters 2.54 cm 0") LD. and 3.18 cm (li") LD. Olympic Swimming Pool Co. $16.24 807 Buena Vista Street Alameda, CA 94501 or other general swimming pod supply houses. 1 Beaker, pdypropylene 250 ml or widemouth quart glass jars. Laboratory supply houses $L00 1 Bolts, 2i X i", NC Hardware stores - 5 each 1 Nuts, i", NC Hardware stores - 5<t each Utilization; The sampler is used to collect liquid waste samples fr m disposal ponds, pits, lagoons, and similar reservoirs. Grab samples can be obtained as far as 3.5 m from the edge of the ponds and at different depths. Very viscous liquids should be sampled slowly or the tubular aluminum handle may bow. Procedure; L Assemble the pond sampler. Make sure that the sampling beaker and the bolts and nuts that secure the clamp to the pole are tightened properly. 2. While wearing proper protective gear, take grab samples from the pond at different distances and depths. 3. Combine the samples in one suitable container. 4. Cap the container; label and affix the seal; record in field log book; and complete sample analysis request sheet and ehain-of-custody record. 5. Dismantle the sampler; wipe the parts with dean towels or rags and store them in plastic bags for subsequent deaning. 6. Deliver the sample to the laboratory for analysis. o0003^75 -95 CCR Weighted Bottle Sampler; This sampler consists of a bottl , usually glass, a weight sinker, a bottle stopper, and a line which is used to open the bottle and to lower or raise the sampler during sampling. There are variations of this sampler as illustrated in the ASTM Methods D 279 8 and 3009 . The ASTM sampler with a metallic bottle basket which also serves as weight sinker is preferred. It can either be fabricated or purchased. Utilization: The weighted bottle sampler can be used to sample liquids in storage tanks, wells, sumps, or other containers that cannot be adequately sampled with a Coliwasa. The sampler cannot be used to collect liquids which are incompatible or which may react chemically with the weight sinker and line. Procedure: 1. Assemble the weighted bottle sampler; 2. While using protective sampling equipment, lower the sampler to the proper depths to collect the following samples: a) upper sample - middle of upper 1/3 of tank contents. b) middle sample - middle of tank contents. c) lower sample - near bottom of tank contents. 3. Pull out the bottle stopper with a sharp jerk of the sampler line. 4. Allow the bottle to fill completely as evidenced by the cessation of air bubbles. 5. Raise the sampler and retrieve and cap the bottle. Wipe-off the outside of the bottle with a towel or rag to avoid contamination. Combine the three samples into one composite sample. 6. A clean catch bottle should be used for collecting each sample. 7. Label the samples collected; affix seal, fill out sample analysis request sheet and chain-of-custody record; record in the field log book. 8. Clean on-site, or store contaminated sampler in a plastic bag for subsequent cleaning.9 9. Deliver the sample to the laboratory for analysis. CO* 0000,1 -96 Wastewater Sampling Pump; This sampl r consists of a pump, a control panel, and an insulated container used to hold up to 2i gallons of sample on ice. This kind of sanpler is available from several companies in a variety of styles. Utilization; The pump can be used to sample most aqueous solutions. Best use is made at monitor wells, wastewater effluents, and hazardous waste pits. Procedure; The manufacturer's instruction manual should be studi d for each model of pump used. General procedures are outlined here. The pumps consist of a section of silicon tubing within which the sample is forced through by two revolving rollers. A length of tygon tube of sufficient length to collect the sample is attached to the suction end of the pump. The tygon tubing should be changed with each new sample; the pump tubing should be changed between each different survey. One gallon of blank water is to be used. One third of the blank water is to be pumped through the tygon and pump tubing and not collected. The remaining two thirds of the blank water is to be collected in a properly------prepared one (1) gallon container and to be shipped along with the sample to the laboratory. Contaminates found in the blank water indicate contami nation within the collection system and will be deducted from that found in the sample. The testing laboratory should furnish the blank distilled/ deionized water. After collecting the blank, the sample should be collected immediately. The sample container and amount should be determined by Table 7. If a variety of tests are to be run, the use of a 2i gallon sample container properly prepared is recommended. When collecting the blank and the sample, never contaminate the container or lid by touching the inside or setting the lid down. Cleanliness is of the utmost importance as a sample contaminated by the field personnel is of no use. 1. Assemble the wastewater sampling pump; attach new tygon collection tubing. Change silicon pump tubing if indicated. 2. Pump 1/3 gallon of blank water through pump and into a s parate discard container. (Do not contaminate sampling area with blank water.)3 3. Pump remaining 2/3 gallon blank water into a clean, labeled, one gallon container; cap the container. (Go to Step 5) -97- oOO oV* C.C* 4. Begin pumping sample into the clean 2i gallon sample container utilizing a grab, composite-tim , composite-flow, or integratedcomposite sampling system. * 5. After pumping sample, cap the container using a teflon-lined lid. Label and affix the seal; record in field log book; and complete sample analysis request sheet and chain-of-custody record. 6. Refrigerate sample. 7. Dismantle sampler. 8. Deliver sample to the laboratory for analysis. Coliwasa; (Table B-6.): This sampler consists of a plastic or glass tube with a stopper in the end of it. The stopper can be opened and closed, allowing the sample to enter, by use of a stopper rod. Use of plastic or glass is dictated by the type of sample to be collected. Utilization! The Coliwasa is used to collect aqueous samples up to five feet in depth. Its narrow dimensions make it ideal for sampling drums, tanks, and waste carrier trucks. The simplicity of design and small expense make the Coliwasa expendable when contaminated. Procedure; A dean Coliwasa is used for each sample. 1. With the stopper in the open position, lower the Coliwasa into the aqueous material. 2. Close the stopper and withdraw the sampler. 3. Empty the sample into a dean suitable container. 4. Cap the container; label and affix the seal; record in fldd log book; and complete sample analysis request sheet and chain-of-custody record. 5. Preserve or refrigerate sample. 6. Deliver sample to laboratory for analysis. -08-- 000037473 *^ .'! i i i l.52m(5'-0") <---------- |Tlrpndod section, rod Threodod p 1 tif* ( PVC *---------- Stopper- rod, I'VC, O.93cm(3/0") 0.0. Pipe, l'VC ft.l3cm(l-5/B") l.D. ft. 76cm0-7/0") O.D. ) CCR 0 0 0 0 3 7 4 7 9 S.S. Bide wires io nnur>e V SAMPLING POSITION TABLE B-6. Stopper, neoprene, 09 CLOSE POSITION Goliwasaj I 3. Definition of sampling goals including specification of the types and extent of samples being sought and their intended use. 4. Specification of equipment to be used including a record of calibration and check out (Table B-7). Designation of materials requirements for containers and apparatus should be made from the standard list presented in Table B-2. 5. Collection and testing of required service equipment for the site visit including containers, blanks, utilities and batteries. 6. Review of the nature of potential hazards and advice to sampling team on appropriate safety precautions. 1.3.4. Preservation and Storage of Samples Ideally hazardous waste samples should be analyzed immediately after collection for maximum reliability of the analytical results. Specific attention should be given to the following; L In a matter of minutes, sulfides and cyanides may be oxidized or evolve as gases; 2. Hexavalent chromium may slowly be reduced to the trivalent state. 3. Certain cations may be partly last due to adsorption to the container walls. 4. Growth of microorganisms may also cause changes to certain constituents of the sample. 5. Volatile compounds may be rapidly lost. Changes may be slowed or prevented by refrigeration at 4 to 6 C and/or by the addition of preservatives according to Table B-8. (Refrigeration may deter the evolution of volatile components and acid gases such as hydrogen sulfides and hydrogen cyanides, but it also introduces the uncertainty that some salts may precipitate at lower temperatures. The addition of preservatives may retard biochemical changes ,-yhut may convert some constituents to stable hydroxides, salts, or compounds. In bsequent analysis, the results may not reflect the original identity of the -proponents.) These methods of preservation or stabilization are therefore, not -100- -.c> o'* TABLE B- 7. DATE Water Sampling Equipment ___ Conductivity Meter ___ pH meter ___ O2 meter ___ Composite sampler ISCO Model 1680 v/batteries, charger & tygon tubing ___ Sampler (pole) ___ glass jars a. 2% gal.(pesticide clear) b. quart Container Case for: ___ Heavy Metals ___ O Is C ___ COD ___ _ Phenols ___ Sulfide ___ Pesticide ___ Asbestos-containers (plastic) ___ Plastic jugs ___ Fecal cups _____ Volatile Organic Bottles w/crimper ___ Thermometer ___ Blank Water (deronized distilled) for flushing __ Blank Water Standard Protective Devices Hard Bats Goggles Respirators ScottAirPak Gloves Coveralls Hip Waders First Aid Kit Flush Bottle (eye) Plastic rainsuits HAZARDOUS WASTE SITE EQUIPMENT Air Sampling Equipment SITES: (1) (2) (3) (4) Soil Sampling Equipment 2 Air sampling pumps Charcoal tubes 2 Fritted bubblers x/llNAOH, DIST B20 MSA test kit v/tube for: Benzene Hydrogen Sulfide Vinyl Chloride Carbon Monoxide Explosimeter & Probe Sampler bottles (glass) Radac Instrument Hand auger & extensi Sample containers 100 fr. rollup tape Clipboard Grid line paper Hand compass Miscellaneous Machette Shovel Bucket v/line Paper towels & toilet tissue Plastic disposal gloves Credit card Map-Louisiana Name tags & cards Water proof pen Container tags fML analytical report forms Walkie talkie Camera, Polaroid Film, 2 packs at least Flashlite Consulting sheet & clipboard Pocket calculator Chain of custody forms -101- 000031'*81 ccR Preservative HgClj Add (HNOg) Add (HgSO^) Alkali (NAOB) Refrigeration * TABLE B- 8. Action Inhibits bacteria Dissolves metals pre vents precipitation Inhibits bacteria Forms salts with organic bases Forms salts with volatile compounds Inhibits bacteria Retards chemical reactions Applicable tot Nitrogen forms, Phosphorus forms Metals Organic samples (COD, oil & grease organic carbon), Nitrogenphosphorus forms Ammonia, amines Cyanides, organic acids Acidity-Alkalinity, organic P, organic N, carbon, etc., biological organisms (coliform, etc.) -102- OCR 000037^82 recommended for hazardous wastes samples unless attention is to be given to only one or two components where the effect of the preservative is specifically known. Recommended preservatives for various constituents are given in Tables B-E and B-15. along with appropriate holding times. 1.3.5. Sample Integrity ....... L Chain-of-Custody Procedure; a. The agency and permittee must both be in a position to demonstrate the reliability of evidence by proving the chain of possession and custody of samples for which analytical test results are presented. ~~ Procedures are presented to create an accurate written-record that can be used to trace the possession of the sample from' the moment of its collection through its introduction into evidence. A sample is in custody if it is in any one of the following states: L In actual physical possession. 2. In view, after being in physical possession. 3. In physical possession and locked so that no one can tamper with it. 4. In a secured area, restricted to authorized personnel. b. All personnel involved should receive copies of custody plans prior to the study of a pollution or hazardous waste case. Prestudy briefings should then be held to apprise participants of the objectives, sample locations, and chain-of-custody procedures to be followed. After the chain-of-custody samples are collected, a briefing should be held in the field to verify the adherence to the chain-of-custody procedures and to determine whether additional samples are required. Table B-9. summarizes these procedur s. c. Chain-of-Custody Record; To establish documentation necessary to trace sample possession from the time of collection, a chain-of-custody record must be completed and must accompany every sample. This record becomes especially important if the sample is going -to be introduced as evidence in litigation. An example of a chain-of-custody receipt is illustrated in Table B-10. d. Sample Delivery to the Laboratory: The sample is delivered to the laboratory for analysis as soon as practical, usually the same day as the sampling. Preferably the sample is delivered in person. The sample must be accompanied by the chain-of-custody record and by a sample analysis request sheet. The sample is deliver d to the person in the laboratory authorized to receive samples; this laboratory person is often referred to as sample custodian. - "103- ccr 00003748 3 TABLE B- FIELD INSPECTION AND ANALYSIS PROTOCOL 1. Predeployment Equipment: Safety Sampling Miscellaneous Equipment: (see attached list-) Sampling: Water Air Soils Miscellaneous 2. Arrival Protocol: Advance notice of arrival Preinspection conference - Topics discussed: a. Sampling site locations (map) Sampling procedure Analytical tests methods Approval for taking photos e. Compliance with plant safety requirements 3. On site sampling procedures: a. Duplicate split samples b. Chain of custody receipting c. Security of samples (placed in secure ice chest in van) d. Numbering of samples A. Departure Protocol: a. Predeparture conference b. Dispensing of Chain of Custody Receipts for each sample site c. Return of any plant-issued safety items d. Approval of photos taken 5.. Enroute precautions: a. Insure that samples are iced and others properly preserved. b. Insure security of samples c. Assurance that sample chest is visible and/or secure with lock .6 Arrival procedures: a. Log in samples in appropriate book with DNR number b. Commence immediate analysis on samples with a short holding time c.. Place remaining samples in secure storage containers for subsequent analysis d. Insure that approved EPA analytical procedures are used in testing of samples "104m CC* 0000n`>8'* * CONTAINER TYPE: OGIan ! Flattie O Other PRESERVED: TABLE B-10. YES Dno 105- CCR 000037^85 e. Shipping of Samples: When a sample is shipped to the laborat ry, it must be packaged in a proper shipping container to avoid leak .ge and/or breakage. A cardboard box that will provide at least 10 cm of tight packing around the sample container must be used. Acceptable packing materials include sawdust, crumpled newspapers, vermiculite, polyurethane chips, and others. Provision must be made to maintain refrigeration when appropriate. 2. Labeling of Samples The sample tag shown in Table B-tt. is used to identify each sample from the time it is collected until the final report from the laboratory is received. Incomplete information may lead to confusion as to sample source, thus making any testing invalid. The following information is the minimum to be included an sample tags: 1. Agency name (client) 2. Agency address 3. Sample source 4. Samplers' name 5. Date and time slapped 6. Whether Composite or Grab The sample source or identification number should also be indicated an the sample container by marker. 3. Sample Seals Sample seals are used to preserve the integrity of the sample from the time of collection until it is opened in the laboratory. Gummed paper seals can be used as official sample seals. The paper seal must carry information such as: Collector's name Date and time of sampling The seal must be attached in such a way that it is necessary to break it in order to open the sample container. An example of a sample seal is shown in Table B-12.4 4. Field Log Book AH information pertinent to a field survey and/or sampling should be recorded in a log book by the agency and by the agent of the site owner. The book is a bound one, preferably with 21.6 X 27.9 cm (8i X Hn) pages numbered consecutively. Entries in the log book must include at least the following: 106- oo 003^ TABLE B-ll. SAMPLE LABELING TAG TABLE B-12. LOUISIANA DEPARTMENT OF NATURAL RESOURCES Name Identification of Site Date of SamplingS... Time,of Sampling SAMPLE SEAL [ -107- ^0 0^ C<* Purpose of sampling (e.g., surveillance, etc.) Location of sampling ( .g., hauler, disposal site, etc.) and address C' Name and address of field contact Producer of waste and address Typ of process (if known) producing waste Type of waste (e.g., sludge, wastewater, etc.) Declared waste components and concentrations Number and volume of samples taken Description of sampling point Date and time of collection Collector's sample identification number(s) Sample distribution (e.g., laboratory, hauler, etc.) References such as maps or photographs taken of the sampling site Any field measurements made such as pH, flammability, explosivity, etc. Field Observations; Sampling situations vary widely. No general rule can be given as to the extent of information that must be entered in the log book. A good rule, however, is to record sufficient information so that someone may reconstruct the entire sampling situation from the field log without reliance on the collector's memory. The log book must be protected and kept in a safe place.5 5. Analytical Report - An analytical report of the scope presented in Table B~L should be presented connecting analytical results with relevant sampling statistics. A -108- CCR 000037488 B.2. ANALYTICAL CITATIONS 2.1. General Laboratory Practices; All laboratories are expected to subscribe to the practices outlined in the EPA Analytical Quality Control Manual (EPA-600/4-79019)except where specific variance is requested. The Table of Contents of this manual is presented as Appendix B-l. Controls aim to promote early recognition, prevention, and corrections of factors leading to breakdowns in the validity of data. Two other usefiil sources which describe laboratory quality control and which should be consulted as secondary standards are the following; - 1) Annon., 1979 Annual Book of ASTM Standards - Part 31 - Water, American Society for Testing and Materials, Philadelphia, Pa. (1979). 2) Annon., Standard Methods for the Examination of Water and Wastewater, 14th Edition American Public Health Association, Washington, D.C. (1976). As noted, any variations from the practices elucidated in the above three sources should first meet with the approval of the Department of Natural Resources. Note is also taken at this time of the soon-to-be released EPA document, SW-846, "Test Methods for the Evaluation of Solid Waste, Physical/Chemical Methods". 