Document dG9jXMY8B7kwGwneBOxQ13x9

SEVERN TRENT STL STL Chicago 2417 ond Street University Park, IL 60466 Tel: 70S 534 5200 Fax: 70S 534 5211 www.stl-inc.com SEVERN TRENT LABORATORIES ANALYTICAL REPORT JOB -NUMBER:- 244402'"' ' P r e p a r e d 'F o r : W e sto n Solutions.,... I n c .. 1400 W eston W :ay:v ' . ':BU'ilding.:.5.-2'' West :Cheste.r, PA-'-i-93 8 0 -14 9 9 Project: Confidential D e c atur - FC Investigation Attention; Jai Ke-saxi' \ Date: 02/-27/.2006 Title : Project Manager E-Mail ; r w r i g h t @ s t 1 - i n e .com This Report Contains Leaders in Environmental Testing ____________ 2 - Z ^ / _______________ Date STL Chicago 2417 Bond Street University Park, IL 60466 PHONE: (708) 534-5200 F A X . .: (708) 534-5211 Pages Severn Trent Laboratories, Inc. WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR - FC INVESTIGATION JOB# 244402 Data Summary................................................................ I Chain of Custody..........................................................28 Case Narrative..............................................................34 Raw Data.......................................................................36 STL Chicago ia part of Savern Trent Laboratories, Inc, S A M P L E :I N f 0 R M A T G N Date; 02/27/2006 Job Number. 244402 Customer... Weston SoLutions, Inc. Attn, Jai Kesari Project Number.. : 20004S91 Customer Project ID___ : CONFIDENTIAL DECATUR Project Description.... ; Confidential Decatur - FC Investigation Laboratory . Sample ID Customer Sample ID 244402-1 DF12-SB-GP01-0-0000 244402-2 DF12-SB-GP01-0-0005 244402-3 D F12- SB-GP01-0-0010 244402-4 DF12-SB-GP01-0-0020 244402-5 DF12-SB-GP01-0-QQ5Q 244402-6 DF12-SB-GP01-DB-0050 244402-7 DF12-SB-GP02-0-0000 244402-0 DF12-SB-GP02-0-0050 244402-9 DF12-SB-GP02-0-0010 244402-10 DF12-SB-GP02-0-0020 244402-11 DF12-SB-GP02-0-0050 244402-12 D F12-SB-GP03-0-0000 244402-13 DF12-SB-GP03-Q-0005 244402-14 244402-15 DF12-SB-GP03-0-0010 DF12-SB-GP03-0-0020 244402-16 DF12-SB-GP03-0-0050 244402-17 DF12-SB-GP04-0-0000 244402-18 DF12-SB-GP04-0-0005 244402-19 244402-20 DF12-SB-GP04-0-0010 DF12-SB-GPD4-0-0020 Sample. . . Date _ Matrix.:. .. Sanpled Soil 02/15/2006 Soi l 02/15/2006 soi l 02/15/2006 Soil 02/15/2006 soil 02/15/2006 Soi L 02/15/2006 Soil 02/15/2006 Soi l 02/15/2006 Soil 02/15/2006 Soi l 02/15/2006 soi L 02/15/2006 Soi L 02/15/2006 Soil 02/15/2006 Soil 02/15/2006 Soil 02/15/2006 soil 02/15/2006 Soi l 02/15/2006 Soil 02/15/2006 soil 02/15/2006 Soi l 02/15/2006 T ime:: Sampled 11:15 11:20 11:25 11:30 11:35 11:35 11:55 12:00 12:00 12:05 12:05 13:40 13:40 13:45 13:45 13:45 14:05 14:05 14:10 14:15 Date T i m e .... Received ' :Received 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 02/17/2006 10:10 10:10 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 10:10 02/17/2006 02/17/2006 10:10 10:10 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 244402 CUSTOMER: Weston Sol t ions, Inc. Customer Sample ID: DFI2-SB-GP01-0-0000 Date Sampled.......:02/15/2006 Time Sampled.......:11:15 Sample Matrix..... :Soi l test method Lloyd Kahn PARAMETER/TEST DESCRIPT IQU- Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR; ' Laboratory Sample ID: 244402-1 Date Received........ :02/17/2006 Time Received........ :10:10 Date:02/27/2006 .ATTN:: :Jai::Xesari. . ; SAMPLE RESULT a FLAGS r 2S00 :m d l . ''.RL 120 530 DILUTI0M UNITS'' b a t c h ' DT DATE/TIME- TEC] 1 mg/Kg 173637 02/20/06 1603 els 1 * In Description = Dry VJgt. Page 2 STL Chicago is part of Severn Trent Laboratori es, [ne. Job Nunber: 244402 CUSTOMER: Weston Solutions,. Inc. Customer Sample ID Date SanpLed..... Time SampLed..... Sample Matrix.... D F 1-SE-GPO t-0-0 DG5 02/15/2006 11:20 Soi L TEST METHOD Lloyd Kahn :PAHME TER/ TE ST :BESEft ]PTI OIL Total Organic Carbon (Soils} TOC Average Duplicates, Solid O LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ED 244402-2 Date Received...... 02/17/2006 Time Received...... 10:10 Date:02/27/2006 ATTN: Jai (Cesari SAMPLE RESULT 2000 FLAGS1 HDL: 110 SL DILUTION UNITS .BATCH1: DT DATE/TIHE ITECH 490 mg/Kg 173637 02/20/06 1635 c l s * [n Description = Dry LJgt. Page 3 ST4_ Chicago l's part of Severn Trent Laboratori es , Inc. Job Nutrier: 244402 :CUSTOMER: Weston Solutions, Inc. Customer Sample ID: D F I2-SB-GP0T*0-0010 Date Sampled.......:02/15/2006 Time Sampled.......:11:25 Sample Hatrix......:Soil TEST WETHOC PARAME TER/TESTDE$C.R3.PTIGJJ Lloyd Kahn ]Total Organic Carbon <Soils} !TOC Average Duplicates, Solid LABORATORY TEST RESULTS . . PROJECTt CONFIDENTIAL DECATUR " Laboratory Sample ID: 244402-3 Date Received....... : 02/17/2006 Time Received....... : 10:10 Date:02/27/2006 ATTN: Jai Kesari SAMPLE. RESULT300 FLAGS :HDL aa RL DILUTION UNITS IBATCH- DT DATE/TIME TECH 380 mg/Kg T73739 02/21/06 0937;els STL Chicago is part of Severn Trent Laboratories, Inc. IA * In Description = Dr/ Wgt. Page 5 STL Chicago is part of Severn Trent Labaratories, Inc, Job Humber: 244402 CUSTOMER Vlestbn S o lu tio n s Inc Customer Sainple ID: D F 12-5B-GP1 --005 Date Sampled...... :02/15/2006 Time Sampled...... :11:35 Sample Matrix..... :Soil TEST METHOD Lloyd Kahn PARADETER/TEST DESCRIPTION Total Organic Carbon {Soils) TOC Average Duplicates, Solid s LABORATORY TEST RESULTS PROJECT CON F IDEMTIA L :DECATUR Laboratory Sample ID: 244402-5 Date Received...... : 02/17/2006 Time Received...... : 10:10 Date:02/27/2006 ATTN: Ja i;Kesa ri SAMPLE RESULT 2000 FLAGS :MDL : 100 :RL44 G DILUTION UNITS BATCH. DT DATE/IKE TECH mg/Kg 173739 02/21/06 11 TO pels * [n Descripti on = Dry Wgt. Page 6 STL Chicago is part of Severn Trent Laboratori es, [ne. Job Number: 244402 LABORATORY TEST RESULTS Date:02/27/2006 r In Description = Dry Wgt. Page 7 STL Chicago is part of Severn Trent Laboratories, Enc. 00 * In Description = Dry Ugt. Page 8 STL Chicago is part of Severn Trent Laboratories, Ine. Job Number: 244402 CUSTOMER: Heston Solutions, Inc. Customer Sample ID: DF12-SB-GP02-O-05G Date Sampled...... :02/15/2006 Time Saripled...... :12:00 Sample Matrix..... :Soi l TEST:!METHOD: PARAMETER/JEST :DESCRtPTJO N : Lloyd Kahn Total Organic Carbon (Soils) TOC Average Dupli cates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR . Laboratory SairpLe ID: 244402-S Date Received....... : 02/17/2006 Time Received....... : 10:10 0ate:02/27/2006 ATTN: Jai Kesari - SAMPLE RESULT: FLAGS 1100 MDL 94 RL Di l u t Tom UNITS BATCH DT j DATE/TIME TECH 410 mg/Kg t73739 02/21/06 1211 els n Description = Dry Ugt. Page 9 STL Chicago is part of Severn Trent LaboratoriesH Ine. Job Number: 244402 LABORATORY TEST RESULTS O Date:02/27/200 * [n Description = Dry Wgt. Page 10 STL Chicago is part oi Severn Trent Laboratories, Inc. Job Number: 244402 LABORATORY TEST RESULTS Date:02/27/2006 HH STL Chicago is part of Severn Trent Laboratories, Ine. c T * In Description - Dry Wgt. Page 12 STL Chicago is pari Severn Treni Laboratories, Ine. Job fclifiiber: 244402 .CUSTQM ft: Wes ton So lut ion s,;:Inc. ; . Customer Sample ID: DF12-SB-GPD3-0-0000 Date Sampled........ :02/15/2006 Time Sampled........ :13:40 LABORATORY TEST RESULTS . PROJECT: COtF IDE HT.1AL DECATUR Laboratory Sample ED: 244402-12 Date Received........ :02/17/2006 Time Received........ :10:10 Date:02/27/2006 . ATTN: Jai; (Cesari- Ci tH STL Chicago is part of Severn Trent Laboratories, Inc. STL Chicago is part of Severn Trent Laboratories, Inc. Job NLtnber: 244402 ;CUSTOMER: :Wes ton ;So luti ons, Ire* Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix.... DF12-SB-GP03-0-0010 02/15/20D6 13:45 Soil :TEST:METHOD: PARAMETER/T ST ;DESCRIPT IOH Lloyd Kahn Total Drganic Carbon (Soils) TOC Average Duplicates, Solid LO t LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 244402-14 Date Received....... : 02/17/2006 Time Received....... : 10:10 D ate ;02/27/2 006 . ATTN:- Ji (Cesari :SAMPLE! RESULT Q FLAGS BIO MDL 95 RL DE LUTION OMITS BATCH DTI- DATE/'TIME TECH 410 mg/Kg 173739 02/21/06 1332 els * In Descr pt ion = Dry Ugt. Page 15 STL Chicago is part of Severn Trent Laboratori es ,, Inc. Job Number: 244402 CUSTOMER: Weston .Solut ions, Inc. LABORATORY TEST RESULTS PROJECT : CONFIDENTIAL DECATUR Date:02/27/2006 ATTN: JaiKesari rH * In Description = Dry Ugt- Page 16 STL Chicago is part of Severn Trent Laboratories, Inc. r4 * In Description = Dry Ugt. Page 17 STL Chicago is part of Severn Treni Laboratoriest Ine. i Job Number: 244402 CUSTOMER: Weston Solutions, Inc. Customer SairpLe ID: DF12-SB-GPO4-O-OD0O Date Sampled.......:02/15/2006 Time Sampled....... :14:05 Sample Matrix......:Soil LABORATORY TEST RESULTS .. . PROJECT: CONFIDENTIAL 'DECATUR-' Laboratory Sample ID: 244402-17 Date Received........ :02/17/2006 Time Received........ :10:10 Date:02/27/2006 ATTN: Jai' Cesari * In Description = Dry Wgt. Page 1B STL Chicago is part of Severn Trent Laboratories, [nc. Job Number: 244402 CUSTOMER : Weston Solution's, Inc. Customer Sample ED: DF2-SB-GPD4-0-Q0D5 Date Sampled..... : 02/15/2006 Time Sampled......: 14:05 Sample Matrix.....: Soi l TEST NE7HC0 PARAMETEP/TEST :0ESCRIPTEOM; Lloyd Kahn Total Organic Carbon (Soils) :T0C Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR.' Laboratory Sample ID: 44402-18 Date Received....... : 02/17/2006 Time Received....... : 10:10 Date:02/27/2006 A7TM: Jai Kesari / rl SAM RLE/ RESULT .QJPLAES 5100 MDL 100 RL DILUTEE) UNITS BATCH DT DATE/7IME TECJ- 440 mg/Kg 173739 02/21/06 1448 c ls In Description = Dry tfgt. Page 19 STL Chicago is part of Severn Trent Laboratories, Inc. Job Humber: 244402 LABORATORY TEST RESULTS Date:02/27/2D06 cOv n Description = Dry Wgt. Page 20 STL Chicago is part of Severn Trent Laboratories, Inc. T ft STL Chicago is part of Severn Trent Laboratories, Inc Job Number: 244402 LABORATORY CHRONICLE Date: 02/27/2006 CUSTOMER: Weston Solutions, Me, ' PROJECT: CONFIDENTIAL OCATUR ATTN: Jai JCessri Lab ID: 244402-1 METHOD H o y d Kahn Client ID: DF12-SB-GP01-0-QQQQ DESCRIPTION Total Organic Carbon (Soils) Lab ID: 244402-2 Client ID: DF12-SB-GP01-0-0005 METHOD DESCRIPTION Lloyd Kahh Total Organic carbon (Soils) Lab ID: 244402-3 client ID: DF12-SB-GP1--010 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (soils) Lab ID: 244402-4 Client ID: DF12-SB-GP01-0-0020 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Lab ID: 244402-5 METHOD Lloyd Kahn Client ID: DF12-SB-GP01-0-005 DESCRIPTION Total Organic Carbon (Soils) Lab ID: 244402-6 Client ID: DF12-SB-GP01-DB-005 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 244402-7 Client ID: DF12-SB-GP02-0-0000 METHOD DESCRIPTION Lloyd Kahn total Organic Carbon (Soils) Lab ID: 244402-6 METHOD Lloyd Kahn Client ID: DF1Z-5S-GP02-Q-005 DESCRIPTION Total Organic Carbon (Soils) Lab ID: 244402-9 client ID: D F12- SB-GP02-0-0010 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (soils) Lab ID: 244402-10 Client ID: DF12-SB-GP02-0-0020 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 244402-11 Client ED: DF12-SB-GP02-0-0050 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 244402-12 CLient ID: DF12-SB-P03-0-0000 METHOD DESCRIPTION LLoyd Kahn Total Organic carbon (Soils) Lab ID: 244402-13 Client ID: DF12-SB-GP3-0-0005 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 244402-14 Client ID: DF12-SB-GP03--0010 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 244402-15 Client ID: DF12-SB-GP03-0-0020 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (SoiLs) Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 173637 173637 02/20/2006 1603 DILUTION Date Recvd; 02/17/2006 Sample Date; 02/15/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 173637 173637 02/20/2006 1635 DILUTION Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 0937 DILUTION Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1028 DILUTION Date Retvd; 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1110 DILUTION Date Rocvd: 02/17/2006 Sample Date; 02/15/2006 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1147 DILUTION Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1159 DILUTION Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 173739 173739 02/21/20D6 1211 DILUTION Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #($> DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1223 DILUTION Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1236 DILUTION Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #<$) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1257 DILUTION Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1308 DILUTION Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1320 DILUTION Date Recvd; 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1332 DILUTION Date Recvd: 02/17/2006 SampLe Date: 02/15/2006 RUN# BATCH# PREP BT #<$) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1344 DILUTION Page 22 22 STL Chicago is part of Severn Trent Laboratories, Ine, Job Number: 244402 LABORATORY CHRONICLE Date: 02/27/2006 CUSTOMER: Lab ID: 244402-16 Client ID: DF12-SB-GP03-0-0050 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 244402-17 Client ID: DF12-SB-GPQ4-0-0000 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (Soils) Lab ID: 244402-16 Client ID: DF12-SB-GPO4-O-O0O5 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 244402-19 Client ID: DF12-5B-GPQ4-0-0010 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 244402-20 Client ID: DM2-SB-GP04-0-0020 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) PROJECT : CONFIDENTIAL DECATUR ATTN: Jai Kesari Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #CS) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1423 DILUTION Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1435 DILUTION Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1446 DILUTION Date Recvd: 02/17/2006 Samp Le Date: 02/15/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1501 DILUTION Date Recvd: 02/17/2006 Sample Date: 02/15/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 173739 173739 02/21/2006 1514 DILUTION Page 23 > 23 Job Number.: 244402 : CUSTOMER; VWeston Sol Ut 1ons r;;Ine .; QUALITY CONTROL RESULTS . ;;:PROJECT-: CONFIDENT IAL DECATUR Report Date.: 02/27/2006 TTR: Jai Kesari- ..... Test Method.. Lloyd Kahn ::Method Oescr ipti on ;:VIotal Organic Carbon :(Soi Is) Parameter......... Organic Carbon, Tot. (TOC) Batch. .-......... 173637 'Equipment Code..'. T0C4 Analyst... : cls:: Test Code.: TOC bC Lab ID Reagent Uni ts ICV 173637-002 I06B5TTC2 MB 173637-003 ccv 173637-015 I06BSTTC2 CCB 173637-016 mg/Kg mg/Kg mg/Kg mg/Kg QC Result QC Result 1934.19 29.00 2071.89 29.00 U U True Value 2000.00 2000.00 Orig. Value QC Calc. F * Limits Date Time 97 % 85-115 02/20/2006 1211 02/20/2006 1215 104 X 85-115 02/20/2006 1657 02/20/2006 1700 Test Method^.v.. . Method Description. Parameter. *,, L. '' " ::::::: --- Lloyd Kahn Total Organic Carbon (Soils) Organic Carbon, Tot. <TOC) ... Batch. ... 173739 :::Equipment Code... .: T0C4 be Lab id Reagent Units QC Result bC Result True Value Orig. value ICV 173739-002 I06BSTTC2 MB 173739-005 ccv 173739-020 JQ6BSTTC2 CC 173739-021 CCV 173739-020 I06BSTTC2 CCB 173739-021 mg/Kg mg/Kg mg/Kg mg/Kg mg/Kg mg/Kg 1841.56 29.00 2018.17 29.00 2119.86 29.00 U U U 2000.00 2000.00 2000.00 QC Calc. F 92 101 106 Analyst'... ; els Test Code.: TOC * Limi ts Date Time % 85-115 02/21/2006 0854 02/21/2006 0858 % 85-115 02/21/2006 1413 02/21/2006 1417 % 85-115 02/21/2006 1530 02/21/2006 1535 Test Method.. .Method D.escription. Parameter.......... Lloyd Kahn Total Organic carbon (Soils) TOC Average Duplicates Batch.. 173637 Equi pment:Code.'..: TDC4: Analyst...: els ' Test Code,; TOCAV2 QC Lab ID Reagent Units LCS 173637-004 I0OFSTLK3 mg/Kg be Result QC Result 4934.35 '" True Value 478Q.QQ Orig. Value QC Calc, F * Limits Date Time 103 % 53-140 02/20/2006 1242 ' Teat- Method..:___ '. Lloyd Kehn !Method Descr ipt ion^ Total Organic Carbon (Soi Is) Parameter.......... TOC Average Dupl icates ; QC Lab ID Reagent Uni ts LCS 173739-004 I00FSTLK3 mg/Kg MS 244402-3 I0BSTTC2 mg/Kg MSD 244402-3 I06BSTTCZ mg/Kg QC Result 4163.33 2327,83 2319.92 QC Result 2327.83 Batch..... -. ..w : 173739 Equipment Code. TC4. Analyst... cts Test :Cpde<, T0CAV2 . . True Va Lue 4780.00 2000.00 2000. Orig. Value SQQ.82 800.82 QC CaLc. F * Limits Date Time 87 % 53-140 02/21/2006 0907 82 % 53-140 02/21/2006 1000 88 % 53-140 02/21/2006 1017 0 R 30 Page 24 * %=% REC, R=RPD, A^ABS Dff., D^% Diff. 24 QUALITY ASSURANCE METHODS R E F E R E N C E S AND - NOTES Report Dote: 02/27/2006 ' REPORT COMMENTS 1> ALL pages of this report are integral parts of the analytical data. Therefore, this report shouLd bo reproduced only in its entirety. 2) Soil, sediment and sludge sample results are reported on a "dry weight" basis except when analyzed for landfill disposal or incineration parameters. All other solid matrix samples are reported on an "as received" basis unless noted differently. 3) Reporting limits arc adjusted for sample size used, dilutions and moisture conteht if applicable. 4) The test results for the noted analytical methodis) meet the requirements of NELAC. Lab Cert. ID# 100201 5) According to 40CFR Part 136.3, pH, chlorine Residual and Dissolved Oxygen analyses are to be performed immediately after aqueous sample collection. Uhen these parameters arc not indicated as field (e.g, pH Field) they were not analyzed immediately, but as soon as possible on laboratory receipt. Glossary of flags, qualifiers and abbreviations [any number of which may appear in the report) Inorganic Qualifiers (Q-Column) U Analyte was not detected at or above the statedlimit. < Not detected at or above the reporting limit. J Result is less than the RL, but greater than or equal to the method detection limit. B Result is less than the CRDL/RL, but greater than or equal to the 1DL/MDL. S ResuLt was determined by the Method of standard Additions. F AFCEE: Result is Less than the RL, but greater than or equal to the methoddetection limit. Inorganic Flags (Flag Column) ICV,CCV,ICE,CCErISA,ISBjCRI,CRA.MRL: Instrument related QC exceed the upper or Lower control Limits. * LC$, LCD, MD: Batch QC exceeds the upper or Lower control limits. + MSA correlation coefficient is less than 0.995. 