Document dYOaDx5oXY0d5KOLDvgB7BEoB

AR 226 -- 0847 ACUTE TOXICITY TO AQUATIC INVERTEBRATES (COROPHIUM VOLUTATOR) TEST SUBSTANCE Identity: A mixture containing perfluorooctanesulfonate, which may also be referred to as PFOS, FC-95, or as a component of FC-602. (1- Octanesulfonic acid) (CAS# 2795-39-3). Remarks: The 3M production lot number was not noted. The test sample is FC-802. Current information indicates it is a mixture of 1% PFOS, 12% diethylene glycol butyl ether, 61.05% water, 20% ethylene glycol, 2%Sultone foamer, 1% sodium octyl sulfate, 1% sodium decyl sulfate, 1% magnesium sulfate, 0.7% xanthan gum, 0.1% starch, 0.1% n-(3-chloroallyl)hexaminium chloride, and 0.05% tolytriazole. ~ The following summary applies to a mixture with incompletely characterized concentrationsofimpurities. Data may not accurately reflect the toxicity of the fluorochemical componentof the test sample. METHOD: Method: ASTM E1367-90, Standard guide for conducting 10 day static sediment toxicity tests with marine and `estuarine sediments. Type: Acute static GLP: No Year completed: 2000 Species: Corophium volutator Supplier: Field collected from an unpolluted sitenear Trondheim, Norway. Analytical monitoring: pH and dissolved oxygen Exposure period: 10 days Test organism age: Adults (4-8 mm size) `Statistical method: LCs values calculated by PROBIT Analysis, National Swedish Environmental Protection Board (Version 2.3, 1990). Calculation of NOEC by single-factor ANOVA followed by Bonferronis procedure. Test conditions: Dilution water: Natural seawater (34 ppt salinity) from an unpolluted site in Byfjorden outside of Stavanger, Norway. Sediment collected at an unpolluted site. The sediment is a muddy sand and had an organic fractionof0.7% and asilt fractionof 0.8%. Dilution water chemistry: Not given. Lighting: Not given. -- Stock and test solution preparation: Each test concentration was prepared by adding test substance to 600 g damp sediment and 200 mL of seawater, that with was shaken for 3 an overlayof 400 hours. The sediment w mL seawater added to as split into three each, and aerate subsamples, d overnight before study initiation. 002194 `Eaxnpdo4s0u0rmeLvoesfsseelasw:at6e0r0wmitLhgcloanstsinbueoaukserasercaotniotna.ining 200 g oftestsediment Number Number of of replicates: organisms 3 per replicate: 10 WNautmebrecrhoefmicsotnrcyendturraitnigontsh:e four plus study: a blank control pH range (0-10 8.08.1 days): (control exposure) 7.9 -- 8.1 (3070 Temperature range: mg/kg 15+ 1 exposure) C Dissolved oxygen range (0-10 days): 91-94 88-96 % % ((c3o0n7t0romlge/xkpgoseuxrpeo)sure) RESULTS wNeoimgihtn)a.l Rceofnecreenntcreatsiuobnsst:anBckec(ofntlruoolr,an2t5h7e,ne4)78a,t 2100.530,mga/nkdg3d0r7y0wmeigg/hktg. (dry Element values: 10-day LCs = >3070 mg/kg (sediment dry weight) 10-day NOEC = 3070 mg/kg (sediment dry weight) Element values based on nominal concentrations Remarks: Substance Testing was conducted on Remarks field. The values a mixture reported as described in the Test apply to that mixture and not the fluorochemical proportion alone. CONCLUSIONS wTehieghFtC).-6T0h2e1100--ddaayyLNCsooOwbasserdveetderEmfifneectd Ctoonbceen>t3r0at7i0onmg(/NkOgE(Cs)edwiamsen3t0d7r0y maikg (sediment dry weight). Validity criteria fulfilled and reference substance was in the normal range. Submitter: 3M Company, Environmental Laboratory, PO. Box 33331, St. Paul, Minnesota, 55133 DATA QUALITY. tReesltiianbgi.litHyo:weKvieirmi,stchhersatnukidnygla=c2k.s Tihnifsorsmtautdiyonmoenetpsurtihtyeocfrtitheeriatfeostr quality substance ~~~ and it lacks analytical confirmation of the amount of fluorochemical proportion in the solution. REFERENCES 002195 Treesqutewsatsofc3onMduNcotregde,bLyaRbFreRfoegraelnacnednuRemsbeearrc9h9,31o2f-S3t,a2v0a0n0g.er, Norwayatthe OTHER eee Last changed: 6/26/00 002196 5La9b3r1e2fn3o, Page lof 31 iii > RF morsowe FRSAARER "FC-602 Light Water Brand ATC plus" Toxicity tests Report RF-2000/003 Tab reno 993123 o[ m [[ aF ee eTe Ee ] 3t Autor Elin Horve Version No. date: Vers. 1/07.01 2000 Soman: The following test results were obtained with "FC-602 Light Water Brand ATCplus": Toxicity: Skeletonema costatum 72hEC, (mg): ~78 ACcoarrotipahituomnsvaolutator ~~ 4180hdLLCC,, ~~ (mglkg dry we(imghgt)):: 53027000 The results relatteo the product as supplied by Novatech. Keywords: `Toxicity, Skeletonema costatum, Acartia tonsa, Corophium volutator. Nopartof 5 docmetmayboapron nayomwithoutpersion ogoFF Pogaand sear 6. fudgoecdrisn Ade Ke, Inger Lisa Andersen Lor RoF RogalfandyRefsealrehag Kare Netland PoorOl Honsaonn 15,PO.box2503Undo,409)SkNverey. onk:+4g751e8750r.00.Fa.