Document dQELyrgbNZQ0o2LVeKNGMq4qR

Compliance Checklist Produced by the editors of ADHESIVES AGE THE WILDEST DREAMS HAVE A WAY OF COMING TRUE. Just a remmderthat planning for tomorrow's possibilities is not only a very important but also a very exciting part of today's work. That's why we are developing unique products for water-borne, hot melts, and other new adhesive and sealant technologies. And why we have an entire department dedicated to serving nearly every segment of your industry. it's why we're maintaining our position as a leading supplier of oxygenated solvents. And at the same time helping our customers reformulate to meet both short- and long-term pollution control standards. Our research and development teams are dedicated to developing a wide variety of products, appli cations and techniques to meet a broader range of customer needs and expectations. And we're expanding our ability to distribute efficiently as well as provide prompt and personal technical service. We already have five full-service regional latex plants. Soon there'll be more. You see, we expect the future to be full of surprises for some people. Andfilled with opportunities for others. PEOPLE PLANNING THE FUTURE. Adhesive and Sealant Intermediates Union Carbide Material Safety Data Sheets For The Adhesives Industry The complete Index of MSD Sheets can be obtained from your Union Carbide representative. Material Form Number Acetone Acetophenone Acrylic Acid. Olactal N-Aminocthyleihanolaminc N-Aminoethyl Piperazine F-43002 F-4335S F-43949 F-43570 F-44209 ANHYDROL Solvent. PM 1473 (A.T.F.D. Special Industrial Solvent Formula AJ ANHYDROL Solvent. PM 1474 [A.T.F.D. Special Industrial Solvent Formula Aj ANHYDROL Solvent Special. PM 4080 F-43059 F-43060 F-43867 ANHYDROL Solvent. PM 4081 (A.T.F.D. Special Industrial Silvern Formula A] ANHYDROL Solvent Special. Anhydrous. PM 4082 ANHYDROL Solvent Special. PM 4083 F-43I97 F-44079 F-45770 ANHYDROL Solvent. PM 4084 (A.T.F.D. Special Industrial Solvent Formula Aj F-43198 ANHYDROL Solvent. PM 4085 F-43943 ANHYDROL Solvent Special 190. PM 407g (Government Formulation DM) F-44334 ANHYDROL Solvent Special 190, PM 4079 (Government Formulation AM) F-44i 15 Benzene Bisphcnol A. UCAR 1.5-Butadiene Butanol 2-Butanol Butyl Acetate Butyl Acetate Mixture. PM 5131 8utyl Acrylate Butyl CARBITOL Sutyl CARBITOL Acetate Butyl CELLOSOLVE Butyl CELLOSOLVE Acetate F-43095 F-43571 F-43120 F-43024 F-43572 F-43019 F-43305 F-43073 F-45017 F-43074 F-43003 F-43282 CARBITOL Acetate CARBITOL Mixture. PM 5949 CARBITOL Solvent CARBITOL Solvent. PM 600 F-43026 F-44381 F-43018 F-45879 Material CARBOWAX Methosy Polyethylene Glycol 550 CARBOWAX Methoxy Polyethylene Glycol 550 CARBOWAX Melhoxy Polyethylene Glycol 750 Form Number F-43443 F-43444 F-4 3445 CARBOWAX CARBOWAX CARBOWAX CARBOWAX CARBOWAX CARBOWAX CARBOWAX CARBOWAX CARBOWAX CARBOWAX Polyethylene Polyethylene Polyethylene Polyethylene Polyethylene Polyethylene Polyethylene Polyethylene Polyethylene Polyethylene Glycol Glycol Glycol Glycol Glycol Glycol Glycol Glycoi Givcol Glycol 200 300 400 600 1.000 ! .500 1.540 4.000 6.000 20.000 F-4 3 3 5 9 F-434?t) F-43430 F-43457 F-4 34 3 is F-43459 F-45440 F 4344 I F-43446 F-43442 KMfrt? 66 Material Form Number CF.LLOSlZE Hxdroxxetnx: Cellulose OP-Gr.:des. General CELLOSiZF Hxdrowethx Ceilu.O'e Vx P-G:ax:es. Gene-a! CEi.LOSOLA E Acetate CELLOSOLAE Solxem Cydoiiex.u'oT'e:so-Decx! Acrylate Diacetone Aieonol Diethanolamine 2.2 - Diethx' x\ acetophenone Dietiv. iantme Diethy lammopropxiamtnc Dietlixlene Glycol Dictliy icnctnammc VN-Diethylcthanola mine Dnsobutyl Ketone N.N-Diniethvlethanolumme 1.4-Dio\ane DipropxI;.-no Glycol EVA-308 Resin. BAKEUTE Co-MER FVA-50! Resin. BAKEUTE Co-MER EVA-505 Resin. BAKEUTE Co-MER EVA-506 EVA-50^ EVA-508 EVA-605 EVA-607 Resm. Resin. Resm. Resm. Resm. BAKEUTE BAKEUTE BAKEUTE BAKEUTE BAKEUTE Co-MER Co-MER Co-MER Co-MER Co-MER Epoxy Hardener ERl.-2793. BAKEUTE Liquid Epoxx Hardener ZZl.-OB.AKELlTE Liquid Eooxx Hardener ZZL-0803. BAKEUTE Liquid Epoxy H,.rdener ZZL-0806, BAKELITE Liquid Epoxy Hardener ZZL-0809. BAKEUTE i aquix! Epoxy Hardener ZZL.-0814. BAKEUTE Liquid Epoxx Hardener ZZL-0840. BAKEUTE l.iq aid Epoxy Hardener ZZL-0846. BAKEUTE L.iquid Epoxy Hardener ZZL-0854, BAKELITE Liquid Epoxx Hardener 7ZL-0S72. BAKELITE Liquid Epoxy Hardener ZZLA-0339. B.AKELi TE Liquid Epoxy Hardener ZZI.A-08i6. BAKEUTE Liquid Epoxx Hardener ZZLA-0848. BAKELITE Liquid Epox> Hardener ZZl.B-0822. BAKELITE Liquid Epoxy Resm ERL-42U6. BAKELITE Cycloaliphatic Epoxy Resin ERL-4221. BAKEUTE Cycloaliphatic Epoxy Resm ERL-4234. BAKELITE Cycloaliphatic Epoxy Resm ERL-4289. BAKELITE Cycloaliphatic Epoxx Resm ERRA-4Q90. BAKELITE Cycloaliphatic (4583- F-458 '6 F-4 5062 K-4 3023 F-4 3075 F-41 F-43063 F-43122 F-45'l i F-4325: F-5923 F-45105 F-45i:3 F-43580 F-43252 F-43593 F-43585 F-4,' i 0? F-43908 F-4364? E-45648 F-44095 F-46056 F-43649 F-44096 F-43650 F-43225 ('-43656 F-44163 F-43658 F-4'659 F-4366 I F-43266 F -4 366 8 F-43669 F-43671 F-44474 F-43662 F-43655 F-43664 F-43674 F-436"5 F-43676 F-43677 F-43760 Material Esten.uoi-204 Ethanol see also ANHVDROL and S'iNASOl. Solx cuts' Ethanol, 190 nrt'ot Ethanol. 2 00 pi\H)t Ethanol. CD-19. 190 proof Ethanol. CD-19. 200 prool Eth.mx'i. SD-2. Uo proof Ethanol, SD-40. 200 proof Ethy i Acetate. L nden.itured Ethyl Acetate. 85-SSG . Denatured Ethyl Acrylate Ethy lei'ediamine Ethylene Glycol Ethyicne Oxide 2-Ethyihc.xy 1 Aeryiate. Inhibited Ethyl idcncnorbo rnene Form Number F-4 3 2 80 F-43353 F-43354 F-43412 F-434 i 3 1- -43551 F-44749 F-43020 K-45199 F-43126 F-43127 F-43022 F-43130 F-43586 F-43429 BBBiMMBMI-- Cikunraidchxde. 25'V Aqueous Solution Glxoxai. 40 "V Aqueous Solution Hexylene Glycol Isobutano] Isohutyl Acetate. 99 -- Isohutx! Acetate, 95G Is.'butxl Acetate Mixture. P.Vl 4413 iM'cnityl Aery laic Isobtuyl Hcptyl Ketone Isocyanate ID I and TDI-P. MAX Isocyanate SF-58. N`IA\ Isophoroite Isophorone 50 and I. PM 5464 Isopropanol. Anhydrous Isopropanol. 9 I G Isopropyl Acetate Latex I 30. ICAR Latex 151. CCAR Latex ! 