2.2. Analytical Techniques; A listing of approved analytical techniques for pertinent waste characteristics is shown in Tables B-21 and B-22. Table B-21.describes the required volume, the essential instrumentation, reliability of analysis, and applicable range for each parameter. The material in the table is for wastewater, sludges, soils, and plant tissues. This list is augmented by the approved analyses for wastes and waters given in Table B-22 (taken from the Federal Register submitted by EPA on December 1, 1976). For updated or revised techniques for organics, metals, etc. the" Federal Register and the new EPA document, SW-846, should be used as a continuing__ reference. Description of preservation and sampling methods is presented in Section 1 of these guidelines. ----------------- A listing of relevant sources for specific analytical techniques is given below: 1. Annon., Methods for Chemical Analysis of Waters and Wastes, Environ. Monitor ing and Siqjport Laboratory, ORD, USEPA, Ciim., Ohio, EPA 600-4-79*4)20,1979. *109- ccR 000037489 Annon., 1979 Annual Book of Standards - Part 31 - Water, American Society for Testing and Materials, Philadelphia, PA., 1979. Handbook for Analytical Quality Control in Water and Wastewater Laboratories. EPA, Technology Transfer, 1979. M. C. Rand, M. T. Taras, and A. E. Greenberg, Standard Methods for the Examination of Water and Wastewater. 14th Edition, American Public Health Association, Washington, D.C. 1976. "Manual of Methods for Chemical Analysis of Water and Wastes". Technology Transfer, U.S. Environmental Protection Agency, Washington, D.C., EPA-626*16 -74-003 (1974). Handbook for Monitoring Industrial Wastewaters, U.S. Environmental Protection Agency (August, 1973). American Society of Agronomy and American Society for Testing and Materials, Methocte of Soil Analysis. Part 2, Chemical and Microbiological Properties, edited by C. A. Black et al., American Society of Agronomy, Inc., Madison, Wisconsin, Number 9 in the Series Agronomy (1965). American Society of Agronomy and American Society for Testing and Materials, Methods of Soil Analysis. Part 1, Physical and Mlnerblogioal Properties Including Statistics of Measurement and Sampling, edited by C. A. Black et al, American Society of Agronomy Inc., Madison, Wis., Number 9 in the Series Agronomy (1965). H. D. Chapman, "Methods of Analysis for Soils, Plants, and Waters", University of California, Division of Agricultural Sciences, Riverside, California (August, 1961). Aimon., 1976 Annual Book of Standards - Part 31 - Water, American Society for Testing and Materials, Philadelphia, Pa., 1976. "Methods for Organic Pesticides in Water and Wastewater", EPA, National Environmental Research Center, Cincinnati, Ohio (1971). Dlfco Manual of Dehydrated Culture Media and Reagents for Microbiological and Clinical Laboratory Procedures, Ninth Edition, Difoo Laboratories Incorporated (1962) "Sellnite Broth". E. A. Benbrook and M. W. Sloes, Veterinary Clinical Parasitology. 3rd Edition, Iowa State University Press, Ames, Iowa 0961). John A. Kolmar, Spaulding, and H. W. Robinson, Approved Laboratory Technic, Fifth Edition, Appleton-Century-Crofts, Ine., New York, New York (1951). -no- CCR 000037490 Analytical methods are a rapidly changing art. The procedures presented here should be viewed as guidelines. Permittees are invited to offer alternatives of equivalent or superior quality far Department approval at application or at any subsequent time prior to reliance upon said method as the basis for compliance. -f < -111- CCR 000037491 Parameter Temperature Total Suspended Solids Total Dissolved Solids Total Volatile Suspended Solids Hardness pH Color Conductance Odor Total Solids Settleable Solids Turbidity Table B*-21. Analytical Techniques 1 Volume of Sample (ml) Essential Instrumentation Reliability (Coefficient of variation) I. GROUNDWATER, SURFACE WATER, AND DILUTE SLUDGES, WASTEWATERS A. PHYSICAL INDICATORS 1,000 Thermometer Depends 50-1,000 Steam Bath, Drying Oven, Filtration Setup, Analytical Balance + 102 100-20,000 Steam Bath, Drying Oven Analytical Balance 5X 50-100 Steam Bath, Drying Oven, Analytical Balance Muffle Furnace 10% 50-100 Titration Setup, Reagents, Indicators + 15% 10 to 20 pH Meter +1.5% 50 Spectrophotometer Reactor tubes - 100-1,000 Conductivity Meter + 8.6 200 - - 100-20,000 Steam Bath, Drying Oven, Analytical Balance, Muffle Furnace + 5% 1,000 Imlioff 100-1,000 Turbldltv Meter 9 + 51 Applicable Range mg/11 ter Depends 4-20,000 10-20,000 10-170 10-400 0-14 (! 5-70 0-112,000 - 10-20,000 JTU NTU -112- CCR 0 0 0 3 7 4 9 2 Parameter Total Phosphorus Inorganic Phosphorus Total Kjeldahl Nitrogen Nitrate-Nitrite Nitrogen Potassium Chromium (total and hexavalent) Copper Nickel Zinc Mercury Table B.-21.(Continued) Volume of Sample (ml) 50-100 100-200 500 50-100 100-1,000 100-1,000 200 to 4,000 100 to 1,000 100 to 1,000 100 to 1,000 Essential Instrumentation 3. Nutrient Indicators Digestion Apparatus Spectrophotometer Kjeldahl Setup, Spectrophotometer Sp ec trophot omet er Atomic Absorption or Spectrophotometer 4. Trace Metals Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer Atomic Absorption Reliability (Coefficient of variation) + 102 + 302 32 + 102 AA + 102 S-20 + 162 Applicable Range mg/11ter 0.01-6 0.01-6 1.25 m O' ro o o CuulC 0.05-10 0.005-2 DA-01-2 AA + 252 S-20 + 32 AA + 102 S-20 + 102 AA + 132 S-20 + 252 AA + 82 S-20 + 152 AA + 102 S-20 + 152 0.01-2000 DA-0.5-10 F-.005-.1 0.005-10 DA-O.2-5 F-.005-0.1 0.02-20 DA-0.3-5 F-0.005-0.1 0.005-10,000 DA-O.3-5 F-0.0002-0.004 0.0002-10 DA-0.02-5 , Flameless 1 . rt tfHH 1 I Parameter Chloride Sulfate Calcium Sodium Iron Magnesium Biochemical Oxygen Demand Chemical Oxygen Demand Total Organic Carbon l Table B. -21. (Continued) Volume of Sample (ml) Essential Instrumentation 25 ttx 100 100 to 1,000 100 to 1,000 100 to 1,000 100-1,000 B. CHEMICAL INDICATORS 1. Maior Solids Constituents Specific ion Probe, Titration Setup Turbometric and/or Analysis Spectrophotometer or Atomic Absorption Spectrophotometer or Atomic Absorption Spectrophotometer or Atomic Absorption 100 to 1,000 Spectrophotometer or Atomic Absorption 100-500 50-100 10 2. Carbonaceous Constituents Incubator, Titration Assembly, D.O. Meter Digestion Apparatus, Titration Assembly Total Organic Carbon Analyzer, or Digestion and Titration Assembly t 1+ N Reliability (Coefficient of variation) + 10% AA + 10% S-20 + 10% AA + 10% S-20 + 10% AA + 10% S-20 + 10% AA + 10% Applicable Range mg/1 Iter O' rSt o o o o a: o u 1-250 1-40 0.003-200 DA-0.2-7 0.001-100 0.004-20 DA-0.3-5 F-0.005-0.1 0.004-200 DA-0.02-0.5 F-0.005-0.1 i pH i + 20% + 10% +5 to 10% Varied 5-2,000 1-140 Parameter Manganese Cadmium Arsenic Cobalt Lead Silver Boron Molybdenum Selenium moxa d. ~m. icontinued) Volume of Sample (ml) Essential Instrumentation 100 to 1,000 100 to 1,000 100 to 1,000 100 to 1,000 100 to 4,000 100 to 1,000 100 to 1,000 100 to 1,000 100 to 1,000 Digestion Equipment, Spectrophot cane ter or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Reliability (Coefficient of variation) AA + 7% S-20 + 15% AA + 20% S-20 + 25% AA + 10% S-20 + 15% AA + 10% S-20 + 15% AA + 10% S-20 + 20% AA + 10% S-20 + 20% S-20 + 25% Applicable Range mg/1Iter 0.0002-10 DA-0.1-3 F-0.001-0.03 0.001-55 DA-0.0005-0.01 F-0.0005-0.01 0.05-100 DA-0.5--5 Flameless 0.03-10 DA-1-20 F-0.005-24 0.05-10 F-0.005-0.1 0.01-4 DA-0.1-4 F-0.001-0.025 0.1-10 000037495 ot ou .f t AA + 10% S-20 + 20% AA + 10% S-20 + 25% 0.1-20 DA-1-40 F-0.003-0.06 0.002-0.02 DA-0.002-0.02 F-0.005-0.1 Parameter Thallum Antimony Fecal Strep. Fecal Collform Salmonella Ascarla ova Bulk Density Moisture Content Porosity Cation Exchange Capacity Water Capacity Part^|e Fraction and parnHt e analysis Table B. -21.(continued) Volume of Sample (ml) Essential Instrumentation Reliability (Coefficient of variation) 100 to 1,000 Digestion Equipment, Spectrophotometer or Atomic Absorption 100 to 1,000 Digestion Equipment, Spectrophotometer or Atomic Absorption C. BIOLOGICAL INDICATORS 1. Pathogenic Indicators 100 Incubator Hillipore Filtering apparatus Microscope Selinite broth (enrichment broth for salmonella) II. SLUDGES. SOILS,* AND PLANT TISSUES A. Physical Indicators 5-50 Drying Oven and Sampler 5-50 Drying Oven, 00 + 1 _ -- + 10% + 10% 5-50 Drying Oven + 25% 10-20 5 to 10 10 to 20 - Weighable Pressure Cell and Analytical Balance Selving^ftulpment, Hydrometer, and Anal^r Balance + 25% - - Applicable Range mg/1 Iter 0.005-20 DA-1.20 F-0.005-0.1 0.02-40 DA-1-40 F-0.02-0.3 o o o o oo 0-1012 Organisms Organisms Organisms ai - - - 00037496 Parameter Total Suspended Solids Total Volatile Suspended Solids pH Inorganic Sulfur Chloride Sodium Calcium Ma^ __lum Iron Organic Carbon Nitrate-Nitrite Nitrogen Total Kjeldahl Nitrogen Table B. -21. (continued) Volume of Sample (ml) Essential Instrumentation Reliability (Coefficient of variation) 50-1,000 Steam Bath, Drying Oven, Filteration Setup, Analytical Balance 50-100 Steam Bath, Drying Oven, Filteration Setup, Analytical Balance 10-20 pH Meter B. CHEMICAL INDICATORS 1. Maior Solids Constituents 10 Total Sulfur-Organic Sulfur Oxidize and Analyze for Sulfate .5-10 Potentiometer or Titration Method (Mohr titration) 2 Analytical Balance 0.5-10 Spectrophotometer 0.5-10 Spectrophotometer 0.5-1.0 Spectrophotometer 2. Carbonaceous Constituents 0.5-1.0 Titration Equipment, Sp ec t rophot omet er 3. Nutrient Indicators 50-100 Spec trophotometer 10-100 Kjeldahl Setup, Spectrophotometer + 10% + 10% +1.5% + 2% + 2% + 2% 2% + 2% +4.1% + 20% + 10% + 3% CCR 0 0 0 0 3 7 4 -9 7 Applicable Range mg/llter 20-20,000 10-170 - i j 1-20,000 1-20,000 1-20,000 20-10,000 20-10,000 10,000-50,000 500-30,000 I ri- i ?[ i i ; t 0.2-4 25-1,500 Parameter Organic Phosphorous Total Phosphorous Potassium Zinc Copper Cadmium Nickel Cobalt Mercury Lead^^ Table B.-21. (continued) Volume of Sample (ml) Essential Instrumentation 1-3 Digestion Equipment, and Spectrophotometer 2-5 Digestion Equipment, and Spectrophotometer .5-1 Muffle Furnace, Spectrophotometer 4. Trace Metals (totals) 1-10 Digestion Equipment, Spectrophotometer or Atomic Absorption 1-10 1-10 Digestion Equipment, Spectrophotometer or Atomic Absorptio* n Digestion Equipment, Spectrophotometer or Atomic Absorption 1-10 Digestion Equipment, Spectrophotometer or Atomic Absorption 1-10 Digestion Equipment, Spectrophotometer or Atomic Absorption 1-10 Digestion Equipment, Spectrophotometer or Atomic Absorption 1-10 Digest iq^^quipment, Spectrop^^p- er or Atomic At>sort ..on Reliability (Coefficient of variation) + 15 X 5* + 4% + 3% 5* + 5% + 10% 52 52 + 10% Application mg/Tfter 25-600 300-3,000 500-25,000 oc au l J, <1-1,500 2-1,000 .1-500 .2-200 0.01-40 5-1,000 ( . 000037^98 Parameter Chromium Antimony Silver Arsenic Thalium Boron Molybdenum Selenium Manganese Table B.- 21, (continued) Volume of Sample (ml) Essential Instrumentation 1-10 1-10 1-10 0.1-1 1-10 0.2-20 1-2 1-5 1-10 Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or - Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Digestion Equipment, Spectrophotometer or Atomic Absorption Reliability (Coefficient of variation) 3* -- + 10* 8* -- 3* + 10* X0* 1 2* Application Range mg/liter 0.1-2,000 "" 0.3-100 1-10 -- 3-200 ,2-5 .2^5 .1-3 Parameter Polychlorinated Biphenyls Dieldrin Fecal Strep. Fecal Coliform Salmonella ABcaris ova Table B. - 21.(continued) Volume of Sample (ml) Essential Instrumentation Reliability (Coefficient of variation) 5. Organic Pesticides 1-2 Gas Liquid Chromatography and Electron Capture Detector 1-2 Gas Liquid Chromatography and Electron Capture Detector C. BIOLOGICAL IHDICATORS 1. Pathogenic Indicators 100 Incubator Mlllipore Filtering apparatus Hicroscope Selinite broth (enrichment broth for salmonella) + 17% + 10% + 10% Applicable Range mg/1 iter ' >0.01 > 0.01 cC Oo 0.1012 Organisms/cc ai 000037500 TABLE B-22 CHEMICAL ANALYSIS TEST METHODS Tables l, 2 and 3 spacify che appropriate analytical procedures, described in "Test Methods for Evaluating Solid Waste" (SW-846), which should be used in determining whether the waste in question contains a given toxic constituent. Table 1 identifies the analytical class and the approved measurement techniques for each organic chemical listed in Appendix VII. Table 2 identifies the corresponding methods for the inorganic species. Table 3 identifies the specific sample preparation and measurement instrument introduction techniques which may be suitable for both the organic and inorganic species as well as che metrites of concern. Prior to final selection of the analytical method the operator should consult the specific method descriptions in -SW-846 for additional guidance on which of the approved methods should be employed for a specific waste analysis situation. -121- CCR 000037501 TABLEE B-22-1 ANALYTICAL CHARACTER 1ST ICS OF ORGANIC CHEHICALS Compound Saaple Handling Clasa/P rac t ton Non-CC Het hods Heaaurenent Techniques GC/HS Conven t-doaal CC - Detector Acetonitrile Volatile 0.24 8.03 NSD Acrolein Volatile 8.24 8.03 NS D Ac rylaaide Volatile B.24 B .01 FID - i Acrylonitrile I lentene Benz(a)euthracene Volatile Volatile Extractable/BN 6 10 (IIPLC) 8.24 8.24 8.25 8.03 8.02 8.10 NSD PID FID Ben zo(a)pyrene Ext ractable/BN 8.10 (IIP LC ) 8.25 8.10 FID Benzotrlcliloride Ext rac table/BN 0.25 8.12 ECO Benzyl chlorlde Volatile or Ex t rac table/BN 8.24 8.25 8.01 8.12 USD ECD Benz(b)fluoanthene Extrac table/BN 8.10<IIPLC) 8.25 8.10 FID Bi 8( 2-chlo roettioxyne thaue) Vo la t lie 8.24 8.01 USD Bia(2-chloroethyl)ether Volatile 8.24 8.01 USD Biu(2-chloroisopropyi)ether Volatile 8.24 8.01 USD Carbon disulfide Volatile 8.24 8.01 USD Carbon tetrachloride Volatile 8.24 8.01 I1SD CCR 0 0 0 0 3 7 5 0 2 wtIo on75 oooo -Oo4' iji Conpound Chlordnne Chlorinated dlbenzodioxine Clilor 1 noted biphenyls Chlo roscetsldehyd e Chlorobenzene Chloroforn C It lor on ethane 2-Chlorophenol Chrysene Creosote Cresol(s) Cr e sy1 lc scid(s > Dichlarobenzene(a) Dlchloroet hane(a) Diehlorone thane Dicltloropliunoxy- acetic acid Dlchloropropu;iol TABLE B-22-1 (Continued) Sanple Handling C1 a a a / f r a c t i o n tton-GC Methods Ext rac table/BN Extractable/BH Extractable/BH Volatile Volatile Volatile Volatlie Extractable/BH Extractable/BH 8.l0(llPLC) Extractable/BH Extractable/A Extractable/A Extractable/BH Volatile Volatile Extractable/A Extractable/BH Measurement Techniques GC/MS Conventional ___ CC - Detector 8.25 8.08 USD 8.25 8.13 ECO 8.25 8.08 USD 8.24 8.01 USD 8.24 8.01 8.02 USD P ID 8.24 8.01 USD 8.24 8.01 USD 8.25 8.04 FID, ECD 8.25 8.10 FID 8.25* 8.10 ECO 8.25 8.04 FI0, ECD 8.25 8.04 FID, ECD 8.25 8.01 8.02 6 . 12 USD, PID, ECD 8.24 8.24 8.01 8.01 USD USD 8.25 8.40 USD 0.25 8.12 ECO * 0suoooo * -n i- \m\ Compound 2.4-D imethy1phenol Dinit robenzene 4,6-Dtnitro-b-crcaol 2.4-Dlnitrotoluono EndrIn Ethyl ether Formaldehyde Formic acid lleptachlor It ex echloro benzene II cxnch loro butadiene llcxachl oruethane II cxach loro eye I open la diene Lindane Maleic anhydride Methanol Methomyl Methyl ethyl ketone Methyl isobutyl ketone TABLE B -J^Continued) Sample Handling Claar/ffaction Hon-CC He thoda Extractable/A Extractable/BN Extractable/A Extractable/BN Ext rac table/P Volatile Volet lie Ex tree tab*le/BH Extractable/P Extrac table/BN Extractable/BN Extractable/BN Extractable/BN Ex t rac table/P Extractabl e/B1I Volat lie Extractable/BN 8.32 (IIP l.C) Volatile Volatile Measurement Techniquea CC/MS Conventional CC - Detector 6.25 8.04 FID. ECD 8.25 8.09 FID, ECD 8.25 8.04 FID. ECD 8.25 8.09 FID, ECU 8.25 8 .08 USD 8.24 6.01 8.02 FID FID 6*24 8.01 FID 8.25 8.06 FID 8.25 8.06 USD 8.25 6.12 ECD 8.25 8.12 BCD 8.25 8.12 ECD 8.25 8.12 ECD 8.25 8.06 USD 8.25 8.06 ECD, FID 8.24 8.01 FID 8.25 8.25 8.01 8.02 8.01 8.02 FID FID FID FID CCR 0 0 0 0 3 7 5 0 5 ' Compound Naphthalene Napthoquinone HI trobenteite 4-Nltrophenol Paraldehyde (ttlmnr of beetaldehyda) Pen tachlo rophenol i Phenol eln Pho ra te Phoeptiorodlth lo tc acid esters Phtlialic anhydride 2-Plcollne Pyrldlne T traclilorobenzene(a) Tetrachloroethane(s) Tetrachlornethene TABLE B-22-1 (Continued) Sample Handling Clsss/Fmctlon Non-CC He t hod a Measurement Techniques GC/HS Conventional CC - Dct cc Lor Ext ractabl e/BN B.lO(lfPLC) Ext rac table/BN 6.23 8.25 Extractable/BN Extractable/A Volatile 6.25 8.24 8.24 8.10 8.06 8.09 8.09 8.04 8.01 FID ECO, Fill F10 ECO, FI 0 ECO, F1U F10 Ext ractable/A Extractable/A Ex tractable/BN Extract a ble/BN tktractable/UN ExtractabJe/BH Extractable/BN Ex tractablc/BH Volatile Volatile 8.25 8.25 8.25 8.25 8.25 8.25 8.24 8.24 8.04 8.04 8.22 8.06 8.09 8.22 6.06 8-09 8.06 8.09 8.06 8.09 8.12 8.01 8.01 ECO ECO, III) KPO ECO, F 1II ECO, FIO FFO. ECO, FIO ECO, Kill ECO, FIO ECD, Fill ECO, Fill ECO, Fill ECO USD 11 SO Compound Tetrachlorophenol Toluene To1uenediamine Toluene diisocyanate(a) T xaphene Trichloroethane Trichloroethene(s) Trlchlorofluoronethane Trlchlorophenol(a) 2,4,S-TP(Silvex) Trichloropropane Vinyl chlorid e Vtnylidene chloride Xylene TABLE B-2. ^ntinued) Sample Hand ling Claa s/Frac tion Non-CC Methods Extractable/A Volatile Extractable/BN a.OS(IIPLC) Extractable/Nonaqueous Extracts hie/P Volatile Volatile Volatile Extractable/A Ex t racta ble/A Volatile Volatile Vola t lie Volatile He a s ur eme nt Techniques GC/MS Conventional CC - Detecto 6.24 8.04 ECD 8.24 8.02 PID 8.25 8.25 8.06 FID 8.25 8.08 USD 8.24 8.01 USD 8.24 8.01 USD 8.24 8.01 USD 8.25 8.04 USD 8.25 8.40 USD 8.24 0.01 USD 8.24 8.01 USD 8.24 8.01 USD 8.24 8.02 PID 1 - 126- or> p aoo 001 \JOo0- ECD Electron capture detector) FID - Flane ionieet ton detector; FPD " Plane photometric detector; USD - Halide specific detector; tlPLC NSD PID - High (treasure liquid cliroeatogrsphy; * Nitrogen-specific detector; - PhotolonizatIon detector. Analyze for phenantlirene and carbazole; if these are present in a ratio betueon 1.4:1- and S:lt creosote should be conslAerod present. 11 | . TABLE B-22-2 Analytical characteristics of inorcanic species Species Antimony Arsenic Heriua Cadmium Chromium Cyan Id ee Lead Mercury Nickel Selenium Silver Sample Hand ling Class Digest Ion Hydride Digest ion Digestion Digestion Hyd rolysls Digestion Cold Vapor Digestion Hydride Digestion Digest ion Measurement Technique At on1c Absorbtion-Flame/Furnace At oa1c AbsorbtIon-Flame Atomic Absorbt ion-Ftirnac e/Flane Atomic Absorbt ion-Kuril ace / Flame A t oaic Absorbtion-Furnace/Flame Absorption Spectroscopy Atonic Abso r btio n-Furnac e/Flame Atomic Abso rbtion Atonic Absorbtion-Furnace/FIone Alomlc Absorbtlo ii-Furnace/Flame Atomic Absorbtion-Furnace/Flame CD SO Method t 8.50 8.51 8.52 8.5 J 8.5A 8.55 8.56 8.57 8.58 8.60 CCR 000037507 t TABLE B-23-3 S4MPLE PR ?A3LnJ10 S / SAM? LI IJORODUCTHSN TECHZrtQCZS Sample Handling Class Volatile Sesivoiatila and ilorwolatile Inorganic Physic*.! Characteristics of 8nt^ 1 Fluid 1 Paste 1! 