Document dY0qpB0q60a5xaaZbZG4eGd6R
Ar226 - 0637
ACUTE TOXICITY TO AQUATIC INVERTEBRATES (COROPHIUM'VOLUTATOR)
EST SUBSTANCE
Identity: A mixture containing perfluorooctanesulfonate, which may also be
referred to as PFOS, FC-95 or as a component of FC-201AF. (1`Octanesulfonic acid) (CAS # 2795-39-3).
Remarks: The 3M production lot number was not noted. The test `sample
is FC-201AF. Current information indicates it is a mixture of 3% PFOS, 18.59% diethylene glycol butyl ether, 37.81% water, 14%ethylene glycol, 8.25% Acrylic foamer, 9% sodium octyl sulfate, 0.3% sodium lauryl sulfate, 3% triethanolamine, 6% sulfonated alkyl ether salts, and 0.05% tolyltriazole.
The following summary applies to a mixture with incompletely
characterized concentrations of impurities. Data may not accurately reflect the toxicity of the fluorochemical component of the test sample.
METHOD:
Method: ASTM E1367-90, Standard guide for conducting 10 day static `sediment toxicity tests with marine and estuarine sediments. Type: Acute static
GLP: No
Year completed: 2000
`Species: Corophium volutator
Supplier: Field collected from an unpolluted site near Trondheim, Norway
Analytical monitoring: pH and dissolved oxygen
Exposure period: 10 days
Test organism age: Adults (4-8 mm size) `Statistical method: LCs values calculated by PROBIT Analysis, National Swedish Environmental Protection Board (version 2.3, 1990). Calculation of NOEC by single-factor ANOVA followed by Bonferronis procedure. Test conditions:
Dilution water: Natural seawater (34 ppt salinity) from an unpolluted
site in Byfjorden outside of Stavanger, Norway. Sediment collected at an unpolluted site. The sediment is a muddy sand and had an organic fraction of 0.7% and a silt fractionof 0.8%. Dilution water chemistry: Not given.
Lighting: Not given.
Stock and test solution
by adding test substance
ptore6p0a0ragtidoanm:pEsaecdhimteesntt caonndce2nt0r0atmiLonofwasesawparteepra,red
~
then shaken for 3 hours. The sediment was split into three subsamples, with
an overlayof 400 mL seawater added to each, and aerated overnight before
study initiation.
Exposure vessels: 600 mL glass beakers containing 200 goftest sediment
and 400 mL of seawater, with continuous aeration.
000265
Number of replicates: 3 Number of animals per replicate: 10 Numberof concentrations: four plus a blank control Water chemistry during the study:
pH ran8g.e0(80.-110 d(caoynst)r:ol exposure) Temper7a.t8u--re8.r1a(n3g0e2:0 m1g5/+kg1eCxposure) Dissolved oxygen range (0-10 days):
91-94 % (control exposure) 49 - 97 % (3020 mg/kg exposure)
RESULTS
Nominal concentrations: Bk control, 92.4, 495,1030, and 3020 mg/kg (dry
weight). Reference substance (fluoranthene) at 20.3 mg/kg dry weight.
Element values: 10-day LCs = >3020 mg/kg (sediment dry weight) 10-day NOEC = 495 mg/kg (sediment dry weight)
Element values based on nominal concentrations Remarks: Testing was conducted on a mixture as described in the Test Substance Remarks field. The values reported apply to that mixture and not the fluorochemical proportion alone. CONCLUSIONS `The test sample 10-day LCso was determined to be >3020 mg/kg (sediment dryweight). The 10-day No Observed Effect Concentration was 495 mg/kg (sediment dry weight). Validity criteria fulfiled and reference substance was in the normal range.
SPauublm,itMtienrn:esot3aM, C5o5m1p3a3ny, Environmental Laboratory, P.O. Box 33331, St.
DATA QUALITY
Reliability: Kiimisch ranking = 2. This study meets the criteria for quality tleasctkinsg.anaHlyotwiecvalerc,onsfairmmpalteiopnuorfitythweaasmnooutnptroofpefrlluyorcohcahreamcitcearlizperdopaonrdtitohneisnttuhdey
solution.
REFERENCES Test was conducted by RF Rogaland Research, of Stavanger, Norway at the
request of 3M Norge, Lab reference number 89312-1, 2000.
000266
OTHER Last changed: 6/26/00
000267
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Page 131
iii
oda RREANAER
"FC-201 AF Light Water Brand AFFF"
Toxicity tests-
Report RF-2000/001
[ew eee Labret no: 983121 No.of pages: 31
"Author | Elin Horve
Gente: 3M Norge
Version No.7 cater Vers. 105.01 2000 Research Program:
Summary: `The following test results were obtained with "FC-201 AF Light Water Brand AFF":
Toxiclty: Skeletonema costatum Acartia tonsa Corophium volutator
72h EC,, 48nLc, 10dLC,
(mon: 50 (mg): 34 (mgkg dry weight): 53020
`The results relate 10 the product as supplied by Novatech. Keywords: Toxicly, Skeletonema cosiatum, Acartia tonsa, Corophium volutator. Nopartof1 Gocumertmaybareproduced in ry fom wihout permission m wing by FF - RogalandReseach
7 . Kiso
Inger Lisa Andersen
in / Voted
TKoarrAeF-NePtolgaanadrd Resear
000268
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Page20f31
CONTENTS:
2. TESTFOR TOXICITY WITH SKELETONEMA COSTATUM cermin &
3.TEST FOR TOXI WIC THI ACATRTY IATONSA .c.vvvvrvsnerrsnsssssssssssssssssssssssssssssssssssssssssssssssessssss 10
4.TEST FOR TOXICITYWITH COROPHIUM VOLUTATOR crv
1S
:
5. DATA SHEET coors
2
000269
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Page 3031
PREFACE:
Ecotoxicological tests were performed on "FC-201 AFLight WaterBrand AFF" in agreement with Novatech. The sample is a concentrate that normally will be used in a 1% solution. Tests were conducted in accordance with the "Harmonised Offshore Chemical Notification Format" (OSPARCOM 1995 /SFT 1995). Theproject was carried out at RF - Rogaland Researchfor 3MNorge. Al the tests were performed by RF - Miljolab. Study director was Senior Engineer Inger Lisa Andersen. The test results arepresented in separate sections. The results relate to theproduct as supplied by Novatech.
