Document dY24d9xGN53g3wO9Mbzk6kovQ

rI . t Lung function in *others exposed to pofyrinyt chloride dust 151 Miller A, Tknub AS, Chora* M, SeHJtoff U. Chmfu la pulmonary faietioa in worker* anpoted to viayi chloride end polyvinyl chloride. Ami JtYAmJSel 1915; Ht:41'S2. v Morris JF, Keek A, Johnson LC. Splrometrie sunderds for healthy neranokin* adults. Am Xwr Jlasplr Mr 1971 {]OS7*47. "Araaud A, Foounkr d* Sent! P, Cut* L, Fiymn H, Chirpio J. Folyvlayl chloride pneumoconiosis. Thorax 1971:33:19-25. * UUs A, Anderson H, Nicholson WJ, Doum S, Hthhrin l AS, Sehkoff IJ. Prevalence of disease imonfcst vmyl chloride end polyvinyl chloride workers. Am* ttYAcoA Sri 191S0M224U .M Cota JE. Luxtfunction. 3rd cd. Oxford: Kidnwn. 1973: 21 1 ** Cota JE, Rirsiter CE, Hifrini ITT, Gilson JC. Avcrsie normal values fhr forced mpirnety volume la white Caucasian mala. Jr A/rd/ 1966;1:1016-9. M Fletcher C, Fete A* Tinker C, Spetxer FE. The natural history of ehroale bronchitis and tmfihyttma. London: Oxford University Press. I97f33>3l. I i \ < i I j b * t f V. ',5 ! 1` t^ : SS ~e- M -A I ! 1 d t "*r i Vk i f: f- / AP00010175 t \ V%, V i i ^c:.y^ " %*" " O <1 -;V >s ^ <r i f i V i i APOOOfOf 76 jaitfi Idff y\ Hazardous Materials -Emergency Action Guide 1976 U.S. Department of Transportation National Highway Traffic Safety Administration AP0b6fdl77 m PREFACE t This guide was prepared to help emergency service personnel during the first 30 minutes of an incident involving a spill of a volatile, toxic, gaseous and/or flammable material that is shipped in bulk. General and specific safety procedures to follow are provided in spill guides arranged alphabetically by hazardous material. Each left hand page identifies a specific hazardous material, outlines its potential hazards and provides immediate action information for fires, spills and first aid. This page also lists certain functions and services for those with appropriate resources and equipment. Each right hand page specifies recommended evacuation areas and distances* for protecting the public from dangerous concentrations of toxic vapors and explosions. Where applicable, necessary water pollution controls are provided. This page also lists procedures to follow when assistance is needed or when appropriate resources and equipment are not available. To establish an evacuation area for a poisonous material, emergency service personnel need only estimate the size of the spill puddle. Illustrations on the right hand page offer quick reference for determining an evacuation based on spill puddle size. Exclusion distances covering ignition control and blast effects are given for certain flammable materials. The time required to evacuate a specific area may not always be practical -- especially lor extremely toxic materials with high evaporation rates. Therefore, the use of the spill guides will not always eliminate a threat to the public near a spill. Evacuation distances are provided to reduce the danger of flying fragments caused by an explosion. Explosions have occurred from two minutes to 48 hours after a tank car or tank truck involvement in afire. The maximum reported fragment distance from an exploding tank car is 4,900 feet. A 100 per cent safe evacuation distance is some distance greater than 4,900 feet, but may not be practical to attain. At a distance of 2,000 feet, the estimate is one fragment-caused fatality per 100 incidents. The probability increases greatly at shorter distances. An evacuation radius should be enlarged as time permits. Every effort should be made to prevent outsiders and non-essential personnel from entering the danger zone. 'Recommended evacuation areas are baaed on principles and calculations developed by the NASA Aerospace Safety Research and Date Institute, Lewis Research Center, Cleveland, Ohio; and under contract lo DOT by the Chemicsl Propulsion Information Agency, Johns Hopkins University, Applied Physics Laboratory. Silver Spring, Maryland. Diffusion data and calculations are based on the publication Workbook of Atmospheric Dispersion Estimate* by D. Bruce Turner, Environmental Protection Agency, Research Trlangla Park, North Carotins. I i i I iii wi AP000I0178 FOREWORD This document was compiled from sources representing the best opinions on the subject at the time of its preparation. However, it.should not be assumed that ail acceptable safety measures are mentioned or that other measures may not be necessary under certain circumstances/ Comments concerning this booklet may be addressed to: U.8. Department of Transportation National Highway Traffic Safety Administration Emergency Medical Services Branch 400 Seventh Street, S. W. Washington, D. C. 20590 Or U.S. Department of Transportation Materials Transportation Bureau MTH-21 Office of Hazardous Materials Operations 2100 Second Street, S. W. Washington, D. C. 20590 It is recommended that this booklet be kept in the vehicles of emergency service personnel (fire, police, medical and maintenance) who may encounter emergencies involving hazardous materials. The booklet may also be of use to emergency service dispatchers and Civil Defense coordinators. This booklet was printed originally in 1973 by the U.S. Department of Transportation's Office of Hazardous Materials (now the Office of Hazardous Materials Operations) under the tide Emergency Services Guide for Selected Hazardous Materials. The National Highway Traffic Safety Admin istration (NHTSA) has revised the original format to achieve a broader application of Highway Safety Program Standards 11,15 and 16 as well as to the total transportation sector. Seven new materials have been added to those contained in the original edition. NHTSA's Enforcement and Emergency Services Division expresses its appreciation to the Office of Hazardous Materials Operations for its technical assistance in preparing this booklet V AP00010179 CONTENTS PREFACE .............................. FOREWORD ........................... CHEM-CARDS....................... HAZARDOUS MATERIAL Acrolein ................................. Acrylonitrile .......................... Ammonia .............................. Ammonia, anhydrous ........... Boron Trifluoride .................. Bromine................................. Carbon Disulfide .................... Chlorine................................. Dimethylamine....................... Dimethyl Ether..................... Dimethyl Sulfate ................... Epichlorohydrin..................... Ethyl Chloride ..... ................ Ethylene................................. Ethyleneimine ....................... Ethylene Oxide ..................... Fluorine ................................. Hydrocarbon Fuels................ (Gasoline and similar fuels) Hydrogen, liquid ................... Hydrogen Chloride................ Hydrogen Cyanide................ Hydrogen Fluoride .......... Hydrogen Sulfide .................. Liquid Petroleum Gas (LPG) Methane, liquid .............. .... Methylamines, anhydrous ... Methyl Bromide ..................... Methyl Chloride............ . Methyl Ethyl Ether ................ Methyl Mercaptan.................. Monomethylamine ................ Nitric Acid, fuming................ Nitrogen Tetroxide................ Oleum/Sulfur Trioxide ......... Oxygen, liquid ...................... Phosgene ............ ................ Phosphorus Trichloride ....... Propane/LPG ........................ Sulfur Dioxide .............. . Sulfur Trioxide....................... Titanium Tetrachloride ...... Trimethylamine ..................... Vinyl Chloride ....................... f Hi V 1 2 4 6 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 52 54 56 58 60 62 64 66 68 70 72 74 76 78 80 82 84 86 vii AP000I0180 *f k-r. i ik CHEM-CARDS Many drivers transporting hazardous materials carry Chem-Cards in the cabs of their vehicles. Each Chem-Card provides: A brief description of a specific hazardous material. A statement concerning the hazardous nature of the material. General guidelines for coping with an emergency situation in case of fire, leak, spill or exposure to humans. This is a facsimile of a typical Chem-Card MCA CHEM'CARD -- Transportation Emergency Guide f CC-55 1 JUftt isss Dimethyl Sulfate Clear, colorless liquid; slight odor HAZARDS f--------------------FIRE cafch fire. CYOnCIIPF Vapor extreme/y irritating. LUNG INJURY MAY BE tArUpUKt DELAYED, liquid minm mvi burnt. IN CASE OF ACCIDENT IF THIS HAPPENS O SPILL or LEAK DO THIS O Keep upwind from small spills. Evacuate area in case of large spills or tank rupture. Shut off leak if without risk. If necessary to enter spill area, wear self-contained breath ing apparatus and full protective clothing including boots. Flush area with water spray. F On small fire use dry chemical or carbon dioxide. On large fire use water spray. Wear self-contained breathing apparatus and full protective clothing. Cool tank with water if exposed to fire. EXPOSURE Remove to fresh air and call a physician at once. If not breathing, apply artificial respiration, oxygen. If breathing Is difficult, administer oxygen. Keep patient at rest and under observation for 24-48 hours; effects may be delayed. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; remove contam inated clothing and shoes at once. uut'im. in. ius Cwwcumrm* N*. Mew D c m, IBS m.w kiu.h i-m wiirit Mi<n< rau. m iwhm inn m iwwi iui lx mwai n. m cats, wnct iWm <> till AP00010181 t Acrolein (Flammable, Thermally Unstable, Poisonous) A Potential Hazards Fire:--May be ignited by heat, sparks, flames. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Runoff may create fire or explosion hazard in sewer system. Health:--Vapors extremely irritating. Contact may cause bums to skin and eyes. --Fire may produce irritating or poisonous gases. --Vapors may be fatal if inhaled. --Runoff may pollute water supply. i I Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at /east 20 yards away. --Keep up wind and estimate Immediate Danger Area. --Evacuate according to Evacuation Tab/e. Immediate Follow-up Action [ > [ [ f Fire:--Small Fire: Dry Chemical or C02. --barge Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance untit welt after fire is out. --For massive fire In cargo area, use unmanned hose holder or monitor nozzles. --Stay away from ends of tanks. --Withdraw Immediately in case of rising sound from venting safety device. ! j l i J Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. --barge Spills: Dike for later disposal. --Small Spills: Take up with sand, earth or other noncombustfbfe, absorbent material. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of contact or inhalation may be delayed. --If victim is not breathing, give artificial respiration. if breathing is difficult, give oxygen. -- If victim contacted material, Immediately flush skin or eyes with running water for at feast 15 minutes. --Remove contaminated clothes. --Keep victim warm and quiet. i Jj .7! AP000I0I82 t r > t For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Prevent runout from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or i\ Environmental Protection Agency of the situation through Chemtrec or your local authorities. \ J Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 360 yards (432 paces) 2 miles long, 1 mile wide 530 yards (636 paces) 3 miles long, 2 miles wide 650 yards (780 paces) 4 miles long, 21/2 miles wide 760 yards (912 paces) 5 miles long, 3 miles wide In the event of an explosion, the minimum safe distance from Hying fragments is 2,000 feet In all directions. I- f f t i ) AP00010183 Acrylonitrile (Flammable, Thermally Unstable, Corrosive) Potential Hazards Fire:--HiQhly flammable. -- Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Runoff may create fire or explosion hazard in sewer system. Health:--Contact may cause burns to skin and eyes. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate ail open flames. No smoking. No flares. Keep internal combustion engines at feast 20 yards away from spill. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Small Fire: Dry chemical or CO3. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Coot containers with water from maximum distance until well after fire is out. -- For massive fire in cargo area, use unmanned hose holder or monitor nozzles. --Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. --Large Spills: Dike for later disposal. --Small Spills: Take up with sand, earth or other noncombustible, absorbent material. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of contact or Inhalation may be delayed. --If victim is not breathing, give artificial respiration. if breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin, or eyes with running water for at least IS minutes. --Remove contaminated clothes. --Keep victim warm and quiet. 4 AP00010I84 ii tdMHMHi iUiiu, For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa. Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action -- For more detailed assistance in controlling the hazard, cali Chemtrec (Chemical Transportation Emergency Center) toil free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, If known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. i Immediate Danger Area Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 20 yards (24 paces) 20 yards (24 paces) 30 yards (36 paces) 30 yards (36 paces) 528 feet long, 528 feet wide 528 feet long, 528 feet wide 526 feet long, 528 feet wide 1*056 feet long, 528 feet wide In theeventofan explosion, the minimum safedlstance from flying fragments is 2,000 feet in all directions. AP00010185 r f 'ase&mi* Ammonia (Nonflammable Gas, Corrosive) Potential Hazards Fire:--May catch fire. Explosion: --Container may explode due to heat of fire. Health:--Vapors extremely irritating. Contact may cause burns to skin and eyes. if inhaled, may be harmful. --Runoff may pollute water supply. Immediate Action____________________________________ -- Get helper and notify local authorities. -- If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Small Fire: Dry chemical or C02. --Large Fire: Water spray or fog. -- Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. --Stay away from ends of tank^ Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. -- Use water spray to reduce vapors. -- Do not put water on liquid ammonia pool. -- Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. Call for emergency medical care. -- it victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. -- Remove contaminated clothes. -- Keep victim warm and quiet. 