11 1 Purge & Trap II I Purge & Trap 11 ! Direct Injection 1 Headspace 1 1 Direct Injection 1 Shake out 11 11 I Shake out 11 ! j1 11 11 1 Direct injection l li 1 Digestion t Digestion 1 Hydride i 1 Hydride i I Solid 1 I 1 Headspace | J 1 1 1 Shaae out i1 1 Soxhlet l I 1 Sonic*eioo i i ii ! Digestion 11 I Hydride i Procedure Method Husber(s) Digestion See appropriate procedure for element of interest. Direct injection 8.80 Hesdspace 8.82 Hydride See appropriate procedure for eleaent of interest. Purge & Trap 8.83 Shake out 8.84 Sonicatlon 3.85 Soxhlet 8.86 t For purposes of this Table, fluid refers co readily pourable liquids, which aay or aay not contain suspended particles. Paste-like aaterials, while fluid in the sense of flowebility, can be thought of as being thixotropic or plastic in nature, e.g. paints* Solid oacartels are those wastes which can be handled without a container (i.e., ean be piled up without appreciable sagging) CCR 000037508 2.2.1. Procedures for Organics: Currently, the Effluent Guidelines Division of EPA has listed required analyses for the priority organic pollutants (65 Pollutants which result in 114 specific organic pollutants for 21 industrial categories. The document, entitled "Sampling and Analysis Procedures for Screening of Industrial Effluents for Priority Pollutants" (commonly known as The Priority Pollutant Protocol) was released in April, 1977. It provides analytical procedures far these 114 organic compounds by gas chromatography - mass spectrometry. This analytical scheme represents a screening approach by defining applies to two classes of compounds, purgeable volatiles and solvent extractable semi-volatiles (amenable to analysis by gas chromatography). These classifications are subdivided into halogenated and non-halogenated purgeables, pesticides, base-neutrals, and acid extracts as listed in Table B-23. The 114 priority organics are also divided into the 12 categories shown in Table B-24. The applicable analytical techniques are described by EPA in the December 3, 1979, Federal Register and are described in Tables B-25 and B-26, and B-27. These methods will supplement those already approved (1973) for NPDES Programs, (See Table B-28). Of the initial series of eight methods, six are for Pesticides and Herbicides. The other two methods are for PCB's and organochlorine solvents. A colorimetric method (Chloramine-T) for benzidine and its salts and methods for pentachlorophenoi will be added and referenced at a later time. Additional methods that have been proposed or are being considered for proposal a, 304(h) methods include, the GC-MS methods for Purgeables (Method 624) and for SemiVolatiles (Method 625) for priority pollutants and a direct aqueous injection method for acrolein and acrylonitrile (See Table B-29). As these materials become approved by EPA, they will be considered by the Department of Natural Resources. Other procedures such as thin layer chromatography, solvent extraction, etc. are currently under review since most of this work is in its initial research stag . Permittees should addres this matter with their best discretion and with the approval of the Department of Natural Resources. -129- CCR 00003<W TABLE B-23 .Major Classes or Organic Compounds Considered. Purgeable Volatile Halogenated Non-Halogenated Solvent Extractable Semi-Volatile Neutrals Bases Acids -iso 000037510 cost TABLE B-.24Organic Compound Classes for which Methods are Presented. Category 1 2 3 4 5 6 7 8 9 10 12 Compound8 Phthalate Esters (6) Haloethere (7) Chlorinated Hydrocarbons (9) Nitrobenzenes (3), Isophorone Nitrosamines (3) (2,3,7,8-TCDD) Benzidines (3) Phenols (U) Polynuclear Aromatics (16) Pesticides and PCB*s (21) Halocarbons (26) Aromatics (3) Acrolein and Acrylonitrile g Numbers in parentheses indicate number of compounds in the category -*131- CCR 0000375U Analytical minimum detection levels far many pesticides already existed in the Federal Register, so it was suggested that those standard methods and detection levels be used to analyze for pesticides and polychlorinated biphenyls (PCB's). However, it is acknowledged that the challenge of chemical analysis of a sample for literally thousands of components is staggering -- especially when these components may be at part per billion levels in a complex sample matrix. The following considerations have been made to make this responsibility a mere manageable one: 1. In addressing the 13 metals on the Toxic Pollutants List the term, ".....and their compounds,** is interpreted to mean "total metals," which includes both inorganic and organometallic compounds. 2. A standard method for analysis of total cyanides was selected and asbestos methodology is deferred until later. 3. The standard EPA pesticide methodologies are recommended for the analysis of pesticides and their metabolites. This typically involves extraction, Florisil column cleanup of the concentrated extract and gas chromatography. 4. Not counting PCB's, toxaphene, and chlordane, there remain 18 groups of organic pollutants each containing 2 to 50 compounds. Table B-25. summarizes this list and also indicates the relative frequency with which these compounds are being found in industrial wastewaters. The particular screening characterization is thus seen to use the following set of categories: --------------------- metals asbestos total cyanides pesticides compounds extracted under acidic conditions compounds extracted under alkaline conditions neutral extractable compounds total phenols purgeable compounds -132 C.C.i*' Table B-4.B EPA list of 12S Priority Pollutants and the relative frequency of these materials in industrial wastewaters *'**'*' uirp9iM*e m imyilsr* Industrial cMipRln1 13 2.7 28.1 293 16.7 7.7 S.0 6.5 10.2 1.4 7.7 1.9 4.2 0.4 1.5 40.2 6.0 0.5 0.2 1.1 IX 0.4 10.6 OX 1i 1.6 1.1 1.5 0.04 41X 6.4 5.6 73 16.9 31 are pwgtabl* organics 5 Acrolein 2.1 10 Acrylonitrile 1.0 25 Benzene 343 26 Toluene IX 24 Ethylbenzene 0.1 14 Carbon tetrachloride 1.8 10 Chlorobenzene 43 16 1.2-Dichloroethane 6.8 25 1.1,1-Triehloroethene 03 8 1.1-Dichloroathane 2.5 17 1.1-Dichloroethylene 10.2 12 1.1.1-Trichloroethane 10.5 13 1.1.2.2*7eirachtoroethane 0.2 2 Chloroethane 7.7 1 2-Chioroethyl vinyl ether 0.1 26 Chloroform 13-Dichloropropene 5 1,3-Dichloropropene 25 Methylene chloride 6 Methyl chloride 1 Methyl bromide 12 Bromoform . 17 Dichlorobromomethane 11 Trichiorofluoromethane 4 Dichlorodilluoromethane 15 Chlorodibromomethane 19 Tetrachloroethylene 21 Trichloroethylene 2 Vinyl chloride 16 1,2-trans-Dichloroethylene 2 bis(Chloromethyi) ether 46 ere baee/neutral extractable organic compounds r 1,2-Dichiorobenzene 9 11,3-Dichlorobenzene 11,4-Dlchlorobenzene 5 Hexachioroethane 1 Hexachiorobutediene 7 Hexachlorobenzane 6 1.2,4-Trichlorobenzene 3 bis{2<Chloroethoxy) methane 18 Naphthalene 9 2-Chtaronephthelene 13 isophorone * 9 Nitrobenzene 3 2,4-DinItrotoluene 9 2,6-Dinttrotoluene 5.7 73 5.1 7.8 10 23 1.6 13 33 -03 ' 3 0.6 0.1 11 Ruorene 12 Fluoranthene 8 Chrysene 14 Pyrene j Phenanthrene (Anthracene . ____ 6 Benzo|a)enthracene 6 Benzo(b)tluoranthene 6. Benzo(k)fluorenihene 8 Benzo(a)pyrene -4 tnder>o(12,3-c,d)pyrne 4 Dibenzo(a,h)anthracene 7 Benzo(g,hIi)perylene 2 4-Chlorophenyl phenyl 1 4-Bromophenyl phenyl ether 0 29 bis(2-Ethy!hexyO phthalate .03 12 Dt-moctyl phthalate 1.1 15 Dimethyl phthalate 03 20 Diethyl phthalate 0.1 23 Dt-n-butyl phthalate 13 ether 0 3.3'-Oichlorobcnzidine 4 Benzidine 4 bis(2-Chloroethyl) ether 7 1.2-Diphenylhytjrezine 1 Hexachlorocyclopentadiene 5 N-NHrosodiphenylamine -133- CCR 000037513 Because of their availability, it was decided to use standard pesticide methodologies for the analysis of pesticides and their metabolites. This usually involves extraction. Florisil column cleanup of the concentrated extract and gas chromatographic. Table B-4.B, (Continued) i* * 4.5 12 Acenaphthylene 4.2 14 Acenaphthene A.5 13 Butyl benzyl phthaiate 0.1 1 N-Nitrosodimothylamina 0.1 2 N-Nitrosodi-rvpropylamine 1.4 6 bit(2-Chioroiaopropyl> athor 26.1 2.3 2.2 1.6 1.1 6.9 25 11 9 6 -6 18 11 are add attractable organic compound* Phenol 1.9 2-Nitrophenol 2.3 4-Nltrophenol 3.3 2.4-Dtnitrophonoi 4.6 4,6-Wnitroocresoi 5.2 Pentechlorophenol 8 10 12 12 15 p-Chloro-m-creaoi 2-Chtorophanol 2.4-Olchloroph*nol 2.4,6-Trichlorophaool 2,4<Oim0thylphenol 0.3 0.4 0.2 0.6 0.8 0.2 0.5 0.5 0.1 0.04 0.1 0.2 0.2 03 26 aro peettddee/PCS'S 3 a<ndosulfan 0.3 4 .i-nOosulfan 0.1 2 Endosulfan sulfate 0.2 4 ot-8HC 0.2 6 d-6HC 0.6 4 -shc 0.5 3 7-8HC 0.9 5 Aldrin 0.8 3 OlOldrin 0.6 ! 4.4'-00E 0.6 2 4,4'-ODD 0.5 2 4.4'-OOT -- 3 Endrm 2 Endrin aldehyde 3 Haptachlor 1 HeptacMor opoxide 4 Chiordana 2 Toxaphene 2 Aroclor 1016 1 Aroclor 1221 2 Aroclor 1232 3 Aroclor 1242 2 Aroclor 1246 3 Aroclor 1254 1 Aroclor 1260 -- 2.3.7.8-Tetrachlorodibenzo- ixiloxin (TCOO) 18.1 19.9 14.1 30.7 53.7 55.5 43.8 20 Antimony 19 Arsenic 18 Bervllium 25 Cadmium 28 Chromium 28 Copper 27 Load 13 aro ittalals 16.5 34.7 18.9 22.9 19.2 54.6 20 Marcury 27 Nickel 21 Selenium 25 Silver 19 Thallium 28 Zinc 33.4 Miscallanaous t9 Total cyanidos Mot ava.iacie No: avat'acle Asbestos I'Vbrour) To^l ot-wn.-Ji ' zrfinft ol 'it'iss eor't'er.ts m* numSer ijf ttm"S tms ttjrroOHnd ! ;md in all m wiitc*- it WAX .inniv:*r i i -uguSf > 7 V|IiBWfi ot ; Irom iS22 to ii-jo ijr ``i -..-*.*9* Jv:".,-, zs ! 7. ' - '.lii ol in--. ...lAccf-es-WO Sua-tuMTOr.es a,vs'-..*; fer Jf'-imcs up'! 23 frr meMM <-uij I 4tcur iJrj? --* 'i.l1 is -134- 7011.-" 4*9 CCR 000037514 Teniff*v. manitorinc) 'phase nicthoas , fHwaC*** TABLE B- 25. JL: a rtavmt :i` -- i 4* 3 Hydro- sr^-nc* 4 Benoit* 5 swni t> w'PPrundum 7 Lanelie E H/droacianca BatteUe to - SWRI 11 Carbo rundum *i*ari ? rilJC*- fefnm Exffaei wnn CHpQ* u-r:- e.. ijrer Tern propran>- m*oGC : sp1000 tiectrci>i:: conOucovn. 9 chleri. nat*S h/arc- carbons Extrect with CHjCtj . FtariaH GCsMWO SHterer.t tempera tures 1.5% OV1/1.5* OV-225 ECO 3 nitro benzene* and iso- Extract with CHjCI*; exchange with toluana Ftorlan il GC 1.5* OV17/1.85* QF-1 ECDanaFID -3 nUrcs* Extract with CHjClj; exchange with haxana FioriaU isothermal GC at two diflerent tamper* atures Carbowax 20M -Alitali FD tcdd Extract with " '.CH*CIS Wash with add and base; carbon and/ _ or silica column Isotherms! GC MS 2 benzi dines and dipheivylhydre* line* Extract with ethyl acetate at pH 8-9 Wash extract with HPLC, add. Isocralic Make add ` elution wash alkaline <t. ' & extract with ethyl -. acetate Udvosorb RP-2 phase Electrochemical 11 phenols Extract with CHjCI,at pH 2 1. None lor 2 1. Temper ature progrtnt- medGC 1. SP-1240DA 1. FID ^ - ir* y.': V* - -^h.^^-'f^S^'i^erphenols ; 2.. SlUca pel of ;\^2.~isothermal, pentatluoro- V'-'.'.GCforO ~benzyl derivatives ' of 9 phenols - 16 potynuCiear aromatics 25paati* ddas - Extract with CHjCl,; exchange with cyclohexane Extract with CHsCI* Silica get; acetonhriie solvant exchange Ftoristt; Collect 3 ' fractions; HPLC. : Gradient elution isothermal GC PerkIn-Elmer HC-ODS phase 1.5% SP' 2250/1.95% Fluorescence at two dmwent excitation & emission wavelengths ECO Hexane. * .solvent .* .... -exchange . SP-2401 26 purgeable* e 1. Purge and ' trap using : .Tanax/sWca Fttftor nonhalo- -genatad compounds. - .-^Eleeabtytie - conductivity * V;, 12 Carbo- - ' .Acrptein, nxtdixn ewyio- nitrite 4 and eous :^' None'. ':.'^' ^'-^TemoeiabtfB - injection - program- medGC !. - - ./.-.' Compounds %r ECD with ox-' tL27* Carbowax 1500 FC CCR 000037515 *P HA erpwtie ptkxtiy pollutants ere divided into 12 groups; 20-lab* will verity the methods betere the endottnii yew. a.so united* that method development work has ceased wen K. * recemmenos ei: ctioroetnyl vinyl elher (lrom Group 2), tie trw dicrsurdbansanes (trom &oup 3)and dichierflditluoromatnano (iremGrwX112) be to'this group. Tho-woua raise tn number of pvrgeabie Priorily Pollutants to 31. TABLE B-26. | Summary of Conditions for Purge and Trap Analyses.* (GC/MS) Method No. 601 (F.R. pp. 5) 602 (F.R. pp. 5) 603 (F.R. pp. 15) Parameter Halocarbons Temp. Ambient Aromatics Ambient Acrolein/ 85 C Acrylonitrile a Detector abbreviations: OHD - Organohalide detector P1D - Pbotoionizatlon detector FID - Flame ionization detector Sorbent Trap Gas Chromatography Column Packing Temperature (C) Detector' OV-1, Tenax Carbopak- Silica Gel, Charcoal 4l* SP 1000 45 to 220 OHD OV-1, Tenax 1.7J Bentone-34 5% SP 2100 + 50 to 90 PID Porpak-N Chromosor b-101 100 to 140 FID t *Source "EPA Proposed Guidelines Establishing Test Procedures for the Analysis of Pollutants" 44 Federal Register 69464 (Dec. 3, 1979), and Environment Reporter -136 iHttLfc __________________________ Summary of Methods for Semi-Volatile Organic Priority Pollutants.* -----,1 --------------------------------------- ------- ------------------------------ ---- ----- ti i____________ EPA Method No. 604 (F.R. pp. 20) 605 (F.R. pp. 25) l Parameter Acids Phenols Bases ! Benzidiner s Method GC Cleanup Silica gel LC h2so4 Column 1% SP 1240 DA, 5% OV-17 Lichrosorb RP-2 Gas jChromatography Temperature (2) i 80 to 150, ! 200 111 Ambient " pfs~t. Detector3 FID, EC NtoOr*> O o o (DERIV.) uQC u ED 606 (F.R. pp. 27) 607 (F.R. pp. 32) 608 (F.R. pp. 37) 609 (F.R. pp. 46) 610 (F.R. pp. 50) 611 (F.R. pp. 53) Neutrals Phthiates Nitrosamines Pesticides & PCBs Nitroaromatics & Isophorone Polynuclear Aromatics Haloethers GC GC GC GC LC GC GC Florisil, Alumina 101 HC1, Florisil Florisil Silica gel Florisil 1.52 SP 2250 + 1.95% SP 2401 10% Carbowax 20 M + 2% KOH 1.5% SP 2250 + 1.95% SP 2401 1.5% OV-17 1.95% QF-1 HC-ODS Sil-X 3% 0V-17 SP 1000 180 and 220 EC, FID 110 and 220 NPD 160 and 200 EC 85 and 145 EC Ambient 100 to 280 60 to 230 UV, Fluoresce FID OHD 612 (F.R. pp. 58) 613 (F.R. pp. 62) Chlorinated 2,3,7,8-TCDD GC Florisil 1.5% OV-1 + 2.4% OV-225 GC N OH, 1.5% SP 2250 + H^SO 1.95% SP 2401 Silica gel. Alumina, Charcoal/ Silica gel 75 or 165 220 210 EC EC MS TABLES B-27. Detector abbreviations; FID - Flame ionization detector EC - Electron capture detector ED - Electrochemical detector NPD - Nitrogen-phosphorus detector UV - Ultraviolet detector F - Fluorescence detector OHD - Organaohalide detector MS - Mass spectrometer detector TEA - Thermal electron analyzer (Continued) I oo uoOf dco> 00003751 TABLE B-28. EPA Method No. 614 615 616 617 618 619 620 621 Existing 304 (h) Methods Parameters Measured Organopbosphorus Pesticides Chlorinated Herbicides Benzidine Organochlorine Pesticides & PCBs Chlorinated Solvents Triazine Herbicides 0-Aryl Carbamates N-Aryl Carbamates & Ureas -139- 00003->*19 cc* TABLE B-29. Additional Methods Being Proposed As 304(h) Methods. EPA Method No. 622 623 624 625 626 627 628 629 630 631 632 633 Parameters Measured Organophosphorus Pesticides 4,4'-Methylene Bis (2-chloroanillne) Purgeables by GC-MS Semi-Volatiles by GC-MS Acrolein 4 Acrylonitrile by DAIGCa Dinitroaniline Pesticides Carbofuran Cyanazine Dithiooarbamates Carbendazim Carbamate and Urea Pesticides Organonitrogen Pesticides aDAIGC - Direct aqueous injection gas chromatography -140- CO* 0000^ APPENDIX A GNIFICAKT WASTEWATER PARAMETERS FOR SELECTED INDUSTRIAL CLASSIFICATIONS A. ALUMINUM INDUSTRY* Suspended Solids Free Chlorine Fluoride Phosphorus Oil and Grease pH Total Dissolved Solids Phenol Aluminum B. AUTOMOBILE INDUSTRY* Suspended Solids COD Oil and Grease Chlorides *>D5 . Chromium Nitrate Ammonia Phosphorus Sulfate Cyanide Tin Copper Lead Nickel Cadmium Iron Total Dissolved Solids Zinc r Phenols V C. BEET SUGAR PROCESSING INDUSTRY BOD, pH Suspended Solids Setteable Solids Total Coliforms Oil and Grease Toxic Materials Alkalinity Nitrogen, Total Temperature Total Dissolved Solids Color Turbidity Foam D. BEVERAGE INDUSTRY BOD, pH Suspended Solids Setteable Solids Total Coliforms Oil and Grase Toxic Materials Nitrogen Phosphorus Temperature Total Dissolved Solids Color Turbidity Foam E. CANNED AND PRESERVED FRUITS AND VEGETABLES INDUSTRY* BOD, COD pH Suspended Solids -141- Color Fecal Coliforms Phosphorus, Total Temperature TOC Total Dissolved Solids CCR 000037521 F, CONFINED LIVESTOCK FEEDING INDUSTRY* BOD, COD3 Total Solids PH Fecal Coliforms Nitrogen Phosphate TOC G. DAIRY INDUSTRY* BOD, COIT pH Suspended Solids Chlorides Color Nitrogen Phosphorus Temperature Total Organic Carbon Toxicity Turbidity H. FERTILIZER INDUSTRY* Nitrogen Fertilizer Industry Ammonia Chloride Chromium, Total Dissolved Solids Nitrate Sulfate Suspended Solids Urea & Other Organic Nitrogen Compounds Zinc Calcium COD Gas Purification Chemicals Iron, Total Oil and Grease PH Phosphate Sodium Temperature Phosphate Fertilizer Industry Calcium Dissolved Solids Fluoride PH Phosphorus Suspended Solids Temperature Acidity Aluminum Arsenic Iron Mercury Nitrogen Sulfate Uranium -142- FLATGLASS, CEMENT, LIME, GYPSUM AND ASBESTOS INDUSTRIES Flatglass COD pH Phosphorus Sulfate Suspended Solids Temperature Cement, Concrete, Lime and Gypsum BOD. Chromates Zinc Copper Chromium Iron Tin Silver Nitrates Organic and Inorganic Waterbreaking Chemicals Synthetic Resins Total Dissolved Solids COD PH Suspended Solids Temperature Asbestos Alkalinity Chromates Phosphates Zinc Sulfite Total Dissolved Solids Chromates COD pH Suspended Solids GRAIN MILLING INDUSTRY* Phosphates Zinc Sulfite Total Dissolved Solids BODSuspended Solids Temperature COD PH TOC Total Dissolved Solids t143- 00003l^23 CCR  K. INORGANIC CHEMICALS, ALKALIES AND CHLORINE INDUSTRY* Acidity/Alkalinity BOD,. Total Solids CODr Total Suspended Solids TOD Total Dissolved Solids Chlorinated Benzenoids and Chlorides Polynuclear Aromatics Sulfates Phenol Fluoride Silicates Total Phosphorus Cyanide Mercury Chromium Lead Titanium Iron Aluminum Boron Arsenic Temperature L. LEATHER TANNING AND FINISHING INDUSTRY* bod5 COD0 Chromium, Total Grease pH Suspended Solids Total Solids Alkalinity Color Hardness Nitrogen Sodium Chloride Temperature Toxicity M. MEAT PRODUCTS INDUSTRY B0DS pH Suspended Solids Setteable Solids Oil and Grease Total Coliforms Toxic Matrials Ammonia Turbidity Total Dissolved Solids Phosphate Color N. METAL FINISHING INDUSTRY COD Oil and Grease Heavy Metals Suspended Solids Cyanide . y -144- CCR 000037524 . TM . : 1 -r - , * ' *-. ` * ' ` *' O. ORGANIC CHEMICALS INDUSTRY* BOD, COD3 pH Total Suspended Solids Total Dissolved Solids Free-Floating Oil TOC Organic Chloride Total Phosphorus Heavy Metals Phenol Cyanides Total Nitrogen Other Pollutants P. PETROLEUM REFINING INDUSTRY* Ammonia BOD, Chromium COD Oil, Total pH Phenol Sulfide Suspended Solids Temperature Total Dissolved Solids Chloride Color Copper Cyanide Iron Lead Mercaptans Nitrogen Odor Total Phosphorus Sulfate TOC Toxicity Turbidity Volatile Suspended Solids Zinc Q. PLASTIC MATERIALS AND SYNTHETICS INDUSTRY BOD COD pH Total Suspended Solids Oil and Grease Phenols Total Dissolved Solids Sulfates Phosphorus Nitrate Organic Nitrogen Ammonia Cyanides Toxic additives and materials Chlorinated benzenoids and polynuclear aromatics Zinc Mercaptans -145- tG* R. PULP AND PAPER INDUSTRY BOD. COD5 TOC PH Total Suspended Solids Coliforms, total and fecal Color Heavy metals Toxic materials Turbidity Ammonia Oil and Grease Phenols Sulfite Nutrients (nitrogen and phosphorus) Total Dissolved Solids S. STEAM GENERATION AND STEAM ELECTRIC POWER GENERATION* BOD Chlorine Chromate Oil pH Phosphate Suspended Solids Temperature Boron Copper Iron Non-Degradable Organics Total Dissolved Solids Zinc T. STEEL INDUSTRY Oil and Grease pH Chloride Sulfate Ammonia Cyanide Phenol Suspended Solids Iron Tin Temperature Chromium Zinc U. TEXTILE MILL PRODUCTS INDUSTRY BOD. Heavy Metals COIr PH Suspended Solids Chromium Phenolics Sulfide Alkalinity Color Oil and Grease Total Dissolved Solids Sulfides Temperature Toxic Materials *Guidelines far these industries not currently available at time of publication. -146- CCR 0000375Z6 '''hi APPENDIX B-l REFERENCES 1. EPA-Proposed Rules, Federal Register, Vol. 44 No. 116, Thursday June 14, 1979 pg. 34393-54416 2. Methods for Chemical Analysis of Water and Wastes, U.S.EPA. EPA-600/4-79-020 (1979) 3. Environmental Technology Consultants, Inc. "Local Pretreatment Program Requirements and Guidance" (manuscript) Sept, 1979 4. Municipal Sludge Landfills, U.S. EPA, Technology Transfer. fePA-6z/l-78-Ol0,SW'-"705 '(1978) 5. APHA, Standard Methods for the Examination of Water and Wastewater, 14th Edition, American Public Health Assoc. , Washington D.C., 1976 6. EPA-Proposed Rules, Federal Register, Vol 43, NO. 243Monday, Dec. 18, 1973 7. ASTM, Annual Book of Standards, D-279-300, 1979 8. Reimers, R. S. and WW. Eckenfelder. "Sampling Techniques" (manuscript) 9. Handbook for Analytical Quality Control in Water and Wastewater Laboratories, U.S. EPA, Washington. D.C. EPA^hOO/T-7T-019 (1979) 10. California Dept, of Health, "California Characterization and Assessment System for Hazardous and Extremely Hazardous Wastes." (manuscript) March, 1978 11. Identification of Organic Compounds in Industrial Effluent Discharges, U.S.EPA. Athens. GA? EPA-600/4-79-0l6~. (1979) 12. American Water Works Association, Hazardous Materials Spills Emergency Handbook. Denver,"tiff: CT9TS7----------------- "J47- CCR 000037527 13. deVera, E.R. , B.P.Simmons, H.K. Hatayama, R.D. Stephens, and D.L. Storm. "Sampling Procedures for Hazardous Wastestreams." (draft manuscript) U.S. EPA, Cincinnati,' Ohio, and California Dept, of Health Sciences, Berkley, California. 