Document bzeR4gB1mjpDgk3j4nx322gZ
Ohawtohd a RusacLL
NCOHrOHATtD
STANDARD SPECIFICATION _______ Physical Properties
STO. No. ^2___
PAGE -3IC-ZJ,
REV. DATE
--2--------__ 3/23/^1
Vinyl Acetate
1. Formula: 2. Molecular Weight: 3* Boiling Point (Normal): 4. Freezing Point: 5- Specific Gravity:
6. Viscosity:
7* Surface Tension: 8. Index of Refraction: 9. Specific Heat: 10. Heat of Vaporization: 11. Flash Point (open cup):
12. Auto Ignition Temperature: 13. Explosive Limits: 14. Critical Properties:
15. Solubility in Water: 16. Solubility of Water In: 17- Max. Allowable Cone, in Air: 18. Heat of Formation: 19- Heat of Polymerization:
Thermal Conductivity:
CH3COOCH = CH2
162.8F -148F 0.9338 g./mol. S 68F. (liq.) (ASp. Or. M T (F) * -0.000?) 2.97 (air * 1.0) -(Vap.) op Centiooise (Liauid) 32 0.54 68 0.41 104 0.33 23.8 Efynes/Cui 77F
d20 = 1*3953
Liquid * 0.460 BTU/lb. F 68F. 164 BTU/lb* .1 ata. Inhibited material: 30F Uninhibited material: 20F 769F. 2.6 to V}A$> by volume in air. To * 4-44.02F Pc = .22.4 atm. Dc * Ve * 2.3# (vt.) 68F. 1.0* (wt.) 9 68F.
1800 BTU/lb. 446 BTU/lb.
Note: Data calculated from: 1) Bulletin 3-56, Celanese Corp. of America 2) Celanese Vinyl Acetate Monomer Brochure 3) Niacet Vinyl Acetate Monomer, Union Carbide
Chemical Co., Bulletin F-7575C
AP00055924
W Cbmiat-
PUT IT IN WRITING
DISTRIBUTION
Subject
Date 21 MAY 1976 VINYL CHLORIDE MONOMER DATA BOOK
rom
( (
G. B H. SPEED
) Take Action ) For Your Comments
____________________
{ ) For Your Approval { } As Requested
{ ) For Your Info ( ) Discuss With Me
{ ) File
( ) Note & Return
TO: W. D. Hoferkamp J. D. Kramer J. P. Parker R. I. Patel F. L. Riddle D. R. Riggs M. H. Stermon G. F. Tillson
D. L. Walker
Attached is a book of data on vinyl chloride, vinyl acetate and propylene that I have accumulated over the years that may be of some benefit to you.
GBUS/pk
AP00055925
KeurFSL * e3ER co.
'TEMPERATURE ! F |:
AP00055926
VAPOR PRESSURE OF VINYL CHLORIDE
PRESSURE PSIA
-TEMPERATURE P
i
AP00055927
J t c u r r c L > C9>ca co
AP00055928
DENSITY LBS/GAL VISCOSITY Ctf
VINYL CHLORIDE (LIQUID)
0.23 0.22 0.21 0.20 0.19 0.18 0.17 0.16 0.15-
AP00055929
KturrtL a eaitH co
AP00055930
* IT'
Keurrsw 4t eac* co. i TEMPERATURE:
I- ' ! OMO
AP00055931
------1
VINYL CHLORIDE MONOMER
30 20
10
Trv Urr Var
0.
