Document daeo8R6x67Lj175gxVexBbQg0

SASGUUEMMNMMCAAYRRYYFOFFROORRMIW WLOIOTRRAKKRYPPTEEERRCFFOHONRROMMLEEODDGFFYOOARRNTTDHHPEERGGOEECRRUMMRAAENNMEGGNOOTVVEEORRNNNFMMIEERNNETT AEEGXXTTEIINNNCGGYUUIIFSSOHHRIINNMGGILFFIOTOAAARMMYCCTOOEMMCPPHOONUUONNLDDOSSGYFFRRAONOMDM MPMURULOLTTCIIUPPLLREEEMCCEOONMMPTPAOANNNIIEEFSSIRE TTEESSTT SSUUBBSSTTAANNCCEE IIddeenntittityy:: AA mmiixxttuurree ccoonnttaaiinniinngg PPeerrffiluuoorrooooccttaanneessuullffoonnaattee,, wwhhiicchh mmaayy aallssoo b(b1ee-Orreceffteearrnrreeesddu lttofooaanssicPPaFFcOOiSdS),, FFCC--9955,, (CAS # oorraass aa ccoommppoonneennttooff 2795-39-3). FFCC--220066.. (1-Octanesulfonic acid) (CAS # 2795-39-3)o sRRaeemmmpalarerkksiss:: FC-TT2hh0ee6.33MMCupprrrrooeddnuutcctitiinoofnnorllmooatttnniuuonmmbibenedrricwwaaatssesnnioottitsnnoaottemedid.x.tTuTrhheeetoetefsstt0.67% sPfPoaFFamOOmSepSr,l,e, 11is177%..5F5%sC%o-dd2dii0ieeu6tthm.hyyoCllecetunnyreleregsgnullytlyfccianootlfleo,bbrumu0ttya.ylt0lio4eetn%thheeisnrro,d,di77ci88au.t.me99s1l1a%%iutwriaywsltaaestuermlr,f,iaxt11teu..,3r3e303%.o%5f HH%0yy.6ddr7roo%xxyy fppoooallmyyooexxryy,ee1tth%hyyllseeonndeeiummmoonnooocotcoytclytsylulpplhfhaeetneny,yll0ee.0tthh4ee%rr,, saaonndddiu00m..00l5a5%u%ryttolollsyyutltrlrfiiaaatzzeoo,llee0...5% HTT.hheeHeffloollllmoloawwniinnaggndssuuDm.mmm Muaalrlryeyraa)ppfppollriieetsshettooGeaarssmttuaudndGyyoddvooennreenbbmyyeaanttthhiAirrgddeppnaacrryttyyF((oDDrrr.. HM Mein.livlHiiittaera#roryymnmTTaeeenncctahhannnlodopllDrooo.ggpMyyeraautlnniledders)PPorfrfooofrccoutuharreememmGeeeexnnrttmtifnfoaogrnurpipGusuohrrivppneoogrssnaeemgsseenoonftftcscAoofmgmrpeoapnmracmyiriunnFlggtoirttphhleee ctcehoonemmvepinpraovanninirmieeosesn,,nmteiiannnlcctpllauruloddppiinrnegogrpt33ieeMMrs't'issoefFFsfCCo-o-a2f2m00t66h.e.exfDDtliaanuttgoaaruommiscaahhyyeinmnngioocattaglaaeccpcncrutousrpraaoftrrtoeetlmliyyom rnreeofuffllleetticchpttele tttheesesttessnaavmmiprplolene.m. ental properties of the fluorochemical proportion of the SSTTUUDDIIEESS ZZDiiennmcc,a, niirrdoo;nn,, 5aa-nnDdda yccooBppippoecerhr eccmooinncttaeelnnttO;; xssyuugrrffeaancceeDetteemnnassniioodnn;:; TCCohxheiemcmiitciycaatllo OOxxyyggeenn Fish (species Dnn(osoetptmeggciaiivvneeedsnn;))n:;5o-tTTDoogxaixivyicceiinBtt)yyi;ottcoBohaWWecamtateitreceiraralffilOlenehaxaiyb((giDDteaianoppnhDhn(neisimapaeammcnaiadegg;snnaTna)oo);tx; igTTcioiotvxyxieicntcio)ittyyFittsoohAA(llsggpaaeeecies (species not given); Bacteria inhibilJon (species not given) RReeppoorrtt ddaattee:: 11997777 MMEETTHHOODDSS:: CaChnhedemmpiocictaaallssOOixxuyymggeedinnchDDreeommmaaatnen.dd wwaass mmeeaassuurreedd uussiinngg ppoottaassssiiuumm ppeerrmmaannggaannaattee and potassium dichromate. dBBeiiogorccahhdeeammtiiiccoaanll tOOexsxtyyggdeeevnneDDloeepmmeaadnnbddyeetvvhaaelluuBaauttneedddesuuassniisnntggalaatTTfoouttraalGl eOOwrraggsaasnneiircckCCuanardrbbeoo.nn degradation test developed by the Bundesanstalt fur Gewasserkunde. TofToxorixcwiicatittyeytrtooteFFsiitssihhngww(aaDssEVeev)vaaLlluua1a5tteedd aaccccoorrddiinnggttootthhee GGeerrmmaann ssttaannddaarrdd pprroocceessss for water testing (DEV) L 15 pTToroxoxicicceiisttyys ttfooorDDwaaappthhennriiaatewwstaaisnsgee(vvDaaElluuVaa)tteeLdd1aa1ccccoorrddiinngg ttoo tthhee GGeerrmmaann ssttaannddaarrdd process for water testing (DEV) L 11 11771166..00000011 EExxhhiibbiitt 11771166 State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNNO011665577779966 TTooxxiicciittyy ttoo AAllggaaee wwaass eevvaalluuaatteedd aaccccoorrddiinnggttoo tthhee GGeerrmmaann ssttaannddaarrdd pprroocceessss ffoorr wwaatteerr tteessttiinngg ((DDEEVV)) LL 1122 TThhee mmeetthhoodd ffoorr eevvaalluuaattiinngg bbaacctteerriiaall iinnhhiibbiittiioonn wwaass nnoott ddeessccrriibbeedd.. RREESSUULLTTSS 7 [>ioo0mar| Fish LC~ Re~ult~ >1000 mg/L Daphnia EC~ [Rites Algae ECso Bacteria inion Bacteria inhibition [soosiico BOD21/COD Z[2I0b0si--d|| >250 mg/L >250 mg/L Inhibited ~7% RReemmaarrkkss:: TThhee aabboovvee ttooxxiicciittyy ddaattaa ddiidd nnoott have tteesstt dduurraattiioonn iinnffoorrmmaatitioonn.. DDAATTAA QQUUAALLIITTYY RReeliliaabbiliilittyy:: KKiliimmiisscchh rraannkkiinngg == 44.. AAllll ssttuuddyy vvaalluueessccoommee ffrroomm aa ssuummmmaarryy fist only. No raw data or method documentation was available. The study sslisuutmmommnalayrr.yy Nffaaoiillereaddwttoodddaiitssaccloloorssmeeeddtuuhrroaadttiiodononcoouffmttooexxniicctiaitttyyiottneesswttiiannsgg..avIItatiisslannboolettc.cllTeeaharerwwshthuyydy `smsauutccehhrilloaolwwsbbtihiooaddteeaggrrraeadkdabnaioblwiilinttyytwwoaarsseaoobdbssyeebrrivvoeedddegwwrhhaedeenn.tthhTeehpperoosddauumccpttlssecpoounnrtttaaiyinnwas materials that are known to readily biodegrade. The sample purity was nnoott pprrooppeerrllyy cchhaarraacctteerriizzeedd aanndd tthhee ssttuuddyy llaacckkss aannaallyyttiiccaall coonnffiirrmmaattiioon ooff the amount of fluorochemical proportion inthe soluion the amount of fluorochemical proportion in the solution. OOTTHHEERR St.Paul, Minnesota, 55133 `SSuubbmmitittteerr:: 33MM CCoommppaannyy,, EEnnvviirroonnmmeennttaall LLaabboorraattoorryy,, PP..OO.. BBooxx 3333333311,, St. Paul, Minnesota, 55133 LLaasstt changgeedd:: 6//226//000 11771166..00000022 33MM_MMNNO0011665577779977 Lap TTEECCHHNNIICCAALL AAW WAARREENNEESSSS 0: TECHNICAL COMMUNICATIONS CENTER -- 201:20N TO: TECHNICAL COMMUNICATIONS CENTER -- 201-2CN (portant -Wheneverpose, aac ullcopyofthemarr you hvessc) (important - Whenever possible, attach a full copy of ~he material you have abstracted.) 