55. LC.AR Latex 380. UCAR Latex 1234. UCAR F-43549 F-43447 F-43064 F-4'21'3 F-431 15 F-45254 F-43301 F-43S03 F-4559 1 F-43954 F-4'984 F-- '065 F-4414? F-43004 F-4 3005 F-43284 F-43755 F-4380' F-455 I 4 F-45515 F-45940 Material Form Number Me:h\; Ann; Acetate Mothy: Ante I Acct.uc .Mixture. PM 447} Metini An;\ 1 Alcohol 3 - Metro I -! -But.mo! 2- Metro I -1 -But ant u. Commercial Metro I n-Butv! Ketone Metre I CAKBITOL Methyl CELLOSOLVE Methyl CELLOSOLVE Acetate N -Metns I Diethanolamine N-Methyl Ethanol am tne Methyl Ethyl Ketone 2-Methy t-5-Elhyi Pyridine Vlcthv I isouniyl Ketone Methyl Uobutyl Ketone Vlcthy! Isobuiyi Ketone Mixture. PM 4914 N-Methyl Morpholine Monocihanolum inc Neopcntyl Glycol Diacrylate 1.5-Pentanedio! 2.4-Pcntanedione Phenolic Bakins Rcsm BKR-2620. BAKELITE ' Phenolic Bakins Resin BKS-2315. BAKELITE " Phenolic Bakins Rcsm BKS-27IO. BAKELITE - Phenolic Resin Solution BLS-2700. BAKELITE Phenolic Resin BRP-8152. BAKELITE Phenolic Rcsm BRPA-4494. BAKELITE Phenolic Resin CK-1634. BAKELITE Oil-Soluble. Heat-Reactive. 1009c Phenolic Resin CK-0405. BAKELITE Oil - Soluble. Non-Heat- Reactive Phenolic Resin CK-2103. BAKELITE Oil-Soluble. Non-Heat - Reactive Phenolic Resin CK-2432. BAKELITE Oil-Soluble. Non-Heat- Reactive Phenolic Resin CK-5254. BAKELITE Oil-Soluble. Non-Heat- Reactive Phenolic Resin CKM-2400. BAKELITE Oil-Soluble. Non-Heat-Reactive Phenolic Resin CKS-1282. BAKELITE Phenolic Dispersion Resin CKU- 5960. BAKELITE Phcnoxy Resin PKHA. PKHH. BAKELITE PKHC. Phenyl Acetate Phenyl Glycol Ether Piperazine. Technical Grade (6(K'r Water Solution) Plasticizer EP-8. FL.EXOL Plasticizer EPO. FLEXOL Plasticizer 3GH. FLEXOL Plasticizer .'GO. FLEXOL Plasticizer 4GO. FLEXOL Plasticizer TOF. FLEXOL Polyethylene Resin DPD-6169. BAKELITE Polyethylene Resin DYDT. BAKELITE Polyethylene Rcsm DYl.T. BAKELITE Polyethylene Resin DYNT. BAKELITE Polyethylene Resin DYNH-I. BAKELITE Polyol LG-168. NIAX Polvoi L.G-Series. General. NIAX F-431 i; F-4 3 2 5 9 Fa? | 15 F-4.'590 F-43.589 F-44037 F-43Q25 F-4320I F-432X3 F-43804 F-45744 F-4300b F-43547 F-4 306b F-43007 F-43302 F-43922 F-431 34 F-44743 F-4392 I F-43569 F-43328 F-44077 F-43816 F-43957 F-44 I 54 F-45883 F-44436 F-43325 F-43245 F-43326 F-43327 F-43268 F-43267 F-4 3161 F-43276 F-44131 F-43919 F-4 3903 F-43362 F-4336I F-43602 F-43815 F-43603 F-43853 F-43906 F-43938 F-43646 F-45962 F-4.5890 F-43794 F-43980 Material Form Number Polvoi LHT-6". MAX Polvoi I.HT-Senes. General. NIAX Polvoi PCP-0200 Series: NIAX Polvoi PCP-0300 Scries, NIAX Polvoi PPG-425. NIAX Polvoi PPG-1025. NIAX Polvo! PPG-1 225. NIAX Poivol PPG-2025. MAX Polvoi PPG-3025. NIAX POl'i OX Water-Soluble Resin WSR N-750 Pnmarv Amvl Acetate Primarv Amvl Alcohol n-Pro panel PROPASOL Solvent B PROPASOL Solvent DM (UCAR2LM) PROPASOL Solvent M (UCAR LM) PROPASOL Solvent P Propylene Glycol Propylene Glycol. Industrial Grade Siianc A-I5I Silane A-i 72 Silane A-174 Silane A-186 Silane A-187 Silane A-189 Siianc A-I 100 Silane A-I 120 Silicone Anlitbam. SAG-47 Silicone Anlitbam. SAG-470 Silicone Copolymer L-77 Silicone Copolymer L-7001 Silicone Emulsion LE-45 Silicone Fluid L-45 Surfactant XD, TERGITOL Nonionic Surfactant XH. TERGITOL Nonionic Surfactant I5-S-9. TERGITOL Nonionic SYNASOL Solvent. Anhvdrous. PM 509 SYNASOL Solvent. PM 3224 SYNASOL Solvent 190. PM 41 (Government Formulation 3? 1) T ricthvlenetetraminc Vinvl Acetate. Inhibited Vinyl Acetate Resins. General. BAKELITE Vinvl Butvral Resin XYHL. BAKELITE Vinvl Resin VAGD. BAKELITE Vinvl Resin VAGH. BAKELITE Vinyl Resin VERR. BAKELITE Vinvl Resin VMCA. BAKELITE Vinvl Resin VMCC. BAKELITE Vinvl Resin VMCH. BAKELITE Vinvl Resin VYHD. BAKELITE Vinvl Resin VYHH. BAKELITE Vinyl Resin VYLF. BAKELITE Vinvl Resin VYNC. BAKELITE Vinvl Resin VYNS. BAKELITE Vinvl Resin VYNW. BAKELITE Vinvl Resin Coaling Solution VYDS. BAKELITE F-43S78 F-43999 F-43998 F-4 3997 F-44003 F-43726 F-4401I F-43-95 F-44010 F-43743 F-43072 F-43288 F-43204 F-43544 F-43206 F-4328! F-43545 F-4 3067 F-43255 F-44938 F-4 3947 F-43925 F-44057 F-43936 F-45729 F-43935 F-45727 F-43330 F-4333I F-4392S F-44185 F-43333 F-43332 F-43805 F-43806 F-43530 F-43077 F-43068 F-44205 F-43I4I F-43142 F-439i4 F-433 1 3 F-43312 F-4315b F-439 I i F-432'5 F-431 58 F-431 5F-431 5 2 F-431 51 F-431 5 3 F-44054 F-43 i 5 * F-43 155 F-4 3040 ANHYDROL. BAKELITE. CARBITOL, CARBOW AX. CELLOSIZE, CELLOSOLVE. FLEXOL. MAX. POLYOX, PROPASOL. SAG, SYNASOL, TERGITOl. and LCAR are registered trademarks of Union Carbide Corp. Lb&e>664 Robert W. Wesson Vice-President and General Manager Coatings and Adhesives Materials Dept. Union Carbide Corporation I t is a privilege for Union Carbide to cooperate with Ad hesives Age in publishing this OSHA checklist. OSHA has come a long wav in a short time. The OSHA stan dards are now very sophisticated. But in their very sophistica tion lies a serious paradox -- the difficulty of unraveling all the new regulations, and then following them. We at Union Carbide hope the accompanying checklist, sum marizing the OSHA regulations, will be of value to harried adhesives manufacturing people. The checklist provides a wa\ to follow OSHA standards, and that is important because the standards have become extremely comprehensive and we are ail obliged to follow them. Of course, regulations alone don't make a safe plant. Effec tive safety programs are needed to ensure that accidents in the workplace are held to a minimum. Employees at every level must be conscious of good safety practice. Union Carbide has long had many committees and groups, at various levels, working in the health and safety area. Recently. Union Carbide estab lished a new corporate department called the Health. Safety and Environmental Affairs Department. The new department will develop an advanced corporate epidemiological program, computerize industrial hygiene and health records, monitor the worldwide environmental impact analysis system, ensure adherence to medical standards, and de velop new corporate systems dealing with product safety. Data generated by this department will be made available to our dis tributors and customers, and to anyone in the adhesives industry who might benefit from it. Union Carbide's emphasis on safety has paid off in the past. For example, the number of our disabling injuries is now less than one-quarter the industrial average. Our Chemicals & Plastics group rating -- which includes the Coatings and Ad hesives Materials Department -- is actually six times better than the average. Sound safety practices and good business go hand in hand. And like other