Document dbpZoOMnNgDgavo9d31LKqMB

MONSANTO COMPANY ORGANIC CHEMICALS DIVISION W. G. KRUMMRICH PLANT MONSANTO, ILLINOIS STANDARD MANUFACTURING PROCESS FOR PYDRAUL A-200 DEPARTMENT B-246 Supersedes: Process Description for the Manufacture of Pydraul A-200 in Department >246. dated January 7, 1962. Prepared by: /. it. &L L. G. Cole PTS Engineer Approved by: ET E. Martin Prod. Supervisor CONFIDENTIAL INFORMATION - This process is the property of Monsanto Company, and Hie recipient Is responsible for Its safekeeping. It contains confidential information of Monsanto Company which must not be reproduced, revealed to unauthorized persons or sent outside the Company without proper authorization. Either retain in a secure file or return to the Standards Department. MONSANTO COMPANY MONSANTO, ILLINOIS SAFETY REVIEW COMMITTEE Messrs: P. E. Heisler E. E. Martin W. D. Robineon - JFQ D. B. Hosmer - GO Process Holders Date: 9-28-64 Tentative Amendment No. __ A Tentative Amendment No. A to the Process Description for the Manufacture of PYDRAUL A-200 (Issued 8-4-64) OBJECTIVE This amendment recommends a change in one of the components of the additive package to improve the odor and functionality of Pydraul A-200. PRESENT PROCEDURE Santolube 393 (0.5%) a zinc dialkyl dithiophosphate, is added to an Aroclor-tricresylphosphate mixture containing Santolube 70 (0.5%) as well as a small amount of Dow Corning 200 defoamer (50 ppm). Most of the finished product is dyed a distinctive blue color with blue and black dye. PROPOSED PROCEDURE Substitute 0.5% (cwt.) Lubrizol 1360, a competitor's sine dialkyl dithiophosphate, for Santolube 393 in the formulation of the fluid. The proportions of the other components will remain the same. The following table lists the revised raw material requirements for Pydraul A-200. Aroclor 1242 33% (vol.) Aroclor 1248 67% (vol.) Lubrizol 1360 0. 5% (wt. Santolube 70 0. 5% (wt. ) Dow Corning Fluid 200 50 ppm HONS 044679 Tentative Amendment No. A (Cont'd.) PROPOSED PROCEDURE (Cont'd,) Most of the final product is dyed to a standard Pydraul color (blue) which does not change any other property. JUSTIFICATION Lubrizol 1360, having a toxicity rating equal to Santolube 393, will eliminate general customers' complaints of a sulfur odor in our current Pydraul A-200 and will increase the thermal stability of the fluid. Increased thermal stability in Lubrizol 1360 is accomplished by the use of primary alcohols in the preparation of the additive. The improved odor control associated with Lubrizol 1360 is well known throughout the industry. D, fli Haswer u> t *&*+**/% L. R. Stark Date: 9*28-64 emc HONS 044680 Copy DISTRIBUTION SHEET 1.. TECHNICAL INFORMATION CENTER, ST. LOUIS RESEARCH .2 TECHNICAL INFORMATION CENTER, ST. LOUIS RESEARCH 3. SECURITY FILE (RECORDS CENTER, ST. LOUIS GENERAL OFFICES) 4. DIRECTOR OF MANUFACTU RING/TECHNICAL PROD . MGR. ORGANIC DIV. 5. PROD. GEN. SUPT. /PROD. SUPERVISOR - W. G. K. 6. PLANT TECHNICAL SERVICES 7. EXTRA 8. EXTRA 9. EXTRA - 10. EXTRA MONS 044681 TABLE OF CONTENTS Page I. Synopsis of Process............................................................................................... 1 II. Process Flow Sheet .............................................................................................. z III. Process in Detail . ,.......................................................................................... 3.4 IV. Comments on Process........................................................................................ 5 Appendix A - Equipment List...................................................................... 6 Appendix B - Finished Goodsand Raw Material Specifications.................................................... 7 Appendix C- Physical Constants............................................................. 3 - 11 Appendix D- Utilities.......................................................................................... Appendix E - Personnel................................................................................... 1Z - 13 14-15 Appendix F - Packaging and Shipping.................................................... 16-17 Appendix G - Material Balance................................................................... IQ Appendix H - Atmospheric and Stream Discharge and Waste Disposal.............................................................. 19 Appendix I - Process Control Procedures.......................................... 20 Appendix J - Safety and Toxicity Date and Accident Reports.................................................................... 21 - Z3 Appendix K - Background.............................................................................. 24 Appendix L - Time Cycles.............................................................................. 25 Appendix M - Quality Consideration......................................................... 26-27 Appendix N - Miscellaneous............................................................................. 28-30 MQNS 044682 Dept. B-246 - Process Description 1. PYDRAUL A-200 SECTION I SYNOPSIS OF PROCESS Pydraul A-200 is a tradename used to designate a mixture of Arocior 1242, Aroclor 1248, Santolube 393, Santolube 70, and Dow Corning Fluid 20&. Pydraul A-200 is a fire resistant, industrial hydraulic fluid. The pydraul series of fire resistant fluids include a low viscosity and low temperature fluid, a high viscosity fluid, and a medium viscosity fluid, Pydraul A-200 is a non-viscosity index improved hydraulic fluid. Pydraul A-200 is the member of the Pydraul series manufactured in Department B-246 of the W. G. Krummrich Plant. The proportion of ingredients used to manufacture Pydraul A-200 is listed below: % Aroclor 1242 33% (vol) '% Aroclor 1248 67% (vol) % Santolube 393 0. 5% (wt.) % Santolube 70 0. 5% (wt.) Dow Corning Fluid 200 50 ppm Most of the final product is dyed to a standard Pydraul color (blue) which does not change any other property. HONS 044683 Dept. B-246 - Proctis Description PYDRAUL A- 200 SECTION II FLOW SHEET This section contains a Pydraul A-200 process flow sheet. 