14. Sampling and Analysis Procedures for Screening of Industrial Effluents for Priority Pollutants"! U.S. EPA, Environmental Monitoring and Support Laboratoiy, Cincinnati, Ohio, revised April, 1977 <m -148- CCR 000037528 /fyvl ANALYTICAL OPERATING PROCEDURES MANUAL PAST C DEPARTMENT OF NATURAL RESOURCES OFFICE OF ENVIRONMENTAL AFFAIRS HAZARDOUS HASTE MANAGEMENT DIVISION October 19, 1980 This public document was published at a cost of S.39 per copy or SL20 per mailed copy by the Louisiana Department of Natural Resources, Office of Environmental Affairs, P. 0. Bax 44066, Baton Rouge, LA 70804, as part of the program to develop a Hazardous Waste Management Program as mandated by Act 334 of the 1978 Legislature. This material was printed in accordance with the standards for printing by state agencies established pursuant to R.S. 34:31. 0003 CC* LOUISIANA DEPARTMENT OF NATURAL RESOURCES Office of Environmental Affairs Hazardous Waste Management Division Amendments: Analytical Operating Procedures Manual October 17, 1980 Part C: INTERIM STATUS STANDARDS GUIDELINES INTRODUCTION These amendments to the Analytical Operating Procedures Manual (AOPM) clarify and set forth in the form of guidelines certain expectations of the Louisiana Hazardous Waste Management Plan (HWMP) concerning the mandatory interim status standards for Hazardous Waste Treatment, Storage and Disposal Facilities uncfer 5.2.2 A of the HWMP, as amended September 5, 1980. Publication of these guidelines serves three purposes: (1) they will be utilized by the staff of the Hazardous Waste Management Division as statements of minimlmum technical requirements for satisfaction of the interim status conditions set forth under section 5.2.2 A of the HWMP; (2) where compliance orders or schedules are issued to existing facilities, adherence to procedures set forth under this section of the AOPM will be made a condition thereof; (3) they are intended to serve as technical assistance and guidance to the regulated community as statements of minimum technical requirements applicable to Treatment, Storage and Disposal Facilities under Interim status. In addition to the utilization of these guidelines for statements of minimum conditions for satisfaction of interim status requirements of section 5.2.2 A, these guidelines will also be utilized by staff of the Hazardous Waste Division for purposes of statements of minimum requirements of Interim or Standard Permits Issued in accordance with section 5.2.3 A, except as precluded by such specific and more stringent minimum requirements otherwise set forth by the HWMP. Where compliance orders, compliance schedules or interim or standard permits are established or issued, adherence to procedures set forth under this section of the AOPM will be made a condition thereof. Publication or utilization of these guidelines does not limit or restrict the Secretary, the Assistant Secretary, or the Environmental Control Commission from using more stringent requirements as may be established through issuance of permit conditions, compliance orders or other lawful means as may be necessary to prevent violations of the HWMP, to establish compliance with the requirements and standards of the HWMP, and to prevent endangerment of the public health or the environment* Full compliance with the Manifest System as set forth in the HWMP is a mandatory requirement for all generators, transporters, and owners and operators of hazardous waste treatment, storage, and disposal facilities. GENERAL C.l. Special Reporting: The owner or operator of a facility that has arranged 149 CCR 000037530 to receive hazardous waste from a foreign source must notify the Hazardous Waste Program Administrator in writing at least four weeks in advance of the date the waste is expected to arrive at the facility. C.2. General Waste Analysis: Before an owner or operator treats, stores, or disposes of any hazardous waste, a detailed chemical and physical analysis of a representative sample of the waste must be obtained. To support the requirements of the HWMP as set forth In sections 8.4.2A1), 8.4.2A2), 8.4.2B, 8.4.9A3), 8.4.9A9), and 8.5.1, each owner or operator shall develop and Implement a waste analysis plan. Such plan shall be up-dated as required (e.g., to Incorporate modifications and additions made necessary by changes of waste streams or operating procedures), and shall be available at the site for inspection. The waste analysis plan must address the following areas of concern: 1. The parameters for which each hazardous waste will be analyzed and the rationale for the selection of these parameters. As applicable, the rationale for the selection of parameters must address the requirements of: a. Receipt and acceptance of hazardous waste and verification of manifest data; b. Technical support to decisions on management of the wastes, including any movement or routing of the wastes, and safe and effective storage, treatment and disposal. 2. The test method or methods which will be used to test for each of these parameters. 3. The sampling method or methods which will be used to obtain representative samples of the hazardous waste. Approvable sampling methods may include: a. Sampling protocols identified in the Federal Register. Vol. 45, No. 98, p. 33127, as follows: Extremely viscous liquid - ASXM Standard D140-70. Crushed or powdered material - ASTM Standard D346-75. Soil or rock-like material - ASTM Standard D420-69. Soil-like material - ASTM Standard D1452-85. Ely ash-like material - ASTM Standard D2234-76. Containerized liquid wastes - "COLIWASA" described in 'Test Methods for the Evaluation of Solid Waste, Physical/Chemical Methods," U.S. EPA, Office of Solid Waste, also described in "Samplers and Sampling Procedures for Hazardous Waste Streams," EPA 600/2-80-018, January, 1980. Liquid waste In pits, ponds, lagoons and similar reservoirs "Pond Sampler" described in "Test Methods for the Evaluation of Solid Waste, Physical/Chemical Methods," U.S. EPA Office of Solid Waste, also described in "Samplers and Sampling Procedures for Hazardous Waste Streams," EPA 600/2-80-018, January, 1980. b. An equivalent sampling method. Note: documentation supporting the choice of the equivalent sampling method must be provided. 4. The frequency with which the Initial analysis of the waste will be reviewed or repeated to ensure that the analysis is accurate and up to date. 5. For off-site facilities, the waste analyses that hazardous waste generators who ship wastes to the site have agreed to supply. 150 CCR 000037531 C.3. General inspection requirements: Section 5.5.2A of the HWMP as amended requires the owner or- operator of any treatment, storage or disposal facility to develop a schedule of routine facility inspections and to keep a log or record of all inspections carried out thereunder* The required schedule of inspections oust include: 1. Inspection of the facility for malfunctions and deterioration, operator errors, and discharges which may be causing, or may lead to: a. Release of hazardous waste constituents to the environment, or; b* A threat to human health. The owner or operator mist conduct these inspections often enough to identify problems in time to correct them before they harm human health or the environment. 2. The owner or operator must develop and follow a written schedule for inspecting and monitoring equipment, safety and emergency equipment, security devices, and operating and structural equipment (e*g*, dikes and sump poops) that are important to preventing, detecting, or responding to environmental or human health hazards. 3. The owner or operator must keep this schedule at the site, and available for Inspection by authorized representatives of th Hazardous Waste Division* 4. The schedule must Identify the types of problems (e*g., malfunctions or deterioration) which are to be looked for during the inspection (e.g., inoperative sump pump, leaking fitting, eroding dike, etc.), and the frequency of inspection for each. 5. The frequency of inspection may vary for the items on the schedule* However, it should be based on the rate of possible or projected deterioration or malfunction of the equipment and the probability of an environmental or human health incident if the deterioration or malfunction or any operator error goes undetected between inspections* Areas subject to spills, such as loading and unloading areas, must be inspected -dally when in use* 6. The owner or operator mist remedy any deterioration or malfunction of equipment or structures which the inspection reveals on a schedule which ensures that the problem does not lead to an environmental or human health hazard. Where a hazard is imminent or has--already occurred, remedial action must be taken immediately* 7. The owner or operator use record inspections in an inspection log. Such inspection log must be kept for a period of at least three years, and must be available for inspection by the authorized representatives of the Hazardous Waste Division. At a minimum, such inspection log oust Include: a. The date and time of the inspection; b. The name of the inspector; c* A notation of the observations made; and d. The date and nature of any repairs or other remedial actions. C.4. Personnel training: 1. Personnel at hazardous waste treatment, storage and disposal facilities mist successfully complete a program of classroom instruction _or on-the-job training that teaches them to perform their duties in a way that ensures the facility's compliance with all applicable requirements of the HWMP so as to assure protection of the public health and the environment. The cwner or operator must ensure 151 CCft 000037532 that this program includes all the elements described in the remainder of .this section* 2. This program mist be directed by a person trained in hazardous waste management procedures* and must include instruction which teaches facility personnel hazardous waste management procedures (including contingency plan implementation) relevant to the positions in which they are employed. 3. At a minimum, the training program must be designed to ensure that facility personnel are able to respond effectively to emergencies by familiarizing them with emergency procedures, emergency equipment, and emergency systems, including, where applicable: a. Procedures for using. Inspecting, repairing, and replacing facility emergency and monitoring equipment; b* Key parameters for automatic waste feed cut-off systems; c. Communications or alarm systems; d* Response to fires or explosions; e. Response to ground-water contamination incidents; and f* Shutdown of operations* 4. Facility personnel Bust sucessfully complete the program required in section C4l. above within six months after the ettective date~'of~ the interim status requirements of Section 5*2*2A of the HWMP. or six months after the date of their employment or assignment to a facility, .or to a new position at a facility, whichever is later* Employees hired after the effective date of the interim status requirements of Section 5.2.2A of the HWMP must not work in unsupervised positions until they have completed the training requirements of C*4.I. 3* Facility personnel must take part in an annual review of the initial training required in C.4.1. 6* The owner or operator must maintain the following documents and records at the hazardous waste site: a. The job title for each position at the hazardous waste site related to hazardous waste management, and the name of the employee filling each job; b* A written job description for each person listed in paragraph C.4.6.a. This description may be consistent in its degree of specificity with descriptions for other similar positions in the same company location or bargaining unit, but mst include the requisite skill, education, or other qualifications, and duties of employees assigned to each position; and c* A written description of the type and amount of both introductory and continuing training that will be given to each person filling a position listed under C*4.6.a*; and d* Records that document that the training or job experience required under C*4*l*, C.4.2., and C*4*3* above has been given to, and completed by, hazardous waste site personnel* 7. Training records on current personnel mist be kept until closure of the hazardous waste site; training records on former employees must be kept for at least three years from the date the employee last worked at the hazardous waste site* Personnel training records may accompany personnel transferred within the same company. Preparedness and prevention: 1* Design and operation of the facility: Facilities mist be designed , 152 CCR 000037533 constructed, maintained, and operated to minimize the possibility of a fire, explosion, or any unplanned or sudd n or non-sudden rel ase af hazardous waste or hazardous waste constituents to air, soil, or surface water which could threaten human health or the environment. 2. Required equipment: All facilities must be equiped with communications and fire control equipment or facilities as required under section 8*4.11} of the HUMP, unless it can be demonstrated to the Secretary pursuant to section 8.4.1G of the HWMP that none of the hazards posed by wastes handled at the facility could require th specified communications and fire control equipment or facilities. 3. Testing and maintenance of equipment: All facility communications or alarm systems, fire protection equipment, spill control equipment, and decontamination equipment, where required, must be tested and maintained as necessary to assure its proper operation in time of emergency. 4. Access to communications or alarm system: a. Whenever hazardous waste is being poured, mixed, spread, or otherwise handled, all personnel involved in the operation must have immediate access to an internal alarm or emergency communications device, either directly or through visual or voice contact with another employee, unless the Secretary has ruled that such a device is not required under section 8.4.ID of the HWMP. b. If there is ever just one employee on the premises while th facility is operating, he must have Immediate access to a device, such as a telephone (immediately available at the point of operation) or a two-way radio, capable of summoning external emergency assistance, unless the Secretary has ruled that such a device is not required under section 8*4.ID of the HWMP. 5. Required aisle space: The owner or operator mist maintain aisle space to allow the unobstructed movementof personnel, fire protection, fire protection equipment, and decontamination equipment to any area of facility operation in an emergency, as required for access to services (HWMP 8.3.2D); such access shall be a component of emergency procedure and contingency plans (HWMP 8.5.3), unless th Secretary has ruled such access is not required, pursuant to th procedures of HWMP 8.5.3E. 6. Special handling for jgnitable or reactive waste: The owner or operator must take precautions to prevent accidental ignition or reaction of ignltable or reactive waste. This waste must be separated and protected from sources of ignition and reaction including but not limited to: open flames, smoking, cutting and welding, hot surfaces, frictional heat, sparks (static, electrical, or mechanical), spontaneous ignition (e.g., from heat-producing chemical reactions), and radiant heat. While ignltable or reactive waste is being handled, the owner or operator must confine smoking and open flame to specially designated locations. "Ho Smoking" signs must be conspicuously placed wherever there is a hazard from ignltable or reactive waste. 7. Arrangements with local authorities: As required by HWMP 8.5.3A,B,C, the cxraer or operator shall: a. Conduct training sessions to be held at regular Intervals to inform the plant contingency team, representatives of local fire and police departments, and emergency response teams of plant 153 CCR 000037534 layout, location of possible hazards, emergency equipment location . and operation, the evacuation plan and route, power and stream cut-offs, communications equipment and phone numbers of all required contacts, and other critical information and procedures * b. The contingency plan required by HWMP 8.5.3A should include arrangements to familiarize, as appropriate for the type of waste handled at the hazardous waste site and the potential need for health emergency and hospital services, hospitals with the properties of hazardous wastes handled at the hazardous waste site and the types of injuries or Illnesses which could result from fires, explosions, or releases at the hazardous waste site* c. Where State or local authorities decline to enter Into such arrangements, the owner or operator mist document the refusal In the operating record* C.6. Contingency plan and emergency procedures: As required by HWMP 8.5.3, each owner or operator must have a contingency plan for his hazardous waste site* The contingency plan must be designed to minimize hazards to human health or the environment from fires, explosions, or any unplanned sudden or non-sudden release of hazardous waste or hazardous waste constituents to air, soil, or surface water* The provisions of the plan must be carried out immediately whenever there Is a fire, explosion, or release of hazardous waste or hazardous waste constituents which could threaten human health or the environment. 