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AL D Marvinol vinyls V6J.00 tU ft TECHNICAL DATA SHEET MARVINOL 22 MARVINOL 22 It a high moleculsr^wslght general purpose suspension type PVC homopolyaer. Its exceptional gel and dry blend properties are veil suited for a variety of applications in calendering* extrusion* vlre and cable* medical tubing and general comooundlng. PROPERTY Specific viscosity Inherent viscosity Apparent Density Oil Absorption TEST METHOD ASTM D-1243-66T (Method B) ASTM D-1243 ASTM D-1893 ASTM D-281 TYPICAL DATA 0.44 1.03 , 29 Ibs/ft 0.90 Screen Analysis ASTM D-1921-63 (cumulative % retained)! 80 mesh 100 mesh 140 mesh 200 megh 3 30 75 97 Gels Moisture 4 Volatiles MARVINOL Test MARVINOL Test 3 minutes 0.30% Hot Dry Blend Time ASTM-2396-69 2.8 minutes Extract Electrical Conductivity ASTM-2396-69 Volume Resistivity MARVINOL Test 0.14 olcrohms/cm/gm 15 x 10l* ohms/cm ASTM Classification A ASTM D-1753 GPS-15353 Physical Froperties(50 nhr DOF) Tensile Strength 100% Modulus Elongation Tear Strength(DIEC) ASTM D-412 ASTM D-412 ASTM D-412 ASTM D-624 2*800 pel 1*500 psl 340 % 450 psl KCT:dmb (12/7/71) Reg* U.S. Fat* Office The recommendations for the use of our products are based on tests believed to be reliable. However, we do not guarantee the results to be obtained by others under different conditions. Nothing in this brochure is intended as a recommendation to use our products so as to infringe on any patent UNIROYAL CHEMICAL Division of UNIROYAL, Inc. Naugatuck, Connecticut 06770 56' --V* ^ -Wf / * Marvinol vinyls TECHNICAL DATA SHEET MARVINOL 1001 A Plastlsol Blending Resin Polymer Polyvinyl Chloride Specific Viscosity (1) .44 Particle Site Trace retained on a USSS 200 mesh screen Specific Gravity Apparent Density Heat Loss 1,40 30 lbs/ft3 0.2% DESCRIPTION MARVINOL 1001 is a plastisol blending resin of controlled particle else. It Is recosaended in blends with MARVINOL 50 or other dispersion grade resins for cost reduction, gloss control and viscosity reduction in all casting and molding applications. Because of its controlled particle site, MARVINOL 1001 may be processed at higjh rates of shear without the usual difficulties of coarse particles culling out on the milling or casting equipment. URL 00792 ACW:dcj 3/12/68 Rev. 5/9/68 Unlroyal Reg. TM for its PVC resins The recommendations for the use of our products are based on tests believed to be reliable. However, we do not guarantee the results to be obtained by others under different conditions. Nothing in this brochure is intended as a recommendation to use our products so as to infringe on any patent. ijniRoya] I U.SRUBBER UNIROYAL CHEMICAL Division of UNiROYAL, Inc. Naugatuck. Connecticut 06770 Marvinol vinyls URL 00793 TECHNICAL DATA SHEET MARVINOL SO Typical Properties Polymer ................................... Resin Type ......... .. Specific viscosity (1) Inherent viscosity (2) Particle else ..................... M fit V........................................ Methanol extractable ... Bulk density ........... Brookfield viscosity (3) Severs viscosity (3) ... Application Homopolytner of PVC Stlr-in plastlsol 0.48 1.15 Trace retained on 200 mesh USS screen 0.2% 1.8% 15 lbs/ft3 7,000 cps 145 poises MARVINOL SO is a high molecular weight PVC plastlsol-grade resin used In the coating of cloth, paper and flooring substrates. MARVINOL SO exhibits a high degree of compatibility with plasticiser, stabiliser and other formu lating ingredients. MARVINOL 50 also possesses exceptionally high clarity and gloss properties. The rheological properties of MARVINOL SO are particu larly suited for high shear knife, reverse roll end strand coating. MARVINOL SO is available in viscosity grades suited for cloth coating where cloth penetration control and pigment floatation resistance are critical properties. MARVINOL SO Is also available in a lover viscosity grade where maximum flov-out is necessary. For all these reasons MARVINOL SO has a continuous record of unsurpassed per formance In the cloth coating, paper coating