+4751 8757.0,Eves00bo2c:195098847800. Lab.refrno.: 99312:3 Page2of31 CONTENTS: LL PREFACE cosets sss sesso. 3 2. TEST FOR TOXICITYWITHSKELETONEMACOSTATUM .c.co.cosssssssssssssns & 3. TEST FOR TOXICITY WITH ACARTIA TONSA covvvvisimsssssssssnes 10 4. TEST FOR TOXICITY WITH COROPHIUM VOLUTATOR ccs sss 15 5. DATASHEET(S).cerrssnrrssnsssmsmmsssssmssssss sss 20 002198 L9a9b3r1e2f3no.: Page ofl PREFACE: ENcoovtaotxeiccho.lToghiecaslamtepsltsewiesraecpoenrcfeonrtrmaetdeotnha"tFCn-o6r0m2alLligyhtwiWlaltbeeruBsreadndinATaC3p%lAusF* FinFa/gr6e%emAeRnt with sNooltuitfiiocna.tioTnesFtosrwmearte"c(oOndSuPcAteRdCiOn Mac1c9o9r5da/nScFeTwi1t9h98t)h.e "Harmonised Offshore Chemical Theproject was carried out at RF -Rogaland Research for 3M Norge. All the tests were performbeyd RF - Miljolab. Study director was Senior Engineer Inger Lisa Andersen. The test results arepresented in separate sections. by Novatech. The results relate to theproduct as supplied TThhiesatcecsrterdeiptoarttioins sitsastueesdtbhyatatlhaebloarbaotroartyoarcycmreeedtistetdhbeyNNAorrweqeugiiraenmeAnctcsrecdointcaetrinonin(gNcA)o.mpetence, `Iteaqluispomsetnatteasntdhawtotrhkeilnagbporroacteodruyrheassfoarsaaltlistfhaecttoesrty mqeuatlhiotdysacsosnutraainnceedsiynsttehme,awcchriecdhitiatnicolnu.des cinetretrinfailedquraelfietryenccoentmratoelrsicahlesmaensd,speacrtoincdiapraytiroenfienreinncteermlaatbeorriaaltso.ry comparisons, and the use of The testsperformedare covered by the accreditation. This test report writing by RF- may not be Miljalab. reproduced in anyform other than in full, without the permission in 002199 Liabrseio, pase sopsi Ep tote i | . 1 - LEST FOR TOXICITY Maine alga: Skeletonema costatum i 1 in 002200 L9a9b3r1e23fn: Page sof31 iii g TEST REPORT GROWTHINHIBITIONTEST WITHTHEMARINE ALGA Skeletonema costatum Q E ie H ROGALAND TEST SUBSTANCE: "FC-502 Light Water Brand ATC plus" TEST RESULT: . `The 72 hours ECy, was calculatteod ~78 mg/l. The test substance was supplied by Novatech, and the test results relate to this product. % TEST DETAILS: : METHOD: NS-ENISO 10253, 1998: Water quality - Marine algal growth With Skeletonema costatum and Phaeodactylum tricornutum. inhibition test gt id TEST ORGANISM: oSrkgealneitsomneimsakceopsttaattRumF,-stRroaginalNaInVdAReBseAaCrch1.. A stock cultureofthe test : He PREPARATIONS: Natural seawater (salinity: 34 %) from an unpolluted site in Byford was used anausntdbraibserinistesfflaoyrctchhoeeargtdeirdnogtwott0ahbImoSeuOdti17u05m25.C3,pTrahineowdratrtoeeucrsowem.amseTnhdfeailtstieeoraenwdsattfherrroowumatgshheaePnGarFriic/shCedfiwltietr,h J Commission. ` T``mmeyes/dtliswuomal.suptiOrotenphsaewrreecdrobencypernesttpriaarrtreiindognfs0r.wo1em0r2ae4spgtrroecapkmasrsooeldfuttfihroeonm.pArtohidssutcsottcoikcnks1oslolulitturiteiooonfngo.rfo1w02t.h4 INCUBATION: `olTraebtsiettdacl0ulstahubarkoeeusrot,f23050r0e0pmlcilceawtleerslefoifrnoccuambcaahtnceodenxicpneonn1te0rn0attimialolnlf.ylagTter-sobtwoitctunlogtmuierdneosfclwuaselkrusmeoicnnuoacnlu-. `The test was run under continuous ligh(t> 50 uE/m* sek) from fluorescent tubes of The test universal natural white type, at a temperatureof 20 + 2C. was run for about 72 hours, and subsamples of5 ml were taken from bthyeftleusotrfelsacseknscee.acph Hdamyeafosrugrreomwetnhtsmewaesruerpeemrefntosr.meAdlgaaslingdriocwatthedwoansdmaetaassuhreeetd. Ir TR0A.02+ 201 L5a9b3r1ef2i3no. Page ofl DATA ANALYSIS: CALCULATIONS: Grow rates were calculated by log linear regression on biomass (fluorescence) i `versus time, as described in NS-EN ISO 10253. | ECs: cTohneceinnthriabtiitoornyoefff2epcrtoodnuctthegigvrionwgt5ho0f%Srkeedluecttoinoenmoafcgorsotwatthurmaitsee(xE,pCrxeos)s.edThaissthe i e1f0f2ec4tmcgoln.c.entration