companies, we take many approaches to attack safety problems. If someone has a better way to protect people -- whether it is OSHA. a competitor or an employee -- we will incorporate the improvement into our operations. We at Union Carbide seek out every opportunity to cooperate with government and industry so that we can all be safer. I recently gave a talk entitled "Beyond Safety Regulations." in w'hich I pointed out how we worked closely with OSHA in providing safety information. I thought you might like to read some of the highlights; they are reproduced on the following pages. tUne> 6 B 4 Beyond Safety Regulations BY ROBERT W. WESSON 1 hough many company records, including Union Carbide's, show that employees are safer at work than at home, as long as lives and limbs are being lost in the plant, industry cannot rest on its excellent safety records or regulations. At Union Carbide, improving safety is a goal that everyone is constantly striving to achieve. are rated for their toxicological properties. Much of this work is done at the CarnegieMeilon Institute of Research in Pittsburgh. Penna. Union Carbide has long benefited from the services of this toxicology research laboratory. It was nearly 40 years ago that Union Carbide established its Chemical Hygiene Fellowship at the Mellon Institute. This was a full year before the enactment of the Food. Drug and Cosmetic Act. which required testing of food additives and other products that might be harmful. 4,000 Compounds Tested During the ensuing four decades, the Fellowship has grown from a two-man opera tion to a staff of over 35. To date, over 4.000 compounds have been assayed to delineate It is a way of life that begins with upper man agement. In addition to a corporate safety department and its committees, each division or operating unit of the Corporation has a safe ty and health organization devoted to its own particular needs. The Chemicals & Plastics people organized a group known as SHARE, which falls under the direction of a vice president. The name is derived from safety, health and affairs related to the environment. SHARE further ensures that Union Carbide's Chemicals &. Plastics operations meet all aspects of the Federal Occupational Safety and Health Act. Union Carbide is extremely cautious with newly developed chemicals and resins. Before manufacture or use in plants, new substances their toxicological properties. Each chemical is examined to answer the following: Under what conditions can the compound be manufactured without injury to plant per sonnel? Can it be shipped without special han K/ft 66-] jhi-m procedures.' It' not, what procedure must be etv.pk'ved"' And. under wuiit ^;n ,-v .ned SC!:'!\ m ;/<- ->;in:n' Sut'ety programs tor the industry ..it large are. o! course, as vita; as the Corporation's interna! procrams For example, results or the work done at Cunegie-Melion by the Chemical H\c;ene Fellowship are made available to the sci entitle com.mumtv through publication and sharing of information. Produet literature rou- tin.elv includes precautionary labeling informa tion. toxicological properties. FDA and EPA status where applicable, and special handling procedures when necessary. Development of MSD Sheets Another advance of which Union Carbide is proud is the development of its Material SafetyData (MSD) Program -- perhaps the largest single endeavor undertaken to provide our cus tomers and our customers' customers with per tinent safetv data. In ! 970, the Department of Labor mandated that MSD sheets be issued on all hazardous products sold to the ship repairing, ship building and shipbreaking industries (the socalled 3-S industries). These sheets were to be retained at the job site by those using the prod ucts. While safety data have always been published on Union Carbide's products, these new require/nents were more detailed and were specific to these three industries. Beyond Government Programs The first Department of Labor MSD regula tion came out on July i. 1970. Union Carbide meanwhile had outdistanced the government program both in time and in scope. By that time, the company had already devised its own modified MSD sheets -- actually more comprehensive than required -- which the Department of Labor approved on June 20. 1970, Union Carbide's first MSD sheet was issued a few months later. Since that time, over 600 sheets have been issued covering an enor mous variety of products going into many dif ferent industries. Eventually, an MSD sheet will be issued on every product produced -- even on those not officially considered hazard ous. This program is much too valuable to limit its use to the legal requirements of the man date. When a request is made for a new MSD sheet by customers, distributors or internally, a ;eam m experts, from chemists to lawyers, col laborates on developing a sheet that is as dear and helpful as possible. These sheets are so carefully cone -- so comprehensive and dear -- that many other companies, and even OSHA. use them as models. To gather the phvsicai data. Union Carbide's labs do extensive testing in areas such as haz ardous ingredients, fire and e.\pjosion. health, reactoitv. spill or leak procedures, special pro tection and soecial precautions. As a result, much more is included in the data sheets than is required bv current OSHA regulations. On each data sheet a list of phone numbers is in cluded so that Union Carbide safety experts can provide assistance at any time, day or night. Not only is a major effort made to prepare the sheets, but also to have them widely distrib uted and used. Customers are encouraged, via direct contact, newsletters, seminars, etc., to ask for the sheets. They can be obtained either through Union Carbide's sales force or distrib utors. Special binders are provided for conve nient filing and efficient retrieval of informa tion. A comprehensive index, which lists all sheets issued to date, is also provided for ready refer ence. Holders of MSD binders automatically receive an updafed index as soon as it is issued. And. of course, ai! MSD sheets are systemat ically reviewed for updating and/or revisions. The MSD Program is only one of many recent efforts to make industry safer. Union Carbide is dedicated to the continued up grading of all safety programs. Our lives depend on it. 684- DECEMBER 1976 re -'g.,v* ' : Sj. ^stance Exposure Limits o p m.1 mg.