2. *QNS 044684 MONS 0 4 4 6 8 5 a raJc2oo2n SAjrroUfBS DRUMS TANK TRVCKS TANK CARS TUM SHUT 910.9b PYDRAUL A-200 DEPT. B-246 7--b* Dept. B-246 - Process Description 3. PYDRAUL A-200 SECTION III PROCESS IN DETAIL, . A BACK GROUND AND BATCH DATA Pydraul A-200 is a tradename used to designate a mixture of Aroclor 1242, Aroclor 1248, Santolube 393, Santolube 70, and Dow Corning fluid 200. The blend is colored with a mixture of Blue A and Azo Black dye. Pydraul A>200 is Monsanto's high Aroclor hydraulic fluid designed as a low cost replacement for Pydraul F-9 Pydraul A-200 was formulated to meet viscosity and lubricating requirements and anti rust characteristics as specified by the Sales Department. The use of Santolube 70 in the Pydraul A-200 blend can cause undersirabl foaming. A concentration of 50 ppm of Dow Corning Fluid (DCF) 200 will inhibit foaming. The raw materials necessary to blend Pydraul A-200 are listed below: Item Aroclor 1242 Aroclor 1248 Santolube 393 Santolube 70 Dow Corning Fluid - 200 Blue A Dye Azo Black Dye 12, 000 gallon Batch 4, 000 Gal. 8, 000 Gal. 700 Lbs. 700 Lbs. 7. 5 Lbs. 326 Gm. 120 Gm. 8, 000 gallon Batch 2,670 Gal. 5.330 Gal. 500 Lbs. 500 Lbs. 5. 0 Lbs. 264 Gm. 80 Gm. B. BLENDING Primary chemical reactions are absent in the production of Pydraul A-200. The only process step in Pydraul A-200 production is the unit operation of blending. Aroclor 1242 and Aroclor 1248 are pumped from storage in department 246 to the # 1 mix tank located in Department B-246. The mixture of Aroclors consists of one part Aroclor 1242 to two parts Aroclor 1248. The mixture of Aroclors is agitated for four hours, and then sampled to measure specific gravity and viscosity. One 16 oz. sample is taken to measure these properties. Small additions of either Aroclor 1242 or Aroclor 1248 are added to alter specific gravity and viscosity to meet specifications if necessary. No steam is applied to the coils of the tank during agitation. Mixing is promoted by heating to 80*C. , but must be allowed to cool to 65 C. or less to fill drums to the proper weight. MONS 044686 Dept. B-246 - Process Description 4. PYDRAUL A-200 SECTION HI PROCESS IN DETAIL B. BLENDING (Cont'd. ) After the period of agitation, Santolube 393 and Santolube 70 are pumped into the #1 mix tank. One half pound each of Santolube 70 and 393 are added for 100 pounds of finished product. The batch is then circulated until the temperature has fallen below 70 C. Santolube 393 imparts good anti-wear properties to the Aroclor mixture. Santolube 70 is a rust inhibitor. Next, Dow Corning Fluid 200 (DCF) is added to the mix - one pound per 2, 000 pounds of product. DCF inhibits foaming caused by Santolube 70. Most of the finished product is dyed a distinctive blue with blue and black dye. The dye does not change any properties other than color. After all ingredients have been added the batch is agitated an additional 4 hours. Three 16 ox. samples are taken from the discharge side of the circu lating pump and analyzed for moisture, specific gravity, viscosity and foam. If the batch meets all specifications (See Appendix B) , the finished Pydraul A-200 is packaged in 5 gallon cans, 55 gallon drums, or loaded in tank cars and tank trucks. Three 16 ox. lot samples are taken from each tank car or tank truck. HONS 044687 Dept. B-246 - Process Description 5. PYDRAUL A-200 SECTION IV COMMENTS ON PROCESS A. RAW MATERIAL YIELDS Raw material yields are about 99% for this blending operation. Small material losses are attributed to samples. The exact amount of raw material usage for a given batch of Pydraul A-200 is not known since slightly different proportions of Aroclors may be needed to meet specific gravity and refractive index specifications. B. CAPACITY The capacity of Department B-246 is about 5 million pounds per year. The supply of Aroclor 1242 and Aroclor 1248 for Pydraul production is limited and thus a controlling factor of Pydraul production. Also, storage facilities are a bottleneck in the production rate. The #1 mix tank has a dual purpose and serves as both a blend tank and storage tank for the final product. C. QUALITY The specifications of Pydraul A-200 are more readily obtained than some of the other Aroclor-base products. The finished product does not have as many properties with rigid specifications as do Pyranols and lnerteens. Some of the critical factors in producing a good quality Pydraul A-200 are as follows: 1. The viscosity of the Aroclor mix must be in specification. 2. The temperature of the Aroclor mix must be reduced to 90*C. before adding the Santolubes to avoid decomposition of the Santolubes. 3. The temperature of the Aroclor-Santolube mix must be reduced to 80*C. before adding the Dow Corning Fluid. MQNS 044688 Dept. B-246 - Proceas Description PYDRAUL A-200 APPENDIX A EQUIPMENT LIST - W. G. KRUMMRICH PLANT 6. Item No, *149 *151 *157 159 160 161 Equipment Name # 3 Storage Pump #4 Storage Pump #7 Storage Pump #1 Mix Tank Pydraul Pump Full Flow Filter Equipment No. 19-0585 66-0853 19-0584 66-1501 19-2077 66-1691 21-0321 23-1288 66-2168 19-1540 66-3133 15-0239 Description Taber Vert. Sub. Pump. Dwg. A-387. Type C-3, 2" x 2", C.I. Body, Length 11'6". Cap. 50 GPM, 60' Static Head, Sp. Gr. 1. 18 at 170#F. Motor is 3 H. P. , 1800 R. P. M. Taber Vert. Submerged Pump Type L-2, 2 1/2" x 2", Length 11*6". Cap. 50 GPM at 40' Stati< Head. Motor is 3 H. P. , 1800 R. P. M. Blackmer Pump. Monel shaft. 