and flooring fields since 1955, MARVINOL SO is also used in dipping and alush and rotational casting where Its automotive fog resistance can be used to advantage. MARVINOL SO is ap proved for use in food contact applications. Through careful emulsifier selection MARVINOL SO possesses low teste and odor pick-up, (1) ASTM-D-1243-60 (2) ASTM-D-1243-66 (3) 60 phr DOP ACW (2/23/72) The recommendations for the use of our products are based on tests believed to be reliable. However, we do not guarantee the results to be obtained by others under different conditions. Nothing in this brochure is intended as a recommendation to use our products so as to infringe on any patent. UNIROYAL UNIROYAL CHEMICAL Division of UNIROYAL, inc. Naugatuck, Connecticut 06770 Marvinol vinyls URL 00794 MARVINOL 56 A Copolymer Plastisol Resin for Adhesive Applications Polymer Inherent Viscosity^ Specific Viscosity^) Retained on 200 Mesh Specific Gravity Heat Loss Methanol Extractable Bulk Density Brookfield Viscosity^) Severs Viscosity^) TYPICAL PROPERTIES Vinyl chloride .99 .41 Trace L38 0.2% 1.2% .24 gms./cm^. 20,000 cps 200 poises MARVINOL 56 is a copolymer plastisol resin specifically designed for adhesive plastisol applications. MARVINOL 56 is also used in the coating of heat sensitive substrates or where only limited fusion heat is available. The normal fusion temperatures for MARVINOL 56 falls in the 275-300"F. range which can be lowered to 250*F. through careful plasticizer selection. MARVINOL 56 is available in a range of viscosities to meet virtually all coating requirements and is particularly suited to those applications where compounds with a high plasticizer level tend to reduce viscosity below a practical coating range. MARVINOL 56 is blended with other plastisol resins to lower gelation temperature in slush and rotational molding applica tions where special control is needed and not obtainable with standard molding resins. (1) ASTM D-1243-66 (2) ASTM D-1243*60 (3) 60 phr DOP The recommendations for the use of our products are based on tests believed to be reliable. However, we do not guarantee the results to be obtained by others under different conditions. Nothing in this brochure is intended as a recommendation to use our products so as to infringe on any patent. ASP-33B4 Printed in U.S.A. UNIROYAL CHEMICAL Division of UNI ROYAL, Inc. Naugatuck, Connecticut 06770 fv. "W, Marvinol vinyls MARVINOL* 5051 A PVC Plastisol Resin for General Coating, Molding and Compounding Inherent Viscosity^ Specific Viscosity^) Retained on 200 Mesh Specific Gravity Heat Loss Methanol Extractable Bulk Density Brookfield Viscosity^) Severs Viscosity^) TYPICAL PROPERTIES 1.15 0.48 Trace 1.40 0.2% 1.6% .24 gms./cm^. 8,000 cps 160 poises MARVINOL 5051 is a high molecular PVC plastisol grade resin with a balance of properties suiting it for use in virtually all plastisol coating and molding applications. These include the spread coating of cloth, paper, and flooring substrates as well as slush and rotational casting, plus general compounding. MARVINOL 5051 has exceptional compatibility, heat stability, fog resistance, long term ultraviolet stability, plus complete freedom from plate-out and spew. MARVINOL 5051 is available in a range of viscosity properties including balanced Brookfield and Severs properties for spread coating on paper and flooring substrates where flow out is essential, as well as on cloth where penetration control is required. MARVINOL 5051 is also available in a low Brookfield range for slush and rotational molding and general compounding. The air release properties of MARVINOL 5051 are exceptional for all applications. MARVINOL 5051 is available in a high gloss range for high gloss coatings for flooring and apparel. With low taste and odor properties Manual 505 is suited for food contact applications. (1) ASTM D-1243-66 (2) ASTM D-1243-60 (3) 60 phr DOP The recommendations for the use of our products are baud on tests believed to be reliable. However, we do not guarantee the results to be obtained