Document dewdwV11BmEpvz9ng651qVq0
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* 3M General Offices
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3M
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June 16, 2000-
Comppaann,y Sanitii zed
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DCihraerclteosr,AuCehrem(iEc4a0l3CCo)ntrol Division
.# 501000000 &
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U40S1MEn.viSrtorenemte,nStaWl Protection Agency
.
Washington, DC
FYIL- 0600-13785
Dear Mr. Auer: Re: Phase-out Plan for POSF-Based Products OR 16]N.A L
-
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*
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INTRODUCTION AND OVERVIEW
-
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-
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envirgnmental risk
.
FIinrsdte,ciwdeingwihsohwttoofuilmfipllleomuerntcoimtsmiphtamseen-touttodaecccisoimopnl,is3hMahsausbsbteaentniagluipdheadseb-youttwoofpobrjoedcuticvteis.on as
Page2 June 16,2000
feoxrpeadnitoiroduesrllyy atsrapnrsaicttiiocnabtloe.altSeerncaotned,prwodeucwtasntbytothmeinbuismiinzeessmasreckteotrpslatchaetddiespruepntdioonnand provide
-
poeurrflPuOoSrFo-abctaasneydl pcrheomdiuscttrsieasr.e Buasleadnicninagwtihdeeseracnognesoidferaaptpiloincsatiisoenxstwrietmheliympcahcatlsleonnginnugmbeercoauusse
segmentsof the economy. terminationofavailability
Where our products meet critical customer could cause major disruption to commerce
needs, an abrupt or compromise vital
health,
c
safety or environmental serious fires
interests
such
as
the
protection
of
people
and
property
threatened
by
Wcoensiadreerastililonrse.ceHiovwiengvearn,d tehviasllueatttiernganthdeaitntfaocrhmmaetnitosnpnreocveisdsearoyurtobebsatlacnucrreetnhteusnedceormsptalnedxing of
-
Ahtotwacwhemewnitll1i, m3pMl'esmepnltanouwirllphraesseul-touitnaplsaunbsftoarntPiOaSlFs-cbaalsee-ddopwrnodiunctpsr.odAusctiilolnusatrnadteidmipnort
vneocleusmseasryafttherrotuhgeh etnhdeoffitrshtequyaeratr.eroWfe2f0o0r1esiene otrhdatersitgonmifeiectanctulsetvoemlserofrepqruoidruecmteinotsn.maLiymibteed
finurAtthteracphrmoednuctt2i,onp,roadtuscitginoinfiocfanPtOlySFl-odweerrilveevdelsm,atweirlilaclosnwtiilnluebethrreoduugchedthien e2n0d01ofto20b0e2.tweAesnsh10own
-
2a0n0d2.303pMeracnetnitcoifpatthese tphraotjemcatneudf2ac0t0u0rebaasneldiniempaonrdtowfoauflfdecdteecdlipnreotdouc4tspewriclelntcoeafsteheentbiarseellyinate tihne,
end of2002. Thereafter, 3M will continue to `manufactured products to specific customers
distribute
small
volumesofcertain
previously
.
Apfrtoeprostehed f"icrrsittiqcuaalrtuesre"ofap2p0l0i1c,at3ioMnsmfaonrufPaOcStFu-rbiansgecdapparcoidtuycwtisllbybeoucromcmuisttotmeedrsenotriroetlhyetro3ceMrtain
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comment on critical customers and other
use decisions for interested parties
POSF-based can provide
chemistries in input on 3M's
the very near future phase-out plan.
so
that
3M
s3uMbmiissdseivoenlsobpeifnogresucbosmtmiteurtceisalfiozracteirotna.inIpriosdeuscstesnttihaalttwhialtlErPeqAuiarnedPr3eMmacnounfdaucctturaen Niomtmiecdeia(tPe.MN)
-
cdiuasltoogmueersononthseusbestsiutbusttiiotnutoeptcihoenmsisattritehse seaorltiheasttwpeossciabnleprdoavtiedewiitnhftohremeadimgoufidsawnictechtoinogurthese
customers to acceptable alternates with minimum delay.