4 MS, MsD: Tho analyte present in the original sample is 4 times greater than the matrix spike concentration; therefore, control limits are not applicable. E SD:Serial dilution exceeds the control limits. H MB, EBl,ER2, EB3: Batch QC is greater than reporting limit or had a negative instrument reading lower than the absolute value of the reporting limit. N MS, MsD: Spike recovery exceeds the upper or Lower control limits. W AS(GFAA) Post-digestion spike was outside 85*115% control limits. Organic Qualifiers (G - Column) U Analyte was not detected at or above the stated limit. ND Compound not detected. J Result is an estimated value below the reporting limit or a tentatively identified compound (TIC). Q Result was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/MS, Y The chromatographic response resembles a typical fuel pattern. 2 The chromatographic response does not resemble a typical fuel pattern. E ResuLt exceeded calibration range, secondary dilution required. F AFCEEResult is an estimated value below the reporting limit ora tentativelyidentified Organic Flags (Flags Column) B MB: Batch QC is greater than reporting limit. compound [TIC) * LCS, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds the upper or lower controllimits. EBl, EB2, EB3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range Concentration is below the method Reporting Limit (RL) Compound was found in the blank and sample. Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds analyzed at a dilution will be flagged with a D. H Alternate peak selection upon analytical reYiew I Indicates the presence of an interfence, recovery is not calculated. M Manually integrated compound. P The Lower of the two values is reported when the % difference between the results of two GC columns is Page 25 CCI Q : a.A L I T REFE A S SUR ANCE M E T H O D S E N C $. A N D H O T E S Report Date: 02/27/2006 greater than 25%. Abbreviations AS Batch Post Digestion Spike (GFAA Samples - See Note 1 below) Designation given to identify a specific extraction, digestion, preparation set, or analysis set CAP Capillary Column CCB Continuing Calibration Blank ccv Continuing Calibration Verification CF Confirmation analysis of original C1 Confirmation analysis of A1 or D1 C2 Confirmation analysis of AZ or D2 C3 Confirmation analysis of A3 or D3 CRA Low Level Standard Check - GFAA; Mercury CRI Low Level Standard Check j tCP cv CaliIbration Verification Standard Di L Fat Dilution Factor Secondary dilution analysis DI Dilution 1 DZ Dilution 2 D3 Dilution 3 DLFat Detection Limit Factor DSH Distilled Standard - High Level DSL Distilled Standard - Low Level DSM Distilled Standard - Medium Level EB1 Extraction Blank 1 EB2 Extraction BLank 2 EB3 Dl Blank ELC Method Extracted LCS ELD Method Extracted LCD ICAL Initial calibration ICB Initial calibration Blank ICV Initial Calibration Verification IDL Instrument Detection Limit ISA Interference Check Sample A - ICAP [SB Interference Check Sample S - ICAP job No. The first six digits of the sample ID which refers to a specific client, project and sample group Lab ID Ah 8 numher unique laboratory identification LCD Laboratory Control Standard Duplicate LCS Laboratory Control Standard with reagent grade water or a matrix free from the analyte of interest MB Method Blank or (PB) Preparation Blank MD Method Duplicate MPL Method Detection Limit MLE Meditm Level Extraction Blank MRL Method Reporting Limit Standard MSA Method of Standard Additions MS Matrix Spike MSD Matrix Spike Duplicate ND PREPF PDS Not Detected Preparation factor used by the Laboratory's information Management System (LiMS) Post Digestion Spike (ICAP) RA Re^analysis of original A1 Re-analysis of D1 AZ Re-analysis of D2 A3 Re-analysis of D3 RD Re-extraction of dilution RE Re-extraction of origihal RC Re-extract ion Confirmation RL Reporting Limit RPD Relative Percent Difference of duplicate (unrounded) analyses RRF Relative Response Factor RT Retention Time Page 26 Q U A L I T Y AS S U R A N C E M E T H O D S R E F E R E N C E S AND N O TE S Report Cete: 02/27/2006 RTW Retention Time Window Sample ID A 9 digit humber unique -for each sample, the first six digits are referred as the job number SEE Seeded Control Blank SD Serial Dilution (Calculated when sample concentration exceeds 50 times the MDL) UCE Unseeded Control Blank SSV Second Source Verification Standard SICS Solid Laboratory Control Standard(LCS) PHC pH Calibration Check LCSP pH Laboratory Control Sample LCDP pH Laboratory Control sample Duplicate HDPH pH Sample Duplicate MDFP LCFP Flashpoint Sample Duplicate Flashpoint LCS Gl Gelex Check Standard Range 0-1 G2 Gelex Check standard Range 1-10 G3 Gelex Check Standard Range 10-100 G4 GeLex Check Standard Range 100-1000 Note 1: The Post Spike Designation on Batch QC for GFAA is designated with an "S" added to the current abbreviation used. EX. LCS 5=LCS Post Spike (GFAA); MSS=MS Post Spike (GFAA) Note 2: The MD calculates an absolute difference (A) when the sample concentration is less than 5 times the reporting limit. The control limit is represented as +/- the Rl, Page 27 27 CHAIN OF CUSTODY 28 CHAIN OF CUSTODY / ANALYSIS REQUEST FORM a 4 -4 4 e g Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE 1 of 6 PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari email: l.kesari (Eftwesto nsoIut ions. com Project Name: Reference No: Decatur, AL FSIAG P Investigation 02181-129-081-0001 ANALYSES REQUESTED Sampler: T. Frinak, T. Walls, D. Armstrong P.O. #: Quotation #: SAMPLE ANALYSIS ExyLIMS # Client Sample Identification DF12 SB GP01 0 0000 DF12 SB GP01 0005 DF12 SB GP01 0010 DF12 SB GP01 0020 telili DF12 SB GP01 0050 SjggfjK DF12 SB GP01 DB 0050 DF12 SB GP02 0000 DF12 SB GP02 0005 DF12 SB GP02 0010 DF12 SB GP02 0020 Collection Date 15-Feb-06 15-Feb-06 15-Feb-06 15-Feb-06 15-Feb-06 15-Feb-06 15-Feb-06 15-Feb-06 15-Feb-06 15-Feb-06 Collection Time 11:15 11:20 11:25 11:30 11:35 11:35 11:55 12:00 12:00 12:05 X X X 3'SD. cO Z. o Sample Matrix Soil Soil Soil Soil Soil Soil Soil Soil Soil Soil CHAIN OF CUSTODY Rei inquis Date 77 Cooler ID No.: Time n 3d Received By: Fed Ex W 5F Cooler Temp. (C): Date Time /3 3 !t>I& Comments 0-3 inches X 0.5-1.0 feet X 1.0-1.5 feet 2.0-2.5 feet 5.0-6.0 feet 5.0-6.0 feet 0-3 inches 0.5-1.0 feet X 1.0-1.5 feet 2.0-2.5 feet X x PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary- Add Raw Data Other: osrs CHAIN OF CUSTODY / ANALYSIS REQUEST FORM Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE 2 of 6 PROJECT INFORMATION Citent: Weston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari email: j.kesa ri@westonsoiutions.com Project Name: Reference No: Decatur, AL FSIA GP Investigation 02181-129-081-0001 ANALYSES REQUESTED Sampler: T. Frinak, T, WalJs, D, Armstrong P.O. #: Quotation #: O SAMPLE ANALYSIS ExyLIMS # rti T 7 : il ^ _==? I y-:A=czz=\ Client Samp e Identification DF12 SB GP02 0 0050 DF12 SB GP03 0000 DF12 SB DF12 SB GP03 GP03 00000105 DF12 SB GP03 0020 DF12 SB GP03 0050 DF12 SB GP04 0000 DF12 SB GP04 0005 DF12 SB GP04 0010 DF12 SB GP04 0020 C ollection Date 15-Feb-06 15-Feb-0 6 15-Feb-0 6 15-Feb-0 6 15-Feb-0 6 15-Feb-06 15-Feb-Q6 15-Feb-06 15-Feb-06 15-Feb-06 Collection Time 12:05 13:40 13:40 13:45 13:45 13:45 14:05 14:05 14:10 14:15 X X X X X X X X EacS 'ooS. +ocj 2o Sample Matrix Sort Soil Soil Soil Soil Soil Soil Soil Soil Soil CHAIN OF CUSTODY Cooier ID No.: Cooler Temp. {C}: Re 1inq fJiy : Qate, Time Received By: Date Time 2//oi. r7 ________ \e<h Eyi \P 's i- - ^530 liO Comments 5.0-6.0 feet o O j- X 0-3 inches X 0.5-1.0 feet X 1.0-1.5 feet 2.0-2.5 feet 5.0-6.0 feet X 0-3 inches X 0.5-1.0 feet X 1.0-1.5 feet 2.0-2.5 feet X X PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sampie Results OnEy Add Case Narrative Add Quality Control Summary Add Calibration Summary Ado Raw Data Other: S a m p le L o # :_ internal Sample Custody Transfer Record M e n -r a h * T* V v~ H n rpjsckl Job Sample Receipt Checklist Report Job Humber.: 244402 Location.: 57222 Check List Number.; 1 Description.: Customer Job ID.... : Job Check List Date.: 02/17/2006 Project Number.: 20004391 Project Description.; Confidential Decatur - FC Investigation Customer...... : Weston Solutions, Inc. Contact.: Jai Kesari Questions ? (Y/N) Comments V2 Date of the Report..: 02/27/2006 Project Manager.... : rew Chain-of-Custody Present?......... .............. . Y Were samples dropped off at or picked up by STL?. . N Custody seal on shipping container?..,.......... . Y ...If "y^s", custody seal intact?................ , Y Custody seals on sample containers?.............. . N ...If ^y^S^r custody seal intact?................ Samples iced?...................... .......... Y Temperature of cooler acceptable? (4 deg C +/' 2) . Y 3,7 Samples received intact {good condition)?....... . Y Volatile samples acceptable? (no headspace)..... Correct containers used?......................... . Y Adequate sample volume provided?................. . Y Samples preserved correctly?........ ............ . Y Samples received within holding^time?............ . Y Agreement between CGC and sample Labels?,..._____ . Y Radioactivity at or below background levels?.... . Y A Sample Discrepancy Report (SDR) was needed?.,.. . N Residual Chlorine Check Required? If samples wero shipped was there an air bill #?. . Y Sample Custodian Signature/Date.................. . Y Page 1 32 I . USAirbill Express 1 Fran Pate 7 Sender's tome / Company [ i J - c . \ \ 1 M 654D 37 6574 Phone .j * J V' ; V > 'l ~ ^ Company <i 1 _iV ^ ^ <_ 7. ..-: Recipients ^ J / *> yO Address___ i. i f ^r We E im r Jifiva- Is P.0,botas or PO.ZPiMIM- , V Addres s ____________________________ __________ l=rd^bEsiii9CtaiEbeh3cilaEp;ti-3FtdEjclaciLkii,piitFtdE'.itcre-EIwe Citv U -^ State J j L __ m ___ lL Di *c 8540 0637 8574 M ^ i Ct!- X . Recipient's opy 4a Express Pacfrage Senrlce toa Saturday Y<&m[y\C FedEtLxisPtcr.iroHritTyrsOj'v'' ernight FFiacddEi jxi hSitaandrtaiTrid>iOLfcvernight 13P&& II-- I FEeaid-EErxreFoilrtsit.!QvenTrCigTCiritg J 7 et.5n a . acaire-.- PI----- &F>e3ddEldxU29D1eUy ITFtHeitddiEasjxjjrsEemexssprirtfeacys*"`s Sever FixE lEtmcfi nra na ew ia tfa ^ w j T i i J g i a Ehfrumid -m -- e TajddSATUHDAVtldtarr,SeeiitnL ftHhkqjm"Tw*c*eri Ht onnst. FedEx3Ds * A * jFaeCdfEcCxhLluYxiaehiijudUiL'.P.'isrty Cn-*iaa vte)jiii-LaErai i'x-jxt.lji 2Ca? Darrtnx-s gcMfc I cc l i-te ere i>Xm i r a i i:aa srtpf E tri FgdE?.|Ki:r-(i. I 1 I 1 [D*irvElc.Be.UH I S S __________ ( __________ bg I ! Cargo Aireraft rJy U1P ltii luIt BI--a--t-t-a-------------- Br m t bC i Aucl N*. er D m & G adjmHi.^itL, w . ----------------- AUutinLjtiJioF-u. j;ip.| | 71 SAbceec1inKdKixe-rri n't I Reoipierti Q nird Party |_ | CredrtCerd |^J CestvthecL Tal Packages Total W e^at Titel fa rfa ra ! y atu et Utel Q ig es 3 .K) i r LLrlJj r ,'is [ n l i d t ; SIDO - iI b - iI i diU siu i rigtar . Jje . Se. hdcH w dEG ii. C^JnCadAlh. B NEW Ke&i dentisi Delivery Signature Options h'i^rw-reiirfcijii. ctEEJind.H la-drwt No Signature r 3 0 5 6 1 .1 1 1 3f5ee-u/it4s.fe.-. jclRkl-eL' iqEitcL-tUti-lTaPrMercrhCT<i:f.JaHisEaetihmnaJifSV-D ADiir-e::c. t SrimgnneTtjre M^MlitnTLT. s-iiekp.i".oar-d.ef*-*ie(VY I ari c -^ HltU t, Ujh Sff .-- , ----- IitI.nlnjr]d;aedi filnihrarerxi-efii,c>'cstitMdteiSijESt*iiehiilkg:ji. n-taiaail itairusp;rV.eTH f" 5E0 | CASE NARRATIVE 34 STL Chicago Wet Chemistry Case Narrative Client: Weston - Confidential Decatur Job #: 244402 Date Rcc'd; 02/17/06 KThaihsnnMarreathtiovde.covers the analysis of the samples in the above Job # for TOC by the Lloyd The samples were analyzed for TOC in duplicate by furnace combustion and non-dispersive infrared detection on a Dohrmann Phoenix 8000 TOC analyzer, after acidification to remove inorganic carbon, and low-temp drying. No correction was made, therefore, for moisture content. The average of the sample bums is reported. 2. The method-recommended holding time of 2 weeks was met. Refer to the Laboratory Chronicle Page for dates of sampling, receipt, and analysis. 3. The TOC calibration curve and the initial and continuing verification standards and blanks met acceptance criteria. 4. The method blanks were less than the reporting limit. For tins test the ICB and method blank are the same. 5. The LCSs were within acceptance limits. 6. The matrix QC done on sample 244402-3 was ill control. Wet Chemistry Section Manager Date 35 RAW DATA km*** log /4 ^ (V2 2/21/06 7:25 TotaL Organic Carbon (Soils) Method Code.. : TOCS Batch Code.., : 173637 Status,,,.,. : RPT Batch Date.. : 02/20/06 Batch Time,. : 1247 User Name___ .. : cls QC Code..... TOCS c a le Code-- TOCS Location Code,,: 57222 Equipment Code.: T0C4 Import Code___ : TEST CODE TTTTTTTTTTTTT a 00000OCCC III c CC CCCC 5s SCCC 234AAA 2ASs s VVV V 2A 234 2 2 SAMPLE; Grp Pos Sample ID Dilution TEST pas Date / Time 1234567111222 789 12 11 ___ICALJ06ASTTC1A_ 0 12 ICV I06BSTTC2 2/20/06 1211 0 13 ___ MB_r 2/20/06 1215 0 14 ___LC5_IOOFSTLK3_ 2/20/06 1242 0 15 2 4 4 3 9 1 J _ S ___ 2/20/06 1308 0 16 244391J _ S ___ 2/20/06 1345 0 17 244391_3_S___ 2/20/06 1412 0 18 19 1 10 244391_3_S_MS_I06B5TTC2_7 244391_3_S_MSD_I06BSTTC2_7 244391_4_S___ 2/20/06 1439 2/20/06 1447 2/20/06 1453 M N 0 1 11 244391 J _ S _ _ 2/20/06 1531 0 1 12 244591 6 $ 2/20/06 1543 0 1 13 1 14 1 15 1 16 244402_1_S__ _ 244402_2_S___ CCV I06BSTTC2 ___CCB__ 2/20/06 1603 2/20/06 1635 2/20/06 1657 0 2/20/06 1700 0 0 0 Page 1 37 *** QC summary *** {V2 ) Total Organic Carbon (Soils) Method Code Batch Code. Status..... Tocs 173637 RPT Batch Date.. : 02/20/06 Batch Time.. : 1247 User Name... : els QC cede....... ; TOCS Calc Code..... : TODS Location Code.. : 57222 Grp Smp Sample ID Pos Test ResuLt Known Original 1 2 ___ICV_I06BSTTC2_ 1 TOC 1934.19 2000 1 3 ___MB__ 1 TOC -2.78 1 4 ___LCS_IOOFSTLK3_ 5 T0CAV2 4934.35 47S0 1 S 244391_3-_S_MS_I0BSTTC2__7 5 OCAV2 4196.99 2000 3094.23 1 9 244391_3_5_MSD_IQ6BSTTD2_7 5 TQCAV2 3742.96 2000 3094.23 1 15 ___CCV_106BSTTC2_ 1 TOC 2071.89 2000 1 16 ___CCB__ 1 TOC -4.14 Report Date: 2/21/06 7:25 Equipment Code.: T0C4 import code___ ; Alternate QC Res 97 F QC Res F 4196.99 103 34 21 104 N N 53 fr Page 1 OCi *** RAW TEST DATA *** CV2 > Total Organic Carbon (Soils) H&thod Code..; TOCS Batch Code,,T: 173637 Status...... : RVWD Batch Date... 02/20/06 Batch Time... 1247 User Name___ els SAMPLE: Grp Pos Sample ID 11 ICAL I0ASTTC1A 12 ICV I0BSTTC2 13 MB 14 LCS I0FSTLK3 1 5 244391 1 S 1 6 244391 2 S 1 7 244391 3 S 1 8 244391 3 S MS I06BSTTC2 7 1 9 244391 3 S MSD IQ6BSTTC2 7 1 10 244391 4 S 1 11 244391 5 S 1 12 244391 6 S 1 13 244402 1 S 1 14 244402 2 S 1 15 CCV I06BSTTC2 1 16 CCB QC Code....... : TOCS Calc C o d e . T O C S Location Code..: 57222 Di lut ion TOC mg/Kg T0C2 mg/Kg Report Date: 2/23/06 10:14 Equipment Code.: TQC4 Import Code___ : T0C3 mg/Kg TQC4 mg/Kg TOCAV2 mg/Kg 1934.19 "2.78 3461.80 5969.63 894.40 3399.62 4196.99 3742.96 1319.28 3951.47 4765.46 2685.19 1534.SI 2071.89 -4.14 6406. S3 2214.19 1797.83 2788,84 1608.50 2199.93 5644.63 2901.26 2456.06 4934.35 4091.91 1346.12 3094.23 4196.99 3742.96 1463.09 3075.70 5205.05 2793.22 1995.43 Page 1 39 *** RAW TEST DATA *** V2 Total Organic Carbon (Soils) Method Code.. : TOCS Batch Code... : 173637 Status...... : RVWD Batch Date., ; 02/20/06 Batch Time.. : 1247 User Name... : els SAMPLE: Grp Pos SampLe ID 11 ICAL I06ASTTC1A 12 ICV I06BSTTC2 13 MB 14 LCS I0DF5TLK3 1 5 244391 1 S 1 6 244391 2 S 17 18 19 244391 3 S 244391 3 S MS I06BSTTC2 7 244391 3 S MSD IO60STTC2 7 1 10 244391 4 S 1 11 244391 5 S 1 12 244391 6 S 1 13 244402 1 S 1 14 244402 2 S 1 15 CCV I0BSTTC2 1 16 ___CCB__ QC Coda....... Toes Calc Code..... : TOCS Location Code..: 57222 Dilution TDCAV3 mg/Kg TOCAV4 mg/Kg Report Date: 2/23/06 10:14 Equipment code.: TOC4 Import Code___ : TOCRl ug TOCR2 ug TOCR3 ug 96.7094 -0.4443 100.3945 244.7547 49.6393 178.8202 131.7855 122.7691 41.4253 59.6672 130.0971 81.0926 61.3924 103.5946 -0.621 176.8284 86.3535 93.4873 140,4379 60.3189 39.5987 142.2446 131.7174 102.4179 Page 2 *** RAW TEST DATA *** CV2 ) Total Organic Carbon (Soils) Method Code.. TOCS Batch Code 173637 Status.... RVUD Batch Date.,. : 02/20/06 Batch timo... : 1247 User Name___ : c U SAMPLE: Grp Pos Sample ID 11 ICAL I0ASTTC1A 12 ICV I06BSTTC2 13 MB 14 LCS 100FSTLK3 1 5 244391 1 S 1 6 244391 2 S 1 7 244391 3 S 1 S 244391 3 S MS 06BSTTC2 7 1 9 244391 3 S MSD I06BSTTC2 7 1 10 244391 4 S 1 11 244391 5 S 1 12 244391 6 S 1 13 244402 1 S 1 14 244402 2 S 1 15 CCV I0BSTTC2 1 16 CCS QC Code,,. TOCS Calc Code, *f : TOCS Location Code..: 57222 Dilution TOCR4 ug UT1 g Report Date: 2/23/06 10:14 Equipment Code.: OC4 Import Code.... : WT2 WT3 WT4 g99 0.05 0.16 0.0290 0.0410 0.0555 0.0526 0.0314 .032 0.0314 0.0151 0,0273 0.0302 0.04000 D .05 0.16 0.0276 0.0390 0.0520 0.0502 0.0375 0.01O 0.0252 0,0454 0.0417 Pago 3 d1 *** RAU TEST DATA *** Total Organic Carbon [Soils) Method Coda,. : t o c s Batch Code.. : 173637 Status...... : RVWD Batch Date... : 02/20/06 Batch Time..