was calculated by interpolation between 32mg/l and | bi NOEC: fCaacltcourlAatNioOnVofANfOoEllCow(eNdobyObBsoenrfveerdroEnfifsecptroCcoendcuernetrfaotricoonm)piasrdionngeebaychsingle- | concentration mean withthecontrol mean. | TESTRESULTS: T--a_b--le." EC and NOEC values abtained with Skeltonema costtum. ItTesstbsbsstnacncee ~~ EECo BECC EEGCu Er, FC-602Light Water - 78 >1024 _---- NoEC: 32 Crm VVaalelseiarnsdiccataelceodnactbedynirntaertpgioilvoaitniogsn.10N% 30O%arancEdal9c0u%lCatnedbbynwinoftghreocwotmhpuratreer. pUrnoigsrammmaell. COMMENTS: Tdhureirnegsuwlhtisacrhetbhaesgerdowotnhgirsocwotnhsirdateersefdotrotbheeteixpmoenesnptainal0 i-n7th2be,ctohnetrpoelricouldtures (see growth curves). VALIDATION: Tcehlel dveanlsiidittyyicnrcirteeraisaedgibvyena ifnactthoertoefstmporroetotchoalnar1e6 fiunlftihleletde,stinpetrhiatodthe control v(acroyrbreysmpoonrdeitnhgatno a1g,0rouwnitthsrdautreiofngmothreetetsthaannd0,t9h4e"7)2, 3,5-dichlorophenol was in the range normally found. hthoeurcsonttersotlrepsHultdsidwintoht Lab. ref. no.: Sample received.: RTeesptorpterdiaotde:: 993123 2009.99 2072.50.11.1209090 Enclosed: Data sheets DU Nee Elin Horve AaalyEtnigcailnteeecrhnician 7HyerFie ( Age Molversmyr SeniQouralRietsyeAasrscuhrSacnicenetist Tohimscesvtrsepl ort i sued by 2 aborapo toryosenedted bny Norwegianp Accrnetion (VNAA)). TTheHrEepEermaayy onorrbeersroodoeccd amnyy" 002202 LaSborerfina: po PRIMARY DATA: Growth Inhibition test with Skeletonema costatum Test substance: FC-602 Light Water Brand ATC plus" Lab.ret: 99312.3 CSotnarct.duantiet:: 2m2g.11.99 | ConMecaesnurreamoennI t:T-- Bhe RbiGoiwT-- samBso[ma|easTsu1rHs2e0d-- Ib|yfElutoRrdes]sce|nce;||valduraeyissi|n|fClmuoornre:sceantcveaurni]tsGafwiaior 0 006 | 032| 15 | sz 161 | ose 0 008 | 023 17 93 166 [0999 | 0 000076 || 0o4s6| 2135 | 111 117816| [00999972 84 | 83 i 0 0 007 035 19 9 012 04 235 | 115 159 | 0.999 150| 0.999 i 00.3322 00.0079 1122 5 116692|| 00.990968 0.08 066 34 145 171 | 0.993 i1 000m7 | 0o6x4 | a37 | i13s | |i1.72| [0.o9s9e1 i] .o00s00s88+|| "oo0s4%ss os 1117082||| 0oossoses si | ws| [es [oor ;i o0o1r 2a16 || ws | | 11764 | 0ose 9 3252 | o0o.oo0n9:|| oo0df5s 1i16s6327||| o0o.ss99es9| 84 } | 202sa || o0o1r || o0v1e3 || a0t2e || caessa || || ooeuss| |oonsmee 1024 009 | ot | 02 | ors 069 | 0944 Reterence subsiancs (3.5dconphenol: vs1o5mmmon || oo0ov1r||| oo04sm6 ||| o0o4ss8||| f7174i | a2 | oo 0 Meanvalues: 032 1 10 32 1024 000087 || o0s4 008 > 00s | 04 009 | 05 009 01 [Feterencesubst 055| 076 | 0%|75] [v00e7%e9]| 055 os| 2 61626| 0[0950579 T 115668|| 00959a5 167 | 0990| mar 164 | 0.999 |substance(53% 0.59| 0.964| initionis). rom ahee002203 rooted Page8of31 | GROWTH CURVES: Growth inhibition test with Skeletonema costatum | Testsubstance: "FC.602LightWaterBrand ATCplus" Lab rot: 983123 | I 1T bi ii ii 5 { FF Control i ansaruen i5.7 0.32 mg FiLH s -- oF sco 4 | rl | |34 IL { i |i1 3 1 mgt = est rato (ours) n 32 mn I! 3 I!2.4 "= CT oi osturation (hours) i if 1 er -- . i oF ssrsonpaey iA -I Lae | El oust Porgy IiEat oF seston BN 002204 Labrefno 9312-3 Page9efal os: i i u Inhibition of the growth of Skeletonema costatum | son tre-coz ish water nrana are pram I serinentar ance: {| FcCo-n6c0e2ntrLaitgihotnWaitner Brand ATC plus Growth rate CCCooonnntttrrrooolll 321 CCCooonnntttrrrooolll 54 Contzol mean : 001.3322 0332 iiileen pp15er0 162 1i.l6e8 ph 11l.0o00o0 3.33i222000 111000...000000 3233202.000000 111000222.0.444000 i} : 11P.7A721 1i1.6a72 1.i16%e5 1i.ll6ee7 alo0l.se4os8 Iinnhpiebricteinotn -:: :- o0ok.ao0 0oo.kl0o 0ao.ll0o oo0.oo0 00o.2l0 Sa707l.8o4 | 002205 al rcs } `vroR : i Av Ww Aca i . } EE |i i "TEyST FOR TOXICITY | Marineherbivore: Acartia tonsa i iat i i ab Trop i jo i | 002206 L9a9b3r1e2f3ro.: Page 11of31 iif : TEST REPORT : ACUTE TOXICITY TEST WITH THE i MARINE COPEPOD Acartia tonsa flQ\ mo>ons RR2CEARECR ii3 TEST SUBSTANCE: "FC-602 Light Water Brand ATC plus" TEST RESULT: - The 48 hours LCsp was calculated t0 200 mg/l. `The test substance was supplied by Novatech, and the test results relate to thisproduct. `TEST DETAILS: METHOD: ItoSOma/rDiInSe1c4o6p6e9po-d1s99(7C:opWeaptoedra,`Crqustua-cDa eeat)l e.rmiinattiy