Document bavL1EKkRLvMVNo6k4YnG31d3
Interoffice Communication
to Distribution
From Tom Grumbles
Date March 28, 1984 subject DRAFT MSDS FOR ALFONICS
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Enclosed are draft MSDSs for three new ALFONICS. As you will see, these products are very similar to existing products. The only significant changes are in Section 3, with a few additions elsewhere. Please review the appro priate sections as indicated below and return any comments to me by April 23.
Thomas G. Grumbles
Enclosure
Distribution:
Sid Pitts - Section 4,7,8,9 Bill Broddle - Section 5 Dr. Drumwright - Section 5 Dan Plummer - Sections 3,6 Joe Ledvina - Section 7 Susan Litzau - Legal Aspects
vvv 000005 70
conoco
MATERIAL SAFETY DATA SHEET
Conoco Chemicals Company Houston, TX 77224
1. PRODUCT IDENTIFICATION
MANUFACTURER'S NAME Conoco Chemicals Company
ADDRESS
P.O. Box 727, Westlake, LA 70669
TRADE NAME SYNONYMS
ALFONIC 610- 60
REGULAR TELEPHONE NO. (318) 491-5403
EMERGENCY TELEPHONE NO.(318) 491-5142
5. HEALTH HAZARD INFORMATION
FIRST AID
EYES:
Flush eyes with large amounts of water for at least 15 minutes. If irritation persists, seek medical aid.
Flush with water, then wash affected area with mild soap and water.
INHALATION: Remove to fresh air. If breathing has stopped, administer artificial respira tion or oxygen. Seek medical aid.
iKj/-ccTirM
^ot *n<^uce Vomiting, if large amounts are ingested, gastric lavage with large amounts
INGESTION: cf water or 5 percent sodium bicarbonate by qualified persons. Seek medical aid.
NATURE OF HAZARD
EYES:
Irritation may occur with exposure to concentrated vapors. Liquid is contact irritant. May cause corneal inflammation.
SKIN:
Repeated or prolonged contact can cause reddening of the skin, scaling, ana dermatitis.
INHALATION: This nnaterial is a negligible hazard due to its low volatility. If vapor is pres ent in high concentrations, irritation to upper respiratory tract may occur.
INGESTION: Low order of toxicity. No hazard by this route in normal use.
EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: Irritation of contacted areas. CHRONIC OVEREXPOSURE: Unknown.
THRESHOLD LIMIT VALUE (TLV)
None established.
THYiriTY hata ICIaICIIY UAIA
This specific product has not been tested. Data from a very similar material is below.
SKIN CONTACT: Acute Dermal LD50, Rabbits: 1.5-17 g/kg Skin Irritation Index, Rabbits: 3.2 (Max. possible score is 8.0).
EYE CONTACT:
Eye Irritation Index: 58 (72 hrs. after exposure) (max. possible score is 110)
INHALATION:
All rats survived a 4-hour exposure to 8 mg/I.
INGESTION:
Acute Oral LD50, Rat: 5.1 g/kg.
SPECIAL PRECAUTIONS: Avoid Eye Contact.
VVV 000000572
6. REACTIVITY DATA
CONDITIONS CONTRIBUTING TO INSTABILITY High temperatures.
INCOMPATIBILITY Can react with strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Should not occur.
7. SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Eliminate open flames. Contain the spill.
NEUTRALIZING CHEMICALS
WASTE DISPOSAL METHOD May be picked up mechanically or with a solid sorbent and sent to an approved landfill or incin erated in accordance with federal, state, and local regulations.
SPECIAL PROTECTION INFORMATION
VENTILATION REQUIREMENTS Mechanical ventilation may be necessary if working with this product in enclosed areas. Trace amounts of ethylene oxide may be present in the product ana could accumulate in vapor spaces of storage or transport vessels. The ACGIH TLV for ethylene oxide is 10 ppm.
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY (SPECIFY IN DETAIL): If needed, NIOSH approved organic vapor respirators should be worn.
EYE: Chemical goggles or full-face shield to protect from splash.
GLOVES: Rubber or other impervious material to avoid repeated or prolonged skin contact.
OTHER CLOTHING AND EQUIPMENT:
VVV 000000573
Other impervious clothing as needed to avoid repeated or prolonged skin contact.
9. SPECIAL PRECAUTIONS
HAZARD CLASSIFICATION INFORMATION
IMCO HAZARD CLASS AND NUMBER
US DOT CLASSIFICATION No hazard classification.
