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TRADE SECRET AR226-3179 DuPont-6818 Study Title H-24616: Static, Acute, 96-Hour Screening Test to Pimephales promelas Laboratory Project ID: DuPont-6818 AUTHOR: Daniel J. Peterson, B.S. STUDY COMPLETED ON: July 11,2001 PERFORMING LABORATORY: E.I. du Font de Nemours and Company Haskell Laboratory for Health and Environmental Sciences EUcton Road, P.O. Box 50 Newark, Delaware 19714-0050 Company Sanitized. Does not ccmfam TSCA CB1 -1- CERTIFICATION We, the undersigned, declare that this report provides an accurate evaluation of data obtained from this study. Work Completed by; -g^a^^^g?. .^Zg^o-^ ^usiuel J. Peterson, B.S. Associate Scientist // -Ju/y ^Of bate Ifsned by Study Director: A^^-^ / ^ Robert A. Hoke,PhD. Senior Research Ecotoxicologist //^7a^ ^PO/ Date Comoany SanKEzed. Dcss not canlam TSCA CBI -2- H-24616: Static, Acute, 96-Hour Screening Test to Pimephales promelas STUDY INFORMATION Substanc" ^^^Sfiff^ Svnonvms/Codes: H-24616 Haskell Number: 24616 Known Impurities: ^B^BBBj Physical Characteristics: Opaque tan liquid Sponsor: E. L du Font de Nemours and Company Wihnmgton, Delaware 19898 U.S.A. Study Initiated/Completed: June 25,2001 / July 11,2001 m-Ufe Initiated/Completed: June 25,2001 / June 29,2001 DuPont-6818 Company Sanitized. Does not contain TSCA CBI .3- H-24616: Static, Acute, 96-Hour Screening Test to Pimephales promelas DuPont-6818 SUMMARY The acute toxidty of H-24616 to the fathead minnow, Pimephales promelas, was determined in an unaerated, 96-hour, static test. The study was conducted with 4 concentrations of H-24616 and a dilution water control at a mean temperature of20.7C (range of20.7-20.8C). One test chamber was used per test concentration with 10 test organisms in each chamber. Based on visual observations, the water control and 1,10, and 100 mg/L test concentrations were clear and colorless at test start. The 1000 mg/L concentration was cloudy at test start. All water quality parameters were within acceptable limits during the exposure. Exposure of fathead minnows to the water control and nominal H-24616 concentrations of 1,10,100, and 1000 mg/L resulted in 0,0,0,0, and 100% mortality, respectively, at the end of 96 hours. No mortality or sublethal effects were seen in the water control test organisms. The highest nominal concentration causing no mortality at test end was 100 mg/L. The lowest nominal concentration causing 100% mortality at test end was 1000 mg/L. Nominal H-24616 concentrations were used for calculation ofLCso values. The results are summarized as follows: Nominal concentrations of H-24616, mg/L 96-hour LCso (95% confidence interval) for H-24616, based on nominal concentrations, mg/L" dilution water control, 1,10,100, and 1000 316 (100 to 1000) H-24616 exhibited low concern for aquatic hazard1' in an unaerated, 96-hour, static, acute test using the fathead minnow, Pimephales promelas. * Stephan, C.E. (1997). Methods for calculating an LC5o. Aquatic Toxicology and Hazard Evaluation, Proceedings of the First Annual Symposium on Aquatic Toxicology, ASTM Special Publication 634 (FJ-. Mayer and J.L. Hamelmk, Eds.), pp 65-84. Philadelphia. 11 Smrehek, J., Clements, R., Morcock, R., and Rabert, W. (1993). Assessing ecological hazard under TSCA: methods and evaluation of data. Environmental Toxicology and Risk Assessment, ASTMSTP 1179. (W.G. Landis, J.S. Hughes, and MA. Lewis, Eds.), pp 22-39. American Society for Testing and Materials, Philadelphia, PA. Company Sanitized. Does not contain TSCA CB1 ~T- TABLE 1 DISSOLVED OXYGEN AND pH OF TEST AND CONTROL SOLUTION SAMPLES Nominal H-24616 Concentration (mg/L) Test Initiation (0 hours) Dissolved Oxygen (mg/L) PH Test Completion (96 hours) Dissolved Oxygen (mg/L) PH Water Control 9.0 7.4 7.7 7.4 1 9.0 7.3 6.9 7.3 10 9.0 7.3 7.2 7.3 100 9.0 7.2 7.3 7.3 1000 8.9 7.2 7.98 7.28 a Measurement taken at 24 hours due to total mortality TABLE 2 MORTALITY OF Pimephales promelas IN AN UNAERATED, STATIC, ACUTE, 96-HOUR TESTWITHH-24616 Nominal H-24616 Concentration (mg/L) Water Control 1 10 100 1000 24 Hours 0/10 0/10 0/10 0/10 10/10 Number Dead / Number at Study Start 48 Hours 72 Hours 0/10 0/10 0/10 0/10 10/10 0/10 0/10 0/10 0/10 10/10 96 Hours 0/10 0/10 0/10 0/10 10/10 Company Sam-feed. Does not contain TSCA CBI -5-