3a ric A. Reiner JC Environmental Lab (EE & PC) F, ric A. Reiner s..,ce Baim took 0 ro 8 aie OGRE AEST ['] Journal [] Book [] Patent . I Environmental Lab fEE & PC) I Location o! Original [~'Pi..Otherspecify) GP-rm.Rn~t ~~ 47816 47816 Reference (e.g., Author. Titla, Isle Date, Volume, P~e, ~ .): oDDFFfrroo..aumnWHHa..tCCeoomrHHmpeepollToulleunmmcnd~ahdsnnns.o""laaonngddTTyhhDDee..fsosMrMttuuuudl!dtypy~hrre,,wv"a"aWsEsEennstvvcciiaarrGrrooerrnnirimmemeeedadnnnttooaauuAllttgebbnIyycmypattchhfteeorWoWefMessittlFiitrGGeaeerrrymmEaaxnnTteicDnDhegenpupoaialrsroZthgmmiyeennngt$ oa:~~nnddWaPPtrreoorccuurrToeemmcoehnnntto..lozy((TTfrroaarnnsstllhaaetteeddWesbbtyy GGG..erDmDiaienerrssAsngeoennn,,cyMMaafrroccrhhMi1i,,lit11a998r800y))..Technology TThhiiss rreeppoorrtt ccoommppaarreess tthhee eennvviirroonnmmeennttaall aacccceeppttaabbiilliittyypfpt 66 AAFFFFFF AAggeennttss `FFiitCCnno--ccx22lli00uuc66idd,,tiiynn,ggaanndFhFdCCeaFFvCC33--y00221100m7700e.,t((aiilddTTeehhcnneeottniicfrfreieieneesstddeeraaarritccnihhoeetnrrh,sse marmeeenpaadossruustrrueerdfdaascbbeFiiCoo-ddt2eee0g0gn~rr6s,aa,idodnaaf.bbriielleiizTttehyye,,prroeaatpqqeouucraatttteiidcc), ~atrrtooroeexecciobbocmiqimimouoetdeednyensedg,dgtsrs~riaaohddneaaeeaavv,,bvoolyiiebbdd.umuiittenntggaCttlouhuhesmseeepcabobrnoiioicffooesddnoeetttnhhggrseerraaatddoSSifaauMottniAiAB,oFOoFnDFnFsFFanrrppdaeerrnssoosuudddulluuttrCcsscfOtatDscsaaesnnhsddsioitnwenttcnechhesdeeeiiiorrtaanlhl.ilaiitnnwwtteeTeterrhrhreeeepprrdeerd3itetifapafoftftpriiiirtcooco-ununlltt daoadaruuruuecctgttthahssonoqriruscsewwseetrrcccieehhaooornssmbmaeeooobnrrleetteoo(.rrTge0egiCaai)vddvCeieiollmcyympmoooanrrrddceeieeesggnorrtccnaarrrsdadeeetedddiodeefonnnccttheeBhateaonDnvt'ooSetrttteehahsesneattdsscc2oC1ommOmmeeDppdaaeaessysttuuhiirrottpiiweiinnervvigdgeeodpptdd.rrhiiooassddtssuuToocchlltttevvhssesee,,eddSMttyyteeeoottsttptaarsllott-hheegave porrrreeogssdauuunlltictsctssctthahiaarnttbeoxnwwpeelrri(eecTaOCbii)lnnyccoocndnossiniidcssettnmeeotnntrttatdwiweoigirnttahhdoevtt.ehhree BBaeODD21rrdeesasuuyllttpsse..riodII.nn tthTheheseseseettetessettsssts 33hMgave products inexplicably did not degrade. C,)(~y L +,t (cupie$1o be sun! by originator) Harmssmi on formaepublshd ntheSM TchniclAwana Gaz. Items submitted on thim form are publi=hed in the 3M Te=hn|cal Awarenem Gazette. 11771166..00000033 33MM_MMNN0011665577779988 CB10ou.mnpdAlepismraeinnlstta1l9tto79RfeiprorCtevoafsserkmde x1i0b. /A31p0r~.l221/9275996 ~.)flb/340o 22/2596 ~Bavironseatel Impact of Tire Extinguishing Torn Conpomds. BndessatStfuudryNecharrcraicehdaiokutunfdorBeschatfung Bundeomat fur gehr~echnLk und BesehaffunK (Government Agency FFoorr M)titllilttaarryy TTeecchhnnoolloof|yy aanndd PPrrocuqrrem~eenntt)) RReeppoortrt:: BBA~ 111111 11--tE/B/B3311EE//7700114455//77660D6666 ooff OOccttoobbeerr 122 1197777.. Reportar: ~tepor~erz ObarregtermgeratDr. 8: Hellman - Oberregieruagevat. D. Willer Li ee a Kobleas 1979 a UE 11771166..00000044 ei nan IR 33MM_MMNN0011665577779999 a-I- Table of Contents. Table oF Contents. "7 I1.. IInnttrroodduuccttiioonn PPaaagee 3 2. 2. Dattndtion Definition of of Problem Problem asnndd TTaasskk ` 3. Test Rasulcs 3. Test haunts 5 5 3.3 Physteal- Chemical Tests. 5$- 3.2 Tests for Mochesteal Degradation ' . 33..33 ~TYoexxii~ceo~looag~y TTeeset~se 1122 4." Bvaipation of Tasslts and Ghacloaten 3".OrTRdaoeccorommimmnmdgnadt~SitpioeoncnsisffifoocrratiTToeenccshhnniiccaall : - Ordains Specifications 115 1- 6. Concluston 19 19 Baclosuras: Knclosuras: Addsesons LLiitteerraattuurree lliisstt ; : wt y y : #3 SfAfLoS eYt EaWINE l etda aea yA 11771166..00000055 33MM_MMNN0011665577880000 a-2- 1. nemobcrion 1. INTRODUCTION ~~ FToorr ftiirree ~exxttiinnSguulisshhiinngs"- ffooaamm ccoommppoouunnddss oonues cc~ann d diisstitnig~usishh ssiixx aapppplliiccaattiioonn cegtons: 1. General application (local fire protection) 1. Central application (local fir~ pro~ee~lon) 2. 2. SSoollvveentr iinndduussttrryy 3. Fighting of carbsnhydride fires for instance in refineries (closed systems) 4 Blsctrical equipment, Migh voltage 5 st oritcattons 1a airports. 5 6. Applications on ships. Sup laporiascn Gr. 55 1s ahvious, thet + fev sveonts fa sien ohm HAS d0 . ` In the present study 1t vill appear that airport fires take on prefers i. In the p~m~at study it vii1 appear that airport fires r~l /~portanca (1). It is obvious, that few seconds !n t~ can portent portent difference difference ffoorr ssaavviinn~g hhuummaann lliivveess,, aanndd tthhaatt tthhee qquueessttiioonn ooff w~ avioee- : meatal m~nr.a.l. eennddaannggaerrLiun~g @ essppeecciaallllyy ooff vvaat~earrss aanadd ssttrr~easaxss ddoosees aessssuumme~ sao~ me vVhieaSt: Lleessss ii~mppoorrttaannccee.. BBuutt wvaacteerr ssaaffeettyy nneeeedd noott bbee coomapplleatteallyy oovvearrllooook~edd sessppeeccli-. - 1d eratatag. RS aalllyy bbe~caauussee mmoosstt ooff "tthhee accttuuaallllyy ussmed tflire~ ~ extxintgulisuhi~ ng c~ ompo oun~ ds aarree uusseedd +7 The Bendaazatale fur Gevasserkuade (Dept. of Vater Technolop) in 1975. 9% the task from the Miststeriums fur Ersibrung, laadeljtachawtte Foust.' (Mfatstry of Food Agriculture end Forestry of Nordrhain-Westfalen) to pvale uate the ipact of fom extinguishing cowppunds on the water quality. Thirty: eight foun extinguishing compounds from 8 suppliers vere evalusted cheateally; physically smd biochemically for possible endangering of water." piteienat brinddsl'a vary 1a degradation sod coxtetty. Kepactally theSi' tien ektidg/- wedibing'soturtons weed can result ta tha folloving damigps 11771166..00000066 33MM_MMNN0011665577880011 > - - PPoottsaoonntinn~g ooff nnaattuurraall vvaat~eerr ppuurriiffiiccaa~tiioonn ((iinn ssttrreeammnss)) ~~ PPootlaeonniinage or or dd~emnaagsee to to ffiisshh ~anndd ffiisshh ffoooodd asnntim maallss.. - - RReedduuccttiioonn ooff ooxxyygseenn ccoonnttaacctt bbyy msettaabbolliiec pprroocceesssseess ((ssuurrffaaccee oorr Sgrroouunndd vvaat~eeer)) -- RReedduuccttiioonn ooff w waatteerr qquuaalli~tyy bbyy oorrsgsenm~ic ccoommppoouunnddss ((Sgeenneerraall)) -- UUnnddeessiirraabbllee rreedduuccttiioonn pprroocceesssseess ifnn t~hheo g~rroouunnd~wwataeterr.. | This report was publicdimzPeevdha.. Ghkadirosucaeiydy. eftention)fuk the Parties iavolved, such es the manufacturers of fom extinguiehiis compounds s#a2u4l. t~ he aauut~hhooririttiieess rTeessppoonnssiibbllee ffoorr wva~tteert ppuurriittyy7.. AAmuomn~g ootthhe~rrse,jtthheesses acoennseiidd-- cerreaetLionn8s w veorree ~taakkeenn iinnttoo ~accoouunntt ~inn ~thhee DDIINN-- settaannd~aarrddss.. 2. DDEEFFIINNIITTIIOONN OOFF PPRROOBBLIE~Mq AANNDD TTAASSKK ." t" ~" After several ddiissccoouurrsseess ~tnn 11997777 bbeettvweeeenn rreepprreesseennttaattiivveess ooff ~thhee BBuunnddeesasaaut~e8s ffuurr gVeehhrrtteacchhantikk aenndd BBeesecchhaaffffuunnKg sanndd tthhee BBuunnddeesss~anssttaal~tt ff~irr ~Geewwaus~- eseerrkkuunnddee ((BBFFGC)),, tthhee ~B1P~G ywaess aauutthhoorriizzeedd oonm OOcctt.. 