1 Filing of the contingency plan: a. As required by HWMP 8.5.3A, the plan shall first be filed with the Secretary. b* Following approval by the Secretary, the plan shall be filed with: the local fire and police departments (if any operate in the area), hospitals, and emergency response teams operating In the area or subject to call by the operator or the Department. 2. Content of contingency plan: a. The contingency plan must describe the actions facility personnel must take tocomply with the requirements of HWMP 8.5.3 In response to fires, explosions, or any unplanned sudden or non-sudden release of hazardous wastes or hazardous waste constituents to air, soil, or surface water at the hazardous waste site. b. If the owner or operator has already prepared a Spill Prevention, Control, and Countermeasures (SPCC) in accordance with 40CFR Part 112 or Part 151, he need only amend that plan to Incorporate hazardous waste management provisions that are sufficient to comply with the requirements of HWMP 8.5.3, and are approvable by the Secretary. c* The plan mustdescribe arrangements agreed to by local police departments, fire departments, hospitals, contractors, and State and local emergency response teams to coordinate emergency services, pursuant to HWMP 8.5.3. d* The plan must list names, addresses, and phone numbers (office and home) of all persons qualified to act as emergency coordinator and this list mist be kept ud to date. Where more than one person Is listed, one must be named as primary emergency coordinator and others must be listed In the order In which they. 154. ______ CCR 000037535 t will assume responsibility as alternates. For new facilities, this information oust be supplied to the Secretary at the time of certification, rather than at the time of permit application, e. The plan must include a list of all emergency equipment at the facility (such as fire extinguishing systems, spill contol equipment, communications and alarm systems (internal and external), and decontamination equipment), where this equipment is required. This list mist be kept up to date. In addition, the plan mist include the location and a physical description of each item on the list, and a brief outline of its capabilities. 3. Copies of contingency plan; A copy of the plan shall be filed with the Secretary and, after his approval, must be: a. Maintained at the hazardous waste site; and b. Submitted to all local police departments, fire departments, hospitals, and State and local emergency response teams that may be called upon to provide emergency services. 4. Amendment of contingency plan: The plan must be reviewed, and immediately amended, if necessary, whenever: a. The permit is revised; b. The facility operations are changed due to expansion, change in type or quantity of waste handled, or other changes which affect the degree or type of possible emergency situation; c. The plan fails in an emergency; d. The list of emergency coordinators changes; or e. The list of emergency equipment changes. 5. Emergency coordinator: As required by HUMP 8.5.3D, at all times there must be at least one employee on the hazardous waste site premises during operation who shall be trained in emergency procedures and in charge of all emergency response measures. An emergency coordinator shall be on call also, when the hazardous waste site is not in operation. The emergency coordinator nust be thoroughly familiar with all aspects of the hazardous waste site's contingency plan, all operations and activities at the hazardous waste site, the location and characteristics of waste handled, the location of all records within the hazardous waste site, and the hazardous waste site layout. In additon, this person must have the authority to carry out the contingency plan* Applicable responsibilities for the emergency coordinator vary, depending on factors such as type and variety of waste(s) handled by the hazardous waste site, and type and complexity of the hazardous waste site. 6. Emergency procedures: a. Whenever there is an imminent or actual emergency situation, the emergency coordinator mist immediately: Activate internal hazardous waste site alarms or communications systems, where applicable, to notify all hazardous waste site personnel; and Notify appropriate State or local agencies with designated response roles if their help is needed. b. Whenever there is a release, fire, or explosion, the emergency coordinator must immediately identify the character, exact source, amount, and areal extent of any released materials. He may do this by observation or review of hazardous waste site records or manifests and, if necessary, by chemical analysis. 155 OCR 000037536 c> Concurrently, the emergency coordinator must assess possible haz rds -to human health or the environment chat may result from the release, fire, or explosion* This assessment oust consider both direct and Indirect effects of the release, fire, or explosion (e*g*, the effects of any toxic. Irritating, or asphyxiating gases that are generated, or the effects of any hazardous surface water run-off from water or chemical agents used to control fire and heat-induced explosions). d* If the emergency coordinator determines that the hazardous waste site has had a release, fire, or explosion which could threaten human health, or the environment, outside the hazardous waste site, he must report his findings as follows: (1) If his assessment indicates that evacuation of local areas may be advisable, he must Immediately notify appropriate local authorities. He must be available to help appropriate officials decide whether local areas should be evacuated; and (2)He must Immediately notify the Secretary, using the telephone contact designated In the contingency plan, and the National Response Center (using their 24-hour toll free number 800/424-8802). The report mist include: Name and telephone number of reporter; Name and address of hazardous waste site; Time and type of Incident (e.g>, release, fire); Name and quantity of material(s) involved, to the extent known; The extent of Injuries, if any; and -- The possible hazards to human health, or the environment, outside the hazardous waste site. e. During an emergency, the emergency coordinator mist take all reasonable measures necessary to ensure that fire, explosions, and releases do not occur, recur, or spread to other hazardous wastes at the hazardous waste site* These measures must include, where applicable, stopping processes and operations, collecting and containing released wastes, and removing or Isolating containers * f. If the hazardous waste site stops operations In response to a fire, explosion, or release, the emergency coordinator must monitor for leaks, pressure buildup, gas generation, or ruptures In valves, pipes, or other equipment, wherever this is appropriate. g. Immediately after an emergency, the emergency coordinator must provide for treating, storing, or disposing of recovered waste, contaminated soil or surface water, or any other material that results from a release, fire, or explosion at the hazardous waste site. Unless the owner or operator can demonstrate in accordance with the HWMP that the recovered material Is not a hazardous waste, the owner or operator becomes a generator of hazardous waste and must manage It in accordance with all app11cable provisions of the HWMP. h. The emergency coordinator must ensure that, in the affected area(s) of the hazardous waste site: (1) No waste that may be Incompatible with the released material is treated,, stoi d, or disposed of until cleanup procedures . are completed; anc 156 CCR 000037537 *T (2) All emergency equipment listed in the contingency plan is cleaned and fit for its intended use before operations are resumed* 1* The owner or operator must notify the Secretary, and appropriate State and local authorities, that the hazardous waste site is in compliance with C.6.8., above, before operations are resumed in the affected area(s) of the hazardous waste site* j* The earner or operator oust note in the operating record the time, date, and details of any incidentthat requires implementing the contingency plan* Any spill or release that could possibly endanger health or adversely affect the environment off-site shall be reported to the Department within 24 hours, as required by HWMP 6.4A. In addition to such notice to the department, a written report to the Department based on the operating record must be sent within 15 days of the incident; such report must Include: (1) Name, address, and telephone number of the owner or operator; (2)Name, address, and telephone number of the hazardous waste site; (3) Date, time, and type of incident (e*g*, fire or explosion); (4) Name and quantity of material(s) involved; (5) The extent of injuries, if any; (6) An assessment of actual or potential hazards to human health or the environment, where this is applicable; and (7) Estimated quantity and disposition of recovered material that resulted from the incident. C.7. Operating record: As required by HWMP 8.5.1, the owner or operator shall keep a written operating record of his hazardous waste site. The following information must be recorded, as it becomes available, and maintained in the operating record until closure of the hazardous waste site: 1. A description and the quantity of each hazardous waste received, and the method(s) and date(s) of its treatment, storage, or disposal at the hazardous waste site* See C.ll*: Recordkaeping Instructions. 2. The location of each hazardous waste within the hazardous waste site and the quantity at each location* Tor disposal facilities, the location and quantity of each hazardous waste must be recorded on a map or diagram of each cell or disposal area. For all facilities, this information must include cross-references to specific manifest document numbers, if the waste was accompanied by a manifest; 3. Records and results of waste analyses performed as specified in BUMF 5.5*2, 8.4.2A,B,C, and 8.4.9A.3); 4. Summary reports and details of all incidents that require implementing the contingency plan as specified in HWMP 8.5.3 and in C.6, above; 5. Records and results of inspections as required by HWMP 5.5.2A. and C.3, above (except these data need be kept only three years). 6. Monitoring, testing, or analytical data where required by HWMP 8.4.10, 8.4.6B.7), 8.6.5B, and 8.4.8B.4) (note: as required for evaluation pursuant to HWMP 8.6.6C, monitoring data for land disposal sites is required to be maintained throughout the period of post-closure care); and 7* All closure cost estimates under HWMP 8.6*2 and 8.6.3 and, for land disposal facilities, all post-closure cost estimates under HWMP 8.6.2 157 CCR 000037538 and 8.6.3. C.8. Availability* retention* and disposition of records: 1. All records. Including plans, required under the HWMP must be furnished upon request,. and made available at all reasonable times for Inspection, by the Secretary or his authorized representative. 2. The retention period for all records required under the HWMP is extended automatically during the course of any enforcement action regarding the hazardous waste site or as requested by the Secretary or the Assistant Secretary. 3. A copy of records of waste disposal locations and quantities, as required by HWMP 8.6.5B, must be submitted to the Secretary and filed with the land records of the Parish in which the hazardous waste site is located, upon closure of the hazardous waste site. C.9. Quarterly report: 1. As required by HWMP 5*4.3, a quarterly report aust be filed with the Department, due no later than 15 days after the end of each quarter: ' April 15, July 15, October 15 and January 15; quarterly reports shall include: a. The EPA identification number (and also State identification number, pending change of State numbers to EPA numbers), name, and address of the hazardous waste site; b. The quarter covered by the report; c. For off-site facilities, the EPA identification number (and the State identification number, while applicable) of each hazardous waste generator from which the hazardous waste site received a hazardous waste during the year; for imported shipments, the report mist give the name and address of the foreign generator; d. A description and the quantity of each hazardous waste the hazardous waste site received during the quarter. For off-site facilities, this information mist be listed by EPA identification number (and State identification number, while applicable) of each generator: The method of treatment, storage, or disposal for each hazardous waste; Monitoring data where applicable, e.g., development of background groundwater quality data. C.10. AnnTin 1 report: 1. An annual report of the closure fund prepared by a certified public accountant shall be submitted to the Secretary. 2. An update of the cost estimate for closure and post-closure shall be submitted with the annual report, together with certification by the owner or operator of any resulting change in the closure and post-closure plan(s) and the Closure Fund. C.ll. Hacordkeeping instructions: For purposes of recordkeeping and reporting as required by the HWMP, the descriptions of wastes and of handling codes are to be provided as follows: 1. Records of each hazardous waste received, treated, stored, or disposed of at the facility must be maintained in the operating record until closure of the facility, in the following manner: a. A description by its common name and the EPA Hazardous Waste 158 & C<* Number(s) from Appendix A of the HWMP or 40 CFR Part 261 which apply to* the waste. The waste description oust also indud the waste's physical form, i.e., liquid, sludge, solid, or contained gas* If the waste is not listed in HUMP Appendix A or 40 CFR fart 261, Subpart 0, the description must also include the process that produced it (for example, solid filter cake from production of , EPA Hazardous Waste Number W051). Each hazardous waste listed in HWMP Appendix A, Category I or 40 CFR Part 261 Subpart 0 has a four-digit EPA Hazardous Waste Number assigned to it* This number must also be used for recordkeeping and reporting purposes* Where a hazardous waste contains more than one listed hazardous waste, or where more than one hazardous waste characteristic applies to the waste, the waste description must Include all applicable EPA Hazardous Waste Numbers Where the waste is identified as hazardous under HWMP Appendix A Category III, but is not a hazardous waste under 40 CFR Part 251, the appropriate description according to the HWMP must be provided* b* The estimated or manifest-reported weight, as required by the HWMP, for each reported waste* The symbol "T" is to be used for short tons, 2000 pounds. 2. The method(s) (by handling code(s) as specified in Table 1, below) and date(s) of treatment, storage or disposal. Table It Handling Codes for the treatment. storage and disposal methods Enter the handling code(s) listed below that most closely represents the technique(s) used at the facility to treat, store, or dispose of each quantity of hazardous waste received* 1* Storage 501 Container (barrel, drum, etc.) 502 Tank 503 Waste pile 504 Surface impoundment 505 Other (specify) 2. Treatment (a) Thermal Treatment T06 Liquid Injection Incinerator T07 Rotary kiln incinerator T08 Fluidized bed incinerator T09 Multiple hearth incinerator T10 Infrared furnace incinerator Til Molten salt destructor T12 Pyrolysis T13 Wet Air oxidation T14 Calcination T15 Microwave discharge T16 Cement kiln T17 Lime kiln T18 Other (specify) (b) Chemical Treatment T19 Absorption mound T20 Absorption field 159 CCR 000037540 T21 Chemical fixation T22 Chemical oxidation T23 Chemical precipitation T24 Chemical reduction T25 Chlorination T26 Chlorinolysis T27 Cyanide destruction T28 Degradation T29 Detoxification T30 Ion exchange T31 Neutralization T32 Ozonation T33 Photolysis T34 Other (specify) (c) Physical Treatment *. (1) Separation of components T35 Centrifugation T36 Clarification T37 Coagulation T38 Decanting T39 Encapsulation T40 Filtration T4I Flocculation T42 Flotation T43 Foaming T44 Sedimentation T45 Thickening T46 Ultrafiltration T47 Other (specify) (2) Removal of Specific Components T48 Absorption-molecular sieve T49 Activated carbon T50 Blending T51 Catalysis T52 Crystallization T53 Dialysis T54 Distillation T55 Electrodialysis T56 Electrolysis T57 Evaporation T58 High gradient magnetic separation T59 Leaching T60 Liquid ion exchange T61 Liquid-liquid extraction T62 Reverse osmosis T63 Solvent recovery T64 Stripping T65 Sand filter T66 Other (specify) (d) Biological Treatment T67 Activated sludge T68 Aerobic lagoon T69 Aerobic tank T70 Anaerobic lagoon 160 CCR 000037541 T71 Composting T72 Septic tank T73 Spray irrigation T74 Thickening filter T75 Trickling filter T76 Waste stabilization pond T77 Other (specify) T78-79 (Reserved) 3* Disposal D80 Underground injection D81 Landfill D82 Land treatment D83 Ocean disposal D84 Surface impoundment (to be closed as a landfill) D85 Other (specify) GROUND HATER MONITORING C.12. Applicability: 1. Within one year from the effective date of the mandatory interim status standards set forth in HWMP 5.2.2A, or upon the issuance of a compliance order or under the terms of an interim or standard permit issued in accordance with HWMP5.2.3A--whichever is the earlier date--the owner or operator of a surface impoundment, landfill, or land treatment facility which is used to manage hazardous waste must implement a ground-water monitoring program capable of determining the facility's impact on the quality of ground water in the uppermost aquifer underlying the facility, except as may be more stringently required under SWMP 8.4.10 for any facility. 2. The owner or operator must install, operate, and maintain a ground-water monitoring system which meets the requirements of HUMP 8.4.10, and oust carry out the ground-water monitoring program during the active life of the facility, and for land disposal facilities, during the period of post-closure care as specified under HWMP 8.8* 6C. 3. For land disposal (burial) facilities, a leachate monitorings system as required under HWMP 8.4.10B.1) shall be installed and operated and maintained, except as an equivalent system may be approved by the Secretary in accordance with HWMP 8.4.10B3). 4. Unlike 40 CFR Part 265.90(c), the HWMP does not provide for waiving in part or in whole of the ground-water monitoring requirements of HWMP 8.4.10A. C.13. Ground-water monitoring system: 1. Technical requirements of ground-water monitoring are set forth in . . .section A.2. "MONITORING EXPECTATIONS" of the AOPM, through section 222 2. The definition of "facilities" in the HWMP requires more stringent Interpretation of monitoring system needs than does 40 CFR Part 265.91(b). C.14. Sampling and analysis: 1* The owner or operator must obtain and analyze samples from the 161 CC 0000375*2 installed groundwater monitoring system and', wh re applicable, from the leachate monitoring system* The owner or operator oust develop and follow a ground water sampling and analysis plan* H must keep this plan at the facility. The plan oust Include procedures and techniques for: a. Sample collection; b. Sample preservation and shipment; c. Analytical procedures; and d* Chain of custody control. Technical expectations for the development and implementation of such plan are provided in the AOPM, sections A. 2 and B* Other satisfactory technical sources providing discussions and technical bases for the plan are: (1) "Procedures Manual For Ground-Water Monitoring At Solid Waste Disposal Facilities," EPA-5 30/SW-611, August 1977; and Methods for Chemical Analysis of Water and Waste," EPA-600/4-79-020, March 1979. 