2 1/2x2 1/2. Motor is 3 H. P. , 1800 R. P. M. Tank (Nooter), Dwg. D-6455, 14' O.D. x 10' high. 3/8" shell, steel construction. Capacity is 15, 000 gallons. Agitator motor is 7 1/2 H. P. 1750 R. P. M. Taber Hori. , Cent. Pump 304 Stainless Steel, 2" suction, 1 1/2 discharge. Motor is 10 H. P. , 1750 R. P. M. Sweetland Filter. Size #10 RH, 54 leaves, C.I. Body, lined with Nickel. ^Equipment assigned to Department 246 also. HONS 044689 Dept, B-246 - Process Description 7. PYDRAUL A-200 APPENDIX B SPECIFICATIONS - W. G. KRUMMRICH PLANT The following is a list of the raw materials used for the manufacture of Pydraul A-200. Specification Sheets are included for the materials. Material Code Raw Material 82113 31100 81176 81101 81102 20640 20317 Santolube 70 Dow Corning Fluid 200 Santolube 393 Aroclor 1242 Aroclor 1248 Blue A Dye Azo Black Dye The following is a list of the finished products manufactured in Department B-246. Specification Sheets are included for the materials. Product Code Product 81096 Pydraul A-200 HONS 044690 V. 0. KRUMMRICH PLANT MONSANTO CHEMICAL COMPANY RAW MATERIAL SPECIFICATION 82113 UtIMO DON'T*. _ B-246 Nltro Plant SANTOLUBE 70 CH1MICAL FORMULA Mixture MOU wt;--- _______ __ _____________ UPinUII Via OF .AM.L. FMkMLIM Mew|| 1 x lo oz. W.M.Bottle general Tests (Made on request only) progertj Specification Appearance Color, ASTM Dll. Neutralization Number Specific gravity 60/60*F Emulsification Test Rust Teat Solubility Viscosity 210*F Flash Point Dark-Oily Liquid 5.0, max. 50-60 Ca. 0.92 30, max. Pass 95$t, min. Ca. 240 SUS 350"F, min. Issued 4/13/62 W.O.Krummrich Plant By Method Numbers Nltro WOK 6-c-Ol T-2134 6-C-21 T-2141 6-A-24 T-2135 -- 6-S-28 T-2139 -- 6-R-04 -- -- 6-X-02 T-2140 -- 6-0-01 T-2138 NOTE1 This material la shipped upon Invoice certification of compliance with specifications. Prior permission will be obtained to ship non-specification grade material. This specification Is the property of Monsanto Chemical Company and Is Intended for Internal use only. MONS 044691 n M M WMV. M/| W. 0. KHUMMHICH PLANT MONSANTO CHEMICAL COMPANY CHEMICAL* DIVISION RAW MATERIAL SPECIFICATION 31100 win* dept*. B-246 Dow Corning Corporation Dow Corning 200 Fluid-350 cs. Issued 3/14/62 W.O.Krummrlch Plant MOL New Mixture SAMPLE POO ANALYSIS 1 x 8 oz. W.M.Bottle Oeneral Tests (Made on request only) Proeertz Specification Appearance Syrupy Liquid Viscosity 25*C 330-3TO os. Color-Modified ASTM D-848-45T 1.5, max. Flash Point 600F, min. Neutralization Number 0.03, max. Stability (Viscosity Change after l6 hrs. 200*C) 10, max. ' Method Number T-2134 T-2132 T-2142 T-2138 80-B (jpq) 118-31100 (jp<j) NOTE! Thla material la shipped upon Invoice certification of compliance with specifications. Prior permission will be obtained to ship non-specification grade material. < m in mm tasv. w/aal HONS 044692 MONSANTO CHEMICAL COMPANY PtMWT COM 81176 266 W. 0. Krummrlch Plant FINISHED PRODUCT SPECIFICATION PftOQWCT Hmm*i ..... Salea and Internal BALM COM 7536-393/800-07-03 Santoluba 395 and Santoluba 393 5M r (Otmmt-I film*) CWMCAk POMMEL A Mixture Iaaued ^AR 8 1964 By ^ML1*1 UBIMIMIINICI OP IMObC FOR AMALYMR ___6-21-61____________________ ____ 2 x 16 oz. W. M. Bottle_____________________________ UNRESTRICTED INFORMATION Routine Testa Appearance Haze (4jf by wt. In P.E. Phosphorus Sp. Or. 60/60*F Sulfur Vise. BIOO'F Zinc RESTRICTED INFORMATION Routine Tests Color, ASTM Copper Corrosion 3 hrs. 100*C. (0.50* by wt. In STO 1) Specification Clear light yellow green to amber liquid 9556, min. 7.8 - 8.25S 1.090 - 1.116 15.1 - 17.1* Report (Range 950-1150 SUS) 8.4 - 9.2* Method f 12,4l8 12,421 12,428 12,425 12,349 12,426 12,427 3, max. ASTM Std., No. IB, max. 12,419 12,420 Hydrogen sulfide Clarity: Dark Insoluble Matter White Insoluble Matter Odor pH (Stanlsol-Butanolwater system) None DIM Std., max. WIM Std., max. Characteristic 5.0,min. 12,422 10,975 12,423 12,860 HONS 044693 m M M (MV. /M MONSANTO CHEMICAL COMPANY ORQAMC CHIMCAU OIVtlMN Krummrlch and Anniston FINISHED PRODUCT SPECIFICATION product rnraaiM ***) Aroclor 1242 PROOUCT fCfeMfMl nmm) PROOUCT CODS 1 DIPT. OR JOO 81101-82612 IWOK-246-Ann.27 use Sales SALKS COM 1040-240-04/11/16-05/09 TVPC Non-Electrical (Trade_________ TYPK issued JUL15 1964 W. 0. Krummrlch Plant By ^ Mixture MOL T. wKmnii imci or 5-4-61 SAMPLS POR ANALTMS 5 X 16 QZ. W. M. Bottles UNRESTRICTED INFORMATION Routine Tests Condition Color, APHA Sp. Or. (25/15.5`c) Acidity (mg. KOH/g.) Moisture (H20) (ppm.) General Tests Distillation Range (ASTM D-20 Corrected) 10# Distilled by wt. 90* " " " Viscosity SlOO'F (SUS) Flash Point (*p) Fire Point Specification Clear 100 max. 1.581 - 1.592 0.010, max. 50, max. 525*C, min. 560*C, max. 82-92 558 - 592 None WOK Annlstc Metnoa no. 10084 0-1 10084 046 10114 052 10087 050 10620 047 10117 14-51-5 10086 10125 10125 049 14-28-5 14-28-5 HONS 044694 MONSANTO CHEMICAL COMPANY Krummrich and Anniston FINISHED PRODUCT SPECIFICATION product <Tro nmt) Aroclor 1248 Mmmm)PRODUCT (CRaiMl PRODUCT COOK 81102 - 82641 lOSPT. OR JOO IwOK 246-Ann.27 issued JUl- 1 5 1964 USE Sales W. 0. Krummrich plant By \ _______ ALU COOS 1040-260-04/ll/l6-03/09 TTF* Non-Eleotrlcal Orade TTP CNCM4CAL FORMULA Mixture MOL Wt. MPIRMOII IPICI OF AMFLS FOR ANALTMS 5-4-61______________________ ____5 x 16 oz. W. M. Bottles____________________________ UNRESTRICTED INFORMATION Routine Tests Appearance Condition Color, APHA Sp. Or, 065/15.5*C Acidity (mg. KOH/g.) Moisture (H*0) (ppm.) Viscosity 0130*F (SUS) Oeneral Tests Flash Point (*F) d 1 o00 Specification Colorless to light yellow-green liquid Clear 100 max. 1.405 - 1.415 0.010, max. 50, max. WOK Anniston Method No. 10084 0-1 10084 10084 10114 10087 10620 10086 0-1 046 052 050 047 049 370, min. 10123 14-28-54 n M M (KV. !/ MQNS 044695 MONSANTO CHEMICAL COMPANY ftMAMC CMSMCALB DIVISION W. 0. Krummrlch Plant FINISHED PRODUCT SPECIFICATION PKODUCT <Tp*Ps WaA> PRODUCT COOK 81096 jOKPT. OK JOO 1 b-246 UBK Rales ALU COOK 4595-200-11-03 TVPt W--PKOPUtfY (Chtmtml > TVPK CMKMCAL POKMVLA Issued 7/12/65 W. 0. Krummrlch By MIXTURE Mk OT. AMPLK POO ANALTStf New_______________________ __________ 2 -r lfi nv. W. M. _____________________ UNRESTRICTED INFORMATION Routine Tests Appearance Flash Point Moisture, K.F. Neutralization Number Sp. Qr. 25/25'C Viscosity, 50'F SIOO'F 210*F RESTRICTED INFORMATION Routine Test Foam Test Specification Cloudy, Blue Liquid Free of Sediment 550*F, min. 0.05max. 0.80 - 1.1Omg.KOH/g 1.415 - 1.450 900 cs., max. 50.0 - 53.0 cs. 2.80 - 5-OOcb 150ml, max.