1122,, 11997777 ttoo caazr~r7y oouutt a esppea~t cciiaall ss~tuuddyy.. TThhiiss ssttuuddyy sshhoouulldd oonnllyy ccoovveerr tthhee pprroodduuccttss uusseedd bbyy tthhee BBuunnddemve~hho~: ((w W..cG~errnaaann aaf!llidVeaerryy)) aanndd aallssoo pprroodduuccttss wwhhiicchh aarree ccoonnssiiddeerreedd ffoorrppoosssslibbllee m nev Antroduction. . As a first objective, the environmental influence of the folioving six 1. extinguiehiag compounds should be determined: . 11771166..00000077 33MM_MMNN0011665577880022 a-4- o Product Produc~ Manufacturer Hanuac~urer Ta1 2 2 3 FFlluuoorr pprrootteeiinn LLigighhet eWtaetrer,, FFCC 220066 "~Soo;~n Light water, 1c 206 (frost proeeeted) light Uater, C 206 ((~noorrmea~l)) FFiirrem DDrr.. RR SStthhaam meerr,, HHa~mabbuurrg FFiirrma 33 MM,, NNeeuussss Firm 3K, Neuss Firm 3 M, Neues 4 Li(gaohrtaaVla)ter,FC 200, Ti 3Mr , Nee uss 5 ProtFoeamiAlnd FireDr. R. Sthamer, Hamburg ' 6 mprirs Fira Soschat As, Frenkfurt/loschet | F~ra Hoochet A~, Frankfurt/Hoechet The Th~ tvo two types types of of Light-Vatar Li~ht-Water aarree ooffffeerreedd aass bbeetinags ""aesgppeecct/a~llllyy ssaaffee ~too tthhee ~ emviim ren~ mentt"" ((A Accc~orrddi~ngg ttoo B BW~B)).. LLiigghhtt WWaatteerr FFCC 220000 1~s8 ~ reprotretedd ttoe be out of production, but should be evalusted for comparison. The teat for be out o~ p~duct~, but s~d be evicted for ~a~s~. ~e t~t ~or environmental {apace should, 1f possible, ba tested for SI solutions se uesd @8v~ronmentgl tnpac: should, If possible, be ~egt~d or 5Z soluttone 88 u~ed ((ffoorr LLiigghhtt W Waatteerr 66%Z)) atendd eennccoomuppauses tthhe ffoolllloowwiinng ppaarrsm matteerrss:: -= S|uurrffsaccee tt~ennssiloonn aaccttiivviittyy : - Bochaatcal dogeadaiton ~-TTooxxiicci~tyy - Sioehaatcal dosrada~i0n - Theme potat. ~- CCoonnttaenntt ooff hheeaa~vy7 mneettaalles ~la point. ...: " . - ... ;: . ~...,,,j. a . G . .":i~:""~i"~.'.~"~_ '~'~ TThhee ffiinnaall rreeppoorrtt sshhoouulldd allssoo coonnttaaiin rraeccoom~meennddaatttioonnss ffoorr tthhee tteecchhnniiccaall The 1261 report vas scheduled for completion {a Sept 1978, Dust, [pp~rooccuurreemme~nntt esppe@cicfl~icicaattiioonnss ((TTLL)).. The flJml report was scheduled for conpletton in Sept 1978.. ssiicckknneeasss, oo~f oonnee ooff tthhee iinnvveessttiiSgatoores tittvawa~s dde~llaayyeedd ffoorr some`woaths. fe Pera 4 ae 11771166..00000088 . Shs ig 33MM_MMNN0011665577880033 --5- R 5 mst msm 3. TEST RESULTS C31 Mhystcal heateal Tests Chemical To toedTbhye frat X~-irrasyt cftealnuseotrrre~sucaneuntlcteg5Kl)i~v-veese the the hoary hea~ mmeettaall coonntteenntt vwhhXicchh wva8s8 ddaetteers- m~eed by X-ray fluorescence . Evaluating che figures of Table 1 Mating the hasvy metal content, the ~ two ~ compounds Fluorprotetn the flgure8 of ,mupeun,is l~luorproeetn (Ho 1) and Protets fora eempoumd (Mo 5) Table 1 118t~ the heavy ne~l content, (No 1) and Protein fomt- empound (J~e 5) Stand out. Tor Tisorprotals the sisc end fron conta of the applictastics "eelation (stxtures) vith 40 ead 35 me/1 respectively, fa relatively high.' " To~orrt~ he s~ econdco~mmpoouunndat~hhee 4amro,an ceoonntteennt~ oof~5S0o a~g//'11 s~vt.,amn~ddss oouutt.. A~L1L oott~hr~x, : beavy ~ natal u~t:a~ coonnceeennttrraat~ioonnss ssuucchh 8a8s tthhoe eessppaecetia~l1l~y rroaecoorrdd~sdd lleevvea~les ffoorr cooppppee~r aarree uinmpuoprotratnatn.t. Table 1 1 ` Hoany mmoetteallccoonntteenntt iinnffoouan~eexxttiinnguiisshhiinngccoompoouunntds8,. pal bo Fo "riginal Products non 5% Solutions =n & ral, To m Lm we e aa wit po 27 f3 ood` wo0 now "oon oo atos Qg0.Eo0 p Huieyll | it T 2 mLA a ol or set os oi Hie [XE - . TET 1) Daterntond by Ds1. ch. 5. sebteenare 1) Deternined by ~Apl. Schla:Lchez-t Fy Ch~. U. Rs 11771166..00000090 33MM_MMNNO011665577880044 6--6- When When the the flase fla~_ point point is is deternined, determined, tthhee rvaatteerr ccoonntteenntt ooff tthhee ssaammppllee mmuusstt bbee ccoonnssiiddeerreedd.. FFllaaumee ppootianttes aabboovvee 1XO00oC0C,, tthhee ~boXiXl~inngg ~ potatt ooff v~aatteerr,, = could could ~woet bboe ddaettaer~ nteadsd.." Ae ~ ccoou~ldd bbee e~xpcetcetedd nnoomnee oo~f ~thhee s~etsetedd 8sa~m1plee8s d4id4 h~avvee a4 ffl~ ea ppooiinn~t b bel~ ow 1~0000oCC.. I~t s8hhoou~ldd bbee oobbvviioouuss tthhsa~t snoomnee ooff tthhee Products vould comtata flammuble solvents. TThhae ssuurrffaaccee,, oorr flnntteerrpphhaassee tteennssiloonnss ccaann bbee sseeeenn ffrrooam TTaabbllee 22.. ~) TThhee s8uurrff~aJccee tt:eennssiioo~n rvaattearr//aatirr tg~enneerraallllyy ddrrooppss 8soomuee ffoorr coonncceennttrraattiioonnss ffrroomm 5500 rmagg//1l ' 0300 mg/l. S00 =s~. The ~, ssuurrffa~c.e, tteen..siioo~n iis, lZaess, tt eaffffeeec=teedd ffoorr SKoo5S ((hProottee~in--~foo.s=m . ~.--i':: eexxttilnng~uuiisshhearr)),, smoosott aeffffeeccttoedd ffoorr ttvoo LI~i8ghhtt--W Vaatteerr ttyyppeess ooff IFCC"220066-- ttyyppee.. TThhee eresasseonn ffoorr tthhiiss Ifse ffoouunndd ~inn tthhee cchheea~iccaall ccoommppoosisittiioonn ooff tthhee eexxttlikg~uiIsshhlinngg compounds. co~pounds. PPrrootteeiinn flooaunn aaggeennttss ccaann bbee eexxppeecctteedd ttoo bbee ggeenneerraallllyy Iansaceetilvv6e ttoo the the vater/atr water/elf iInntteerrpphhaassee;i wvhhilZlee tteennssliddee8s aanndd aallseoc ssoo ccaalllleedd "t'ssyynlltthheettiicc-p'pror_o dduuccttss aarree 1fantteerrpphhaassee aaccttiivvee.. TThhee Itnntteerrpphhaassee aaccttiivviittyy i{ss lleessss a~ pprroodduucctt specifi, 8pecl~Ic, bbuutt rraatthheerr aa g~rroouupp sspveeceilffilcc cchhaarraacct~eerrslsstt~ic.. Tabla Ta~1. o 22. Intershuce Inte s"~e.tctiivviitt,yy ~!fl~e NHOo.. Interphiee Interph~e 'aAccttiivviittyy xxt~ 22o0CC ((ddyynn//comm)) 0- 100 i 0 %0 ; : : 2' " `3| I . $ " rt 0 " n wo o nC 33 o a 0 ow " 8 B a 2 DDeetteerrmmiinneedd aaccccoorrddiinngg ~t:oo AAbbeell--PPeennsskkyy tinn cclloosseedd vveesssseell;; DDIINN 5511 775555,, EEdd.. 996666 3 Ilnntteerrpphbaassee-- TTeeanssiloonmeetteerr,, aaccccoorrddtlnags ttoo NNeoooyy,, F~ilrrmm.. AA.. KKrroomsss,, HHaammbbuurrgg 11771166..00001100 33MM_MMNNO011665577880055 --7- 52 Tase for Mochemtcal Degradation eva She waspete aracaritic ofcomms, se aot oo com fe cmon pet edt erg 4 Totiitim By 5 e0l)chraommtbe wsestke,soev)a.tThe biochenteal sotto oxrgen speaks fod vin 55 erin Aly evaluate the degradation. Wben the CSB analytical test 8ives reliable A results (this, for instance, 1s not slvays true when hyceophoble compoimdd + "3 acd Satay tested) ome mune conser positive result darivad from che Same vaf1o'ss useful,vhtlenegativeresultscannotbecomted, since thesday 1 Sackhation