. PSIA
AP00055932
ii Y'Z * iti iNCHts
AP00055933
PHYSICAL PROPERTIES OF VINYL CHLORIDE MONOMER
Formula Molecular weight
CH2 * CHC1 62.501
Density, liquid
fc/ml
F
at 14 32 50 59 68 77 86 95
104 113 122
0.9649 0.9471 0.9293 0.9201 -0.9109 0.9014 0.8918 0.8820 0.8721 0.8620 0.8517
d (g/cc) = 0.9471 - 0.001746t (C) - 0.00000324 (-2
n0
lb/gal
8.052 7.904 7.755 7.678 7.601 7.522 7.442 7.360 7.278 7.193 7.107
Refractive index, Dielectric constant
at 100 kc/s and 17.2C/63F
Freezing point, C/F Boiling point at 760 mm Hg, C/F
-
Viscosity of liquid, absolute, cP
F
at -4 14 32 50 68 86
104 122
Viscosity of vapor
*
.. * ->c
Specific heat, liquid, at 25 C, kcal/kg,C; or Btu/lb,F vapor, at 25 C (cp), kcal/kg-mole,C
or Btu/lb-mole,F vapor, at 25 C (cv), kcal/kg-mole,C
Heat of fusion, Btu/lb
or Btu/lb-mole,F
cal/g
1.398
6.26 --153-7/--244_7 -13.37/7.9
0.274 0.248 0.225 0.207 0.193 0.181 0.171 0.161
0.38 12.83
10.84
33.12 18.14
AP00055934
/ Surface tension,
9*
oF
dynes/cm
at -22 -4 14 32
50 68 86 104 122
Critical temperature, K Critical pressure, atm. Critical viscosity, cP Critical volume, ml/g Critical density, g/ml.
Solubility in. water at 40 C (LG4F) and autogenous pressure, grams/100 grams (approx.) atmospheric pressure, grams/100 grams (approx.)
Solubility of water in vinyl chloride, grams/100 grams
Solubility Dischloroethane and Ethyl Alcohol:
Press, nzm He
C2H4C12
C2H50H
R/100 E of solvent
400
23.2
17.2
300
16.7
12.1
200
10.5
8.05
100
5.25
3.76
Vapor pressure, psia
F
at - 4 14 32 50 70 85
104 122 140
10 10
158
-T Log P = 0.8420 - 1150.9/T 1.75 log T - 0.002415T
PV/RT
at - 13.37
25 156.5
- 11.93
77.0 313.7
23.9 22.3 20.9 19.4 18.0 16.4 14.8 13.3 12.0 431.4 52.7
0.0369 2.70 0.370
2-3 0.5 0.11
12 18 26 35 4B 66 88 115 147 180
0.9640 0.9178 0.264
AP00055935
9 r
o
Change (dt/dp) in boiling point with pressure. C/mm Hg
oF
at -11.93 77.0
0.03423 0.01355
c /c PV
p
at 32 50 68 86
104 122 140 158 176 194 212 248 302
Heat of combustion to form H20(1>, C02(g), KCl(g), Btu/lb kcal/mol(gas)
Free energy of formation, Btu/lb
Heat of formation kcal/molCgas 025C) kcal/mol(log O 18C)
Heat of vaporization @ 57F, Btu/lb
Estimated Latent Heats
F Btu/lb
at - 4 32 68
122
159 147 140 126
Heat of polymerization. Btu/lb kcal/kg kcal/g-mole
Entropy, 5 cal/C/mol
1.1 1.146 1.132 1.124 1.119 1.120 1.124 1.130 1.140 1.153 1.163 1.176 1.183
8750 2826
--3310
7.5 4.1
158
-720 -400 - 25
i 63.06
AP00055936
Thermal conductivity of vapor, Btu/ft, h, F
at 32 50 68 86
104 122 140 158 176 194 212 248
302
0.0057 60 63 66 69
73 78 83 88 93 98 108
121
Thermal conductivity of liquid, Btu/ft, h, F
Weber correlation
Palmer correlation
at 30C./86F Weber Palmer
k = 0.864`Cp'sp.gr.(sp.gr./mole wt)1^3
k - C41.4).-(T )-(sp.gr.)-(cr) x < Hy
,,t)X/3
0.073 0.0932
Polymer shrinkage, vol.%
34
Vapor density (air = 1.00)
2.15
Explosive limits in air
Lower, vol.%
wt.% g/m3
grains/cu.ft.
4
8.3 112
40
Upper, vol.% wt.% g/m3 grains/cu.ft.
Flash point, C/F(Cleveland open cup) Ignition temperature (autogenous), C
,P
Odor (pure vinyl chloride) (inhibited)
Color Corrosivity
22 37.8 613 219
-78/-108.4 472.22 882
Faint sweet odor Faint phenolic odor Colorless Koncorrosive when dry at ambient temperature. Acer lene impurities react with copper.
AP00055937
DR CHK AFF S6AU
slqlii
For
TEMPERATURE, *F
VINYL ACETATE LIQUID DENSITY
Crawfors a F%otkxz
Contract
TAMFOWP, CONN.