* Method Number 12,809 12,805 12,810 12,794 12,804 12,857 12,805 Disposition of lots falling this limit will requre approval of the Sales Department. HONS 044696 Dept. B-246 - Process Description 8. PYDRAUL A-200 APPENDIX C PHYSICAL CONSTANTS - W, G. KRUMMRICH PLANT This section contains physical and functional properties of Pydraul A-200. Pydraul A-200 was formerly named OS-95. HONS 044697 3.... PHYSICAL CONSTANTS DATA IUIIVAUM in--' mrzr r^OHMUL ___ AflQCLQB.U4fl eOMPILIB RV--------------------------------------------- A. M. Ellenburff NAME Fottnule Moitculv Weicht Aauoraoct Bollim Point47S0 an Range____________ Bollint Paint 4 3 tm " Boillni Point 4 aa IsHint Point____H_______________________ CnnmtiilM Point___________________________ HiItlrva Paint SolWlonlotnt____________ a________________ Sotcilic Gravity * 25/25 C SmcIIIc Gtoattv * 65/15.5"C. Pound! m Gal. 25C Co(liciil d Ewanion 25-65n Roiioctin Mu * 25urH Infia Rad Soadiim fRtftnmi Ultra Viola! Soactmat fKtftrmet) Viacoiltr a 130F. YiawHtr*________________________________ SuefmTamil* Dvnes/cm fl20"C. Solubility In Mu____________________________ lolUllltv in 3A Alcohol 6 25"C. Solubility in Pyridine B 29UC. bAVc 4-25 57 C12 H6 Cli 292 (AVC. 1 Yellow Tinted Moh.Oil 345-385C. 1R5-21QUC Non-crystallizing 1.445 1.405-1.415 12. 04 0. 00070 cc/cc/"C. 1.6285-1.6305 73-80 SUS 44.2 Tnftnluhlft 15 g. /10Q cc nr.4c./ioo cc Cl. ______ ioujice. a oate_____________ Monsanto Bull. OP-115(195 1! II II Soeclflcatlons 9/9/54 M.^. OP- 115 SDeciiicatlon 9/9/54 M.B. OP-115 J. CoU. Scl. 7.166. 119521 M. fl. OP-115 ft Flaili Point K/umi c. o. c. Fill Point "C rnr HUit of Cofibustlm Ht!< ot Fotnution____________________________ TlwiMi ability tcd-An/ain.)_________________ L4intHi4 of Futon L4nnt Ha4 ot Van. cal/em. SoKitlc HoU 2Bl/f!_____________________ Criticni TwotiUmt_________________________ , Ciltlenl Pmmi_____ _ OHnoduion Cantart Stleclflc Heat B 3Q0"C. I96r ' None 54 0.277 0.356 Four Point Thermal Conductivity, cal/ M f M cm/^C/sec. Dielectric Constant. 100C.. mm __________________ fcA gy.____:______ U i 0C. or lower 23.6 28V 4.5-4. 7 ToilCitV (Cim Rtfrtmct) MOTF' Tkm, ... Contact Medical DeDt. II II Calculated M R OP-1 IS If II To be oubltshed M.B. OP-115 MONS 044698 M.B. OP-115 I]'N i** PHYSICAL CONSTANTS DATA TBWTTOW TRUCTUMAL FORMULA AROCLOR 1242 eOMPILIB f V--------------------------------------------- I bAfi * A. M- Elltnburg4-25-57 Formili SMkuIm Wiiiht NAME Cl 2 Ho CU 257 (*.l Ball In Point M 7HI m Ranee BotllmPolit 03 " 325 - 360 -C. 155-195 "C Bat MII* Point a an CnmoHliint Point _ __________ IUMm Point Sail Smelite Gravity 25/25'C. SoocllleCimitY 25/15.5"C. Pounds por Gal. 25 C Cootticimtol Exnanton 25-65 "C. Refractive Indn 25 'C. * 2 Infra Rod Saoctian rntUntim) Ultra Viola Sptdnia (Mwmc*j Non-crvstalUzina 1.380 1.381 - 1.392 11.50 0.00068 cc/cc/'C 1.6245 - 1.6265 Vlouiltvo 210'F. 34-35 SUS VlacoMtv e 100F.___________________ 82-92 SUS Sod nTanln DyiFl/CRl @ 20 "C . Sol ailitr In Me 45.3 Insol ible / toliailltv in 3A Alcohol 29 "C. 23. 3 a. /100 ec SHAHItvIn Pyr?.dine @ 30 *C. 132 5 b /tOO cc souwee a oati____________ tr ti M SDeciiicatrcin 2-14-55 M. B. OP-115 It BpacJlicatirt* 2. 1A-88_____ M. B. OP-115 II I, Cell. Sc:. i., 166,11047 M. B OP-li5 1 '' It Flaah Point *7**o* c.o.c. Fin Point C c.o.c. InfCeMI* Hu ol Fewilon_________________________ Tlarail Shfcilitv (cETkC/'ali.) 180"C. None LMMtHoBotV*. cel/am. Soeciflc HoR @25 C. Critical TMewriim Critical Prawn ________________ Oilimlilim rnaeat Sp ecrfic Heat 300 "C. 61 0.293 0. 380 Pour Point M M Thermal Conductivity, cal/ cm/ "t/iec. m U Dielectric Conetani. 100WC., 60 cv. i -14''C. or lower 24.0 28C. 4.7 - 4.9 M If M B OP- T1 5 If II m n OP-11 s HONS 044699 Toiled* (Git* RafartneaJ Contact Medical. Dent. M. B OP-115 NOTE: Tkata data tkaaJd mat k* talmaaad aataid* at VhiuaiiM Ck. tl*+ ttdditinmml Dept. B-246 - Process Description PYDRAUL A-200 APPENDIX C PHYSICAL, CONSTANTS W. C. KRUMMRICH PLANT 9- PYDRAUL A-200 - PHYSICAL fc FUNCTIONAL PROPERTIES Appearance: Slightly cloudy, light yellow, oily liquid. Viscosity: at 210F. at 100* F. at 40"F. Centistokes 2. 86 30. 14 1920. Saybolt Universal Seconds 35.8 142. 8500. Density: at 100" F. at 60'F. 1. 4161 gm. /ml. 1. 4305 gm. /ml. Flash Point (COC): Fire Point {COC): 380*F. 680F. (1) Hot Manifold (MIL-F-7100), 1300"F. - Does not flash or burn on tube or after leaving tube. Low Pressure Spray Flammability (AMS 3150-B) - Flame brightened, but not increase. High Pressure Spray Flammability (AMS 3150-B) - Will not ignite, did Molten Metal Ignition (molten aluminum alloy at 1150 to 1250F. ) - Does not spontaneously ignite. Flashes by spark. Pour Point: +50"F. Neutralization No. mg KOriTgm. to pH 11: <2> 0. 83 Steam Turbine Oil (j) Rust (ASTM -^65) 10. 0 at 48 hours Foam (ASTM D-892) at 75"F. at 200" F. at 75"F. F oam Vol. ml. 35 8 35 Collapse Time Seconds ------- 55-----------60 60 Shell Four-Ball Wear: Steel-on-steel 4 Kg. -0.21mm. 167 "F. , 630 RPM, 1 hr. 10 Kg. - 0. 29 40 Kg. - 0.43 Pydraul A-200 was formerly named OS-95. HONS 044700 Dept. B-246 - Process Description 10. PYDRAUL A-200 APPENDIX C PHYSICAL CONSTANTS (Cant'd.) - W. G. KRUMMRICH PLANT Shell Four-Ball Wear: -------- M ftPM, 1 Hr. Steel-on bronze 4 Kg. -1.20 10 Kg. -1.40 40 Kg. - 1. 70 Almen E. P. Passing load Passing torque - 48 lb. - 41 lb. 24,000 psi. Almen Wear (wt. loss mg.): 1. 3 mg. Timken Load (passing): 50 lb. , 16, 340 psi film strength Steam Turbine Oil Oxidation (ASTM D-943): (1008 hours exposure) Viscosity 100 *F. Initial Final 210 *F. Initial Final Acidity Initial, TAN Final, TAN Fluid Appearance: Steel Appearance: Copper Appearance: Four-Ball Wear: 30.12 cs. 30. 03 cs. 2.87 cs. 2.86 cs. 0.82 0. 21 Greenish brown with greenish white deposit in tube bottom. Soft black deposit on surface. Black rough (etched) surface. Initial 10 Kg. -0. 29 mm. , Final 10 Kg. -0. 