parted for the Mi-test under seme conditions doss aot sasiepens sufficient tina for adaptation of the organisms active in the bologteal Dobkin. Tt 1s ot cersata thas toste {abhieons can bo excluded ds "aacpaondsaztdl5e38by(5)e.etaTosibnegteahrefSns5ur8e8resaucltts,coonnceemraainagctahreydeogurtadaatxioonn) sthen dopritacton tase, hare che tacubation tine, the fsoclationmaterial and otha pacenatars other parameters aaxree ddaettearrmnt!aneedd,, ssoo c~hhaatc ffuusrtthbaerr bbrreaaskkdiodwvnn tthh~ann ffoorr tthhoe Fiv~e: aap MtBant can bo evaluncad, ~Y ~-~ ~n be ~~. "' : At At preseat pr~ there there are are fatemationsl ~te~atl~ eeff~fee~rts~s ~wnddee~rvaayy ttoo d~tta~nddaarrditizsoe def d~"..... ' fein compounds & nev 7.0.degradation T03t (6) devatopad by the Rmtuasirtate 44 total argante carbon (100). fur Gevasserkunde was used. Ite test criteria is the complete breakdown of hd the orsi organic carbon (TOC). ,"'FFoorr tthh~e tt:eesstt pprroocceedduurree tthhe tteess.tt ccoommppoouunddseaerrvvees~ aasstthheeoonnlZyy saoouurrcc~e ooff carbon. Inorganic mineral salts are added in advaice. The incubation takes Placfea a derwvecap flask vich ate apace, placed fa a shaker, au pZae~ ~a 8c~p f~sk ~h ~r space, p~ ~ a ~r. ~"d~r~- ibn"bate for th t15e extinguishing foun compods wr carried digrada- ~on ~ts for t~ fire ~t~g~8~ f~ ~uNs ~re ~rrtN out:it 20 C " ~ ut at 20C 1au'e~nhee ddasrrkk~, /isat ddemvvi~aatti~oonn ffrroomm tthhee s8traaCteedd tteesstt pprroocceedduurreess.. 3 . 11771166..00001111 33MM_MMNN0011665577880066 +-8- When When the the ppeerrcceennttaaggee bbrreaaskkdioovvnn accccoorrddilnngg ttoo tthhee TTOOCC-t-etesstt iiss ccoommppaarreedd ttoo ~-----rerseusu~ltt8s ffrroomm ootthheerr ddeegsrraddaattiioonn tteessttss,, Iit nmuusett bbee ttaakkeenn iinnttoo `aaccccoouunntt,, tthhaatt tthhee dasppescace of one material from the solution is often considered as de- disappearance of one ~ateriX froa the 801ution ~s often considered as de- Sradation. Under ceratn circumstances a high degradation can be simulated Under cera~n clrcunstances high degradation can be simulated hich vh~ch aaccttUuaLltllyy I1Ss bbaasseedd uuppoonn pphhyyssilccaLlt pprroocceesssseess ssuucchhaass,ffoorr iLnassttaanaccee~sabbasoorrpp-- 10m of solide vhich has 0 relation to complete biologics] braskdovnamd r.~on of esXJ~le vl~ch ha~ no r~ation to ~pXeto b~olo81~1 breakdovn ~nd 94h3a0eacrentntgsftoortchoempelxpeetreileynwceoslagkatihaecreodmpbeynpesrttiecisreotimonatalo@verrouindnror ~l~ ~ t~eulte for completely ~olubXe compounds a~ ~~ l~r e~ ~, .-..~- hin Che reskin 1s mented by the "modORD renning tat" (3, TEMat TThhies. " some ademstagesspre ve:ta mmooddlf~ioed OECD --ssccrreeeenn!irnigg Cteosstt"" uwaass degra ttaesstteedd bbyy da i est. dss i/nnttaerrnnaattiioonnaall rroouunndd oremte~set~s.~. ath cant 40 only vali datiand vhem a ota besskion 1s recorded Tn cases lace tha products tasted hare are aixtures uusseeddtfoorr teossttLiun~g oof emnuullsiloons aanndd ssuussppeennssiioonnss.. Sine the products tested hare are uixtures tthhea reste results Ooff tthhee dadeg~rraadd-- at~n test is onXy waX~ defined vhe~ corral breakdovn is recor4ed~ ~[n c~see Vhare perticls breakdovs fa Ghaecved,chia can be dus to the fact that oaly Part of the product can be broken dovn, while other parts can not. The braskdovnofmixturecanthenbemanpulatsd by the mesufastursr by addition Of compounds of-compounds wwhhi:Lcchh aarree eeaassiillyy bbrrookkeenn ddoowvs~,bbuutt ootthheerrvtri~ses wwiitthhoouutt ffuunnccttiioonn.. & | ~Evveenn ~t:hhoouug~hh,, iitt i1ss uusseeffuu~l ttoo tteesstt tthhea bbrreesskkddoovvua ooff tthhee pprreesseenntt umi~xttuurree : Products because Productsbecause iLtt ggiivveess a pprreell!iJnn~tnnaarryy rraannkkinn~g ooff tthhee pprroodduuccttss.. FTootr Fature : 4t, teats, V~hhiicchh ccoouulldd bbee ~ carried out'out aafftteerr & ppeerriioodd ooff a ffee~v yyeeaarrss ooff uussee,, ' should it'Sbould belie attempied attempted ttoo tCeosstt tthhee bbrree~skkddoovwnn ooff tthhee ssiinsggllee coomspqi~nsennttes o6ff the products. 11771166..00001122 1 PR 33MM_MMNN0011665577880077 --9- f--. EESULTS: TIA does Laat he mses eset Shesand Table 3 does list the neasure~ent results obtained for the orS/hal PEodata, evaluate the potential for sadsgerias fr che ogtnnt products, to evaluate the potenelal for ~ndanser/ns of She water. Table 4 Hate the peancae of agradacio of the appscacioof he vatar, sunte lises the Percentage o dsErada~ion of selueions afin sored oF dara days ~to8geeethheerr w~ ich oot~heerr degradacion PaTERSCrs of {ntarest. Tha specific' TOC- degradation curves are incorporated ia attachments 1-6. tg "me Yalwes ebtained from Table 3 show that the differeat products contats varyingsmountsof organtecompounds. Ofcourseonsshouldcount a lowcontent of orgaate matertale and of orpeate carbon found 1a products 1,4 and S as Posters actors vie vases adasgurag 1n 0 bo gut, ; Tor th spplscaston solutions (cable 4) he 699aad E5) are 14uted so. ~8~ve factors ~ ~ter e~nse~s is to be JudK~. : : For the applteaelon solutions (~able 4) the ~P and #~B~ are l~et~ t~ - gether with the ratio between these two factors and can be used in addition 9/30 TO dagrdaston emus tach avsltions. ~. ~e ~ ~gra~Cl~ re~lt~r.t~.~t~. Accor~ to the ra~o Ancontng 0 toe sus + hethe ppr~odduucctt ~ No 66 ssh~ oud ld bbee c~osntsdideerreedd assy 0 degrade. Tor the products 1 (48#2~4 35, W~ hich aaccc~orrddi~ngl tt?o tthhee ~ THC- ddeegsrraad~ateiio~n test appes mediumdegradable ; eoac0oulSd scoretly bfermdeaeomchceachoemnteact eaxt3ti0onmoof o11r0eactcoaspresn nms (~ al~ eseabl~sh~ f~m ~he ~taboli~ t~) 8, Te dugeacon of anch Joc, spaeatals, a evatoted a sotto Son]Jotue,e0x;ticngouimshminog ncomapnotunhdoNwosk sohnodvsBaacfaarvtoarasblceiornatfino osfhKeemaa0r,pucpoenesusmp 039.50248,PrCootgiacttheNrow2itshhoave477fTa0vCe-radoeigeradCatMionD. It must be raced 8 medium degradable. ratte, bt since th ines ths FeV -do'mbt" indicate a good ot TM degredation of degradation Tate it is product 3 1s even less classified them that as difficule to degrade. Oe ities we attics vo sete, of product 2, so it oy oR Even though the degradation duriag the T0C-test vas forthe strences oe Gad EER 11771166..00001133 33MM_MMNN0011665577880088 -- 7300 Forel Fezeo oble 3 PPootteennt'iizall "foorr NYoo MKM0nO,4 uUs~Oed~ i shee eenndd,a.n~gnear~iinngs ooff wwaatteerrss bbyy Kr, K2CrO7 uusseedd OOrrgg..