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DU PONT Material Safety Data Sheet Page 1 MATERIAL IDENTIFICATION DUPONT OIL BRONZE LIQUID DYE C S 269 MSDS NUMBER CORPORATE NUMBER : 1638PC : DU000615 Revision Date Date Printed 04-Nov-90 28-NOV-90 MANUFACTURER/DISTRIBUTOR Du Pont 1007 Market Wilmington, Street DE 19898 PHONE NUMBERS PRODUCT INFORMATION TRANSPORT EMERGENCY MEDICAL EMERGENCY 1-(800)441-7515 1-(800)424-9300 1-(800)441-3637 CHEMICAL FAMILY AZO DYE MIXTURE TRADE NAMES / SYNONYMS OIL BRONZE LIQUID BRONZE LIQUID DU PONT REGISTRY NUMBER: TSCA INVENTORY STATUS : NPCA-HMIS RATINGS : DP69-0-0 Reported/Included Health: 1 Flammability: 3 Reactivity: 1 Personal Protection rating to be supplied user depending on use conditions. by COMPONENTS Material *XYLENE *(ETHYLBENZENE) (BENZENE) 1,3-BENZENEDIOL, 2,4-BIS[(ALKYLPHENYL)AZO] (C.I.SOLVENT YELLOW) 2-NAPHTHALENOL[(PHENYLAZO)PHENYL]-AZO ALKYL DERIVATIVES (C.I.SOLVENT RED 164) CAS Number 1330-20-7 100-41-4 71-43-2 29190-28-1 65087-00-5 68310-04-3 71819-51-7 * Regulated as a toxic chemical under section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372. i 40 7.6 <.04 33 27 000009813 MSD8 NO. 1638PC DU PONT Material Safety Data Sheet GS 269 Page 3 HEALTH HAZARD INFORMATION ANIMAL DATA: OIL BRONZE LIQUID DYE Oral LD50: > 5,000 mg/kg in rats XYLENE (mixed isomers) Inhalation 4 hour LC50: 6,700 ppm in rats Skin Absorption LD50: 4,320 mg/kg in rabbits The product ingredients are moderate to severe skin and eye irritants in animals. Animal effects attributed to xylene include narcosis caused by skin absorption. Toxicity described for xylene from exposure by inhalation include upper respiratory irritation; central nervous system and behavorial effects; decreased weight gain; hearing loss; and effects on the liver, kidneys, heart, spleen, lungs, bone marrow, and blood. Central nervous system effects; decreased body weights; and liver effects were seen in animals exposed by ingestion to xylene. Tests on xylene in animals demonstrate no carcinogenic activity. While one dye component did produce genetic damage in bacterial cell cultures, xylene does not produce heritable genetic damage in animals or genetic damage in bacterial or mammalian cell cultures. Although abnormal sperm were observed after an intraperitoneal injection in rats, xylene did not produce reproductive effects; developmental toxicity was observed but only at concentrations that were maternally toxic. HUMAN HEALTH EFFECTS OF OVEREXPOSURE BY: Skin contact with xylene may include drying of the skin with irritation and rash. Skin permeation can occur in amounts capable of producing the effects of systemic toxicity. Eye contact may include eye irritation with discomfort, tearing, or blurring of vision. Inhalation of xylene may include nonspecific discomfort, such as nausea, headache, or weakness; and temporary nervous system depression with anaesthetic effects such as dizziness, headache, confusion, incoordination, and loss of consciousness. Higher exposures may lead to cardiac stress; anemia and other blood changes; respiratory effects; possible liver and kidney damage; or fatality from gross overexposure. Ingestion of xylene may include gastrointestinal irritation; nonspecific discomfort, such as nausea, headache, or weakness; liver effects and temporary nervous system depression. Individuals with preexisting diseases of the central SAL 000009814 MSDS MO. 1638PC DU PONT Material Safety Data Sheet u S 2 6^ age 5 FIRST AID INHALATION If inhaled, immediately artificial respiration. a physician. remove to fresh air. If not breathing, give If breathing is difficult, give oxygen. Call SKIN CONTACT Flush skin with water. The dye can be removed with hand hand cleaner. Call a physician. cream or EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGESTION If swallowed, water. Never physician. do not induce give anything vomiting. Immediately give two glasses of by mouth to an unconscious