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Oi/15/88 10; 3} 9802 S8 5770 VT. RECORDS CTR. Manual of HuiO/rd* to Health from Chealools U**d At Th* Plants and Lftbormtortoa Of Carbida and Carbon Cbaaicala Carp. (21008 f Copy Humber Ce^yrighted j9' ' Carbida & Carbon Champa Co#j. Cooperatively prepared by the Medical Department, G ft G G C Industrial Toxicology Department, U.C.C. Works Laboratory, C4CCC, south Charleston Chemical Hygiene Fellowship, Mellon Institute, Pittsburgh, Pa. First Edition May 1, 1949 1 UCC100487-1 Page 001 uCC manual.max (ucc,100487 UCC 100487 OS/13'99 10:20 TT802 949 3770 VT. RECORDS CTR. @008 1 9ag 3 5-1-49 430 i- . i '* >' ' - i,f:I I.,il< .i . ' ............................. - ; >.Thls. manual-is intended-for tho.ua* of,-employees.-cfttha^Carbld#' & Carbon Chemicals Corporation who>havu `rspanslMlitla>Cos.-Duumfuaturlngj engineering and research operations. Tha judgements oxpressod herein refer to health hazards In > chemical' manufacturing proceduroa.< which.n.r conducted with reasonable caro. They stress accidental single expocyras.-aB apposed to repeated or substantially continuous exposures. Ho tabular miannry can predict the 3afety of .technical applications of -.chemical*, particularly where human contact or exposure is Inevitable, oft-repented* or,prolonged. This annual la net intended for auch predictions. Inch application must be judesd or. its. own-merits, with full Knowledge of-.all ths.=-particulars. *K'R0Cy*> The estimates In this manual are based upon experiments with small animals and tho .experience of industrial-physicians.;*:; In?.a'large number of Instances analog/ in chemical structure hus been railed upon to allow predictions where no observations have been recorded. The judgamenta expressed are necessarily tentative and subject to revision as dxperlenca . aceusultttes. Despite care used in checking the tables there undoubtedly exist inconsistencies and omissions, Uhsn crude nlxturss are being handled the hazards nay be somewhat greater than Cor the partially purified or sutetaiitiAlly pure chemicals considered herein. . l.' ,* ' ` The undersigned expects to serve os a clearing house for the collection of new observations and corrections in preparation for subsequent editions. >*,. *J V i-un?- `n -i"* Henry P. Smyth, Jr. Mellon Institute _ flttoturgh 13, Penna. II UCC100487-2 Page 002 uCC manuai.max 0S/15/M 10:21 <fr8Q2 8*8 3770 YT. RECORDS CTR. 0007 or>P' ... i Symbols used to describe relative haard ! 1. No residual Injury* Id to bo expected from ooidot*l !i exposure even IX no treatment is applied. sb -residual - injury my 'result froa eo:ooid*ot<il . (;'/T:-:'iiyj:.'i;'-*xpo,avtra,jir;nti-treatfflent Is applied'..; ''i! ...-..u-.C- .f *vt **; j hn-q-Uz;;. VUjor'-reeidual' injury my result IT no treatnantf-ia; ' j,; <*** t [ <1 -appliodi-"- , i:4 *'.'"xij... *v . `L'JilS . -JV.'.. ....*;:><: *. *,: * i.*,).? if. s ijjiv/ v-->i residual--injury nay result ta-spits*of prompt- <*jJr-o-? ... 1 ........ . - - * '.i:;;iPlayaiail properties of- chemical-make. the`particular ' J exposure almost impossible, j :-.21:;.'.:.*. ?.s:r.- .... . : ..I... . .. ,it r J ,!! Ji-.r ? iV rid? < Vi v;.'See supplemental nates on Icft-aide.^ofjpasa--'.-' `^ CNJl ....... 1.-*- *t >: 'li' '..r)OiP.."-. */*>? *1 vVh ,(' I "9iiw i- wa.ij* * Aoeteldehyde Way sensitise, the skin vss.- \ : J .J. i;... * Aootoaootaoctyl ethylcnadiasiihe' ' Kay sensitise the skin * Aotomylaoeions Stains the skin brown > . -:.i I -Lvi^/atni ...1 j-*: .;'/ si.j "jj.. :.: . in.-m- s.i'f : i '.--.i : --jft 1- l.f. J ta:: miiiffliiitif UCC100487-3 Page 003 uCC manual.max UCC 100489 08'lS/aa 10:25 0902 999 J770 vr. RECORDS CTR. Page SI (2)009 ! ___________________ Vanadium (metal) "Varsol" . ________ . Victoria blue B bass dye rTwalTSif- (SJS~pBH----- "Braatlw ; !'in* j i ! l. - |Pena-: Irrita- inj " ` j Cnat'i *; jtrtv- tian Vapor lor; ,f jtlcn : " or }Vapor r Suet! j In Sjye ;-- . |1 t |2 1 j 'I " "I 1' ' 1 !> 11 . .2 h 3 3 3 1 i' 2 3 Vinyl acetate '' 2 2 ;i*'r ' ~3 1 Vinylneotylena ' Vinylbutyl CARBIXOL - - ... 3 1 2 2 r!-- 2 . i Vinyl butyl ether A' ' 2 ` ' *3 i ! Vinyl 'buiyratr \ --.. ........................ [ Vinyl chloride V-in---y--l--c--h--lor-o..e. .tbyl ..e..t.h...e..r................ ....... 2-Vinyicrotonaldehyde 2 2 3 3- . 2 j1 3 i 2 jt 2 2 j1 4 . |.4* 3 . 4 2 "l" .frjrty * 4 Vinyl ethyl ether vinyl 2-ethylhaxyl ether 2 '2 Cl*''" 3 1 !! \ 2 ;2 i 2 1 1 2 Vinyl hejsyl ether Vinyl isobutyl irtber jj Vinyl isopropyl other j "Viaylite" resins 1 | "Vinylita" adhesive* ! i -------- jr | 2 2 2 |1 i j1 i2 | 2 !) ji 2 ---- 1;: 1 2 it 1 1 |1 1 |1 2 1J 3 2 2 1t z t1 1 1 1 | Vinyl 2-methoJCyethyl ether j2 ?2 | 1 2 3 1 Vinyl nethyl ether !. __ . 1 L ........... . .. . 12 j2 ; 1 4 1 _____ L J i ij t 1 . J _j |1 ! ! 1 i i[ I ' l ' j---------------- -------- -------------- ----- ------------ ---------------------------- ---------- -------------- j------................ .. .......t :'! i -J; If * See additional notes on left side of thia pag. 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