2. Within the first quarter following implementation of the monitoring plan, all monitoring wells must be sampled and analyzed thereafter with the following frequencies: a. Samples collected to establish ground water quality must be obtained and analyzed for the parameters specified in AOMF A.2.1.2, except as the scope of parameters may be defined by the Secretary after baseline establishment so as to eliminate any compounds consistently not found in the waste handled at the facility, at least annually. b. Samples collected to indicate ground-water contamination must be obtained and analyzed for the following parameters quarterly: specific conductivity, mho/cm at 25 degrees C temperature, C (field and laboratory) total dissolved solids (TDS), mg/liter chloride, mg/liter pH dissolved organic carbon, mg/liter total organic carbon (TOC) two principal metals or other designated parameters (ones found in the largest quantities or which best serve as indicators), as designated by the Department, in mg/liter; where halogenated organics are present in waste components, total organic halogen will be specified. c. Elevation of the groundwater surface at each monitoring well must be determined each time a sample is obtained. C.15. Preparation, evaluation, and response: 1. Within one year after the effective date of the mandatory interim status standards set forth in HWMP 5.2.2A, or as required by compliance order or interim or standard permit condition--whichever is earlier--the owner or operator must be in compliance with the requirements of HWMP 8.4.10A.2), for development of and adherence to a groundwater sampling and analysis plan for the purpose of monitoring groundwater so as to determine any significant change in groundwater quality. Such plan and adherence thereto shall meet' the-- technical requirements of AOPM A. 2. 2. When monitoring shows that the concentration of a chemical species has increased above baseline levels by a statistically significant amount, i.e., as indicated by the Student's single-tailed test at the 162 CCR 000037543 95Z confidence level -(s e AOPM Appendix B), the owner or operator must take the following actions: a. Notify the Department within 48 hours by telephone, and'in writing within 7 days; b. Undertake confirmatory analyses; c. Determine the cause of the increase, e.g., the result of a spill, a design failure, an improper operating procedure, etc., and initiate corrective action; and d. Determine the extent of the ground-water contamination and the actual or potential threat to public health or the environment, where applicable. e. Provide to the Secretary a written assessment of the ground-water quality, within 15 days of determination of a significant increase of contamination. 3. If. the owner or operator determines, based on the results of th ground-water quality assessment in section C.14.3.e. that no hazardous waste or hazardous waste constituents from the facility have entered the ground water, then he may reinstate the monitoring procedures set forth in AOPM A.2 for determination of background ground water quality, and appropriate routine sampline and analyses on indicator parameters. Such action must be noticed to the Department in the written assessment prepared in accordance with C.14.-2.e., above. 4. If the owner or operator determines, based on the evaluation and assessment, that hazardous waste or hazardous waste constituents from the facility have entered the ground water, he shall Implement a continuing sampling and analysis program for all parameters relevant to continued assessment of ground water quality on a quarterly basis until closure of the facility (if the ground water quality assessment plan was implemented prior to closure of the facility). C.16. Recordkeeping and reporting: The owner or operator shall report the following ground water monitoring information to the Secretary: 1. During the first year when initial background concentrations are being established for the facility, the following information: a. Concentrations or values of all the parameters required to be sampled and analyzed, within 15 days after completing each quarterly analysis; b. Separate identification for each monitoring well any parameters whose concentration or value has been found to exceed the maximum contaminant levels identified by EPA interim primary drinking water standards. 2. Concentrations or values of the required parameters for each ground-water monitoring well, along with required evaluations for these levels. a. Separate identification must be provided for any significant differences from initial background found in the upgradient wells. During the active life of the facility, this information must be reported as part of the quarterly report required under HWMP. 3. The owner or operator must keep records of the analyses and evaluations specified in the ground-water monitoring plan throughout the active life of the facility and, for land disposal facilities, throughout the post-closure care period as well. 4 The owner or operator must, annually, submit to the Secretary a 163 CCR 000037544 report containing the results of his ground-water quality assessment program which includes, but is not limited to, the calculated (or measured) rate of migration of hazardous waste or hazardous waste constituents In the ground water during the reporting period* CLOSURE AHD POST-CLOSURE C.17. Applicability: 1* Pursuant to HWMP 8.6.1, closure and post-closure requirements in existence as of the effective date of the HUMP, or any new facilities permitted thereafter, except that any facility totally closed before the effective date of HWMP 5.2.2A is excluded from these requirements unless such facility is required to meet closure conditions under previous compliance order or a previous permit condition. 2. Requirements for post-closure care apply to all land disposal facilities not previously totally closed. C.18. Closure performance standard: 1. Pursuant to HWMP 8.6.2, the owner or operator oust close his facility in a maimer that: a. Minimizes the need for further maintenance; and b. Controls, minimizes or eliminates, to the extent necessary to protect human health and the environment, post-closure escape of hazardous waste, hazardous waste constituents, leachate, contaminated rainfall, or waste decomposition products to the ground water, or surface waters, or to the atmosphere. C.19. Closure plan; amendment of plan: 1* On the effective date of HWMP S.2.2A mandatory interim status standards, or on the effective date of an interim or standard permit, or of a compliance order requiring such plan--whichever is sooner--the owner or operator must have a written closure plan. He must keep this plan at the facility. This plan must identify the steps necessary to completely close the facility at any point during its intended life and at the end of its intended life. The closure plan mist include, at least: a. A description of how and when the facility will be partially closed, if applicable, and ultimately closed. The description must identify the maximum extent of the operation which will be unclosed during the life of the facility, and how the requirements of HWMP 8.6.2 will be met; b. An estimate of the maximum inventory of wastes in storage or in treatment at any given time during the life of the facility; c. A description of the steps needed to decontaminate facility equipment during closure; and d. A schedule for final closure which must include, as a minimum, the anticipated date when wastes will no longer be received, the date when completion of final closure is anticipated, and intervening milestone dates which will allow tracking of the progress of closure. (Par example, the expected date for completing treatment or disposal of waste inventory must be Included, as must the planned date for removing any residual wastes from storage facilities and treatment processes.) 2. Pursuant to HWMP 5.3.4A.8), closure and post-closure plans are a required consideration element for permit application by the owner or 164 CCR 0000375*5 operator 3* The owner or operator nay amend his closure plan at any time during the active life of the facility* (The active life is that period r during which wastes are periodically received*) The owner or operator must amend his plan any time changes In operating plans or facility.design affect the closure plan, and must submit such amended plan to the Secretary for approved and filing as a condition of the facility permit* At any time the Secretary evaluates the facility permit, including any modifications thereof, amendment to the closure plan may be required* 4. The owner or operator must notify the Secretary at least 90 days before the date he expects to begin closure, as required by HWMP 8.6*3; with the notification, the following information must be submitted; a- Date of planned closure; b. Changes, if any, requested in the closure plan submitted with the permit application to take advantage of new technology, unforeseen situation, and other requests which improve the safety of the closed facility; c. Closure schedule and estimated costs of each phase of the closure plan; and d* Request for release of closure funds in amounts and times as required by the closure schedules* e. Pursuant to HWMP 8.6.4B, if the owner or operator applies to the Secretary for approval of change of the closure plan previously approved as a condition of the facility permit, the procedures established for the permit process (HWMP 5.3) will be followed in evaluating the requested changes and making a determination, including provlson of notice and potential for public comment* C.20. Time allowed for closure: 1* Timely adherence to the closure schedules approved by the Secretary will be required* Each phase of closure must be evaluated by the Secretary and will be accepted or rejected. Closure funds for each phase of closure will not be released until after acceptance of such phase by the Secretary, as provided by HWMP 8.6.4A. 1). Failure to comply with timely schedules may result in issuance of a compliance order, or other enforcement action as provided under HWMP 10.0. Failure of the owner or operator to obtain approval of closure renders him subject to declaration that the facility is an abandoned site* In such case, the State has the authority to take necessary action to properly close the site, retain control of the closure fund, and to seek recovery of any costs from the owner or operator (see Attorney General's statement on new 1980 State authority in such circumstances) 2. Expected schedules for timely closure are as follows: a. Within 90 days after receiving the final volume of hazardous wastes, the owner or operator oust treat all hazardous wastes In storage or in treatment, or remove them from the site, or dispose of them on-site, in accordance with the approved closure plan; and b. The owner or operator must complete closure activities in accordance with the approved closure plan and within six months after receiving the final volume of hazardous wastes. The Secretary may approve a longer closure period under HWMP 8.6.4B, .165 OCR 00003*546 '1x If the owner or operator has demonstrated that: (1) the required or planned closure activities will, of necessity, take him longer than six months to complete, and (2) that he has taken all steps to eliminate any slgniiicant threat to human health and the environment from the unclosed but Inactive facility. C.21. Disposal or decontamination of equipment: 1. Pursuant to HWMP 8.6.5A, all movable equipment, containers, and facilities shall be decontaminated, and inspected and approved by the Department prior to removal from the site or disposal on the site following approved procedures. Proper decontamination shall include removal of all hazardous waste and residues from such equipment, containers, and facilities, or appropriate disposal of them as hazardous wastes. C.22. Certification of closure: 1. Pursuant to HWMP 8.6.5D, the operator and a Registered Professional Engineer who supervised the closure shall submit to the Secretary certification that the closure has been accomplished in accordance with the approved plan; such certification shall be in addition to inspection and acceptance of each phase of closure by the Secretary. 23. Post-closure care and use of property; period of care: 1. Pursuant to HWMP 5.3.4A8<b)lv) as a requirement for interim or standard permit, and 8.6.2A (mandatory closure plan), and as a requirement for land disposal facilities, post-closure care must consist of at least: a. Ground-water monitoring and reporting (see C.14 and C.15); and b. Maintenance of monitoring and waste containment systems as specified under HWMP facility standards by type of facility, and related sections of AOPM, where applicable. 2. The Secretary may require any or all of the security requirements of HWMP 8.4.X (also see statements on security .requirements in section C of the AOPM) during the post-closure period, when: a. wastes may remain exposed after completion of closure; or b. Short-term, incidental access by the public or domestic livestock may pose a hazard to human health. 3. Post-closure use of property on or in which hazardous waste remains after closure must never be allowed to disturb the integrity of the final cover, liner(s), or any other components of any containment system, or the function of the facility's monitoring systems, unless the owner or operator can demonstrate to the Secretary, either in the post-closure plan, or by petition to the Secretary pursuant to HWMP 8.6.6E and/or C, that the disturbance: a. Is necessary to the proposed use of the property, and will not increase the potential hazard to human health or the environment; or b. Is necessary to reduce a threat to human health or the environment. Pursuant to HWMP 8.6.6C, the Secretary will conduct an annual evaluation of the site for from date of closure, whe period to be not less than twenty years 166 CCR 00003754-7 Procedures established in the Permit Process will be followed in evaluating and rendering decisions on such petitions * 5 . Pursuant to HWMP 8.6.6, any proposed transfer of ownership of the property after closure shall be reported to the Secretary at least 60 days prior to execution of such sale* The Secretary must approve any new owner. Criteria for approval include (HUMP 8.6.6B): a. Agreement to land use restrictions necessary to protect public health; and b. Financial responsibility covering liability due to change in land use. 6* The owner or operator must provide post-closure care in accordance with the pproved post-closure plan for at least 20 years after the date of completing closure. The Secretary will conduct an annual evaluation of the site during this time period, and may modify the conditions of maintenance and monitoring as appropriate to the maintenance and monitoring records. The Secretary may extend the time of maintenance and monitoring, or other care, if he finds there has been noncompliance with any applicable standards or requirements, or that such continuation is necessary to protect human health or the environment. Post--closure plan; amendment of plan: 1. On the effective date of HWMP 5.2.2A interim status standards, or as may have been required on a prior date by compliance order or permit condition, the owner or operator of a land disposal facility must have a written post-closure plan. He must keep this plan at the facility. This plan must identify the activities which will be tarried on after final closure and the frequency of those activities. The post-closure plan must include at least: a. Ground-water monitoring activities and frequencies as specified in HWMP facility standards (see AOPM C.14 and C.15, and sections on facility standards) for the post-closure period; and b. Maintenance activities and frequencies to ensure: (1) the integrity of the cap and final cover or other containment structures as required under applicable facility standards, and (2) the function of the facility's monitoring equipment as required under HWMP 8.6.5C and 5.3.4A.8)b). 2. The owner or operator may amend his post-closure plan at any time during the active life of the disposal facility or during the post-closure care period (with the approval of the Secretary). The owner or operator must amend his plan any time changes in operating plans or facilities design affect his post-closure plan, or evaluatou or modification of his permit makes such modification necessary. 3. The owner or operator of a disposal facility must submit his post-closure plan to the Secretary as a condition of an interim or standard permit and also concurrently with the closure plan submission at least 90 days before he plans to begin closure. The procedures for acceptance or modification are similar to those for closure plan (se^, AOPM C. 18.). The plan may be modified include 167 CCR 000037548 security equipment maintenance (see AOPM C.18.). If an unpermitted existing facility plans to begin closure within 90 days of the effective date of HWMP 8.2.2A mandatory interim status standards, the owner or operator mist submit the necessary plans on the effective date of the mandatory interim status standards. C.25. Notice to local land authority: I. At the time closure is accepted, the owner or operator must prepare and submit to the Secretary and the Parish land authority in th Parish in which the facility is located, a certified plat indicating the locations of all burial sites and facilities, and the contents (by hazardous waste type or identification and the quantities of wastes as documented by the operating record) of those sites (such a certified plat must be prepared by a professional land surveyor, utilizing surveyed bench marks of record), as required by HWMP 8.6.5B. Por wastes disposed of before the effective date of th HWMP, the owner or operator must identify the type, location, and quantity of the wastes to the best of his knowledge and in accordance with any records he has kept. C.26. Notice in deed to property: 1. The owner or operator, at the time of acceptance of closure, must file the certified plat discussed in C.24 with the land records of the Parish in which the facility is located, pursuant to HWMP 8.6.5B. 2. State law provides, pursuant to HWMP 8.6.6A, that the owner or operator must report to the Secretary for his approval any proposed transfer of ownership of the property. Criteria for approval by the Secretary, as set forth in HWMP 8.6.6B, includ agreement by the proposed new owner to land use restrictions necessary to protect public health, and acceptance by the proposed new owner of financial responsibility covering liability due to any change in land use. 3. HWMP 8.6.6C. also requires the Secretary to conduct an annual evaluation of the site for a period to be not less than twenty years from date of closure, to afford addltonal supervision and control of subsequent maintenance and use. CLOSURE AND POST-CLOSURE FINANCIAL REQUIREMENTS C.27. Applicability 1. HWMP 8.6.2 requires all owners and operators of hazardous waste treatment, storage and disposal facilities to estimate the cost of closure, and long-term monitoring and other long-term maintenance after closure of such facility, and to create a "Closure Fund" to provide assets at time of closure and for post-closure care. 28. Cost estimate for facility closure: 1. On the effective date of the mandatory interim status standards set forth in HWMP 5.2.2A (or for prior periods as required by complianc schedules or interim or standard permit conditions under HWMP 5*3.4 and 8.6.2) each facility owner or operator must have a written estimate of the cost of closing the facility in aaecordance with applicable facility standards under the HWMP. He must keep this estimate, and all subsequent estimates required under the HWMP, at 168 COR 000037549 the facility, and must file the estimate with the Secretary as a conditon of permit application* For estimate of costs, the estimate must equal the cost of closure it the point in the facility's operating life when the extent and ma tner of its operation would make closure the most expensive, as Indicated by Its closure plan. 2. The owner or operator must prepare a new closure cost estimate whenever a change in the closure plan affects the cost of closure, or as may be required by the Secretary in periodic evaluation of the facility permit, or any modification of the permit such as to affect closure cost. 3. An annual report of the closure fund prepared by a certified public accountant shall be submitted to the Secretary. 