onofacute lethaltoxicity TEST ORGANISM: AUcnairvterisaittoynosfCao(pDaennah)a,gseunp.plied by the Marine Biological Laboratory, CULTIVATION: The test organismswere suppliedas eggs, and were cultivatedinaccordance `with the "Paris Commission - Ring Test Protocol" (VKI). Large copepodites and adults were used in the test. 1 PREPARATIONS: Natural seawater (salinity: 34 %o) from an unpolluted site in Byford was used parsiboarstios ufsoer.the dilution water. Thewaterwas filtered through a GF/C filter i i Tmwaegts/etlrs.woalOsutthpieroernspcaworneecrdeenbtpyrraesttpiiarorrneisndgwf0er.ro9em9p9ar8esgptarorcaekmdssooflfruottimhoetnh.pirsAosdtusoctcotkciksnos1loultluiittorineoo.nfodfi1lu0t0i0on INCUBATION: The test was run in glass containers (28 mi roled rm vials) ach containing 25 mloftest vials were ke solution pt under aan1d651/a8nhimlailghst,/4darrekplpihcoattoepsefroirodeaacthactoenmcpenetrraattuiroen.ofT h e. 2da0t:a 1sheeCt.. pH and oxygen measurements were performed as indicated on the I 002207 L99o31b33e: Page 12631 DATA ANALYSIS: CALCULATIONS: The effect on the survival ofAcartia tonsa is expressed as the concentration of a product lethal to 50%ofthe test animals (LCs0). The combinedmortality 3 LpeCrstevstalcuoensceanntdratthieo9n 5we%rceounsfieddefnocreclailmciutlawteirone.caTlhceul2a4tehdobuyrsusainndg4t8hehours b standard procedure PROBIT. Analysis, National Swedish Environmental Protection Board (Version 2.3, 1990). This programme also calculate test concentrations lethal to 10% and 90% ofthe test animals, | NOEC: CfaacltcourlaAtNioOnVofANfOoEllCow(eNdobOybBsoenrfvererdoEnfifsecptroCcoendcueraetrfoartcioonmpiardionngeebaychsingle- concentration mean with the control mean... TESTRESULTS: dceTaawbrtltoeatIo.tLonnsCsTa aTndTNOORECvvaeluses hobrtaaliduneedbd24WwhAiwotMuhrs"sFFOG-S60022LiigghhttWWaatteerrBaBrra8annbbddoAAuTnTsCCppuuss"" LCi 120 (56-190) 87 (42-130) LCy 350 (250-490) 200 (140-270) 3 LLCwo. NOE: o97m0 e(6o50--22m00e) 100 a4s50o(e32m0--90s0).n 100 Vales indica 10% 50% and 05 eatfe 24 5n3esd, Onis mr Vues oe i ThcecomaputbelsypPrRolOgBrIaTemamneaGdlyrsaandh9no9o3 ec1odnfers mirnas ae ce MOEerredty |3 "VALIDATION: `oTxhyegveanlicdointcyecnrtirteartiiaogniavtetnheinetnhdeotfetstheprtoetsotcwolasagrreefautlefirltlheda,ninortheaqtutahle1d0i4ssmogl/vle,d |3 thLeCpseorfce3n,t5a-gdiecmholrotraolpihteynoinl t(hreefceornetnrcoel)swwaass ilnestshethraanng1e0n%o,ramnadlltyhefo4u8ndh.ours $ Lab. ref. no.; 99312:3 Sample received. 20.09.99 3 `Test period: 2225.11.99 Report date: 07.01.2000 Enclosed: Data sheets SEA Elin Horve Engineer `Analytical technician 0 Ws v Age Molversmyr Senior Research Scientist Quality Assurance -- {orm thr ham in Fl wou penton ing oH 002208 || La9b3.1r2e-f3no.: Page 13of 31 ! PRIMARY DATA: Acute toxicity test with Acartia tonsa | Test substance: "FC-602 Light Water Brand ATC plus" || Lasbar.oreaft.e: 9190.31112.:939 Measurement: Number of dead | Total | Nsupmecbiemreonf NUMBER OF DEAD | number | pr. vessel 24 hours 48 hours. || Conc(enmtora)tion |Sppecrimeon||oBAnDcC .FE ||BA DG FE | Toa | AcE BDF | Tom | i {ol 000000 000010 || sss 100 5 0 | 000 | 0 | 410 4 43 i 2 7 4 : 56 4 5 Referencesubstance(3.6 dichiorophenol): _ _ 1.0 mg/h FER 3 01 1 Theresultwiththereferencesubstance iswithin the rangenormalyfound. | i| 1i ---- 002209 hLoibo. -- | Testsubstance: "FC-602LightWaterBrandATCplus" | Lab.ref.: 993123 `Start date: 10.11.99 Measurofooxmygeenannttpsh LsTeton wren] !| | concmengtr)ation | (Oxmyoge)n p-H O(xymgoenn p-H (Omxyognen o-H Comen e To TTaeo] | [ e E e Te ea | [ee a | TT TTT Rotorenc sbsiance(5dehoopnancy _ _ | | 002210 || pLabrsefmo: | || Page 15of 31 TEST FOR TOXICITY * Marine Amphipode: Corophium volutator i _ 5 3 002211 L9a9b3r1ef2i3no.: Page 16of31 TEST REPORT ds ! a ACUTE TOXICITY SEDIMENT TEST WITH THE MARINE AMPHIPOD Corophium volutator Q RE we RESEARCH TEST SUBSTANCE: "FC-602 Light Water Brand ATC plus" TEST RESULT: `The 10d LCs was calculated to >3070 mg kg" dry weight sediment. "The test substance was supplied by Novatech, and the test results relate o this product. TEST DETAILS: MeTsoD: TAoSxiTcMityE1T3e6st7s-9w0i,thStMaanrdianredaGnudidEestFuoarriCnoenSdeudcitmienngts1.0 