~0 ccoonntteenntt wn ait ,oorriiggiinnaall pprroodduuccttss B CG~oo2nn~tteenntt aa)) oOrrggaannitce ppaarrtt b) 1 1 to 0.03 1s ours 2 00m 3m 0.34 3 0,085 29% 0,22 soon tn 0,30 Sosa 2m ow $e 4,03 on 4) only wproxinate values " 5 7" " " 10, "ot 2 " 8 b) only approximate values, durnoff values at 600C and variable duration TTaabbllee 44 BBloiocchheenmioicaall ddeox~rer~ddaatti!oonnOoff, aap+pplliioc.aatt~i.onrreoaaddy~ seool],uut~iAoonnse((5~ 6) o Bate of Cal a aeol,4 m(ay KnorEo)rp)Bmo:eB05n 508 888, Degrad. Degret. Fina TEmE nmethavol.intou 2o)o. ten Elon prtns 5.000 % 1 40% ol.I ~.I 2)e1l 0ee)l oe | mottan Few) Lodhi iy 1.0m iy oF Feel yg iusaedas, w,o,eooeo 33 0s. .O adiiftftioi~ondst . dirrioalt FCT 120 16.500 44s 34 00 - 2 adstfefrls0o1u1ltt S110 20.000 3.2% 60 02 4 eoddiut.a. +. " 6.230 2.000 41.000 08 1,1 " oo otn~ iyuat~oo --_--_-- = 2) Z) Evalustion ~aluation ooff bbiioooohheomatiooaa~l ddeeg~rPaat~aattiioonn iinn ~ 00-- tteemntt ((aatt s=t+aannddaarrdd * temperature of 250) o0-- 22o ~% adlifrfftieouulltt ttoo ddee~rrraaddee 2200 -- 4400 ~ e+1l1ie~hhttllyy adeeglr~eada~dtlee 4400 =- 7755 %% lmoeddliuunm ddeeggrraaddaabbllee ?755 =- l1e60o %~vvee+ryy ddeegerPa'daabbllee 11771166..00001144 i 33MM_MMNNO011665577880099 ue -11- ffoorr pprroodduucctt 44 Cthhearnt ffoorr pprroodduuccttss 22 eanndd 33,, 1it wvaass ccllaassssilfflieedd aass ddHlffffilccuulltt ttoo ddeegsrraaddee.. th~haat~ FFoorr fflirrse eexxttlinngguuilsshhilnagg t46t ccaann bbee bbrrookkeenn ddoow~n.. ffoommn ccoommppoouunndd 55,, A F~innddiinn8g wwhhiicchh tthhee mmeettaabboolliissmm tteesstt iLsn coonntfirr~eoedd bbyy tthhee Ifnnddilccaattee8s rreessuullttss ooff tthhee TTOOCC-- tteesstt.. TThhee pprroodduucctt f1eo ccllaassss~if1iaedd aass nmeeddliuumm ddeeggrraaddaabbllee.. : For product 6 ue f1ade a complicated degradation bebmvior which aight Flsisate from the high toxic affect of this product. After 7 daye degrade- ldouya$fl6arr e114at0a7dsotyifatghdeaTy0s,Cb1ustbrtohkeennsdeowtnn.tenFsuirvtehdeergdradeatgiorn aTendodiuansgtTeimViotianse d4o5w6n87of7 6t0e2sot fdtayhsescatnarbteinegvaTlOuCadteodseastaaknepadiaapctea.tioTnhepesrlioowddfoowrn1thaebmriecatrdoown organten favolved. 33 Texteotonstasting sreon (@), tThnethreesu"lStvsalcuosnticoenrnionfgtthoexVicateerffeEcntdsangteorvairndgsbaylgFaoessanEdxtbiancgtueirsihainvgerCeoudpiosucaudsssTMed. , Tthoethries8~ev8aluca~ticoen~vnhgich~o1xslccoen~cfeecr~nesd~wircdh8tasatle~ofoarndprobdaucc~tesr~th~ atreposdsiibaley ~.. Could be uaed Ln large amounts, the Coxteolory seatevere: dacemstfind, 1s > addition co the facorporation- metabolism tests, also tests vith small crab 40d 1fi6shh v~err@e c carari~ ed oouut~.. contiraed. T~hIiss vvaa~y ~thhee pprre~vioou~s rr@ esusl~tes cco~uldd bb@e ffu~ rtherr ccaansse hTheettooxxi1coollssyytteesstt 11s8ccaarrrriieeddoouutt aaccccoort~dtiinnSg t~oot~hhee GOeremr~ennsst~amnddaartddpprroo-ffoorr wvaat~esrr tt-a-sttlinnSg ((DIEVV)) ((44)) LL 1111,. LL 1122,. aanadd LL 1I~5.. Tl~orr tthheessse,,tchhee Llaattee~st ~Feus~t pprroocceadduurreass vweerrse uusseedd aass ppuubblldisshheedd Por fish-tests tha concentrations bbyy tthhee rreessppoonnsslibbSlee ~woorrkki/nngs ued vara from 0 to 10,000 ccoommintitcCeenes8... mg/1, where Pot flsh-te~ts the coucentratlons u~ed were from 0 to lO.O00 ~S/l. ~here ; it 7117166..00001155 33MM_MMNN0011665577881100 12 -12- a8 llaarrggee ggrraauvas~tiioonn ooff ddiilluuttiioonnss veaass uusseedd.. ~Thhee ffuurrtthheerr ttooxxoollooggiiecaall tteesstt ~veerrse carried carried oouutt w viitthh si~maalllleerr, ggrraaddaattiioonnss ffrroo~m 00 ttoo 221100 ~ ng//lL ttoo ..f~ asrue re,, tthhaatt tthhee - pprroodduuccttss ccoouulldd bbae ddiiffffeerreennttiiaatteedd aass ~weellll a8s ppoossssiibbllee.. mss: I~SULTS: Ia~Iu tthhee eenncclloossuurreess 11 ttoo 66,, tthhee rseemsuullttms ooff tthhee tcooxxitccoolloosryy rtaessetss are,elre: presented, .preeeatI[~:- 48 dose reaction curves and the results are calculated and presented fn Table 5... + Product No 1, "Tluorechamgetst (Raclosure 1) 1s eo toxic at concentratioin"s I 1, "lquotsehsISeist (laeXom~e 11 l~ ~ texteat eoneenCretion~ .iii~i: of 10,000m/2 that 411 test entaals dd dte (0c,0 = 10000 w/1). Bue for 88 concentration 1000 ng/L the product da sot detrimental (ICs 1000 m/D): (X0- attaceive concentration vith respect the corcesponding teat. 86,00 ds tthhee lLoovvaesstt tteesstteedd ccoonncce~nnttrraattiioonn ffoorr vvhhiicchh aa 1IO0O0X rr~elstuLl~tt w viitthh rreessppeecctttO to tthhee: tant rut criteria criteria i1si rroeccoorrddeedd.;.-YFoorr tthhee ffiilsbh tteesstt,, tthhiiss i1sa tthhee ccoonncceennttrraattiioonn aatt Wesch all animals die; whlchall aniI~s die; EGZC0 1s is the the highest higheIt tteesstteedd ccoonnccenetnrtartaitoion naatt~vhhiicchh nm~e significant li~;l~fiCmlt Zre~aIC cttiiOo~n iLIe oobbsseezr~veedd vith vit:~ rreeJspp~ectt tGoo tthhee tteesItt ccrri~tteerrtisa)),. "Towards theena11"ab, Taphots mapas (vater flee) che product ta hot datrinental ac the highest concentrations tested (Ege 250 mg/l) | "Tha photonathests activity of alpes ie easily effected by Floorichum Selst. The effact is still below the critical lente at conceitrationosf' iE 30 %/2; but at 100 =g/1 1t 1s sigatticant. | iy SER To The bacteria oxygen uptake during break down of peptone is increased by the product. This makes the biochenteal brask down of the product itself plausible. Tota result 1s alto confiraed by the TC - degradation tant (sme. 333, "a product ot, Lash Water, FC 206, frose-tamured (enclosure 23, reacts atatlar to product No I ta the fish and dephnta tests. Alwo che result of tthhee iLnoccoorrppoorraactitoonn tteesstt fiso sshiantillaarr ttoo tthhee fFiirrsatt pprroodduucctt.. JBautt tthhee sinbi~bkiteitooun ooff-tthhIe'pPhhoottoossyyanthta~sitise aaccttiivviittyy iiss lleessss aa~ndd bb ecm omes 8si~gattfti~ icIanmtt oon~ltyy'aSit', tthhee . hhiighest concentration eouceutratiou 225500 msge/Lll.. (m= result of the mmitts~boollilm es'i read result of the To :. :.j.. , : , ;. , ........ . . ~.,~.-,..... " ~', ?~;.... ....~' ..,~ . .... ~.~..~;~;.. ....... 