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PITT-CONSOL CHEMICAL COMPANY Removal, Handling, Storage and Disposal of Asbestos A. Plant Pre-removal Procedure 1r / The following procedures shall be followed by person^involved in the removal or stripping of asbestos material: 1. Notify the Safety Director in advance, extension 48. 2. Obtain a completed work permit from Shift Supervisor for tne Safety Director's approval. 3. Discuss with the Safety Director method of asbestos removal, use of required safety equipment, and use of any monitoring device. 4. Minimum safety equipment required for asbestos removal: a. V Respirator or dust mask.^^^' Vc,T" b. Disposable coveralls and head covers. c. Eye protection, hard hat, and boots. ' Notify the Safety Director when work is completed for: a. Post-removal inspection and monitoring. b. Personnel decontamination procedures. Note: The Shift Supervisor will be in charge during the Safety Director's absence. B. Removal and Handling Asbestos material should be handled in wet state, whenever practicable, to prevent the emission of asbestos fibers to the atmosphere. Dry Removal Dry removal of friable asbestos material is not recommended, but may be necessary in instances of unavoidable damage through the wet removal techniques. Because this material may result in heavy contamination, it requires specific EPA approval. 1 Wet Removal Wet removal of asbestos is based upon tiie ability of water to lower the friability of the wetted material and the movement of the released fibers. Water or wetting agent will render the material less friable and more cohesive, thus reducing airborne asbestos. Fibers that are released will fall rapidly if wet. Wet Removal Procedures Isolate the work area to prevent contamination and fiber dispersal to other areas during stripping. Cover equip ment and other items with polyethylene sheets if necessary to prevent them from getting wet. Flag the work area and put up warning Wet insulation. Re-spray as required '-during removal of the material. signs. if dust sv K'- rc*- occurs Use wetting agent if water run-off poseg safety and cleanup problem, and during the winter.* 5. Remove asbestos material in small sections with two-person teams, on scaffolding platform if needed. Never drop asbestos material to the ground. Transfer the material into 6-mil pre-labelled asbestos bags prior to starting the next section. 6. Clean up debris and other fallen material by wetting before placing in pre-labelled asbestos bag. 7. Keep the collected materials wet and sealed in bags during the entire operation. 8. Inspect the work area visually to insure adequate and complete removal of asbestos fibers. Additional cleanup and inspection should be conducted after 24 hours. Any settled fiber should be wetted before placing in pre-labelled asbestos bags. 9. Notify the Safety Director for post-removal inspection and monitoring. C. Storage and Disposal 1. All asbestos material, scrap, debris, containers and asbestos-contaminated clothing should be collected in pre-labelled asbestos bags, adequately wetted and sealed. 2 2. Sealed bags containing asbestos material will be deposited to Asbestos Storage Pile for off-site disposal. 3. All asbestos bags should be tagged indicating the weight of each bag and the date of removal. 3 r '> *\ n n r ^ o 121:0466 appendix a FEDERAL REGULATIONS Subpart D--National Emission Standard for Asbestos 61.20 Applicability. The provisions of this subpart are apible to those sources specified in 2 61.21 DiTiniiions. Terms used in this subpart are defined in the act. in subpart A o( this part, or in this section as follows: (ai "Asbestos'' means actinolite. amosite. amhophyllite, chrysotile. crocidolite, trcmolitc. (b) "Asbestos material" means as bestos or any material containing as bestos. (c> "Particulate asbestos material" means finely divided particles of asbestos material. <d) "Asbestos tailings" means any solid waste product of asbestos mtrung: or milling operations which contains as bestos. te) "Outside air" means the air out side buildings and structures. if) "Visible emissions" means any emissions which are visually detectable without the aid of instruments and which contain paniculate asbestos material. <g) "Asbestos mill'' means any facility engaged in the conversion or any inter mediate step m the conversion of asbestos ore Into commercial asbestos. Outside storage of asbestos materials is not con sidered a part of such facility. ill) "Commercial asbestos" means any variety of asbestos which is produced by extracting asbestos from asbestos ore. n> "Manufacturing" means the comv ? of commercial asbestos, or in the of woven friction products the comoining of texciles containing commercial asbestos, with any other material^). In cluding commercial asbestos, and the processing of this combination into a product os specified In S 61.22(c). (1) "Demolition" means the wrecking or taking out of any load-supporting structural member and any related re moving or stripping of friable asbestos materials. <k) "Friable asbestos material" means any material that contains more tiian-l percent asbestos by weight and that can be crumbled, pulverized, or reduced to powder, when dry. by hand pressure. <1> "Control device asbestos waste" means any asbestos-containing waste material that Is collected in a pollution control device. fm) "Renovation" means Lhe remov ing or stripping of friable asbestos ma terials used on Any pipe. duct, boiler, tank, reactor, turbine, furnace, or structural member. Operations in which load-supporting structural members are wrecked or taken out are excluded. [Paragraph (m) revised by 41 FR 26373, June 19.197fc| Included, provided a number of such op erations can be predicted to occur during' a given period of time based on operating experience. <o> "Emergency renovation" means a renovation operation that results from a sudden, unexpected event, and Is not a planned renovation. Operations necessi tated by non-routuie failures of equip ment are Included. (p) "Adequately wetted" means suf ficiently mixed or coated with water or an aqueous solution to prevent dust emissions. <q) "Removing" paeans taking out friable asbestos materials used on any pipe. duct, boiler, tank, reactor, tur bine. furnace, or structural member from any building, structure, facility, or installation. CD "Stripping" means taking off fri able asbestos materials from any pipe, duct, boiler, tank, reactor, turbine, fur nace, or structural member. {Paragraph (q) and (r) revised by 43 FR 26373 June 19,1978] (s) "Fabricating" means any process ing of a manufactured product contain ing commercial asbestos, with the ex ception of processing at temporary sites lor the construction or restoration of buildings, structures, facilities or instal lations. (t) "Inactive waste disposal site" means any disposal site or portion thereof where additional asbestos-con taining waste material will not be depos ited and where the surface is not dis turbed by vehicular traffic. (u> "Active waste disposal site" means any disposal site other than an inactive site. (v) "Roadways" means surfaces on which motor vehicles travel Including, but not limited to. highways, roads, streets, parking areas, and driveways. (w) "Asbestos-containing waste mate rial" means any waste which contains commercial asbestos and is generated by a source subject to the provisions of this subpart, including asbestos mill tailings, control device asbestos waste, friable as bestos waste material, and bags or con tainers that previously contained com mercial asbestos. (40 FR 48292, October 14, 1975J (x) "Structural member" means any load-supporung member, such as beams and load-supporting walls: or any non- load-supporting member, such as ceilings and non-load-supporting walls. [42 FR 12127, March 2, 1977] 61.22 Emission slanilartl. (a) Asbestos mills: There shall be no visible emissions to the outside air from any asbestos mill except as provided in paragraph (f) of this section. [39 I R 15936, May 3. 1974 | <n) "Planned renovation" means a '(.'novation operation, or a number of uch operations, in which the amount friable asbestos material that will be d or stripped within a given pe- *>- tune can be predic ted. Operations hat axe individually non-scneduled are lb) Roadways: The surfacing of road ways uuh asbcsios tailings or with js* besios-conuming waste ihai is generated by any source subject lo paraaruphs k). id), (el or (h), of this section is prohibited, except for temporary road ways on an area of asbestos ere deposits. The deposition of asbestos tailings or as- bestos-containio" waste on roadways covered with snow or ice is considered "surfacing." (c) Manufacturing: There shall be no visible emissions to the outside air, ex cept as provided in paragraph (f) of this section, from any of the following op erations If they use commercial asbestos or from any building or structure in which such operations are conducted. [40 FR 48292. October 14. 1975 j (1) The manufacture of cloth, cord, wicks, tubing, tape, twine, rope, thread, yarn, roving, lap, or other textile ma terials, (2) The manufacture of cement prod ucts. (3) The manufacture of fireproofing and insulating materials. (4) The manufacture of friction products. (5) The manufacture of paper, millboard. and felt. (6) The manufacture of floor tile. (7) The manufacture of paints, coat ings. caulks, adhesives, sealants. (S) The manufacture of plastics and rubber materials. (9) The manufacture of chlorine. (10) The manufacture of shotgun shells. (11) The manufacture of asphalt con crete. (d) Demolition and renovation. The requirements of this paragraph shall apply to any owner or operator of a demolition or renovation operation who intends to demolish any institu tional. commercial, or industrial build ing (including apartment buildings having more than four dwelling units), structure, facility, installation, or por tion thereof which contains any pipe, duct, boiler, tank, reactor, turbine, fur nace, or structural member that is cov ered or coated with friable asbestos materials, except as provided in para graph (d)(1) of this section; or who in tends to renovate any Institutional, commercial, or industrial building, structure, facility, installation, or por tion thereof where more than 80 meters (ca. 260 feet) of pipe covered or coated with friable asbestos materials are stripped or removed, or more than 15 square meters, (ca. 150 square feet) of friable asbestos materials used to cover or coat any duct, boiler, tank, re actor, turbine, furnace, or structural member are stripped or removed. <1) (i) The owner or operator of a demolition operation is exempted from the requirements of this paragraph: Provided, (A) The amount of friable asbestos materials in the building or portion thereof to be demolished is less than 80 meters (ca. 2S0 feet) used on pipes, and less than 15 squire meters (ca. 160 square feet) used on any duct, boiler, tank, reactor, turbine, furnace, or structural member, and (3) the notification requirements of para graph <dxi)(il) are met. (ii) Written notification shall be postmarked or delivered to the Admin istrator at least 20 days prior to com- Env iionquo* Report*, lS*e. 61.22id)( 1 Hu)j 58 OCR 000030049 HAZARDOUS EMISSIONS s-4i: 121:046? mcnccmont of demolition and shall in clude the information required by onracraph (d><2) of this section, with lie exception of the information re quired by paragraphs (dK2) (lit). (vi), (vii>. <viii), and ux) of this section, and shall state the measured or estimated amount of friable asbestos materials which is present. Techniques of esti mation shall be explained. (Paragraph (4) revised by 4.1 FR 26374, June 19, I975j Written notice of Intention to de molish or renovate sitall be provided to the Administrator by the owner or opera tor of the demolition or renovation oper ation. Such notice snail be postmarked or delivered to the Administrator at least 10 days prior to commencement ot demo lition. or as early as possible prior to commencement of emergency demolition subject to paragraph (dMC) of this sec tion. and as early as possible prior to commencement oi renovation. Such no tice shall Include the following informa tion: u> Name of owner or operator. <iiv Address of owner or operator. (m) Description of the building, structure, facility, or installation to be demolished or renovated, including the size, age, and prior use of the structure. and the approximate amount of friable asbestos materials present. |Parararh (iii) revised bv 43 FR 26374, June 19. 19761 <iv) Address or location of the buildin structure, facility, or installation, tv) Scheduled starting and comple tion dates of demolition or renovation. (vli Nature of planned demolition or renovation r.r.d method's) to be em ployed. (vitJ Procedures to be employed to meet the requirements of this paragraph and paracrapn <ji of this section. (viiiJ The name and address or loca tion of the waste disposal sue where the fr.able asbestos waste will be deposited. (ix> Name. ;h!e. ar.d authority of the State or local governmental representa tive who has ordered a demolition which is subject to paragraph <d) (6) of this section. <3)<i For purposes of determining whether a planned renovating operation constitutes a renovation within the meaning of this paragraph, the amount of friable asbestos material to he re moved or stripped shall be: (A) For planned renovating opera tions involving Individually non-schedulcd operation*, the additive amount of friable asbestos material that can be pre dicted wilt be removed or stripped at a source over the maximum period of time for which a prediction can be made. The period shall be rot less than 30 days and not longer than cnc year. 