4. Annual reevaluation offactors affecting changes In closure cost should be done by the owner or operator, including effects of inflation. The adjustment by an inflation factor derived from the annual Implicit Price Deflator for Gross National Product as published by the U.S. Department of Commerce in its Survey of Current Business is a recommended method (per discussion by EPA, 40 CFR 265.142(c)). C.29. Cost estimate for post-closure monitoring and maintenance: 1 A cost estimate for post-closure monitoring and maintenance is required under the same schedule(s), and under the same responsibilities on the owner and operator, as is required for closure -costs (this is a component of closure cost requirements of the HWMP). USE AND MANAGEMENT OF CONTAINERS C.30. Applicability: 1. These requirements apply to all owners or operators of facilities required to be permitted under the HWMP. C.31. Condition of Containers: 1. HWMP 8.4.5A requires that containers be handled and stored to minimize damage and potential leakage. / 2. If a container holding hazardous waste is not in good condition, or if it begins to leak, the owner or operator must transfer the hazardous waste from this container to a container that is in good condition, or manage the waste in some other way that complies with the requirements of HWMP 8.4.5A. C.32. Compatibility of waste with container: 1. HWMP 8.4.11C requires that container materials shall be compatible with the wastes contained therein. 2. The owner or operator must use a container made of or lined with materials which will not react with, and are otherwise compatible with, the hazaardous waste to be stored, so that the ability of the container to contain the waste is not impaired. C.33. Management of containers: 1. HWMP 8.4.5A requires that containers shall be handled and stored to minimize damage and potential leakage. I A container holding hazardous waste must always be closed during storage, except when it is necessary to add or remove waste* 169 CCR 000037550 3. A container holding hazardous waste must not be opened, handled, or stored in a manner which may rupture the container or cause it to leak. C.34. Inspections: 1. HWMP 8.4.5 requires that containers shall be handled and stored to minimize damage and potential leakage. 2* The ewner or operator must inspect areas where containers are stored, at least weekly, looking for leaks and for deterioration caused by corrosion or other factors. C.35. Special requirements for ignitable or reactive waste: 1. Containers holding ignitable or receive waste must be located at least 50 feet from the facility's property line. TANKS C.36. Applicability: 1. HWMP 8.4.4 applies to all treatment, storage and disposal facilities that use tanks to treat or store hazardous waste. C.37. General operating requirements: 1. HWMP 8.4.11 requires that treatment and storage facilities containing ignitable, reactive or incompatible wastes shall be sufficiently separated or protected to prevent mixing, ignition or reaction as a result of a spill, tank failure or other cause. Protection shall include use of container materials compatible with the wastes contained therein. 2. HWMP 8.4.4B.1) requires that a spill containment area capable of containing the waste in case of a spill shall surround the tank. Capacity of the containment area must equal the capacity of the tank plus precipitation resulting from a 24-hour, 25-year storm. 3. Where hazardous waste is continuously fed into a tank, the tank must be equipped with a means to stop this inflow (e.g., a waste feed cutoff system or by-pass system to a stand-by tank). C.38. Waste analysis and trial tests: 1. In addition to the waste analyses required by HWMP 8.4.2, whenever a tank is to be used to: a. Chemically treat or store a hazardous waste which is substantially different from waste previously treated or stored in that tank; or b. Chemically treat hazardous waste with a substantially different process than any previously used in that tank; the owner or operator must, before treating or storing the different waste or using the different process: Cl) Conduct waste analyses and trial treatment or storage tests; or (2) Obtain written, documented information or similar storage or treatment of similar waste under similar operating conditions, to show that this proposed treatment or storage will meet all applicable requirements of HWMP 8.4.4 and 8.4.9. C.39. Inspections: 1. The owner or operator must inspect, where present: a. Discharge control equipment at least once each operating day, to 170 CCR 000037551 ensure that It Is In good working order; b. Data gathered from monitoring equipment (e.g., pressure and temperature gauges), at least once each operating day, to ensure that the tank Is being operated according to its design; c. The level of waste in the tank, at least once each operating day, to ensure compliance with HHMP 8.4.4B. d. The construction materials of the tank, at least once weekly, to detect corrosion or leaking of the fixtures or seams; and e. The construction materials of, and the area immediately surrounding, discharge confinement areas (e.g*, dikes) at least once weekly, to detect erosion or obvious signs of leakage. C.40. Closure 1. At closure, all hazardous waste and hazardous waste residues must be removed from tanks, discharge control equipment, and discharge confinement equipment* C.41. Special requirements for ignltable or reactive waste: . 1. Ignltable or reactive waste must not be placed in a tank, unless: a. The waste is treated, rendered, or mixed before or immediately after placement in the tank so that (1) the resulting waste, mixture, or dissolution of material no longer meets the definition of ignltable or reactive waste under HUMP Appendix A, Category III, and HHMP 8.4.11C is complied with; or b. The waste is treated or stored in such a way that it is protected from any material or conditions which may cause the waste to ignite or react; or c. The tank is used solely for emergencies. 2. The owner or operator of a facility which treats or stores ignltable or reactive waste in covered tanks must conply with the National Fire Protection Association's (NFPA's) buffer zone requirements for tanks, contained in Tables 2-1 through 2-6 of the "Flammable and Combustible Code-1977". C.42 Special requirements for incompatible wastes: 1. Pursuant to HHMP 8.4.11A, incompatible wastes, or incompatible wastes and materials, shall not be placed in the same tank. 2. Hazardous waste must not be placed in an unwashed tank which previously held an incompatible waste or material. SURFACE IMPOUNDMENTS C.43. Applicability: 1 Application is to all owners or operators of hazardous waste facilities that use surface impoundments to treat, store, or dispose of hazardous wastes, pursuant to HHMP 8.0 and 8.4.3 C.44. General operating requirements: 1. As required by HHMP 8.3.4, the site as a whole, as well as thefacility (e.g., a surface Impoundment) shall be isolated from outside surface water and shall contain any potential discharges, including runoff. A surface impoundment must maintain enough freeboard to prevent any overtopping by overfilling, wave action, or a storm. There shall be at least 2 feet of freeboard; such freeboard will in many cases be insufficient to meet the requirements of BUMP 8.3.4, ':% - I 171 OCR 000037552 .y,;. , ^1 , ... . ./.T-r 8.4.3B, and 8.4.7 B.l) and 2); if so, the higher appropriate freeboard mist be used and maintained. C. 45. Containment system: X. Earthen dikes shall be properly engineered to minimize wind and water erosion and to preserve their structural integrity, by use of protective cover including grass or other acceptable method. C. 46. Waste analysis and trial tests: 1. In addition to the waste analyses requlired by HWMP 8.4.2, analyses required by HHHF 8.4.9A shall be performed whenever a surface impoundment is to be used to treat a waste substantially difference from waste previously treated at that facility, or whenever a previously unused treatment method is to be employed. C.47. Inspections: 1. The owner or operator must inspect: a. The freeboard level at least once each operating day to ensure compliance with HWMP 8.3.4A and 8.4.3 (see C.45*, above). b. The surface impoundment, including dikes and vegetation surrounding the dike, at least once a week to detect any leaks, deterioration, or failures in the impoundment (the condition of surrounding vegetation should be observed as a possible indicator of any release or leakage from the impoundment). C.48. Closure and post-closure: 1. At closure, the owner or operator may elect to remove from the Impoundment: a. Standing liquids; b. Waste and waste residues; c. The liner, if any; and d. Underlying and surrounding contaminated soil. 3. If the owner or operator does not remove all the impoundment materials listed in paragraph 1. of this section, or does not make the demonstraton in paragraph 2. of this section, he must close th Impoundment and provide post-closure care as for a landfill under HWMP 8.6. If necessary to support the final cover specified in the approved closure plan, the owner or operator must treat remaining liquids, residues, and solids by removal of liquids, drying, or other means. C.49. Special requirements for ignitable or reactive waste: 1. Ignitable or reactive waste must not be placed in a surface impoundment, unless: a. The waste is treated, rendered, or mixed before or immediately after placement in the impoundment so that (1) the resulting waste, mixture, or dissolution of material no longer meets the definition of ignitable or reactive waste under HWMP Appendix A, 172 000037553 CCR Category III A or C, and (2) HWMP 8.4.11 is complied with; or b The surface impounds nt is used solely for emergencies. C.50. Special requirements for incompatible wastes: 1. Incompatible wastes, or incompatible wastes and materials, must not be placed in the same surface impoundment, unless the requirements of HWMP 8.4.11 and 8.4.9A.2),3),4),5),6),7),8), and 9) are complied with. WASTE PILES C.51. Applicability: 1. These requirements apply to owners or operators of facilities that treat or store hazardous waste in piles. Alternatively, a pile of hazardous waste may be managed as a landfill under HWMP 8.4.7. C.52. Protection from wind: 1. The owner or operator of a pile containing hazardous waste which could be subject to dispersal by wind mist cover or otherwise manage the pile so that wind dispersal is controlled. C.53. Waste analysis: 1. In addition to the waste analysis plan and waste analyses required by HWMP 5.5.2A., 8.4.2A.,B., and C., the owner or operator must analyze a representative sample from each incoming movement before adding th waste to any existing pile, unless (1) the only wastes the facility receives which are amenable to piling are compatible with each other, or (2) the waste received is compatible with the waste in the pile to which it is to be added. The analysis conducted must be capable of differentiating between the types of hazardous waste the owner or operator places in piles, so that mixing or incompatible wastes does not Inadvertently occur. The analysis must include a visual comparison of color and texture. C.54. Containment: 1. If leachate or run-off from a pile is a hazardous waste, then either: a. The pile must be placed on an Impermeable base that is compatible with the waste under the conditions of treatment or storage, run-on must be diverted away from the pile, and any leachate and run-off from the pile must be collected and managed as a hazardous waste; or b* (1) The pile must be protected from precipitation and run-on by some other means; and (2) no liquids or wastes containing free liquids may be placed in the pile. C.55. Special requirements for Ignltable or reactive waste: 1. Ignltable or reactive wastes must not be placed in a pile, unless: a. Addition of the waste to an existing pile results in the waste or mixture no longer meeting the definition of ignltable or reactive waste under HWMP Appendix A, Category III A or C; or b The waste is managed In such a way that is is protected from any material or conditions which may cause it to ignite or react. C.56. Special requirements for Incompatible waste: 173 CCR 0OOO37554 * 1 Incompatible wast s, or incompatible wastes and materials, may not be placed in the same pile, pursuant to HUMP 8*4.11, unless such placing is carried out safely and by design as a treatment procedure, and all requirements of HHMP 8.4.9A. have been met, including prior tests or documentation and other requirements for safety and performance. 2. A pile of hazardous waste that is incompatible with any waste or other material stored nearby in other containers, piles, open tanlts, or surface impoundments shall be separated from the other materials or protected from them as required by HHMP 8.4.11C., e.g., by means of a dike, berm, wall, or other device. 3. Hazardous waste must not be piled on the same area where incompatible wastes or materials were previously piled or placed, unless that area has been decontaminated sufficiently to ensure compliance with HHMP 8.4.II. LAND TBRATMEMT C.57. Applicability: 1. These requirements apply to owners and operators of hazardous waste landfarming (land treatment) facilities. C.58. General operating requirements: 1. Pursuant to HHMP 8.4.7 and (under permitted operation) 3.3.4A.7), no hazardous waste shall be placed in or on a land treatment facility unless the waste can be made less hazardous or non-hazardous by biological degradation or chemical reactions occurring in or on the soil. 2. Run-on must be diverted away from the active portions of a landfarming facility, pursuant to HHMP 8.3.4A. 3. Run-off from active portions of a facility must be collected and properly disposed of, pursuant to HHMP 8.4.6B.6). C.59* Haste analysis: 1. In addition to the waste analyses required by HHMP 8.4.2, before placing a hazardous waste on or in a landfarm, the owner or operator must: a. Determine the concentrations in the waste of any substances which exceed the maximum concentrations contained in the Table, "Maximum Concentration of Contaminants for Characteristic of HP Toxicity", HHMP Appendix A, Category III D; b. For any waste listed in HHMP Appendix A, determine the concentration of any substances which caused the waste to be listed or identified as a hazardous waste; and c. Ensure by operations and monitoring that concentrations of hazardous waste or components of hazardous waste or dissolution of hazardous waste do not accumulate in the soil to a degree posing a threat to human health or the environment. C.60. Food chain crops: 1. No food chain crops may be grown on an active landfarm for the treatment of hazardous wastes. C.61. Dhaaturated zone (zone of aeration) monitoring: 1. As required by HHMP 3.5.2 and 8.4.6b.7), the owner or operator must have in writing, and must Implement, an unsaturated zone monitoring 174 000037555 ccfl. plan which Is designed to: a* Detect the vertical migration of hazardous waste and hazardous waste constituents under the active portion of the landfarm; and b. Provide information on the background concentrations of the hazardous waste and hazardous waste constituents in similar but untreated soils nearby; this background monitoring must be conducted before or in conjunction with the monitoring required under paragraph X.a. of this section. 2. The unsaturated zone monitoring must include, at a minimum: a. Soil monitoring using soil cores, and b. Soil-pore water monitoring using devices such as lysimeters. 3. To comply with paragraph l.a. of this section, the owner or operator must demonstrate in his unsaturated zone monitoring that: a. The depth at which soil and soil-pore water samples are to be - taken is below the depth to which the waste is incorporated into the soil; b. The number of soil , and soil-pore water samples to be taken is based on the variability of: The hazardous waste constituents in the waste and in the soil; and The soil type(s); and c. The frequency and timing of soil and soil-pore water sampling is based on the frequency, time, and rate of waste application, proximity to ground water, and soil permeability. 