-'M1 ' 5 15 0.4 1.5 0.1 0.001 10 5 02 0.4 0.01 0 05 2 0.5 ~ ~ 0.15 13 6.000 1 6 0.25 20 10 5 0.2 0.1 02 0.05 9 4.170 4.170 35 2 0.075 0.07 3 8 1.5 0.1 5 2 22 Uranum (soluDfe compounds) Uranium (insoluDie compounds) C Vanadium: V-Q-, dust . V20.-, fume . -- -- -- -- Vinylcyanide. see Acrylonitrile Vinyl toluene .. Warfarin ... Xylene (xyloi) . . <. d-ne -- 5* ~ Yttrium .. Zinc chloride fume . -- 100 -- 100 5 -- -- Zirconium compounds (as Zr) -- 0.05 0.25 0.5 0.1 -- 480 0.1 435 25 1 1 5 "Parts of vapor or gas per million parts of con taminated air Dy volume at 25JC. and 760 mm. Hg pressure. `Approximate milligrams of particulate per cubic meter of atr ;Nc footnote "c" is used to avoid confusion with the C" that precedes some materials to indicate ceiling value notations.) "An atmosphenc concentration of not more than 0.02 p.p.m.. or personal protection may be necessary to avoid headache. 'As sampled by method that does not collect vapor. 'For control of general room air. biologic monitoring is essential for personnel control. Other Materials Individual standards have been issued for the fol lowing; consult referenced sections for details: MaterialReference isoesros. Coal ta* pi ten vo:a(:'es. in'erc-etat-cr C>` 4-Nitrobiphenyi. aipha-Naphthy famine. Methyl chloromethy! ether 3.3'-Oiehlorobenzine (and its salts) biS-Chloromethyl ether. beta-Naphthytamine. Senzipme. 4-Aminod`Dhenyl. Ethyleneimme. beta-Propiolactone. 2-Acetyiammofluorene. 4-Dimethyiaminoazobenzme. N-Ni'rosodimethylamine. Vmyl chloride. 19-C OCl 2* ; '002 1910.1003 1910.1004 1910.1006 1910.1007 1910.1008 1910 1009 1910.1010 1910.1011 1910.1012 1910.1013 1910.1014 1910.1015 1910 1015 1910.1017 Substance Mineral Dusts Mppcf Mg,'M: Silica: Crystalline: Quartz (respirable) .. Quartz (total dust) . .. Cnstobalite: Use Vi the value calculated from the count or mass for mulae for quartz. Tndymite: Use Vt the value calculated from the for mulae for quartz. Amorphous, including nat ural diatomaceous earth 2S0' % SiC. + 5 -- 20 lOmg/M'1 " %Si0.i-2 30mg/M' %S-0..5-2 SOmg/M'1 %SiO. Silicates (less than 1% crys talline silica): Mica .................... . Soapstone ....................... Talc (non-asbestos-form) Talc (fibrous). Use asbes tos limit ......................... Tremolite (see talc, fibrous) Portland cement............ Graphite (natural).................. Coal dust (respirable fraction less than 5% SiQ-J ... For more than 5% SiO. . Inert or Nuisance Oust: Respirable fraction . . Total dust ......................... 20 20 20" 50 15 _ _ 2.4mg/M:l or 10 mg/M' %SiO.. + 2 15 5mg/M` 50 15mg/M:' Note: Conversion factors -- mppcf* 35.3 "million particles per cubic meter "particles per c.c. "Millions of particles per cubic foot of air. based on impinger samples counted by light-field technics. '`The percentage of crystalline silica in the formula is the amount determined from air-borne samples, ex cept in those instances in which other methods have been shown to be applicable. "Both concentration and percent quartz for the application of this limit are to be determined from the fraction passing a size-selector with the following characteristics: "Containing <1 % quartz; if >1% quartz, use quartz limit. 5 8 Hour Time Weighted Averages and Acceptable Ceiling Concentrations Acceptable maximum peak above the acceptable ceiling concentra tion for an 8-hour shift. 6 G 4 r. exposure i_:rr!i:s a.p.m.' mg./M:'' Substance Exposure Limits 3.3 m.'' mg./M Substance Expo p p.T r* pe. see t i ne . :me -- SKm dust methane . r ... ipoxy-i -propanol) lyi ether, see mol . e Azmpnosmethyi Skm ., a , ane -- Skm hmaiene -- Skin i ' *? i: tate Skm mde nlonde ude -- Skm x-oe(90%) mde ;-? . . ne v -- 20 -- __ -- C.t 1.000 5 5 ;C 50 ___ -- -- -- -- too cc 50 3 5 to 005 -- o.t -- :u ' 'v1' c-C a--:- - - - 3 .. : e j: i c;n ie ... d petroleum Skm see Metnyl - see '.`ihv me 'propyne) me-propadiene APP) ue 2 >2 ivC 5 500 50 0.5 -- -- -- 1.000 -- -- - i5 -- 3r -- -- -- .. - 1 ooo 1.000 -- 94 15 1 2.5 02 5.600 9 20 20c 150 ___ -- 0.5 0.5 10 0.2 5`Jv 410 i0 300 1.3 10 1 4, 1.4 0.2 2 10 CiC j6C '00 ;'-'0 10 95C 930 12 2.100 240 '*0.9 0.15 0.5 1.800 w IS 5 --* 15 -- n1.650 1.800 ethoxymethane) . -- a-*- ^ ` ; iconoi. see utyl carpmoi t) ketone (2- 1 000 _ .V 10 -- too 3.100 ..C- 12 -- 465 ' Methyl isoDutyl carbinoi -- Skm Vef*v: 5::-\ ^exo"9 see Methyl isocyanate -- Skin . Methyl "emac-vate Methyl propyl ketone, see 2- Penfanone . ... Ca Methyl styrene . . . C Me'^vene b spne-'-v soevanate VC-i MolyOdenum Soluble compounds . Insolubfe compounds . Monomethyl aniline -- Skin C Mcnon-em.i - yc-sr-e -- Sxm Vfp'O.IO-me -- Skm Naphthalene ......................... Nickel carbonyl . ... Nickel, metal and soluole empds. as Ni ...................... Nicotine -- Skin .. Nitric acid .................. Nitric oxide ... . p-Nitroaniline -- Skin . Nitrobenzene -- Skm p-Nitrochlorobenzene -- Skm Nitroethane .... . . Nitrogen dioxide . Nitrogen tnftuonde Nitroglycerin -- Skm . . . Nicromethane ................ i -V-oorooare :-N-:-dprCDara Nitrotoluene -- Skin . Nitrotnchloromefhane. see Chloropicrin ......................... Octachloronaphthalene -- Skm Octane Off mist, mineral . Osmium tetroxide Oxalic acid ... ... Oxygen difluoride Ozone . . . Paraquat -- Skin Parathion -- Skin . . Peotaborane . . Pentachloronaphthalene -- Skin Pentachloropnenoi -- Skm 2-Pentanone . Perchloromethyl mercaptan Perehforyf fluoride . e"c e-.m :.j' nates -acT'-a- p-Phenylene diamme -- Skm Phenyl ether (vapor) Phenyl ether-oiphenyi mixture (vapor) Phenylethylene. see Styrene Phenyl glyddyl ether (PGE) Phenyihydrazine -- Skm Phosdrm (Mevmpnos'l --Skm Phosgene (carbonyl chloride) Phosohme . . Phosphonc acid Phosphorus (yellow) . . Phosphorus pentachionoe Phosphorus oentasuihde P*r>nhnri i rrutPUnfidA 25 -- 0.02 10 00 -- too 0 22 -- ___ 2 02 20 100 10 0.001 -- -- 2 25 1 1 -- 100 5 10 02 100 2: 25 5 -- -- 7w0 -- -- -- 0.05 o.: -- -- 0.005 -- -- i 000 200 0.1 3 :uC 2 -- s 1 -- 10 5 -- 0.1 0.3 -- -- -- -- 05 100 -- 0.05 20 -- 480 0u 5 15 9 0 25 , 400 50 0.007 1 0.5 5 30 6 5 1 310 9 23 2 250 30 90 30 -- 0.1 2.350 5 0.002 0.1 0.2 05 0 1i 0 01 0.5 0.5 2 552 700 0.8 13.5 2 -CO 3 01 7 7 -- 60 22 01 0.4 0.4 1 0.1 1 1 3 Propyne. see Methyiacetytene Pyrethrum . . Pyridine . .. Quinone . .. -- -- 5 0.1 Rhodium, Metal fume and dusts, as Rh .................... Soluote salts . Rotenone (commercial) Selenium compounds (a3 Se) Selenium hexafluoride .... Silver, metal and soluble Sodium fluoroacetate (1080) Skm................................. Sodium hydroxide -- -- ___ -- -- 0 Cf __ -- -- Stodda-d 30tven* Strychnine . . . Sulfur dioxide . . . Sulfur nexafluoride . Sulfunc acid . . . Suifur monochloride . Sulfur pentafluoride Sulfuryi fluonde .. . Systox, see Demeton1- . 