Dwa. No.
Rev.
SFC-2.2
0
AP00055938
0.01
DK CMK iVf tou
Ink / Worn bVK IT, H. T.
60
TEMPERATURE #F
Vim ACETATE VAPOR PRESSURE
150
Cmwwvons a ttvmmmuu
Cofrnuer
rrAMTOAD. COMM. OMW. No. Rsv.
SFC-2.3
0
AP00055939
AP00055940
INCOAPODUID STANDARD SPECIFICATION
Physical Properties
STD. NO. RAOC REV. DATE
SFC.A 3FC-6-1
1/2Q/61
Potassium Persulfate
1. Formula:
k2s28
2, Molecular Weight:
270.3
3. Physical State: 4. Solubility in Water:
White Crystals Temp. F
Lbs. per 100 lbs. Water
68 4.7
86 7.5
104 10.5
122 15.3
140 20.5
158 27.3
5. Storage & Handling:
a) Aluminum or stainless steel scoops, shovels, etc. are suitable
for removal of K2S20gfrom shipping containers.
b) Storage tanks, pipelines, etc. for aqueous solutions should be Type 304 or 316 stainless steel. (Chemical Stoneware & Glass
are suitable). Do not use monel metal, copper, brass, or iron to prevent corrosion and decomposition. s) Cool dry storage should be provided.
Ref: Bull. No. 11, "Potassium Persulfate" Becco Chemical Division, Food Machinery and Chemical Corporation.
AP00055941
Osuwforo . Russell IMCDMOnaTCO
STANDARD SPECIFICATION ________Physical Properties
STD. No. PAGE REV. DATE
SFC-7
5FC-7-I 0 3/20/qI
Lauroyl Peroxide
1. Formula:
^11^23^^2^2
2, A.ctive Oxygen:
Pure compound -4.01$; Min. Spec. 3*7&6
3* Molecular Weight:
398.6
4. Physical State:
Soft White Granules
5 Melting Paint:
120-122F dec,
6, Solubility in Water:
less than 0,1 part/100 parts of water
% 68F.
7. Storage and Handling:
Lauroyl peroxide is a flammable solid and should be kept away from heat,
sparks, radiators, steam pipes, fire, open flames, direct rays of the
sun, and other sources of heat. It may be stored at room temperature
(80F) but prolonged storage should be at refrigerator temperatures
to preserve its active oxygen. Do not fractionally grind unless a solvent
be used to take up the heat or other means of heat dissipation be used.
8. Packing & Shipping:
Shipment is made under yellow label via express, truck, or railroad. Mail shipments are forbidden.
Ref: Technical Data Bulletin No. 10A., Cadet Chemical Corporation.
AP00055942
ft HuBOELI. O ff POMATI9 STANDARD SPECIFICATION
Physical Properties
STD. No. PAGE REV. DATE
SFC-10
SFC-10.1 0
3/20/61
Vinyl Chloride (Chloroethylene)
1. Formula: 2. Molecular Weight: 3. Boiling Point (Normal):
b. Freezing Point:
5. Specific Gravity:
6. Viscosity:
7. Surface Tension:
8. Index of Refraction: 9. Specific Heat:
10. Heat of Vaporization: 11. Flash Point: 12. Auto Ignition Temperature: 13. Explosive Limits: 14. Critical Properties:
15* Solubility in Water: 16. Solubility of Water In: 1?. Max. Allowable Cone, in Air: 18. Heat of Formation: 19. Heat of Polymerization: 20. Thermal Conductivity:
CH2= CHC1
62.5
+7.93F.
-244.82F.
1.00 g/ffll. -22F.
0.914 g/ml. d 68F.
F. Centiooise (Liauid)
-40 0.34
32 0.225 86 0.181
F, Dynes/Cm
-22 23.8? -4 22.27
l4_c
20.88
rd1^ = 1.398 f
Liquid ^ 0.38 BTU/lb./F.
cp * 12.83 BTU/lb.mol/F. 77F,
cv = 10.84 BTU/lb.mol/F 77F. Cp/cv = 1.183
128.27 BTU/lb. 77F. Cleveland Open Cup - 108F 84lF. 4 to 22$ by volume in air Tc = 313.7P. Pc = 55*2 atm. Dc s 0.370 g/ml. Vc * 2.70 ml/g.