4. The owner or operator must keep at the facility his unsaturated zone monitoring plan and the rationale used in developing this plan* 5. The owner or operator must analyze the soil and soil-pore water samples for the hazardous waste constituents that were found in the waste during the waste analysis under C.59.1. and 2. C.62. Recordkeeping: 1. The owner or operator of a landfarm must keep records of the application dates, application rates, quantities, and location of each hazardous waste placed in the facility, in the operating plan of the facility. C.63. Closure and post-closure: 1. In the closure plan and post-closure plan required under HWMP 5.3.4A.8) and 8.6.3, the owner or operator must address the following objectives and indicate how they will be achieved: a. Control of the migration of hazardous waste and hazardous waste constituents from the treated area into the ground water; b. Control of the release of contaminated run-off from the facility into surface water; c. Control of the release of airborne particulate contaminants caused by wind erosion; and d. If food chain crops are intended to be grown on the land after closure, satisfaction of the requirements of 40 CFR 265.276, and demonstration to the Secretary, and acceptance by him, of the satisfaction of such requirements, prior to such land use. 2. The owner or operator must consider at least the following factors in addressing the closure and post-closure requirements of paragraph 1. of this section: a. Type and amount of hazardous waste and hazardous waste constituents applied to the landfarm; 175 ... CCR 000037556 b. The mobility and the expected rate of migration of the hazardous waste and hazardous waste constituents; c. Site location, topography, and surrounding land us , with respect to the potential effects of pollutant migration (e.g., proximity to ground water, surface water and drinking water sources). d. Climate, Including amount, frequency, and pH of precipitation; e. Geological and soil profiles and'surface and subsurface hydrology of the site, and soil characteristics, Including cation exchange capacity, total organic carbon, and pH; f. Unsaturated zone monitoring information obtained in accordance with C.6X.; and g. Type, concentration, and depth of migration of hazardous waste constituents in the soil as compared to their background concentrations * 3. The owner or operator must consider at least the following methods in addressing the closure and post-closure care objectives of paragraph 1. of this section: a. Removal of contaminated soils; b. Placement of a final cover, considering: (1) Functions of the cover (e.g*, infiltration control, erosion and run-off control, and wind erosion control), and (2) Characteristics of the cover. Including material, final surface contours, thickness, porosity and permeability, slope, length of run of slope, and type of vegetation on the cover; c. Collection and treatment of run-off; d. Diversion structures to prevent surface water run-on from entering the treated area; and e. Monitoring of soil, soil-pore water, and ground water. 4. In addition to the requirements of HUMP 8.6.3 and 8.6.6 (see C.22.), during the post-closure care period, the owner or operator must: a. Maintain any unsaturated zone monitoring system, and collect and analyze samples from this system in a manner and frequency specified in the post-closure plan; b. Restrict access to the facility as appropriate for its post-closure use; and c. Assure that growth of food chain crops (if any) meets requirements as noted in C.60. C.64. Special requirements for ignitable or reactive waste: 1. Ignitable or reactive wastes must not be landfarmed, unless the waste is Immediately incorporated into the soil so that: a. The resulting waste, mixture, or dissolution of material no longer meets the definition of ignitable or reactive waste under HUMP Appendix A Category III A or C; and b. Ho threat to human health or the environment resulting from extreme heat, fire or explosion or violent reaction; nor from uncontrollable toxic mists, fumes, dusts, or gases in sufficient quantities to threaten human health; nor from production of uncontrolled flammable fumes or gases in sufficient quantities to pose a risk of fire or explosion; nor from damage to the structural integrity of the device or facility containing the wastes occurs. C.65. Special requirements for incompatible wastes: l* Incompatlbl wastes, or incompatible wastes and materials, must not 176 CCR 000037557 be placed in the sane landfarm area LANDFILLS C.66. Applicability: 1. These requirements apply to owners and operators of facilities that dispose of hazardous waste in landfills; a waste pile used as a disposal facility is subject to these requirements* C*67. General operating requirements: 1* Pursuant to HHMP 8.3.4A and 8*4.7B*1) and 2), run-on must be diverted away from the active portions of a landfill* 2. Bun-off from active portions of a landfill must be collected* 3* The owner or operator of a landfill containing hazardous waste which is- subject to dispersal by wind must cover or owherwise manage the landfill so that wind dispersal of the hazardous waste is controlled* C.68. Surveying and recordkeeping: 1* The owner or operator of a landfill must maintain the following items in the operating record of the facility, which must be kept up to date at least until closure of the facility, and is required by HHMP 8* 6* 5B*: a* On a map or plat of the site, the exact location and dimensions, including depth, of each cell with respect to permanently surveyed benchmarks; and b. The contents of each cell and the approximate location of each hazardous waste type within each cell* C.69. Closure and post-closure: 1* The owner or operator must place a final cover over the landfill, and the closure plan required under HWMP 5.3.4A and 8.6.3 must specify the function and design of the cover. In the post-closure plan, the owner or operator must include the post-closure care requirements stated In paragraph 4. of this section. 2* Inthe closure and post-closure plans, the owner or operator must address thefollowing objectives and indicate how they will be achieved: a. Control of pollutant migration from the facility via ground water, surface water, and air; b. Control of surface water Infiltration, including prevention of pooling; and c. Prevention of erosion. 3. The owner or operator must consider at least the following factors in addressing the closure and post-closure objectives of paragraph 2. of this section: a. Type and amount of hazardous waste and hazardous waste constituents in the landfill; b* The mobility and the expected rate of migration of the hazardous waste and hazardous waste constituents; c. Site location, topography, and surrounding land use, with respect to the potential effects of pollutant migration (e.g*, proximity to ground water, surface water, and drinking water sources); d. Climate, including amount, frequency, and pH of precipitation;' e. Characteristics of the cover including material, final surface contours, thickness, porosity and permeability, slope, length of 177 wuqij a.MNPui * ooooV^8 ccfc run of slope, and type of vegetation on the cover; and f* Geological and soil profiles and surface and subsurface hydrology of the site* 4. In addition to the requirements discussed under C.22., during the post-closure care period, the owner or operator of a hazardous waste landfill must: a* Maintain the function and integrity of the final cover as specified in the approved closure plan; b. Maintain and monitor the leachate collection, removal, and treatment system (if there is one present in the landfill) to prevent excess accumulation of leachate in the system; c. Maintain and monitor the gas collection and control system (if there is one present in the landfill) to control the vertical and horizontal escape of gases; d*. Protect and maintain surveyed benchmarks; and e. Restrict access to the landfill as appropriate for Its post-closure use, C.70. Special requirements for Ignltable or reactive waste: longer meets the definition of ignltable or reactive waste under HWMP Appendix A Category III A or C; and b. No threat to human health or the environment resulting from extreme heat, fire or explosion or violent reaction; nor from uncontrollable toxic mists, fumes, dusts, or gases in sufficient quantities to threaten human health; nor from production of uncontrolled flammable fumes or gases in sufficient quantities to pose a risk of fire or explosion; nor from damage to the structural integrity of the device or facility containing the wastes occurs* C*71. Special requirements for incompatible wastes: 1. Incompatible wastes, as required by HUMP 8.4.112., must not be placed in the same landfill cell. C.72. Special requirements for liquid wastes: 1. Bulk or non--containerized liquid waste or waste containing free liquids must not be placed into a landfill, unless: a. The landfill has a liner which is chemically and physically resistent to the added liquid, and a functioning leachate collection and removing system with a capacity to remove all leachate produced; or b. Before disposal, the liquid waste or waste containing free liquids is treated or stabilized, chemically or physically (e.g., by mixing with an absorbent solid), so tht free liquids are no longer present. 2* A container holding liquid waste or waste containing free liquids must mot be placed in a landfill, unless: a. The container is designed to hold liquids or free liquids for a use other than storage, such as a battery or capacitor; or b. The container is very small, such as an ampule. 178 00003155? A C*73. Special requirements for containers: 1. An empty container must be crushed flat, shredded, or similarly reduced in volume before it is buried beneath the su? face of a landfill. INCINERATORS C.74. Applicability: 1. These requirements apply to owners and operators of facilities that treat hazardous waste in incinerators. C.75. General operating requirements: 1. Before adding hazardous waste, the owner or operator must bring his incinerator to steady state (normal) conditions of operation -- including steady state operating temperature and air flow -- using auxiliary fuel or other means. C.76. Haste analysis: 1. In addition to the waste analyses required by the HWMP as discussed in C.2., the owner or operator must sufficiently analyze any waste which he has not previously burned in his incinerator to enable him to establish steady state (normal) operating conditions (including waste and auxiliary fuel feed and air flow) and to determine the type of pollutants which might be emitted. At a minimum, the analysis must determine: a. Heating value of the waste; b. Halogen content and sulfur content in the waste; and c. Concentrations in the waste of lead and mercury, unless the owner or operator has written, documented data that show that the element is not present. C.77. Monitoring and Inspections: 1. The owner or operator must conduct, as a minimum, the following monitoring and inspections when incinerating hazardous wastes: a. Existing lnstuments which relate to combustion emission control must be monitored at leaat every 13 minutes. Appropriate corrections to maintain steady state combustion conditions must be made immediately either automatically or by the operator. Instruments which relate to combustion and emission control would normally include those measuring fuel feed, air flow, incinerator temperature, scrubber flow, scrubber pH, and relevant level controls. b. The stack plume (emissions) must be observed visually at least hourly for normal appearance (color and opacity). The operator must immediately make any indicated corrections necessary to return visible emissions to their normal appearance. c. The complete Incinerator and associated equipment (pumps, valves, conveyors, pipes, etc.) must be Inspected at least dally for leaks, spills, and fugitive emissions, and all emergency shutdown controls and system alarms must be checked to assure proper operations. C.78. Closure: 1. At closure, the owner or operator must remove all hazardous waste and : i v\ 179 CCR 000037560 i hazardous waste residues (including but not limited to ash* scrubber waters, and scrubber sludges) from the incinerator* THERMAL TREATMENT C.79. Applicability: 1. These requirements apply to owners and operators of facilities that thermally treat hazardous waste in devices other than incinerators* C*80* General operating requirements: 1* Before adding hazardous waste* the owner or operator must bring his thermal treatment process to steady state (normal) conditions of operation -- including steady state operating temperature -- using auxiliary fuel or other means* unless the process is a non-continuous (batch) thermal treatment process which requires a complete thermal cycle to treat a discrete quantity of hazardous waste* C*81. Waste analysis: 1* In addition to the waste analysis required by the HWMP as discuss d in C.2., the owner or operator must sufficiently analyze any waste which he has not previously treated in his thermal process to enable him to establish steady state (normal) or other appropriate (for a non-continuous process) operating conditions (including waste and auxiliary fuel feed) and to determine the type of pollutants which might be emitted* At a minimum* the analysis must determine: a. Heating value of the waste; b. Halogen content and sulfur content in the waste; and c* Concentrations in the waste of lead and mercury, unless the owner or operator has written* documented data that show that the element is not present. C.82. Monitoring and Inspections: 1. The owner or operator must conduct, as a minimum, the following monitoring and inspections when thermally treating hazardous waste: a. Existing instruments which relate to temperature and emission control (if an emission control device is present) mist be monitored at least every 15 minutes* Appropriate corrections to maintain steady state or other appropriate thermal treatment conditions must be made immediately either automatically or by the operator. Instruments which relate to temperature and emission control would normally include those measuring waste feed, auxiliary fuel feed, treatment process temperature, and relevant process flow and level controls. b. The stack plume (emissions), where present, must be observed visually at least hourly for normal appearance (color and opacity). The operator must immediately make any indicated--- operating corrections necessary to return any visible emissions to their normal appearance. c. The complete thermal treatment process and associated equipment (pumps, valves, conveyors * pipes, etc) must be inspected at ~ least dally for leaks, spills, and fugitive emissions, and all emergency shutdown controls and system alarms must be checked to assure proper operation. C.83. Closure: 180 tc* 1. Ac closure, the owner or operator oust remove ell hazardous waste and hazardous waste residues (Including, but not limited to, ash) from the thermal treatment process or equipment* C.84. Open burning; waste explosives: l* Open burning of hazardous waste is prohibited except for the open burning and detonation of waste explosives* Waste explosives include waste which has the potential to detonate and bulk militaryt propellants which cannot safely be disposed of through other modes of treatment* Detonation is an explosion in which chemical transformation passes through the material faster than the speed of sound (0.33 kilometers/second at sea level). Owners or operators choosing to open bum or detonate waste explosives must do so in accordance with a table of minimum distances from the property of others, as presented in 40 CFR Fart 265.382. CHEMICAL, PHYSICAL, AND BIOLOGICAL TREATMENT: C.85. Applicability: 1* These requirements apply to owners and operators of facilities which treat hazardous wastes by chemical, physical, or biological methods in other than tanks, surface impoundments, and land treatment facilities C.86* General operating requirements: 1. Chemical, physical, or biological treatment of hazardous waste must not allow the occurrence of any events harmful to human health or the environment, including extreme heat, fire, explosion, release of toxic gases or other injurious substances, or damage to containment equipment or facilities. 2. Hazardouswastes or treatment reagents must not be placed in the treatment process or equipment if they could cause the treatment process or equipment to rupture, leak, corrode, or otherwise fail before the end of its intended life. 3* Where hazarous waste is continuously fed into a treatment process or equipment, the process or equipment must be equipped with a means to stop this inflow (a.g., a waste feed cut-off system or by-pass system to a standby containment device). C.87. Waste analysis and trial nests: 1. In addition to the waste analysis plan and analyses required under the HUMP and discussed under C.2., the requirements of HWMF 8.4.9A must be met whenever a new and substantially different waste is to be treated at a facility, or a new treatment process is to be employed. C.88. Inspections: 1. The owner or operator of a treatment facility must Inspect, where present: a* Discharge control and safety equipment (e.g., waste feed cut-off systems, by-pass systems, drainage systems, and pressure relief systems) at least once each operating day, to ensure that it is in good working order; b. Data gathered from monitoring equipment (e.g., pressure and temperature gauges), at least once each operating day, to ensure that the treatment process or equipment is being operated CCR 000037562 according, to its design; c. The construction materials of the treat&ant process or equipmen , at least weekly, to detect corrosion or'leeicing of fixtures or seams; and d. The construction materials of, and the area immediately surrounding, discharge confinement structures (e.g., dikes), at least weekly, to detect erosion or obvious signs of leakage (e.g., wet spots or dead vegetation)* C.89. Closure: 1* At closure, all hazardous waste and hazardous waste residues must be removed from treatment processes or equipment, discharge control equipment, and discharge confinement structures. C.90* Special requirements for lgnitable or reactive waste: 1. lgnitable or reactive waste oust not be placed in a treatment process or equipment unless: a* The waste is treated, rendered, or mixed before or immediately after placement in the treatment process or equipment so that (1) the resulting waste, mixture, or dissolution of material no longer meets the definition of lgnitable or reactive waste under the HWMP Appendix A, Category III A and C*, and (2) no physical or chemical effects (e.g*, explosion or release of toxic gases) are allowed which could be harmful to human health, the environment, or the integrity of the containment systems and equipment C.91. Special requirements for incompatible wastes: 1* Incompatible wastes and materials may not be placed in the same treatment process or equipment, unless that process or equipment is designed and is capable of safe handling of the mixture* 2* Hazardous waste must not be placed in unwashed treatment equipment which previously held an incompatible waste or material. / SECURITY C.92. General Requirements for Facilities: 1. Pursuant to HWMP 8*4.1, each treatment, storage and disposal site must provide security and control of access as follows, unless exemption from these requirements in whole or in part can be demonstrated in accordance with HWMP 8-4.1G on the basis that lesser requirements will provide adequate safety and protection: a. Perimeter barrier, which shall enclose the entire hazardous waste site and shall have the capability to deny unauthorized Ingress or egress, except by willful entry, and prevent entry by domestic livestock; b. Entry facilities, including: (1) Gate at each entry point equlped with secure locking device; (2) Gate house for guard, or electromechanical equipment permitting controlled access; and (3) Floodlighting -- each entry shall be well lighted to insure safety and security at night; and (4) Safety control devices as may be required under HWMP 8.4.IE. 2. Other security measures and procedures as may be required under HWMP 182 CCR 000037563