This test reporti issued by a laboratory accredited by Norwegian Accreditation (NA). The accreditation states that the laboratory meets the NA requirements concerning competence, equipment and workingproceduresfor all the test methods contained in the accreditation. Italso states that the laboratory has a satisfactory quality assurance system, which includes internal qualitycontrolschemes, participation in interlaboratory comparisons, and the use of certified reference materials and secondary reference materials. The testsperformed are covered by the accreditation. This test report may not be reproduced in anyform other than infull, without thepermission in writing by RF - Miljlab.
000270
L9a9b31r2e1fo.:
Pagedof!
TEST FOR TOXICITY
Marine alga: Skeletonema costatum
"
000271
Labrefro.:
Pages of31
- TEST REPORT
(GROWTH INHIBITION TEST WITH THE MARINE ALGA Skeletonema costatum
A fIiiii
mJocooteme RREOSGEAALRACNHD
TEST SUBSTANCE: "FC-201 AF Light Water Brand AFF"
TEST RESULT:
`The 72 hours ECs was calculated to ~50 mg/l.
"The test substance was supplied by Novatech, and the test results relate to this product.
TEST DETAILS:
METHOD:
NS-EN ISO 10253, 1998: Water quality - Marine algal growth inhibition test
`with Skeletonema costatum and Phaeodactylum tricornutum.
TEST ORGANISM: Skeletonema costatum, stain NIVA BAC 1. A stock cultureofthe test organism is kept at RF - Rogaland Research
PREPARATIONS:
Natural seawater (salinity: 34 %:) from an unpolluted site in Byfjord was used
as basis for the growth medium. The water was filtered through a GF/C filter, and briefly heated to about 75C prior to use. The seawater was enriched with
`nutrients according to ISO 10253, and recommendations from the Paris
Commission.
Test solutions were prepared from a stock solution. A stock solutionof 511.2 `mg/l was prepared by stirring 0.5112 gramsofthe product n1 lire ofgrowth medium. Other concentrations were prepared from this stock solution.
INCUBATION:
Test cultures of 50 mi were incubated in 100 mi flat-bottomed flasksonan orbital shaker, 3 replicates for each concentration. Test cultures were inocu-
lated to about 2000 cells/ml from an exponentiallygrowing inoculum culture.
`The test was run under continuous light (> 50 uE/m*sek) from fluorescent tubes of universal natural white type, at a temperature of20 2C.
`tThheetteeststlwaassksrcunacfhordaabyofuotr 7g2rohwotuhrsm,eaansdurseumbesnatmsp.leAslgoalf5gmrolwwtehrweatsakmeenasfurroemd
by fluorescence. pH measurements were performed as indicated on data sheet.
000272
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PageSof31
DATA ANALYSIS:
CALCULATIONS: Growth rates were calculated by log linear regression on biomass (fluorescence)
`versus time, as described in NS-EN ISO 10253.
ECso:
NOEC:
The inhibitory effect on the growthofSkeletonema costatum is expressed as the
cefofneccetntcroantcieonntroatfaiopnrwoaduscctaglicvuilnagte5d0b%y irnetdeurcptoiloantioofngbreotwwtehenra3te2m(gE,/Clsoa)n.dThis
100mg/1
Calculation of NOEC (No Observed Effect Concentration) is doneby single-
factor ANOVA followed by Bonferronis procedure for comparing each
concentration mean with the control mean.
TESTRESULTS: Table 1. EC and NOC values obtained with Skeletonema costatum.
Testowbstance
"WFeC-r20B1raAnFd LAiFghFtF"
BCo
-
ECGs
ECy
50
-
NOEC: 10 VVuueessairencceocolnceenbtruyantetiopnotslgaoitnodgn,9NOESC19arancdol5lateobyhsinoigfgtonocaompruatee,r pUrnosgramgmel. Groped nSar 33.
COMMENTS:
VALIDATION:
`The resaurelbatsesd on growth rates for the time span 0 - 72 h, the period during which the growth is considered to be exponentialinthe control cultures
(see growth curves).
The validity criteria given in the test protocol are fulfilled, in that the control
cell density increased by a factor of more than 16 in the test period
(corresponding to a growth rateofmore than 0,9 d'"), the control pH did not
vary by more than 1,0 units during the test and the 72 hours test results with 3,5-dichlorophenol was in the range normally found.