day Static Sediment | TEST ORGANISM: Corophium volutator, from an unpolluted site near Trondheim. || | CULTIVATION: aTehreatteedstsoeragwaantiesrmast w1e5rCe.suAppslmiaeldlaasmaoduulnttso(f4-n8atmurmalisnesaiwzee)eadnwdawseruesehdeflodrin | fecding. PREPARATION: SNattauvraanlgesreawwaasteurse(sdalfionritdyi:lu3t4io%nc)waftrero.m aSneduinmpoelnltuctoeldlesictteedinatBaynfiuonrpdoelnluotuetsdisdiete awnaaslyusseeddffoorroprrgeapnaircincgontteestntseadnidmepnrtosp.orTtihoensseildtifmoernetaicshatmetu.ddy sand and was i dEaacmhptseestdicomnecnetnitnraatiploanwstaicsbupcrkeepta.red20b0ymalddoifnsgetahweatperrowduacst aindd6e0d0agnrdamtsheof | | 4bu0c0kmeti woafssesahwaakteenrfwoars3 ahdoduersd.toTchaechs,edainmdetnhtewbaesakdeirvsidweedreinatcortahtreedeobveearkers, { tnihgehdt.am1p0 saendiimmaelnstwwearse athneanlyrsaenddfoomrlwyasteelrecctoendtefnotr,eaancdhablleackoenrc.enAtrastaimopnlsearoef calculated as mg kg" sedimentdryweight. INCUBATION: sTehdeimteesnttw,aasppr.u4n0i0n mgllasosfsceoantwaaitneerrsan(d60100maln)imeaalcsh,c3onrteapilinciantges20fo0rgeoafcthest --_-- tcoenmcpeenrtartautrieono.f 1T5he+b1eaCk.erpsHwearnedkoexpytguenndemreacsourrienmueonutsswaeerraetipoenraftoarmed as indicated on the data sheet. i ---- ------ 002212 9La9b3.r1e2f3no. page 170f31 DATA ANALYSIS: CALCULATIONS: tTrhaetieofnfoecftaopnrotdheucsturlveitvhaallotofC5o0r%oopfhtieumevsotluatnaitmoarliss(eLxCpsr)e.sseTdhaesctohmebcionnecden- `mortality per test concentration were used for calculation. The 10 day LCsp `value and the 95% confidence limit are calculated by using the standard 29P30R,O%1B9o9Ift0Th)A.enaeTlshytissainspi,rmNoaalgtsri.aonmamleSawlesodicsahlcEulnavtiertoensmtecnotnaclenPtrroatteicotnisonleBtohaalrtdo(1Ve0r%siaonnd NOEC: Calculation of NOEC (No Observed Effect Concentration) is done bysingle- cfoanctcoerntArNatOioVnAmefaonllwoiwtehd tbhye Bcoonnfterorlromneiasnp.rocedure for comparing each TESTRESULTS: Table 1. LC and NOEC values obtained with "FC-502 Light Wate Brand ATC plus". -- Todas Co so Lon 30m Lon >30m0 NoEC: 200 GVVraaallupuehes ainrdeicncealtete 100%., b50y%PRanOdB9Ia0%aletyhal.ity NaftOerR1a0rCdayls. cdb Units in mgckgo"mpsuetdiemsenrt dorymweisght. VALIDATION: The validity citeia given in tthest protocol are fulfilled, i that the dissolved oxygen concentration at theendofthe test wasgreaterthanor equal to 60 %, the percentage mortality in the controls were less than 15% and a test with. Fislufooruanndtteonbe e(rweiftehreinncaec)cweapsteidn ltihmeitrsanogreorngoarmnailclcyofnotuenndt.buTthtehesesdiilmfernatctuisonedis recommended higher . Table 2. Characterstics ofthesedimentsed fr testing Organi conten 0) 07 Sit fncion 0) os Lab. ref. no.: Sample received. R`Teepsotrpterdiaotde:: 993123 20.09.99 03-12.12.99 07.01.2000 Enclosed: Data sheets SNe x,Hye _-- Elin Horve Age Molversmyr Engineer Analytical technician Senior Research Scientist Quality Assurance formotherthan infull,withoutthepermission in wrbiyRtF-iMinljlgab. 002214 Prrit Pes80st PRIMARY DATA: Acute toxicity test with Corophium volutator Testsubsane: "FG-602LightWaterBrandATCpls" Vesssamart: Lab. ref.: `Startdate: Nmbordoat 993123 03.1299 iI nTaoalr|| Nesupmercbiemreeonf| seme 10s NUMBER OF DEAD Conve w% 1w0 1 (Cmoncgecnrt/yrawetkiigohngt)|| Sppre.cciomnecn.|| A 8 C D E ACE F| B D F| Tot 5o8o |i Total | [-- =e _ The eslwit arelrercesubtance winhrangerraty om. 7_ ] 002214 Lab. refno. Page 19of 31 en Tre Tow] CCeomTTeee w e eeee] ] (mg/kgdryweight) (%) + (%) * (%) ` CCeoT Te e Te ew e a[w eeo]] 002215 993133 EEG aE DATA SHEETS ~ 002216 99312-3 HISDATASLAD (delse-, Wille og Sikkerhersdatabiad) sDoeksusmaetnczearz. : 0078-/21507/39-79 SUksrgeivteet ue :: 1110//1111//3588 VSiedersio1na:y 05.0o0n THeNlSe-fcoant:edl63ade6s47e5s 0u0sac/bTeeildeef:axa:v K3ilj84eav1d7el88ingen ved 34 Nozge A/S. 1 IDENTIFIRASION AV KIENIXALIZT 0G ANSVARLIG FIRMA. Iaporter: 3 Norge A/S | HancelFsCn-a2v0n1:3F LIGET WATER (TW) 13 APFF (FRSEZZ PROTECTED) || Telefo2n2,55Git13ci0n0formasjonssensraten: |i | 2 OPELYSNINGER ON KIZMISK SAMMENSZTNING. | Tntormasjon on enkeltkomporener, faresymbol(er) og risikesetninger i stoFevA cas-nz vexz-2a0s2NT | v2a-(2-3UTOKS)E-2TTOANROSL / (brETYLaNGLYRoLMONORUTYL ZTE) 171322--138545 3150.0--2319.00 . 