* : 1247 User Name.,.. : cls SAMPLE: Grp Pos Sample ID 1 1 12 13 14 15 16 17 13 19 1 10 1 11 1 12 1 13 1 14 1 15 1 16 ICAL I06ASTTC1A ICV I0BSTTC2 MB LCS IOOFSTLK3 244391 1 S 244391 2 S 244391 3 S 244391 3 S MS I0BSTC2 7 244391 3 S MSD I0BSTTC2 7 244391 4 S 244391 5 S 244391 6 S 244402 1 S 244402 2 S CCV I06BSTTC2 CCB QC Code... Tocs Calc Code. ___ : TOCS Location Code..: 57222 Di lutl'Oh DL FAC N/A TCS mg/Kg 3.2000 1.0000 5.6537 4.0000 2.9767 3.112S 5.0955 4.87Q0 4.6444 9.6677 6.0952 4.232S 3.9163 3.2000 1.0000 <V2 ) Report Date: 2/23/06 10:14 Equipment Code.: TOC4 Import Code,... : TCS2 mg/Kg TCSAV2 mg/Kg TCS mg/Kg Page A 42 Calibration Report Print Date/Time: 2006/02/21 7:12:46 Cal, Curve ID: SOILCURVE Created: 02/20/2006 12:00 Calibration Factor (m): 1,070e+05 Y Intercept (b): -296565 r-squared: 0.99773 Standard ID Y X Expected Measured Message Date & Raw Data ug C ug C Time 0 ugram C -2378 0.000 2.748 No Sample Det 02/20/2006 09:53 10ugramC 1395589 10.000 15.809 02/20/2006 10:07 20 ugram C 2153844 20.000 22.893 02/20/2006 10:23 40 ugram C 4050968 40.000 40.617 02/20/2006 10:38 80 ugram C 7850154 80.000 76.111 02/20/2006 11:14 120 ugram C 12399791 120.000 118.615 02/20/2006 11:24 200 ugram C 19561260 200.000 185,521 02/20/2006 11:34 300 ugram C 31645466 300.000 298.418 02/20/2006 11:43 400 ugram C 43510584 400.000 409.268 02/20/2006 11:54 Multiple Analysis Report Print Date/Time: 2006/02/21 7:16:51 Sample ID Result Std. Dev. RSD Mode ALT 0 ugram C -2378 TC 1OugramC 1395589 TC 20 ugram C 2153844 TC 40 ugram C........... ............ 4050969... .......... TC 80 ugram C 7850154 TC 120 ugram C 12399791 TC 200 ugram C........ ............... 19561260... ...........TC 300 ugram C 31645464 TC 400 ugram C 43510584 TC ICV......................... ....... 96.7094.............. ...TC .. ICB-MB -0.4443 TC ICB-MB 186.4889 TC LCS........................ ....... 100.3945............. ...TC .. LCS 2.0672 TC LCS 176.8284 TC 244391-1............... ........... 244.7547... .. ...TC 244391-1 86.3535 TC 244391-2 49.6393 TC 244391-2............... ........... 93.4873... , ...TC 244391-3 178.8202 TC 244391-3 140.4379 TC 244391-3ms.......... .............. 418.5937... ...........TC 244391-3ms 131.7855 TC 244391-3msd 122.7691 TC 244391-3msd........ ............... 41.4253... .......... TC 244391-4 60.3189 TC 244391-5 407.0427 TC 244391-5............... ........... 567.1361... .......... TC 244391-5 59.6672 TC 244391-5 39.5987 TC 244391-6............... ........... 130.0971... ...........TC 244391-6 142.2446 TC 244402-1 81.0926 TC 244402-1............... ........... 1317174... 244402-2 61.3924 ...........TC TC 244402-2 102.4179 TC CCV...................... ........ 103.5946............. ...TC .. CCB -0.6621 TC Detailed Analysis Report Print Date/Time: 2006/02/21 7:17:10 Sample ID: 0 ugram C Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02200950 Timestamp: 02/20/2006 09:53 Sample Type: TC Standard Rep# 1 ppm C ug C Raw Data Beginning Ending Baseline Baseline Time -2378 4.805 4.785 120 Integration Last Message: No Sample Detected Sample ID: 10ugramC Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename; 02201003 Timestamp: 02/20/2006 10;07 Sample Type: TC Standard Rep # 1 ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 1395589 4.627 5.624 234 Integration Sample ID: 20 ugram C Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201018 Timestamp: 02/20/200610:23 Sample Type: TC Standard Rep# 1 ppmC u g C Raw Data Beginning Ending Baseline Baseline Time 2153844 4.641 5.641 253 Integration Sample ID: 40 ugram C Method: boat Cal. Curve; SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201032 Timestamp: 02/20/2006 10:38 Sample Type: TC Standard Rep # 1 ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 4050969 4.661 5.661 296 Integration Sample ID: 80 ugram C Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201106 Timestamp: 02/20/2006 11:14 Sample Type: TC Standard R ep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 7850154 4.704 5.702 343 Sample ID: 120 ugram C Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201118 Timestamp: 02/20/2006 11:24 Sample Type: TC Standard Rep# 1 ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 12399791 4.949 5.948 339 Integration Sample ID: 200 ugram C Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode; TC Filename: 02201128 Timestamp; 02/20/2006 11:34 Sample Type: TC Standard Rep # 1 ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 19561260 7.991 B.989 274 Integration Sample ID: 300 ugram C Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201136 Timestamp; 02/20/2006 11 ;43 Sample Type: TC Standard Rep # 1 ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 31645464 5.171 6.169 347 Integration Sample ID: 400 ugram C Method: boat Cal. Curve: SOILCURVE Operator ID; CAROL Mode: TC Filename: 02201146 Timestamp: 02/20/2006 11 ;54 Sample Type: TC Standard Rep # 1 ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 43510584 5.316 6.313 443 Integration Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201205 / ------ ) \ Timestamp: 02/20/200612:11 ) Sample Type: Cal. V e rific a tio iL --^ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 96.7094 96.7094 10055008 4.872 5.872 353 Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201212 Timestamp: O2/2O/2O06 12:16 Sample Type: Sample \ 1 / R ep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.4443 -0.4443 -21793 5.603 5.250 120 Last Message: No Sample Detected Sample ID Method: Cal. Curve Operator ID: CAROL Rep # ppm 1 186.4889 Mode: TC Filename: 02201224 iQ lf Timestamp: 02/20/2006 12:31 Sample Type: Sample Data Beginning Ending Integration Baseline Time 52 5.001 6.001 309 Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201237 Timestamp: 02/20/2009 12:42 Sample Type: Sample R ep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 100.3945 100.3945 10771782 5.110 6.109 274 Sample ID: LCS \ ,S 10^ M de: TC Method: boat \ C /i Filename: 02201244 Cal. Curve: SOILCURVE Timestamp: 02/20/2006 12:47 Operator ID: CAROL \ Sample Type: Sample Rep # ppm C ug C (Raw Data Beginning Ending Integration Baseline Baseline Time 1 2.0672 2.0672 247034 5.157 6.153 104 Sample ID: LCS Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201250 Timestamp: 02/20/2006 12:56 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time R ep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 39.5987 39.5987 4264325 5.834 6.832 267 Sample ID: 24^391-6 Method: t Cal. Curve: SOILCURVE Operator ID: CAR Mode: TC Filename: 02201538 JTimestamp: 02/20/200^15:43) Sample Type: Sample l Rep # ppm C u ^ C Raw Data Beginning Ending Integration Baseline Baseline Time 1 130.0971 130.09X1 13951089 5.988 6.985 284 Sample ID: 244391-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201548 Timestamp: 02/20/2006 15:57 Sample Type: Sample Rep # ppm C ug C Raw D^ita Beginning Ending integration BaselineV Baseline Time 1 142.2446 142.2446 15251326 5.066 6.056 472 Sample ID: 244402-1 Method: boat Gal. Curve: SOILCURVE Operator ID: CAROL )de: TC Filename: 02201S57 / "" lestamp: 02/20/2006 16:03 Sample Type: Sample Rep # ppm C ug C ion 1 81.0926 81.0926 Raw Data Beginnipg Ending Integrat Baseline Baseline \hm e 8705746 5.676 6*672 293 Sample ID: 244402-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201621 Timestamp: 02/2^/2006 16:27 Sample Type: Sampl Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 131.7174 131.7174 14124518 5.271 6.271 310 Sample ID: 244402-2 Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201629 Timestamp: 02/20/20Q6 16:35 Sample Type: Sample 48 Rep # ppm C ug C Raw Data Beginning Ending integration Baseline Baseline Time 1 61.3924 61.3924 6597079 5.082 6.080 278 Sample ID: 244402-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201639 Timestamp: 02/20/2006 16:48 Sample Type: Sample R ep# pjjm C ugC Raw Data Beginning Ending Integration Baseline Baseline Time 1 102.4179 102.4179 10988363 5.029 6.027 467 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201648 Timestamp: 02/20/200616:57 Sample Type: Cal. Verificat Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 103.5946 103.5946 10791989 7.054 8.488 480 Last Message: Endpoint Timeout Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02201657 Timestamp: 02/20/2006 17:00 Sample Type: Sample v / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.6621 -0.6621 -45107 8.165 7.528 120 Last Message: No Sample Detected STL Chicago Page No.:._ TOC in Soils Book No.: Method: Lloyd Kahn Instrument; Phoenix 8000 (TQ4) LabNet Batch:___ Calculations: Date of Standard Curve;___ TOC (mg/kg) = ug C /grams sample Book# T v T-'Fage # MS, MSD Known Cone, (mg/kg) = 100 ug C / grams sample MS, MSD Observed (mg/kg) = ug C / grams sample MS, MSD Rec. = fobserved mq/ka - ava. sample result fmg/kq)! x 100 known concentration in mg/kg Standard Traceability: (Note: Working Standards are prepared daily from the noted Stack Solutions.) Stock I (Curve) T O / A T T V L / Stock II (ICV/CCV) T olio/S S'7 r o 7 LCS Source ID TCXtfS'ILjC^ [_CS True Value V Acceptance Range S 3 - / 7T v _____ Sample ID: Sample Weight (g) ugC Comments: n9 io r /o H O ncS / T9 oO' G GO ./ Os 17 v-7f 3-2. f ? !, l/7 <--<0 _ l , tt 0 H T, Cf C.