'U> For coch planned renovating op eratinn not covered by paragraph id) <3) M m a i. the total amour.: of friable a.sUeruos material that can be predicted 1 he removed or stripped at a source. ;i> For purposes of determining whm.nvr an emergency renovating op eration ru;-_stuutes a renovation within the meaning of this paragraph, the amount of friable asbestos material to be removed or stripped shall be the total amount of friable asbestos material that will be removed or stripped as a result of the sudden, unexpected event that necessitated the renovation. <4> The following procedures shall be used to prevent emissions of particulate asbestos material to outside air: <i) Friable asbestos materials, used on any pipe, duct, boiler, tank, reactor, turbine, furnace, or structural member, .shall be removed from any building, structure, facility or installa tion subject to this paragraph. Such removal shall occur before wrecking or dismantling of any portion of such building, structure, facility, or installa tion that would break up the' friable asbestos materials and before wreck ing or dismantling of any other por tion of such building, structure, facili ty, or installation, that would preclude access to such materials for subse quent removal. Removal of friable as bestos materials used or\ any pipe, duct, or structural member which are encased In concrete or other similar structural material is not required prior to demolition, but such materials shall be adequately wetted whenever exposed during demolition. (ii) Friable asbestos materials used on pipes, ducts, boilers, tanks, reac tors. turbines, furnaces, or structural members shall be adequately wetted during stripping, except as provided in paragraphs (d)(4)(iv), (d)(4Xvi), or (dXvii) of this section. (iii) Pipes, ducts, boilers, tanks, reac tors. turbines, furnaces, or structural members that are covered or coated with friable asbestos materials may be taken out of any building, structure, facility, or installation subject to this paragraph as units or in sections pro vided the friable asbestos materials ex posed during cutting or disjoining are adequately wetted during the cutting or disjoining operation. Such units shall not be dropped or thrown to the ground, but shall be carefully lowered to ground level. tiv) The stripping of friable asbestos materials used on any pipe, duct, boiler, tank, reactor, turbine, furnace, or structural member that has been removed as a unit or in sections as pro vided in paragraph (d)(4Xiii) of this section shall be performed in accord ance with paragraph (d)(4)(H) of this section. Rather than comply with the wetting requirement, a local exhaust ventilation and collection system may be used to prevent emissions to the outside air. Such local exhaust ventila tion systems shall be designed and op erated to capture the asbestos particu late matter produced by the stripping of friable asbestos materials. There shall be no visible emissions to the outside air from such local exhaust ventilation and collection systems except as provided in paragraph (f) of this section. |4(i)-(iv) revised by 43 FR 26374. June 19. 1978| (v) All friable asbestos materials that have been removed or stripped shall be adequately wetted to ensure that such materials remain wet during all remain ing stages of demolition or renovation and related handling operations. Such materials shall not be dropped or thrown to the ground or a tower door. Such ma terials that have been removed or stripped more than 50 feet abo%e ground level, except those materials re moved as units or in sections, shall be transported to the ground via dust-tight chutes or containers. (vi) Except as specified below, the wet ting requirements of this paragraph are suspended when the temperature at the point of wetting is below O'C <32'F'. When friable asbestos material are not wetted due to freezing temperatures, such materials on pipes, ducts, boilers, tanks, reactors, turbines, furnaces, or structural members shall, to the maximum extent possible, be removed as units or in sec tions prior to wrecking. In no case shall the requirements of paragraphs <d' u) (iv) or (d)(4)(v> be suspended due to freezing temperatures. (vii) For renovation operations', local exhaust ventilation and collection sys tems may be used, instead of wetting os specified m paragraph (d> i4) (ii>. to pre vent emissions of particulate asbestes material to outside air when damage to equipment resulting from the wetting would be unavoidable. Upon request and supply of adequate information, the Ad ministrator will determine whether dam age to equipment resulting from wetting to comply with the provisions of this par agraph would be unavoidable. Such local exhaust ventilation systems shall be de signed and operated to capture the asbes tos particulate matter produced by the stripping and removal of friable asbestos materia). There shall be no visible emis sions to the outside air from such local exhaust ventilation and collection sys tems, except as provided in paragraph lf> of this section. (5) Sources subject to this paragraph are exempt from the requirements of 5 5 61.05(a), 61.07. and 61.09. (6) The demolition of a building, struc ture. facility, or installation, pursuant to an order of an authorized representative of a State or local governmental agency, issued because that building is structur ally unsound and In danger of imminent collapse is exempt from all but the fol lowing requirements of paragraph <d> of this section: (it The notification requirements spec ified by paragraph (d) (2) of this section: <ii) The requirements on stripping of friable asbestos materials from previously removed units or sections as specified m paragraph (d) <4Miv) of this section; (iii) The wetting, as specified by para graph (d)(4)(v) of this section, of fri able asbestos materials that have been removed or stripped; (iv) The portion of the structure being demolished that contains friahle asbes tos materials shall be adequately wetted during the wrecking operation. 139 FR 15936. May 3, 1974; 40 FR 4S292, October 14. 19751 <e) Spraying. There shall be no visi ble emissions to the outside air from the spray-on application of materials containing more than 1 percent asbes- S-18-78 RuMidicU by TWfc-fcURtAO OF NATIONAL AFF AIRS. INC., WASHINGTON. D C. 20037 CCR 000000050 121:0463 FEDERAL REGULATIONS tcs. on a dry 'Aright basis, used on equipment and machinery, except as provir-H in paragraph (f) of this sec tion. teriais .`.prayed on buildings, strum.. es, structural members, pipes. *nd conduits shall contain less than 1 crcent asbestos on a dry weight basis. [ Paragraph (c) revised by 4 3 FR -6374. J une 19.197bi (1) Sources subject to this paragraph arc exempt from the requirements of } 61.CS<a>, $ 61.07, and J 61.09. (2) Any owner or operator who in tends to spray asbestos materials which contain more than 1 percent as bestos on a ary weight basis on equip ment and machinery shall report such intention to the Administrator at least 20 days prior to the commencement of the spraying operation. Such report shall include the lolloping informa tion: (i) Nr.mc of owner or operator. (ii) Address of owner or operator. (nl) Location of spraying operation. (iv> Procedures to be followed to meet the requirements of this paragraph (3) The spray-on application of ma terials in which the asbestos fibers are encapsulated with a bituminous or re sinous binder during spraying and which are not friable after drying is exempted from the requirements of paragraphs (e) and (e)(2) of this sec tion. [Parar *is (2) and (2) revised by 43 FR 26374 19. 1978! if* Rather than meet the r.o-visiblcatssion requirements as specified bv paragraphs ia), (c), (di. <ei, <h>, (j*. and Ik) of this section, an owner or op erator may_elect to use the methods spec ified by 5 61.23 to clean emissions con taining particulate asbestos material be fore such emissions escape to. or are vented to. the outside air. (gi Where the presence of 'uncombined water is the sole reason for failure to meet the no-visiblc-emisslon require ment of paragraphs <a>, lc>, <d>. (e*. ' h*. i j >. or i k > of this section, such failire shad not be a violation of such emis ion requirements. <h) Fabricating: There shall be no isible emissions to the outside air. exCDtns provided in paragraph if) of this ecuon, from any of the following oprations if they use commercial asbestos >r from any building or structure in hich such operations are conducted. (1 > The fabrication of cement building roducts. (2> The fabrication of friction prodcts. except those operations that pri marily install asbestos friction materials n motor vehicles. (3) The fabrication ol cement or siltite board for ventilation hoods; ovens; cctrical panels; laboiatory furniture; bulkheads, partitions and ceilings for marine construction; and flow control devices for the moiten metal industry. (i) Insulating: Molded insulating ma terials which are friable and wet-applied Insulating materials which are friable after drying, installed after the effective date of these regulations, shall contain no commercial asbestos. The provisions of this paragraph do not apply to insu lating materials which are spray applied; such materials are regulated under 5 61.22(e). (j) Waste disposal for manufacturing, fabricating, demolition, renovation and spraying operations: The owner or op erator of any source covered under the provisions of paragraphs (c>, id), (e>, or (h) of this section shall meet the fol lowing standards: (1) There shall be no visible emissions to the outside air. except as provided in paragraph (j)<3) of this section, dur ing the collection; processing, including incineration; packaging; transporting; or deposition of any asbestos-containing waste material which is generated by such source. (2) All asbestos-containir.g waste ma terial shall be deposited at waste dis posal sites which are operated in accord ance with the provisions of 01.25. (3) Rather than meet the requirement of paragraph (j) (1) of this section, an owner or operator may elect to use either of the disposal methods specified under (j) (3) (i) and (ii) of this section, or an alternative disposal method which has received prior approval by the Ad ministrator: (i) Treatment of asbestos-containing waste material with water: <A) Control device asbestos waste shall be thoroughly mixed with water into a slurry and other asbestos-containing waste material shall be adequately wetted. There shall be no visible emis sions to the outside air from the collec tion, mixing and wetting operations, ex cept as provided in paragraph if) of this section. (B) After wetting, all asbestos-con taining waste material shall be sealed into leak-tight containers while wet. and such containers shall be deposited at waste disposal sites which are operated in accordance with tire provisions of 61.25. (C) The containers specified under paragraph (j)i3)(i)(B) of this section shall be labeled with a warning label that states: Caution Contains Asbestos Avoid Opening or Breaking Container Breathing Asbestos Is Hazardous to Your Health Alternatively, warning labels specified by Occupational Safety and Health Standards of the Department of Labor. Occupational Safety and Health Admin istration lOSHA) under 29 CFR 1910.93a(g) (2) tii) may be used. (ii) Processing of asbestos-containing waste material into non-friable forms: (A* AH asbestos-containing waste material shall be formed into non-friable pellets or other shapes and deposited at waste disposal sites which are ooerated in accordance with the provisions of J 61.25. iB) "There shall be no visible emis sions to the outside air from the collec tion and processing of asbestescomoining waste material, except as specified m paragraph (f) of this section. (4) For the purposes of this para graph (j), the term all asbestos-con taining waste material as applied to demolition and renovation operations covered by paragraph (d> of this sec tion includes only friable asbestos waste and control device asbestos waste. (k) Waste disposal for asbestos mills: The owner or operator of any source covered under the provisions of para graph (a) of this section shall meet tire following standard: (l) There shall be no visible emis sions to the outside air. except as pro vided in paragraph (k) (3) of this section. during the collection, processing, pack aging, transporting or deposition of any asbestos-containing waste mate rial which is generated by such source. (2) All asbestos-containing waste ma terial shall be deposited at waste disposal sites which are operated in ac cordance with the provisions of 5 61.25. (3) Rather than meet the requirement of paragraph (k)(l) of this section, an owner or operator may elect to meet the following; requirements m para graphs (k) (3) (l) and (u). or use an alternative disposal method which has received prior approval by the Admin istrator: <i) There shall be no visible emissions to the outside air from the transfer of control device asbestos waste to the tailings conveyor, except as provided in paragraph (f) of this section. Such waste shall be subsequently processed either as specified in paragraph ik> (3) (ii) of this section or as specified in paragraph i j) (3) of this section. (ii) All asbestos-containir.g waste material shall be adequately mixed, with a wetting agent recommended by the manufacturer of the agent to effectively wet dust and tailings, prior to deposition at a waste disposal site. Such agent shall be used as recommended for the partic ular dust by the manufacturer of the agent. There shall be no discharge of visible emissions to the outside air from the wetting operation except as specified in paragraph (f) of this section. Wetting may be suspended when the ambient temperature at the waste disposal site is less than --9.5eC (ca. 15 F). The ambient air temperature shall be determined by an appropriate measurement method with an accuracy of l'C (p:2:F. and recorded at least at hourly intervals dur ing the period that the operation of the wetting system Is suspended. Records ol En lonntnl R*po<t*r tSc. 61.22[jH3)i so HAZARDOUS EMISSIONS S-412 121:0469 such temperature measurements shall be railed at the source for a minimum o j years and made available for inspec- > on by the Administrator. (1 > The owner of any inactive waste disposal site, which was operated by sources covered under 5 Cl.22 (a>, (c) or (hi and where asbestos-containing waste material produced by such sources was deposited, shall meet the following standards: (H There shnil be no visible emissions to the outside air from an Inactive waste disposal site subject to this paragraph, except as provided in paragraph tJ) la) of this section. (2i Wanting signs shall be displayed at all entrances, and along the property line of the site or along the perimeter of the sections of the sue where asbestoscontaining waste material was deposited, at intervals of 100 m ica. 330 ft) or less, except as specified m paragraph <1>(4) of this section. Signs shall be posted in such a manner and location that a person may easily read the legend. The warning signs required by this paragraph shall conform to the requirements of 20" x 14" upright format signs specified in 29 CFR 1910.145 (d) (41 and this paragraph. The signs shall display the following legend In tiie lower panel, with letter sizes and styles of a visibility at least equal to those specified in this paragraph. LEGEND Asbestos Waste Disposal Mte Do Not Create Dust Dreaming Asoestcs is Hazardous to Your Heaitb Notation 1" Sana Serif. Gothic or Bloch *,t" Sans Serif. Gothic or Block 14 Point Gothic Spacing between lines shall be at least equal to the height of the upper of the two lines. (3) The perimeter of the site shall be fenced in a manner adequate to deter access by the general public, except as specified in paragraph i]j<4) of this section. <4) Warning signs and fencing are not required where the requirements of paragraphs (1 M5> in or di) of this sec tion are met. cr where a natural barrier adequately deters access by the general public. Upon request and supply of ap propriate Information, the Adminis trator will determine whether a fence or a natural barrier adequately deters ac cess U> the general public. (5) Rather than meet the requirement of paragraph ri>(l) of this section, an owner may elect to meet the require ments of this paragraph or may use an alternative control method for emissions from inactive waste disposal sites which has received prior approval by the Administrator. (i> The asbestos-containing waste material shall be covered with at least 15 centimeters (ca. 6 inches) of com pacted 'non-asbestos-containing mate rial, and a cover of vegetation shall be grown and maintained on the area ade quate to prevent exposure of the asbestos-containmg waste material; or (ii) The asbestos-containing waste material shall be covered with at least 60 centimeters (ca. 2 feet) of compacted non-asbestos-containing material and maintained to prevent exposure of the asbestos-containing waste: or (iii) For inactive waste disposal sites for asbestos tailings, a resinous or petro leum-based dust suppression agent which effectively binds dust and controls wind erosion shall be applied. Such agent shall be used as recommended for the partic ular asbestos tailings by the dust sup pression agent manufacturer. Other equally effective dust suppression agents may be used upon prior approval by the Administrator. For purposes of this para graph. waste crankcase oil is not con sidered a dust suppression agent. (40 FR 4S292, October 14. 