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Associated Lead Inc. 2545 Aramingo Avenue Philadelphia, PA 19125 { 1 800-523-0882/3 in PA. 800-822-3959 TRI-MAL A Stabilizer and Vulcanizing Agent for Chlorosulfonat d Polyethyl n DS-033 DESCRIPTION TRI-MAL is a tribasic lead salt of maleic acid in the form of a soft crystalline powder. In chlorosulfonated polyethylene, it functions as both a chlorine acceptor and vulcanizing or curing agent. ADVANTAGES Excellent thermal stability Controlled cross linking activity Good color retention and weathering Superior water resistance in cured stock Resists scorching Good electrical insulation properties TYPICAL PROPERTIES Composition..................................... -- Tribasic lead maleate Form.................................................. -- Soft crystalline powder / Specific Gravity................................ Lead Content, PbO %..................... .... 6.3 .... 89.0 Moisture, loss, 2 hrs. @105CC........ .... 0.2 Fineness, through No. 325 sieve, % .... 99.8 Solubility.......................................... Insoluble in all common solvents APPLICATIONS Wire and cable extrusions Mechanical stocks Coatings for fabrics and rubber Adhesives and sealants DO 087024 CONFIDENTIAL GENERAL RECOMMENDATIONS The level of TRI-MAL used in chlorosulfonated polyethylene generally ranges from 20 to 30 parts. The exact level needed will depend on the rate of vulcanization desired, and the degree of heat stability and tightness of cure required. TOXICITY AND HANDLING Precautions should be taken when working with lead compounds. A Material Safety Data Sheet is available on request. ( NOTE: The recommendations made herein are based on our research and the research of others, and are believed to be accurate. No guarantee of their accuracy is made, however, and the products discussed are sold without warranty, express or implied, and upon condition that purchasers shall make 4/81 their own tests to determine the suitability of such products for their particular purposes Likewise, statements concerning the possible use of these products are not intended as recommendations to use these products in infringement of any patent Associated Lead Inc. MATERIAL SAFETY DATA SHEET '^vSECTION I v- ^L LCTURERS NAME ASSOCIATED LEAD, INC. REGULATORY AFFAIRS DEPARTMENT 3/1/82 STREET ADDRESS 2545 ARAMINGO AVENUE CITY. STATE, ZIP PHILADELPHIA, PA. 19125 PRODUCT CLASS Stabilizer MANUFACTURER'S COOC I D. 34033 TRAM NAME Tp'roal EMERGENCY TELEPHONE NO. 215*427-4681 i IsSmSPsP INGREDIENT OUSSNGRE PERCENT BY WEIGHT nv PPM m g/m3 LEI % VAPOR PRESSURE mm Hfl @ 68F Tribasic Lead Maleate 100.0 -- 0 05^ j (1) OSHA Standard, 29 CFR 1910.1025 n0.'2? (2) A ZH year Implementation schedule in effect as of Jan. 11 1982 for certain industries including cabl'e coating, pottery, explosives, glass, ammu n'tion and plastic: and rubber manufacturing. (2) OSHA Standard, 29 CFR 1910.1000 Table 1-2 in effect during thp ypAr implpmpAt.at-inn pprh'nH OILING RANGE N/A VAPOR DENSITY 1 1 HEAVIER [lj//\ Q LIGHTER THAN AIR S EVAPORATION RATE 1 1 FASTER |\|/A O SLOWER THAN ETHER % VOLATILE BY VOLUME WEIGHT PER GALLON SPECIFIC GRAVITY 6.3 CATEGORY N/A EXTINGUISHING MEDIA (T| WATER-FOG OTHER EH CARBON DIOXIDE [^] DRY CHEMICAL UNUSUAL flRI AND EXPLOSION HAZARDS FLASH POINT ____N/A LEI Unknown Isolate from heat, open flames and all sources of sparks including static electricity. Use non-metal lie scoops. Equipment and hoppers must be properly Grounded. SPECIAL FIRE FIGHTING PROCEDURES "-- None. STABILITY UNSTABLE incompatabiutv t* ` "',IAU TO AVOID) STABLE CONDITIONS TO AVOID Keep dust accumulation to a minimum. ..one. HA2AADOUS DECOMPOSITION PPOOUCTS On ignition, oxides of lead may be volatilized. HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID Tpmppyaturp<; greater than 40QF N/A--NOT APPLICABLE iaiil DO 08702S CONFTDFNTIAl lTMBtJ^mp UMJT vilul , " % t ... p.CbOmg/m based on lead using engineering and work practice controls rffective 2% yrs. from 1/ Depending on individual susceptability and degree of overexposure* effects are generally sees only after long-term exposure, although short-term high-level exposure may also be poison Symptoms may include tiredness, decreased appetite, metallic taste and stomach cramps resem bling colic (intermittent rather than continuous pain). More severe symptoms could include true muscle weakness, intense headaches and on rare occasions convulsions and even more rare death. Kidney damage may occur without symptoms. Lead crosses the placenta, Fetal exposurt should be kept within guidelines of the Communicable Disease Center of the U.S. Department HEW-30ug/100g of blood. (MHGIMCV AND Mtl AID PtOClDUEIi . " -- ------------1 "---------------------" Abnormal Ingestion - Induce vomiting. Use syrup of ipecac-one ounce followed by eight ounces 5f water. Call a physician at once. External - The product may be removed by washing with soap and water. '..'ear gloves, goggles and respirator. Clean area returning all material possible to containe DUUo notliut uUs3Ce cUoUmNlpj-MreCsis^CeUd adlilr fI oU rI cVlleCadnllilnligy fI loIUoUrI sJ and other surfaces.* These surfaces' . w ----------------- should be cleaned by vacuuming, taking care that the material is not returned to the work area. WA$TC DI$PO$Al METHOD Keep waste rags in a labeled safety container-do not incinerate. accordance with state, local or federal regulation._______________ Disposal must be in RESPIRATORY PROTECTION NICSH approved respiratory protection must be used in accordance with existing standards. Vc-dical Removal Protection (MRP) and biological surveillance are necessary. Respirator must be worn if PEL of 0.05mg/m3 is' exceeded. See 29CFR 1910.102S(k); 1910.134. VENTUAftON _ ~~ r" All work areas where lead compounds are used must be ventilated to keep TLV below acceptable fU&tt&ww See Z9CFRyl910.94. IY* PROTECTION OTHEE PPOTICTIVE EQUIPMENT Yes - gogg,les * B1 ____________ Use respirator. Use clean workclothes. Change workclothes daily. PMCAUTiOnS TO IE TAKEN IN HANDlINQ AND STOEINQ WrPEOiAL#REOAMpbN S I DO 0B7026 CONFIDENTIAL Take every precaution to avoid contamination of the atmosphere. *Special care should be give to removing lead from hair and under fingernails. *Working or contaminated clothes and shoes must not be worn home. ^Before entering eating areas, work clothing should be removed or loo dust vacuumed off clothing surface. *Take every precaution to avoid ingestion and inhalation *Use gloves and avoid spilling on hands, face or body. *Do not smoke, eat or apply cosmet in v/ork area. *Wash hands and face thoroughly before entering into eating areas. While the information and recommendations set forth are believed to be accurate as of the^at Associated Lead Inc. MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE OR ACTION BASED THEREON. Because of the nature of the product, user assumes all ri .nth respect to it N/A--NOT APPLICABLE