11771166..00001166 33MM_MMNN0011665577881111 Ete - ddeeffiinnilttoellyy ddtitfffeerreanntt tthhaann ffoorr tthhee ffiirrsatt pprroodduucctt:: TThheerree iiss nnoo methaboltc ~~ iinnccrreeaassee vvhhitcchh ccoouulldd bbee finntteerrpprreatteedd aass &8 ssiiggnn ooff bbrreeaskk ddorawms.. TThhee T0C ddeeggrnaddaattlioonn tt~ estt aalxseos ddoosess sshhoo~w aa bbrreeaskk ddoo~van ooff lleessss tthh~enn 10%. TThhee rreessuullttss ooff t~hhee bbiioollooggiiccaall t~eessttss c~arrrrlieedd oouutt ccoonncceer:nniinn$g pprroodduucctt Wo. No. 3 3 "e Bi~ ght W Vaat~eerr,.F~C 2,~0066~, ~ nor!m~ al,"" aarree nneeaarrllyy ~ iodde~atIicca~l ~too ~thhee rrees8u~lt8s oobbtta~inne~d ffoorr pp rod~ uct No. 2 Light Water, frost protected. The only difference 103 that the texte affects tovacds algae indicated for product 2 are not found ffoorr ppr~oddu~ctt ~ Wo.. 33.. 3 Product P~d~ ~ No., 46,, ~ "Lsighhtt ~Waatteerr,. ~ PC 220~0,, ~ nor1 ma,l" ," f~s8 d di/ffffeere~ntt ffr~ om tthhee oc f~ oun aqg~enttes G~tseccuusss~edd pprre~voiouussllyy bbyy hhavai~ ag aa ddeeffi~n1ittee toxic effect tovards fi tin, oSTP5Ee end atoms. ft~h, s~e~ ~d ~sae. Tor For t~eshh cthhee cant sminste ate aires at 1000 wi (BC, (ECo = " 100 mg/1, 1~ ~/1, Cig El00 = - 11000P~ag//11)).. :Inn tthhee ddaapph~mee tteesstt,. 333~% ooff t~hea a~ tmais 4d1ie6d4 w wiitthhiinn 2244 hhoouurrss aatt 110000 umg8//L1,, aatt 225500 nng8//1L aabboouutt 775SZT ooff tthhee aanntiuasmlhs : ded died ((g3C6~5 - = 5300 uug~//11,, EECyIoOp0 =- 550000 mg/2). Thedacorporation test for The 4neowpontXon test for tthhiiss pprroodduucctt iiss a~lrrueaddyy ssuurrppaasssseedd aatt ccoounccoean- ttrraatb~loonnss ooff 55 ruigg//ll:; aatt "225500 mng8//1l aa ccoommpplleettee iinnhhiibbiittiioonn ooff aalisgeles aaccttiivviittyy iiss rreeccoorrddeedd ((EBCC, -= 22 rmaeg//1X,, EECC -= 225500 mg/l). y SEE TY PPrroodduucctt N_Hoo... 55, . PPrrootteeiinn FToosana AAggeenntt,, f/aa aallll bbiioolloogsiiccaall tteassttss idso seqqu~hbll 5 to product Wo. 1. Wo significant torte effects vere found tovarde alga st ccoonncceennttrraattiioonn ooff aabboouutt 225500 q mgl/ll.. FPoorr tthhee muamtthhaabboollitseua tteesstt aenn facrease fa iF bbe~cttearrtiaa ooxxyyggeenn ccoorrppoorraattiioonn wvaass rr~eccoorrddeedd,, bbuutt Iitt vwaass hleesss tthhaenn ffoorr pprroodduucctt | lBioe:. 11.. TThhee rreessuulltt ooff tthhee umaetthhaabboollitseus tteesstt ccoorrrreessppoonnddss ttoo arreelhattlivveellyy y.f Ppoossiittiivvee .r~eatcltioonn ttoowvaarrddss tthhee bbrreeaakk ddmovean tteesstt.. "' Product Wo. 6, Expyrol, Le exceptionally high ta toxicity and ih daley of SFhek dow. The toxicity against fieh is an high a for product tol 4 (EC 2 100m8/1 and 30; = 1000 mg/1). Tor small crab this procust fs' snd Cet nie fra ia ae 11771166..00001177 33MM_MMNNO011665577881122 Es -14- espectally especially toxic toxic ((EECCo, = = 2255 mugg//1l aanndd EECCylopp0 =- 550000 mg/1). _ TThhee iinnccoorrppoorraattiioonn tteesstt sshhoo~vea aana iinnhhiibbiittiioonn aatt 1100%Xccooncnecnetnrtrasttiloonnss aabboovvee 1100 mmgg//l1.. PFoorr 225500 magg//ll tthheerree 1iss aa 6655X% ifnahhiibbiittiioonn.. The The m meettaabboolliissmm ccuurrvvee ooff tthhiiss pprroodduucctt iinnddiiccaatteess tthhaatt Litt ccoonnttaaiinnss m meettaa-- bboollilcc aaccttiivvee aass w veellll aass ttooxxticc ccoommppoouunnddss.. Bosulte TTaabbllee 5~ Resutt~ ooff ttooxxiiccoolloo~gyy tteenstt (( esxxo[,rreesssseedd iinn oorrddeerr ooff ppootiseosnn ocllansseseese)) Ce No --_N--o (PFDiiVasLnh (DE~L 1155)) DD((aaDDpp3VhhVLnnLee1IT 1I)) ((DDABAEE VllVEgLgaaee1122))T BBiiaannhcchiittbbeeh iirrttii,.aa . o( (cDneDnEnhBhVhVaLaaLnnwco11eee22)o)) oTvTeeoovvettaalaallluluuaasttiioonn xx)) Tom [ u ur ? : + nam 2yommr ur wm m n/m mr m ll/llX - mn 307 om o--zeg .n n 1 ur = um 2 s m ou ur w mr u nr m _--_-- I/II . ur -n 3 3 II Fotean Poi.o~n class c].a.~z I 1 : + bPPrroooavvneenn5 iinnnghh/iibbii1ttiioonn oonn tect te.~t, aanniimm'i~lle~ aatt cc.onnncceennttrr~ait~iioonnss below 5 mg/ I i P#n2i1~9.9~0n oclla~e I1I1 +, AAes idnn I1~, rree-sjiionn 55 ttoo 27o0>~ mmgg//ll PFooitcroonn lclaas~tz 1I1i1i:, NHoo dd~a,snu~g,s~ a~tt ccoonncceonnttrraattiioonn~s bbeellooww 2255.po nmgg//lL Drotar evaluationi X)Tot.~l evaluati~nt Jonrt critical limit of concentration in maltiplisd CC~aIlccuullaatteedd hbyy wweeiirghhtteedd aavvaarraiggee.. TThhee ttee.s~tt resUult with ]o',';es~ critic.~l limit of concentration i~ mUltlplied bbyy 55;:" 4. ~. Evaluation Evaluation of of Results KesulCs aanndd CCoonncclluussiioonnss Summarizing the single criteria of the test, one can obtain different resultSs,,~.~derpizeinnd8ingthueposninwghleatcirmitpeorritaancoef the test, one can obtain different 1s given to the lfferent criteria. * The results, The original products constitute a depending upon what importance original products constitute a threat to biological systems such is given to the dlferen criteria. threat to biological systems such aass tthhee 1li1ffee 1ina ssttrreeasmass aanadd bbiioollooggiiccaall ssyysstteemmss ooff ppuurrilffiiccaa~tiioonn ppllaannttss,, dduuma 0 to tthhaetirr bhiigghh ttooxxiicc lleevveell ttoo wwhhiicchhi.h~hee ssuurrffaaccee tteennssiioonn,, aanadd ffoorr pprroodduucctt 1I,, 11771166..00001188 33MM_MMNN0011665577881133 -15- hn conte of sts 0 add. The diablo vat pty c the content of zinc is added. The drinking rater supply could be endangered Ch conten of Sunt ch arp eterno out be sntngues by the content of Just ~he orga~Zc u~er!al in ~he original o~potmds. '~ Alo the spptcaston grsagen 56 3 sotucisohn oofrags sos A!so the application .strength 5-6 ~ 8olution8 of all products tested " 5 100d to dager or bionsent acems dn 50 Ste shpeste coat can lend to denser for biological systen~ due to their physical, c,heatcLt ant Conte characterises, pat, cons aad toxic characteristica. ay By the the further fur=her ddiilluutt.tioonn bbyy a a ffeacttteorr ooff 2200. ttoo 800,, wvhhiisch i1ss aaccttiivvee iinn the pplication of foun dierattinguishing-opapodnds: sha that: Leovtientle "C2 me/1 for bactarts, 10 - 25 mg/L for f1ah) 1anotexcesnddaalde tthh~e wsuurrftauccee tteaumslt~onn aaccttiivviittyy ccsann 2Loooossoe 1lrcJs ~mpmoprocretennccee,. % '"Z:Itt rtJh~ena.