1975j 61.23 Air-clo:ming. If air-cleaning is elected..as permitted by 61.22(f) and 61.22id> (4) uv), tire requirements of this section must be met. (40 FR 48292, October 14. 19751 <a) Fabric filter collection devices mdst be used, except as noted in para graphs .(b) and (c) of this section. Such devices must be operated at a pressure drop of no more than 4 inches water gage, as measured, across the filter fabric. The airflow permeability, as determined by ASTM method D737-69, must not exceed 30 ft*/miryft* for woven fabrics or 35 ftVmin/ft* for felted fabrics, except that 40 ftVmin/ft! for woven and 45 ft5/ min/ft* for felted fabrics is allowed for filtering air from asbestos ore dryers. Each square yard Of felted fabric must weigh at least 14 ounces and be at least one-sixteerth inch thick throughout. Synthetic fabrics must not contain nil yam other than that which is spun. (b) If the use of fabric filters creates a fire or explosion hazard, the adminis trator may authorize the use of wet col lectors designed to operate with a unit contacting energy of at least 40 inches water gage pressure. <c) The administrator may authorize the use of filtering equipment other than that described in paragraphs 'a> and fb> of this section if the owner or operator demonstrates to the satisfaction of the administrator that the filtering of par ticulate asbestos material is equivalent to that of the described equipment. (d> All air-cleaning equipment au thorized bv this section must be properly installed, used, operated, and maintained. Bypass devices may be used only during upset or emergency conditions and then only for so long as it takes to shut down the operation generating the particulate asbestos material. 61.21 Reporting. The owner or operator of any existing source to which this subpaxt is applicable shall, within 90 days after the effective date, provide the following information to the administrator: (a)A description of the emission con trol equipment used for each process: ib* If a fabric filter device is used to control emissions, the pressure drop across the fabric filter in inches water gage. U) If the fabric filter device utilizes a woven fabric, the airflow permeability in ft'/min/ft'; and. if the fabric is syn thetic. indicate whether the fill yarn is spun or not spun. i2) If the fabric filter device utilizes a felted fabric, the density in oz/yd5. the minimum thickness in inches, and the airflow permeability in .ftVaun/ft'. (c) For sources subject to 61.22(j) and 61.22 (k): (1) A brief description of each process that generates asbestos-containing waste material. (2) The average weight of asbestoscontaining waste material disposed of. measured in kg/day, (3) The emission control methods used in all stages of waste disposal. (4) The type of disposal site or incin eration site used for ultimate disposal, the name of the site operator, and the name and location of the dispos"1 site. (d) For sources subject to < .22(1): (1) A brief description of the site. (2) The method or methods used to comply with the standard, or alternative procedures to be used. (e) Such Information shall accom pany the information required by 5 61.10. The information described in this section shall be reported using the format of Appendix A of this part. (40 l: R 48292. October 14. 1975; 61,23 \Tasic di>poaal silcs. In order to be an acceptable site for disposal - of asbestos-containing waste material, under 61.22 (j) ana (k), an active waste disposal site shall meet the requirements of this section. (a) There shall be no visible emissions to the outside air from any active waste disposal site where asbestos-containing waste material has been deposited, except as provided in paragraph (e) of this section. (b) Warning signs shall be displayed at all entrances, and along the property hne of the site or along the perimeter of the sections of the site where asbestoscontaining waste material ls deposited, at intervals of 100 r.i 'ca. 330 ft) or less except as specified in paragraph (d) of this section. Signs thall be posted in such 8-18-78 (Sac. SI.25(b)J PuHixlwd (> TIH bl/Rl U ' ()l MIl'iNU. All AIKS. IM' . W -\ SI I INC.TON. D C. 20037 CC* OODnnnncT 121:0470 FEDERAL REGULATIONS q manner and location that n person may asily read the legend. The wnrr.inc igns required by Uus paragraph shall cc'-nii to the requirement.? of 20" x 14" u it format signs specified m 29 CFR ..i45'dJ i4> and tins paragraph. The .is shall display the (allowing legend n the lower panul. with letter sices and styles of a visibility at least equal to taoie specified in this paragraph. LLC.END Asbestos Waste Disposal Srrr Do Not Create Dust Breathing Asbestos is Hazardous to Youf Health Notation 1" Sans Serif. Gothic or Block Va" Sans Serif. Gothic or Block 14 Tolnt Cothto pacing between lines shall be at least equal to tiic height of the upper of the two lines. (c) The perimeter of the disposal site nail be fenced in order to adequately eter access to the general public except as specified m paragraph id) of this section. (d) Warning signs and fencing are at required where the requirements of iragraph (e)(1) of this section are met. or whore a natural barrier ade quately deters access to the general ibhc. L*pon request and supply of ap,-opnate information, the Administra te will determine whether a fence or a natural barrier adequately deters access to the general public. ( lather than meet the require. paragraph (a of this section, an i .'r or operator may elect to meet Uiu requirements of paragraph 'e>(l> or '") (2) of this section, or may use an al- mative control method for emissions om active waste disposal sites which rjxs received prior approval by the Administrator. (1) At the end of each operating day, at least once every 24-hour period iile the site is in continuous operation, the asbestos-containing waste material which was deposited at the site during : operating day or previous 24-hour riod shall be covered with at least 15 itimeters lea. 0 Indies) of compacted non-asbestos-containing material. (2) At the end of each operating day. i at least once every 24-hour period die the disposal site is in continuous operation, the asbestos-containing waste material which was dc;>osited at the site H"nng the operating day or previous 24- ur period shall bo covered with a res ults or petroleum-based dust suppres-. sion agent which effectively binds dust and controls wind erosion. Such asent Tuall be used as recommended for the I rticulax dust by the oust suppression agent manufacturer. Other equally ef fective dust suppression agents may be used upon prior approval by the Admin istrator. For purposes of this paragraph, waste crankcase oil is not considered a dust suppression agent. [40 FR 48292. October 14. 1975! (Sec. 114 of the Clean Air Act as amended (4 2 U.S.C. 7414)1 Subpart C--National Emission Standard for Beryllium 61.30 Applicability. The provisions of this subpart are ap plicable to the following stationarysources: (a) Extraction plans, ceramic plants, foundries, incinerators, and propellant plants which process beryllium ore, beryl lium. beryllium oxide, beryllium alloys, or beryllium-containing waste. (b> Machine shops which process beryllium, beryllium oxides, or any alloy when such alloy contains more than 5 percent beryllium by weight. 61.31 Definitions. Terms used In this subpart arc de fined in the act. in subpart A of this part, or m this section as follows: (a) "Beryllium" means the element beryllium. Where weights or concentra tions are specified, such weights or con centrations apply to beryllium only, excluding the weight or concentration of any associated elements. (b) "Extraction plant" means a fa cility chemically processing beryllium ore to beryllium metal, alloy, or oxide, or performing any of the intermediate steps in these processes. (c) "Beryllium ore" means any natu rally occurring material mined or gathered for its beryllium content. (d) "Machine shop" means a facility performing cutting, grinding, turning, boning, milling, deburring. lapping, electrochemical machining, etching, or other similar operations. (e) "Ceramic plant" means a manu facturing plant producing ceramic items. (f) "Foundry" means a facility en gaged in the melting or casting of beryllium metal or alloy. (g) "Beryllium-containing waste" means material contaminated with beryllium and.-or beryllium compounds used or generated during any process or operation performed by a source subject to this subpart. (h) "Incinerator" means any furnace used in the process of burning waste for the primary purpose of reducing the volume of the waste by removing com bustible matter. <i> "Propellant" means a fuel and oxi dizer physically or chemically combined which undergoes combustion to provide rocket propulsion. (j) "Beryllium alloy" means any metal to which beryllium lias been added in order to increase its beryllium content and which contains more than 0.1 per cent beryllium by weight. <k) "Propellant plant" means any facility engaged in the mixing, casting, or machining of propellant. 61.32 Emiion standard. (a) Emissions to the atmosphere from stationary* sources subject to the provi sions of this subpart shall not exceed 10 grams of beryllium over a 24-hour period, except as provided in paragraph (b) of this section. (b) Rather than meet the require ment of paragraph (a) of this section, an owner or operator may request ap proval from the Administrator to meet an ambient concentration limit on beryl lium in the vicinity of the stationary source of 0.01 jig/m*. averaged over a 30-day period. (l) Approval of such requests may be granted by the Administrator provided that: (i) At least 3 years of data is avail able which in the judgment of the Ad ministrator demonstrates that the fu ture ambient concentrations of beryllium in the vicinity of the stationary source will not exceed 0.01 pg/mJ, averaged over a 30-day period. Such 3-year period shall be the 3 years ending 30 days before the effective date of this standard. <li) The owner or operator requests such approval in writing within 30 days after the eflective date of this standard. (iil) The owner or operator submits a report to the Administrator within 45 days after the effective date of this standard which report includes the fol lowing Information: (a) Description of sampling method Including the method and frequency of calibration. (b) Method of sample analysis. (c) Averaging technique for determin ing 30-day average concentrations. (d) Number, identity, and location (address, coordinates, or distance and heading from plant) of sampling sites. (e) Ground elevations and height above ground of sampling inlets. (/) Plant and sampling area plots showing emission points and sampling sites. Topographic features significantly affecting dispersion including plant building heights and locations shall be included. (<;) Information necessary for esti mating dispersion including stack height, inside diameter, exit gas temperature, exit velocity or flow rate, and beryllium concentration. <fi) A description of data and proce dures (methods or models) used to de- En.i ronminl Rpor f IS*c. 61.32(h)! 62 CCR 00000005 % APPENDIX B Chm ' 57:0401 OCCUPATIONAL SAFETY AND HEALTH STANDARDS SUBPART Z--TOXIC AND HAZARDOUS SUBSTANCES (Excerpts from Code of Federal Regulations, Title 29, Chapter XVII, Section 1910.93 of Subpart G redesignated as 1910.1000 at 40 FR 23072, May 28, 1975; amended at 41 FR 11505, March 19, 1976; 41 FR 35184, August 20, 1976; 41 FR 46784, October 22, 1976; 42 FR 3304, January 18, 1977 (Corrections); 43 FR 2586, January 17, 1978; 43 FR 5963, February 10, 1978; 43 FR 11527, March 17, 1978; 43 FR 13563, March 31, 1978; 43 FR 19584, May 5, 1978; 43 FR 27962, June 1978; 43 FR 28472, June 30, 1978; 43 FR 45762, October 3, 1978; 43 FR 49726, October 24, 1978; 43 FR 51759, November 7, 1978; 43 FR 52952, November 14, 1978; 43 FR 57601. Decembers, 1978; 44 FR5446, January 25, 1979; 44 FR 14554, March 13, 1979; 44 FR 50338. August 28, 1979; 44 FR 60980. October 23. 1979; 44 FR 68827, November 30, 1979 (Corrections); 45 FR 35212, May 23, 1980; 45 FR 54333, August 15, 1980 (Corrections); 46 FR 6134, January 21, 1981) Editor's Sole: The effective date of the Jan. 21, 1981, amendments to section 1910.1025 was ex tended from Feb. 20, 1981, to March 30, 19S1, in the Feb. 6 Federal Register In accordance with President Reagan's Directive. .utopjrt Z--Toil: nd Hazardous Substances Sec.: 1910 1000 Air Contaminant*. 1010.1001 Asbestos. >910.1002 Coil txr pitch volatiles; Interpre tation of term. 1910.1003 1910.1004 1910.1005 1910.1004 1910.100? 4-NUrobiphenyl. alpha- Naphthylamlue. 4.1` -- M-tMlene fcl, (2-chloroam- linc). [ Deleted | Methyl chlorometbyl ether. 