person. Call a NOTES TO PHYSICIAN Activated charcoal slurry may be administered. To prepare activated charcoal slurry, suspend 50 grams activated charcoal in 400mL water and mix thoroughly. Administer 5mL/kg, or 350mL for an average adult. Gastric lavage may be advisable for significant ingestions. PROTECTION INFORMATION GENERALLY APPLICABLE CONTROL MEASURES AND PROCEDURES Keep away from heat, sparks and flames. Keep container in a cool place. Keep container tightly closed. Ground container when pouring. Use of non-sparking and explosion-proof equipment may be necessary depending on type of operation. Use ventilation that is adequate to keep airborne concentrations below exposure limits. Avoid conditions that are likely to generate airborne mists. SAL 000009815 MSDS No. 1638PC DU PONT Material Safety Data Sheet GS 269 Page 7 SHIPPING INFORMATION DOT Proper Shipping Name : XYLENE SOLUTION Hazard Class : FLAMMABLE LIQUID UN/NA NO. : 1307 DOT Labels(s) : FLAMMABLE LIQUID DOT/IMP Proper Shipping Name : Hazard Class : UN No. : DOT/IMO Label : Special Information: XYLENE SOLUTION FLAMMABLE LIQUID, 1307 FLAMMABLE LIQUID PAGE 3158 3.3 Shipping Containers Tank Truck Steel Drums - DOT 17E STORAGE CONDITIONS Store in well ventilated area. Keep container tightly closed. in accordance with National Fire Protection Assn regulations. Store TITLE III HAZARD CLASSIFICATIONS Acute Chronic Fire Reactivity Pressure : Yes : Yes : Yes : No : No ADDITIONAL INFORMATION AND REFERENCES CALIFORNIA PROPOSITION 65: This product contains trace quantities (<400 ppm) of benzene, a chemical known to the State of California to cause cancer. The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. 000009a16 $M- DU PONT Material Safety Data Sheet G S 2 70 Page 1 MATERIAL IDENTIFICATION DUPONT OIL RED B LIQUID MSDS NUMBER CORPORATE NUMBER : 1701PC : DU000613 Revision Date Date Printed : 04-Nov-90 s 28-Nov-90 MANUFACTURER/ DISTRIBUTOR Du Pont 1007 Market Wilmington, Street DE 19898 PHONE NUMBERS PRODUCT INFORMATION TRANSPORT EMERGENCY MEDICAL EMERGENCY 1-(800)441-7515 1-(800)424-9300 1"(800)441-3637 CHEMICAL FAMILY DISAZO DYE TRADE NAMES / SYNONYMS C. I. SOLVENT RED OIL RED B LIQUID RED B LIQUID 164 DU PONT REGISTRY NUMBERS TSCA INVENTORY STATUS s NPCA-HMIS RATINGS : DP364-08-3 Reported/Included Health: 1 Flammabi 1 ity: 3 Reactivity: 1 Personal Protection rating to be supplied user depending on use conditions. by COMPONENTS Material *XYLENE (ETHYLBENZENE) (BENZENE) 2-NAPTHALENOL[(PHENYLAZO)PHENYL]-AZO ALKYL DERIVATIVES (C.I. SOLVENT RED 164)* CAS Number 1330-20-7 100-41-4 71-43-2 71819-51-7 % 35 (6.7) (c.035) 56-61 * Regulated as a toxic chemical under section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372. SAL 000009817 HSD8 NO. 1701PC DU PONT Material Safety Data Sheet Cr S 2 7 0 Page 3 HEALTH HAZARD INFORMATION ANIMAL DATA: OIL RED B LIQUID Oral LD50: > 20.8 g/kg in rats Skin Absorption LD50: > 10.2 g/kg in rabbits XYLENE (mixed isomers) Inhalation 4 hour LC50: 6,700 ppm in rats The product ingredients contain moderate to severe skin and eye irritants in animals. Animal effects attributed to xylene include narcosis caused by skin absorption. Toxicity described for xylene from exposure by inhalation include upper respiratory irritation; central nervous system and behavorial effects; decreased weight gain; hearing loss; and effects on the liver, kidneys, heart, spleen, lungs, bone marrow, and blood. Central nervous system effects; decreased body weights; and liver effects were seen in animals exposed by ingestion to xylene. Tests on xylene in animals demonstrate no carcinogenic activity* While one dye component did produce genetic damage in bacterial cell cultures, xylene does not produce heritable genetic damage in animals or genetic damage in bacterial or mammalian cell cultures. Although abnormal sperm were observed after an intraperitoneal injection in rats, xylene did not produce reproductive effects; developmental