`The remainderofthis letter addresses five aspects of 3M's phase-out plan
+ Scopeofthe plan
+ Details of production scale-down
Proposed critical use applications
-
# Proposed substitutes for POSF-based products # 3M stewardship actions during the phase-out period
Page 3 June 16, 2000 SCOPE OF 3M'S PLAN
=
aGlcoobnasilsItemnptacftrs.am3eMw'osrkphtaosper-ooduutcptliaonn aisngdloubsaelaicntisvciotpees. wIinthdienvealnodpionutgstihdee ptlhaen,USw.e3hMave applied
rpreocdougcntiszeosutthsaitdeEtPhAe UdSo,esbuntotwheavweanjutritshdeiActgieonncoyvetro mbaeniunffaocrtmuerde aabnoduutsoeuorfpPhaOsSeF--obuatsaecdtions on
a worldwide basis.
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-
manufacturing they evolve
resources
ficiently.
We
will
keep
EPA
informed
of our
manufacturing
plans
as
Sptaactkuasgionfg,FDmeAdiRceagludleavtiecdesPraondducottsh.erTahpepl3iMcatpihoansser-eoguutlaptleadn
includes products used by the Food and Drug
in
food
-
rAedgmuilnaitsetdraatpipolinc(aFtiDoAn)s.anFodraspsuorcpioasteesdopfrocdoumcptairoinsovno,luwmeesh.av3eMprwiolvlidbeedianfborremaiknogutFoDfAFoDfAo-ur
phase-out plans for products within that agency's jurisdiction.
IdinscclounstiionnuoefmAadnduiftaicotnuarleCohfempirsotdruicetss.bFasoeldloowninCg-o6uarnidniCti-a1l0anhnoomuonlcoegmsenotf,PO3SMF.haWs edemciaddeed tthois
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relatively small volumes and are highlighted in the attachments to this letter
DETAILS OF PRODUCTION SCALE-DOWN
BinavseenltionreieIdnvalelntPoOrSyFo-fbaAsfefedctperoddPurcotdsucctusr.renTtolyesmtaanbulifsahctaubraesdelbiynethfeorcpohmapsaen-yo.utTdheicsisiinovnesn,to3rMy is
pcraetseegnotreydainndAtihteanchlimsetsntin5d.ivi[dAutaalcphrmoednutcts iisn CeBacLh]caTtheegoArtytabcyh3meMntprgordouucptsctohdees,e CprAoSduNcutsmbbeyru,se
-
tchheemAitctaalchnmaemnet parnodvtihdeespeprrcoejnecttaegdeoYfeafrlu2o0r0o0chpermoidcuacltsi(onFCtso)taplsrefsoernteaicnhthiendpirvoidduucatl. pIrnodaudcdittiaonnd,
use category.
-
oSfin1c9e9s9ixtomeosnttihmsatreepmraoidnucintiYoenavro2l0u0m0e,s3fMor utsheedreumpadiantdeedrboufsitnheesyseafro.reTcahsetssepersetpiamraetdedatvtohleuemneds
oatrheeprrceosmepnotendenftosr)b.otThhetheFCFCpopuonrdtiaognesofretpherepsreondtutcottaalnsdoltihdese(nitnicrleupdrinogdurcetacftoarnmtuslcatoimobnin(eFdC wpiltuhs
the FC starting material) and do not represent the POSF molecule itself.
.
cPartoedguocrtieisonfoDruPrOiSnFg-tbhaesFeidrsptroQduuacrttsearroefp2a0p0e1r. aAntd tphaeckpargesienngtctoiamtei,ngtsheahnidgtheexstitl-ev,olleuamteheurseand
carpet protectors. While it is 3M's desire substantially to discontinue manufacture of these
Paged June 16, 2000
cpursotdoumcetrss.byTtoheacencdoomfmothdeatyeeatrh,etsheisneoebdjse,ct3ivMe pmluasnts bteo ablalloawncceudstwoitmhertshetonpeleadcseoffin3aMl'osrders by
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230M00wialnldlawcilklpnroedeudcttoiocnonctaipnauceitpyrotodufcutlilyonsadtuirsifyngcuthsetofmiresrt qrueaqrutierreomfen2t0s01d.urTihnegretfhoerree,moauirndpehrasoef-
-
out plan through
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carpet
protectors
ATtatkaicnhgmeinnttosa1ccaonudnt2 piolslussitbrlaeteptrhoedudcotwionnwaorfdthterseendpriondpurcotdculcatsisoens odfurPiOnSgFt-hbeafsiersdt qmuaatretreiraolsf 2001,
-
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vbaoslisu.meIsn 2in00220,01glosbhaolulpdrobdeuc9t.i8opnerscheonutldtode3c0l.i2npeetroce4n.5topfertcheentporfotjehcete2d020000b0asbealsienlei,newiotnhangolobal
production currently anticipated in 2003.