6 APobbfbi86 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico, and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424*9300. You will be asked for the following information'. Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Ammonia is water soluble and can kill fish. Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Runoff to storm sewers or sanitary system is acceptable if a water deluge and/or flooding is possible. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or. your local authorities. Evacuation Table -- Based on Prevailing Wind of $*12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 40 yards (48 paces) 60 yards (72 paces) 80 yards (96 paces) 90 yards (108 paces) 1,056 feet long, 528 feet wide 1,584 feet long, 1,056 feet wide 2,112 feet long, 1,056 feet wide 2,112 feet long, 1,584 feet wide In theeventofanexplosion.theminimum safedistancefrom flying fragments is 2.000 feet in all directions. I AP00010187 Ammonia, Anhydrous (Nonflammable Gas, Corrosive) Potential Hazards Fire:--May catch fire. Explosion:--Container may explode due to heat of fire. Health:--Vapors extremely Irritating. Contact may cause bums to skin and eyes. If inhaled, may be harmful. --Runoff may pollute water supply. Immediate Action____________________________________ --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area. -- Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Small Fire: Dry chemical or C02. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. --Stay away from ends of tanks. Spill or Leak:--Do not touch spilled liquid.--Stop leak if without risk. --Use water spray to reduce vapors. --Do not put water on liquid ammonia pool. --isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. Call for emergency medical care. -- If victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. --If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. --Keep victim warm and quiet. 8 1 AP000I0I88 For Assistance Call Chemtrec toil free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico, and Alaska, call (202) 483-7616. Additions! Follow-up Action_________________________ ______________ --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toil free (800) 424-0300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control______________________________________ --Ammonia is water soluble and can kill fish. Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Runoff to storm sewers or sanitary system is acceptable if a water deluge and/or flooding is possible. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 40 yards (48 paces) 60 yards (72 paces) 60 yards (96 paces) 90 yards (108 paces) 1,056 feet long, 528 feet wide 1,584 feet long, 1,056 feet wide 2,112 feet long, 1,056 feet wide 2,112 feet long, 1,584 teet wide In the event of an explosion, the minimum safedistance from flying fragments is 2,000 feet in all directions. ' 1 j APOOOibf89 r Boron Trifluoride (Nonflammable Gas, Poisonous) Potential Hazards Fire:--Cannot catch fire. --Cannot support combustion. Health:--Vapors extremely irritating. Contact may cause burns to skin and eyes. -- Vapors may ba fatal if inhaled. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. -- If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Eva~uation Table. immediate Follow-up Action Fire:--Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. Spill or Leak:--Stop leak if without risk. --Use water spray to reduce vapors. --Isolate area until gas has dispersed. -- Do not apply water directly to leak. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of inhalation may be delayed. --If victim is not breathing, give artificial respiration. Administer oxygen at once. In case of severe exposure, continue intermittent oxygen administration for at least 6 hours. --If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. --Keep victim warm and quiet. 10 AP0O0I0190 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands. Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control -- Prevent runoff from lire control or dilution water from entering streams or drinking water suppty. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of thesituation through Chemtrec or your local authorities. i 1 j g { 1 ' j [ j j ! , Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 210 yards (252 paces) 1 mile long, 3/4 mile wide 400 square feet 310 yards (372 paces) 1 3/4 miles long, 1 mile wide 600 square feet 380 yards (456 paces) 2 mile* long, 1 1/2 milee wide 800 square feet 445 yards (534 paces) 2 1/2 miles long, 13/4 miles wide Caution: Although Boron Tnfluoride does not form an explosive mixture, the container In which it is shipped may explode under pressure from a fire. For maximum safety, evacuate 2,000 feet in all directions. 1 APOOOf0191 Bromine (Corrosive, Oxidizer) Potential Hazards___________________________________ Fire:--Cannot catch lira --May ignite combustibles. Health: -- Liquid causes bums to skin and eyes. --Vapors extremely irritating. -- Vapors may be fatal it inhaled. --Runoff may pollute water supply. i f [ Immediate Action __________ --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action__________________________ Fire:--Move containers from fire area if without risk.. --Cool containers with water from maximum distance until well after fire is out. Spill or Leak:--Large Spills: Dike for later disposal. --Smafi Spills: Neutralize with lime water if available or flush area with water. --Do not touch spilled liquid. --Stop leak If without risk. --Use water spray to reduce vapors. First Aid:--Remove victim to fresh air. Call for emergency medical care. --If victim is not breathing, give artificial respiration. If breathing is difficult, give oxvgen. --If victim contacted material, immediately flush skin or eyes with running water for at least IS minutes. --Remove contaminated clothes. --Keep victim warm and quiet. is AP00010192 For Assistance Call Chemtrec toll free (800) 424-9300 In tha District of Columbia, the Virgin Islands, Guam, Samoa. Puerto Rico and Alaska, call (202) 463-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (600) 424-0300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water PoUution Control --Bromine is water soluble andean kill fish. Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 195 yards (234 paces) 1 mile long, 2/3 mile wide 400 square feet 285 yards (342 paces) 1 1/2 miles long, 1 mile wide 600 square feet 350 yards (420 paces) 2 miles long, 1 1/4 miles wide 800 square feet 410 yards (492 paces) 2 1/3 miles long, 11/2 miles wide Caution: Although Bromine does not form an explosive mixture, the container in which It is shipped may explode under pressure from a fire. For maximum safety, evacuate 2,000 feet in all directions. t APobdtbfW r t Carbon Disulfide (Flammable Liquid) i Potential Hazards____________________ .__________ Fire:--Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Runoff may create fire or explosion hazard in sewer system. Health:--Fire may produce irritating or poisonous gases. -- Vapors indoors may causa dizziness or suffocation. -- Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. -- If possible, wear full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines af faast 20 yards away from spill. -- Keep upwind and estimate Immediate Danger Area, --Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Smalt Fire: Dry chemical or COs. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. f --Cool containers with water from maximum distance until well after fire is out. i --Stay away from ends of tanks. Spill or Leak:--Stop leak if without risk. --Use water spray to reduce vapors. --Large Spills: Dike for later disposal. --Small Spills: Take up with sand, earth or other noncombustible, absorbent material. First Aid:--Remove victim to fresh air. Cali for emergency medical care. -- If victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. --Keep victim warm and quiet. I i i t 14 AP00010194 For Assistance Call Chemtrec toll free (800) 424-9300 1 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. i Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec i (Chemical Transportation Emergency Center) toll free (800) 424-9300. Vou will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. <in IS --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control ____________ --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. i Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 20 yards (24 paces) 526 feet long, 528 feet wide 30 yards (36 paces) 528 feet long, 528 feet wide 600 square feet 40 yards (48 paces) 1,056 feel long, 528 feet wide BOO square feel 45 yards (54 paces) 1,056 feet long, 528 feet wide In theevent of an explosion, the minimum safe distance from flying fragments is 2,000 feet In all directions. AP00010195 Chlorine (Nonflammable Gas, Poisonous) Potential Hazards Firs:--Cannot catch fire. --May ignite combustibles. Explosion:--Container may explode due to heat of fire. Health:--Contact may cause burns to skin or eyes. -- Vapors may be fatal if inhaled. --Runoff may pollute water supply. immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. --Do not get water inside containers. --Do not use water on chlorine leak. --Stay away from ends of tanks Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. --Isolate area until gas has dispersed. --Do not get water inside containers. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of contact or inhalation may be delayed. -- If victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for at ieast 15 minutes. -- Remove contaminated clothes. ' -- Keep victim warm and quiet. 16 AP0b6f6f96 r ^ :Y-V,g- . --<------ -------------- -------------- . j For Assistance Cali Chemtrec toll free (800) 424-9300 I In the District of Columbia, the Virgin Islands, Guam. Samoa, Puerto Rico and Alaska, call (202) 483-7616. i Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (808) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. | Name of product and shipper, If known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on ; population. i Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec oryour local authorities. . 1 Immadiatv Danger Area Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 160 yards (192 paces) 1 mile long, 1/2 mile wide 240 yards (288 paces) 1 1/2 miles long, 1 mile wide 300 yards (360 paces) 1 1/2 miles long, 1 mile wide 340 yards (408 paces) 2 miles long, 11/2 miles wide in the eventof an explosion, the minimum safe distance from Hying fragments is 2,000 feet in all directions. 17 \ &i AP000I0197 f Dimethylamine (Flammable Gas, Corrosive) Potential Hazards Fire:--Highly flammable. -- Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion hazard indoors, outdoors or in sewers. Health:--Vapors extremely irritating. Contact may cause bums to skin and eyes. Immediate Action -- Get helper and notify local authorities. -- If possible, wear self-contained breathing apparatus and full protective clothing. -- Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at least 20 yards away from vapor cloud. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. j Immediate Follow-up Action Fire: -- Let burn unless leak can be stopped immediately. --Small Fire: Dry chemical or C02. --Large Fire: Water spray or fog. -- Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. Apply water from sides of tanks. --F6r massive fire in cargo area, use unmanned hose holder or monitor nozzles. If this is impossible, withdraw from area and let fire burn. , -- Stay away from ends of tanks. i j 1 j | Spill orLeak:--Oo not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. -- Isolate area until gas has dispersed. i First Aid:--Remove victim to fresh air. Call for emergency medical care. -- If victim is not breathing give artificial respiration. If breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. -- Keep victim warm and quiet. is l ____________ _________________ 1 1 AP00010198 For Assistance Cali Chemtrec toil free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action -- For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Wafer Pollution Controf --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Baaed on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Ba 200 square feet 400 square feet 600 square feet 800 square feet 70 yards ( 84 paces) 1,584 feet long, 1,056 feet wide 100 yards (120 paces) 4,224 feet long, 1,584 feet wide 125 yards (150 paces) 3,168 feet long, 2,112 feet wide 150 yards (180 paces) 3,696 feet long, 4,224 feet wide in theevent of an explosion, the minimum safe distance from flyingfragments is 2,000 feet in all directions. apoooioi99 Dimethyl Ether (Flammable Gas) Potential Hazard*_______________________ _____________ _ Fire:--Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion hazard indoors, outdoors or in sewers. Health:--Vapors indoors may cause dizziness or suffocation. --Contact may cause burns to skin and eyes. Immediate Action --Get helper and notify local authorities. -- If possible, wear full protective clothing. -- Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at toast 25 yards away from spill. --Keep upwind. Isolate hazard area. --Evacuate by at least 2,000 feet. Immediate Follow-up Action Fire:--Let burn unless leak can be stopped immediately. --Small Fire: Dry chemical or C02. --Large Fire: Water spray or fog. --Move containers from fire area If without risk. --Cool containers with water from maximum distance until well after fire Is out. Apply water from sides of tank. --For massive fire In cargo area, use unmanned hose holder or monitor nozzles. If this is impossible, withdraw from area. --Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. -- Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. --Use standard first aid procedures. AP00010200 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424*9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. 1 ' , * I I I | > i [ tn Cat* of Explosion, th* Minimum Salt DftUnc* from Flying Fragment* la 2,000 Part In All Dlractlona. 21 _____ J AP00010201 Dimethyl Sulfate (Combustible Liquid, Poisonous) Potential Hazards Fire:--May catch fire. Health:--Liquid causes burns to skin and eyes. --Vapors extremely irritating. -- Vapors may be fatal If inhaled. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at least 20 yards away. --Keep upwind and estimate Immediate Danger Area. -- Evacuate according to Evacuation Table. immediate Follow-up Action Fire:--Small Fire: Dry chemical or COa. -- Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water if exposed to fire. --Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Large Spill: Dike for later disposal. --Small Spill: Flush area with water. --Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of inhalation may be delayed. --If victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. --If victim contacted material, Immediately flush skin or eyes with running water for at least 75 m/nutes. --Remove contaminated clothes. --Keep victim warm and quiet. n AP00010202 r For Assistance Call Chemtrec toll free (800) 424-9300 in the District of Coium bia, the Virgin islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483*7616. Additional Follow-up Action____________________________________ -- For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, It known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control___________ ___________________________________ -- Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. t 1 \ { ' I ! i | Evacuation Table -- Baaed on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 50 yards (60 paces) 1,056 feet long, 528 feet wide 400 square feet 600 square feet 75 yards (90 paces) 1/2 mile long, 1/4 mile wide 95 yards (114 paces) 1/2 mile long, 1/3 mile wide 800 square feet 110 yards (132 paces) 1/2 mile long, 1/3 mile wide Caution: Although Dimethyl Sulfate does not form an explosive mixture, the container In which if is shipped may explode under pressure from a (ire. For maximum safety, evacuate 2.000 feet in ail directions. J AP000I0203 Epichlorohydrin (Flammable, Poisonous) Potential Hazard* Fire:--Highly flammable. Explosion:--Container may explode due to heat of fire. Health:--Vapors extremely irritating, Contact causes severe bums to skin and eyes. --Inhalation harmful -- lung injury may be delayed. --Runoff may pollute water supply. Immediate Action______________ --Get helper and notify local authorities. -- if possible, wear self-contained breathing apparatus and full protective clothing. --Keep internal combustion engines at least 20 yards away from spill. -- Keep upwind and estimate Immediate Danger Area. -- Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Small Fire: Dry chemical or C02. --Large Fire: Water spray or foam. --Cool containers with water from maximum distance until well after fire is out. --Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Do not touch spilled material. --Stop teak if without risk. --Use water spray to reduce vapors. --Small Spills: Flush area with water spray. --Large SpUls: Dike for later disposal. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of contact or inhalation may be delayed. --If victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. --if victim contacted material, immediately flush skin or eyes with running water for at least IS minutes. --Remove contaminated clothes. --Keep victim warm and quiet. APOOO10204 i For Assistance Call Chemtrec toll tree (800) 424-9300 In the District of Columbia, the Virgin islands, Guam, Samoa, Puerto Rico and | Alaska, call (202) 483-7616. Additional Follow-up Action______ --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. | * * Location of the accident. | Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. , Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Epichlorohydrin is water soluble and can kill fish. Prevent runoff from fire control or dilution waterfrom entering streams ordrinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Baaed on Prevailing Wind of 6-12 mph. Approximate Sire of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Ba 200 square feet 400 square feet 600 square feet 800 square feet 26 yards (32 paces) 37 yards (45 paces) 46 yards (56 pacts) 54 yards (64 paces) 528 feet long, 528 feet wide 1,056 feet long, 528 feet wide 1,056 feet long, 528 feet wide 1,056 feet long, 1,056 feet wide In theeventofan explosion, the minimum safedistancefrom flying fragments is 2,000 feet in all directions. Ethyl Chloride (Flammable Liquid, Corrosive) Potential Hazards Fire:--Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Runoff may create fire or explosion hazard In sewer system. Health:--Contact may cause burns to skin and eyes. If inhaled, may be harmful. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep interna) combustion engines at least 20 yards away from spill area. --Keep upwind. Isolate hazard area. -- Evacuate by at least 2,000 feet. Immediate Follow-up Action Fire;--Small Fire: Dry chemical or C02. --Large Fire: Water spray or fog. --Move containers from fire area If without risk. --Cool containers with water from maximum distance until well after fire is out. --For massive fire in cargo area, use unmanned hose holder or monitor nozzles. If this is impossible, withdraw from area and let fire burn. --Stay away from ends of tanks. Spill or Leak:--Do not touch spilled material. --Stop leak if without risk. --Use water spray to reduce vapors. --Large Spills: Dike for later disposal. --Small Spills: Take up with sand, earth or other noncombustible, absorbent material. First Aid:--Remove victim to fresh air. Call for emergency medical care. -- If victim is not breathing give artificial respiration. If breathing is difficult, give oxygen. --If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Keep victim warm and quiet. j j 26 AP00010206 L ^ For Assistance Call Chemtrec toll free (800) 424-9300 I In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action_____________ _____________________ -- For more detailed assistance in controlling the hazard, call Chemtrec , (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. ; j j ' j j In Case of Explosion, tho Minimum Soft Dlt "e* from Flying Frogmont* U 2,000 Foot In All Direction* i 27 Jt AP00010207 Potential Hazards__________________ ___________________ Fire:--Highly flammable. --Flammable vapors may spread from spill. Explosion: --Container may explode due to heat of fire. Health:--Vapors indoors may cause dizziness or suffocation. --Contact with liquid may cause bums to skin and eyes. Immediate Action ______________________________ --Get helper and notify local authorities. --If possible, wear full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at least 50 yards away from vapor cloud. --Keep upwind, isolate hazard area. --Evacuate byaf /east 2,000 feet Immediate Follow-up Action ________ Fire:--Let burn unless leak can be stopped immediately. --Small Fire: Dry chemical or CO*. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after lire is out. Apply water from sides of tank. --For massive fire In cargo area, use unmanned hose holder or monitor nozzles. If this is impossible, withdraw from area. --Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak: --Do not touch spilled liquid. --Stop leak if without risk. --isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. --Use standard first aid procedures. 28 AP00010208 r For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up /teflon ______________ __ --For more detailed assistance in controlling the hazard, call Chemtrec ' (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. 1 In Cat* of Explosion, th* Minimum Sate Olatanca from Plying Fragment* la 24)00 F*t In All Direction*. 29 AP00010209 Ethyleneimine (Flammable, Thermally Unstable, Poisonous) Potential Hazards Fire:--Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Runoff may create fire or explosion hazard in sewer system. Health:--Vapors extremely irritating. Contact may cause burns to skin and eyes. --Fire may produce irritating or poisonous gases. -- Vapors may be fatal if inhaled, --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatua and full protective clothing. --Eliminate ail open flames. No smoking. No flares. Keep internal combustion engines af least 20 yards away from spill. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Tabta. Immediate Follow-up Action Fire:--Small Fire: Dry chemical or CO*. --Large Fire: Water spray or fog. --Move containers from fire area If without risk. --Cool containers with water from maximum distance until well after fire is out -- For massive fires in cargo area, use unmanned hose holder 's"*' or monitor nozzles. If this is impossible, withdraw from area and let fire burn. --Stay away from ends of tanks --Withdraw Immediately in case of rising sound from venting safety device. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. --Large Spills: Dike for later disposal. --Small Spills: Take up with sand, earth or other noncombustible, absorbent material. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of contact or inhalation may be delayed. --If victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. -- if victim contacted material, immediately flush skin or eyes with running water for af least 15 minutes. --Remove contaminated clothes. -- Keep victim warm and quiet. 30 --------------------------------------------------------------- . | AP000I02I0 For Assistance Cal! Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action -- For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (600) 424-9300. You will be asked for the following information: ' Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. e Type of environment (populated, rural, business, etc.) e Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control -- Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or environmental Protection Agency of the situation through Chemtrec oryour local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet BOO square feet 180 yards (216 paces) 1 mile long, 1/2 mile wide 260 yards (312 paces) 11/2 miles long, 1 mile wide 328 yards (390 paces) 2 miles long, 1 mUe wide 360 yards (456 paces) 2 miles long, 11/2 mile wide in the event of an explosion, themlnlmum safe distance from flying fragments is 2.000 feet In all directions. 91 f < Ethylene Oxide (Flammable, Thermally Unstable, Corrosive) Potential Hazards Fire:--Highly flammable. --Flammable vapors may spread from spill: Explosion:*--Container may explode due to heat of fire. --Runoff may create fire or explosion hazard in sewer system. Health:---Contact may cause burns to skin and eyes. If inhaled, may be harmful. --Fire may produce irritating or poisonous gases. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. --if possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at least 25 yards away from spill. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Let burn unless leak can be stopped immediately. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until welt after fire is out. --For massive fire in cargo area, use unmanned hose holder or monitor nozzles. If this is impossible withdraw from area and let fire burn. --Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. --Large Spills: Dike for later disposal. --Small Spills: Take up with sand, earth or other noncombustible, absorbent material. First Aid:--Remove victim to fresh air. Cali for emergency medical care. Effects of contact or inhalation may be delayed. --If victim Is not breathing, give artificial respiration. If breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. -- Keep victim warm and quiet.- L "i AP00010212 t For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance In controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-0300. You will be asked for the following Information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Ethylene Oxide is water soluble and can kill fish. Prevent runoff from fire control or dilution water from entering streams ordrinking water supply. Dike for later disposal. Notify Coast Guard or Environmental ProtectlonAgencyof the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 8-12 mpn. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feat 400 squara feat 000 square feet 800 square feet 25 yards (30 paces) 30 yards (36 paces) 40 yards (48 paces) 45 yards (54 pacts) 528 feet long, 528 feet wide 528 feet long, 528 feet wide 1,056 feet long, 528 feet wide 1,056 feet long, 528 feet wide In the eventof an explosion, theminimum safe distance from flyfng fragments fs 2,000 feet in all directions. W i i AP00010213 f t *'! A Ruorine (Oxidizer. Corrosive. Poisonous) Potential Hazards_________________________________ Fire:--May ignite combustibles. Explosion:--Container may explode due to beat of fire. --Reaction with fuels may be violent. --Gas explosion hazard indoors, outdoors or in sewers. Health:--Vapors extremely irritating. Contact may cause burns to skin and eyes. -- Vapors may be fatal If inhaled. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. --if possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Small Fire: Dry chemical or C02. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. --Stay away from ends of tanks. --Do not put solid stream of water on fluorine pool. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. --Keep combustibles away from spilled material. --Large Spills: Dilute with large amounts of water and dike for later disposal. --Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. Call for emergency medical care. --If victim is not breathing, give artificial respiration. if breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. --Keep victim warm and quiet. v i i ! 34 1 I apooo10214 For Assistance Call Chemtrec toll free (800) 424-9300 in the District of Columbia, the virgin islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 463-7616. Additional Fotlow-op Action__________ --For more detailed assistance in controlling the hazard, call Chemtrec {Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: - Your location and phone number. Location of the accident. Name of product and shipper, If known. The color and number on any labels on the carder or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control -- Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Tabla -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 105 yards (126 paces) 150 yards (180 paces) 185 yards (222 pacas) 220 yards (264 paces) 1/2 mile long, 1/2 mile wide 1 mile long, 1/2 mile wide 1 mile long, 1/2 mite wide 1 mile long, 1 mile wide In theeventofan explosion, the minimum safe distance from flying fragments is 2,000 feet In all directions. 39 r Hydrocarbon Fuels (Flammable Liquid) Potential Hazards Fire:--H^hlyfiammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Runoff may create fire or explosion hazard in sewer system. Health:--Vapors indoors may cause dizziness or suffocation. immediate Action --Get helper and notify local authorities. --If possible, wear full protective clothing. --Eliminate all open flames. No smoking. No flares. --Keep upwind. Isolate hazard area. --Evacuate by at laast 2,000 feet. immediate Follow-up Action Fire:--Small Fire: Dry chemical or COa. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire Is out. --Stay away from ends of tanks. Spill or Leak:--Stop leak If without risk. --Use water spray to reduce vapors. --Large Spills: Dike for later disposal. --Small Spills: Take up with sand, earth or other noncombustible, absorbent material. First Aid:--Remove victim to fresh air. --Use standard first aid procedures. l: AP00010216 For Assistance Call Chemtrec toll free (800) 424-9300 in the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 463-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toil free (800) 424-9300. You will be asked for the following information: Your location and phone number. v Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. In cut of Expiotlon, the Minimum Safe Distance from Flying Fragments la 2,000 Feat In All Directions. 37 * ----------------------------- -----------------------------------------------------------------------AP000102I7 Hydrogen,uquid (Flammable Gas) Potential Hazards____________________________ _______ Fire:--Highly flammable -- flame may be invisible. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion hazard indoors, outdoors or in sewers. Health:--Contact with liquid may cause burns to skin and eyes. --Vapors indoors may cause dizziness or suffocation. Immediate Action --Get helper and notify local authorities. -- If possible, wear futi protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at feast 250 yards away from vapor cloud area. --Keep upwind. Isolate hazard area. --Evacuate by at feast 2,000 feet. immediate Follow-up Action Fire:--Let burn unless leak can be stopped immediately. --Move containers frpm fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. Apply water from sides of tank. --Stay away from ends of tanka. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Isolate area until gas has dispersed. First Aid:-$temove victim to fresh air. --Use standard first aid procedures. ] AP00010218 For Assistance Call Chemtrec toll free (800) 424-9300 !n the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7618. Additional Follow-up Action _________________________________ --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. In Cm* of Explosion, tho Minimum Safe Dlstsneo from Flying Fragments Is 2,000 Foot In All Directions. ! j AP000I0219 ( 1 f Hydrogen Chloride (Nonflammable Gas, Corrosive) Potential Hazards Fire:--Cannot catch fire. Explosion:--Container may explode due to heat of fire. Health:--Vapors extremely irritating. Contact may cause burns to skin and eyes, If inhaled, may be harmful, --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area. -- Evacuate according to Evacuation Table. Immediate Follow-up Action_______________ ___________ Fire:--Small Fire: Dry chemical or CO*. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. --Stay away from ends of tanks. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. --Large Spills: Dike for later disposal. --Small Spills: Flush area with water. --Isolate area until gas has dispersed. First Aid;--Remove victim to fresh air. Call for emergency medical care. --If victim is not breathing, give artificial respiration. if breathing is difficult, give oxygen. --If victim contacted material, immediately flush skin or eyes with running water for at least IS minutes. --Remove contaminated clothes. --Keep victim warm and quiet. 40 u AP000f0220 For Assistance Call Chemtrec toll free (800) 424-9300 in the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616 Additional Follow-up Action__________________________________________ --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: e Your location and phone number. Location of the accident v Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control_________________ --Hydrogen Chloride is water soluble and can kill fish. Prevent runoff from fire control or dilution water from entering streams ordrinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Immediate Dingar Atm Evacuation Table -- Baaed on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evaeuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feat 600 square feet 800 square feet 125 yards (150 pacta) 1/2 mile long, 1/2 mile wide 180 yards (216 paces) 1 mile long, 1/2 mile wide 225 yards (270 paces) 1 mile long, 1 mUa wide 260 yards (312 paces) 11/2 miles long, 1 mile wide In theevent of an explosion, the minimum safe distance from flying fragments is 2,000 feet in all directions. r .. i I np--------------------------- ---- - -- --- -------------- \ Hydrogen Cyanide (Flammable Gas, Extremely Hazardous, Poisonous) Potential Hazards Fire:--Highly flammable, --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion and poison hazard indoors, outdoors or in sewers. Health:--Vapors nonirritating, deaden sense of smell. Skin contact poisonous. -- Vapors may ba fatal If inhaled. --Runoff may pollute water supply. Immediate Action --Get helper and contact local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at least 20 yards away from vapor cloud area. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action ________________ Fire:--Let burn unless leak can be stopped immediately. --Small Fire: Ory chemical or CO*. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water for maximum distance until well after fire is out. --Stay away from ends of tanks. --Fight fire from maximum distance. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. --isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of contact or inhalation may be delayed. -- If victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. --If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. --Keep victim warm and quiet. AP00010222 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616, Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toil free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. * Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. *T, Evacuation Tablo -- Based on Prevailing Wind ot 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 60 yards (72 paces) 1,584 feet long, 1,056 feet wide 90 yards (108 paces) 2,112 feet long, 1,584 feet wide 110 yards (132 paces) 3,168 feet long, 1,584 feet wide 130 yards (156 paces) 3,696 feet long, 2,112 feet wide In theeventofanexplosion, the minimum safedistancefrom flyingfragments is 2,000 feet in all directions. I AP00010223 Hydrogen Fluoride (Corros)ve, Poisonous) Potential Hazards Fire:*--Cannot catch fire. ' Health:--Vapors extremely irritating. Contact may cause bums 1 to skin and eyes. If inhaled, may be harmful. --Runoff may pollute water supply. Immediate Action____________________________________ --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind. Estimate Immediate Danger Ana. --Evacuate according to Evacuation Table. Immediate Follow-up Action _______________ Fire:--Small Fire: Dry chemical or CO*. --Large Fire: Water spray or fog. --Move containers from fire area If without risk. --Cool containers with water from maximum distance until well after fire is out. --Do not get water Inside container. Spill or Leak:--Do not touch spilldd material. --Stop leak if without risk. -- Use water spray to reduce vapors. --Small Spills: Flush area with water. --Large Spills: Dilute with large amounts of water and dike for later disposal. -- Isolate area until gas has dispersed. i 1 First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of contact or inhalation may be delayed. --If victim is not breathing, give artitical respiration. If breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or [ eyes with running water for af least 15 minutes. --Remove contaminated clothes. --Keep victim warm and quiet. i AP000I0224 t For Assistance Call Chemtrec toll free (800) 424-9300 in the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec ' (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control -- Hydrogen Fluoride is water soluble and can kill fish. Prevent runoff from fire control or dilution water from entering streams or drinking water. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 160 yards (192 paces) 1 mile long, 1/2 mile wide 400 square feet 225 yards (270 paces) 1 1/2 miles long, 1 mile wide 600 square feet 280 yards (336 paces) 1 1/2 miles long, 1 mile wide 800 square feet 326 yards (390 paces) 2 miles long, 1 mile wide Caution: Although Hydrogen Fluoride does not form an explosive mixture, the container In which it is shipped may explode under pressure from a fire. For maximum safety, evacuate 2,000 feet In alt directions. wmr 4 APOOOl0225 Hydrogen Sulfide (Flammable Gas, Extremely Hazardous, Poisonous) Potential Hazards ______________________ _________ Fire:--Highly flammable. -- Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion and poison hazard indoors or in sewers. Health:--Vapors nonirritating, deaden sense of smell. -- Vapors may be fatal if inhaled. --Runoff may pollute water supply. Immediate Action. --Get helper and notify local authorities. --if possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep Internal combustion engines at least 30 yards away from spill. --Keep upwind. Estimate Immediate Danger Area. -- Evacuate according to Evacuation Table. Immediate Follow-up Action_______________________ ______ Fire:-- Let burn unless leak can be stopped immediately. --Small Fire: Dry chemical or C02. -- Large Fire: Water spray or fog. -- Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. --Stay away from ends of tanks. -- Fight fire from maximum distance. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. -- Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of contact or inhalation may be delayed. -- If victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for af least IS minutes. --Remove contaminated clothes. -- Keep victim warm and quiet. 46 Apoobiom For Assistance Call Chemtrec toll free (800) 424-9300 in the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toil free (600) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. , Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet yards ( 96 paces) 2,112 feel long, 1,056 feet wide 110 yards (132 paces) 4,224 feet long, 1,584 feet wide 140 yards (168 paces) 3,698 feet long, 2,112 feet wide 160 yards (192 paces) 1 mile long, 1/2 mile wide In theevent of an explosion, the minimum safe distance from flying fragments is 2,000 feet in all directions. AP00010227 r t m M I"1 --I' l ............... ..... ..................... ............................................................. . ...... n......... -- I II ' I--IWll il* Uquid Petroleum Gas ilpo (Flammable Ga6) Potential Hazard* Fire:--May be Ignited by heat, sparks, flames. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion hazard indoors, outdoors or in sewers. Health:--Contact with liquid may cause burns to skin and eyes. --Vapors indoors may cause dizziness or suffocation. Immediate Action --Get helper and notify local authorities. --If possible, wear full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at least 35 yards away from vapor cloud. -- Keep upwind, isolate hazard area. -- Evacuate by at least 2,000 feet. Immediate Follow-up Action Fire:--Let burn unless leak can be stopped immediately. --Small Fire: Dry chemical or COa. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum cf/s fanes untit well after fire is out. Apply water from sides of tank. --For massive fire in cargo area, use unmanned hose holder or monitor nozzles. If this is impossible, withdraw from area and let fire burn. --Stay away from ends of tanks. _ _ --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. -- Use standard first aid procedures. 48 APO0OIO228 For Assistance Call Chemtrec toll free (800) 424-9300 In me District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Foltow-up Action --Formore detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. In Casa of Explosion, the Minimum Safe Dlitanea from Flying Fragments It 2,000 Feat in All Diraetiona. 49 AP000I0229 Methane, Liquid (Flammable Gas) sm Potential Hazards Fire:--Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion hazard indoors, outdoors or in sewers. Health:--Contact with liquid may cause bums to skin or eyes. --Vapors indoors may cause dizziness or suffocation. Immediate Action_________________________ --Get helper and notify local authorities. --If possible, wear full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at least 60 yards from vapor cloud. --Keep upwind. Isolate hazard area. --Evacuate by at least 2,000 feet Immediate Followup Action Fire:--Let burn unless leak can be stopped Immediately. --Small Fire: Dry chemical or CO* --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. Apply water from sides of tank. --For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if this is impossible withdraw from area. --Stay away from ends of tanks. --Withdraw Immediately In case of rising sound from venting' safety device. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. -- Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. --Use standard first aid procedures. so 11. 1 AP00010230 For Assistance Cali Chemtrec toll free (800) 424-9300 in the District of Columbia, the Virgin islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 493-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. In Cm of Explosion, th* Minimum Sete Oletanc* from Flying Fragment* In 2,000 Feet In All Direction*. AP00010231 Methylamines, Anhydrous (Flammable Gas, Corrosive) Potential Hazards_____________________________ ________ Fire:--Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion hazard indoors, outdoors or in sewers. Health:--Vapors extremely irritating. Contact may cause burns to skin and eyes. Immediate Action --Get helper and notify local authorities. -- If possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at Ieast 20 yards away from vapor cloud. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Let burn unless leak can be stopped immediately. --Small Fire: Dry chemical or CO* --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. Apply water from sides of tanks. --For massive fire in cargo area, use unmanned hose holder or monitor nozzles. If this is impossible, withdraw from area and let fire burn. --Stay away from ends of tanks. Spill orLeak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. --Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. Call for emergency medical care. --If victim is not breathing give artificial respiration. If breathing Is difficult, give oxygen. --If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. --Keep victim warm and quiet. 