~`eWeeemms rreeassseennsabbltae: too aevvaalluuaat~et ~thhea rwaatteerr ddaannggeerr bbyy tthhee products products a `aaccccoorrddiinngg ttoo tthheeiir ttooxxiicciittyy aatt tthhee ccoonncceennttrraattiioonnss wvhhii~chh ccaann bbee rreeascchheedd durin8 during " ' 3 epiasion, and accordin 5a Chote Moshedegeantion ss oh sos at present are only degradation results avetleble for she fintahed nixed pro- application, and according to their biochemical de8radatio~ oven though there at present are only degradation results avstlable for the ~intshed ~ p~o- dduucetlss.. Tor nono he compan th dugrdeEion 1s 0 ae For none 05 the oapounds the degradation is so easy as ~ cl~saify . then 0 aviromstaty friendly comnts. Tn the selection soaes5hceansecyicnheo as anvitonen~ally friendly o~pbunds. In the selection one then ~ust differ- oeant'ilasttee rreellaattiivveellyy bbeattteer pprroodduuccttss ffrroomm rreellaattiivveellyy ,w.wororssee pprroodduuccttss.. i ./`When fire-extiaguishisg foun compounds are a5plied, the about 5 % sela- ."l~Fnlomns.a~vae~aesa pprreevviioouussllyy ssttaatteedd ddiilluutteedd bbyyea ffaaccttoorr of of 20 20 to to 80,- 80. 45 104 Fries of concmcacion beeen 135 0 300 mt. A are in a rasion of concentration batvenn 125 to 500 ~/1. At TThheey tthheenn . ...5. ii tt r rts on ~o~ . 3nd. 5 sca tons scare sersmmn trataon the e~da of p~duc~ ~.~ and ~. 5 are ~e~ut acute deter SPv~ ECerEooESa~nethtrheseridpoicoluEtnnli~obb.yycat e~oafctaohreo onpfr2itc~iia55t..iodnSuicahtcdleotsilu.o~+ln~otn0cnomfeore 51 betasn 30 43d 200 10 necessary to gut betow the toxic Java. such dilations, 1177166..0000119 3MM_MMNNO001657814 Th oretucts 2ad 3 ar of Little oncom ve tent omprtias ars 16 . -16- : fens 4ar6e RnOoEt cCAarrttaalnn f/nn pprraaccttiiccee.. PPrroodduucctt NNoo.. 44 sshhaoyves tia~.aadddtlttliooun sa lloowv ddeepsrreeas ooff degradation desradat~on aanndd sshhoouulldd nnoott bbee uusseedd ffoorr tthhaatt rreeaassoonn.. The roducts 2 and 3 are of little concern v~m toxic re rtles are ttaakkaenn ifnattoe aaccccooumn.t. BBuutt bbootthh pprroodduucct~ss aarree ddiif~fiiccuull~t ttoo ddeeg~rraa~dee aanndd coouurl,s thus thus Hacer dlsturb ann4d G&u~psu-slrr tthhee drinking vater supply) md che use of these pro dt duucctth ss the erefr or~e sshhoouf ullddbo beaavr oids ed. Ofthe Temaiaiagproductsthe SahcoteLevel corde tigendot fomcompoundHo.:1 has atelastrely! i 0 ha Mak ontnt of ga Tok wines hath properties are lost to a large extent dus to the dilution during " Seagon,d stace the product 1s relatively eas to degrade, the endangering F he Vaters dus to this product ppasss to be of Lisle taportesce. The .Tha TOupLag group!n8 of of the the 6 6 pprroodduuccttss pprrooppoosseedd hheerree ddooee8s ttaakkee bbiioollooggiiccaall aanndd cchheemaiccaell rreessuullttss ~{anttoo aaccccoouunntt,, bbuutt ddboeess nnoott ceoonnssilddeerr aappppllii~caaCtiloonn a~cchh~mLto~n8l~ Chatactertstics. characteristics. IIff iI~t id&e nnoott ppoossssiibbllee~,dduuee ttoo 8apppplliiccaatt~ioonn t~eacchhnincicaall,jrrsaas8soo~n8s Avoid aVoid ~hhee uussea ooff pprroodduuccttss wvahdicchh aarree dd1iffffiiccuullt ttoo ddeeggrraaddee oorr aarree esesppsecctiaailllyy fortes toxle, htheenn i1t6 vtmouulldd bbee aaddvviissaabbllee ~coottc e~ rtt tto hhaetisrsm si~ngnl~e e ~_~n n.s~tt stfoorrds dee-r 8s~dtatlaon daaanddat~ooxt~ieciaeffffoeeccttnsS.[ FFuurrtthheerr iitt sshhoouulldd bbee aatttteemmpptteedd ttoo rreeppllaaccee coomappoonneannttes eensppeeccLiaal~ll~y bbiioolloogsiiccaallllyy ddasm maag~inn8g bbyy lleessss ddaamnaag8i/~n8g umSa.tteerrmiailtes oOff es#n!iuvni!i~rloaanrrmeeenfftf~aeelcctt.c,.o.n8cS~eicrchnh. aapppprrooaacchh hhaass bbeeeann ssuucccceessssffuull ffoorr oot~hheerrmnaatteerritsall8s ooff i environmsnta! CO~cern. . 3. 5. RBaeccoommemnednadsattioonnss ffoorr tteecchhnniiccaall oorrddearrilnng speecltftlceaattliool:nos #.~ A Based Kased upon upon the the {nvestizations investigations ss ,as M~lilasccuusssesde#d~thyhee',-gf4aLlilmorvi~g8s rreeqquuiicree-- ete can be made of the manafacture of foam fire-sxtioguishing compounda: 7 pmreeL(ns1,me.'hcteOaniabblbioofellooonmgasldleeceaoalmolpfodduotehnpgderrsaam ddsaaahctnotiouuofnlnadccctbhuheararewraaacolctflerr-fosiram lssttttailbcfelis'rdeaoo-bffeaxdtcth.hln)ee~oourrgssaehnnitlncc~coeom~ uppo~ onauan8 tdsos present n foam coupound8 should be wall utabllshed.~ . Te The breakdown should be as The break ELdo~n should be ate s eeaassyyaexa ppoossssiibllee,,rirtgShhtt nno~v pe iittf~eo coonusis~dejrroedd B 11771166..00002200 .. 33MM_MMNNO011665577881155 an-17- 8 as fur,f~Lr, vonvhen a 5500%Z bbrreeaskk ddooowms 1as rreeccoorrddeedd ta the motties cxca-sersemtos- Test (7). For test vhich records complete chma~csl deardefies such as Ofhes tence can be used 1a replacement of the shovemsationnd, Sf 1 haw bu Cthhae TT0O0G-d-degescraaddaatt~ioonn tteeastt ((66)),, a 4400 Z1 bbereaaskk ddoowvnn sshhoon~Ltdd bbee tchhee amltualtauunms rreeqquuiirreedd.. O~her tests ~n be used in r~plecmsm~t of the abov~autloued if it has b~ Proves, that equal results are obtained as for the tests According to (6) aad (7), when these products are tested. 2 "Toa foxteafficts of the fom compounds overs vater orgadten, dspactally Vfaiictairetna,tlsyignasm,meoosltfe PsEeDnsSeScainndb rio at abouts ba as 4 the Keg smatt as possible. or bactarta, alg A & dap ad Hah 10 above 1500 ng/L foun spent 4a acer. Yor toxicology Procudure for Vhich test, qual L 11, L 12, and L!15 of DEV type results can be proven, (4), or similar are to be seed. "Tha haevy metal content should not excemd 1 3sing ox forothermete uann' ema~oouunntt seconded. ffoorr vwhhilcchh a a coorrrreessppoonnddilnags ddeeggrreeee ooff bbaacctteerrtiaa ttooxxiicc atfacts te recorded. | ` 66.. CCoonncclluussLioonn ; rAAccccoorrddiinngs ~too tthhee ttaasskk tthhee foolllloovwiinnSg ssiixx fooaanm `cooumppoouunnddss~, ddeetteerrmniinneedd bby7 the ""BBuunnddaessaimntt i~cr W~eenhrr~teecchhna~ikk wu~dd BBeasscchhastfffuunngS"- Lta~ KKoobblle~azr~,vvaerr~e levvaalluuaa~teldd ith relation vL~,h., rl~tLon ttoo ppoossssiibbllee Iennddalnngseerriinngs ooff wwaatteerrss:; rFil~saIrt~prrootteetlnu;; LLi1gshhtt WWaatteer,r./. # .:, - . Felitily favorable biologie charactariacicn. The final consiiatins oe toxttelor, biochemical dageadation, heavy natal content wut fram pote. C 206, normal; LightWater 76Soe, Procalusthuummictal; pyeol 715. Frost protected; Light Water The cant taciudes faterphase FC 200,norsal; acttviey, tox~ oloKy, bloch~mlc~l deerde,ion, heavy metal content and fll Point. TThhae