3.3'--DlThlorobcr.zidine (end Its salt-1 1910.1009 hla-Chloromethvl ether. 1910 1003 beta-Naphthylamlne, 1910 1010 Bem-ldlne lino ion ' 4-Amtnodipheny* 1910.1013 Ethyler.elfiilnr. 1910.1013 fcxca-Pronsolactone 1910.1014 2-Aertvlamlnofluorerie. 1910.1015 1910.1016 1910 101? 4 Dl methflammoiir.o benzene. N-S itroso^in-eihyh.mtoe. Vir7l chloride. 1910.I01S Inorganic artenic. 1910.1025 Lead. 1910.1028 Benzene. 1910.1029 Coke oven emissions. 1910. KWJ Cotton duil. (OnviicdJ t9l0.1C44 l,2-4ibiomo-3-chloropropane. 1910.104! Aasiommle. 1910.1046 Exposure to cotton dust in cotton gins. (Omitted! 1910 1490 Source of standards. 1910.1200 Standards organization*. " '910.1000 contaminants. ut employee's exposure to any ntaici.ai luted m uMc 7- 1. Z-2. or Z-3 of this section ihall be limited In accord ance with the requirements of the follow ing paragraphs of this section. (a) Table Z-l: (1) Materials with names preceded by "C"--Ceiling Values. An employee's ex posure to any material in able Z-l. the name of which Is preceded by a "C" (e g., C Boron trifluoride). shall at no time exceed the ceiling value given for that material in the table. (2) Other materials--fi-hoyr time weighted averages. An employee's expouirc to any material in table Z-l, the name of which Is not preceded by "C". In any 6-hour work shift of a 40-hour work week, shall not exceed the 8-hour time weighted average given for that material In the table. tb) Table Z-2: 11) S-ftour time weighted averages. An employee's exposure to any materia! listed in table Z-2. in any 8-houi work shift of a 40-hour work week, shall not exceed the 8-hour time weighted average limit given lor that material in the table. t2> Acceptable ceiling concentrations. An employee's exposure to a rr.atariat listed in table Z-2. shall not exceed at any time during an 8-hour shift uie ac ceptable celling concentration limit given *`or the material in the table, except for a time period, and up to a concentration not exceeding the maximum duration and concentration allowed !n the column under "acceptable maximum peak above the acceptable ceiling concentration lor an 8-hour shift". (3) Example. During an 8-hour work shift, an employee may be exposed to a concentration of Benzene above 25 p.pan. (but never above 50 p.p.m.) only for a maximum period of 10 minutes. Such ex posure must be compensated by expo sures to concentrations less than 10 p.p.m. so that the cumulative exposure for the entire 8-hour work shift dees not exceed a weighted average of 10 p.p.m. (c) Table Z-3: An employee's expo sure to any material listed m table Z-3, in any 8-hour work shift of a 40-hour work week, shall not exceed the 8-hour time weighted average limit given for that material in the table. (d> Computation formulae: (1) 6) The cumulative exposure lor an 8-ho*tr work shift shall be computed as follows: ssc.r.+cr.-!- . . . c.r. B where: E Is the equivalent exposure for the work ing shift. C ts the concentration during sty nerloJ of time r where the concentration remains constant. r la the dur.fij, in hours of the exposure at the concentration C. The value of E shall not exceed the 8hour time weighted averaee hmit in table (Sec. 1910.1 OOQld Ml 1 '.ill Published by Tilt BUREAU OF NATIONAL AFFAIRS, INC.. WASHINGTON, D.C. 2003* CCR 000000054 57:0402 REFERENCE FILE 2-1. Z--. or Z-? for ilic nuiaul in- volwd. (ti) To illustrate the formula pre scribed in paragraph (d)(l)(i) of the sccti''". note that isoamyl acetate has an ;r time weighted average limit of p.p.m. (table Z-\). Assume that an employee is subject to the following exposure: Two hours exposure at \S3 ppm ^Tso hours exposure at 7S p.p.nJ. Four hours exposure at SO ppm. Substituting Otis information in the formula, wc have 2 x 150 + 2 X 75 ft X50 ----------=ei.2Sppm. 6 .Since 81.25 p.p.m. is Jess than 100 p.p.m.. the 8-hour time weighted average limit, the exposure is acceptable. (2) ti) In case of a mixture of air con taminants an employer shall compute the equivalent exposure as follows: c, c, c E-= --+--+ . . . -- L, L, L Where: E- la the equivalent exposure for the. mixture. C Is the concentration or a particular con taminant, iL is the exposure limit fur that contami nant. Irom ublc 2-1. 2-1. or 2-3. The value of E- shall not exceed unity <n. (ii) To illustrate the formula pre scribed in paragraph (d)(2)(i) of the sec tion, consider the following exposures: Material Actual concentralion pfAheur tipoaiuc fc-hour ump weighted *<>rare exposure limil Acetnn. Twt-lf ^1 ) SOD ppm... I.9TX) p.p.m. k-tuttauon. iT.iM( 7.1). *5 p p m... . 2i.i ppm. Tolurne 7.. Me Z. 2)........ luppsi.... 2Uj ppm. Substituting in the formula, we have: 500 45 40 1 .000 200 200 E- =0 500 4- 0.22 54 0.200 ..=0.325 Since E. is less than unj ty (1). the expo sure combination is within acceptable limits. (e> Ip achieve compliance with para graph <a> throuan (d> of this section, administrative or engineering controls must first be determined and imple mented whenever feasible. When, such controls arc not feasible to achieve full compliance, protective equipment or any Kher protective measures shall be used o keep the exposure of employees to air contaminants within the limits pre scribed in this section. Any equipment and'Or technical measures used for this Purpose must be approved for each par ticular use by a competent industrial hygienist or other technically qualified person. Whenever respirators are used, their use shall comply with S `910.134. Table Z-l- Substance p.p.m.* me ./XU * AiviaMi-fivile................................ Acetic .tCI-l..................................... 4c> 1 ic -.mliydrule......................... Ac.-tai e............................................ . Ar> ici.itnl*.................................. Ac* 1? 1 v.c ilidiloride. s-v 1. 2 200 10 5 1.000 40 Aret` Icne li-trji-rjiuid.-............ Acrolein. ........................ 1 0. 1 Aldrin --Skin................................. All'i alcohol- Skin..................... 2 l C Aljvldycidvl ether (AGE). .. 10 Ally I propyl \\511lhrte................ 2 2-Amnoi-tlianul. See Ethanol- amtne.................................... 2-Amtnopvndine...................... nJ Ammonia.................................... 50 Ammonium suli-iutu-' (An- mate)............ ................ n-Am>l acetate............................... 100 iff Amyl acetate............................ 325 Aniime--Skln.................................. 5 Ai-.Ki-lir.e (o, p. isomers) -Skin..................... Ar.lni'ony and coin pounds tas ,-in............................................................... ANTI' (alpha naphthyl thiourea) ............ ''Ofiiamo Arsenic compounds (as A)) [43 FR W5S4. May 5. 14*8) Arsine.. ................ Atmphus-rnftliyl- Skm.. .. Barium 'soluble compounds). p-llrnJiv;uinnri-. s?c Quin otic. Dcniny i p#rondr.......................... Sm-.\l Chloride.................. .Hiphens I, s--e Diphenyl........... Boron oxide.................................. C Boron inlluofidf................... Hronnnr......................................... BrorroMr---Skin...................... Buianothiol. see Butyl mer- 3-cBaucttaamn n...#........,................................................................ 2-Bmoiy ^thano' (Butyl Cellosolve) --Skin.............................. Butv| acetate in-butyl acetate). ktc-Butyl aCMBtr............................ lert-Buiyi acetate........................... Butyl alcohol................................... aec-Butyi alcohol............................ tert-Butyl al<-<hol.......................... C BuiyUmihn--Skin..................... C tert-Butyl chromate'i.as CrO,i --Skin ................................. r.-Butvl jlycidyl ether (BOE).. 0 04 1 01 05 1.000 200 50 140 2W 200 100 150 too 5 50 10 O-tettButrUoluene..................... 10 Calcium oxide....................................................... Camphor............................................. Ca.-"iryi (Serin $.')............................................. Carbon black ....................................................... Carbon dioxide............................... 6,000 Carbon monoxide. .................. -0 Chlordanc--SWjn............................................. Chlorinated camphene--Skin.................... Chlorinated diphenyl oxide............................. C Chlorine 1 Chlorine dimidr ............. ....... ... ai C Chlorine tnfluofide................... C Chlorn&eetaldebydc.................. o. i i Chlorowruiphennne (phenacylchloride)..................... a 05 Chlorobmtrne (monochlonjb*nrnei......................................... 75 0-Chlorobenty Udene malononiinle (OCDM)............ CUnrotiromomelliane................... 0.05 200 5-Cl-loto-l .3-tiutadiejie, see Chloropfene ........................ .. Cfiiorodiphenyl (42 percent Chiormei --Skin ........................ Ct.lr.rodiphenyl (54 percent Chlorincl --Skin ........................ 1-Chlnro 2 3-cpmypropane, see Epichioehydrn-*........................... 3-Chiorr*:h*nol, see Ethylene cf- loryht dfli'................................ Chliro-lh>iYiiv. >ce Vjuyl chloride ...................................... C ChbiroJ-.r.m UricMororr-K n jrr....................................... so I Chl'iKi l-riitropropjiie............... CM.,mm nn ........................ 20 0.1 CliHiropre'.e 12-chlnro-l.3- buUdier.e) -Skill....................... 25 360 25 20 2.4;>l :o 14 0. 25 0.15 5 3 45 1J 2 3$ IS 421 6i0 19 0.5 0.5 0.3 0.5 0. 2 0.2 0.5 5 0.7 5 2.200 590 240 710 950 950 300 450 300 IS a 270 35 eo 5 2 4 3.5 9.000 55 0.5 0.5 as 3 0.3 0. 4 3 0.3 350 0.4 1,050 1 0.5 240 IPO 0.7 90 Tuble Z-I-Continued p.p m. mc./M Chromium, sol. chr.itn'c. chfumous salu a< t.:r....... ............................. Mot.il and i'1-ol. sail? ...................................... Coal Ijr pitch vnUliIrs (heneetie sniupi* (tjctior.' a>iUirCe-if. II ,p. pht'n.inthrenc, acridine, ch-yse-ir. (') rtne.............................. Coh.t.i, tne;.i; funis' and dust.......................... Cup-,`r Jui;-..'............................................................ 1 lusts on l Misis................................................. Cotin-i iius: ;raw:........ ........................................ Crac hethtcide ................................................... CrcsoT tall corners) - Skip.......... 5 I'rotpi'.aldo.ydc............................. 2 Cun-.rr.e-Skin...................................... 50 Cyanide ros CN)-Sltin...................................... Cyclohexane..................................... 300 Cyclohexar.ol...................................... SO Cyclohexanone...................................... 50 Oyciohf xrr.e ................ 300 Cyclopentadicne.................................. 74 2, 4-1).. .......................................................... DOT-Sk.rt............................................................. DDVP. SVin........................................................... DcCuhorane- 5kin,.................... 0. 05 DcmctonlS; - $km.................................................. Duct :one alcohol (4-liy Jroxy- 4-methyl-.'pcni.vtone)................... 50 1,2-Oiammtwrhane. see Et hy li-ne-luminc................................................ Dutoineihai-.e.................................. 0.2 J)ilit,r;inp. ................................ 0. 1 Diborane............................................. Dibutyl phosphate.......................... 0.1 ] hihciyjphthalatr................................................. C chDiehlcroheiueno.................. so p-r>iehlorohenirn-..................... 75 lltcMnrodtl'.aatO'.v.etliane........... . 1.003 l,3-D;el:lor.-5.i.di.-i.eth} 1 hvdir.toir:.................................. ],|.Di:Mor.^iliane,. . ... 1.2-Dichlor.)eth)-|'nc................... 200 2CO C I)i< hlorne;!t> , ether -- Skin.. Dichlcrorrethane, see Met Ii a lenechlortde.................... 15 Dkhloromonohuoromcthanp .. l. 000 C l.l-DicMt.rO-l-t'.'.lructhane... 10 !.?-Dicl.'.orcpropari-\ see Brupvlencjiclilo: id................ Dichluroutrahuoto* thane......... . 1,000 Oleldri.-i- Skin.............. ................... rile* My lamlne.......... ........................ l)lc<hyl*mi.-.o ethanol--Skin... Diethylethfr, See Ethyl tther__ hinuorortihromomeUiane. C Diclveidyl ether (DUE)......... 0. 5 Dihydrpiyb'MCue. aec Hydri/iuinone.............................. .................. . . DiiSCiLuiyJ ketone........................... 50 DnsopropyUrti Inc--Skin............. 5 Dlrurthoxyii,ethane, see Methylal......................................... Dimethyl acetamide--Skin........ 10 DlniethyUrr.l/ie............................... 10 Diiuethy lan.mobeniene, ut Xylidene. tnTTii'Vri-) larii'-.-ietS -dimethyS- anihnel- S'n.............................. 'Dimethylbemene. see Xylene......... Dimethyl 1.:-diUroni&-2,;-dt. chloroethyl phosphate. riiibron j............................................. . hlmethy Ifonnamide --Skin........ 2,$-tnn-.ethy:V ptanor.e, see Uusol/ulyl ketone......................... l.l- himethy u.> <lt aunt--Skin... Uimeuiy iphtt.aiaie.............................. . UimeihyUuKjte--skip................. DmltroOeniene (all isomers) -- Skin....................................................... DinitiCfO erejl--Skin.....___ ..... Tllniirutoluer.e -- Skin...................... ..... Dionne (iJJ-thyler.e diotitle)-- Skin .................................................. niplienyl........................................... 10) a2 Dipnenyimetharie dnaoevanate (see Methylene bisphenyi isocyanate : MUI>............................... Dipropylere dycol methyl ether --.Skin 100 Dl-sep. octyl !' thalate (Di-2elhvlhetvirh haiate)........................................ 0. 4 1 00.. 21 0. X 1 l 15 *6 245 5 I, 050 200 2CO 1.015 200 10 1 .....l 0.3 0. 1 240 0. 4 0. I 0.1 5 5 300 450 4.950 0. 2 400 790 90 4, 200 60 7.000 28 290 20 34 Id I 0.2 15 360 1 600 5 F.pichlorli) dr.r -Skin.................. El'S - Skin . . 5 19 0.5 See routootfi at ehd of tauJe. 'V. Chemical Regulation Beponer Sec. 1910.1000(e). Table Z 1j 44 CCR 000000055 Table Z-1 -Continued Table Z-l-Continued Table Z-1 -Continued Sgbxience p.p.tn.* mg./M* * Substance p.p.nv* * 6ubstar.ee p.p.ffl* mf./M* J,7 Kr* s l>r,r*". KS I'rGpvX'nrOJi'te. . ....... 1.3-FfOiy-l-|'lno). irf 'a i > civtoi................................ hn*tinol. sv Ethylmsrcnpt*n.............................................. Elhanuljmlnt ... .................. ?.>:t'iox>cthx>'Ol -- Skin .............. ? El*iotvrthx laeetei* iCellolot re ifvlatf) -- Mcln........ . .... Ethy 1 sevk.vte.. v.myl .cryUie-Fkin. ................ ElSvl uirunul (cthar.o.)............... Filivlniirir.................... ................. Ethyl jce-imyi knona t6- mttryl-J-htt'tJnane)............... Ethyl hrntrnr................................. Elhvt Liror.;ilf................................ Ethy t b*ii) i ketone (4......------------ .... Elhvi rMorMe................. .. Ethyl mi er....................................... Etl.y) formate.................................. C Ethyl mercaptan................ Ethyl Uirai#................................... Ethylene eiilorohydrtn--9kln.. Ethy lrnedlamlre.................. C Kthy Irne rlj col dlnlliati and or M:ro.-iyc*r'n-- Fkln... Elhylene glycnt m"~omMhyl etner ace ui v >fa >let`-yl 3 200 ICO (to :i S.ono 19 too 200 i.CCO ICO 10 1CU s 10 a2 Elhylene imlne--Skin................ Ethylene o:Ca................................ Ethyllolft* f hlorlle. See 1,1- as IO N-E thy Imorpholine--Skin......... 30 yetbam................................ ............... EMr-irane-tliim dust. Fluor) 1* iu F /................................. Fluorine.................................. .. al F'lH'raxmt'Icr methane........ i.oco Formic acid...................................... s Furfural -- 5kln................................ i Vorfjryl elvonol........................... .. w Ulyo'ioi ii.ir.pbiy-iprcpenv.l...................................... so OJyrol ir.oric-einyl ether, see r-Ethoivetranol........................... OuthtOfi a-. Set Al JtpftM* methyl.............................................. .. . ................ ................ .. itchier-->kln............................ .tine(n- plane'............ .. SCO . .MitchlorOMraiie -- 5 tin............ ilM3Chlf.fon.it hthelent -- si In.. . Mrtane tn-l flint)..................... .. J-Hatan.n-..................................... Ketone 'Methyl Lsobutyl k'tnn)........................................... iee-Meiyi acetate............................ Hvrt"*tine--'iln............................ I SUO 100 no id 1 Mydwcn brunilde........................ C Hydrogen ch.p'ld*.................... Hy dr even e> ari-ie --."i In....... ITylnVer. D'rriiJa tix/'i)............ Hydo*en ielenlde........................ 3 3 10 1 am Hydrryjuln jne................................... C todti.e............................................ ai Jn*n onde film*................................ jioxmvl a.ftile............................... Hcwinyl *|:3h-l............................... 10) 1J0 lsobutyl areieta.............................. itobrnyl alconol.............................. Itopho-nre........................................ j'opropyl #eeti!f.................... .. lynpropyl alcohol______ ________ isoprupylinlRi......... Isipr .pi let her................................. hopropyl <: ye Idyl ether HOE). Ketent................................................ Lln`len*-- 5kln.................................. ISO 100 35 36) *00 4 600 50 as Lithium hy 1: ide.............................. Ll'.ii (ilqutiled petroleum fast.................................................. 1.000 Mr,fimi oMe tune................... Vi*thion -Sdii.............................. rhy<irie*............................ C V'a\**r\*................................... Mfpltyl Oi'.d.................................... ais 'is'"' Melhonethtol, iei Mtlhyl mereiplji....................................... Vrthoeye*- 'nr..................................... 3 Metftne .ethanol, see Methyl rellewolee......................................... Methyl aretati.................... ........... Mrlhy j S'e!' ter.i (or iflvnu. . .. 1,<XX> Methyl anelvlen* propadlen* mixture iMAPI'l...................... Methyl aerv.ale-skin . ........... Me thy 111 Mhr.Mtint > methane).. 1.000 10 l.oan Metny nW-r, i (c.clhenoi).......... ?.o 10 6 740 640 1,400 100 18 436 890 2.600 1.200 300 26 850 16 26 1 94 15 1 12 0.3 5, tOO 9 20 300 ISO 0.6 0. fl 3,000 )0 0.2 1,800 410 410 300 1.3 10 7 11 i. 4 0.2 2 1 10 624 360 700 300 140 940 960 12 2.100 240 a9 as aois 1,500 IS IS I & 100 010 t.&so I. wo as 9.ICO 300 12 Methyl amyl alcohol, see Methyl lsobutyl carbind........ Methyl (rj-amyl) kstona (2* Hspunone).................................. 100 46S C Methyl bromide--Skin............ 20 50 Methvl putvl ketone, see 2- Hexsnone.......................................... Methvl esllo<olv--Skin............... Methyl cellosclvc acetatfr-Sfcla 24 25 80 no Methyl chloroform......................... Melhylcyclohcxone.............. .. Meth> Icyclvheiiiioi....................... 350 600 100 1,900 2,000 470 0-Mtthyiryclohxmnone -- Skin.. 100 460 Methyl ethyl ketor.e IMEL), see 2-t>utanone................................ . Methyl formate............................... 100 Methyl Iodide--Skin..................... 6 Methyl lso`.iu,ty I ca.-Dlnol--Skin. 25 25) 28 100 Methyl isobutyl ketone, see Hexoria............................................... Methvl isocyanate--Skin............ 0.01 0.06 C Methyl mercaptan................... Methyl methacrylate.................... 10 100 20 410 Methyl propyl ketone, sea 2- Pentanone......................................... C a Methyl styrene........................ 100 450 C Methylene blsphenyl Isocyanate (MD3)....................... <MT2 0.3 Molybdenum: Soluble compounds................... Insoluble compounds.............. .............. ............ 6 IS Monomethyl aniline-- Skin......... 2 9 C Mononielhyl hydrexlne-- Skin................................................ Morpholine--Skin........................ Naphtha (coaltar)................ .. Naphthalene.................................... Nickel carbonyl.............................. 0. 2 JO 100 10 a ooi 0.V ?0 400 60 0.00) Nickel, metal and soluble .........empds, as Nl.................................... ................................t Nlcctlne--Sxln.................................... . 0.6 Nltrie acid........................................ 2 6 Nitric oxide............................ .. 26 p-Nltroanlltna--Skin......... . 1 6 Nllrobeneene--Skin...................... p-Nltrorhlorobn*ene--Skin.......... Nltroethane...................................... " Nitrogen dioxide.......................... Nitrogen tntluonde............. ........... C Nitroglycerin--Skin...................... 1 ................ 100 10 0.2 6 1 510 29 2 Nltromethac.e.................................. 100 1-Nltropropane...... ......................... 2-Nltrcpropane................................ Nitrololuene--Skin................ . Nltrotrichlaromethane. tee 26 26 6 Chloroplcnn..................................... . Dctachloronaphlhalene-- Skin........ Octane.................................................. Oil trust, mineral............................. . Osmium tetrozlde.............................. Oxalic add............................................ Oxygen dlfiuoride......................... 0.OS Oion*................................ ................. 0.1 Paraquat--Skin.................................. Perathion--Skin.................... .. Pentaborane..................................... PentacMnronaphtlialen-- Skin... a ooj Pen tachlorophenol--Skin.___ .... Pentane..................... ...................... . 1.000 2-PenUnone..................................... Perchloroinethyl mercaptan.... 200 ai Perehloryl fluoride......................... 5 Petroleum diulllates (naphtha). Phenoi--Skin................................... 600 6 jvPhenylene diamine--Skin...... Phenyl ether (rapor).................... 1 Phenyl ether-blphenyl mixture (vapor)........................... 1 Phenylethylene. see Styrene...... Phtny I tlyeidyl ethr (POE)... Phenyihydraxme--Skin............... 10 6 Phosdrin (Meyinphos (g) )-- Bkln..................................................... Phosxene (carbonylchloride)... Phoxphine..................................... . ai as Phosphoric acid.................................. PhosPnonis (yallo-w)......................... Phosphorus pentachloride.............. Phosphorus pentasulAda.................. Phoepflorus tnehiorida................. Phtba'iic anhydride............. as 2 Picric Bd--Bkln.......................... .. PlTil to (2.PlealyM,3Indandione)...................................... Platinum (Soluble Salts) as 260 90 90 90 0.1 5 0.008 ai a2 0,6 0.1 i a oi as as 2.9SO TOO as 13.6 2.000 19 ai 7 7 50 22 ai at a4 l 0.1 i i 3 1? ai ai a an Propane........... ............................. 1,000 1,800 n-Prooyl acetate............................. 200 540 Propv| alcohol................................. 200 600 ruPro. yl nitrate...................... 28 110 Propylene d:chlorlde.................... 75 560 Propylene imrne--bkln................ 2 S Propylene cude.............................. 100 240 Propyne. see siethyl&cetylena............................................ Pyrethrum................................................................ * Pyridine............................................. 6 16 Qulnone.............................................. 0.1 ae Rhodium. Metal fume arid dusts, as Rh............................. .. .................. Soluble solta..................................... ............. a) aoci Ronnel.................................................. ......................... 15 Rotenone icninrr.rreiBri................... Selenium compounds (as Se).......... ------ !... 6.2 Selenium heiafluc-ride.................. a os a4 Silver, metal and soluble com pounds.............................................. .............. a oi Sodium fluoroactUlt (1QW)-- Skin................................................... ................... a os Sodium hydroxide............................ ................... 2 6tiblne................................................ 0.1 as SioddjnJ solvent............................. 500 2,00l Strychnine.......................................... .................... 0.14 Sulfur dioxide................................... 6 13 Sulfur hexartgoride......................... 1,000 5,000 Sullurlc acid....................................... .................. l Sultur TTionochlcrlde...................... Sulfur pentafluoride..................... Sulfuryl fluoride.............................. 1a 033 s 60.24 20 ........Systox, see Demeton .................. 2.4.ST.................................................... 10 Tantalum............................................ ................................5 TEDP-Skln..................................... ................ Tellurium............................................ .......... Tellurium hexafluoride................ 0.03 a2 ai a2 TEPP-Skln...................................... ................ 0.04 C TerphenyU.................................. 1 9 1.1.).2-Tetrachlor>2.2-difluoro- ethene............................................. 600 4,170 1.1.2.2-Tetrachloro-1.2-dlfluoro- ethlne........ .................................... 600 4,170 1.1.2.2-Tetrochloroethane--Skin 6 36 Tetracnloromethftne. Carbon. ........tetrachloride................................... TeirnchlorcRiphlhalene--Skin -. 2 Tetraethyl lead (aj Pb)--Skin.. ................. 0.075 Tetrahydrofuran............................ 200 690 Tetramethyl lead ( Fb)-- Skin.................. ................................ Tetramethyl jucclnonltrll*-- Skin.................................................. ................ 0.6 0.075 a Tetranllromethane........................ 1 8 Tetryl (2.4.6-trlnitrophenyl. methylnltramlnt>--Skin....... ................ 1.5 Thallium (soluble com pounds)--Skin as T1.................... ................ 0. 1 Thlram................................................. ................................ 5 Tin (lnorzanlc empds. except oxides............................................ -- Tin (organic empds)....................... C Tc!une-2.4-dlisocyanate......... ......... ............ a 02 2 ai a 14 ^Toluldlre--Skin ........................ 6 22 Toxephene, see Chlorinated camphene......................................... Trlbutyl phosphate......................... 6 1.1.1-Trlehloroethin* * Methyl chloroform..................... 1.1.2-Trichloroethane--Skin..... 10 45 Tlunlumdioxids............................... .............. 15 Ttljhlofomathane, see Chloro form.................................................... Trieh loronaphthalena--Skin........ 5 1.2,J-Vrichloroprt>pene.................. 60 300 1.6.2-TrichVoro 1,1,2-UVf.UOXOalhw.ia........................ -.................... Trlethylarotna.................................. Trlfluoromonobfomometh arve... 1, COO 24 1,000 7,600 1QO 6,100 2.4.b-Tr1nltrophenol, sea Picric acid.................................................... 2,4,6-Trl nluophenylmet hyl- nliramina, see Tetryl.................. Trl (tltrowluene-- Skin................. . Triorthocresyl phosphate.............. ............ ......... 1.6 ai Triphenyl phwphau...................... Turpentine........................................ Uranium (soluble compounds).. Uranium (insoluble compounds) ............ 100 ............. .......... 3 660 a os a 25 C Vanadium: VfOi dust..... ................................. . ViOifume...................................... . ........ .......... 0.6 ai Vinvl banxena, see Styrene......... Vlnylcyanide, see Acrylonitrile. Vtnyl toluene.............. ..................... Warlarln.............................................. Xylar.a (xylol)................................. IjO .............. 100 480 ai 436 XylMin*--Skin................. 6 26 Yttrium............. ................. -............ 7.Inc chloride fume.............. Zinc oxide fume............................... .............. ..................... I 1 6 Zirconium compounds (as Zr).. .............. S Parts of Taper cr ces Pr million parte of cocu.nlnated air by toiu me at 25* C. and 750 mm. Eg pnuuri. * Approximate milligrams of paniculate par cubic meter of air. (No footnote "c" Is used to avoid confusion with calling veioa notations ) Un atmospheric concentration of not more than 0.92 p.p.m.. or personal protection may be oeceeaary lo avoid headache. [Sac. 1910.1000(e), Table Z-11 Published by THE BUREAU OF NATIONAL AFFAIRS. INC.. WASHINGTON. O.C. 20037 9 CCR 000000056 -.0404 reference file Table 2-2 Mettrial t-hc*jT llm* vk)iM ev(_-a* Acceptable ceding coacentrelloo AcrepcaM rriJUnum peak [*> the acceptable celling concede*- tlon for an 6-ftour ihilt, -- -- Concentration AleiUnum durelloo ........................................... 10 p.p.m............. ttp.r.st.................. BOp.pm................. ICtnlnutea. yinum end bery.lluia compound* ....... ......... .. SSj-f.^l1............... 30mlcuipj, 4237.79-1970', n , ^ ,,, CaJmlur.. fume (W7.S-1P7CI)............................ O.Ung. W.......11-1 mP- ......................... ................ CalmUm'dut IZ37.J-1970)............................. ................................... O.Bing.M*................................................ [ Son .lltullM* (237 S-1986)..........................Mppm................. SOp.p.m..................lOOp.p.tn..................... Do. I bon tetrachloride (7J7.17-1967)................ lOp.pjn................. 20 Jl.p.ni..................SXp.p.ffi.................. STT.Inulealn any 4 hours. 1 yiene dibromlil*(ZJ7.3l-1970'.................. 3> ppm............... JOp.p.a................. 50 p.p.m............. i m'nutw. Ethylene dichlond* IZJ7.21-1949)................... W p.p.sc................ ll p.p.m............. 3W p.p.m................A minutes (n any 3 hours. For.Tifcl-lehrd* (Zjrw-iwm..............................Jp.pm..................6 p.p.m....................lOp.p.m.................... JOminuies. f lrrn fluoride iZ37 26*lW9i...............................do........................................................... -.............................. i idJe u ,1ul ;Z37.2a-l9u9)........................ 2.0 Rig /M*........ ............................................... ........................... I J and Its incifentc compounds (Z37.U- 0.2 nig./M*.................................................................................... 19!. Wihsl chi,'rule l7J".23-l'fc>Si ...................... 100 p.p.m.........200 p.p.m.................... 300 p.p.m......... . 5 minute* In any 3 hours. (ethyltn* Chloride (Z37-3-1W?).................. . 500 p.p.m......... 1,000 p.p.m.............. 2.000 p.p.m..........S minutes In any 2 hours. no (alkyl) mercury (Z37.S>IM9).......... 0.01 ... 0.0* mfuM ................................................. t in# <Z3:.1S-I9d9).......................................... 100 p.p.m.........200 p.p.m....................WO p.p.m................ minutes in any 3 hours. TrlclJocoethylen* (237.19-1067]........................... do................... do........................ 300p.p.m................ Sminutesln any 2 hours. TeLrachlorcethyUoe (237.22-1987)........................... do..........................do.................................. do..................... 6 minutes In any 3 hours. T. ns r2j?.l?-l97)......................................... 209p.p.m......... 300p.p.m.................. MOp.p.m................lOminutas. 3! o*ten tulAJe (Z3.2-1988)........................................................ 20pp.m................... AOp.p.m................lOmlnutos cnee only U no other measur able exposure Mrrury (737.6-1971).......................................................................... lmg./lOM* . occurs. : -me acid and chromates (Z37.7-1971)............................................ do *.......................................................... ruoitional exposure* to benzene ere object to L*ie requirement of Section 1910 102e*cepi as specilicellv eiempled bv n 1910 iLljiiiili Exposure! eaempied by Section 1910 iC2l<a ir21 are covered t> Pin Section 1910 iwOO ntrv nn leod teiurncJ to table ji 44 I R I45J4. March 13, l^j Table Z-1 --Mineral Duet* Aerodvnamle diameter lurut dettsily sp.-.ere) Percent passing selector Substance Mppcf Mg/M1 "~ 3 ----------------------------------------------------------------------------------------------------------------------2.6 Ilea: Crviiaillne: 3.0 AO tresplrable)................ 250' lOm^'M' 10 90 76 0 20 0 r#sio>-*-0 rrSio,-j i (total dust)........................................ iinut'M* CilstobUn*; Ute M the ..ue ce rplstcj r.-om the unt or mast tormulae (or ism. 1 .jytr.ite. I'se 4$ the value ce'culaled Irom the (ormill**- lor Quru 1nor:ino!. inclutlmg natural * >n\*c*m*ne .t.i.letfhe . >................ Ilealas (lea than l% trff ut.lme sl.ica): Mica............................................ tpetone..........I.."!""'"". Icfnon-asbe'Uje forml .. icinbrousl. Use asbetioi .IBJlt ............................ 30 TrSIO, 20 30 jo Portler. 1 remrri............... . 03 3r--*ille I natural)....................... 1 -* dust (respiratle fraction than a1*2b3lO,i......................................... foc more then 67, SiOi................................... 3.4m/M' or IPxa/kP n or Nuisance Dust: iplrcble fraction................ alduit................................. %aiOH-3 )i tmf W' 40 16m*, Ml Norf Coneertion (actors-- iPtetKU J-n.uiion tresticie* per cubic meter pertli-.ei per c.r IKona ol cmrtic.e-e tr cuble foot of air, V-aaed on n fr jn-npis <ounte-l hy i`(fhl.fl-|d lecnniet e iTT(ii*e ot rrystalime a..tea t.i me lormula atstunt delercnlrieil (r*\n\ air-6<--Tn iunpla. eiTK n ih'.ee insiarw-re in vhien ether method} bee* poen tnarr, to > al*lli.-abie. " >h conrer.ieetton eud peTrent quarte lor the acpU`I ot this unit ar U> tj determlne^J Irom the fraction as re "ei wlrrW with the bllne|r\| chir^leriiLlci ` Vaitinj < j'l, quartr; if > 1% quant, um quant m The n-.ee^urrments under this note refer to the use or an AEC instrument. If the respirable fraction of cor.l dust Is determined with a M RE the hgure corresponding li rhil of 2.4 M> in the table (or coalduti Is 4.5 Mg/M1 1910.1001 Asbestos. (a) DeAnUions. For the purpose ol this section, (1) "Asbestos" includes chrj'soUle. amoslte, crocidolite, tremollte, anthephylhte, and actinollte. (2) "Asbestos fibers" means asbestos fibers longer than 5 micrometers. (b) Permissible exposure fo airborne concentrations of asbestos fibers--(1) Standard effective July 7, 1972. The 8-hour time-weighted average airborne concentrations of asbestos fibers to which any employee may be exposed shall not exceed five fibers, longer than 5 micrometers, per cubic centimeter of air, as determined by the method pre scribed in paragraph (e) of this section. (3) Standard effective July 1. 1976. The 8-hour time-weighted average air borne concentrations of asbestos flDers to which any employee may be exposed shall not exceed two fibers, longer than 5 micrometers, per cubic centimeter of air, as determined by the method pre scribed in paragraph Ce) of this section. (3) Cethnp concentration. No em ployee shall be exposed at any time to airborne cencentratlons of asbestos fibers in excess of 10 fibers, longer than 5 micrometers, per cubic centimeter of air, u determined by the method pre scribed in paragraph (e) of this section. (c) Methods of compliance--(1) ngiiteering methods. <J) npineerir.p eonfroh. Engineering controls, such as, but not limited to. isolation, enclosure,' ex haust ventilation, and dust collection, shall be used to meet the exposure limits prescribed in paragraph (b) of this section. (it-) Local exfcausf renfiiofioa. (a) Local exhaust ventilation and dust col lection systems shall be designed, con structed, installed, and maintained in accordance with the American National Standard Fundamentals Governing the Design and Operation of Local Exhaust Systems. ANSI 29.2-1971, which is in corporated by reference herein. lb) See ! 1910.6 concerning the avail ability of ANSI Z9.2-1971, and the maintenance of a historic file in connec tion therewith. The address of the Amer ican National Standards Institute is given in S 1910.100. (iii> Particular tools. All hand-op erated and power-operated tools which may produce or release asbestos fibers In excess of the exposure limits pre scribed in paragraph 'b) of this section, such as. but not limited to, saws, scorers, abrasive wheels, and drills, shall be pro vided with local exhaust ventilation sys tems in accordance with subdivision (11) of this subparagraph. (2> tVor*: practices--<n Wet methods. Insofar as practicable, asbestos shall be handled, mixed, applied, removed, cut scored, or otherwise worked in a wet state sufficient to prevent the emission of airborne fibers in excess of the ex posure limits prescribed in paragraph <b) of this section, unless the usefulness of the product w'ouid be diminished thereby. (U) Particular products and opera tions. No asbestos cement, mortar, coat ing, grout, plaster, or similar material containing asbestos shall be removed from bags, cartons, or other containers in which they are shipped, without being either wetted, or enclosed, or ventilated so as to prevent effectively the release of airborne asbestos fibers in excess of the limits prescribed in paragraph (b) of this section. (ili) 5pravi7ip, demolition, or removal. Employees engaged in the spraying of asbestos, the removal, or demolition of pipes, structures, or equipment covered or insulated with asbestos, and In the removal or demolition of asbestos in sulation or coverings shall be provided with respiratory equipment in accord ance with paragraph <d)(2)(i:i) of this section and with special clothing in ac cordance with paragraph <d)<3> of this section. <d> Personal protective equipment-- (1) Compliance with the exposure limits prescribed by paragraph 'b) of this sec tion may not be achieved by the use of respirators or shift rotation of em ployees. except: (i> During the time period necessary to install the engineering controls and to institute the work practices required by paranraph <ci of this section: (ii) In work situations in which the methods prescribed in paragraph 'c) of Chemical Reguianon Resone' [Sec. 1910.1C01(d)m(.i|] '0 CCS 000000057 OCCUPATIONAL STANDARDS CHM-?1} 57:0405 this section are either technically not feasible or feasible to an extent insuifl'Mcnt to reduce the airborne eoncentra- ns of asbestos fibers below the limits .escribed by paragraph (b) of this section: or <iil> In emergencies. (iv) Where boih respirators and per sonnel rotation arc allowed hv paragraphs (d)llHil. (ii). or (iii) of this section, and both are practicable, personnel rotation shall be preferred and used. (2) Where a respirator is permitted by paragraph ld)(l) of this section, it shall be selected from among those approved by the bureau of Mines, Department of the Interior, or the National Institute for Occupational Safety and Health, Educa tion. and Welfare, under the provisions of 30 CFR Part 1! (37 F.R. 6244, Mar. 25, 1972). and shall be used in accordance with subdisisions (i), (ii), (iii), and (iv) of this subparagraph. (i) Air purifying respirators. A reusable or single use air purifying respirator, or a respirator described in paragraphs (d)(2) (ii) or (iii) of this section, shall be used to reduce the concentrations of airborne asbestos fibers in the respirator below the exposure limits prescribed in para graph (b) of this section, when the ceil ing or the 8-hour time-weighted average airborne concentrations of asbestos fibers are reasonably expected to exceed no more than 10 times those limits. (ii) Powered air purifying respirators. A full facepiece powered air purifying spirator, or a powered air purifying resirator, or a respirator described in para graph fd)(2i(iii) of this section, shall be used to reduce the concentrations of airborne asbestos fibers in the res pirator below ihe exposure limits pre scribed in paragraph (b) of this section, when the ceiling or the 8-hour timeweighted average concentrations of asbestos fibers are reasonably expected to exceed 10 times, but not 100 times, those limits. (Lii) Type "C" supplied-air respirators, continuous How or pressure-demand class. A type "C continuous flow or pres sure-demand. supplied-air respirator shall be used to reduce the concentra tions of airborne asbestos fibers in the respirator below the exposure limits pre scribed in paragraph (b) of this section, when the ceiling or the 8-hour timeweighted average airborne concentra tions of asbestos fibers are reasonably expected to exceed 100 times those limits. (iv) Eifcbitshmcnf o/ a respirator pro gram. fa) The employer shall establish a respirator program in accordance with the requirements of the American Na tional Standards Practices for Respira tory Protection. ANSI 288.2-1969, which is incorporated bv reference herein. (b) See $1910.6 concerning the avail ability of ANSI Z83.2-ioty ana tne main tenance of an historic file in connection therewith. The address of the American National Standards Institute is given in 1910. ICO. (c> No emplovee shall be assigned to tasks requiring the use of respirators if. based upon his most recent examination, an examining physician determines that the employee will be unable to function normally wearing a respirator, or that the safety or health of the employee or other employees will be impaired by hisuse of a respirator. Such employee shall be rotated to another job or given the opportunity to transfer to a different po sition whose duties he is able to perform with the same employer, in the same geo graphical area and with the same senior ity, status, and rate of pay he had just prior to such transfer, if such a different position is available. (3) Special clothing: The employer shall provide, and require the use of, spe cial clothing, such as coveralls or similar whole body clothing, head coverings, gloves, and foot coverings for any em ployee exposed to airborne concentra tions of asbestos fibers, which exceed the ceiling level prescribed in paragraph <b) of this section. <41 Change rooms: (i) At any fixed place of employment exposed to airborne concentrations of asbestos fibers in ex cess of the exposure limits prescribed in paragraph (b) of this section, the em ployer shall provide change rooms for employees working regularly at the place. (ii) Clothes lockers: The employer shall provide two separate lockers or con tainers for each employee, so separated or isolated as to prevent contamination of the employee's street clothes from his work clothes. tiii) Laundering; (a) Laundering of asbestos contaminated clothing shall be done so as to prevent the release of air borne asbestos fibers in excess of the ex posure limits prescribed in paragraph <b> of this section. (b) Any employer who gives asbestos- contaminated clothing to another person for laundering shall infortp such person of the requirement in paragraph (d)(4)(iii) (a) of this section to effectively prevent the release of airborne asbesios fibers in excess of the exposure limits prescribed in paragraph (b) of this section. (c) Contaminated clothing shall be transported In sealed Impermeable bags, or other closed, impermeable containers, and labeled in accordance with para graph (g) of this section. (e) Method of measurement. All de terminations of airborne concentrations of asbestos fibers shall be made by the membrane filter method at 400-450 X (magnification) (4 millimeter objective) with phase contrast illumination. (f) Monitoring--(1) Initial determi nations. Within 6 months of the publi cation of this section, every employer shall cause every place of employment where asbestos fibers are released to be monitored In such a way as to determine whether every employee's exposure to asbestos fibers is below the limits pre scribed in paragraph <b) of this sec tion. If the limits are exceeded, the em ployer shall immediately undertake a compliance program in accordance