52 ku APOOO10232 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, theVirgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 463-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (600) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control___________________________________ --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of SplU Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square lee! 400 square feet 600 square feet 600 square feet 70 yards ( 84 paces) 1,584 feet long, 1,056 test wide 100 yards (120 paces) 4,224 feet long, 1,584 feet wide 125 yards (150 paces) 3,168 feet long, 2,112 feet wide 150 yards (180 paces) 3,696 feet long, 4,224 feet wide in theeventof an explosion, theminimum safe distance from flying fragments is 2.000 feet in all directions. t. Methyl Bromide (Poisonous) Potential Hazards Fire:--Cannot catch fire. Health:--Liquid causes burns to skin and eyes. Absorption by clothes or shoes may cause delayed burns. --Vapors extremely irritating. -- Vapors may be fatal if inhaled. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. -- If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area, --Evacuate according to evacuation Table. Immediate Follow-up Action Fire:--Move containers from fire area If without risk. --Cool containers with water if exposed to fire. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --isolate area until gas has dispersed. --Do not use rubber boots or rubber protective clothing. First Aid: --Remove victim to fresh air. Call for emergency medical care. Effects of contact or inhalation may be delayed. --if victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for at least IS minutes. --Remove contaminated clothes. --Keep victim warm and quiet. AP00010234 r For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7610. Additional Follow-up Action -- For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. e The color and number on any labels on the carrier or cargo. Weather conditions. e Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Ba 200 square feet 400 square feet 600 square feet 800 square feet 25 yards (30 pacas) 35 yards (42 paces) 45 yards (54 paces) 50 yards (60 paces) 528 feet long, 528 feel wide 1,056 feet long, 528 feet wide 1,056 feet long, 528 feet wide 1,056 feel long, 52B feet wide Caution: Although Methyl Bromide does not form an explosive mixture, the container in which it Is shipped may explode under pressure from a fire. For maximum safety, evacuate 2.000 feet in all directions. AP000i0235 ; i mill-- fed JMttfelfa Methyl Chloride (Flammable Gas) Potential Hazards Fire:--Highly flammable. --Flammable vapors may spread from spill. v Explosion:--Container may explode due to heat of fire. f --Gas explosion hazard indoors, outdoors or in sewers. Health:--Contact with liquid may cause burns to skin and eyes. --Vapors indoors may cause dizziness or suffocation. --Fire may produce irritating or poisonous gases. Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at /east 20 yards away from spill. -- Keep upwind. Isolate hazard area. --Evacuate by at least 2,000 feet. I Immediate Follow-up Action Fire:--Let burn unless leak can be stopped immediately. --Small Fire: Dry chemical or CO2. --Large Fire: Water spray or fog. -- Move containers from fire area ff without risk. --Cool containers with water from maximum distance until well after fire is out. Apply water from sides of tank. --For massive fire in cargo area, use unmanned hoseholderor monitor nozzles. If this is impossible withdraw from area and let fire burn. --Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Do not touch spilled liquid. --Stop leak il without risk. --Use water spray to reduce vapors. -- Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. --Use standard first aid procedures. se 1 AP00010236 I For Assistance Cali Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action___________ _______________________________ --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. In C*m of Explosion, the Minimum Sofo Distance from Flying Fragments Is 2,000 Fool In Alt Directions. r APOOOf0237 t 'f Methyl Ethyl Ether (Flammable Gas) ! Potential Heard* Fire:--Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion hazard indoors, outdoors or in sewers. Health:--Vapors indoors may cause dizziness or suffocation. --Contact with liquid may cause bums to skin and eyes. Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. -- Eliminate all open flames. No smoking, No flares. Keep internal combustion engines at least 25 yards away from spill. --Evacuate by at least 2,000 feet. Immediate Follow-up Action Fire:--Let burn unless leak can be stopped immediately. --Small Fire: Dry chemical or C02. --Large Fire: Water spray or fog. --Move containers from fire area If without risk. --Cool containers with water from maximum distance until well after fire is out. Apply water from sides of tank. --For massive fire in cargo area, use unmanned hose holder or monitor nozzles. If this Is impossible, withdraw from area and let fire burn. --Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. -- Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. --Use standard first aid procedures. ... "1 AP00010238 For Assistance Cali Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controiling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424*9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. In Cm# of Explosion, ths Minimum Ssfo Dbtance from Flying Fragment* Is 2,000 Foot In All Directions. r AP00010239 t t; r >----fr----***fc*gr thiMUMMjdteiBliiliififcttimiiiirtwlM-rrn utlMMi Methyl Mercaptan (Flammable Gas) Potential Hazards Fire:--Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion hazard indoors, outdoors or in sewers. Health:--Vapors indoors may cause dizziness or suffocation. --Contact with liquid may cause bums to skin and eyes. Immediate Action__________ --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. -- Eliminate all open flames. Ho smoking. No flares. Keep internal combustion engines at least 20 yards away from vapor cloud. -- Keep upwind and estimate Immediate Danger Area. -- Evacuate according to Vacuaf/on Table. Immediate Follow-up Action Fire:--Let burn unless leak can be stopped Immediately. --Small Fire: Dry chemical or C02. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. -- Cool containers with water from max/mi/m O/stence until well after fire is out. Apply water from sides of tank. --For massive fire in cargo area, use unmanned hose holder or monitor nozzles. If this is impossible, withdraw from area and let fire burn. --Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. -- Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. --Use standard first aid procedures. i j 60 AP00010240 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control__________________________________ ___________ ,, --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Baaed on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 50 yards (60 paces) 1,056 feet long, 528 feet wide 70 yards (84 paces) 1,584 feet long, 1,056 feet wide 90 yards (108 paces) 2,112 feet long, 1,584 feet wide 100 yards (120 paces) 4,224 feet long, 1,584 feet wide In the event of an explosion, the minimum safe distance from flying fragments is 2.000 feet in all directions. 81 Monomethylamine {Flammable Gas, Corrosive) Potential Hazards_____________________________________ F re:--Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion hazard indoors, outdoors or in sewers. Health:--Vapors extremely irritating. Contact may cause burns to skin and eyes. Immediate Action --Get helper and notify local authorities. -- If possible, wear self-contained breathing apparatus and full protective clothing. -- Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at least 20 yards away from vapor cloud. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Let bum unless leak can be stopped immediately. --Small Fire: Dry chemical or CO* --Large Fire: Water spray or fog. -- Move containers from fire area if without risk. -- Cool containers with water from maximum distance until well after fire Is out. Apply water from sides of tanks. -- For massive fire in cargo area, use unmanned hose holder or monitor nozzles. If this is impossible, withdraw from area and let fire burn. --Stay away from ends of tanks. Spill orLeak: --Do not touch spilled liquid. -- Stop leak if without risk. --Use water spray to reduce vapors. -- isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. Call for emergency medical care. -- If victim is not breathing give artificial respiration. If breathing is difficult, give oxygen. --if victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. --Keep victim warm and quiet. AP00010242 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evaeualion Table -- Baaed on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 70 yards ( 84 paces) 1,584 feet long, 1,056 feet wide 100 yards (120 paces) 4,224 leet long, 1.584 feet wide 125 yards (ISO paces) 3,168 feet long, 2,112 feet wide 150 yards (180 pecee) 3,696 feet long, 4,224 feet wide In the event of an explosion, the minimum safe distance from flying fragments is 2,000 feet in all directions. S3 Nitric Acid, Fuming (Oxidizer Corrosive, Poisonous) Potential Hazards Fire:--May ignite combustibles. Explosion:--Mixtures with fuels may explode. --Runoff may create fire or explosion hazard in sewer system. Health:--Contact may cause burns to skin and eyes. -- Vapors may ba fataf if inhaled. --Runoff may pollute water supply. ' Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action____________________ Fire:--Small Fire: Dry chemical or CO,. --Large Fire: Water spray or fog. --Move containers from area if without risk. --Cool containers with water from maximum distance until well after fire is out. -- For massive fire In cargo area, use unmanned hose holder or monitor nozzles. Spill or Leak:--Do not touch spilled material. --Stop leak If without risk. --Keep combustibles away from spilled material. --Use water spray to reduce vapors. --Small Spills: Take up with sand, earth or other noncombustible, absorbent material. --Large Spills: Dilute with large amounts of water and dike for later disposal. --Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. Cali for emergency medical care. Effects of contact or inhalation may be delayed. --ft victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for at leest 15 minutes. --Remove contaminated clothes. -- Keep victim warm and quiet. t APOOO10244 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action_______________________________ --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Nitric Acid is water soluble and can kil I fish. Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Runoff to storm sewers or sanitary system is acceptable if a water deluge and/or flooding is possible. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Immediate Danger Arw Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 65 yards (76 paces) 1,528 feet long, 1,056 feet wide 100 yards (120 paces) 4,224 feet long, 1,584 feet wide 120 yards (144 paces) 3,168 feet long, 2,112 feet wide 140 yards (168 paces) 3,696 feet long, 2,112 feet wide In the event of an explosion, the minimum safe distance from flying fragments is 2,000 feet in all directions. l AP000I0245 Nitrogen Tetroxide (Oxidizer, Corrosive, Poisonous) Potential Hazards Fire:--May ignite combustibles. Explosion:--Mixtures with fuels may explode. -- Runoff may create fire or explosion hazard in sewer system. Health:--Contact may cause burns to skin and eyes. -- Sapors may be fatal if inhaled. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. -- If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action. Fire:--Small Fire: Dry chemical or C02. --Large Fire: Water spray or fog. --Cool containers with water from maximum distance until well after fire is out. -- For massive fire in cargo area, use unmanned hose holder or monitor nozzles. Spill or Leak:--Do not touch spilled material. --Stop teak if without risk. --Keep combustibles away from spilled material. -- Use water spray to reduce vapors. --Small Spills: Take up with sand, earth or other noncombustible, absorbent material. --Large Spills: Dilute with large amounts of water and dike for later disposal. --isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of contact or inhalation may be delayed. --If victim is not breathing, give artificial respiration. If breathing Is difficult, give oxygen. --If victim contacted material, Immediately flush skin or eyes with running water lor at least 15 minutes. --Remove contaminated clothes. --Keep patient warm and quiet. ee AP000I0246 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toil free (900) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any iabels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Evaporation of the material to the air at its slow, natural rate is preferable to flooding, which will produce large clouds of fumes. Residue may be flushed to storm drain or sanitary system. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mph> Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 70 yards (84 paces) 1,584 feet long, 1,056 feet wide 100 yards (120 paces) 4,224 feet long, 1,584 feet wide 12S yards (150 paces) 3,168 feet long, 2,112 feet wide 150 yards (180 paces) 3,696 feet long, 4,224 feet wide In theevent of an explosion, the minimum safe distance from flying fragments is 2,000 feet in all directions. Oleum/Sulfur Trioxide (Corrosive. Poisonous) Potential Hazards Fire:--May ignite combustibles. Explosion:--Explosive concentrations of gas may accumulate in tanks containing acid. Health:--Contact with material will cause severe bums to skin and eyes, If inhaled, may be harmful. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. -- If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. immediale Follow-up Action Fire:--Small Fire: Dry chemical or CO. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. --Do not get water inside container. Spill or Leak:--Do not touch spilled material. --Stop leak if without risk. -- Use water spray to reduce vapors. --Small Spills: Flush area with water spray or fog. --Large Spills: Dilute with large amounts of water spray or fog and dike for later disposal. --Isolate area until gas has dispersed. --Do not get water inside container. First Aid --Remove victim to fresh air. Call for emergency medical care. -- If victim is not breathing give artificial respiration. If breathing is difficult, give oxygen. --If victim contacted material, <mmad/afe/y wipe off excess quantities with cloth, then flush skin or eyes with running water for at least 15 minutes. --Keep victim warm and quiet. -s"1 AP00010248 \ i For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. ^Adjust evacuation area according to wind changes and observed effect on population. _ Water Pollution Control --Oleum/Sulfur Trioxlde is water soluble and can kill fish. Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. t Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Ba 200 square feet 400 square feet 600 square feet 800 square feet 185 yards (222 paces) 268 yards (322 paces) 332 yards (268 paces) 387 yards (465 pacts) 1 mile long, 1/2 mtla wide 1 1/2 miles long, 1 mile wide 2 miles long, 1 mile wide 2 miles long, 1 mile wide In the vent of an explosion, theminimum safe distance from flying fragments is 2,000 feet in all directions. r AP60616249 Oxygen, Liquid (Oxidizer) Potential Hazards Fire:--Materials may ignite in oxygen vapor. " --Automobile engine may catch fire in oxygen atmosphere. Explosion:--Container may explode due to heat of fire. --Mixtures with fuels may explode. --Gas explosion hazard Indoors, outdoors or In sewers. Health:--Contact with liquid may cause burns to skin and eyes. Immediate Action --Get helper and notify local authorities. -- If possible, wear full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines away from vapor cloud area. --Keep upwind. Isolate hazard area. --Evacuate by at least 2.000 feet. Immediate Follow-up Action Fire:--Small Eire; Dry chemical or COa. --Large Fire: Foam or water. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. --For massive fire in cargo area, use unmanned hose holder or monitor nozzles, tf this Is Impossible, withdraw from area and let fire burn. Spill or Leak: --Do not touch spilled liquid. --Stop leak if without risk. --Keep combustibles away from spilled material. --Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. --Remove contaminated clothes. --Use standard first aid procedures. 70 AP00010250 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action_________________________ ________ ______ --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. r In Cm* of Explotion, th* Minimum Saf* Olitanct from Flying Fragment* I* 2,000 F**t In All Directions. AP00010251 Phosgene (Nonflammable Gas, Poisonous) Potential Hazards Fire:--Cannot catch fire. Explosion:--Container may explode due to heat of fire. Health:--Contact causes burns to skin and eyes. -- Vapors may be fatal If inhaled. --Runoff may pollute water supply. Immediate Action__________________________________ -- Get helper and notify local authorities. -- If possible wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate immediate Danger Area. --Evacuate according to Evacuation Table. Immediate FoBow-up Action________________ __________ Fire:--Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. --Do not get water inside container. Spill or Leak:--Do not touch spilled material. --Stop leak if without risk. --Use water spray to reduce vapors. -- Isolate area until gas has dispersed. --Do not get water Inside container. First Aid:--Remove victim to fresh air. Call for emergency medical care. -- If victim is not breathing, give artificial respiration. if breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. --Keep victim warm and quiet. _______i AP000I0252 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa. Puerto Rico and Alaska, call (202) 483-7616, Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toil free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control________________ _______________________________ --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Evaporation of the material at its slow, natural rate is preferable to flooding with waterany warmer than 45*. which will increase the quantity of fumes. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. ImmwUato Danger Aral Evacuation Table -- Based on Prevailing Wind of 8-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 390 yards (468 paces) 2 miles long, 11/10 miles wide 570 yards (684 pacas) 31/2 miles long, 2 miles wide 700 yards (840 paces) 41/2 miles long, 21/2 miles wide 820 yards (984 pacts) 5 milts long, 3 miles wide In the event of an explosion, the minimum safe distance from flying fragments la 2,000 feet in all directions. 73 s\ AP000I0253 Phosphorus Trichloride (Corrosive, Poisonous) Potential Hazards Fire: --Cannot catch fire. Explosion*.--Contact with water may form flammable and poisonous gas and cause explosions. Health:--Liquid causes burns to skin and eyes. --Vapors extremely irritating. -- Vapors may be fatal if inhaled. --Runoff may pollute water supply. Immediate Action ___________________ --Get helper and notify local authorities. -- If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action ___________ ' Fire:--Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. --Do not get water inside containers. Spill or Leak: --Large Spilt: Use flooding amounts of water on the entire spill. --Small Spill: Absorb with dry sand or soda ash. --Do not touch spilled liquid. --Stop leak if without risk. --Do not get water inside containers. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of contact or inhalation may be delayed. --if victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. --If victim contacted material, Immediately flush skin or eyes with water for at least IS minutes. --Remove contaminated clothes. -- Keep victim warm and quiet. AP00010254 I l For Assistance Call Chemtrec toll free (800) 424-9300 in the District of Columbia, the Virgin islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, cal) Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Prevent runoff from fire controTor dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. i Evacuation Table -- Based on Prevailing Wind of 8-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feel 70 yards ( 84 paces) 100 yards (120 paces) 12S yards (ISO paces) 150 yards (180 paces) 1,584 feet long, 1,056 feet wide 1/2 mile long, 1/3 mile wide 2/3 mile long, 1/2 mile wide 3/4 mile long, 1/2 mile wide In the event of an explosion, the minim um safe distance from flying fragments Is 2,000 feet In all directions. AP0b6t6255 r T-|ffl|-;-T--- Propane/LPG (Flammable Gas) .... Potential Hazards Fire:--May be Ignited by heat, sparks, flames. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion hazard indoors, outdoors or in sewers. Health:--Contact with liquid may cause burns to skin and eyes. --Vapors indoors may cause dizziness or suffocation. Immediate Action --Get helper and notify local authorities. -- II possible, wear full protective clothing. -- Eliminate ail open flames. No smoking. No flares. Keep internal combustion engines at feast 35 yards away from vapor cloud. --Keep upwind. Isolate hazard area. --Evacuate by af least 2,000 feet. Immediate Follow-up Action_____________________ _______ Fire:--Let burn unless leak can be stopped immediately. --Small Fire: Dry chemical or COs. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. Apply water from sides of tank. --For massive fire in cargo area, use unmanned hose holder or monitor nozzies. If this is impossible, withdraw from area and let fire burn. -- Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. --Use standard first aid procedures. AP00010256 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 463-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (300) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. In Casa of Explosion, tho Minimum Solo Distinct from Flying Fragments la 2,000 Feat In All Dlrtctions. 77 AP00010257 Sulfur Dioxide (Nonflammable Gas, Corrosive) I Potential Hazards I F Ire:--Cannot catch fire. ' Y Explosion:--Container may explode due to heat of fire. , Health:--Vapors extremely irritating. Contact may cause burns 1 to skin and eyes. If inhaled, may be harmful, a --Runoff may pollute water supply. ? Immediate Action --Get helper and notify local authorities. --if possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area. -- Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Move containers from fire area if without risk. --Cool tank with water if exposed to fire. Spill or Leak:--Large Spill: Dilute with large amounts of water and I dike for later disposal. : --Small Spill: Flush area with water spray or fog. --Stop leak if without risk. --Use water spray to reduce vapors. --Isolate area until gas has dispersed. I First Aid:--Remove victim to fresh air. Call for emergency medical care. --If victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for at least IS minutes. --Remove contaminated clothes. -- Keep victim warm and quiet. 78 it. APOOO10258 For Assistance Call Chemtrec toll free (800) 424-9300 in the District of Columbia, the Virgin Islands, Guam, Samoa. Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following Information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control -Sulfur Dioxide is water soluble and can kill fish. Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. knmwflat* Danger Atm Evacuation Table -- Baaed on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate Prom Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Bt 200 square feet 400 square feet 600 square teat 600 square feet 70 yerda ( 84 paces) 100 yards (120 paces) 125 yards (150 paces) 145 yards (174 pacas) 1,584 feet long, 1,056 feet wide 1/2 mile long, 1,564 feet wide 3/4 mile long, 1/2 mile wide 3/4 mile long, 1/2 mile wide in the event of an explosion, the minimum safe distance from flying fragments is 2.000 feet in all directions. Sulfur Trioxide (Corrosive, Poisonous) i Potential Hazards | Fire:--May ignite combustibles. Explosion;--Explosive concentrations of gas may accumulate in tanks containing acid. Health:--Contact with materia! will cause severe burns to skin and eyes, if inhaled, may be harmful. --Runoff may pollute water supply. ' Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Small Fire; Dry chemical or COa. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. -- Do not get water inside container. Spill or Leak: -- Do not touch spilled materia). --Stop leak if without risk. --Use water spray to reduce vapors. --Small SpHIa: Flush area with water spray or fog. --Large Spills: Dilute with large amounts of water spray or fog and dike for later disposal. -- Isolate area until gas has dispersed. --Do not get water inside container. First Aid: --Remove victim to fresh air. Call for emergency medical care. -- If victim is not breathing give artificial respiration. If breathing Is difficult, give oxygen. --if victim contacted material, immediately wipe oft excess quantities with cloth, then flush skin or eyes with running water for et least 15 minutes. -- Keep victim warm and quiet. \ { , j 1 AP00010260 For Assistance Cali Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action___________________________________________ -For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information; Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control -Sulfur Trioxide is water soluble and can kill fish. Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Dletance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 185 yards (222 paces) 268 yards (322 paces) 332 yards (268 paces) 387 yards (465 paces) 1 mile long, 1/2 mile wide 1 1/2 miles long, 1 mile wide 2 miles long, 1 mile wide 2 miles long, 1 mile wide In the eventof an explosion, the minimum safe distance from flying fragments is 2,000 feet in all directions. A APOOO10261 Titanium Tetrachloride (Corrosive) Potential Hazard Fire:--Cannot catch fire. Health:--Fumes in air react violently with water to form Hydrogen Chloride gas. --Vapors extremely irritating. Contact may cause burns to skin and eyes. If inhaled, may be harmful. --Runoff may pollute water supply. Immediate Action___________________________________ --Get helper and notify authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area. -- Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Move containers from fire area if without risk. --Cool containers with water from maximum distance until welt after fire is out. --Do not use water to fight fire Involving this material. --Do not get water inside containers. Spill or Leak:--Large Spills: Dike for later disposal. --Do not touch spilled material. --Stop leak if without risk. --Cover spills with dry sand or soda ash. After removal, flush area with water. -- Isolate area until gas has dispersed. --Do not get water inside containers. First Aid:--Remove victim to fresh air. Cali for emergency medical care. Effects of contact or Inhalation may be delayed. -- If victim is not breathing, give artificial respiration. y If breathing Is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. -- Keep victim warm and quiet. t AP006l6262 For Assistance Call Chemtrec toil free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Foffow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control----------------------------------------------------------------------- --Titanium Tetrachloride is water soluble and can kill fish. Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Ba 200 souare feet 400 square feet 600 sauare feet 800 square feet 20 yards (24 paces) 528 feet Iona. 528 feet wide 25 yards (30 paces) 528 feet Iona. 528 feet wide 30 yards (36 paces) 528 feet long, 528 feet wide 40 yards (40 paces) 1,056 feet long, 528 feet wide Caution: Although Titanium Tetrachloride does not form an explosive mixture, the container in which it is shipped may explode under pressure from a fire. For maximum safety, evacuate 2,000 feet in ail directions. 83 Trimethylamine (Flammable Gas, Corrosive) Potential Hazards Fire: --Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion hazard Indoors, outdoors or in sewers. Health:--Vapors extremely irritating. Contact may cause burns to skin and eyes. Immediate Action ___________________________________ --Get helper and notify local authorities. -- if possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at feast 20 yards away from vapor cloud. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action Fire: --Let burn unless leak can be stopped immediately. --Small Fire: Dry chemical or C02. --Large Fire: Water.spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. Apply water from sides of tanks. --For massive fire in cargo area, use unmanned hose holder or monitor nozzles. If this Is impossible, withdraw from area and let fire burn. --Stay away from ends of tanks. Spill orLeak: -- Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. --Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. Call for emergency medical care. -- If victim is not breathing give artificial respiration. If breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for af least 15 minutes. --Remove contaminated clothes. -- Keep victim warm and quiet. vi _i [ I. jj j \ | *4 ' i- 4 AP000I0264 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following Information: Your location and phone number Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control________________________________________ --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet BOO square feet 800 square feet 70 yards ( 84 paces) 1,584 feet long, 1,056 feet wide 100 yards (120 paces) 4,224 feet long, 1,584 feet wide 125 yards (150 paces) 3,168 leet long, 2,112 feet wide 150 yards (180 pacss) 3,696 feet long, 4,224 feel wide In the event of an explosion, the minimum safe distance from flying fragments is 2,000 feet in all directions. as r. f Potential Hiardi Fire:--Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion hazard indoors, outdoors or in sewers. Health:--Contact with liquid may cause bums to skin and eyes. --Vapors Indoors may cause dizziness or suffocation. --Fire may produce irritating or poisonous gases. Immediate Action --Get helper and notify local authorities. -- If possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at least 20 yards away from vapor cloud. --Keep upwind. Isolate hazard area. --Evacuate by af feast 2,000 feet Immediate Follow-up Action Fire:--Let bum unless leak, can be stopped immediately. --Small Fire: Dry chemical or COa. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. Apply water from sides of tank. --For massive fire In cargo area, use unmanned hose holder or monitor nozzles. If this is impossible, withdraw from area and let fire bum. --Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. I Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. --Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. -- Use standard first aid procedures. AP00010266 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action_______________ --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toil free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. in Cati of Explosion, tho Minimum Sate Oiitancs from Flying Fragments la 2,000 Feat In All Olfactions. -- AP000I0267 iSHBNMI For Assistance Cali Chemtrec toil free (800) 424-9300 In the District of Columbia, the Virgin (elands, Guam, Samoa, Puerto Pico, and Alaska, call (202) 483-761$. Additional Follow-up Action_________________________ ______________. -- For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (600) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on sny labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control_____________ ____________________________________ --Ammonia is water soluble and can kill fish. Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Runoff to storm sewers or sanitary system is acceptable if a water deluge and/or flooding is possible. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet 600 square feet 800 square feet 40 yards (46 paces) 60 yards (72 paces) 60 yards (96 paces) 90 yards (108 paces) 1,056 feet long, 528 feet wide 1,584 feet long, 1,056 feet wide 2,112 feet long, 1,056 feet wide 2,112 feet long, 1,584 feet wide in theevent of an explosion, theminirmimsafedistancefrom flying fragments is 2,000 feet in all directions. } I AP000I0I89 nhh4* i. Boron Trffluoride (Nonflammable Gas, Poisonous) Potential Hazards Fire:--Cannot catch fire. --Cannot support combustion. Health:--Vapors extremely irritating. Contact may cause burns to skin and eyes. -- Vapors may be fatal if inhaled. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate immediate Danger Area. --Evacuate according to Evaluation Table. Immediate Follow-up Action Fire:--Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. Spill or Leak:--Stop leak if without risk. --Use water spray to reduce vapors. --Isolate area until gas has dispersed. -- Do not apply water directly to leak. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of inhalation may be delayed. -- If victim is not breathing, give artificial respiration. Administer oxygen at once. In case of severe exposure, continue intermittent oxygen administration for at least 6 hours. --If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. --Keep victim warm and quiet. 10 AP00010I90 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands. Guam, Samoa, Puerto Pico and Alaska, call (202) 483-7616. Additional Follow-up Action --For detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. i 1 j E f 1 ' j ( Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square test 210 yarde (292 paces) 1 mile long, 3/4 mile wide 400 square feet 310 yarde (372 paces) 1 3/4 miles long, 1 mlie wide 600 square feet 380 yerds (456 paces) 2 miles long, 1 1/2 miles wide 600 square feet 445 yards (534 paces) 21/2 miles long, 13/4 miles wide Caution: Although Boron Trifluorida does not form an explosive mixture, the container in which it is shipped may explode under pressure from a fire. For maximum safety, evacuate 2,000 leet in all directions. 1 AP000I0191 Bromine (Corrosive, Oxidizer) Potential H>ard> Fire:--Cannot catch fire. --May ignite combustibles. Health: -- Liquid causes burns to skin and eyes. --Vapors extremely irritating. -- Vapors may be fatal if inhaled. --Runoff may pollute water supply. i t j Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action__________________________ Fire:--Move containers from fire area if without risk.. --Cool containers with water from maximum distance until well after fire is out. Spill or Leak:--Large Spills: Dike for later disposal. --Small Spills: Neutralize with lime water if available or flush area with water. --Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. First Aid:--Remove victim to fresh air. Call for emergency medical care. --If victim is not breathing, give artificial respiration. If breathing is difficult, give oxvgen. --If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. --Keep victim warm and quiet. 12 AP00010192 f fI For Assistance Call Chemtrec toll free (800) 424-9300 \k in the District of Columbia, the Virgin Islands. Guam, Samoa, Puerto Rico and Alaska, call (202) 463-7616. ` Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec [! (Chemical Transportation Emergency Center) toll free (600) 424-S300. You will be asked for the following information: f Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo, Weather conditions. Type of environment (populated, rural, business, etc.) I Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Bromine is water soluble and can kill fish. Prevent runoff from fire control or i dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. ii i Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 195 yards (234 paces) 1 mile long, 2/3 miie wide 400 square feet 285 yards (342 paces) 11/2 miles long, 1 mile wide 600 square feet 350 yards (420 paces) 2 miles long, 11/4 miles wide 600 square feet 410 yards (492 paces) 21/3 miles long,11/2 miles wide Caution: Although bromine does not form an explosive mixture, the container in which it is shipped may explode under pressure from a fire. For maximum safety, evacuate 2,000 feet in all directions. AP00bi6i93 Carbon Disulfide (Flammable Liquid) Potential Hazard* Fire:--Highly flammable. -- Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Runoff may create fire or explosion hazard in sewer system. Healtn:--Fire may produce irritating or poisonous gases. -- Vapors indoors may cause dizziness or suffocation. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. -- If possible, wear full protective clothing. -- Eliminate all open flames. No smoking. No flares. Keep internal combustion engines af least 20 yards away from spill. --Keep upwind and estimate Immediate Danger Area. -- Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Smalt Fire*. Dry chemical or COa. -- Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after lire is out. --Stay away from ends of tanks. Spill or Leak:--Stop leak If without risk. --Use water spray to reduce vapors. --Large Spills: Dike for later disposal. --Small Spills: Take up with sand, earth or other noncombustible, absorbent material. First Aid:--Remove victim to fresh air. Call for emergency medical care. --If victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. --Keep victim warm and quiet. 14 APOOOlOf94 ------------------ ------------- - For Assistance Call Chemtrec toll free (800) 424-9300 I n the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following Information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. T * Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square leet 400 square feet 600 square feet BOO square feet 20 yards (24 paces) 30 yards (36 paces) 40 yards (46 paces) 45 yards (54 paces) 52B feet long, 528 feet wide 528 feet long, 528 feet wide 1,056 feet long, 528 feet wide 1,056 feet long, 628 feet wide In theeventofan explosion, the minimum safedistancefrom flying fragments is 2,000 feet in all directions. ! APOOOf0195 amtmrn Chlorine (Nonflammable Gas, Poisonous) Potential Hazards Firs:--Cannot catch fire. -- May ignite combustibles. Explosion:--Container may explode due to heat of fire, Health:--Contact may cause burns to skin or eyes. -- Vapors may be fatal if inhaled. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. -- Keep upwind and estimate Immediate Danger Area. -- Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. --Do not get water inside containers. --Do not use water on chlorine leak. --Stay away from ends of tanks Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. --Isolate area until gas has dispersed. --Do not get water inside containers. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of contact or inhalation may be delayed. -- If victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. --If victim contacted material, immediately flush skin or eyes with running water for at least IS minutes. -- Remove contaminated clothes. -- Keep victim warm and quiet. 16 apoooioi96 r -y-t't-. iuj I Ii i For Assistance Cali Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 463-7616. Additional Follow-up Action -- For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (808) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. immediate Danger Area Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feel 400 square leet 600 square feet 800 square feet 160 yards (192 paces) 1 mile long, 1/2 mile wide 240 yards (286 paces) 1 1/2 miles long, 1 mile wide 300 yards (360 paces) 11/2 mllaa long, 1 mile wide 340 yards (408 paces) 2 miles long, 1 1/2 miles wide In the event of an explosion, the minimum safe distance from flying fragments is 2,000 feet in all directions. i i l I AP00010197 Dimethylamine (Flammable Gas, Corrosive) Potential Hazard*_________________________________ Fire:--Highly flammable. -- Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Gas explosion hazard indoors, outdoors or in sewers. Health:--Vapors extremely irritating. Contact may cause bums to skin and eyes. Immediate Action_____ _ -- Get helper and notify local authorities. -- If possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines a? /east 20 yards away from vapor cloud. --Keep upwind and estimate Immediate Danger Area. -- Evacuate according to Evacuation Table. { Immediate Follow-up Action Fire: --Let burn unless leak can be stopped immediately. --Small Fire: Dry chemical or C02. --Large Fire: Water spray or fog. -- Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. Apply water from sides of tanks. --Ffir massive fire in cargo area, use unmanned hose holder or monitor nozzles. If this is impossible, withdraw from area and let fire burn. , -- Stay away from ends of tanks. I j 1 ] I Spill orLeak: -- Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. -- Isolate area until gas has dispersed. First Aid: --Remove victim to fresh air. Call for emergency medical care. -- If victim is not breathing give artificial respiration, if breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for at feast 15 minutes. -- Remove contaminated clothes. -- Keep victim warm and quiet. < APOOOf0198 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action -- For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Waler Pollution Control -- Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Baaed on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate Prom Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Ba 200 square feet 400 square feet 600 square feet 800 square feet 70 yards ( 84 paces) 1,5B4 leet long, 1,056 feet wide 100 yards {120 paces) 4,224 feel long, 1,584 feet wide 125 yards (150 paces) 3,168 feet long, 2,112 feet wide 150 yards (180 paces) 3,696 feet long, 4,224 feet wide In tbeeventotan explosion, theminimum safe distance from flying fragments is 2,000 feet in ail directions. tsaam Dimethyl Ether (Flammable Gas) Potential Hazards Fire:--Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. -- Gas explosion hazard Indoors, outdoors or in sewers. Health:--Vapors indoors may cause dizziness or suffocation. --Contact may cause burns to sKin and eyes. Immediate Action --Get helper and notify local authorities. -- If possible, wear full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at least 25 yards away from spill. --Keep upwind. Isolate hazard area. --Evacuate by at least 2,000 feet. Immediate Follow-up Action Fire:--Let burn unless leak can be stopped immediately. --Small Fire: Dry chemical or C02. --Largs Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire is out. Apply water from sides of tank. -- For massive fire In cargo area, use unmanned hose holder or monitor nozzles, if this is impossible, withdraw from area. --Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. -- Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. --Use standard first aid procedures. 20 AP00010200 For Assistance Cal! Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa. Puerto Rico and Alaska, call (202) 483-7616. 'Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424*9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. I In Cat* of Explosion, th Minimum Safe Distance from Flying Fragments Is 2,000 Faat tn Ml DUseUons. J AP00010201 1-------- ---- ---.......... ............. r. UiM Dimethyl Sulfate (Combustible Liquid, Poisonous) f Potential Hazards Fire:--May catch fire. Health:--Liquid causes burns to skin and eyes. --Vapors extremely irritating. -- Vapors may be fataI if inhaled. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. --if possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate ail open flames. No smoking. No flares. Keep Internal combustion engines at feast 20 yards away. -- Keep upwind and estimate Immediate Danger Area. -- Evacuate according to Evacuation Table. Immediate Follow-uo Action___________________ _ Fire:--Small Fire: Dry chemical or C02. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water if exposed to fire. --Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Large Spill: Dike for later disposal. --Small Spill: Flush area with water. --Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of inhalation may be delayed. -- If victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. --If victim contacted material, immediately flush skin or eyes with running water for at /east 15 minutes. --Remove contaminated clothes. --Keep victim warm and quiet. 22 i n APOOdtOm r For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands. Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Oike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. j Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 50 yards (60 paces) 1,066 feet long, 528 feet wide 400 square feet 75 yards (90 paces) 1/2 mile long, 1/4 mile wide 600 square feet 95 yards (114 paces) 1/2 mile long, 1/3 mile wide 800 square feet 110 yards (132 paces) 1/2 mile long, 1/3 mile wide Caution: Although which it is shipped mDiamyeetxhpylloSduelfuantededropersesnsoutrefofrrmomana explosive mixture, fire. For maximum the container in safety, evacuate 2.000 feet in alt directions. m J AP00010203 r ""--------------- Epichlorohydrin (Flammable, Poisonous) ...................... .... . --------- '-mil j Potential Hazards________________________________ Fire:--Highly flammable. Explosion:--Container may explode due to heat of fire. Health:--Vapors extremely irritating. Contact causes severe burns to skin and eyes. --Inhalation harmful -- lung Injury may be delayed. --Runoff may pollute water supply. Immediate Action_________________________________ --Get helper and notify local authorities. -- if possible, wear self-contained breathing apparatus and full protective clothing. --Keep internal combustion engines af least 20 yards away from spill. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Small Plrs: Dry chemical or C02. --Large Fire: Water spray or foam. --Cool containers with water from max/mum distance until well after fire is out. --Stay away from enda of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Do not touch spilled material. --Stop leak if without risk. -- Use water spray to reduce vapors. --Small Spills: Flush area with water spray. --Large Spills: Dike for later disposal. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of contact or inhalation may be delayed. --If victim is not breathing, give artificial respiration, if breathing is difficult, give oxygen. --If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. --Keep victim warm and quiet. 1. AP000I0204 For Assistance Cali Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 433-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (600) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control__________________________________ ____________ --Epichlorohydrin is water soluble and can kill fish. Prevent runoff from fire control or dilution water from entering streams ordrinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Immsdlsts Dsngar Area Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Ba 200 square feet 400 square feet 600 square feet 800 square feet 26 yards (32 paces) 37 yards (45 paces) 46 yards (56 paces) 54 yards (64 paces) 528 feet long, 528 feet wide 1,056 feet long, 528 feet wide 1,056 feet long, 526 feet wide 1,056 feet long, 1,056 feet wide in theeventofan explosion, the minimum safedistance from flying fragments is 2,000 feet in all directions. ------ --- ------------- flliMk Ethyl Chloride (Flammable Liquid, Corrosive) iMa Potential Hazards Fire:--Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. --Runoff may create fire or explosion hazard in sewer system. Health:--Contact may cause burns to skin and eyes. If inhaled, may be harmful. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at least 20 yards away from spill area. --Keep upwind. Isolate hazard area. --Evacuate by at least 2,000 feet. Immediate Follow-up Action Fire.--Small Fire: Dry chemical or COj. --Large Fire: Water spray or fog. --Move containers from fire area ff without risk. --Cool containers with water from maximum distance until well after fire is out. --For massive fire in cargo area, use unmanned hose holder or monitor nozzles. If this is impossible, withdraw from area and let fire burn. --Stay away from ends of tanks. Spill or Leak:--Do not touch spilled material. --Stop leak If without risk. --Use water spray to reduce vapors. --Large Spills: Dike for later disposal. --Small Spills: Take up with sand, earth or other noncombustible, absorbent material. First Aid:--Remove victim to fresh air. Call for emergency medical care. -- If victim is not breathing give artificial respiration. If breathing is difficult, give oxygen. --If victim contacted material, Immediately flush skin or eyes with running water for at least 15 minutes. -- Keep victim warm and quiet. 26 1 AP00010206 For Assistance Call Chemtrec toll free (800) 424-9300 1 In the District of Columbia, the Virgin islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 48S-7616. Additional Follow-up Action -- For more detailed assistance in controlling the hazard, call Chemtrec v (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: 1 Your location and phone number. Location of the accident. I Name of product and shipper, if known. * The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment(populated, rural, business, etc.) Availability of water supply. i Water Pollution Control --Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. i ) j ' * j { ! In Can of Explosion, tha Minimum Safa Dial -ct from Plying FragmanU la 2,000 Paat in All Directions. 27 -- AP00010207 Potential Hmrdi Fire:--Highly flammable. --Flammable vapors may spread from spill. Explosion:--Container may explode due to heat of fire. Health:--Vapors indoors may cause dizziness or suffocation. --Contact with liquid may cause bums to skin and eyes. Immediate Action --Get helper and notify local authorities. --if possible, wear full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at least 50 yards away from vapor cloud. --Keep upwind, isolate hazard area. --Evacuate byaf least 2,000 feet Immediate Follow-up Action___________________ Fire:--Let burn unless leak can be stopped immediately. --Small Fire: Dry chemical or COa. --Large Fire: Water spray or fog. --Move containers from fire area if without risk. --Cool containers with water from maximum distance until well after fire Is out. Apply water from sides of tank. --For massive fire In cargo area, use unmanned hose holder or monitor nozzles. If this is impossible, withdraw from area. --Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. 'Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Isolate area until gas has dispersed. First Aid:--Remove victim to fresh air. --Use standard first aid procedures. 26 AP00010208 r For Assistance Call Chemtrec toll free (800) 424-9300 tn the District of Columbia, the Virgin islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec v (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following Information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. In Csss of Explosion, tho Minimum Soft OIslam* from Flying Fragments I* 2,000 Fact In All Oirsctions. AP000I0209 mfiaiMtt Ethyleneimine (Flammable, Thermally Unstable, Poisonous) A Potential Hazards____________ Fire:--Highly flammable. I -- Flammable vapors may spread from spill. i Explosion:--Container may explode due to heat of fire. ; --Runoff may create fire or explosion hazard in sewer system. Health:--Vapors extremely irritating. Contact may cause burns to skin and eyes. -- Fire may produce irritating or poisonous gases. -- Vapors may be fatal if inhafed. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. --If possible, wear self-contained breathing apparatus and full protective clothing. -- Eliminate all open flames. No smoking. No flares. Keep internal combustion engines a! least 20 yards away from spill. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. L. Immediate Follow-up Action Fire:-- Small Fire: Dry chemical or COa. Large Flra: Water spray or fog. Move containers from fire area if without risk. Cool containers with water from maximum distance until well after fire is out. For massive fires in cargo area, use unmanned hose holder or monitor nozzles. If this Is impossible, withdraw from area and let fire burn. Stay away Irom ends of tanks Withdraw immediately In case of rising sound from venting safety device. Spill or Leak:-- Do not touch spilled liquid. Stop leak if without risk. Use water spray to reduce vapors. Large Spills: Dike lor later disposal. Small Spills: Take up with sand, earth or other noncombustible, absorbent material. First Aid:-- Remove victim to fresh air. Cali for emergency medical care. Effects of contact or inhalation may be delayed. (f victim is not breathing, give artificial respiration. If breathing Is difficult, give oxygen. If victim contacted material, Immediately flush skin or eyes with running water for af least 15 minutes. Remove contaminated clothes. 30 Keep victim warm and quiet. ------------------------------------------------------------- . ' | AP00010210 For Assistance Call Chemtrec toll free (800) 424-9300 In the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 483-7616. Additional Follow-up Action j ! I --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (800) 424-9300. You will be asked for the following information: 1 Your location and phonenumber. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. i | i Water Pollution Control ! -- Prevent runoff from fire control or dilution water from entering streams or drinking water supply. Dike for later disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mph. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area Should Be 200 square feet 400 square feet' 600 square feet 800 square feet 180 yards (216 paces) 1 mile long, 1/2 mile wide 260 yards (312 paces) 1 1/2 miles long, 1 mile wide 325 yards (390 paces) 2 miles long, 1 mile wide 360 yards (456 paces) 2 miles long, 1 1/2 mUe wide In the event of an explosion, theminimum safe distance from flying fragments is 2,000 feet In all directions. Ethylene Oxide (Flammable, Thermally Unstable, Corrosive) Potential Hazards Fire:--Highly flammable. --Flammable vapors may spread from spill: Explosion:*--Container may explode due to heat of fire. --Runoff may create fire or explosion hazard in sewer system. Health;--Contact may cause burns to skin and eyes. if inhaled, may be harmful, -- Fire may produce irritating or poisonous gases. --Runoff may pollute water supply. Immediate Action --Get helper and notify local authorities. -- If possible, wear self-contained breathing apparatus and full protective clothing. --Eliminate all open flames. No smoking. No flares. Keep internal combustion engines at least 25 yards away from spill. --Keep upwind and estimate Immediate Danger Area. --Evacuate according to Evacuation Table. Immediate Follow-up Action Fire:--Let burn unless teak can be stopped Immediately. --Move containers from fire area if without risk. --Cool containers with water from max/mum d/stance until well after fire is out. -- For massive fire in cargo area, use unmanned hose holder or monitor nozzles. If this is Impossible withdraw from area and let fire burn. -- Stay away from ends of tanks. --Withdraw immediately in case of rising sound from venting safety device. Spill or Leak:--Do not touch spilled liquid. --Stop leak if without risk. --Use water spray to reduce vapors. --Large Spills; Dike for later disposal. --Small Spills: Take up with sand, earth or other noncombustible, absorbent material. First Aid:--Remove victim to fresh air. Call for emergency medical care. Effects of contact or Inhalation may be delayed. --If victim is not breathing, give artificial respiration. If breathing is difficult, give oxygen. -- If victim contacted material, immediately flush skin or eyes with running water for at least 15 minutes. --Remove contaminated clothes. -- Keep victim warm and quiet.- 32 1 AP000102I2 r For Assistance Call Chemtrec toll free (800) 424-9300 in the District of Columbia, the Virgin Islands, Guam, Samoa, Puerto Rico and Alaska, call (202) 433-7616. Additional Follow-up Action --For more detailed assistance in controlling the hazard, call Chemtrec (Chemical Transportation Emergency Center) toll free (300) 424-9300. You will be asked for the following information: Your location and phone number. Location of the accident. Name of product and shipper, if known. The color and number on any labels on the carrier or cargo. Weather conditions. Type of environment (populated, rural, business, etc.) Availability of water supply. --Adjust evacuation area according to wind changes and observed effect on population. Water Pollution Control______ --Ethylene Oxide is water soluble and can kill fish. Prevent runoff from fire control or dilution water from entering streams ordrinking water supply. Dike for tater disposal. Notify Coast Guard or Environmental Protection Agency of the situation through Chemtrec or your local authorities. Evacuation Table -- Based on Prevailing Wind of 6-12 mpn. Approximate Size of Spill Distance to Evacuate From Immediate Danger Area For Maximum Safety, Downwind Evacuation Area 6hould Be 200 square feet 400 square feet 600 square feet 800 square feet 25 yards (30 paces) 30 yards (36 paces) 40 yards (48 paces) 45 yards (54 paces) 52B feet long, 528 feet wide 528 feet long, 628 feet wide 1,056 feet long, 528 feel wide 1,058 feel long, 528 feel wide In the event of an explosion, the minimum safedistance from flying fragments is 2,000 feet in all directions. y Mil ibwhu.i III ----------------------------------------------------- HMUW ........-- ' 1 1111 " AP0Q0I02I3