dPirfofdeurecnttiornaowfmSattaerrtiailnsgaMnadteirnitaelrsmeadniadtIenst(eirnmcelduidaitnegs.PO3SMFhiatsseplfr)evuisoeudsliyn tihdeenmtiafniuefdatcotuErPeAofthe
cPhOeSmFi-cbaalsseudndperrodtuhcets.19398MTwSaCsAreIqnuviernetdotroy
provide Update
1997 Rule
production volumes (IUR). Attachment 6
for severalofthese provides these IUR
production Attachment
figures, shows
corrected 1997 U.S.
to reflect a production
rveocleunmterseafnoarlyPsiOsSooff149,9078p3r,o0d0u0ctIibso.n
data. For
The year
2000,
a
s1u.b5m%isdseicornesasoenlisyainntcilcuidpeatUe.dS.frpormodtuhacttinounmbaenrd,imwphoircthatwioonu,lda bfuert4h,e0r22ad,j0u0s0tImbes.ntBeiscanueesdeetdhetoUR.
reflect POSF estimate that
production at 3M's Antwerp facility. total worldwide POSF production in
Afier accounting for Antwerp 2000 will be 8,100,000 Ibs.
operations,
we
dPercoldiuncetisoignnioffisctaanrttliynginma2t0e0r1iaalnsdan2d00i2ntbeercmaeudsieaotfetshfoer sPuObSstFa-nbtiaaslesdcparloed-udcotwsnwiinlprnoedceuscstairoinloyfthe
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-
products will be in
which 3M a position
continues to to determine
manufacture. Once the anticipated production
mixof levels
these products is finalized, for the corresponding raw
3M
materials. 3M for purposesof
waillSaNsUseRmbclonetrthoilsliinngfomramnautfiaocntuifreEPofAPbOeSlFie-vbeassietdiscnheemeidsetdriteso.set
production
caps
PROPOSED CRITICAL USE APPLICATIONS
PcornotciensusefoafrteCrritthiecaelndUsoef 2Se0l0e0c,ti3onM. sTcoreiedneendtiiftys cernittiircealpprroodduuccttliunseeussfionrgwfhoiucrhcrpirtoedriuaction would
.
1. 2.
Does Does
the the
product product
provide perform
environmental, health a unique or important
or safety function
benefits? for which
there
is
no
tneecehdneidcatlolyquaaclciefpytaobrlpersouvbestoiuttutseuacvhaialsaubblsetiotruftoer? which additional time will be
Page 5 June 16,2000
3. `Igsouvseeronfmetnhtealpraocdtiuvcittisepse(cisfuicehdabsynaatfieodnearlaldeofrenssteat)ebaegeafnfceyctoerdiwfotuhled product were
-
no longer available?
4.
Does 2001
3M and
have binding beyond?
contractual
commitments
to
customers
which
extend
into
-
dPeroedmuecdtssumieteatbilengfoornperoordumcotrioeonfftohlelsoweicnrgittehreiafiwrestrqeuaarstseirgonfed2t0o01the critical use category and
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-
rationale for information
bcyonptrionvuieddinpgroCdAucStinounmbbeeryso,ndchYeemairca2l00c0o.mpAotstiatcihomnesntan4d
complements this projected volumes
for
these
dcreittaiiclaelduusseecpatreogfoirlieess.forThPeOStFw-obaAstetadcphrmoednutcstsshporuolvdidbeedrienvi3eMw'esdMian yco2n6j,un1c9t9io9nwwhiitthe tphaepemrore
ennatmitelsedthFaltuaoprpoecahremiincAatltaUcshe,meDnitst4riabruettihonosaentdhaRtealreeassepeOcivfeircvailelyw.tiEedPtAo s3hMo'usldprnooptoestehdatcrtihteicCalAS
-
uses. Critical uses that are identified subsequent limited productionof chemicals not shown in the
to the CAS
dateof this submission names column
may
require
jNuedegdmfeonrtsFurreftlheecrteIdnipnuAttotnacChrmietinctal3 Uasned S+elaercetiporne.li1mtiinsariympaonrdtawnetrteobkaeseepdionnmiinnfdortmhaattitohne
currently available to 3M employees regarding the downstream applications in which POSF-
pbraosceedsspersodoufctitss acruestusoemde.rs3aMndn,ectehsesraerfiolrye,hcaasninnoctommpalkeetedekfninoiwtliveedgjeuodfgtmhenetsenadb-ouustetphreoadvuacitlsabainlidty
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-
pcrliatnicwalituhseEPsAel.ectFioorn.thTisorpeearsmoni,t ousuerrsscorfeePnOiSnFg-pbraosceesdsphraosduncottsfoulrloytchaeprtiunrteedrecsutsedtopmaertrievsietwos on
address this subject, we would aspectsof3M's phase-out plan
encourage EPA to solicit public at the carliest possible date.