2.AST .. Tantalum . . . . TE DP -- Skin .... Tellurium . . . Tellurium hexafluoride TEPP -- Skin .. C Terphenyis ............... 1,1.1.2-Tetrachloro-2.2-d'fluoro ethane.................... 1.1.2.2-Tetrachloro-1.2-difluoro emane ... . 1,1,2.2-Tetrachioroethane -- Skirt............................... Tetrachioroethylene. see Per- chloroethylene Tetrachloromethane. see Carbon tetrachloride Tetrachioronaphthalene -- Sk r Tetraethyl lead (as Pb) -- Sk n 'a'-a1--. -a- Tetramethyl lead (as Pb) -- Skm . .. Tetramethyl succtnonitrtle -- Skin . .. ... TetramtTomethane . Tetryf (2,4.6-trinitrophenyl- methylnitranvne) -- Skm Thallium (soluble compounds- -- Skin as T1 . . . Thiram........................... Tin (inorganic empds. except oxides) . :.. -- 5 1.000 -- 1 0 0. 5 -- -- -- -- -- oc -- 500 500 5 -- -- -- -- -- 9s -- -- -- -- 2 ':;uepe-' -t-^-soeva'a--; o-Toluidme -- Skm . Toxaphene, see Chlorinated camphene .. Tributyl phosphate . * * * * : ^ ~ * o a ' ^ " * . - Vi-n, o-rlp'-n 1 2 ' .cey- ' ; o <. ;e Tnchloromethane, see Chlnroform . . 5 -- -- -N 1 XT': . ' ' -i -- adhesivesane DECEMBER 1976 AIR CONTAMINANTS Reference: 1910.1000, OSHA General Industry Standards. Items that apply most directly to the adhesives in dustrv appear in red. Exposure Limits Substance p.p.m." mg./M 1'' Acetaldehyde .... . Acet-c acd Acetic anhydride Acetone Acetonitrile...................... Acetylene dicnioride. see 1. 2-Oichloroethyiene . . . Acetylene tetrabromide . Acrolein...................................... Acryiamide -- Skin.................. Acrylonitrile -- Skm . . . Aldrin -- Skin . .. . . AJIyl alcohol -- Skm................ Ally! chloride........... . . . C Ailyl glycuJyl ether (AGE) Allyl propyl disulfide................ 2-Aminoemanoi. see = :nano:amine 2-Aminopyndine........................... Ami-noma Ammonium suifamate Anraie.' n-Amyl acetate sec-Amyl acetate......................... Aniline -- Skin ......................... Amsidine (0. p-isomers) -- Skin Antimony and comooun^s fas Sb! . ANTU (alpha naphthyl thiourea) Arsenic and compounds (as As) Arsine ............................................. Azinphos-methyl -- Skin ......... Barium (soluble compounds) . o-Benzoqumone. See Quinone Benzoyl peroxide . Benzyl chloride ........................... Biphenyl, see Oiphenyi ............. Bisphenol A, see Oiglycidyl ether ... . Boron oxide ................................ C Boron trifluoride.................... Bromine ........................................... Bromoform -- Skin....................... Butadiene (T.3-t>utaaiene> Sutanethioi, see Butyl mercaptan .................................. 2-Butanone 2-Butoxy ethanol fButyi Ceiiosoive) -- Skm . Butyl acetate (n-butyi acetate) sec-Butyi acetate ten-Butyi acetate Butyl alcohol sec-3utyl alconoi .' ten-Butyi alcohol . . C Butylamine -- Skin ........... C ter?-Butyl chromate (as CrOj) -- Skin ......................... o-3utyt giycidyi ether :BGE'; Butyl mercaptan ...................... p-tert-Buty(toluene ...................... Calcium arsenate...................... Calcium oxide......................... Camphor .................................. Carbaryl (Sevin*).................... 200 .A 5 `. Dec 40 -- 1 0.1 -- 20 -- 2 t 10 2 -- 05 d0 -- oc 125 5 -- -- -- -- 0.05 -- -- -- -- 1 _ -- -- 1 0.1 0.5 1.00C -- 200 50 :50 200 200 too ` 5C too 5 -- 50 10 10 -- -- 2 -- 360 05 20 2 -00 70 -- 14 0.25 0.3 45 0.25 5 3 45 12 -- 2 3^ *5 525 650 19 0.5 05 0.3 0.5 0.2 0.2 0.5 -- 5 5 -- -- 15 3 0.7 5 2 200 -- 590 240 71C 950 950 300 450 300 15 0.1 35 60 1 5 -- 5 Exposure Limits o p m." mg ,'M Substance Crotonaidehyde Cumene -- Skm . . Cyanide (as CM) -- Skm -ic;;ne3.ie Cyc.ohexa~oi Cyt:cnexa-;-e Cydonexene .. Cydopentadiene . 2. 4-0...................... DOT -- Skin .. . DOVP. see Dtcniorvos Oecaborane -- Skm . Demeton* -- Skin D;acetcne a 4--iycrc*;y 4-mec!'v'-2-pe'ranore) 1.2-diammoethane. see Ethylenediamine .. Diazomethane .................. Oiborane .... ... Gouty onoaore C o-Dichloropenzene . . C-uonoosen'ene D'Chfcrodiiluorpmetnane 1.3-Dichloro-5, 5-dimethyl nydantoin .............. 1.1-Dichloroetnane . . 1.2-0ichioroethyfene ... . C Dichloroethyi ether Skin Oichloromethane. see Methylenechlonde . . .. Oichloromonofluorometh ane C-i ,1-Oichloro-i -nitroetnane 1.2-Oichloropropane. see Propyienedichloride .... Oichlorotetratluoroethane Oichlorvos (OOVP) -- Skin Oieldrin -- Skin .. . . Oiethyiamine......................... Diethylammo ethanol -- Skin Diethyfether, see Ethyl ether Difluorodibromomethane . . . C D:givoc>: efer :0Gc; Dihydroxybenzene. see 26 50 245 5 3GC 050 50 200 50 000 300 1.015 75 200 10 1 0.05 0.3 0.1 50 240 0.2 0.1 50 :oo 100 200 15 0.4 0.1 5 300 450 4 350 0.2 400 790 90 1.000 10 4.200 60 1.000 25 10 100 05 7,000 1 0.25 75 50 860 23 Ethylidine cf Dichioroei N-Ethylmorp Ferbam . Ferrovanadu Fluoride (?s Fluorine Fluorotnchlc Formic acid Furfural -- r,j .-fury 20 Glycidol (2. Glycol mono 2-Ethoxye Guthion'. Hafnium . Heptachlor Heptane Hexach!oro Heutachloror rrexi'e ' 2-Hexanone !-?< V sec-Hexyl 3 Hydrazine Hydrogen 0 C Hydrogen Hydrogen c> Hydrogen p< Hydrogen si HydrOQuinor C Iodine Iron oxide l Isopropylam Isopropyleti- Diisobutyl ketone.................... Diisopropytamine -- Skin . . Dimethoxymethane. see Methyial .................................... Dimethyl acetamide -- Skm . .. Dimethy/amine.............. Dimethylammobenzene, see Xylidene .................................. Dimethy!aniline(N-dimethyl- aniline) -- Skin .. ., G'nethyOe'oer.e. see X,.er.e Dimethyl 1,2-dibromo-2,2-di- chloroethyi phosphate, (Dibrom) ............................... C-metr.yi'ormamtoe -- $k-n 2.6-Dimethylheptanone, see Diisobutyl ketone.................. t.l-Dimethylhydrazme -- Skin Oimethylphthalate.................... Dimethylsultate--Skin.......... Dinitrobenzene (all isomers) -- Skin........................................... Dinitro-o-cresol -- Skin........... Dinitrotoluene -- Skm . ... Oiphenyi 50 5 -- 10 70 5 290 20 -- 35 7$ -- 25 --3 0 30 Ketene . Lead arsen Lindane -- Lithium hyc L.P.G. (liqui gas .. Malathion v.ve : 1 C Mangane Methanethi! mercapta Methoxych: 0.5 1 5 5 Methyl acel Methyl acet mixture I 1 Methyial (d 0.2 Methyl amm **.