by others under different conditions. Nothing in this brochure is intended as a recommendation to use our products to as to infringe on any patent. ASP-338S Primed in U.S.A. UNIROYAL I t! A selection guide to Marvinol: a family of PVC resins. URL 00796 URL 00197 The MARVINOL tine of vinyl resins includes dispersion resins, piastisol biending resins and general purpose suspension resins for calendering and extrusion. This brochure is intended to acquaint you with the basic properties of these materials so that you may make a proper selection for your application. All MARVINOL resins are available in 50-tb. bags and MARVINOL sus pension resins are available for bulk shipment as well. Detailed technical information is availble upon request through our MARVINOL technical sales representa tives. Such information will provide the latest technology associated with the use of these materials. MARVINOL DISPERSION RESINS MARVINOL dispersion resins are available for use in ail pfastisois and organosols. MARVINOL 5051 is a general purpose resin for coating, molding and compounding. MARVINOL 53 is specifically for chemically blown foam laminates. And MARVINOL 56, a vinyl chloride acetate copolymer is used for adhesive tie coat applications. MARVINOL 5051 MARVINOL 5051 is most useful in a wide variety of slush and rotational molding, knife and reverse roll coatings, hot and cold dipping, spray and general compounding applications. The careful balance of high and low shear rheological characteristics and exceptional air release properties makes MARVINOL 5051 ideally suited for all these applications. The high degree of compatibility of MARVINOL 5051 with other formulation ingredients and freedom from plate-out combine with high gloss to make MARVINOL 5051 a pre-eminent resin for all flooring and cloth coating applications. MARVINOL 5051 is also available in a reduced gloss range. The availability of MARVINOL 5051 in various viscosity ranges suits this resin for such diverse requirements as maximum flow-out in paper coating and controlled penetration in cloth coating. MARVINOL 5051's other properties include exceptional freedom from fogging for automotive applications and low taste and odor pick-up for closure applications as well. MARVINOL 5051 is also useful in pressure molded, chemically blown foam where high molecular weight is a requirement rather than the low molecular weight normally required for atmospherically blown foam. MARVINOL 53 MARVINOL 53 (used with Uniroyal's blowing agent, Celogen AZ) is the number one resin for the chemically blown foam laminates so popular in vinyl cloth coating, paper coating and floor coverings. MARVINOL 53 provides exceptional quality foam over a very wide range of oven processing temperature and time conditions, as well as an ability to be formulated over a wide range of recipe changes including plasticizer type and level and blowing agent concentration. K also possesses excellent fog resistance for automotive applications and low taste and odor properties for food closures. MARVINOL 53 is available in a variety of viscosity grades for applications where high shear coating performance may be coupled with cloth penetration control through partial gelation or controlled low shear viscosity, or where applica tions require maximum flow-out. - HBt MARVINOL 56 MARVINOL 56 is a copolymer dispersion resin for tie-coat applica tions. Its exceptional compatibility combined with reduced fusion temperature ideally suits this resin for all plastisol adhesive applica tions. Such applications include rotogravure printing thin gauge adhesive coats to bond cloth and vinyl film. MARVINOL 56 can also be used as a coating for heat sensitive substrates and works exceptionally well with lower temperature blowing agents (CELOGEN OT). MARVINOL 56 is available in a variety of viscosity grades, particu larly useful where high plasticizer level adhesives tend to drop plastisol viscosities below the level needed for proper coating rheology and coating weight. in combination with selected