1,2-ETFaanzoetsoyrm,boler/zisikosetninger: Fazesymboles/zisikosetninger: Kis Xa; R:36 R122 107-211 "100 ANLKFYOLT-ESRULFFLAUTO-RSOAALLTAEYRLANID-OEALVAT TRIETANOLANIN TTrraaddee SSeecczzeess 145..00 -- 1106..00 102-716 "a0 _ PERREFSLTUERORAOVALOKRYGLA-NSIUSLKFZONFALTU-OSRAKLJTEENRIFALIER TTrraaddee sSeeccrreett Ik1k.e0.Kj5e.n0t 00221' 993123 o FC-201a7 LIGHT WATER (D4) 13 APP (rrezzz pRorECTED) VVieraens FasenEa, Viseigate skadavickainges fre Helsefaze: ---- : sixtoshes: [-- Crem---- SAStuies asceskTsoneeayaaeeseTosperunwdaiigadmeeldberriekelSiugyettsiensssduensdervaseaess{empienrge:s 13 [S-- eyii seTsaekas hoaidessmyemdpcosniepss ocgapreitetligTeommeseseetreveenae.etFotrhaane Tor Tor cox brutes agen og Mase tiisens soter, THieak tasking: | #svpiasnasytmipntgoemieirioapnpnstderl,ybrfionrgEvreidekomTmaetnedesbosr:sfyrmapsonese vadrazes, i konzak: lege. 1 | TatarKEeodanivteaaiiksntenkTga:gpeicsuamniectcta.iba6che.AlFerkamknaolelGbireemksnaisgmeosmmkaunthseannchpdaveisdelos 1 ten PE -- Egneterbartainrniselsuknoifngosxmibdedaenlm:slukkinguniddel. Tike apne brannaluningsaiddats Ssponesiagacisiks ved beans: | 1 : - | 002218 993123 FO-201AF LIGHT WATER (TN) 1% APEF (FREEZE PROTECTED) Fosbrenningspzodukzes ved bran: 2eosedyzes ved siukking av brann: TELTAK VED UrrisIRTET Ursnize. PesonSleisveesiveeisinlettaikltaukn:der andre punter i dette HNS-datablades. TilakVabesnvosecidbleeuzsreinoldnsszihkdmseaetts.eruiStapsliieli.lpp:Sapviglrlensseasmleusmiodpdpelbuanritd.delDbeackc,tiRlenmgedjonet oncddes mad vaan. Plasseres i en egnt beholder med lok. FlemiSnegpuanvksdje13a,tkFaileirenaivatgallasv kjemikalieavearl. 7 ERDTERING 0G praEvARING. 3ecinSMg4de5lsiekekslelefsloalgresegiseknkieidsloemorrp.hpdbLeeavrgarrheivnsogr:vepdrodtueksspeestatkuern uknodmemre 4i3kgonrtaadkeer med cbeelhsoiludse.zenLastzeecst vleudkketsempnezratpurroed:uksoevte:ik0ksgraedrer& cbreulks.ius. fold uforanelise materiales: VentilOapsgjboenv:as enballasjen pd ot godt ventilert sted. Sikkeshetssiluak for 4 forhindze brann: SikkesThkektebsrteialrtsaakz.for & forhindre eksplosjon: Sikkezhetssiltak for 4 forhindre statisk elekerisites: ForhoHlodlsdregelbeasllvaesdjebnrukt:ect produkset kan royking flourkkkerts.akeRoyfkoirnugrenfsonribundgt:avUntdoebrakkbernukoga/velles sTtoaybkielnizoegsfoagrlirgeeskdteikviotnepto,nersiknagdsepleiogdeukdteekrompkoannendtaenrn,es. Se punke. i, == 002219 4Sa5v.ariejs.sno. rages FC-201AF LIGHT WATER (TH) 1% AFPF (rReEzE PROTECTED) 8 EXSIONIAINGSXONTROLL 0G FERSONLIG VERNEUTSTER, ; oyevesUan:nsh 4 dams, veraebeiller med vsepnrsaiyleerl:les tike i eynene. Bruk teste Hindveh3r3ia0n:Kdseegsniandgeavvessrreondaunkssiekse.r anbetales: Bucyiqumms. Vaevrnheehnasniskksesrmesasvissoimgeesnedreismleatveerdiales) Annet hudvera enn hiadvern: Unngh hudkontake. Anceczertavesn: oSeU%rynsaeeagl(nduzif)scikfneoonrdddnukadzjmieepnnsegs:rnaiovAngngdelesvudafzss1ekbseAatfrzaoebvrteeniridmngsa:eattenrhpoiaasarllttveaim.traiesenkBsea:svmeaaeslsg:reisosk:ei.nskeosnasvmeenfetoriagsonjdoenen pDertodu5ktei:k.keVsapsiseuss,sasdtreikkoenszhdeelrlerSrurnodyiksesneudndesripearobgelvdemmne.d Vask hRendene etter hiadtesing og fer spising. AnbetaESlvoitdsksvaeunntttsiuldgannsdijenodgnr:sevsecavtairlnasobennyitkckees.erSetcislscfroerdkiellsiisr,enmkdeseigynet vsednatiinliasscjroantivseLiktoamtescemopgk/oenlsleenstzkaosnjtornoalnleerhoslpdreasy aenidleers atigrpae.faite Adn. mores for foruzensning { asbeidsatmosfare, Februss 1396: va A(w1m7e3z2k-n1i8-n5g)es; agen ada. nora. 2-(2-A83n-UmcTeiOznNkeSnsYisEnTgOveResSr:Ya)lA-pmSoeTmAs:NiOkLa3n5s/k (gDrIeSnTsYLeEvNeGrEdLiIRaOsLbOeNfOaBlUtSYaLvETpErRo)dus(e1n1t2e-n3.45) (Tagen norsk aa. nosm) 1 ,2- E8sT--AttNiiDnnIeeOrrLss Takvezdl (vpv1oe0emr7d:d-:i212-m5p1ao)/m:m(dd:a-ng1()0stov()stev) . Takverdl ag/ad: - (dang) AMFOTEARvneFzLkUnOiRnOgAeLsK:YLIAnNgIeOn-DaEdRaI.VAnTor(aT.rade Secret) ALKYLA-nSnUeLzFkAaTi-nSgAeLsT:ERin(gTernadeadaS.ecrneotr)m. i |i i |]; ; 1 | ! |i| | |i ;: i : ;i i |t [;} a ii i 0i 02220 993123" vo FC-201AF LiGRT WATER (TY) 13 APPT(FREEZE PROTECTED) 7 actS-itnienerrss