41 mm. Oxidation-Corrosion: (Fed. Spec. 791 Method 530.8, 168 hrs. at 250*F.) Metal Attack (wt. change mg/cm. 2 ) Copper - 0. 05 no etch, greenish to straw stain. Aluminum - + 0. 01 clear Magnesium - 0 very slight trace surface pitting Steel -40.01 clear Cadmium Plate - 0. 01 clear (Viscosity 100*F. Initial Final 210*F. Initial Final Acidity, TAN Initial Final Evaporation Loss, %: 30. 1 cs 31. 8 cs 2. 86 2. 93 0. 82 0. 68 0. 6~ 04470i Dept. B-246 - Process Description II. PYDRAUL A-2 00 APPENDIX C PHYSICAL CONSTANTS (Cont'd,) - W. G. KRUMMRICH PLANT Oxidation-Corrosion: (Fed. Spec. 791 Method 530. 8, 168 hrs. at 250*F.}(Cont'd. Fluid Appearance: Clear, light amber, no deposits. (1) fluid boiled over onto heater. (2) Apparent high acidity due to nature of additives present. (3) Rust rating: REL M-400, 10.0 - no rusting. MOHS PYDRAUL A-200 COMPATIBILITY LUBRICATING PROPERTIES Fluid <% Vol. ) 100% A-ZOO 90% A-200, 10% Pydraul F-9 75% A-200, 25% Pydraul F-9 25% A-200, 75% Pydraul F-9 10% A-200, 90% Pydraul F-9 100% Pydraul F-9 Almen Load Pounds Pounds Load Torque Four-Bkll Wear (620 rpm, 167*F. > 1 hr. ) Steel-on-Steel Steel-on-Bronze 10 Kg-- 40Tfi. --nnr?-- 48 41 0. 29 mrn 0. 43 mm. 1.40 47 41 0. 23 mm, 0. 50 mm. -- 38 43 0. 22 mm, 0. 55 mm. -- 50 45 0. 22 mm. 0. 63 mm. -- 50 47 0. 22 mm. 0. 68 mm. -- 50 44 0. 28 mrn 0. 67 mm. 1.18 100% A-200 90% A-200, 10% Cellulube 220 75% A-200, 25% Cellulube 220 25% A-200, 75% Cellulube 220 10% A-200, 90% Cellulube 220 100% Cellulube 220 48 41 0. 29 mm. 0. 43 mm. 43 53 0. 25 mm 0. 53 mm. 37 54 0. 23 mm 0. 58 mm. 50 55 0. 28 mm 0. 58 mm. 50 52 0. 30 mm 0. 48 mm. 27 35 0. 33 mm 0. 54 mm. 1. 40 -- -- -- -- 0.81 SNOW 100% A-200 90% A-200, 10% Houghto-Safe 1120 75% A-200, 25% Houghto-Safe 1120 25% A-200, 75% Houghto-Safe 1120 10% A-200, 90% Houghto-Safe 1120 100% Houghto-Safe 1120 48 41 0. 29 mm 0. 43 mm. 40 44 0. 24 mm 0. 50 mm. 36 56 0. 22 mm 0. 55 mm. 49 57 0. 31 mm 0. 57 mm. 50 47 0. 37 mm 0. 51 mm. 50 51 0. 34 mm 0. 56 mm. 1.40 1. 57 1. 47 1 12 0. 98 0. 90 Dept. B-246 - Process Description 12. PYDRAUL A-200 APPENDIX D UTILITIES - W, G. KRU MM RICH PLANT The utility calculations are based on design calculations for a 5 million pounds per year production rate. The breakdown of utility by individual equipment is only as estimate. The estimate of utility usages are average values in most instances as it is difficult to measure the operating time and load for a particular piece of equipment with great accuracy. The total usage of each utility was taken from the cost sheets. Estimates of individual operating time and percentage of total load were made to calculate the distribution of utilities as given in the following pages of this section. 1. POWER CONSUMPTION A. Electricity - 440 V. , 3 phase, 60 cycle Peak Item Equipment No. Motor Motor H. P. Load KW Monthly Usage KWH 160 Pydraul Pump 10. 0 8.8 240 149 #3 Aroclor 3.0 Storage Pump 2. 6 20 151 #4 Aroclor 3. 0 2.6 Storage Pump 20 157 #7 Aroclor 3. 0 2.6 Storage Pump 20 159 #1 Mix Tank 7. 5 6. 6 600 Agitator TUTS rrr 9do B. Electricity - 110 V. , One-phase, 60 Cycle Peak Load Equipment KW Monthly U sage Miscellaneous 2 2. COMPRESSED PLANT AIR ZOO HONS 044704 Item Using Normal No. Equipment uBe SCFM Peak use SCFM Monthly usage MSCF 159 #1 Mix Tank 15 30 1000 Dept, B-24fe - Proce Description PYDRAUL A-200 APPENDIX D UTILITIES - W. G. KRUMMRICH PLANT (Cont'd.) 3. LOW PRESSURE STEAM 80 psig at 325F. Item No. Using Equipment Normal use Lb. /Hr. Peak use Lb. /Hr. 159 #1 Mix Tank 700 Miscellaneous 200 900 1000 500 I5W !> Monthly Usage Lb. 400 40 440 MONS 044705 Dept, B-246 - Process Decrlptlon 14. PYDRAUL A-200 APPENDIX E PERSONNEL Departments 246, a-246, b-246 and C-246 are closely related. Operating personnel may work In all of the departments In a given day. For this.reason, the description of operating classlfloatlone and assignments for departments 246, a-246, b-246 and C-246 Is given as though all four of the departments are Just one department. Operating Classifications Job Premium Operator Standard Operator Repairman Packer Porter Swlngman Total Number of Men 7 day/week Sohedule ' 10 &4 Schedule 43 43 11 22 ** i0 12* 9* The swlngman works two shifts per week (Saturday and Sunday) as a relief foreman, two shifts as a repairman, and one shift operating the premium Job. There Is an open shift on tne standard operator Job that is covered by overtime. The premium operator and standard operator cover three shifts each day. The repairman works the day shift, and with the swlngman, there Is 7 days per week repairman coverage. Packers work the day and middle shift 5 days per week. The porter works half time In department 246 and half time in department 24J. The premium operator has lead responsibility for his shift. The work force works all three departments Aroclor, Pyranol and Pydraul as one coordinated operation, The assignment of time is 70# to Aroclors, 15# to Pyranol and 15# to Pydraul. Operating Assignments: Premium Operator: Has overall responsibility and operates 5 chlorlnators 2 stills and covers the necessary absences of the standard operator. Standard Operator: Operates.2 blend tanks filter, 2 finished product tanks, storage tanks, makes fyranol and pydraul mixes, loads trailer, and tank cars, charges chlorlnators and transfers receivers and also belongs to the Fire Brigade. Repairman: Unloads cars and trailers of Biphenyl, Trichlorobenzene and Tetra-Tricnlorobenzene and finished product, makes weekly safety inspections and department minor repair work. MONs 044 706 Dept, B-246 - Process Description 15. PYDRAUL A-ZOO APPENDIX E PERSONNEL Packer: Fills, stencils and labels 5 gallon, 30 and 55 gallon drums and clean-up assignments when not drumming. Porter: Cleans office, control room, repair room, wash room and smoking shelter. Swlngman: Works one day per week as premium operator, two days as repair man and two days as relief foreman. As relief foreman takes overall supervision and day shift on weekends Including