plasticizers the fusion temperature of MARVINOL 56 based compounds can be reduced to the 120" C range. MARVINOL PLASTISOL BLENDING RESINS The MARVINOL line of dispersion resins is complemented with an equally versatile line of plastisol blending resins. MARVINOL 10 has been the preeminent resin for all slush and rotational molding applications for over two decades. MARVINOL 16 with its controlled particle size is specifically designed for the needs of the coating industry. MARVINOL 19 serves in general compounding applications. Detailed information on these resins follows. MARVINOL 10 MARVINOL 10 is one of the original plastisol blending resins and possesses unique properties which have never been matched in competitive products. MARVINOL 10 is used principally in slush and rotational molding where up to 50% of the primary plastisol resins may be replaced. Here MARVINOL 10 has as a most valuable property with its unusual ability to lower gelation temperature, a highly desirable feature in slush molding. Also, the high molecular weight of MARVINOL 10 provides hot strength, an essential property for slush and rotational molding when parts are removed from the mold prior to complete cooling. And the high molecular weight of MARVINOL 10 provides maximum physical strength during the service life of a molded boot, toy, or automotive part MARVINOL 10 additionally enhances viscosity and air release properties as a desired feature for the processing of plastisol compounds. plastisol blending URL 00798 URL 00799 marvinol 18 MARVINOL18 is a carefully controlled particle size plastisol blend ing resin specifically designed for high speed, thin gauge coatings on cloth, paper and flooring substrates. The absence of large particles allows for the replacement of up to 35% of the plastisol resin in such applications with no subsequent accumulation of large particles in the coating trough or large particles slipping through the coater to cause streak marks in the coating. With its controlled particle size, MARVINOL 18 is most useful as a gloss control agent. With its carefully selected molecular weight MARVINOL 18 can be used simultaneously in both top coatings and foam coatings where physical strength and foam quality are critical properties. Again, due to a controlled particle size distribu tion, resin settling in low viscosity compounds is minimized. MARVINOL 19 MARVINOL 19 is a general purpose plastisol blending resin suited for a variety of molding and dipping applications. Plastisol viscosity and air release are enhanced with its use. calendering, extrusion and injection molding MARVINOL GENERAL PURPOSE RESINS MARVINOL 22 and MARVINOL 23 are suspension type, hot dry blend resins for calendering and extrusion applica tions. They exhibit high heat stability, excellent compatibility and electrical properties, freedom from gels, and are readily air-veyed. MARVINOL 22 and 23 differ only in molecular weight. V Applications for Marvinol* Dispersion and Plastisol Blending Resins Application MARVINOL MARVINOL MARVINOL MARVINOL MARVINOL MARVINOL MSI S3 S6 10 11 IS Cloth coaling Paper coetmg Malal coating e Flooring e Slush molding Rotational molding Hoi dipping Cold dipping + General compounding Adhasivtt Atmospherically biown loam Lower temperature loam Pressure molded team Mechanical loam * Food closures URL 00800 IVSarvinor Resin Properties MARVINOL* Inherent Via. ASTMD 1243 Specific Via. Specific Gravity Methanol Brookfield Severe Extract Vlacoatty Viscosity % cpe Poises (a 60 phr DOP Gelation Temperature c Dispersion 5051 S3 56' 1.15 .08 .99 .40 140 36 1.40 .41 1.30 1.6 8.000 180 7.000- 1.6 20.000 100 1.2 20.000 200 75* 70* 67* PLASTISOL BLENDING i Retained on (Cumulative! Bulk Density #/tt Oil Absorb lion 40 10 1.20 .50 1.40 24 .7 nit 100 1 200 270 mesh 20 18 04 .34 1.40 30 .4 nil 1 19 .04 .34 1.40 30 .5 20 CALENDER S EXTRUSION 22 1.06 .44 1.40 29 .9 nil 30 9S 23 .93 36 1.40 30 9 rtf 25 95 ' Al MARVINOL retifts ere PVC horopotymers except MAfivWOL M wheh m a vnyl efMoriM -wnyt acetal* eepoiymer.