Lab. ref no:
`Sample received.:
`Test period: Report date:
9312-1
20.09.99
04-07.10.99 05.01.2000
QU Noroe
Elin Hove,
Engineer
Analytical technician
HHlkrsy
Age Molversmyr|
Senior Research Scientist
Quality Assurance
Enclosed: Data sheets
Trfhoremecphteroharn intsflld, wbhyb+oWubohtersptrryisseoncraewbryiNnorbgywegRiFa-nMAclcre.diaton (VA) Threportmay nobereproducedmany
000273
Laonbsritiee
Page 731
PRIMARY DATA: Growth inhibition test with Skeletonema costatum
Test substance: "FC-201 AF Light Water Brand AFF" StLaarbt.craotte:s 0949.3110.2919
MeCaosunrce.meunnitt:: mTgh/ebliomasswas measuredbyfluorescence; vabes in fluorescence unis
Grow
oT]
Concentration | 1405| 0a92e5 |061.1003.908|] 071.01:04.099| [draayt:et||Ciororne-||aottsttesatr|t|aottetensdt
00 oo1i1s || oossos || 9729 || s= 221000|| 00099979
00 ootn || oossea || 694 || ase 221016|| o10s0s0
0 ou | ose | 3 |
204| 1000
0
0.12
0.71
71
55
0011 oosa|| ooszts || 7s2s
o1 o14 | oss | 83
00332 || 0o4i || 0os7e|| 8s7s || =&
032 | ows | oes | 92 |
014 | 0s3 | 82 |
"| 2.14| 1.000
221027|| 01.500%0 214| 00s 221114|| o0s9s9 213| 03% 211| 1000
00.1135 | 00.8s8 | 899 | 661
221105|| 0o.o99m9
3322 0o1i4 || oosrs || s82s || TM 221146|| 00999s0
a2 ois | oss | 73 | @ 211 | oom
00 00116s"|| 0o4uss
257 220065|| 003936
br} 016 | oss
ry 200| ose
00114s
a2s7 || 255 || 118626| |oossets
os
as | 194| 0997
11000 oosss|| oo0t|| ooo
000000
10 ol o | 0
000
BoforTesncmeoslubs|tance0(1345|dhior0o4p7henol:
To [9
15mg | 016 | os
106| 096
1.5 mg
0.18
045
1.01 | 0992
_
Meanval0ves: 0012 3|2 0 232
oTu H| Eos | 5 7 |S@
[oouw || oozs || 95 || e&
oaiise || 0oss || 86 || &sm
ml 0.14
04
4al
721710 [[0o5s%e 221132|| 0o3s%s 22104s| |1o.s0e0s0| 2180| wees 0.995|Theresult
olt0re 00274
LSoasrieshn.
Pagesorst
GROWTH CURVES: Growth inhibition test with Skeletonema costatum
Tost substance: "FC.201 AF Light Water Brand AFFF" Lats sag12
no ome i|
.
i340
bi
nnn
no ome 5s
.
|3
1.1 Tw
5 nro
'
032 mg
i
ii :
fo
of escnsnpon
n
1 man
i
3i,
LL
oF essenton
I'
32 mg
s
i1
A
- est Graton ours)
fli 22 mg
I i i
i.
=
4 msn
I7
10 mgn
i:
i1
1
=
a tot duration urs)
fl7 100 mgt pl3 s
b=
JN eminem 000275
LEabrtefro
Page90f3i
|
iInheibition of the growth of Skeletonema costatum ng/L ("6C-201 AF Light Water Brand APE")
Experimental data:
C"oPnCcT3e0n1trAaFtioLnighitn water Brand APE" Growth rate
CCCooonnntttrrrooolll 123
23a0sn
CCCooonnntttrrrooolll 4
Ziloo an
contro mean
2.10
003.11111000
22p.e017
000.133323
2pIemd]
1.1100000
2peee1]
33325%00
2ia.m306
11010.00.00000
2.230006s
33232.000000
1ismee
| |
01i000l..00e00
a0la.0a0000
Iinohpiebricteinotn ot::
:: : 0 1aoll4os 0oa.ll0s 0oa.ll0s 0aa.ll0os 12is4s H1T.e3og 111000000..%00
| 000276
Labrefro.:
Page 100f31
ii
993121
TEST FOR TOXICITY
Marine herbivore: Acartia tonsa
i
000277
Labrefno.
Page 11/31
i
59312.1
TEST REPORT ACUTE TOXICITY TEST WITH THE MARINE COPEPOD Acartia tonsa
A ii
AGE=DT.ERNG RBESEAyRCH
}
TEST SUBSTANCE: "FC-201 AF Light Water Brand AFF"
`TEST RESULT:
-
The 48 hours LCso was calculated to 34 mg/l The test substance was supplied by Novatech, and the test results relate to this product.
TEST DETAILS:
METHOD:
1toSOm/aDriInSe1c4o6p6e9po-d1s99(7C:opWeaptoedra,quCarluisttya-ceDae)t.ermination of acute lethaltoxicity
TEST ORGANISM: Acartia tonsa (Dana), supplied by the Marine Biological Laboratory,
Universityof Copenhagen.
CULTIVATION:
The test organisms were supplied as eggs, and were cultivated in accordance
with the "Paris Commission - RingTest Protocol" (VKI). Large copepodites. and adults were used in the test.
PREPARATIONS: Natural seawater (salinity: 34 %) from an unpolluted site in Byfjord was used
as basis for the dilution water. Thewater was filtered throauGFg/hC filter
prior to use.
|
Tmegs/tlwsoalsutpiroenpsawreerdbeypsrteiprarriendg f0r.o4m9a97gstroacmkssoofluttihoenp.roAduscttoickns0o.5lultiitorneooff999.4
|
i
dilution water. Other concentrations were prepared from this stock solution.
fi
INCUBATION: The test was run in glass containers (28 ml rolled rim vials) each containing
2Vi5almslowfetreesktepstoluuntdieonr aan1d6Sb/a8nhimlailgsh,t/4darrekplpihcoattoepsefroiroedaacthactoencmepnetrraattuiroen.ofThe
-
201C. pH and oxygen measurements were performed as indicated on the
data sheet.
000278
&
a eeeNees Tla7 51875000.Fasc+47 51875200,Eerpriesumioec: 930084800,
99La1b2r-e1fro:
Page 120f31
|
DATA ANALYSIS:
|
CALCULATIONS: The effect on the survivalof Acartia tonsa is expressed as the concentration of
paLeCprytrpoedsvutaclctuoenlsecteahnantldrtatothi5eo09n %5we%orfcetouhnesfeitddeseftnocarencilamilamcliutslaw(tLeiCrosne0.)c.aTlhcTeuhle2a4tcehodombubyrisnuaesindndmgo4tr8hteahloiutrys
'
standard procedure PROBIT Analysis, `National Swedish Environmental
`Protection Board (Version 2.3, 1990). This programme also calculate test
|
concentrations lethal to 10% and 90%ofthe test animals.
NOEC: fCaacltcourlaAtNioOnVofANfOoEllCow(eNdobOybBsoenrfveerdroEnfifsecptroCcoendcuernterfaotricono)mpias rdionngeebaychsingleconcentration mean with the control mean.