#66? ^MShyi amy ) 4 1 Methyl -S' 0.2 Methyl (n-ai Heptanor 300 7.600 100 5.100 i5 560 :e g *y ie f9, 1, Material 3-hou r time weighted average Acceptaoie ceiimg concent ration Benzene (Z37 4-19691 Beryllium ana Beryllium compounds 'Z37.29-1970) Cadmum fume (237 5-1970) Cadmium dust tZ37 5-19701 CarOon disulfide (Z37 3-1968) 0 2 p m 2 ag. M O.t mg :M 0 2 mg -M: 20 p p m 25 p p m 5 ug 'M 3 mg. M 0 6 mg ,'M 30 p p m Chromic acid and chromates ,Z37 7-1971) Ethylene diprpmide (Z37.31-1970) -- 20 p.p.m do 30 p p m Fiuorde as dust (Z37 28-1969) . Hydrogen fluoride (Z37.28-1969) Hydrogen suifide 'Z37 2-1966)^. 2.5 mg . M ' do ___ 20 p p m Concentration Maximum duration 50 p p.m 25 m9"'W: ___ -- :00 p.p.m -- 50 p.p.m . 10 minutes. 30 minutes. Do. 1- v : * '<= 5 minutes. 50 p.p.m 10 minutes once only if no other measur- aoie exposure occurs. Mercury (Z37.8-1971)............. Methyl chloride (Z37.18-1969) Organo (alkyl) mercury (Z37 30-1969) 100 p p m 1 mg./10Ms 200 p.p m 0.01 mg ,'M;: 0 0<i mg.'M 1 300 p.p.m 5 minutes >n any 3 hours. Tetracnioroethylene (Z37.22-1967) ... do do X/C1 pom 5 minutes in any 3 hours. E PROTECTION ed Reference re Extinguishers 1910.157 and Hose Systems 1910.158 Sprinkler Systems 1910.159 Chemical shing Systems 1910.160 oxide Extinguishing 1910.161 Alarm Signaling 1910.163 L ENVIRONMENTAL CONTROLS ELECTRICAL REQUIREMENTS Reference: 1910.309 (a) The requirements contained in the follow ing articles and sections of the National Electrical Code, NFPA No. 70-1971; ANSI C11971 (Rev. of Cl-1968) shall apply to all electrical installations and utilization equipment: Articles: 500 Hazardous Locations. 501 Class I Installations (Hazardous Locations). 502 Class II Installations (Hazardous Locations). 503 Class HI Installations (Hazardous Locations). Sections: 250-58 (a}-(b). Equipment on Structural Metal. 250-59 (a), (b), Portable and/or Cord Connected and and (c). Plug Connected Equipment, Grounding Method. 400-3 (a)-(b). Flexible Cords and Cable. Uses. 400-4 Flexible Cords and Cable Prohibited. 400-5 Flexible Cords and Cables. Splices. 400-9 Overcurrent Protection and Ampacities of Flexible Cords. 410-10 Pul! at Joints and Terminals of Flexible Cords and Cables. 422-8 Installation, Appliances w/FIexibie Cords. 422-9 Installation, Portable Immersion Heaters. 422-10 Installation, Appliances Adjacent to Com bustible Material. PC 4 f) 422-11 Stands for Portable Appliances. '^ " O , > 422-12 Signals for Heated Appliances. 422-14 Water Heaters. 422-15 (a), (b). Installation of Infrared Lamp and Indus- rone, see 2- ol-.e -- Skm oive acetate -- form tare xanol iexano<"ie -- Skin - _ .. . -- 25 25 500 too too e -- Sen too 5 -- SO 2.000 470 460 250 28 Picric acid -- Skin Pivai' :2-P:vaiyi-i,3- mdandione) Platinum (SoluDie Saits! as P? Propargyi aiconpt -- Skm Propane n-Propyl nitrate Propylene d'Chioride P-ooyiene ;mme -- Sk.n Propylene oxide oo -- -- -- t.OCO 25 15 0t 0t 0 002 -- 1 30C '- ' to 350 24C t .2.3-TricMoroprooa.ne '.2-Tnch!oro 1.2.2-trifluoro etnane Tnethylamme Trifluoromonooromomethane 2.4.6-Tnnitrooheno! see P'cric acid . 2.4.5*Tnnitropnenylmethyinitramme. see Tetryl . Trinitrotoluene -- Skin ' .'>; , - -s-- j-- ....... ... Turpentine . 50 1.000 25 1.000 -- -_--. too HowTo UseThis Checklist various sections within this chart represent as designated under the Occupational Safety i Health Act as crucial to the safe operation of ir plant. To see how your plant measures up to HA standards, evaluate conditions in each of areas that appear on this checklist. The reences indicate the sections of the Act that )ly. This checklist does not represent the com te scope of the Act. For specific situations not covered here, a thorough study of the compl< OSHA Standards is recommended. An ongoi subscription to the OSHA General Industry St< dards and Interpretations and all changes as th are enacted can be obtained for $21.00 from t Occupational Safety and Health Subscription Sei vice, care of the Superintendent of Documen U.S. Government Printing Office, Washing^ D.C. 20402. HIVE Reference 1910.133 1910.134 1910.135 on 1910.136 3S 1910.137 SS Reference 1910.36 HAZARDOUS MATERIALS Material Reference Compressed Gas 1910.101 Acetylene 1910.102 Hydrogen 1910.103 Oxygen 1910.104 Nitrous Oxide 1910.105 Flammable and Combustible Liquids 1910.106 0 Spray Finishing Using Flammable and Combustible Liquids 1910.107 0 Dip Tanks Containing Flammable or Combustible Liquids 1910.108 1 j Explosives and Blasting Agents 1910.109 Flii To Be Chec Portable F Standpip? Automatic Fixed Dr>' Extingu Carbon D System System; Carbon monoxide.................. Chlordane -- Skin .................. Chlorinated camphene -- Skin Chlorinated diphenyl oxide . . Chlorine ........................ Chlorine dioxide ... . C Chlorine trifiuoride.................. C Chloroacetaldehyde a-Chloroacetophenone (phenacylchlonde)........... 50 -- -- -- o.i 0.1 1 c.os 55 0.5 0.5 0.5 3 03 0.4 3 0.3 oe-zene' o-Chlorobnzylidene malononitrile (OCBM) . . Chlorobromomethane . .. 2-Chloro-l.3-butadiene, see Chloroprene............................. Chlorodiphenyl (42 percent Chlorine) -- Skin.................. Chlorodiphenyl (54 percent Chlorine) -- Skin . . . . ->-so'C 2 i-ecox.c-'ccans. see 2-Chloroethanoi. see Ethylene chlorohydrin.................... Chioroethyiene, see vinyl chloride ...................................... C Chloroform (tnchloromethane) 1-Chloro-l-nitropropane ........... Chloropicrin .................................. Chloroprene (2-Chloro-l ,3- butadiene) -- Skin.................. Chromium, sol. chromic, chromous salts as Cr ........... Metal and insol. salts........... Coal tar p.tcn voiatnes (cenieoe soluble fractioni anthracene. 3aP. pnenanthrene, acridine. cnrvsene. pvrene . Cobalt, metal fume and dust .. . Copper fume ............................. Ousts and Mists ...................... Cotton dust (raw)...................... Crag* herbicide ........................... Cresol (alt isomers) -- Skin . . 