toxicity was observed but only at concentrations that were maternally toxic. HUMAN HEALTH EFFECTS OF OVEREXPOSURE BY: Skin contact with xylene may include drying of the skin with irritation and rash. Skin permeation can occur in amounts capable of producing the effects of systemic toxicity. Eye contact may include eye irritation with discomfort, tearing, or blurring of vision. Inhalation of xylene may include nonspecific discomfort, such as nausea, headache, or weakness; and temporary nervous system depression with anaesthetic effects such as dizziness, headache, confusion, incoordination, and loss of consciousness. Higher exposures may lead to cardiac stress; anemia and other blood changes; respiratory effects; possible liver and kidney damage; or fatality from gross overexposure. Ingestion of xylene may include gastrointestinal irritation; nonspecific discomfort, such as nausea, headache, or weakness; liver effects and temporary nervous system depression. Individuals with preexisting diseases of the central SAL 0OOO98ia MSDS NO. 1701PC DtJ PONT Material Safety Data Sheet 6 S 2 7 0 page 5 FIRST AID INHALATION If inhaled, immediately artificial respiration. a physician. remove to fresh air. If not breathing, give If breathing is difficult, give oxygen. Call SKIN CONTACT Flush skin with water. The dye can be removed with hand cream or hand cleaner. Call a physician. EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGESTION If swallowed, water. Never physician. do not induce give anything vomiting. Immediately give two glasses of by mouth to an unconscious person. Call a NOTES TO PHYSICIAN Activated charcoal slurry may be administered. To prepare activated charcoal slurry, suspend 50 grams activated charcoal in 400mL water and mix thoroughly. Administer 5mL/kg, or 350mL for an average adult. Gastric lavage may be advisable for significant ingestions. PROTECTION INFORMATION GENERALLY APPLICABLE CONTROL MEASURES AND PROCEDURES Keep away from heat, sparks and flames. Keep container in a cool place. Keep container tightly closed. Ground container when pouring. Use of non-sparking and explosion-proof equipment may be necessary depending on type of operation. Use ventilation that is adequate to keep airborne concentrations below exposure limits. Avoid conditions that are likely to generate airborne mists. PERSONAL PROTECTIVE EQUIPMENT EYE/FACE PROTECTION Wear safety glasses or coverall chemical splash goggles. RESPIRATORS Where there is potential for airborne exposures in excess applicable limits, wear NIOSH/MSHA approved respiratory protection. of PROTECTIVE CLOTHING Where there is potential for skin contact have available and wear as appropriate, impervious gloves, apron, pants, and SAL 000009319 MSDS HO. 1701FC DU PONT Material Safety Data Sheet (SHIPPING INFORMATION - Continued) Shipping Containers Tank Truck Steel Drums - DOT 17E 6 S 2 7 0 Page 7 STORAGE CONDITIONS Store in well ventilated area. Keep container tightly closed. in accordance with National Fire Protection Assn regulations. Store TITLE III HAZARD CLASSIFICATIONS Acute chronic Fire Reactivity Pressure : Yes s Yes : Yes s No s No ADDITIONAL INFORMATION AND REFERENCES CALIFORNIA PROPOSITION 65: This product contains trace quantities (< 300 ppm) of benzene, a chemical known to the State of California to cause cancer. The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Responsibility for MSDS : R. v. Daum Chemicals & Pigments Wilmington, DE 19898 800-441-9442 # Indicates updated section. End Of MSDS ^4 4 00 O09 Pr-inted 10-19-1990 . ~*m 512 0 ADDITIVE Hi 8-002372 MATERIAL SAFETY DATA SHEET Page l _ 4 26 1 - GENERAL INFORMATION CHEHLINK INDUSTRIAL, A DIVISION OF CHEMUNK, Z COUNTRY VIEW ROAD MALVERN, PA 19355-1435 INC. EMERGENCY CONTACT 24HRS 800/424/9300 CHEMTREC SECONDARY 24HRS TELE NBR 215/640/2200 CHEML1NK GENERIC NAME ORGANOSIL1CONE DEFOAMER DOT PROPER SHIPPING NAME NOT REGULATED DOT HAZARD CLASS NOT REGULATED REVISION 