comment
on
the
critical
use:
-
oSfurtfhaecptraonptoPsreodpecrrittiiecsaol fusPeOpSrFod-uBcatsseiddeMnattiefrieidalbsy. 3AMs Aatrteaicnhtmheenitnd3usitllruisatlrastuersf,atchteangtrecaattemgaojroyr,ity
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cmoondsetrsuocftioonpe,raetlieocnt.ronFiicr,stoiils athnedirotabhielritmyatrokeltowseergmseunrtfsa.ceTtheenysipornoovfildiequviadlsueantdh/roorugsholitdws.o bSaesciocnd
-
itsyptihceailrlaybialcihtiyetvoedemautlvseirfyy lanodw cdiosnpceernsteraatihoonsst woiftmhaitneraiaflosr.muTlhaetsieonsudrufeacttoantthechsaurrafcatcetraisnttiscsabairliety
to migrate to interfaces and surfaces
t`Thheeussceioenftiffliucorloisteurraftaucrteadnotscu(mpeernftlsuotrhoa-tctohnetalionwiensgtssuurfrafcatcaenttse)n.siTohnissaitstabiencaabulseeartehedeurniivqeude from
Prehdyuscitcioocnhecmapiacbaillicthyartahcatneroitshteircssoufrfpaecrtfalnutso,risnuacthedascosimlpiocounnedosr
give them greater hydrocarbon oils.
surface tension Accordingly,
Page 6 June 16, 2000 wothhielres.flFuoorrotshuersfeacatppalnitcsamtiaoynsn,o3t Mbeisespsreontpioaslining stoomceonatpipnluiecaptrioodnus,cttihoenytahrreouirgrhep2l0a0c2eawbhleilien 3mMany works with its customers to switch to CBI)
While Attachments 3 and 4 list critical industrial applications known to 3M at this time, we
epxhpaescet-otuhtatamnnooruencwielmlenbte.idTeontiafdiderdesass 3thMi'ssposcsuisbtiloimteyr, bwaeseurfgoecutsheats oannythSeNiUmpRlidceavteilonospoefd boyurEPA
-
a3lMloowraidtdsictuisotnoamlerisnd.usTtroiapllaucseeslidmuirtisnogn2s0u0c1h-2us0e0s2, itfhseuSchNuUsResmairgehtdeitnecrlmuidneeadntaonbneuaclrictiacpalobny
total production of POSF-based products for industrial applications during 2001 and 2002
Assuming that production does not exceed this cap, 3M could market these products for
-
additional uses first identified after December EPA confirming that the use is "critical"
31,
2000if
3M
or
its
customer
files
a
notice
with
INTRODUCTION OF SUBSTITUTES FOR POSF-BASED PRODUCTS
Atthe current time, 3M is planning to introduce [CBI
3M STEWARDSHIP ACTIONS DURING THE PHASE-OUT PERIOD
E3Mn'vsirDoencmaetnutraflacCiolnittyrohlasv.e bSienecner1e9d9u7c,edmabnyufSaOcpteurrcienngtrfeolreawsaessotfepwaetrefrludoirsocohcatragnesylancdhe4m0ispterriceesnatt
for air emissions. During the phase out ofPOSF-based products, 3M will continue to implement
its ongoing emission reduction programs. These include source reduction and recycle, off-site
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Designated wastewater streams are permitted hazardous waste thermal
being collected and treatment facilities.
transported off-site for disposal at These practices will continue during
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streams. Systems have been installed and are operating in both Antwerp, Belgium and Decatur,
Alabama. Carbon adsorption has been shown to be effective in the removal of POSF and POSE
based compounds.