0.05 200 -- -- -- -- -- -- 50 20 0.1 25 -- -- -- -- -- -- -- -- 5 050 0.4 1.050 -- 0.5 -- -- 240 100 0.7 90 0.5 02 0.1 0.1 1 15 22 vc Dipropylene glycol methyl ether -- Skin . . .. __ 100 D'-sec. octyl phtnalate (Di-2- 9thylhexytphthalate) Endnn -- Skin . .. EpiChlorhydrin -- Skin . ... -- -- 5 EPN -- Skin ..-- 1.2-Epoxyproparte. see Propyieneoxide 2,3-cPOxy-1 -propanol, see -- Glycidol ... -- Ethanethiol. see Ethylmercaptan -- Ethanolamme............................... 3 2-cthoxyethanol -- Skin . 200 2-c'nc<va:-.'3Ca-ara -Ce; o- sc e ace:ate- -- - urn,: acetate -f, ac.-. ate -- " 25 :cc Ethyiamme ... . 10 Ethyl sec-amyl ketone (5- methyi-3-heptanone) Ethyl benzene . . ......... 25 100 Ethyl bromide ...................... 200 Ethyl butyl ketone (3- Heptanone)............................. 50 Ethyl chloride . ................ 1.000 Ethyl ether.................................... 400 Ethyl formate............................... 100 C Ethyl mercaptan...................... 10 Ethyl silicate ............................. 100 Ethylene chlorohydrin -- Skin . 5 Ethylenediamine ........................ Ethylene dibromide. see 1,2- 10 Dibromoethane ......................... -- Ethyiene cich;c'`ce. see :.2- u-'icnioroethare . C Ethylene glycol dinitrate and/or Nitroglycerin -- Skin -- 0.2 Ethylene givcc.; .'tc"cmethyi atner acetate, see Metnvi Ceiioscive acetate -- Ethylene irrune -- Skm C.5 Etnyiens CXice 50 600 5 0.1 19 0.5 -- -- -- 6 740 .V .-`.C 18 130 435 890 230 2.600 1,200 300 2S 850 16 25 -- -- 1 rC Methyl but- Methytcyc1: Methylcyci: o-Methyicy '" ' ............... T 3 v C t i a F WALKINGJg|^K|||URFAG|S 0:2 1910.26 1910.27 Q Manually PropefledMobile : ^ Ladder Stands and Scaffolds 1910.29 Q Other Working Surfaces 1910.30 PERSONAL PROTI EQUIPMEN To Be Checked Eye and Face Protection Respiratory Protection Occupational Head Protection Q Occupational Foot Protei Q Electrical Protective Devi Ktn6& 86o i MEANS OF EGR General Requirements >d Reference 1910.141 Carriage Disposal 1910.143 Physical Hazards 1910.144 evention Signs 1910.145 AL SERVICES AND FIRST AID 1 shall ensure the ready availability nei for advice and consultation on salth. of an infirmaiy, clinic, or hospital in he workplace which is used for the jured employees, a person or perquately trained to render first aid. pproved by the consulting physician ail able. or body of any person may be ous corrosive materials, suitable drenching or flushing oftheeyes and cvided within the work area for $ncy use. 110-17 (a}-(c). Guarding Live Part 110-16 Arcing Parts. 110-21 110-22 Marking. Identification. 240-1S (a), (b). Location in Premises (for Overcurrent (c), and (d). Protection Devices). 240-19 (a) and Guarding of Arcing or Suddenly Moving (b). Parts of Overcurrent Protection Devices. 250-3 (a)-(b). D.C. System Grounding. 250-5 (a)-(c). A.C. Circuits & Systems To Be Grounded. 250-7 Circuits Not To Be Grounded. 250-42 (a)-(d). Fixed Equipment Grounding, General. 250-43 (a)-(i). Fixed Equipment Grounding, Specific. 250-44 (a)-(e). Nonelectrical Equipment Grounding. 250-45 (a), (b). Equipment Connected by Cord and Plug, (c). and (d). Grounding. 430-142 (a)-(d). Stationary Motor, Grounding. 430-143 Portable Motors, Grounding. 250-50 (a)-(b). Equipment Grounding Connections. 250-51 Effective Grounding. 250-57 (a)-(b). Fixed Equipment Method of Grounding. 422-16 Appliance Grounding, 422-17 installation of Wall-mounted Ovens and Counter-mounted Cooking Units. (b) Every new electrical installation and all new utilization equipment installed after March 15, 1972, and every replacement, modification, or repair or rehabilitation, after March 15, 1972, of any part of any electrical installation or utilization equipment in stalled before March 15, 1972, shail be In stalled or made, and maintained, in accor dance with the Provisions of the 1971 National Electrical Code, NFPA No. 70-1971; ANSI Cl1971 (Rev. of Cl-1958). (c) Notwithstanding the provisions of para graphs (a) and (b) of this section, the effective date of the requirement in section 210-7 of the National Electrical Code, that all 15- and 20-ampere receptacle outlets on single phase circuits for construction sites shall have approved ground-fault circuit protection for personnel, is postponed pending reconsid eration of the requirement Louisville (Cincinnati. Ohio Sales Office) ... . . .............. Enterprise-2226 Metropolitan Area Sales Office; Hackensack, NJ. 07601 .... One University Plaza .. ................. 201-646-1111 M-nneaoolis (Chicago, III. Sales Office).......................................................... 800-621-2510 Moorestown, N.J 08057 .... 308 Haroer Drive . ... 609 235 6200 Mew Vor* (Metropolitan Area Sales Office Hackensack. N J.j.................. 21 2-695-5054 Phnaaeiphia (Moorestown, N.J. Sales Office)............................................ 215-923-3200 Pittsburgh (Moorestown, N.J. Sales Office) ................................................. 412-922-5700 St. Louis (Chicago, Hi Sales Office)....................... .......................... 314-726-0324 San r-ancisco (Long Beach. Calif. Sales Office) ....................................... 800-352-3789 Prom Arizona, Idaho. Montana, Nevada. Oregon Utah. Washington, or Wyoming ................................................. ............ 800-421-3724 Southfield. Mich. 48037 . . 26500 Northwestern Hway....................... 31 3-354-0800 6 B 5:? the acceptable ceiling concentra tion tor an 8-hour shift. 