arranging for maintenance night sheets and line-up of work. HONS 044707 Dept. B-246 - Process Description PYDRAUL A-200 APPENDIX F PACKAGING it SHIPPING 16. Aroclor, Pyranol & Pydraul are filled about half In drums and half in tank cars or tank trucks. A substantial amount (about 4o%) of Aroclor is used to make Pyranol and Pydraul. Sales are largely directly to the customer. The remainder Is In bulk shipments to the J. F. Queeny Plant. All electrical grade tank truck shipments are made In the customers trucks which are stainless steel. Non-electrical Aroclors are shipped in leased trucks and may be Iron although other materials of construction are suitable Pydraul is shipped In Steel tank trucks. Electrical grade Aroclor and Pyranols are shipped In lined tank cars either 4,000 or 8,000 gallons In capacity. The lining Is either tin, zinc or aluminum spray because Iron contamination Is detrimental to the electrical properties. Electrical grade cars are either owned by Monsanto or on a long term lease. Non-Electrical grade Aroclor is shipped in steel cars. All electrical grade lots and bulk shipments of non-electrical material are sampled from the final container. That Is all tank cars and tank trucks are sampled and analyzed after loading. All electrical grade drums are sampled from one of the drums. Tank cars and tank trucks are Inspected to be aure they are free of dirt and water or other foreign material before loading. Heels are drained before loading some materials. Car washing when necessary Is done by the repair track. Tank cars are sealed with a numbered aluminum seal Lacquer lined drums are used for Aroclor and Pyranol and plain steel drums are used for Pydrauls. A summary of products, weights and containers current use Is as follows: Product ' Weights and Containers 5 Oal. 50 oal. 5b Qal. TT TC 1252 1242 1248 1254 1254 Xylene 1260 1262 MCS295 _ 60 CO 60 - 60 60 '- 600# - 600# - 600# - 600# - 600# 600# - 600# - 645# _ Yes Yes Yes - Yes - Yes Yes Yes - Yes - * Pyranol i486 Pyranol 1481 _ - 675# _- - 675# HONS 044708 Dept. B-246 - Process Description PYDRAUL A-ZOO APPENDIX F PACKAGING k SHIPPING 17. Product 5 Qal. Weights and containers 30 flal. 55 Qal. TT TC Pyranol A-13B2B Inerteen PPO Pydraul a-200 Pydraul 200 65 65 59 *^o*>o8* 675# 674# - 4000 Oal. 4000 Oal. k 8000 Oal. - 645# Yes - - 625# " HONS 044709 Dept. B-246 - Process Description ib. PYDRAUL A-ZOO APPENDIX G MATERIAL BALANCE - W, G, KRUMMRICH PLANT A detailed material balance on Department B-246 was not made because blending and material losses in the process are negligible. The greatest material losses are the samples which are less than 1 pound per hundred pounds of finished product. MQNS 044710 Dept. B-246 - Process Description 19. PYDRAUL A-200 APPENDIX H ATMOSPHERIC - STREAM DISCHARGE Waste materials are absent in the production of Pydraul A-200; no materials are sewered. The temperature of the blend is about 70*C. At this temperature evaporation losses of the finished product are very small. Thus, almost no product is discharged to the atmosphere. MGNS 044711 Dept. B-246 - Proeeaa Description 20. PYDRAUL A-200 APPENDIX I PROCESS CONTROL PROCEDURE - W. 0. KRUMMRICH PUNT The data gheet In this section le typical of those used by operating personnel to record the various stages of the blending process as they are completed. The process control procedure is listed below: Sampling Point Frequency Reason for Sample Normal Range Method Number Discharge of circulation pump of #1 Mix , tank One 16 oz. Sample every batch Sp. gravity Viscosity 0.011 10 SUS 10,114 10,086 Discharge of circulation pump of jf*l Mix tank Three 16 oz. Samples every batch Sp. gravity Viscosity 0.015 12,804 12,837 0 50 F - 900 CS., Max. 100IF - 3.0 CS 210 F - 0.17 CS Moisture 0.05S*,Max. 12,810 Flash Point 350F,Min. 12,803 Neutralization 0.30mg K0H212.794 Number Foam Test 150 ml,Max. 12,805 Tank truck or Tank oar Three 16 oz. samples once every load The samples are the same as those in Item 2 above. MONS 044712 Dept. 6-246 - Prooeaa Description PYDRAUL A-200 APPENDIX J SAFETY AND TOXICITY DATA - W. 0. KRUMMRICH PLANT SAFETY EQUIPMENT* The following la a list of safety equipment (personal and departmental) required In Department 246. 1. FIRE EXTINGUISHERS A. Dry Chemical (3) - Southwest corner Bldg. CRMaln Floor. - West wall at top of stairs of Second Floor. 21. B. Carbon Dioxide Snow- South-West corner of Bldg. CR, Ground Level. 2. CHLORINE GAS MASKS (4) - South-West corner, Second Floor - Control Room, Second Floor - East side, outside Control Room - Wall, South-West corner of Sprinkler House, Main Floor. 3. SCOTT AIR MA3KS - 4. SAFETY SHOWERS (2) - South-East corner of Bldg. CR, Ground Level. - South-East corner of Bldg. CR, 2nd Floor. 5. DAVIS VAPOTESTER 6. EYE BATHS 7. SPRINKLER SYSTEM The safety equipment for Department B-246 is the same as that of Department 246. MQNS 044713 Dept. B-246 - Process Description 22. PYDRAUL A-200 APPENDIX J SAFETY AND TOXICITY DATA (Cont'd.) SAFETY PRECAUTIONS The following are safety precautions followed In the operation of Department 246. 1. SAFETY EQUIPMENT OF EMPLOYEE Each employee has the following safety equipment: (1) hard hat (2) Bafety glasses (3) goggles (4) rubber or canvas gloves (5) rubber overshoes. Special equipment may be Issued as necessary for performing a particular Job In a safe manner. 2. SAMPLING Precaution must be taken to avoid skin contact of samples and Inhalation of vapors. 3. FIRES Pydraul A-200 Is not a fire hazard. Automatic fire extinguishers and sprinklers have been Installed In building CR to combat any flre3 that may come about. 4. TOXICITY Toxicity does not present a serious problem. However, a complete change of clothes Is supplied to each person, and time Is allotted at the end of each shift to take a bath. Instructions are also Issued to avoid actual skin contact with Pydraul A-200 as much as possible and to wash hands and face before eating. 