vveerraet: mpogm/:ml:- $ PETTLaU-OtRiOnAeLcKsYEv-eSrUdLiFOmNgA/Ta-dS:ALT0E,R1 (Trade Seces) A(sImnegzeknninnogresrk: sAdam.ecinkoawnmls.k grensevesdi assefalt av produsenten. RESTERS-AtVinOerRsGANvIeSrKEs mFgL/UaOdRsKJZ0M1INALGrIeEnRse(vTezraddie Saencszeefta)lt av J. fpenp------------ ilssendstorm, fasse, luke: ons Sokegunke/-incervatls Saelsesunke/-incervails Kiar raviarger vase. 15-0 - 100 C (sayanends kokepinks) Ike zelevant Fremmesunke: Selvantennelighet: Sxsstosjonsgrenses, nedre: Zksplosjonsgrenses, ovze: Despreyii: Loselighes 1 van: > 100 C (Miniflash) Tike rotevant Ihe relevant Ikke relevant - 16 emis (Kelkalers v/20 ) Blanner Spesifikk vekt: : = 1.10 (vann=l) Dasptesthes: a- 10 (luge) (Ralkulest v/20 Flykeige organiske forbindelser (VOC): = 353 g/L SCAQHD (g/L av Produkte) - Fordampningshastighet: < 1 (butylacetat=l) Viskositet: = 18 centipoise To 002221 La5d9.3r1e3t3no. ragesvy FE-301A7 LIGHT WATER (TN) 1% AFFE (FREEZE PROTECTED) se a seer | Foshold som skal unnsts: i HatestTeilkeerKseonnt.skel wants: FazlisGReaaszssbeporanlmtoannlioleknragisdppraoordgeuikkknlaaerssst.ondTiecmkmsiisdk. deRykdozmopgoennatrliunogriadv. bGruikfstfieerddiaymper, blanding forventes ikke 4 representere noen risiko. seebil5i1t5e1s1o5g FFaeralkinsivipcoelsy:mesisssion vil ikke forekome. [Rip ---------- EifextWseaoradcesozeyarns,e:evyehiererritoegsjookni:essysmppnt.ones kan vare coches, hevelse, 1| sttakHssoeydrmephzteaodtn:eshudkiecnrviatzaesiornedh(aatt,tehrevlealnsgev,ariKgiseelloegrtesiieemnetca.tt kontakt): Languazig elles giensast eksponesing kan fore til: | poi Allergisk hudreaksjon: symptomer kan vare redhet, hevelse, blemmer | Effektn2e1ormmeanizkn,enldsnkdeinonvgaf:zoreeksspiolntering som ovestiger asbafelts administrative Pschhveicc,knsionugniasvhasse,ntmraanlgnleecnvdeseysKteaomcedti:nessjyosrpsteormneer. kamnedsveesree hodspise, reaksjonsevne, sleret tale, svimmelhet og i ekstreme tilfeller bevisstleshet. - Ssveerligt,asihoonsti(nogveoeglnuytseivnegi.er): symptones kan vare shehet i nese 03 EttektOeyratsovreslogkingu:tfort med organiske dutta produkter, vise: effekter fsloumorLkejveenrifkoerlsitsyrr,reissoemr,fivnenkeistas, mNBeuenklgaaplereatntedt,sakbstpiepnraytzfieotreo,gmenshneleaessvthkoeelsrogSflar.nateDkeasftpfeofknovereserilnigzsgoemorveprhifvnogirefnkoesrksienemenietssekeleagt, fluorkjemikaliez ndr de brukes som forutsatt og i henhold til ! I | | 02222 La9b9.3r1e2f3ro. Pa27gofe31 FC-201AT LIGET WATER (TH) 1% AFFF (FREEIZ PROTECTED) veiledning. Svelsing kar fore sil: i 2hevziisnkeaningogavsygnyszsemnees:sess.ymptomer ker vare redisest urimensde, blod | kAosmpmiezrasnjeodnsonleuunngoennie.(LZunngaelbmeitnennenleilsseAsrosneksktyilldetsilsattanfdreenmmeedrlegeme: ohgopskseesto.p)p: blsoydmpotgonelsuagkeanbecveanrnaelhsoestisnogm, kapaustveavraensLkievrs,trugeinsdpei.ng, Informasjon om allessi, overfolsomhec: Kresztrenkallende esenskeses: } Asvestotskadelige esenskapes: | Regroduksjonsskadelige egensiaper: cd AndeeDestktaedepvirzoidnuikncgeetr,inhneeihsoel:der en eller flee organiske |i fluozkjentkalies, som muligens kan sbsorbeses og lagres i kroppen | onveedrbelyetnngirnegstsitdo,tieenrte(xmestoamboluitzgtaensg)s,moloegkyklaea:seklkluemsilesroems ved | Sfjoxensmaetacneeskeeksrpofnzeazienkgsepro.nerDietngfoovreelrifgogrerorgienngeinskkejefnltueorhkejlesmeisktefleiketres || az de brakes som foritsate og i heshold til veiledaing. i sFeonceeckeolnlsetenbefavoloirngianngiesnkeogfulaudoerrkpjoepauilkaasljioensesi bsloomdeatrbetiidlerdee,n har i| vsagsne paurbbleiisdeerrte vsiisdee:n i1n97g0endrseknaed.el3ise eepfiedxetmeiro.logiske studier av || 12 OPPLISNINGER OM MILJOFAZE. i PersisDtetetnes/apirooldougkitsekt niendnberryoslhdaesrheetn:eller flere organiske afillujoerektjen(ipkearlsiiesstenscoem).muligens ikke ez nedbrytbase og forblir i | i AndzeNesdkbardyetvaiicnkgn:inger, milje: ii 0300D 2(0Chdeamgieccasl O(xSyigoecnheDaeimcaanld)Oxy=ge1n71D0ema0n0d0)mg=/k4g3:4 000 mg/ks; 8020/00 = 29. on Akvatisk gitsigher: $022 28 wo3133 co FC-201A7 LiGHT WATER (TH) 13 ATF (FREEZE PROTECTED) 53510cimzaretr;s LesD for fisk (Fathead minnow (Pinephales promelss)) = s$3iit;imers 2030 for dapinia (Water flea (Daphnia masnal) = > 1000 5350 atiinzeesester1s0005f0o,r Maligreor=on> 1(0P0h0otaasb/elc;tesiun phosshoreum) = 63 a3stii;mers 2050, Activated Sludge Respiration Inhibition = > 1000 asi. Sorg for aviallshbngtering ihe. gieldende forskrifser. 