TESTRESULTS: TTaabeleL1.LLCCaanddNNOOEC values obtained weityh:"FC~-2~01--AF Light Water Brand AFF
carta tonsa
24 bows
48 hours
LCi
20 (10-29)
12( -29)
Cu
5267-1)
M(-)
Los
130 (92-260)
9309- )
Ne Voaluees idie carPeR1O0B%d 3a0n5aaends0an5de9b5l5tcyooanfefori24daetnendrvc4aleshoarrse.inUdinciatsedm.mNf.O1 EVoaCrluecsaalreculatbeyd {hecomputeprogrammeGraphPad Inia 3.0.
VALIDATION:
The validity criteria given in the test protocol are fulfilled, in that the dissolved
oxygen concentration at the endofthe test wasgreaterthan or equalto 4 mg/l,
the percentage mortality in the controls was less than 10%, and the 48 hours LCsof3,5-dichlorophenol (reference) was in the range normally found.
Lab. ref. no.
`Sample received.
`Test period:
Report date:
9312-1
20.09.99
06-08.10.99
05.01.2000
SNort
Elin Horve
Engineer
Analytical technician
Te Bloons,
`Age Molversmyr
`Senior Research Scientist
`Quality Assurance
Enclosed: Data sheets
ETrEis et reports soe by Wbortory scrdited by Norwegian Accrediation (VA).
Th report may n-ot-b oreproduced n any
orm othe hn in Tl without he periseion fn wring by RF - Milla.
.
000279
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Page 130f31
}
PRIMARY DATA: Acutetoxicitytest with Acartia tonsa
i
SB | Testsubstance: "FC-201 AF Light Water Brand AFF"
SLtaabr.trdeaft:e: 90963.1102949
|i
--
re Number of
nTuomtbaelr|| psrp.evceismseenl
|| concentaton | Specimen A
0) prone. | 8 DF
--N-- UMBER-- OF DEAD--]|
24hours
48hours
Tol | AB C0 EF| Tow
f
555[000
000
1
555 [001 1 101
{|
12
|
1
55 55 | 45 44 "
{
1
l
|
|
Reference substance(3,5-dichiorophenol): _____ _
|
012000
_1: is |
The result with the reference substance is within the range normally found.
000280
Lab.ref.
933121
|
| or| wm een || Measurements of oxygen and pH.
|
| connor [Goma | oom or | omen | |
L
(mg)
(mg)
:
(mg)
=
(mg/l)
-
|
e | oo oe| w]| | -- e T eTT e w] e]
fotTT =]
-
L9a93b1r2e-f1ro:
Page i5of31
|
|
|i!| |
|
i
TEST FOR TOXICITY
|
Marine Amphipode: Corophium volutator
i
||
| 000282
L9a93b1r2e-f1no
Page 16.01 31
TEST REPORT
ACUTE TOXICITY SEDIMENT TEST WITH THE MARINE AMPHIPOD Corophium volutator
Aiil
fQ ve REF ewe KESEAReH
TEST SUBSTANCE: "FC-201 AF Light Water Brand AFF"
TEST RESULT:
The 10d LCso was calculated to 3020 mg kg dry weight sediment.
The test substance was supplied by Novatech, and the test results relate to this product.
TEST DETAILS:
|
METHOD:
AToSxiTcMityE1T3e6s7t-s9w0i,thStMaanrdianred aGnudidEestFuoarriCnoenSdeudcitmienngts1.0 day Static Sediment
i
TEST ORGANISM: Coraphium volutator, from an unpolluted site near Trondheim.
|
CULTIVATION: The test organisms were supplied as adults (4-8 mm in size) and were held in
|
aerated seawater at 15C. A small amount ofnatural seaweed was used for
1
feeding.
|
PREPARATION: Natural seawater salinity: 34 So) from an unpolluted site in Byfjorden outside
`wSatsavuasnegderfworaspruespeadrifnogrtdeisltustieodnimweanttesr.. TSheedismeednitmecnoltliesctaemduatddanyusnapnodllauntdedwasiste
|
analysed for organic content and proportion silt for each test.
i
Each test concentration was prepared by adding the product in 600 grammes
i
o`fbudcakemtpwassedsihmaeknetnifnoar p3lahsotuircs.bucTkheet.se2d0i0memnltowfasseadwiavtideerdwianstoatdhdreeed baenadketrhse,
|i
400 ml
night.
of
10
seawater was
animals were
added to each,
then randomly
and the beakers were aerated over
selected for each beaker. A sample
of
i
|
tchaelcdualamtpedsaesdimmgenktgw"assedaniamleynsteddrfyorwewiagthetr. content, and all concentrations are
|
INCUBATION:
"The test was run in glass containers (600 ml) each containing 200gof test
`sediment, app.
concentration.
400
The
ml ofseawater and
beakers were kept
10 animals, 3 replicatesforeach
under continuous aeration ata
tienmdipceartaetduroenotfhe15dat1asChe.et.pH and oxygen measurements were performaeds
= !
|
|
|
000283
tdrlr warn 13,7, x2509 hong,47)Seng:NyB47987500Ft19,7200Epo 588650
L9a9b3r1e2f1no.:
Page 170/31
DATA ANALYSIS: CALCULATIONS: rTahteioenffoefcta opnrotdheucsturlveitvhaallotfoC5o0r%opohfituhemtevsotluatnaitmoarliss(eLxCpsr)es.seTdhaesctohmebcionnecden-
vmoarltuaelaitnydptehret9es5t%cocnocnefnitdreantcieonlwimeirtearuesecdalfcourlactaelcdublaytiuosni.ngTthhee s1t0adndaayrLdCso P23R,O1B9I90T)A.naTlhyissisp,rNoagtriaonmamleSawlesdoicsalhcEulnavtierotensmtecnotnaclenPtrroatteicotnisonleBtohaalrdto(1Ve0r%siaonnd 90%ofthe test animals. NOEC: fCaacltcourlaAtNioOnoVfANfOoEllCow(eNdobyObBsoenrfveerdroEnfifsecptroCcoendcuernetrfaotricono)mpiasrdionngeebaychsingleconcentration mean with the control mean.