with paragraph (c) of this section. (2) Personal monitoring-- (1) Sam ples shall be collected from within the breathing zone of the employees, on membrane filters of 0.8 micrometer po rosity mounted in an open-face filter holder. Samples shall be taken for the determination of the 8-hour timeweighted average airborne concentra tions and of the ceiling concentrations of asbestos fibers. (ii) Sampling frequency and patterns. After the initial determinations required by subparagraph (1) of this paragraph, samples shall be of such frequency and pattern as to represent with reasonable accuracy the levels of exposure of em ployees. In no case shall the sampling be done at intervals greater than 6 months for employees whose exposure to asbestos may reasonably be foreseen to exceed the limits prescribed by paragraph (b) of this section. (3) JPnvtronmenfcZ monitoring--(1) samples shall be collected from areas of a work environment which are represent ative of the airborne concentrations of asbestos fibers which may reach the breathing zone of employees. Samples shall be collected on a membrane filter of 0.8 micrometer porosity mounted in an open-face filter holder. Samples shall be taken for the determination of the 8hour time-weighted average airborne concentrations and of the ceiling con centrations of asbestos fibers. (ii) Somplin? frequency and pattern. After the initial determinations required by paragraph (0(1) of this section,' samples shall be of such irequency ana pattern as to represent with reasonable accuracy the levels of exposure of the employees. In no case shall sampling be at intervals greater than 6 months for employees whose exposures to asbestos may reasonably be foreseen to exceed the exposure limits prescribed in para graph (b) of this section. (4) Employee observation of monitor ing. Affected employees, or their rep resentatives, shall be given a reasonable opportunity to observe any monitoring required by this paragraph ana shall have access to the records thereof. (g) Caution sipns and labels. (1) Cau tion signs. (1) Posting. Caution signs shall be provided and displayed at each location where airborne concentrations of asbestos fibers may be in excess of the exposure limits prescribed in paragraph <b) of this section. Signs shall be posted at such a distance from such a location so that an employee may read the signs and take necessary protective steps be fore entering the area marked by the signs. Signs shall be posted at all ap proaches to areas containing excessive concentrations of airborne asbestos fibers. (ii) Sign specifications. The warning signs required by paragraph (g)(l)(i) of this section shall conform to the re quirements of 20" x 14" vertical format signs specified In $ 1910.145(d) (4), and to this subdivision. The signs shall dis play the following legend in the lower panel, with letter sizes and styles of a visibility at least equal to that specified In this subdivision. [Sec. l91D.1001(g)(1Xn>1 11-7-30 Published by THE BUREAU OF NATIONAL AFFAIRS, INC.. WASHINGTON. D.C. 20037 11 CCR 000000058 i?:040G REFERENCE FILE Legena Notation AjbeU>s................ I-* Sane Ser'X. Oothlc or Block. uai Hazard__________ _ *i" Sans Serif, Ootnic or Block. a Brcathh ; Oust... ; Gothic. at Auicncd Protective \ * Gothic. Equipment. l)o Sot Remain In Are* vt ' Oothlc. Unless Tour Work Re* quirea It. irr*iruni Asbestos Dust i point Oothlc. May He llozoraoua To Tour Hesltb. Spacing between ju.t4 shall be at least equal to the height of the upper of any wo lines. (2) Cflurion labels-- (li LabWmp. Cau- ..on labels shall be affixed to all raw materials, mixtures, scrap, waste, debris, And other products containing asbestos bers. or to their containers, except that o label is required where asbestos fibers nave been modified by a bonding agent, coating, binder, or other material so that Hurme any reasonably foreseeable use. incline, storage, disposal, processing, or ansportatlon. no airborne concentra tions of asbestos fibers m excess of the exposure limits prescribed In paragraph 'll of this section will be released. (ii) Label specifications. The cau.ion ibcls required by paragraph (g){2){i) of this section shall be pruned in letters of sufficient sice and conirast as to be readily isible and legible. The label shall state: Cactiok Contains aj Boston Fibers Avoid Creating Dust breathing Asbestos Dost May Cause Serious Bodily Harm ., Housekeeping--1 j Cleaning. All t..atrial surfaces in any place of employ ment shalt be maintained free of accu sations of asbestos fibers if. with their rpersion. there would be an excessive voncentratlon. (2) Waste disposal. Asbestos waste, "rap, debris, tags, containers, equip- ent. and asbestos-cor.iarmnated clothg, consigned for disposal, which mayproduce in any reasonably foreseeable use. handling, storage, processing, dis~->sal, or transportation airborne concenations of asbestos fibers m excess of th>. posure limits prescribed in paragraph (b) of this section shall be collected and disposed of In sealed impermeable bags, other closed, impermeable containers. (1) Recordkeeping--(1) exposure rec- da. Every employer shall maintain rec ords of any person*! or environmental monitoring required by this section. Ree ds shall be maintained for a period of . least 20 years and shall be made avail_jlc upon request to the Assistant Sec retary of lobor for Occupational Safety and Health, the Director of the National istitutc for Occupational Safety and c-alth, and to authorised representa- *i -es of either. (2) Acrpis. Emplovcc exposure records 'quired by this paragraph shall he proded upon request to cmplovees, desig nated representatives, and the Assistant Secretary- in accordance with 29 CFR 1910.20 (a)-(e) and (g)-(i). [45 FR 35212. May 23, I9S0) (3) Employee notification. Any em ployee found to have been exposed at any time to airborne concentrations of asbes;o$ fibers in excess of the limits pre scribed in paragraph ib) of this section shall be notified m writing of the expo sure as soon as practicable but not later than 5 days of the finding. The employee shall also be timely notified of the cor rective action being taken. (J) Medical examinations--<l) Gen eral. The employer shall provide or make available at his cost, medical examina tions relative to exposure to asbestos re quired by this paragraph. (2) Preplacement. The employer shall provide or make available to each of his employees, within 30 calendar days fol lowing his first employment in an occupation exposed to '.irborne con centrations of asbestos fibers, a compre hensive medical examination, which shall include, as a minimum, a chest roent genogram (posterior-anterior 14 x 17 inches), a history to elicit symptom atology of respiratory disease, and pulmonary function tests to include forced vital capacity (FVC) and forced expiratory volume at l second (FEV\.). "(3> Annual exarmuafionj. On or be fore January 31. 1973, and at least an nually thereafter, every employer shall provide, or make available, comprehen sive medical examinations to each of his employees engaged in occupations ex posed to airborne concentrations of as bestos fibers. Such annual examination shall include, as a minimum, a chest roentgenogram (posterior-anterior 14 x 17 Inches), a history to elicit symptom atology of respiratory disease, and pulmonary function tests to include forced vital capacity (FVC) and forced expiratory volume at 1 second (FEV,.). (4) Termination of employment. The employer shall provide, or make avail able. within 30 calendar days before or after the termination of employment of any employee engaged in an occupation exposed to airborne concentrations of asbestos fibers, a comprehensive medical examination which shall include, as a minimum, a chest roentgenogram (pos terior-anterior 14 x 17 inches), a history to elicit symptomatology of respiratory disease, and pulmonary function tests to include forced vital capacity (FVC) and forced expiratory volume at l second (FEV,.*). (5) Recent examinations. No medical examination Is required of any em ployee. if adequate records show that the employee has been examined in ac cordance with this paragraph within the past 1-year period. (6) Medical records--(1) .Mainte nance. Employers of employees examined pursuant to this paragraph shall cause to be maintained complete and accurate records of ail such medical examina tions. Records shall be retained by employers for at least 20 years. (ii)_.4rcm. Records of the medical examinations required by this paragraph shall be provided upon request to em ployees. designated representatives, and Assistant Secretary in accordance with 29 CFR 19l0.20(a)-(e) and <jO-(i). These records shall also be provided upon the request to the Director of NIOSH. Any physician who conducts a medical exam ination required by this paragraph shall furnish to the employer of me examined employee all the information specifically required by this paragraph, and any other medical information related to occupa tional exposure to asbestos libers. [45 FR 35212, May 23. 1980; 45 FR 54333, August 15, 1980} 1910-1002 Coal (at pitch volatiles; in terpretation of term. As used in See. 1910.1000 (Table 2-1), coal tar pitch volatiles include the fused poly cyclic hydrocarbons which volatilize from the distillation residues of coal, petroleum, wood, and other organic mat ter. 1910.1003 4-Nitrohtphcnyl. (a) Scope and application. (1) This section applies to any area in which 4-Nitrobiphenyl, Chemical Abstracts Service Registry Number 92333 is manu factured, processed, repackaged, re leased, handled, or stored, but shall not apply to transshipment in sealed con tainers, except for the labeling require ments under paragraphs (e) (2), (3), and (4)of this section. (2) This section shall cot apply to solid or liquid mixtures containing less than 0.1 percent by weight or volume of 4-Nitrobiphenyl. (b) Definitions. For the purposes of this section: (1) "Absolute filter" is one capable of retaining 99.97 percent of a mono disperse aerosol of 0.3 particles. (2) "Authorized employee" means an employee whose duties require him to be in the regulated area and who has been specifically assigned by the employer. (3) "Clean change room" means a room where employees put on clean clothing and/or protective equipment in an environment free of 4-Nitroblphenyl. The clean change room shall be con tiguous to and have an entry* from a shower room, when the shower room facilities are otherwise required in this section. (4) "Closed system" means an opera tion involving 4-Nitrobiphenyl where containment prevents the release of 4Nltrobiphenyl into regulated areas, nonregulated areas, or the external environ ment.. (5) "Decontamination" means the in activation of 4-Nitrobiphenyl or Its safe disposal. (C) "Director" means the Director, National ` Institute for Occupational Safety and Health, or any person di rected by him or the Secretary of Health. Education, and Welfare to act for the Director. Chemical Regulation Reporter !S*c. 1410.1POa.bk6)) CCR 000000059 Date: APPENDIX C Pitt-Consol Chemicals Conoco Inc 191 Doremus Avenue Newark, NJ 07105 1201) 344-3800 U.S. Environmental Protection Agency Air Facilities Branch 26 Federal Plaza, Room 802 New York, New York 10007 Re: Asbestos Removal - Notification Dear Sirs: This letter is to inform you of our intention to remove asbestoscontaining pre-cast insulation from existing equipment on (1). This removal is necessary to (2) and will generate approximately _(3) of insulation. (1) (2) (3) Fill in inclusive date. Fill in why?, repair steam tracer, make tie-ins, etc. Insert unit measure of insulation to be removed, e.g., 300 feet of 1-inch thick insulation on 2-inch pipe or 180 square feet of 2-inch thick insulation on 10 feet diameter tank. It should be noted that we require our personnel and contractors to use the wet method for asbestos removal discussed in 40 CFR 61 and 29 CFR 1910.1001. All insulation containing asbestos material, scrap, debris and asbestos-contaminated clothing will be stored wet in sealed pre-labelled asbestos bags until shipment. We plan to continue to notify you at least 10 days prior to any shipment. Please contact us if you have any questions. Very truly yours. Harry D. Garrison Plant Manager cc: CCR OOOOOOAn APPENDIX D Pitt-Consol Chemicals Conoco Inc. 191 Doremus Avenue Newark. NJ 07105 (2011 344-3800 Date: U.S. Environmental Protection Air Facilities Branch 26 Federal Plaza, Room 802 New York, New York 10007 Agency Re: Asbestos Removal - Annual Notification Dear Sirs: This letter is to inform you that we anticipate the removal of asbestos-containing pre-cast insulation from existing equipment during the next year. We currently do not have any planned removals. However, historically,we have found it necessary to remove some of this insulation due to routine maintenance, e.g., valve replacement, replacement of steam leaks, making tie-ins, repairing steam tracers, etc.. We do not anticipate any single removals of nearly 260 feet of pipe insulation or 160 square feet of flat insulation; however, because we accumulate this material prior to disposal, there is a chance we may ship more than this amount at one time. Note that we plan to continue to notify you at least 10 days prior to any shipment. Also, we will notify you of any significant removals (greater than 260 feet of pipe or 160 square feet of flat insulation) in advance if possible, i.e., it is not an emergency removal. It should be noted that we require both our personnel and any contractors which we employ to use the wet method for asbestos removal discussed in 40 CFR 61 and 29 CFR 1910.1001. After removal all asbestos-containing material, asbestos-contaminated clothing and debris are stored wet in sealed pre-labeled plastic bags until shipment. Please contact us if you have any questions. Harry D. Garrison Plant Manager be: RHD, WFR, AVG, HP CCR 000000061 appendix E JACK STANTON DIRECTOR DEPARTMENT OF ENVIRONMENTAL PROTECTION DIVISION OF ENVIRONMENTAL QUALITY SOLID WASTE ADMINISTRATION 32 EAST HANOVER STREET. TRENTON. N. J. 08625 LINO F. PEREIRA ADMINISTRATOR SOLID WASTE MANAGEMENT Re: Disposal of Asbestos Waste Dear Sir: Pursuant to inquiries regarding the disposal of asbestos ceiling materials from school buildings in particular and asbestos ;aste in general, the Solid Waste Administration, after consultation with the U.S. Environmental Protection Agency, requires the following steps be taken when landfilling this material: 1. Only landfills registered to accept industrial waste (I.D. #27) are to be used for disposal. 