0.11$
500 ppm for 8 hr. -exposure Hp = 216 BTU/lb. Hp = 490 BTU/lb., 0.03 BTU/hr. ft.^ (F/ft.)
NOTE: Refer to Dow Chemical Company bulletin on Vinyl Chloride Monomer for detailed discussion of hazards, handling procedures* etc.
AP00055943
Latent Heat - Bfcu/Lb
DR ilnfa
CHK
Latent Heat of Vaporization Vinyl Chloride
APR For
SCAUt
IMe..MILVII *WM,
MMXI.YN tT. H. 1-
STOCK NO. MOM
Orawforp a F%u*cu
Contract
VTAMPOMi COMM. Owe. No. Rev.
SFC-10.2
0
AP00055944
Temperature, F
om CHK APW Br.tktM 4W.WI
Mnlu
Heat Capacity Of Vinyl Chloride
Ht*.. MMAnf IT. V.
iwrm
Rnr.
SFC-10.3 0
AP00055945
0.62
0.86
0.90
0.94Density G/M1.
0,98
1.02
DR
CHK
APP
Worn
CALK
MtlVIl MM. Mte.. OORLVH t7. M. V.
Vinyl Chloride Liquid Density
(TMK M*. NM
Oimw^oftoa RueaBu^
contract
VTAMFOMO. COM*!.
Owe. No. RlV.
SFC-10.4
0
AP00055946
Chawtojid ft RvtacLt. IMCttRPOftATIQ
STANDARD SPECIFICATION
Physical Properties
rro, NO.
page SFC-12.1
REV. --2_________
DATE
1/21*61
Sjdiuri_3isulfite 1. Fcrsiuls. 2. Molecular Weight 3. Physical State 4. Specific Gravity
5. Melting Feint
6. Solubility, g,/l00 ml. of:
NaHSOj 104.06 White powder - yellow in solution 1.561 - 1.539 302F. (-7H20)
Cold Water 32.8 32F.
Hot Water 196 6 104F.
Ref: Handbook of Chemistry & Physics
AP00055947
OhJCWTOJ5D t Husssll----------------------------------------------
IHCOIQ&TlO
STANDARD SPECIFICATION
Physical Properties.
STD. NO, _ 5FC-18
page
SFC-18.1
*EV. __0 .
DATE
3/22/61
Benzoyl Peroxide 1. Formula 2. Molecular Weight 3. Melting Point 4. Boiling Point 5 Solubilities:
6. Shipping:
7. Fire Hazard: 8. Explosion Hazard:
(C6K5C0)2o2
Reference
242,22
(1)
103-106C dec. 108C 217.4.222.8F dec. 226.4F
dec. explosive
g/lOOg solvent at 68F
(2)
in Acetone
- 18.5
Ethyl Alcohol - 1.2
Methyl Alcohol - 1.7
MEX MIX
- 19 - 12.4
Toluene Water
- 12.7 -<0.1
Yellow label
(1)
I* 5i 20 and 50 lbs* net in (3)
wooden cases pure or as paste
mixed with other substances
Moderate, by virtue of its oxidizing ability
(1)
May explode spontaneously.
Should be kept either bone
dry or with > 30# water.
Ref. 1. Sax, N. I. Dangerous Properties of Industrial Materials. (1957) Reinhold Publishing Corp., N. Y,
2. Encyclopedia of Chemical Technology, 2.
3. Manufacturers literature.
AP00055948
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A =: ! 0 /A
M = /<-/.'ny.
L/it(%) f ULL (7,) .
vX * f(J0?o
k^s 7 10 0 0^4
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7 ten/ 0
Dt, - 2-1'^ J /0 xtlJrtj.fU
f'T- D/fi f
VAfSA
ctf-a
(LtA.Lts-J-'ji '
W, =
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If w'- in-j>
(/< =
7 VfC^
frj 0)6^;/^ . ^ r,VJt
y UO^Otil)
~~ ^-=r=*"
Wj - /, 7 * 1-r = 0-5 ~
AP00055949
VC A?
c//. - CM
Ot -------- r> zoz (j) i MLo (j) i HU ( J
Afy (^/.3s''/& ' Il$T'M70.
A f/c - Q~
t'JA') ~(~f, zr r-*d 3 -
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AP00055950