TESTRESULTS:
f Table 1. LC ani d NOEC valuen s obtained waithi r: "iFCa-2n01.AFS La ighta WaterbBral ni d AFFn FTM
`Corophium voluator
106ays
Lc
50
EA
>3020
Lon
>3020
NVVoaaluleess:ianrdeiccaatlec1a0t%e,d5b0y9P%RaOnBdI9T0%anallysltsy. NafOeErC1a0rdeysca.lcUunliastieedmsbgythebcogmpsutiemprdorgyrawmemigeh. GraphPadinSat 3.0
VALIDATION:
Tpehrecevanltiadgietymocrrtitaelriitaygiinvethneicnotnhterotlesstwperroetolceosls atrheanfu1lf5il%leadn,idntahtaestttwhieth Folxuyogreanntceonnece(nrterfaetreinocnew)awsaslesisn tthheanrranegceonmomremnadlelyd f(o6u0n%d,)biuntotnheeodfitsshoelvteesdt ocfotncheentrreaptliicoantses(3a0ft2e0r mtegn kdagy"s.drTyhweeisgehdtimseendtimuesnetd) iasffteorufnidvteodbaeyswaitnhdinin one accepted limits for organic content but the silt fraction is recommended higher.
ETaE ble 2. Chaaraacteristics ofethe e sediment uosedd for testing
Organic content (4)
Sit ration (4)
01
08
Lab.ref.no:
Sample received.: Test period: Report date:
59312-1
2009.99 0313.12.99 05.01.2000
SSeNe, ToHors
Elin Horve
Age Molversmyr
-
Engineer Analytical technician
Senior Research Scientist Quality Assurance
Enclosed: Data sheets
"TToismeisthrepohrrats sinuflel,dwbiytoultabhoerapteorrymiascsciroendiitnedwrbiynNgorbwyeRgiFa-nMAiccjrlebd.iation (A). The reprt may notbereproduced in any
wd
000284
Labrefro
Page 13of31
PRIMARY DATA: Acute toxicity test with Corophium volutator
Test sobsnce: F201 AFLightWat BrandAFFF"
os sz
ent: Nombaroldoad
|
ovann|| ppoamcmienonn|
pre
sen
wan
||
|| Scorocentmatonm|especrimen| A5 5 &F|| &8 6 | tom | i5 ooeF | Tow|
|
0 0 10
000
|
10 10 10
000
I
|
0 10 10
| =|
| we
1
|
|
|
I I -- LL.
--
ce
_-
-
--
ce
--
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000285
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Page 19of31
est substance: "FC-201AF Light WaterBrand AFF"
LSaabncraoite: s0s0s1i2z9-9
MeasurofeoxmygeennantdpsH.
|
[ow
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[ | Ooges n pH |o | Ovewn em noH||
[| (mghkg dry weight) (%)
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Page200f31
DATA SHEETS
000287
LaSborseifrso.
ogee
ES oATABLAD (elses, Hilfe og Sikkerhessdazablad) siorktseensetarr.: 1003-/4111/4368 USsusaiecvees ue:L04I/0ULs) Vseirdesion L+av.i 06.010b Tel5i-fdoanc:abl6a3ce8s4 o7x5 u00saz/beTiedleefcaxa:v H6i3lj84eav1d7s3l8ingen vad 3M Norge M/S. |
||
T TonviIrTEASTON AY KIEWIGALIER 06 ASVARLIG FIRGA.
|
zagorser: M Nozge A/S
|
sandelsCn-a4v0a1: LIGHT WATER 3RAND ATC PLUS
seizreosajrosnss0u3m8m9e3s7,. Prodekezegisteset:
Telafo22n's, Gif1z3in0f0oraesjonssentialen:
i
| TGP RSeLseSNSIeeNAGREARE onARKEIRERHISK ESARGNTSZSTNIVGa.essss sssanrusmmennannnats |
Iaformasgon on enkeltkongoneates, fazesymol(ex) of risikosetainger |
szoreNAVY
case: vexs-saosewr |
vLi2s-EFraraonsryosuboler:/cisikosesningers Xa; Ri22 TLaonea ltah
2(-P2IEFaTaYvcLmeEosNRyGSmLTbYEoXTlOaeLKrHE/OYcN)iOsBEiUkTToYAsLeELtTnEiR/n)ger: Xi Rid 112-303
-n
FSLAUEOTRAILSK(LEL OOVVEERRFFLIAATTEEAAKCITIIVVEE SSTTOOFPTEESR| TTrraadde SSeeccrceett Loiss |
TMARrGEeNSTEeESRTsUAMVSUOLRFGAATNISKE FLUORGIEMIGALIER TTrraa7dd4ee87SS-ee8cr3ze9err Ik0k.e5.=K-i1eLns: || oo
0| 00288 i
L5a9b3r1e2f1ro.
Page 220f31 .
FC-602 LIGHT WATER BRAND ATC PLUS
I ------ 3 VIXTIGSTE FARTMOMINTIR.
Viksigsse skedeviskainges
S---------- |
Kea izrisers oyaens, huden og lufeveiene. Stickeshes:
sitjorSapzees:iataviall.
. 1 rorstaasmiasTiTaR
-
|
TitcekSkoyvlnle:soaks oynene med rikelige mengder vasa. Kontaks lege cnicdelsers.
SKioynizlakhsudLeenge.med rikelige menger vana. Evis irritesjonen vedvares,
TilsekBuiisanksnydmipncgo:nes oppsshz, bring vedkommesds bor fra eKoknstsaokn:esilnegges.kilden. Sorg for frisk luc. Hvis symptomene vedvarer,
Tita svelging:
KSoendtiaski:ngklesgeessuomniedldle.lbaGrit.aldFrriemknaolel gbireenktnoinngmeurseksun tiil saeamrlbdevimsesdtles
person.
Co
5 TILTAX VED SRASLUKNING.
Zgnec brannslukningsmiddel: Produktet er et brannslukkingsmiddel.