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and our
human health effects. We plan to share new data when it scientific dialogue with EPA on the interpretation of key
sbteudcioesm.es
available
and
to
continue
Page 7 June 16, 2000
We look forward to meeting with you and your staff on June 20 to discuss our phase-outplan and obtain EPA's feedback.
`We appreciate EPA's cooperation on this matter.
Best regards,
. Ulta bo Wappen
William A. Weppner, Ph.D.
Director
Environmental, Health, Safety & Regulatory
Speciality Material Markets Group
Affairs
3M Center, Bldg. 236-1B-10
St. Paul, MN 55144
Pounds POSF Containing Chemi
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Summary of the Phase-Out Plan for the production of POSF-
-
Containing Chemistry
Attachment 2
"p2Tr0ho0id1suscautnimdomn2a0l0re2yv.eplrsCerisientnisctuasblstuoctsqaeulseenrstetqipumliaanitenydgeapprrrsoo.dduuTccthtiieoonsnufimonrm2a200r001y0,snwodhi2pcr0he0s2iesnautrsseepfmrucolljaeucdtaeeddbaopsnreolAdituntceatcifoohrnmeconovtmep3ar.rfionrg 20otal 00 B3aMselPiOSnEe Chemistry manufactured '2Y0200000" ppeerrfflluuoorrooooccttaannyy!]ccoonnttaaiinniinnggcchheemmiisstiyr-yp-opuounnddsspprroodduucecdedinglUoSb:ally: 69,595517,500000
`I 'O1Yt92h9e09n r00peprf efrlfulo curooroor occtftaom anrnyyB!caa oscneotlnat itinaneiicni noignmcgpo hacerhmiein smsoitnsyt-yp-opuonudnsdsimupsoerdtefdornFtDAtahepUSp:l2i39c.a9a0r0et3,i53o2,n00s0
-
Yz922:0o0800%n1110ppee3rr0ff.li2ucoo%rr.aooorccettsaapnnecyyt||ivcceoolnnytt,aaioifnn0iinn0gg c0chheebmmaiissstiiryny--.ppoouuSnneddesscaoutseebgdeorfpiorerosFdbuDclAeodawpgplfloobiraclUaltSyi:opn9rso7wd9iul0cl0tbi0oent3op030u.,m0b00e00r.9.,7o0r0
-
yY2a0o0i2 perfluorooctanyl containing baseline. Se categories below for
cUhSempirsodtuyc-tpioounnndusmtboebres produced
globally:
#47900
or
4.5%of
2000
2002 perfluorooctany! containing chemistry-pounds used for FDA applications wil be zero.
-
SPOapReTrE&D BPYacCkAagTiEnGg ORYCategos
G21l10o00b1a0tlope3r/f5l1u/o01ropoecrftlaunorcooonctatianniyn|gcocnhteamiinsitnrgy-cphoeumnvdissiprryo-dpuocuendd:s obe produced: 3e2r9o72fo00$24,300 Anticipated compte phase-out by 4/101
Y2S0O0n0lpyefluorooctany! containing chemisty-pounds produced: 10110 313101 perfluorooctany| containing chemisiey-pounds
o
be
produced:
2z6er7o0t0o 077700
_
Estimation based on Y2000 forcast rom customers before phase-out plan announcement
g*Thoiwsne0sttihmeaPteOSinFclmuodleesctuoltael solid poundsoffluorochemical containing compound and hasnotbeen broken
>prIomjpeoctritosnasrfeonro2t0i0n0clauedendotina2va0i0la0blper,oduction totals. 3M is presenting 1999 import figures because
.