13 Forni av TENTIAL. Hetade: for fjerning av kjesikaliesveells mSpaetseieaklsavfealllle.r Lbeevhearnciaivinaglslanlteislsenforofsfpeenstilsiigavgeoadlklj.ent innsamler, AEnObVeEfDaRlAcTsIGaOvRial07l:sgrAuVpPpAeLsL: FAA ORGANISKE PROSESSER. UeENnxDgcEikRooKrdAieTnIgGae7OmRiI0d6i0e70r3,:0:dHaeAlsvoifgnaeflnelskrstifeoransonrPigSadDBnliesrakve05feltketesssetmnoaiftdfilekerir,., spe, vaskevaske: oAegfasolslessitoutti.pummes: 7151 Organisk aviall med halogen. Spesielle Komponenter: fluosfosbindelses. 14 orpLreNINGER OW TaASFORT. AoR-Kiasse: - siffer: Bokstavs margnummer: corzcokort: -nurmees zeao-Klasse: 0G Klasse: : - : - - 3 022: L9a9b3.r1e2f3no. Page 290/31 FC-201AF LIGHT WATER (TH) 1% AFFF (FREEZE PROTECTED) I40G-sice: = Ewsenz.: - mag: - ovrigeTiokeppltyrsaanisnpgoerss:farlis sods. 15 OPFLYSNINGER OM LOVER 0G FORSKALFIZA. Nerkeetikers: SymbolEE(eLsS)T:STOELIG (Xa) Inneholder: 2-E(s2y-lebnussioykksoylet1o4ksy) -ezanel 19 3 R-sesnFianrgleisg: ved svelging. Irriterer oyaene. S-setninger: i Unngd inndnding av camp/sproytetdke. Unngd konzak: med eyrene og sltarnagkvseriGgrunkdoingtakm:edmesdorheudemne.ngdFiezr mvaannnsotgoffkeotntaikteynleengee;. Estktyelrl hcuadskhoenntdaekeo,g vviasskdmeenscesibpeenoolgdevraennn.elVleedr sevteilkgeitntge,n.kontakt lege Yi-geugoe: i 00 - | Kerr. 02y2r0kesmha/y1g,. lufebehor: oveigeOveonpnpelvyastneinmgeerckoimngmeecckebsatsiekretttpehn:tidligere merkeforskrifter og vil vianriedl4ertfiidnneerpsAtatptreosdakatvetfoelngetnidde mferrekmiovnegr,. sMoemckeizngbeanservtilph cevidezte merkeforsizifeer av januar 1938. Symbol: IRRITERENDE (Xi) "I Inneholder: 2-(2-busoksyetoksy)-etanol, 1,2-standiol IKrornittaekz:ermeedyneeynnee.ne.UssUgnhngihnnldaandgivnagrigavedlalmepr/sgpireenytsaeccehkkeo.ntUankntghmed _ hmuednegnd.esFivzanmnanogsckoofnfseetktiloeygen.eneE;ttesrkylhludksotnrtaakkst,gruvnadsikgmemdedsispteoreof Vann. Ved svelging, drikk to glass vann og kontakt lege i umiddelbare. 00R225 La9b9.3r1e3f.3no. Page 300f 31 FO-201AF LIGHT WATER (TH) 13 AFF (FREEZE PROTECTED) f00i-geupe: SeesieSLplilkekCeozlmhoveressisdeoagtoambbelsautdseasrfmboeerlisdfeearlr:sleigeogkjdeinsiskrailbiues:i.on av Helse-, ilje- os |i 23.. FFoorrsskisziifftc oomm kkllaassssiiftiisseerriinngg, ogmesmkariknigngm.va.v favarlsiSgoeffkjseommikalier. k45..anFFoomrressdkkfezrriieffetmoiolmmjessfptaeorsfeif.aklaasvtioatlelk.. 6 eee. | 16 Nome GpaLeSNTIGE AV SETHDNING Fo SRUKERNES stcnas 00 Aion. | Anvendelsesonzides: . | Filadannende skumkonsentrat for slukking av bramn ihydrokarbonesx. i VikiigDsatzaablkeidldef(rra) 34veGdenue:zraarlbeOifdfeilcseesn, aSvt.EMSPa-udla,taMbilnandeets:ota, USA. ResaHteille doaptpacbaltaedreitng:ex cavidess. Tilpasses nye EMS-detabladforskzifses, fastsatt i jances m1e9c38k.e-Eeoeg. ;| i fame coslysninges | o3I7pnefdloyreamsnaeisajgpoenrreondogpuhkbtedsetutentedeo:pEpNltSeo-tmdnmaiatnlageblasfdnoegmthhoelneddr.siZraihhkevtmeih:solbbderuutkkiloavgviprhrieonddntubekvrtaiernregnecsssim || pirkokeduketzeti' siamksevbairnemsejdondetmseed adnNdSr-edatparboldaudkette,r eelllleerr esnohmvmesedfaonvaeers pbreouskesasv || es brukerens ansvar. ii i i oy | : ii | i 00226 . La99v3.1r2j.3no. Pa31gofe31 FE-201AF LIGET WATER (TH) 1% AfPE (FREEZE PROTECTED) FOLGENDE PRODUKTER DEXKES AV DETTE HMS-DATABLADET: 3M To-nr. 2F-0002-0842-9 F3i%ghLtiignhgt FWoaatme,r F13C-2A0Z1FAF7,fir20e0 L 3M Toone. + 27-0002-0841-1 F3MighLtiignhgt Water Foam, F1C3-2A0F1FaF7,F1i0r0e0 L 3 Ione. XF-0008-0205-8 F3igLhitgihntg Fwoaatme,r F1C%-2A0F1FaF7,FiBreulk | 34 oar. XF-0008-0203-3 3M Lighs Water 1% AFFF Fize - Fighting Foam, FC-201a7,1000 L 3 o-nz. + X7-0008-0202-5 3 Light Fighting Water Foam, F1%C-A20T1F%,Fir2e00 1 3 1o-nr, XF-0008-0200-5 . F3iKghLtiignhgt vate: Foem, F1C%-2A0F1FaF7,Fize20 L ! weber POBox 2503Ulsnchasg 4008 Stavanger Norway en =3< Pro.feOlsavsHoanrssensuei 15 BS Thormeniensgt, 55 S 5008 Bergen o Norway = Telefax +a755543860 OO = oH o uF :;3 7d 4 23 a02228