& rr Y C7' T" y = ~0Ai0OGC~ 'J-i <2-0 o /O O / Y'9 91/ 1> O o hod T /90 D~<y C7 X /f, W f i/c i, 2- -X C d T^T0V--- /tA? - MT ^- _ i 0 ^LC S-- 0 , < ---O/XG.. cf''/1GXr 7U-.T ,, r.:) o d fO - A r - t f 7 C,---- 9-. -o, c/?y 07 V yj i/Vi O / o, / 5 ?o Cr<f1-- C O S 0L/7W'e r "^i... 2//.CX:/C- " ' ... 2 x 1L1-0C-S1 0 . o X i G ( 1, {' A 7 O .O H / 0 0000,7907 i ~ / O - 9 9 0 OC- I O'- O 9 f S' 9 1 /,:2 /7 -- I - x o ,o 0 .o sxO d fII. -- ^ -Z~7kT g o. ~cr s o ve < 0 Zt t i :) ri Y F 7 9 r?/c ?i .p '/O r j 7 f \ / \' OX . T-1, ( OAA'- A> u l< Y 7 r sn>l~ Prep Analyst;^ :**?- Date: ^ A n a lv s t r " ^ - - - ^ - - - / ^ .. Date: tg ^ / x & / o G Reviewed by:_ 9 Date: J O o / T STL Chicago Page No.:_ 4-4- TOC in Soils Method: Lloyd Kahn V) Book No.: Instrument: Phoenix 800Q fTQC4) LabNet Batch:______________ Calculations: TOC (mg/kg) = ug C / grams sample Date of Standard Curve;__ Book # _________Page #_ MS, MSD Known Cone. (mg/Kg) = 100 ug C / grams sample MS, MSD Observed (mg/kg) *= ug C / grams sample * * * RUN LOG *** H2 <V2 ) 2/27/06 12:54 Total Organic Carbon (Soils) Method Code..: TOCS Batch Code.. .: 173739 RtiitLJF...... : RVWD Batch Date.. : 02/21/06 Batch Time,, 1048 uetr Name..... : els QC Code...... , : TOCS Calc Code..,... : TOCS Location Code..: 57222 Equipment Cede.: TOC4 Import Code, TEST CODE T TTTTTT TTTT TT 0 000OO0 CCC I I I c c c Cc c C SSSCCC 23 4AAA 2A SS s VV V V 2A 234 2 2 SAMPLE: Grp Pos Sample ID 11 ___ICAL_I06ASTTC1_ Di Lution TEST PDS Date / Time 1234567 111222 7 290 12 0000 0 12 13 14 15 16 ___ 1CV_I06BSTTC2_ ___ MB__ ___ L C S J Q Q F S T L K 3 _ 244402_3_S___ 244402_3_S_MS_I06BSTTC2 _5 2/21/06 0854 0 2/21/06 0858 0 2/21/06 0907 2/21/06 0937 2/21/06 1000 0 0 0 17 244402_3_SJ i S D J 06BSTTC2_5 2/21/D 1017 0 18 244402 4 5 2/21/06 1028 0 19 244402_5_S___ 2/21/06 1110 0 1 10 244402_6_S___ 2/21/06 1147 0 1 11 244402^7^3___ 2/21/06 1159 0 1 12 244402 S S 2/21/06 1211 0 1 13 2444Q2_9_S___ 2/21/06 1223 0 1 14 244402_1D_S___ 2/21/06 1236 D 1 15 244402J I S ___ 2/21/06 1257 0 1 16 2444Q2_12_S___ 2/21/06 1308 0 1 17 1 18 244402_13_S___ 244402_14_S:__ 2/21/06 1320 2/21/06 1332 0 0 1 19 244402J 5 _ S ___ 2/21/06 1344 0 1 20 ___CCV_l06B5TTC2_ 2/21/06 1413 0 1 21 1 22 ___ CCB__ 244402_16_S___ 2/21/06 1417 0 2/21/06 1423 0 1 23 1 24 244402_17_S___ 244402_18_S___ 2/21/06 1435 2/21/06 1448 0 0 1 25 244402_19_S___ 2/21/06 1501 0 1 26 2 4 4 4 0 2 _ 2 0 ^ S _ 2/21/06 1514 0 1 27 ___CCVJ06B5TTC2_ 2/21/06 1530 0 1 28 ___CCB__ 2/21/06 1535 0 Page 1 52 *** QC Summary *** (V2 ) Total Organic carbon (Soils) Method Code..: ro c s Batch Codo... : 173739 Status...... : RVUt) Batch Date.., 02/21/06 Batch Timo.,:.: 1048 User Name___ .; cLs QC Code.... f+. : TOCS Calc Code,,,,., : TOCS Location Code., : 57222 Grp Smp Sample id POS Test Result Known Original 1 2 ,__ ICVJ06BSTTC2_ 1 TOC 1841.56 2000 1 3 ___MB__ 1 TOC -2.90 14 LCS I00FSTLK3 5 T0CAV2 4163.33 4780 1 6 244402_3_S_MS_106BSTTC2_5 5 T0CAV2 2327.83 2000 800.82 1 7 244402_3^SJ1SDJ06BSTTC2_5 5 TOCAV2 2319.92 2000 800.82 1 20 ___CCV_I06BSTTC2_ 1 TOC 20ia,17 2000 1 21 ___CCB__ 1 TOC 0.85 1 27 ___CCV_I06BSTTC2_ 1 28 CCB 1 TOC 1 TOC 2H9.S6 -2.19 2000 Report Date: 2/37/06 12:54 Equipment Code,: TOC4 import Code...,: Alternate QC Res 92 F QC Res F 2327.83 87 82 88 101 0 106 Page 1 *** RAW TEST DATA *** CV2 ) Total Organic carbon (Soils) Method Code.. TOCS Batch Code... 173739 Status--- --- RVWD Batch Date...: 02/21/06 Batch Time...: 1048 User Name___ : els SAMPLE: Grp Pos Sample ID 11 12 13 14 15 16 17 18 19 1 10 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 18 1 19 1 20 1 21 1 22 1 23 1 24 1 25 1 26 1 27 1 28 ICAL I06ASTTC1 ICV 106BSTTC2 MB LCS I00FSTLK3 244402 3 S 244402 3 S MS J06BSTTC2 5 244402 3 S MSD 106BSTTC2 5 244402 4 S 244402 5 S 244402 6 S 244402 7 $ 244402 8 S 244402 9 $ 244402 10 S 244402 11 S 244402 12 S 244402 13 S 244402 14 S 244402 15 S CCV 106BSTTC2 CCB 244402 16 S 244402 17 S 244402 18 S 244402 19 S 244402 20 S CCV I0BSTTC2 ___ CCB__ QC Code.*. ___ : TOCS Calc Code*. ___ : t o c s Location Code**; 57222 Di lut ion TOC mg/Kg 0C2 mg/Kg Report Date: 2/27/06 12:54 Equipment Code.: T0C4 Import Code.... : TC3 mg/Kg T0C4 mg/Kg T0CAV2 mg/Kg 1841.56 -2.90 4489.71 880.69 2327.83 2319.92 1085.65 1897.31 2199.54 2725.82 1183.13 15B9.25 1039*18 1043.80 2240.02 996.22 838.96 793.97 2018.17 0.85 1206.54 1315.29 4898.51 1745.44 1959.03 2119.86 -2.19 3836.95 720.95 1442.04 2125.58 2201.G7 3036.04 975.46 1308.92 934*34 1080.67 2437.22 971.10 784,23 728.91 1400.88 1815.35 5240.12 1834.07 2143.99 4163.33 800.82 2327.83 2319.92 1263.35 2011.44 2200.70 2880-93 1079.30 1449,09 986.76 1062.23 2338.62 983.66 811.60 761*44 1303.71 1565.32 5069.32 1789.76 2051.51 Page 1 :1 54 ++* RAW TEST DATA *** CV2 ) Total Organic Carbon (soiLs) Method code..; TOCS Batch Code... : 173739 Status...... : RVWO Batch Date.. : 02/21/06 Batch Time.. : 104 User Name... : els SAMPLE: Grp Pos Sample ID 11 1CAL I06ASTTC1 12 ICV I06BSTTC2 13 MB 14 LCS I0OF5TLK3 1 5 244402 3 S 1 6 244402 3 S MS I06BSTTC2 5 1 7 244402 3 S MSD I06BSTTC2 5 1 8 244402 4 S 1 9 244402 5 s 1 10 244402 6 S 1 11 244402 7 S 1 12 244402 8 S 1 13 244402 9 S 1 14 244402 10 S 1 15 244402 11 S 1 16 244402 12 S 1 17 244402 13 S 1 18 244402 14 S 1 19 244402 15 S 1 20 CCV I06BSTTC2 1 21 CCB 1 22 244402 16 S 1 23 244402 17 S 1 24 244402 18 S 1 25 244402 19 S 1 26 244402 20 S 1 27 CCV I0BSTTC2 1 28 CCB C code.,,...,. : TOCS Calc Code..... : TOCS Location Code.. : 57222 Dilution T0CAV3 mg/Kg TDCAV4 mg/Kg Report Date: 2/27/06 12:54 Equipment Code.: TOCA import Code-- : TQCR1 ug TCR2 ug T0CR3 ug 92.07775 -0.4637 136.0383 44.9154 124.0731 134.7876 68.2871 87.8453 99.8590 124.5700 57.3817 80.2573 49.7766 48.6413 107.9688 47.2208 43.2063 41.2070 100.9086 0.1355 59.7239 65,1070 222.8824 84.4791 89,5278 105.993 -0.3496 109.7368 39.4361 81.6192 94.3759 101.2862 144.5157 43.9682 63.6137 48,9594 50.1432 115.0370 49.0407 35.9962 33.0924 67.5226 78.6046 242.6177 89.1357 102.9115 Page 2 55 *** RAW TEST DATA <V2 ) Total Organic Carbon (Soils) Method Code., : TOCS Batch Code... : 173739 Status...... : RVUD Batch Date.., 02/21/06 Batch Time... 1048 User Name___ ,: cls SAMPLE: Grp Pos Sample ID 11 ICAL I0ASTTC1 12 ICV I6BSTTC2 13 MB 14 15 LCS I00FSTLK3 244402 3 S 1 6 244402 3 S MS I6BSTTC2 5 1 7 244402 3 S MSD I0BSTTC2 5 1 8 244402 4 S 1 9 244402 5 S 1 10 244402 6 S 1 n 244402 7 S 1 12 244402 B S 1 13 244402 9 S 1 14 244402 10 S 1 15 244402 11 S 1 16 244402 12 S 1 17 244402 13 S 1 IB 244402 14 S 1 19 2444D2 15 S 1 20 CCV IQBSTTC2 1 21 CCB 1 22 244402 16 S 1 23 244402 17 S 1 24 244402 1B S 1 25 244402 19 S 1 26 244402 20 S 1 27 CCV I06BSTTC2 1 2B CCB OC Code,....., : TOCS Cale Code..... : TOCS Location Code..: 57222 Dilution T0CR4 ug WT1 g Report Date; 2/27/06 12:54 Equipment Code.: QC4 Import Code___ : UT 2 WT3 WT4 ggg 0.05 0.16 0.0303 0.0510 0.0533 0.0581 0.0629 0.0463 0.0454 0.0457 0.0485 0.0505 0.0479 0.0466 0.0482 0.0474 0.0515 0.0519 0.05 0.16 0.0495 0.0495 0.0455 0.0484 0*0457 0.05 0.16 0.0286 0.0547 0.0566 0.0444 0.0460 0.0476 0.0502 0.0486 0.0524 0*0464 0.0472 0.0505 0.0459 0.0454 0.0482 0.0433 0.0463 0.0486 0*0480 Page 3 *** RAU TEST DATA *** (V2 ) Total Organic Carbon (Soils) Method Code..; TOCS Batch Code...: 173739 Status....... : RVWD Batch Date...: 02/21/06 Batch Time...: 1048 deer Name :els SAMPLE: Grp Poa Sample ID 11 ICAL IQ6ASTC1 1 2 ___ICV_I06BSTTC2_ 1 3 ___MB__ 1 4 ___LCS IQQFSTLK3_ 1 5 244402j S___ 1 6 244402 3_ S MS_I06BSTTC2_5 1 7 2 4 4 4 0 2 " 3 S D I06BSTTC2 5 1 8 244402 4 S___ " 1 9 244402"s" s___ 1 10 244402 6 S 1 11 244402_7_S___ 1 12 244402 8 S___ 1 13 244402~iTs___ 1 14 244402- 10 S___ 1 15 244402j T s ___ 1 16 244402 12 5___ 1 17 244402"13^S___ 1 18 244402J 4 _ S___ 1 19 244402 15^S___ 1 20 ___CC\M06BSTTC2_ 1 21 CCB~ 1 22 244402_16_S___ 1 23 2 4 4 4 Q 2 J 7 S ___ 1 24 244402_13_S___ 1 25 244402_19_S___ 1 26 244402 20_s___ 1 27 ___ CCVJ06BSTTC2 1 28 CCB QC Cade........ : TOCS Calc Code..---- : TOCS Location Code..: 57222 Dilution DLFAC N/A TCS mg/Kg Report Date: 2/27/06 12:54 Equipment Code.: T0C4 Import Code--- : TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg 3.2000 1.0000 5.4329 3.0274 3.0019 2,7539 2.6778 3.5281 3.5011 3.4298 3.2421 3.2291 3.1904 3.4409 3.3543 3.2686 3,2854 3.2888 3.2000 1.0000 3.2753 3.4483 3.4858 3.2990 3.4152 31..02000000 Page 4 57 Calibration Report Print Date/Time: 2006/02/22 7:30:37 Cal. Curve ID: SOILCURVE Created: 02/20/2006 12:00 Calibration Factor (m); 1.070e+05 Y Intercept (b): ^-296565 r-squared: 0,99773 Standard ID Y X Expected Measured Message Date & Raw Data ug C ug C Time 0 ugram C -2378 0.000 2.748 No Sample Det 02/20/2006 09:53 10ugramC 1395589 10,000 15.809 02/20/2006 10:07 20 ugram C 2153844 20.000 22.893 02/20/2006 10:23 40 ugram C 4050968 40.000 40.617 02/20/2006 10:38 30 ugram C 7850154 80.000 76.111 02/20/2006 11:14 120 ugram C 12399791 120.000 118.615 02/20/200611:24 200 ugram C 19561260 200.000 185.521 02/20/200611:34 300 ugram C 31645466 300.000 298.418 02/20/200611:43 400 ugram C 43510584 400.000 409.268 02/20/2006 11:54 Multiple Analysis Report Print Date/Time: 2006/02/22 7:48:29 Sample ID Result Std. Dev. RSD Mode ICV 92.0775 TC ICB-MB -0.4637 TO LCS 136.0383 TC LCS.............................. ,,109.7368... .......... TC .. 