1910.37 cits 1910.37 1910.37 1910.37 1910.37 1910.37 ess 1910.37 ; 1910.37 1910.37 1910.37 1910.37 s 1910.37 is 1910.37 1910.37 1910.37 ' 1910.37 LJ Liquid Petroleum Gases Anhydrous Ammonia 1910.110 1910.111 OCCUPATIONAL NOISE EXPOSURE Reference: 1910.95 Permissible Noise Exposures' (Table G-16) Duration per day (hours) Sound level dBA slow response 8 90 6 92 4 95 3 97 2 .....................................................100 IVz...................................................................102 1 % .....................................................110 % or less.......... .................................115 'When the daily noise exposure is composed of two or more periods of noise exposure of different levels, their combined effect should be considered, rather than the individual effect of each. If the sum of the following fractions: C1/T1 + C2/72 . . . CnITn exceeds unity, then, the mixed exposure should be considered to exceed the limit value. Cn indicates the total time of exposure at a specified noise level, and Tn indicates the total time of exposure permitted at tiiat level. Exposure to impulsive or impact noise should not exceed 140 dB peak sound pressure level. To Be Chec* Sanitation Nonwater < Systems Q Marking of Accident P and Tags MEDIC 10R5eference 1910.1! (a) The employer of medical parser matters of plant h< (b) In the absence near proximity to l treatment of all in sons shall be ads First aidsuppliesa shall be readily av (c) Where the ey< exposed to injur facilities tor quick body shall be pi immediate emergt U.S. Sales Offices Atlanta. Ga. 30329 ...................17 Executive Park Dr .................. Baltimore (Moorestown, N.J. Sales Office) ..................................... 8oston, Mass. 02194 .................. 300 First Ave., Needham Hgts. . Charlotte (Atlanta. Ga Sales Office)................................................... Chicago. Hi. 60606 .................. 120 South Riverside Plaza......... Cincinnati. Ohio 45227 . . West Street & Madisonville Road Cleveland, Ohio 44114 .. , . 1300 Lakeside Ave..................... Dallas, Texas 75207 ..................... 2710 Stemmons Freeway ......... Detroit (Southfield, Mich. Sales Office) ............................................ Houston (Dallas, Texas Sales Office!.............................................. Indianapolis (Cincinnati, Ohio Sales Office! ..................................... Kansas City (Chicago, HI. Sales Office) .............................. .. . ... Long Beach, Caiif 90802 . . 100 Oceangate. 1 1 F|................. . 404-633-6161 . 301-944-8211 . 617 444 5400 . 704-364-1400 312-454 2000 . 513 272 0206 . 216-621 4200 . 214-631-0010 . 313-354-0800 . 214-631 0010 Enterprise-2226 . 800-621 8236 . 213 435-3721 Keton (2 ......................... 100 465 Phosphorus pentasulfide ... OkALk.iKi -- ns 1 j Tnchloromethane, see n I ru.... MAItKIAL^ riMNULinu MfiU STORAGE To Be Checked Reference Handling Materials-Generai Indoor General Storage Powered Industrial Trucks 1910.176 1910.177 1910.178 MACHINERY AND MACHINE GUARDING Reference General Requirements To Be Checked 0 Types of Guarding 1910.212 1910.212 0 Point of Operation Guarding 1910.212 0 Barrels, Containers, Drums 1910.212 0 Exposure of Blades 1910.212 j | Anchoring of Fixed Machinery 1910.212 10 e onecKea 0 Exit Components 0 Protective Enclosure of 0 Width and Capacity 0 Egress Capacity and Occupant Load 0 Arrangement of Exits Access to Exits Exterior Ways of Exit A 0 Discharge from Exits 0 Headroom > 0 Changes in Elevation 0 Maintenance .. andWorkmanship -;w- y: Q Furnishings and Dedorati a > ^0*.'vt Automatic Sprinkler Sysf Q -Alanh and Fire Protectio* -- Systems 0 Fire Retardant Paints 0 Exit Markings C*r&ryi (Savin*) UNION CARBIDE Adhesives and Sealants Materials 270 Park Avenue New Ycr-<. N.Y. 10017 PEOPLE PLANNING THE FUTURE. BPS OiDfianyi Metnyi in-r Heptano 8. J. Kotsher Publisher Adhesives Age Mary C. McMurrer Editor Adhesives Age T he Occupational Safety and Health Act has far-reaching implications tor all who engage in the manufacture of gooes or who provide commercial services. In the adhesives industry, which is but a single segment of all U.S. industrial activity. OSHA has received a great deal of attention ar.d has been the subject of many hours of discussion and planning within individ ual companies and by industry organizations. Nevertheless, the very scope of the Act has made its comprehension a formidable undertaking for harried manage ment in the average adhesives manufacturing company. The ev eryday concerns of bustness operations, the many environmental regulations that demand compliance, and a host of hazardous material and consumer safety controls ieave little of manage ment's working time for concentration on so broad and all.nclusive a subject as the safety of workers in the manufacturing environment. With these considerations in mind, the staff of Adhesives Ace has undertaken to provide adhesives management with a working checklist of what is required to achieve compliance with the Occupational Safety and Health Act. \r, compiling this checklist, we have reviewed the provisions of the Act and have culled out those that most directly apply to such installa tions as may be found in the adhesives industry. The checklist in this fold-out insert is intended to spotlight the most common areas of safety concern for adhesives plants; it is not intended to be a complete digest of the entire Act. We strongly urge company management to obtain complete copies of the OSHA Standards, and to become familiar with then. Perhaps the Pest way is to secure a subscription to the OSHA Standards service provided by the U.S. Government Print ing Office. Washington. D.C. 20402. At a one-time cost of S2I.0C, such a subscription furnishes a complete copy of the Act. plus all cnanges as they are enacted from time to time. The Adhesives Age OSHA compliance checklist has been referenced to provide management with a guide to the sections of the Act that apply to the areas covered. With a copy of the Standards in hand, the plant manager can tell at a glance what safety measures must be taken, and where to find the appropriate regulations. One word of caution: It is impossible to anticipate every man ufacturing situation and every plant feature. Where conditions not covered by the checklist exist, a thorough search cf the OSHA Standards must be carried out by plant management, in order to accurately determine specific compliance requirements. Safetv in the workplace :s everyone's business. We trust that this OSHA checklist will assist adhesives management in the performance of this important obligation. We at Adhesives Age welcome the participation of the Coatings and Adhesives Materials Department of Union Carbide Corporation as the sponsor of this special fold-out OSHA com pliance checklist. The long history of devotion to hig.i safety standards at Union Carbide makes i: most appropriate for that company to join in this effort toward the achievement of higher safety standards for the entire adhesives industry.