2. All wastes are to be immediately wetted before being deposited in a temporary container for transfer to a landfill facility. Said container must be closed between fillings and closed during transfer to the land fill site (in case of a "dumpster'1). OR the material is to be immediately wetted and placed into a suitable per manent container such as metal drums or "fiber pak" and transferred to the landfill. 3. A registered solid waste hauler shall be used to transfer such wastes. 4. A separate excavation is to be prepared at the landfill site, the asbestos material deposited, and immediately covered. 5. The presence of a County Health Officer and/or an inspector from the Solid Waste Administration Enforce ment Section may be required as necessary to oversee the final disposition. New Jersey Is An Equal Opportunity Employer CCR 000000062 Page 2 6. A report will be submitted by each generator (e.g., a school district) to the Bureau of Hazardous Waste, Solid Waste Administration, ten (10) days prior to disposal as per the National Emission Standards for Hazardous Air Pollutants, 40 CFR 61, Subpart B, Section^61.20 through 61.25, indicating the quantities of asbestos material, the hauler identification, and the landfill site into which it is to be emptied. Also, a copy of the report must be sent to: U.S. Environmental Protection Agency, Air Facilities Branch, 26 Federal Plaza, Room 802, New York, New York 10007, Attention: EPA Region II, Asbestos Technical Advisor (212) 264-3059. Since asbestos is classified as a hazardous waste when it is air borne, the Solid Waste Administration requires compliance with the above procedure pursuant to the hazardous waste provisions of N.J.A.C. 7:26-1 et seq Very truly yours Lino F. Pereira Administrator oa o o r. i `j. :i ri : ' 1 * fr - J '/ 1 , t A *1 r: 11 f i; j < t i > .> ' ri i- ' i^ , - S. 1J (i 1", t i > - V' i > /I O' ;) j :i r 1 o f: 1. . } (*- LI o f.-, !>- ' m m ; j r1 oi on M O ; r i rt ..r r < nr ; O O C< "d d 1 1 io :i o O i'/ *i r.. - 1 (L '; i" a C t - i - . t * - i < tn n t-- ;j H c> : i C c ci rn i j CJ 1 t-t p ;i *-( - o j r /u l1 o 11 cr. f> fi >\ o Q O o 03 > n >7 t -* T-! (i o to '!"1 O' CD I o cr C.j' -1 Cj MO Q i/. 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Re cent met ; -- - i area indicates tha -- brief, hi Cn`lL TJ-e~vol exposur A~ ) cm, low level w os ure, leads to an increase c cr. This fact , coupled with the van a o 1111 y o se to any care ino gen .ic agent, makes i t imoose a safe extes u r e le vel for asbestos. Typica " ^ cts arc observ c a , as asbestos TSIStCC disease 5 latency period of on 10 to 20 years asbestos fiber s i 5 not limited to the s e wh o contact with sour C o C S tudie s of the familie ry workers ind i c a - A a higher than nor mal inci - cer . This has be n linked to fibers brought the cloth ins -o u. u he workers. This ha s been .he federal gov m en t in the occupati cr.al 'ni cil t?cui-rec: ' c s-r-i r? re work ?. n.d scree t clothes hich enoosurc to asb sstos mat trials. Once the home, ashes le s b econes en trained in che a i r 4-hour expesur e o 'w cu rs. These family studies very young are th o most susce p t i b 1 e t o the .sr . Here . the s e ac ts are especially critics ) ;hcols and oche r o ub 1 ic builci ngs, we ^o do~ ' --n- o~ of young reci p i e n ts Every reasor.no ie error -- linir.ate such ur.n o r- r\ ssary hum an expos ure. or .0 c u o s r i c n. J. \:r ,' i ,i .. .CTION . be emnhasired th a L. es identified ac c immediate action is ir.g to Se cticn 12* * requi -- => n soraysd-cn sur face m aterial h as been ed on II. the fir St s --L, eW. p is to determine if asbe 3 - n significant qua u _ tics, in the mate rial in .native laborat orv a lysis sh culd be undent k nannies having th c c CU ^ V* 0 ^ "1 U ` to cond uct asbc 5 - . tcached . (It S h 0 u n 0 tn *" that th e State C f -icnt cf n.nvirc nmc n ta 1 Protect ion dees not hav do asbestos, a na 1 \; s i "*: 1 y> 1 Except for tab ing the same Is for a n alysis. s K oul d net be disturbs o m an'-' t f a r " r~ t a u u. * n* u. s n c'jid o e closed or activ educed until t he X ab oratory r esuits a re obtai n - ary corrective ac ic ns are cc n o 1 c t e d the "i t'*1 ^ rt * ^ "" an 1_ r- sis of th. e $ r r a v c d * o r. prove no be r.c ^ '*l u r. ' ' r> (1 . e . , 1 ess t h a n 11 as b e C ut ba ?ae < " , no i u r" then action is rcov. * vn *t the laboratory an ;; lv 3 1 s Cl t h o spray? d -on ccnrirn the or CSC n 3 0 ot asb cs cos, fur then ru 1es (-.0 CTR 6. IZlfc)) provide tha r*. * ,n n a s e c s . U C U c i n 5 U i 7 ' e or fireproof build ings structures , . crad'Ji:; shall centa in less then i 'j asbestos on a c _ -> _ 5 v _ r\ \ AS C C N'TAI N IN G MAT T AIA L V O C "Z ~' < 12 ns ~ ,- <-l g removal procedure has been bie federal rcgultions (40 C or. Standard for Asbestos). A scion o.peration involvingv the r\ * i 1 ^ r* i~, T) ~ r> ~ A 60 . Subparr y person re?rcnremoval of rsviev; said, regu- o n. 10 (pi a clea vac u ? or -> c o i i _utc 5h:~f cant: 500 polyoxyethylene Istsr U' o os containing material and/or substr manually removed tine placed in'a see transport to a ssnitsrv landfill. C nc use''1 ?.? .i ong asoestes c c n s * AT -- anc ;;ocrs m the removal ares, arc t W...I - W w \J A eaeve cr." rer.amm s te. i. *' ' i ^ ^ e , piaster t a .vori-anc ns clothing are tc do deocsit scaled, arid disposed material in senatorlandfill and i " -- r\ ^ p he ^np g 'i - : ^ ^ 1 b (60f-:?:-76^5) 5c:::: u ...: ,, v -< ' ' -- 'rcc r.asu i i____ ;:ou:c o ^o -- -i ^ - r : - r> CCR 000000066 CCR 0 0 0 0 0 0 0 6 7 r* *: r; .) , - ]t o O l P. i ^. O O; 1 r ! r . * i r O J 't I -c 1 r* j ;: .; 3: r 1 r> * -- n. O . > P J i,. c-> f 1 i f~. 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( o p 0-.<yD- ii CD tt. yy i -i M fly pO* 0<l :CDi CjI -' 0i C/l 1 ' P O --' . y13 -r| C PP P zr n t-` 1 C-) rt n 1 II o p `IDV rrj :r r-i ' 1) p o tj- t-1 i * . t-1 o t - o o ' > r t p t-` P` O fii o 4 t P- P i n o H- O no Oi ;1 P rt th *3 f t, n p: r> n 13 i *i ID i 1 rj l J' t a op. n t 1 ' '.1 H- p *\ 1 fD P o oi p Py (D J pi m i-i 1--f p b' ri t'- CD H' t-*' O' tl n CD n p P` t J" n pj ,--v p p CD r-> O' p * i fj 0'D CD 1/1 (j. . 13 O' - P o f o ID p ID Py P H< l--f n CD 3 mn P P|.y-, V--* J '-pC P in 1h 01 f P CD o Pi n O l-` P- O a On ID P o-< .. CD H npP O Wp o(n H f> H. p 1 S O' i ID 1- ` p fD p V1 1 1 fD ID. CD p o' U. fi rt (D P H 1ft-1 P CD t-* tJ ,--. f-J- 'P *' P V) I ' <; n 01 p t-* t-" o' n (-> o CD o Hi rV-i1.. t-1 f t 05 ).J. J,' o H1 o P U'l p p O rj ft, P rt r-j f (0 n. J ft P p" rt H- CD Cl M t y; T1 " P ID t-` cn p CD O 1-i. Ml ri. 13 rt o O' rt CD j ! 11 lr CD 1 Jri i ,--. f P CD t/i c: r t 'd f/i cD o 1 CD Hi CD o t-` < 1 PP O' ! 1 CD CD P P o ri Mi O PP P cr rt CD CD m in rt rt O cn HP P rj P P/ <0 ID. i CD tD P C. f< Ml P fl CD 'tl i ' P . :i o tf v,' i . i t-' f> i O i ;! 1) i ` > C 3 (i p i * C) c o p n. i ' C/l rt CD 1 O n. ID CO n. ft o CD n. i J i 1o CJ CO o p y 01. O' o O1 i r1 rf H- O P CD rt tr f.f ID t-* C O' P CD rt P CD rt rt !r P ID ' P rf * f CD Cf3 CD PP O CD 'J OO t fi rt rr rt CD ' y O i I rk arbiter, the workers must remove the disposable rricr tc 1 e a v i r.g the site and it is strongly r c c o m at the'-' be advised to shower rricr to satins*. The or snravea asbestos containing materials ire:'* such structural members as ceiling and/or walls is consid ered a renovation by the 13.S. Environmental Protection Agency (Me tiara 1 Emission Standards for Hazardous Air Pollutants Sec tion 51.27(b) (-)) and as such a report must be sent in duplicate for each site location addressed to: *J. S. environmental Protection A gone-', P.cgior. Director , Enforcement Divisten Attention: Marcus Kan11 Room dud, federal Office Building 26 Federal Plata New York, Mew York 10007 XI This report must be sent at least 10 days prior tc the com mencement of removal , and in accordance with 40 CFR 61.22(d)(2) must contain the followers: information: 1. Marne cf owner or operator. 2. Address cf owner or operator. 5. Description of the building, structure, facility, or .ilttion to be" demolished or renovated, including the site, prior use of the structure, and the approximate amount 1 c* asbestos material usee for insulation and fireurccfi: \) .n 4. .Address or location cf the building, structure, facil- Sch.cdu.ee starting ar.c corn let ion dotes of demcliticr. c: v r. ^ i c J1. o. Mature c: pitnr.ee cemeuutaon or renovation wO c"^/' ''vr'd i method (s) 7> p q ^ ^ -nrv ^ r\ r* r' . accrcss or vocation or the waste basnet o asbestos waste will be denosited. CCR 000000068 LABORATORY FACIII7IB; 13o t/. n . to r > -* .. 1 n c folicv.-ir. g companies have indicated that they are c f a c n d u cting asbestos analysis. Companies and/or contra c * o r s c lists should not be construed to be an endorsers nt by anrrrert. Testing .firms arc included merely on th e basis ffirmative response to telephone incuiries which a sked or not the companies were eatable of: asbestos determination analysis percent asbestos bv rv wcicht in a riven sami 1 those listed have recnested r.'nnt the ^sttitup Hp r> j a c e a "nv-iyCA ' uidiiiC ba^ <-tiiu jua.xxeu. lu LAesr address in rd tube. (Telephone contact should be made before sen .ales to determine other samulinc recuirements .') o to - <v lA u r ici r,w> ^ lj. t v~i Plymouth Meeting Mail ymouth Meeting, PennsyIvania tender: Mr. Ronald Neu Inc . 1P4 62 lephor.e Nugiber: 215-323-5300 Extension 572 aiysis turnaround time - 10 to 20 days st SbC/samrle analysed h tn * in* no gor> rl , t o ,~i , 1 >- a\* ten Environmental Consultants ' * Ci Id Road Michitan 43 0 7 5 Mr. Robert Soul xephene Number: 31e- 424 -SSCO alysis turnaround tame'- 5 to 10 days at $25/samoIe anaivaed ">1 n- i fni n ) rj.:i ur0r0 .associates 22 Mouth. Mich.icon Avenue x 0a0o , 6C616 To : onh.cn0 Number: 312*342 -7100 Analysis turnaround time - 10 to 15 day Recrmmcna sending sample b -/ UPS o r P1 r. Cast $ 100/samele nr.alvied lent Carri n -- CCR 000000069 C S5C/ "* "ft 3r v <.cs ;c::cs: IJ (/) * c * c* An s n cu 6 Cosz 275/sar.ris analysed days .} vrilliar. ?*. Bradley and Associates S7 Hq7.c::c*: Road Terafiy, Nov; Jersey 07670 i w ^ w w . . V . i W il Uo.L' U 4 i- l*r ^ ^ Ar.ai.vsis turnaround tide - 2 v;esk Cost SSO/s a,:u,, _ ~ r >' Ar. 1v s tu ou Cos; d 30 /s ar.p I c to S hours i it i i CCR 000000070 APPENDIX F (con-ocoj Pitt-Consol Chemicals Conoco Inc. 191 Doremus Avenue Newark. NJ 07105 (201) 344-3800 Date: Bureau of Hazardous and Chemical Solid Waste Administration 32 East Hanover Street Trenton, New Jersey 08625 Wastes Re: Asbestos Disposal - Notification Gentlemen: Pitt-Consol Chemical Company wish to inform you of our intended disposal of approximately (Quantity) C.Y./# of asbestos material removed from (Source: Pipe, Tank, etc.) insulation. This material is stored at 191 Doremus Avenue, Newark, New Jersey 07105 and will be hauled by (Transporter: Name & Address), (EPA No. ) on (Date) 1981. The material is wetted and sealed in pre-labelled asbestos bags and will be disposed of at (Landfill: Name & Address), (EPA No.). This landfill is approved to handle industrial waste No. 27. Please contact us if you have any questions. Very truly yours. cc: US EPA Air Facilities Branch 26 Federal Plaza, Room 802 New York, New York 10007 File: Asbestos (RCRA) CCR 000007l APPENDIX G ANALYSIS PLAN FOR PROPER HANDLING, TREATMENT, STORAGE AND DISPOSAL OF WASTES 1. Any waste suspected to be hazardous under EPA criteria will be classified by: a. Using analyses of like wastes or b. Testing suspected hazard by EPA Methodology 2. Wastes deemed hazardous will be tested for other parameters which could effect proposed disposition. All informations pertinent to that waste will be compiled on a "Waste Data Sheet". 3. Sampling and Analysis will be by the procedures designated on the waste data sheet. 4. Appropriate analyses will be invoked or repeated when the waste is available for sampling (i.e. when a vessel needs to be cleaned out) and: a. when there is a process change which might significantly change a waste product. b. when there appears to be a difference between the waste and the description on the Waste Data Sheet, or c. when a reasonable period of time has passed since the last analysis (this will be based on degree of hazard, volume, disposal cycle and effect on the disposal methods used.) 5. No waste suspected to be hazardous will be shipped without a waste analysis. 6. No hazardous waste will be shipped without a manifest prepared by the Environmental Encrineer or Senior Process Engineer and signed by the Plant Manager or Acting Plant Manager. CCR 000000072 Waste Data Sheet No. 1 (By Laboratory) 1. Waste Name: 2. Process Creating Waste: 3. Sample Date: 4. Waste Properties: 1. Type (organic, inorganic, both): 2. Number of phases: _____________________ 3. Physical State (solid, liquid, etc.): 4. Density: ________________________ 5. pH: 6. Flash Point (p.m.): Composition: (See attached Waste Data Sheet No. 2) 1. Organics, Wt. % 2. Water, Wt. % 3. Solids, Wt. % 4. Ash, Wt. % 5. Metals, ppm Not Present Not Expected to be Present As Ba Cd Cr Pb Hg Se Ag Zn Cu Fe Other __________ __________ __________ __________ _________________ _________________ _________________ _________________ ____________________ ____________________ ____________________ ____________________ 6. Inorganics: Sulfides 7. Sampling and Analysis Techniques Parameter Sample Method Analytical Method CCR 000000073 Waste Data Sheet Mo. 2 (By Laboratory) Waste Name: ______________________ -- Date: ------------------ ---------------------- Tine: --------------------------- ----------- Sample ;Jumber: _____________ ________ .-- D.ME ________________ ________ Anisole________________ ----------- Phenol ----------------------- --------------- Ortho cresol_______________________ -- M 4 F cresols_________________________ 2.6 Xylenol ________________________ unid. Anisoles____________ _____________ 2, 4+2,5 Xy lends___________ __ ________ 3.5 Xylenol ______________ ________ 2.3 Xylenol ------------ ------------------- .----- 3.4 xylenol________________________ 2.4.6 Tri M Phenol _________________ 2.3.6 Tri M Phenol ____________ 2, 3,5+2, 4,5 Tri M Phenols ______ __ 2,3,4+3,4,5 Tri M Phenols _______ penta M Benzene 2r3,5,6+2,3,4,6 -- TetraMPhenols 2.3.4.5 Terra Phenol _______________ Unids------------------------------------------ ----------------penta M Phenol________________ _______ Hexa M Benzene _ polymers or Residue ________________ Color or Ha2en_______ ___________ -- Methanol ___________ _ il,0 ______________________ Specific Gravity _______________ FP _______________ ----------- pH __________________ _____ Phenyl Disulfide _____________________ Tolyl Disulfides ____________________ Sylyl Disulfides ___________________ ,\ctive Sulfur ___________________ _ CCR 000000074