Ikke egnet brannslukningsaiddel:
Eksponesingszisiko ved brana:
-
00028
L5a9b3.1re2f1no.
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.
FC-602 LIGHT WATER BRAND ATC PLUS
r Fosbzenningsprodukzes ved brann: yi
2rosedyzes ved slukking av brann:
-
:
TILTAX VED UTILSIKTIT UTSLI?Z.
:
sezsontige vesmesilescs
|
Se vernesiltak tades andre punkter i dette ES-datablade:.
TilzeVxenvsedileussilosmirkidcee::. uzSspliilzle:avgrenses
' umiddelbarc.
Dekk
til
med
ex
:
osndzsiodrebtazmeenddevemnaat.eriPallaes.serSeosilli esnamleegsnetopbpehuoalidiedrelvmeerdt.lokAke.ngior
: }
Fierning av kjemikelieaviall: Se punks 13, Fiesaing av
kjemikalieavfall.
7 EADTERING OG 0PPBIVARING.
|
i
setinTgAelsiekrefolragrseiskkeisocmprpibdeevrazhivnogr: produktet kan komme i kontakt med ||
cmaetlsieulsl.esLalgergeesnidvleeds.teLmapgerreastuvreeds otveemrper0atgurardeusndecrels4i9usg.radFeorld
:i
beholdesen tate lukies ndr produktet ikke ez i sruk.
Utorenelige mezerieier:
VenzilOapspjboenv:as emballasjen pd et godt ventiless sed.
|i
Sikcerhetstiltax for & forhindre braan:
i
SikkerThkektebsrteinlntbaakr.for 4 forhindze eksplosjon:
!i
Sikkerhetstiltak for & forhindre statisk elektrisites:
|
ForholHdosldceegnlbeasllvaesdjebreakt:ext lukket. Royking forbuds: Under bruk av pfrooydkuenkeeotg kfaanrlizgoeykidnegkofmoproAnzeszaiknegspfroorduurkentsensinkganavdeatnoebsa.kkeSne posu/neklsle1r0, stabilitet og reaktivitet, skadelige dekomponenter.
!
i
00250
LaEb.roefno.:
Pa24gofe31
FC-602 LIGHT WATER BRAND ATC PLUS
| 2 SxsroNIRIiGSKONTROLL CG PERSONLIG VERNEUTSTER. i
oveveUnn:ast & 4 damp, spray eller thke i oynene. Buk teste vetaesriller med ventilez.
Sdndve3z-au:k egnede vernehanskes av hensikesmessig meteriale ved hanicaedczaelreisn:g aBvucypirgoudmuakit.et. Vernehansker av folgende materiale(r)
AnnesGnhnusdvhezhnuckeonnnsahkisn.dvesn:
Andedrezzsvern:
|
Uanvaglhckticnfnolrnudrienngsaiavngelsuftibsirsebteimdastsetrmioaslaer.enBasvealrstespdenkonasvenftorlagsejnodneen
|1
o<ycpaen(irs)kegoddkejmeprezs odgncevdarsektetfsovrearing:e phaarltvimkalsekse: meAd/Z2fSiEl.ter mot
|| sweating:
.
Dpertoc=ukiaizx.keVassokiseusz,sadtrtiekkoenschdeelrlesrurnedyiksesmeudndes:iveasbogeidvanmne.d Vesk
Rendens eter hindering og for spising.
AsbefaHlv:isvecnitsiulgansijnognssventilasion ikke ex tilstrekkelis, md egnet Gvoednkzjieinassjoinndesdirxesattavdeasmnpkboennsyestnetsz.asjSoenregneforholSdielssiurnedkekrelisgabefalte adainissrative normes og/eller kontroller spray eller thke.
ada. nome: for foruzensning i arbeidsatmosfare, Febrier 1996:
aw A(n1s7e3z2i-a18i-n5g)er: Tagen ada. nom.
1,2-EaT-RcIie0rLs (v1e0r7d-i23s1s)a: - (sev) T8a-kcvieczedsis vpeomr:di2m5g/m(id:amp1)0 (sev) Takvezdi ag/ad: - (damp)
2-(2-BU6T-cOiKnSeYrSsTOvKeSrYd)l-pZpTmA:NOL35 / (DIETYLENGLYKOLHONOBUTYLETER) (112-34-5) A(nTsaegceknninnogresrk: aAdam.erinokzamn)s-k grenseverdi anbefalt av produsenten.
FLUORAALnKmYeLsiOaiVnEgReFrL:ATEIAnKgTenIVEadaS.TOFnFoSmR. (Trade Secret)
SINTETAInSsKeEckOaiVnEgReFsL:ATEIAnKgTeInVEadmS.TOFnForEmR. (Trade Secret) .
i : ;| ii
00291
Lpabi.rtehfno.
Page250/31
F-s02 LIcar ATER BRAND ATC PLUS
7 Amerkinger: Ingen ada. norm.
TeaAseme(sTirnaidengeSre:cceang)en ada. norm.
.
RISTIRS-AtVineOrRsGANvIeSrKdEi mFLgU/OmR:KJE0,M1IRAGLrIeEnRse(vTerraddie Saencszeefsa)ls av 3.
|
Pop
--------
Tilssendstorm, : farse, luke:
Uwigsjheensnonvsaiskkeerls, ravarves,
oi:
ns
Fokepunke/-inervails
ca. 93.00 C (3egynnende)
Ssetsepunks/-inzesvalis
Tike relevant
FLemmegunie: setvenseanetighet:
Tagen (Sesaslash cC) Tike retevans
Skssosjonsgrenses, nedze:
kha rotevans
Sksstosjonsgrenses, ovee:
fike retevans
Damptaviks
ca. 16 mE (alkulers v/20 )
Loselighet vanns
Standsar.
Spestein ves:
ca. 1.08 (vanast)
ommpseschess
c0a.60).85 (lufeml) (xeveatess ||
Flykeige organiske forbindelser (VOC): p= 33r9 g/L SCAQHD (Kalkuless
Forasmpningshastighet:
<1 (usylacetated)
Viskosicess
Tike Kien
|
10 smamimroo mmrvIzer.