Freuusuulletss yvaorrae pprreesseenntteedd aanndd ddtisaccuusssseedd aanndd aa ccoonna~ltuunstiooun rreeaacchheedd, -- Tni~eI~ ppr~odduuact~s!P~ ho~nm inlin s aanndd P;Pro~tCet~nnscshcahuam~itit=e~l w weirree rreeccoemednededdddoe~ t~oo. rela~/~7: favorable biolosic c~rac~e~stics. ~e fill c~~l "~ * 4 Contrace apmer. : : 2i siven 4s recomendations for technical delivery terms (TL) to be wedby 11771166..00002211 33MM_MMNN0011665577881166 ar-18- LILTITEERRAATTUURREELLIISSTT, (@) Pala, he Study Miscachum fr Tiopsegbreniessmptmg" (1) Fiala, It. : Study "H~ttelschau~ fur Flugzeugbraudbekampfung" Pole poiathas ur Flapping: Deutsche Forschungs- und Verschsanstalt fur Luft- uunndd Rita~uun~feahhrrtt ee..V V..,, ]Krs,bl'law-..W,,raahba~ 19.7777,. @) Moaesnaalsafur Cloanmrineo,mias Gutacheen aber de Sasser (2) fur Gew~sserkunde~ Gu~achte= uber die gasserse- Surtatewasr tte dss . fahrlichkelt ~ou Schaualoachaitteln, Koblenz 1975. ((33)) Hellmann, Hall~nn, HB..::TenSsSiccdhheaau~mD-le,1dtse~crsghcemhniattlstttee1ll3-- (li1hh9rr7e6e),m~ogg2ll7ii0cc-hhee 2VW 7a3.assssearrggeef~aahhrrdduunngs,t Tensida Detergent~ 1--3 (1976), 2i0 - 273. (4) DDeeuuttsscchhee EEiinnhheeii~tssvveerrfaahhrreenn zzuurr WWasasgegerr--,, AAbbwwasassseerr-- uunnddScShchllaamsmm-- ania fu terSse ntstb untersuchung, genheim, Erganzungslle~erung 1972. irSeiicie AsnALaiaEh (s5) ZZaahhnn,, RR.. uunndd HH.. VWelellleennss:: EEiin einnffaches VVeerrffaahhrreenn zzuurr PPrr~iffuunngg ddeerr pr rt septaue items biologischenAbbaubarkeit van Produkten und Abwassme a RH serinhaltsstoffen. Chemtker Zeitung 9_~8 (1974), 228- 232. irre, Jas Ce (6) MHi~lllleerr,, DD.. uunndd TT.. TTitttttitzzeerr:: DDeerr TTOOCC-A-Abbbabuatuetesstt -- eeiiun VVeerrfaahhrreenn + to esta zur Pr~Tung van organischen Substanzen auf voll- Stiatert, simianSra df vol s~andlgen blolog~schen~Abbau. Zeltschrlft fur Soloriscies be" etticteifs fr Wagger- und Abvasserforschungl2 (!979), 14-21. (9 Fosher, 4... vertebra me Basan di btongtas (7) Fischer, W.K.: MeBverfahren zur Best~.ma_ung der blologlsche~ ' panes mee estonidaecMotostac Abbaubarkeit van waseerloslichen, orsanischen .~ ~ Usweltchenikalien mit Kohlenstoffanalyeik (DOC) ~(Mlotdcihfiee~d kOEaClDi.Sncr.eiatnin[oghTlees-t,t)o.~f.n.~vtik (~OC) \ scrip x che tim . A manu- ETE Rem Ki. etn, CE s~rlp~ ox the erm .Renke K, ~m~dor~ sent ~o " ame seer, sm the.E.C, o a~ recommended process. (2|, 2. 1978). actones Enclosures Toxcatop conertratin/eascion curve snd deradecion curve 3 60 6. Toxicology - concertratlon/reactton curves and degradation curves. T_nauilsled 8. Llrsa flee Sy TF 11771166..00002222 3MM_MMNNO001166557817 - Nlirr..11 FFlluuoorrpprrooteiinn 100 - +8900 a] m3AoxtTReooeonseoeoryerEmatsitoR n tert DVL 12 ZZ=n ZNR,e~siehtahhaebonolsli"ir~am a %toosrtt 19DD;';LVT, 1127 vrw r.a6O ~=, ~ish to~% D'~VL 15 T rr o r 1 t cf afof T L -- e T a r : -zo T Ir r m o e Or r oe ] "wf~ ow-e40 53g iFae -- -100 wk 100 I C r r r rr 1 T ] a -- T E T~ T ESS ES] 5 I00 2255 55O0 110000 225500 10100000 1100000000 ~Lonn~e'eennttrranttiioonn ,mmgg//lI 8 O0 F060 Sa --_-- _ I~ 1] --] Su I Ff] Ea] rent or sone temmaiin es o Tes~ oi: TOG- do~'~'~iaLion . [|] 0 27 1% 2u1n -------- Degmdletion Fime, [27 11771166..00002233 33MM_MMNNO01657818 NNrr.. 22 LLiigghhtt wwaotteerr,, FFCC 220066,, ffrroossttggeesscchhiLiittzztt 400 ili PTL TOXIOObO~Y T~ST h~ IncorPoration tost ~.~';VL 12 _. ~= D~hno t~ ~EVL II ge Z= Ips Eethaboli~m ttee~rtt D!;VI, 112 ~.Fimh tozt D;~VI, I~ "4 }--eeo Lr *( | 1 TTT 1 = 20 r Fr rr 3 I TTT 1 0 {emmariemolbnn asec rere r.., yey S H n TT 1 Tog11 TTTTT 40 |1 rT 1s TTT] Ep) HTT m1 g0 -80 = Z=: --~i0000 =H ,00 r= rrr * 1 1 1T TX 55 010 25% S5000 100 225500 11000000 10000 J~oonnzoennttrroattiioonn rmagg/!l! "80 FF : Ee E-- 3 IEE : 00 0 ---- ee CT) 7 1" 221 i} Dygmdation rime, Gyo 11771166..0000224 3MM_MMNNO01657819 | - NNrr.. 33 LLiigghhtt wwaatteerr,, FFC 20066,, normmaoll 100 oe -- = Fe--] +80 60] ABmAn~oOuxXsIzIIncnCiccoOnoouLrrOoePpOoooYyrrvaaemTrtt~stiiSeooTnBn atteenstt11 DVL Di':VL 12 12 BEZe= LK~,e'Et:ehtahbtaboolslti.r~am Stteeasnvtt 10DngeVvTi,, 112 YsT owfD-- c r or r " P- Vi~,h %e::tr DgVL 15 iE gE ya 2O0p - -- t J r-- --e--1 sFi-- r 1 D ] N L t ] 2 HH -- | 50 1 -- Fn 100 ] 100 1 TT 1 S5 100 2255 5SO0 110000 225500 10100000 1100000000 (C'oonngzeenntlrraattiioonn mmg9//|I : -- 8O 6O I-- ---- De] 2} g 20 -------- . T~eenst~i''Oof ~`TTO0CC-- ddeeg~rta~d,azttiioonn - 1 ; -- /-- 3 0 7 7 1% 1/, 2! Co 21 Degmdation time,Gye 11771166..00002255 33MM_MMNN0011665577882200 | NNrr. 4.4 LLiigghhtt wwaatteerr,, FFCC 220000,, nnoorrmmaall +100 +80] sao] Tr3AA=Oo.~uIrTbICcnocOoco~seorOompGap'rYe0re rmaT~t.ts'.'iiSsooTenn tteesstth DD~VVLL 1122 fZZe=o1li4eetethhaabbeolliir~mm ttreo~ritt DL 12 D:".VI, 12 D= Daphne test DEVL Ii , ]'- :,'i~h to:~t D'~.;VI, 15 PsEafeearf---- -- + T TI TI Tt TI Tir --1,| T] --T, ----] Edom] ,&.,= O. e ,:=........... .r ,..... ~-..-..-.~ ..Tp-r..... ~--..~.. ~"".'.(.~)"~ 1 S ~~ TIN NT T T -zO "'~.~ ~ I P*'B~" -40 = ---- I S I ~! %:.. T 1 . o5 5.,=~ .--60 2 N _.. e CP "~oe e "%e . o E,:, o-n80 ..... . Ye -I00 .~, "- 5 100 25% S5000 1100 225500 G11o00n00e00entration m1g01/0t000000 l[onlrentrotion mgll tO0 MT 7 -- iw I] 6O 4O i2 . 1 i "---------- 20O Tort of T00- domradation 1 0 0 ---------- -- 7 1% 221 Dgmietoon Fim, Guys 11771166..00002266 33MM_MMNNO00116657821 | NNrr. .55 PPrrooteteinisncshchQauummmmitittteell o+110000 cB,w6Y0 BBeB rtR iRa so PT BA: e pees mama *E-R -.60 T Tr S aT 2.20 r 1Tr FT1r a [ern "0 - zo E40 iE -- 6w0 2g EH .w100 Ee l= y 1 rr rte [1 --] IU i Eo] - ---- 1 | rT 55 100 255 5500 W|0o0 2Z5500 11000000 1100000000 K~o'onne~e'netnrlraottiioonn mmgg//1I "100 ~~] 0 80 oe g -- : ---- 6O ia T 1 T] 5 eb IE lL FE Toot Test 6~f 00 TOO- ddneggrraatdaattiioonn ----] --_-- ]| |\ 0 7 -- ee 1] | % Degmdetion Free, Oy02e1 11771166..00002277 33MM_MMNN001166557788222 NNrr..6 EExxppyrooll FF 1155 O0800] Toxososy me!r wg60] Pon RAL PY fdas Z= ~:eth.~boli,om eten.~tt wnD":VL 1v2e S FOr T olrT r] t , i P- Fish %err Di~VL. IS I I s a E Ea M II T oTT rr yo] TT - =r F Nr e 3 FER ziiee ia ESS ae -- -- ] 3 Po--------] wf Te sn O0 TY 25 50 100 25 _ 1000 - 1100000000._ Concentration RG/1 E: e TT IN| fa IEN 3 TN] 5 1 TN] g 1] Te.-..l Of 'POC- 0 I i i 0 ?7 1% h2i1l It ---------- Dgmdetten ine, Gs 1 11771166..00002288 33MM_MMNN0011665577882233