03: 12/15/89 UN/NA NUMBER N/AP 2 - SUMMARY OF HAZARDS CAUTION ( NFPA RATING: HEALTH - 1; FLAMMABILITY - 0; REACTIVITY - 0 PHYSICAL HAZARDS: NONE KNOWN ACUTE HEALTH EFFECTS: (SHORT-TERM) EYE: DIRET CONTACT MAY CAUSE SLIGHT IRRITATION SKIN: NO HAZARD IDENTIFIED (SEE CHRONIC HAZAROS) INHALT ION: NO HAZARD IDENTIFIED INGESTION: NO HAZARD IDENTIFIED CHRONIC HEALTH EFFECTS: (LONG-TERM) PROLONGED OR REPEATED SKIN EXPOSURE MAY CAUSE IRRITATION. NO OTHER INFORMATION IS AVAILABLE ABOUT THE EFFECTS FROM LONG-TERM OR REPEATED EXPOSURE. AS WITH ANY INDUSTRIAL CHEMICAL, GOOD HYGIENE SHOULD BE USED TO PREVENT CHRONIC CONTACT WITH LIQUIDS, MISTS, VAPORS, AND FUMES. 3 - COMPONENTS COMPONENT NAME CAS NUMBER WATER POLYPROPYLENEGLYCOL 7732-18-5 9016-45-9 IHGREOIENTS NOTPRECISELY IDENTIFIED ARE PROPRIETARY OR NONKAZARDOUS. 7SCA INVENTORY -ALL INGREDIENTS ARE LISTED. SARA SECTION 313 INFORMATION -NO INGREDIENTS ARE REPORTABLE. CARCINOGENICITY -NO INGREDIENTS ARE LISTED BY IARC, NTP, OR OSHA. SAL 000009921 Printed 10-19-1990 t^Ctn 5120 ADDITIVE ID: $-002372 MATERIAL SAFETY DATA SHEET / HEALTH HAZARDS (continued) SKIN IRRITATION NAY CAUSE SLIGHT IRRITATION UPON PROLONGED EXPOSURE. INGESTION NO APPROPRIATE HUMAN OR ANIMAL HEALTH EFFECTS DATA ARE KNOUH TO EXIST. LARGE AMOUNTS INGESTED MAY CAUSE GASTROINTESTINAL DI SCONFORT. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE NO ADDITIONAL MEDICAL INFORMATION FOUND. 8 - PROTECTIVE EQUIPMENT / CONTROL MEASURES RESPIRATORY PROTECTION IF EXCESSIVE MISTS/VAPORS ARE GENERATED USE A NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR WITH AN ORGANIC VAPOR CARTRIDGE AND A DUST/MIST PREFILTER. EYE PROTECTION EYE PROTECTION SUCH AS CHEMICAL SPLASH GOGGLES AND/OR FACE SHIELD MUST BE WORN WHEN POSSIBILITY EXtSTS FOR EYE CONTACT DUE TO SPLASHING OR SPRAYING LIQUID, AIRBORNE PARTICLES, OR VAPOR. CONTACT LENSES SHOULD NOT BE WORN. SKIN PROTECTION WEAR IMPERVIOUS RUBBER GLOVES. USE OTHER PROTECTIVE CLOTHING AS NECEAARY TP PREVENT PROLONGED OR REPSATED CONTACT. ENGINEERING CONTROLS USE LOCAL EXHAUST AT POINT OF MIST/VAPOR RELEASE. OTHER HYGENIC PRACTICES USE GOCO PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, ORINKING, SMOKING, OR USING TOILET FACILITIES. PROMPTLY REMOVE SOILED CIOTHING/UASH THOROUGHLY BEFORE REUSE. SHOWER AFTER WORK USING PLENTY OF SOAP AND WATER. OTHER WORK PRACTICES USE GOCO PERSONAL HYGIENE PRACTICES. WASH HANDS 8EF0RE EATING, DRINKING, SMOKING, OR USING TOILET FACILITIES. PROMPTLY REMOVE SOILED CLOTHING/WASH THOROUGHLY BEFORE REUSE. SHOWER AFTER WORK USING PLENTY OF SOAP AND WATER. 9 - EMERGENCY AND FIRST AID INHALATION REMOVE TO FRESH AIR IMMEDIATELY. OBTAIN MEDICAL ATTENTION IF BREATHING DIFFICULTY PERSISTS. EYE CONTACT IN CASE OF EYE CONTACT, IMMEDIATELY RINSE WITH CLEAN WATER FOR 20-30 MINUTES. RETRACT EYELIDS OFTEN. OBTAIN EMERGENCY MEDICAL ATTENTION IF PAIN, BLINKING, TEARS OR REDNESS PERSIST. SKIN CONTACT WASH THOROUGHLY WITH SOAP AND WATER INGESTION INGESTION UNLIKELY. HOWEVER, IF INGESTED, OBTAIN EMERGENCY MEDICAL ATTENTION. EMERGENCY MEDICAL TREATMENT PROCEDURES NO ADDITIONAL MEDICAL INFORMATION FOUND. Page 3 S 426 Printed 10-19-1990 ,D:I^Cth 51-2o0237A2 DDITIVE MATERIAL SAFETY DATA SHEET 1-, - DISCLAIMERS (continued) THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH UE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESS OR IMPLIED, REGARDING ITS CORRECTNESS. THE CONDITIONS OR HETHQOS OF HANDLING, STORAGE, USE AND DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL ANO MAY BE BEYONO OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAT CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. THIS MSDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PROOUCT. IF THE PROOUCT 1$ USED AS A COMPONENT IN ANOTHER PROOUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. THIS MSDS HAS 8EEN PREPARED IN ACCORDANCE WITH THE REQUIREMENTS OF THE OSKA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). Page 5 6s 426 SAL 000009823