244402-3 44.9154 TC 244402-3 39.4361 TC 244402-3ms................. .......124.0731... .......... TC .. 244402-3msd 134.7876 TC 244402-4 68.2871 TC 244402-4...................... .... 81.6192... .......... TC .. 244402-5 87.8453 TC 244402-5 94.3759 TC 244402-6...................... .... -0.1723... .......... TC 244402-6 -42.1698 TC 244402-6 99.8590 TC 244402-6...................... ....101.2862... .......... TC ,, 244402-7 124.5700 TC 244402-7 144.5157 TC 244402-8.................... .... 57.3187... .......... TC .. 244402-8 48.9682 TC 244402-9 80.2573 TC 244402-9...................... .... 63.6137... .......... TC .. 244402-10 49.7766 TC 244402-10 48,9594 TC 244402-11.................... ..... -0.2235... .......... TC ,, 244402-11 -0.0144 TC 244402-11 48.6413 TC 244402-11.................... ..... 50.1432... .......... TC .. 244402-12 107.9688 TC 244402-12 115.0370 TC 244402-13.................... ..... 47,2208... .......... TC ,, 244402-13 49.0407 TC 244402-14 43.2063 TC 244402-14.................... ..... 35.9962... ...........TC .. 244402-15 41.2070 TC ccc24ccc4vvv4.0.2.-.1..5................ 33.0924 ,,123,2396... 82.4007 100.9086 TC .......... TC .. TC TC CCB................................ ... 0.1355............ . 244402-16 59.7239 244402-16 67.5226 ...TC ,, TC TC 244402-17.......................... 65.1070,,, ...........TC .. 244402-17 78.6046 244402-17 222.8824 244402-18................... ..... 242.6177... TC TC .......... TC 244402-19 84.4791 TC 244402-19 89.1357 TC 244402-20.......................... 89.5278... .......... TC ,, 244402-20 102.9115 TC CCV 105.9938 TC CCB.............................. .. -0.3496............ . ...TC .. Detailed Analysis Report Print Date/Time: 2006/02/22 7:48:41 Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02210848 Timestamp. 02/21/2006(08:54 Sample Type: Cai. Verificati Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 92.0775 92.0775 9559222 5.202 6.202 350 Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02210855 Timestamp: 02/21/206 08:58 Sample Type: Sample l Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.4637 -0,4637 23868 5.720 5,414 120 Last Message: No Sample Detected Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02210900 Timestamp: 02/21/200i Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 136.0383 136.0383 14587020 4,988 5.987 297 Sample ID: LCS Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02210912 Timestamp: 02/21/2006 09:21 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 109.7368 109.7368 11771762 5.162 6.162 293 Sample ID: 244402-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02210932 / Timestamp: 02/21/2006 09:37 Sample Type: Sample ( \ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 60 1 44.9154 44.9154 4833415 4.749 5.748 266 Sample ID: 244402-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02210938 Timestamp: 02/21/2006 09:43 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 39.4361 39.4361 4246920 5.257 6.257 248 Sample ID: 244402-3ms Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC --. Filename: 02210950 f Timestamp: 02/21/2006 10:00; Sample Type: Sample V . Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 124.0731 124.0731 13306288 5.226 6.226 383 Sample ID: 244402-3msd Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC _ Filename: 02211010 Timestamp: 02/21/2006 10:17 Sample Type: Sample ( R ep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 134.7876 134.7876 14453154 5.388 6.387 370 Sample ID: 244402-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211023 Timestamp: 02/21/21 I6 10:28 Sample Type: Sample R ep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 68.2871 68.2871 7335079 5.839 6.838 245 Sample ID: 244402-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211052 Timestamp: 02/21/2006 10:58 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 81.6192 81.6192 8762112 4.847 5.845 301 Sample ID: 244402-5 Mode: TC Method: boat Filename: 02211105 Cal. Curve: SOILCURVE Timestamp: 02/21/2100611:10 Operator ID: CAROL Sample Type: Sample 1 y Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 87.8453 87.8453 9428546 5.902 6.899 249 Sample ID: 244402-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211117 Timestamp: 02/21/2006 11:23 Sample Type: Sample Rep# p pm C ugC Raw Data Beginning Ending Integration Baseline Baseline Time 1 94.3759 94.3759 10127563 5.319 6.319 287 Sample ID: 244402-6 Mode: TC Method: boat Cal. Curve: SOILCURVE Q Filename: 02211128 < (j Timestamp: 02/21/2006 11:31 Operator ID: CAROL p , V) u t JO Sample Type; Sample Rep# ppm C \jgC 1 -0.1723 -0.17^3 Raw Data Beginning Ending Integration Baseline Baseline Time 7322 4.878 5.424 120 Last Message: No Sample Detected Sample ID: 244402-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Jl 0M J iV) L (\) * Mode: TC Filename: 02211135 Timestamp: 02/21/2006 11:38 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration BaselineX Baseline Time 1 -42.1698 -42.1698 -4488006' 97,628 98.482 135 Sample ID: 244402-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211142 ( Timestamp: 02/21/2006 il:4 7 Sample Type: Sample 1 Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 99.8590 99,8590 10714465 5.721 6.716 276 Sample ID: 244402-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211148 Timestamp: 02/21/2006 11.53 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 101.2862 101.2862 10867230 5.068 6.044 294 Sample ID: 244402-7 Method: boat 02211154 Cal. Curve: SOILCURVE Operator ID: CAROL Mode: Filename: TC Timestamp: 02/21 /2O(06 11:5 Sample Type: Sample R ep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 124.5700 124,5700 13359481 6,186 7.133 211 Sample ID: 244402-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211159 Timestamp: 02/21/2006 12:04 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 1 144.5157 144.5157 15494429 9.195 10.191 Integration 251 Sample ID: 244402-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211206 Timestam p: 02/21/20 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 57.3187 57.3187 6161036 6,037 7.036 253 Sample ID: 244402-8 Method: boat Cal. Curve; SOILCURVE Operator ID: CAROL Mode; TC Filename: 02211212 Timestamp: 02/21/2006 12:16 Sample Type: Sample Rep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 48.9682 48.9682 5267224 6.252 7.252 240 Sample ID: 244402-9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC ^ ----- - Filename: 02211218 / Timestamp: 02/21/2006 12:23 Sample Type: Sample l Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 80.2573 80.2573 8616336 5.193 6.191 283 Sample ID: 244402-9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211224 Timestamp: 02/21/2006 12:30 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 63.6137 63.6137 6834843 5.535 6.534 270 Sample ID: 244402-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211231 Timestamp: 02/21/201 Sample Type: Sample 12:36. Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 49.7766 49.7766 5353745 5.383 6.361 246 Sample ID: 244402-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211238 Timestamp: 02/21/2006 12:44 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 48.9594 48.9594 5266275 5.243 6.242 256 \ >O, r Sample ID: 2 4 4 4 0 2 -1 1 ^/ k ? Mode: TC Method: boat \ /)A Filename: 02211245 Cal. Curve: SOILCURVE Timestamp: 02/21/2006 12:48 Operator ID: CAROL \ Sample Type: Sample R ep# ppm C ug c \ Raw Data Beginning Ending Integration \Baseline Baseline Time 1 -0.2235 -0.2235 \l8 4 4 4.978 5.022 120 ZLast Message: No Sample Detected Sample ID: 244402-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC 72 Filename: 02211250 Timestamp: 02/21/2006 12:51 Sample Type: Sample R ep# ppm C ug C Rafy Data Beginning Ending Integration dine Baseline Time 1 -0.0144 -0.0144 24220 86.995 87.911 8 Sample ID: 244402-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC ___ ... Filename: 02211252 / Timestamp: 02/21/2006 12:57 Sample Type: Sample V ^ R ep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 48.6413 48.6413 5232232 6.978 7.968 219 Sample ID: 244402-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211257 Timestamp: 02/21/2006 13:02 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 50.1432 50.1432 5392992 5.662 6.660 250 Sample ID: 244402-12 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211303 ^ ----- ^ JTimestamp: 02/21/2006 13:08 \ Sample Type: Sample l Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 107.9688 107.9688 11582517 5.568 6.565 263 Sample ID: 244402-12 Method: boat Cal. Curve; SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211309 Timestamp: 02/21/2006 13:14 Sample Type: Sample Rep# ppmC ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 115.0370 115.0370 12339082 5,499 6.497 291 Sample ID: 244402-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC s' Filename: 02211315 f Timestamp: 02/21/200 13:20 Sample Type: Sample \ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 47.2208 47.2208 5080178 6.006 7.006 232 Sample ID: 244402-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211321 Timestamp: 02/21/2006 13:26 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 49.0407 49.0407 5274984 5.218 6.217 243 Sample ID: 244402-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211327 v Timestamp: 02/21/200613:32 \ Sample Type: Sample ) R ep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 43.2063 43.2063 4650476 5.195 6.190 241 Sample ID: 244402-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211332 Timestamp: 02/21/2006 13:37 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 35.9962 35.9962 3878723 5.375 6.373 244 Sample ID: 244402-15 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211340 / Timestamp: 02/21/2006 13:44 Sample Type: Sample ( ^ Rep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 66 1 41.2070 41.2070 4436476 5.941 6.937 178 Sample ID: 244402-15 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode. TC Filename: 02211345 Timestamp: 02/21/2006 13:49 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 33.0924 33.0924 3567910 5.273 6.273 234 Sample ID: 0^ V Method: boa V S Cal. Curve: urvT \ Operator ID: CAR ry Mode: TC Filename: 02211353 Timestamp: 02/21/2006 Sample Type: Sample l Rep # ppm C Raw Data Beginning Ending Integration Baseline Baseline Time 1 123.2396 123.2396 13217080 5.409 6.409 290 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL ^ "M o d Filename: Timestamp: Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 1 82.4007 82.4007 8845769 5.492 6.490 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC . Filename: 02211408 Timestamp: 02/21/2006 14:13 Sample Type: Sample ( Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 100.9086 100,9086 10826813 5.724 6.719 288 Sample ID: CCB Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211414 Timestamp: 02/21/20 Sample Type: Sample R ep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.1355 0.1355 40264 5,258 6,353 120 Last Message: No Sample Detected Sample ID: 244402-16 Method: boat CaL Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211419 / Timestamp: 02/21/2006 14:23 Sample Type: Sample ^ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 597239 597239 6418488 6.375 7.369 247 Sample ID: 244402-16 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211424 Timestamp: 02/21/2006 14:30 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 67.5226 67.5226 7253244 5.342 6.338 269 Sample ID: 244402-17 Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC ^ ------- Filename: 02211430 / \ Timestamp: 02/21/2006 14:35/ Sample Type: Sample i J R ep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 65.1070 65.1070 6994684 5.343 6.341 273 Sample ID: 244402-17 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211436 Timestamp: 02/21/2006 14:41 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 78.6046 78.6046 8439439 5.535 6.531 267 Sample ID: 2 4 4 4 0 2 ^ ^ ^ 5 ^ Method: boat Cal. Curve; SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211442 Timestamp: 02/21/2006 14:48 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 68 1 222.8824 222.8824 23882632 5.302 6.299 317 Sample ID: 244402-18 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211449 Timestamp: 02/21/2006 14:56 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 242.6177 242.6177 25995060 5.552 6.552 364 Sample ID: 244402-19 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211456 ------ ^ Timestamp: 02/21/2006 15:01 Sample Type: Sample l , Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 84,4791 84,4791 9068231 5.835 6,833 268 Sample ID: 244402-19 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211503 Timestamp: 02/21/2006 15:08 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 89.1357 89.1357 9566663 5.254 6.252 289 Sample ID: 244402-20 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211509 Timestamp: 02/21/2 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 89.5278 89.5278 9608640 5.589 6.588 272 Sample ID: 244402-20 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211515 Timestamp: 02/21/2006 15:21 Sample Type: Sample Rep # ppm C ug C Raw Data B eginning Ending Integration Baseline Baseline Time 1 102.9115 102.9115 11041193 5.570 6.569 304 Sample ID: CCV Method: boat Cal. Curve; SOILCURVE Operator ID: CAROL Mode: TC Filename: 02211523 Timestamp: 02/21/200615:30 Sample Type: Cal. Verification R ep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 105.9938 105.9938 11048793 5,341 6.339 382 Sample ID: COB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC - Filename: 02211532 f Timestamp: 02/21/2006 15:35 Sample Type: Sample V Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3496 -0.3496 -11657 5*786 5.623 120 Last Message: No Sample Detected STL Chicago TOC in Soils 73 f Page No. Book No.: 3 4 .S Method: Lloyd Kahn Instrument: Phoenix BQOO ( T Q C 4 LabNet Batch:, Calculations: Date of Standard Curve: TOC (mg/kg) = ug C / grams sample Book # 1 7 * 7 /' Page # MS, MSD Known Cone, (mg/kg) ~ 100 ug C / grams sample MS, MSD Observed (mg/kg) = ug C / grams sample MS, MSD Rec, = [observed ma/ka - ava. sample result fmg/kg)] x 100 known concentration in mg/kg 3 Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve\T / , < rrc ( A ' Stock II (ICV/CCV) tot,K<?7 rz LCS Source ID S oo ^ s !C\LCS True Value C> Acceptance Range S'}-/fyer*.______ Sample ID: roA/ 'tO-Ditb ' CT Los Sample Weight (g) 7 c T C O. I-.C O. .030 3 ' 0 - 02*0 ugC 9 2,our -Om J30,639? Comments: Qs{/ i ltCOr A O CKJO.. 77, T/sk 1 "7 0 . os'll 39. 73 C / 7> ^ ^ O-ovS? /7 y,7/ / '23217.9? /%?n\m-` J n . o s i / no,i7i0 ion 0 1 im'. n km - y " 0 ^ 0 02.9 6?.2r? / * ^; o . o s e c Si,0ns ~< 6 .. o k 0 3 il.fts* kn 1 - r 0 w.vtw 0-- -MHO----- -------- r o-o^K_|---- -- - G D-ohs^-I ~u> -7 O'&004v/&so" 7' t o / ``- H X 119$700 - 7 >k 9. s o n _ -V .. 05. 0 S v s - V?,Yi?7 VT, 7 ^ ^ iy-i 0 , C S'a I T tS t ' 0 > V H ( j 03,0/77 PreP Analyst: ^ Analyst; Reviewed by: 9 'W l0 Date: f '-0 O -/j_ & Date: n A t 6 -- Dat 71 STL Chicago TOC in Soils lYl !*> Page No,g Book No.: O 7 / ? 9 " Method: Lfoyd Kahn Instrument: Phoenix 8000 fTOC4) LabNet Batch: Calculations: TOC (mg/kg) = ug C / grams sample Date of Standard Curve: V 0 tj o ^ Book # y Page # l/_ 5 MS, MSD Known Cone, (mg/kg) - 100 ug C / grams sample MS, MSD Observed (mg/kg) = ug C igrams sample MS, MSD Rec. = [observed mo/kq - ava. sample result {mg/kg)] x100 known concentration in mg/kg Standard Traceability: (Note: Wortting Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve)________ ' Stock II (ICV/CCV) _______________ LCS Source ID ______ LCS True Value_________________Acceptance Range Sample ID: ^ t .... -/ > Sample Weight (g) ug C o ^ 7 7 *6 o . <g.a y H tW ------ /1J' f ?-"C^ Comments: _____- M ___ I -n I ~v> 0 <0 `U , & 0^( (s^ 0 ..'-.g 2. i o n . !<*$*? J -lA I " ij I ' i ~`7 --t > 1 e>. ....... r c .....- - a ..>/*? K $ o'*, 7-o <-A7. 2 - 2 ^ H^ 7 y ?. 55 ^ 6 2 . *-/ |. eo7c> J ..... . ? o H "i .o r2 M -- ---------------------------- - ---- --------- CC^ <?-c>r iX ^ i C:C-fy' CL [ / o -^ n-^-xQ CC\/ C C(p <0*7 b 0 j 40 Q. g v(4 5~~ vAt-^O" ta'i-C 'cf/^/t^CV/] 7i 5 jj ....voj4-,/u; 1 i -n T7 0'O^T0 v^i 7- ^ & _ tV' . 6c-( Q, Prep Analyst:,C Analyst: Reviewed by;u > c Cs jj, Q--- 4t & r Date: Date: / ~ Date: J-/J 7/b_______ CHI-22-12-095/S-0 5/01 72 STL Chicago TOC in Soils 77 7 Page No.:. Book No.: 2 S '9 9 ' Method: Lloyd Kahn Instrument; Phoenix 8Q00 (TQC4) LabNet Batch: Calculations: TOC (mg/kg) = ug C / grams sample Date of Standard Curve; Book # f y Page # _ 9 MS, MSD Known Cone, (mg/kg) = 100 ug C / grams sample MS, MSD Observed (mg/kg) = ug C / grams sample MS, MSD Rec. ~ [observed mg/kg - avq, sample result (mq/kq|l x1Q0 known concentration in mg/kg Standard Traceability: (Nota: Working Standards are prepared daily from the noted Stock Solutions,) Stock 1(Curve) LCS Source ID j . Stock II (ICV/CCV) ,, (A .P _CS True Value ,Acceptance Range Sample ID: if i - j 11 t1........... ; . : G 0 > Is 0 /b Sample W eight (g) - o 4 >" > ' C -o^. V -/ O 0 OM. 9 7 0- 7 , < 0 ./ C ug C '! 2- 1 7 7 .7 7 , i y a H. n s 7 S 9.% Z ~)Y f x .in v -/3YY Comments: ''"-T... Prep Analyst: ^ Analyst: /^ Revi ewed bv: . '1l 'X Date;_ D a te : Date: J.J?j /k 1-/-2.J ( Ot j