5. MISCELLANEOUS There are many accidents that can occur which may be classified as health and safety hazards. These accidents may result from such things as broken steam lines, acid leaks, bare steam lines, etc. 6. SAFETY RECORD The last lost-time accident in Department 246, A-246, B-246 and C-246 was January 28, 1948. The frequency of minor injurle Is low, around one per month for all departments combined. 044714 Dept. B-246 - Process Description 2-i. PYDRAUL A-200 APPENDIX J TOXICITY DATA AROCLORS AND PYDRAULS TOXICITY: ThlB material Is a liquid under normal conditions and has a medium toxclty range for liquid lnjestion and a high toxicity for vapor Inhalation. The maximum allowable concentration (M.A.P.) Is 1 mg/cubic meter. FIRE HAZARD: There Is no fire hazard under normal conditions. OTHER HAZARDS: This material can cuase dermitltis, systemic poisoning from the fumes, and yellow atrophy of the liver. There are skin, mucous membrane and eye hazards encountered In handling this material. TREATMENT AND ANTIDOTES: Call a physician and remove patient from fumes. STORAGE AND HANDLING: Protect the skin, lungs, and eyes by wearing approved protective clothing, respirator and goggles. There are no special storage restrictions under normal conditions except to store In a venti lated area. SHIPPING: There are no special shipping restrictions. 044 715 pept b-2^6 - process Description 21*. PYDRAUL A-200 APPENDIX K BACKGROUND - W. 0. KRUMMRICH PLANT Monsanto has been actively Interested In functional fluids since 1948. iwo lines of products, sRydrol fire resistant aircraft hydraulic fluids and pydraul fire resistant Industrial hydraulic fluid, have been introduced and several individual fluids have reached commercial status. Formulation work was done by Monsanto on an Aroclor base fluidu in an effort to develop a satisfactory fluid of lower price than the pydrauls available on the market. viscoBlty index improved versions were abandoned due to unfavorable costs ana performance characteristics. This project resulted in a non-vlscoslty Index improved, fire resistant, Aroclor ,base industrial type hyaraullc fluid designated OS-95. in May 1958, six batches of OS-95 (Later to be named pydraul A-200) were prepared for the first time in the research pilot plant, since 1958, the production of pydraul a-200 has Increased to nearly, 4JO,000 pounds per month. HONS 044716 pept. 13-246 - process Description 25- PYDRAUL A-200 APPENDIX L TIME CYCLES - W. G. KRUMMRICH PLANT The design capacity of Department b-246 is 500,000 pounds per month, or 6 mlliion pounds per year. The normal production of the department is around 4 million pounds per year. The limit ing factor of the process is the amount of Aroclor available to form pydraul a-200 and the available storage facilities of the finished product. The following table shows the time cycle to blend a 12,000 gallon batch of pydraul a-200. TIME CYCLE ITEM TIME Charge Aroclor 1242 and Aroclor 1248 Agitate Aroclor 1242 and Aroclor 1248 Mixture Sample Aroclor Mixture Charge santolube 593 and santolube 70 and Charge DCF-200 Charge Dye to Batch Circulate Blend (Agitate, Transfer to storage Air) 2.5 Hrs. 5.0 Hrs. 4 nrs. i Hrs. 1$ Hr. 1$ Hr. } Hr. J Hr. 5 Hrs. lb-48Hrs `H.5-V3.5 hH. The time cycle for the preparation of a pydraul a-200 batch Illustrates the storage bottleneck, it takes approximately 16 hrs. to pump a finished batch into a tank truck, and approximately 48 hours to drum a finished batch. HONs 44 ?u Dept b-246 - process Description 26. PYDRAUL A-gOO APPENDIX M QUALITY CONSIDERATIONS - W. 0. KRUMMRICH PUNT pydraul a-200 is an Aroclor base, fire resistant, industrial type hydraulic fluid which waB formulated to meet viscosity and iuoricatlng requirements, and anti-rust characteristics specified by the sales department. The physical and functional properties of pydraul a-200 are discussed in the following sections. 1. VISCOSITY The required viscosity range of pydraul a-200 Is 200 to 300 absolute sus. The results of formulation work as given in table 1 indicate that a mixture of one part Aroclor 1242 to two parts of Aroclor 1248 by weight exhibits the lower limit viscosity of 200 SUS absolute at 100p. 2. LUBRICATING PROPERTIES Results of four-bail wear tests on the Aroclor base stocks as given in table 2 indicates the necessity of an anti wear additive, santolube 393 Imparts good anti-wear properties to Aroclor based fluids. 3. RUST INHIBITION previous work with rust inhibitors for pydrauls has Indicated that santolube 70 is relatively effective as an inhibitor as measured by the ASTM D-665 rust test. t. MISCELLANEOUS A- APPEARANCE pydraul a-200 Is a blue liquid with a hazy appearance. The haze is due to very small quantities of antifoamant, DCF-200. B. FOAM The use of santolube 70 In the pydraul blend causes underslrable foaming, a concentration of 50 ppm dw Corning Fluid 200 inhibits foaming. C. NEUTRALIZATION NUMBER Unused pydraul a-200 has a total acid number of about 0.8. This apparent high acid number is due to the nature of the santolube 393 and santolube 70 present. HONS 044718 pept b-246 - process Description 27. PYDRAUL A-2QO APPENDIX M QUALITY CONSIDERATIONS - W. g, KRUMMRICH PLANT 4. MIS CBLLANEOUS (Cent1d. ) It Is important that any contemplated process changes be carefully evaluated before the actual change is made, since the quality of pydraul a-200 can only be determined by full scale performance tests. Tests such as those given in table .5 are necessary to evaluate the product. HONS 044 719 SNOW Formulation Number 1 2 3 4 5 6 7 8 9 10 TABLE 1 HIGH AROOLOR FLUID FORMULATION Kinematic viscosity Centistokes Formulation ($ wt.) 100F. 210F. 55jt Aroolor 1248, 45$ Aroolor 1242 l8j( Arodor 1254, 82$ Aroolor 1242 27.6 24.7 -- -- 785* Aroolor 1248, 22$ Aroolor 1232 22.6 -- 6l$ Aroolor 1248, 39$ Aroolor 1242 29-0 -- 20$ Aroolor 1254, 80$ Aroolor 1242 25-7 -- 81$ Aroolor 1248, 19$ Aroolor 1232 24.30 -- 65$ Aroolor 1248, 35$ Aroolor 1242 30.17 -- 27$ Aroolor 1254, 73$ Aroolor 1242 29.6 -- 88$ Aroolor 1248, 