. 00292
L9a9b3r1e2f1no.
page 20031
FC-602 LIGHT WATER BRAND ATC PLUS
--m--------m---- |! rorrorze som ska unngts:
MeseziTailkee:kjseosme.skal uangds:
-
FariigKeesssopnamiocnnoiknsgisdproogdukkeaersb:ondicksid. Hydrogenfluorid. Gifsige damper,
gbalsasnedsingellfeosrvsenetretsikliekrk.e T4errmeipsrkesdeenkcoemrpeonneoseissgFisavikob.ruksfesdig
|
StabilSiszeebrileo.g Fraeraliizsivpitoelcy:merisasjon vil ikke forskomss.
11 02a2LYSe NINGER-- OM E-- ELSEFA-- REA. S-- A -- ASI-- A 9-- 39A-- A m-- am ma-- nn. ||| 2otekzweirldooyyee:irzizasjon: syaptomes kan vare rodhes, hevelse, smerter og
shzez.
=teekzweirlehuhdu:dizzizeson (eczer langvarig eller gjeacact kontakt):
symptomes kas vare radhes, hevelse og klse.
|
Sifekzereinrndadiengs:aksgonering som overstiges asbefelse adninistracive i|
sommes, ken fore tilt
sechhveisz,kaisnegvaiagvheste,ntimaalnnselsevnedseysktoeomredti:nassjyomnpsteovnaeer,kennedvsaartet hodepine, ceaksjonsevae, sioret tale, svimmelnat og i ekstreme tilfeller bevissslosnes.
sIvreslisc,asjhoonsi(nogvreoglunfyesvienige.r): sympromer kan vase srhet i nese og ||
EffekzDeyrzefsvoerlsgeikngu:sfers med orgeniske fluorkjemikalier, som finnesi
dmeasntgelenprdosduakpzseest,ittv,isesrlovehfeftekssearmtsoemffelkevteesrfosrosmtyprhrveilcskeerr, neveukriotlaopg,i,
bhueklssoeyestsf,eksbeirnyzfeorofmenhneemastkoelrogfir.a eDektspofnoerreilingggeosverifnogernokrjgeaantieske
v"eliuloesdknjienngi.kalier nz de brukes som forutsact og i hemhold til
-
Svelging ken fore til:
_#ihvuizziknneinngogavryngygzaemneer:ters.ysptomes ken vare redusert urinmengde, blod
i
Aksopnmiezrasnjeodnsipnleucnogneine.(LEunngaelbmeisnennenleilsgeAscsoamksktyilldetsilasttanfdreenmmeedrlegemes040293
wpao.rrej.no.
ragessof 51
FC-602 LIGHT WATER BRAND ATC PLUS
|
oNpeosktaesto.s): blsoycmpatgomeLrunkgeabaetveanrneelheoestisnogu, kpunustveevreaasLkievre,trguissnpei.ng,
Informasjon on allergt, ovestolsamhess
.
Keatitzenkallente sgenskapess
Anvessottsiacelise egensiasest
Repzoduks jonsskadelise egenskapest
| Anczevfeslzkucaoedrekvpiiraconkdknuaikiaeigaaesss,,iashnoeenihsoeml:edLeirseennselkleenrSbfsloerrseecoersgaonsisk1eagees & kioppen
|
over lasgze tid, snten som utgangsseleyies sli som
1
gWrTA ioeredsbmdcroeeynrtnbtnreeiusnkkageekssrsspzosofnofraemfreirsfnkogur(epumroce.nsteaarbsDoitelnsigotgftooerv&ree)lrh,ifesoxeornaog:lodrksaienntngiiieasnkkivekueimleulflenldecunreoiecnshkgej,vleesndeiekfafieiketrer
||
Vsfaeocseseksoegmluslbseleinsbeerfasavloksrniigdneagnneins1k97ea0g fdulnurdoeernrk.zjoepmoiislkeeslsjipoeinrdeesmiibositoooudseiatockbeetiidlsetcdaeed,nierharav
ears acseidare visas ingen sadelise ebfekeec.
Zftorreesszyonr'selv.edrorende produktets gif:tighet er tilgjengelig pd
| 12 omsieswivean on wiiserane.
Pecsisbfcelesuntoesc/kapiireoonldioukgiaitlseiksesinsenodnbnerhmyoculhldaiesgrheenetsn: eilklkeerofflenceedboyrigsaenrieskeog fomblir { ailioet (persisence).
akosok2sik34olaogiilsjkoe-pdroedsu:kcdasablad er tilgjenselis ol foressecsel.
AndreVesdkbaedyeivbiarckhneirn,ger, milje:
C50000 200
52(0cdhadeagmgoieecrsasl:(OBx0iy,og4c1eh3nem8Di/ec9ma;alndo)x:yge0n,55d2emoa/nsd;:
0,254
5/3
20 dagezs Boo/coD: 0,36.
Avatis giteignes:
.
96 cineca 150 for Fisk (ached minsou (iseohales oromelas)): > 00023
L9a9b3r1e2f1o.
Page 28031
FC-602 LIGHT WATER BRAND ATC PLUS
$18000cimnge/sLs; EC50 $ initsess o5
f1Sormidneupthcneiras (ZDCa3p0h,niaPhmoatgonbaa)c:ter1i00u0n
mpgh/ols;phoreun
(#ic0%0x Syszen): heaholdsvis 210 mg/l og 220 mg/l. | =
S075 for evfallshindsering inc. gjeldends forskrifcer.
i
13 FIIANING AV KIEMIKALIZAVFALL.
NesodesSspoetstfiaoairlia-fvjeeealrllnlei.rngbLeaenvvaesnkdjleaimvnifkgaalsllaineltaeivlseyaelnflor:o.ffsepnetsliiaglavgioadlklj.eat iansanles,
HAnObVeEfDaRlAzTeIGOaRvIial07l:sgAruUpFpAeLsL: FRA ORGANISKE PROSZSSER.