Page 102
CTTaehrxipsteictla.et,FeagobLrreyiactinh&celrUup,dheolsastAneprdyp,aCrealarn&pdeLCteoaTmthmreeerr,actAifamtleerCnmatarreCk(eactto(ensgsuoomrlaeydrapanrdt opfrocfoemssmieornacli)alFaabrrireaPryotpeacctkoargses), 'G1Yl12o10b001a0l1p0er3f7l3u1/o0r1oocptearnfyl!uocroonotcatianniynlgccohnteamiinsiinyg-cphoeumnidssirpyr-opdouucendd:s tobe produced: 408120515,02006,400 Anticipated complete phase-out by 4/1/01
u21s10/o00n10l0pyer3f/l3u1/o0r1oopctearnfyu!orcoooncttaainnyilngccohnteamiinsiinrgy-cphoeumnidsstrpyr-opdoucuendd:s tobeproduced: 20.4t1o96.0340.0800
-
AITdhndidisutcsvaettsre.igaoInrlsyeSciutnirccfliuaddecest,satnhInttseE,rxmteAedrdinadatiletss,iavalenssdoMfaiCnnoidantCginog&ast,OiEinlgeacsntdrCoIpanlttaeterignnaoglr&3yMEiAcphpilnigcaSturifoancstants, Household
GY'lY2o200b00a10lppeerrfflluuoorrooooccttaannyy!l ccoonnttaaiinniinngg cchheemmiissitryy--ppoouunnddss tporboedupcreod:duced: 1580810.770000
~
2002 perfluorooctanyl containing chemisiry-pounds o be produced: 432.600
YYu22s00o0010nyppeerfflluuoorrooooccttaannyy]! ccoonnttaaiinniinngg cchhemeismtyi-spoiunrdsyfpo-rbopedupocreuodd:nucdeds: 1285088.040000
Y2002 perfluorooctany! containing chemisiry-pounds to be produced: a8.400
-
Fire Fighting Global
Foams
Catego
'''YY222000000120 pppeeerrrfflluuuooorrrooooooccctttaaannyny]!y| cccooonnntttaaaiiinnniiinnngggccchhheeemmmiiissstttyyy---pppooouuunnndddsss pttorobbdeeuppcrreoo:dduucceedd::
39373.630000 15300
-
'uYs20o0n0 yperfluorooctany containing chemisty-pounds produce: Y2001 perfluorooctanyl containing chemisty-pounds to be produce:
25063..550000
2002 perfluorooctany| containing chemistry-pounds o be produced.
1530
-
Page 202
.
Atachment6
- LO]POSF and Core Reactant Product Volumes LT]
[1PR9re9op7doUurSc'tteiidnao'sn [1P9r8o7duucstion
-
[c-aOscNtaamneesory Tocris, 11223344 55867755
S19u9b8mi1sUsRion 2[00b0raeowsnoMerakdy
tos)
ts)
T 307357 [|nFeOpttaandcescadtiooe rnoa.mds, 7122334 4586r 8TTAHE e 2402000 s4o08m3.a00
756818 |heptadcatuoro:
- 2oors17 JGelayncine. Ne-ertyrNVrepiadecauerSaaloondy poss1 um
--------
e 151.602 |[nFeOptcaadencsaatiluoorrea:mds, Ne ay 122334355667785 e
- M [FpOlCaidasncasaaftuoe onraomNidms. 11223334558e 6 TT8HE- e
1691902 J|eTOnCelrapnteesaudtoencara(dte2,uWoraoltyyaroyet1iny2233 4455687 TERE
---------- 2.145.000)
- e [26448057 _T_O|cnaenpetsaidocraalmNod-rsez. 1n1yd2io2xye3in3y 4m4e58t68.T TTARE- 1.861.000
023825
[Preopeaacnae2 letyi(heptadecatuoroocyysutonylaminclethy ster
ee 7678
. d 25268773 Z(Pvreoppteangceicca3tu5o.ro7octye )sutonylmethyiaminolehy ester e 777.789
e [376-147 [lEiPornoyple(nnceipctasddec.atZvmoroaocTtyis2ifonylaminojeT tny ester 53507]
1465024m 9 |2[P(rhoeppleandceciactr isuaodr.ooZcty)seuttony2metnylaminoletny
To
ester
an327
1]a
le23.50.7 e pHexanese uony| tuoride. 1.122.33445.5666 idocatuore |
0160
|
.
Bo7.517 11:1e2c2a3:n3e4s4u5o5r6y6.a7.o7r8..899.10.10,10 heneicosatuoro.
20.71
.
osrre2000
Paget