12$ Aroolor 1232 31.3 -- 66$ Aroolor 1248, 33$ Aroolor 1242, 0.5$ santolube 393, 0.5$ Santolube 70, 100 ppm. DCF-200 30.22 2.87 Saybolt Seconds Kin, 100 F. Ab"sa 100 F- 130 183 117 166 108 150 -- 193 -- -- 142 -- -- 200 ---- ---- 142 200 T2Y440 SNOW TABLE 2 PYDRAUL A-200 ADDITIVE STUDY Aroclor 1242 % pydraul p-9 Aroclor 1248 ipt JL. Sant. 393 Sant. 70 Other Additive * 4-Ball wear (1) 0.63 Cellulube 220 0.56 T-410 100 -- 0 0 0 0 -- 0 T-512 100 0 0 0 0.81 0.83 t-410 33 T-512 66 0.5 0 0 -- T-410 33 T-512 65.95 1.0 0.05 0 -- r-4io T-412 t-410 T-412 T-412 T-412 3315 T-512 3315 T-523 33 T-512 33 T-523 33.1 T-523 33.1 T-523 66.3 0.5 66.3 0.5 66 0.5 66 0.5 66.1 0.5 66.25 0.5 0.05 0.05 0.5 0.5 0.05 0.05 0 0 0 0 0.25(2) 0.1q(4) 0.55 0.53 0.46 0.45 -- -- 0. CM d T-412 33-0 T-523 66.15 0.5 0.05 -- -- 33-0 -- 66 0.1 0 0 0.53 f1) 1 hr., 40 kg., 630 rpm, steel-on-steel. (2) squealing during most of run. (3) No. 5 process Oil (santolube 70 Inert). (4) Dioctylmaleate. Almen EP Load Torque pounds psi 50 43 27 -- 50 44(2) 40 (2) 38(2) 34(2) 35 -- 38 39 34 46 38 48 50 38(2> 41 kO 40 -- -- ---- -- -- TABLE 5 EVALUATION OF USED PYDRAUL A-200 Chevrolet - Bay City Division - 260 nrs. (14 hrs. at 19QF-) Viscosity 100?., cs. 210F., cs. 4-Ball wear (650 RPM, 1 Hr. 1678F.) pydraul a-200 New_________ pydraul a-200 Chev.-flay city civ.. 260 Hr. 50.65 2.89 51.8 5.05 Steel-on-steel 4 kg. 10 kg. 40 kg. Steel-on-Bronze 4 kg. 10 kg. 40 kg. Neutralization Number Rust Test (reL. F-101, 10.0-perfect) Appearance .21 .29 *5 1.20 1.40 1.70 0.82 TAN 10.0 yellow, slight cloudy .20 .26 59 95 1.48 1.69 0.82 TAN 10.0 Reddish-brownnearly opaque ONS 0*4722 pept. b-2^6 - proceaa Description PYDRAUL A-2QO APPENDIX N MISCELLANEOUS - W. 0. KRUMMRICH PLANT This section contains the following Information 1. Additional Raw Material information 2. References 3. production cost standard pept b-246 - process Description 29- PYDRAUL A-200 APPENDIX N RAW MATERIALS . 1. AROCLOR 1242 Aroclor 1242 Is received from department 246 by pipeline. Aroclor 1242 batches are composited in a storage tank and a lot analysis is run on the composite sample. The Aroclor 1242 must pass all non-electrical specifications before it is transferred to department b-246. 2. AROCLOR 1248 Aroclor 1248 is received from department 246 by pipeline. Aroclor 1248 is composited and sampled in the same manner as Aroclor 1242. 3. SANTOLUBE 393 Santolube 393 is received from Department 266 in 55 gallon drums. 4. SANTOLUBE 70 Santolube 70 is received from the Nltro plant in 55 gallon drums. 5- BLUB A DYE Blue A dye is purchased from the Dupont company. The material is received in 25 lb. boxes. 6. AZO BLACK DYE Azo black dye is from the Allied chemical company. The material is received in 25 pound boxes. 7. DOW CORNINO FLUID 200 Dow corning Fluid 200 is purchased from the Dow corning Corporation. The material is received in 5 gallon cans. MOWS 044724 pept. b-246 - process Description 30. PYDRAUL A-200 APPENDIX N REFERENCES 1. st. louIb Research Report no. 2472, job no. 2-02-760.01 3505 (II), February 16, i960. Title: Functional FluidB Application Research Summary* This Report includes application studies of Aroclor base fluids. Discussion includes formulation, physical and functional properties of pydraul a-200. 2. St. Louis Research Report no. 2842, job no. 2-02-750.01-3550, November 7, 1961. Title; Application Research - Fire Resistant Fluids Summary: Report includes investigation of problem areas arising In pydraul fluids. Reference Job numoers are 3505, 3766 and 4009. 3. St. Louis Research Report No. 1562, Job No. 2-02-750.01-2815, July 6, 1956. Title: Functional Fluids - Application Research for 1954-55. Summary: Report Includes formulation studies, property determinations, and sample preparations of Pydrauls. HONS 044725 PRODUCTION COST STANDARD Piodud Pvrtrmil A-POO J Da*. No. B-246 P^.r.J. 810.96 Thpory* SoS. o2 Yi.idon f//.e |sd yV/; yf Th.y /St. r/ * Th*ory/5id /&/ % Thoory/Std /0/, 9/ Capocllr A ^ On< * Co.t Unit 1QQ jba Jan >m>. ynif Ca l.lQ6il ^0 4* PnOOUCTION*OUANTIT V lXINII*MOUNT INVCNTOnv VAkUCACAP on n ACKCT 1 NONA RACKET * $1iono * ^ cx>v * nACXIT A \ lk> ao-1_______ " AMOUNT UNIT COAT AMOUNT UNIT COAT AMOUNT UNIT COAT AMOUNT MATCRlAk COAT _ 1 iFF 'V"44 \ 1 JUcrt T ' OLo>V T CAM LCCTAICIT V f 7. \Tkipi O^lg StS ______ comaacaaco air wat CQ.pk ANT PUCk> AA PUCk'Olk ICC i. AQON.MANUP ACT unN PATWOLL-OYCnMC AO pact on v auppuica kAeon AT onT CI.OTMINI A kAUNORV proo. ocnr. cont. can. * tcchnicai. nviec uich. cun. / 3 f A / y y "o\ ~i vsr \ OVA tfV* W\ rSi se t>< 71* rO oua 'oO a? G=J \T4 ?y 13V W\ 0cO asa OyJ *o QccfJS^ \Tf (1% -V*\ IK \k\ n \ ou 5sa \o 10a ' 4o )\1 _____ 2X 111. Total Dlnei Cnv*ralan ocnncciATiON r*ial hWrNi CmnnIwi Total Fro*t>el Cat CXPKNAC* QUANTITY kA*OR kAOOR IT (AM CkCCTNICITV comrrimko air WATtn.PUQCNAPCD PUtk-A A* uCk'Qlk UNIT UNIT Pn Houna XXX XXX XXX MCN XXX m wa. C KWM Ylf M CP MCAk. MAk. M CP Ak. "Slol Mo *ot &JA fr^N QUANTITY % 4 \^o QUANTITY _________ 3o 2a< *5- 3o- 5T2 \k\\ \ i \*o orsr 3W 04 4 yi ***** _s iik Mo 414 MSSS QUANTITY "PUN O * vAH 2o QUANTITY *\ O' ?> 4-4 O3 ___________ i /a. ,. \a rr\j'2oX fb|iS2l ICC kKt. LAC. MAN/HM LWOR ITWMY QAM XXX <****$>/>> ~ XXXX XXXX NUMOCn on uottra CQUIPMCMT UACOi oT. ho, CVO*vn l* OCWT. NO. DCAT. NO. Sb Q X Si. % % Si ' % % j Jo * DAri AMIPTA f^A IT* nY XXX XXX So j /f J Z 3- //____ C ____i_____ PRODUCTION COST STANDARD Pydraul A-200 eoi 81101 fill 02 EtrS 817H7 MAMA Arcelor 2142 Aroalor 1248 S&ntolube Aunfcnlube 70 | PLANT IKnpmrich lOAPT. NO. -- 810.06 _______ COCT UNIT 1 Cl>0 lha 11. LL goo p*i STANDARD ?V*?L Y! V\o ,r-- MV. UNI COOT <lo^ UNIT COAT 0V*\ W\i\- t V-<L OiA \^-s- HA MATMIAL OAOtMOUaiNO 9 NANOLINO 0009 TOTAL MATMIAL* Y.POOOUCTf A/.,, tX3--1 9-1-V NOT TOTAL MATMIALS O-AWFICATlOH CB9T Of HUT-DOWN twr r *TT^.r.- COAT OP CHAPA COVBO PAOOUCTIOM COOP ' CLA--IPICATION (OwWJ CO*T 00 *TANOY CP9T TO MOV A MAW ItANMY LAOOM - NO. OP MIN ____ 1_2 fipu nt*A 4ri C*Tki**\ S>o Y/A e: ' ___at* MONS 044727