ZsUaeNkaD-sEkjRooXdrAeiTnEgG0s7OnRiI0d5l0e07r3,:06:caelsAoivgnfefaneleklrstjfeornasomrPigSdaDlnBeissakveogflesoktsosestmmoiefdtflieekrsk,,.
sive, vaskevaske:
A05viamlodlesstioufzi.numses: 7151 Organisk avfall med halogen.
Spestelle komponenzer: Exylenglykol, fluosforbindelser.
14 072LYSNINGER OM TRANSZORT.
A0R-Klasse:
-
sister:
-
bokszev:
.
=
razgaunnes:
-
carrckors:
-
N-nunmes:
-
TCA0-Klasse:
.
HOG Klasse:
-
IHOG-side:
-
sanz:
-
MEAG:
-
-
| 000295
L5a9b3.1re2f1ro.
Pagedof3
FC-602 LIGHT WATER BRAND ATC PLUS
ovzigeTiokeppltyrsannisnpgoerrt:arlis sods.
;
13 0PPLYSNINGER OW LOVER 0G FORSKRIFTER.
Hercenzikest:
SyaborST(LenS)Z:SKAGELIG (Xn)
i
ZanehZoledyelse:niykol 18-22 3
i
2-(autoiyesoksy) -ezanol 10-35 1
-
a-sesnTiantgieirc: ved svelsing. Xen iritere oysens, buen og lufeveiene.
TCainngahvariinsnlaKdoainnegakeetvmtdedatmheu/dsepner.vamyMesnAeessbkaezs.ekyiUslnsvsessnhidrekesosntpadskrsguonmddetidsvomeyenndteinlseecrotorese |||
Saeninaeg.rerVeerdivkaesnsvceelongg.inKgOo,pnptbkaeokvnatralekesgee.uletEgieeltgeicreunggiheeulnlikdosentofegokrsv,ibsazvnad.seknnmeedbehsoilpdeeroegn
fi-gzenze:
||
00
Koz. 0y-r30kesmhay/g1. lufshehov:
ouzigevVaeotnapapelvyasfcnieinnngeseascpkhoimnpgrmoeedszekkeibeeattsiekreesnssptehind:tifdrleimgoeverrs.meMceksekfinogresnkrivfitler og vil
{CieviiddleerrsieiameerrskceafrocressksaivfcefrolgaevndJsanmuesr:ki1n9g9,3. son er besert ph
i|
Symbol: Ingen Inneholder: 1,2-etandiol, 2-(2-butoksyetoksy)-etanol xvXaeonnncsiailkrectrittmeeerdsstsoeyydnneeern.nes,oUFnhnugldhaenngivnaongrdinglduifnktgovnetaiavekndeea.mmpeM/dAsphbruadereynec.ecainFkvzee.ndmeaUsnnnpgsdhtoGfofdett VLeeogdye.nsavnePele;gtienssgk,yhlulddkroisnktsrkaakkteso, ggrvlaaanssdskismveadmnendsiogsgetokrooengtmaveaxnntng,dleesWgAevauinkankiedodgeslvbekalozgntet.sa.kt Oppbevares utilgjengelis for barn.
Yai-gruppe:
ee
29Sa
La9b9r3e1f2n1o.:
Page 30031
FC-602 LIGHT WATER BRAND ATC PLUS
[7 -_-- Seestelie lover og bessenmerses:
{
I. forsizifs ox uiasseidelse og distribusion av Helse, Milja- og
|]
2S.ikFkoerhseisrsidfaszaobnlaKdissfsoirtifsaerrliineg oKgjemmiekrakliinegr.av farlise kjesikalies. 3. Forsirifc on Klassifisesiag, mecking m.v. av soff som
|: |
k4.an Fmoerdsfiorrietemoinljosfsaorfef.kartotek.
|
56. zFeoes.sirifs on spesialaveall.
|
i
w16eAnsOR oaLisInGa-R AV sETvoN1N=G=nFso8nsaBsAsRRiiEvSImEsricenidsewoeonmmniesnes.ssins |
Aavend0Fe5illspaeodslaoanmnzseednddleeors:sekniudmikeornseealtlesrasvafsokrers.lukking av brann i hydrokarbones I|!
ViksiDgsatzeeblkeilddef(az) 3veGdenuesrearlbeiOfdfeilcseesn, aSvt.AS-Padualt,sbMliandneets:ota, USA.
ii
AzsexHecliel oCpaptdaabsleardiensg:ox revidess. Tilpasses nye #S-desablaciorskziteer, fastest Januar
m1e9c98k.e- Soege.
|i |
2570 opglysningers
|
2oIvvnpfdloeyrisncnaeisnjgopenrseondouskptdebredsettutsnedoeErppSfn-aodsranmtiaanlbgelaafdnoegr:hhoelneddr.eiEraihhkeveneihrgoldbbrruutkkiloagvvirhperionddnutikevsraeirtnegnedsneom i
pirkokeduiezzeti siaknsovmebrinmeesdjondetmteed ox brukezens anavas.
aRnMd-rdeasparboldaudkette,r
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esnohnvmeerdfaoarnee:n
bprruoskesasv
|| i
i|! oh1
L9a3br3edfno:
Page 310/31
Fo-602 LIceT WATER BRAWD ATC PLUS
rr FOLGENDE
os,
rp
2 10-ne.
3 Tome.
SRODUXTER +
+
+
+:
DEXKES AV DETTE HHS-OATABLADET: x3e-0A0T0E8R-/0A2T2C1-756-602 Brasnsiukain Seskum | Produkeion xe-0008-0100-1
3M Light Waterl/6WAFFF/AIC Fire Fighting Foam, FC-602,1000 L
x3F-0L0i0g8h-t00W7a8t-e3rd/SAAFFE/ATC Fire Figncing Foam, Fe-603, 20%
3e0L0i0g8h-e00M7a7t-e1ry/erarsr/a:nc rice Fighting Foun, FO-G02, 200
| ii| : :
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