UN NUMBER
EEC DANGEROUS SUBSTANCE CLASSIFICATION
ADR CLASS NUMBER
EEC SPECIAL RISKS AND SAFETY ADVICE
CAS NUMBER 68439-45-2
TRANSPORTATION AND STORAGE
USUAL SHIPPING CONTAINERS
Tank cars Tank trucks Drums
STORAGE TRANSPORT TEMPERATURE
ELECTROSTATIC ACCUMULATION HAZARD Ambient
STORAGE/TRANSPORT PRESSURE Ambient
LOADING/UNLOADING TEMPERATURE
Ambient
VISCOSITY AT LOADING/ UNLOADING TEMPERATURE
HANDLING AND STORAGE MATERIALS AND COATINGS
SUITABLE
UNSUITABLE
Carbon steel--if moisture control is suitable.
Recommend baked phenolic coating.
Stainless Steel
Aluminum
Zinc Galvanized
THE ABOVE DATA IS BASED ON TESTS AND EXPERIENCE WHICH CONOCO BELIEVES RELIABLE AND ARE SUPPLIED FOR INFORMATIONAL PURPOSES ONLY. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WAR RANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO.
NOVEMBER 1982
VVV 000000574
CH-260
MATERIAL SAFETY DATA SHEET
conoco
Conoco Chemicals Company P.O. Box 19029 Houston, TX 77224
5. HEALTH HAZARD INFORMATION
FIRST AID
EYES:
Flush eyes with large amounts of water for at least 15 minutes. If irritation persists, seek medical aid.
SKIN:
Flush with water, then wash affected area with mild soap and water.
INHALATION: Remove to fresh air. If breathing has stopped, administer artificial respira tion or oxygen. Seek medical aid.
Do Not Induce Vomiting. If large amounts are ingested, gastric lavage with large amounts INGESTION: of water or 5 percent sodium bicarbonate by qualified persons. Seek medical aid.
NATURE OF HAZARD
EYES:
Irritation may occur with exposure to concentrated vapors. Liquid is con tact irritant. May cause corneal inflammation.
1
SKIN:
Repeated or prolonged contact can cause reddening of the skin, scaling, ana dermatitis.
INHALATION: This material is a negligible hazard due to its low volatility. If vapor is pres ent in high concentrations, irritation to upper respiratory tract may occur.
INGESTION: Low order of toxicity. No hazard by this route in normal use.
EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: Irritation of contacted areas. CHRONIC OVEREXPOSURE: Unknown.
THRESHOLD LIMIT VALUE (TLV)
None established.
TOXICITY DATA
SKIN CONTACT: Acute Dermal LD50, Rabbits: 1.5-5.0 g/kg Skin Irritation Index, Rabbits:l. 5 to 3.2 (Max. possible score is 8.0).
EYE CONTACT: Eye Irritation Index: 32-58 (72 hrs. after exposure) (max. possible score is 110)
INHALATION:
INGESTION:
Acute Oral LD50, Rat: 3-5 g/kg.
SPECIAL PRECAUTIONS: Avoid Eye Contact.
VVV 000000576
6. REACTIVITY DATA
CONDITIONS CONTRIBUTING TO INSTABILITY High temperatures.
INCOMPATIBILITY Can react with strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Should not occur.
7. SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Eliminate open flames. Contain the spill.
NEUTRALIZING CHEMICALS
WASTE DISPOSAL METHOD May be picked up mechanically or with a solid sorbent and sent to an approved landfill or incin erated in accordance with federal, state, and local regulations.
8. SPECIAL PROTECTION INFORMATION
VENTILATION REQUIREMENTS Mechanical ventilation may be necessary if working with this product in enclosed areas. Trace amounts of ethylene oxide may be present in the product ana could accumulate in vapor spaces of storage or transport vessels. The ACGIH TLV for ethylene oxide is 10 ppm.
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY (SPECIFY IN DETAIL): If needed, NIOSH approved organic vapor respirators should be worn.
EYE: Chemical goggles or full-face shield to protect from splash.
GLOVES: Rubber or other impervious material to avoid repeated or prolonged skin contact.
o00 OTHER CLOTHING AND EQUIPMENT: Other impervious clothing as needed to avoid repeated or prolonged skin contact.
9. SPECIAL PRECAUTIONS
HAZARD CLASSIFICATION INFORMATION
IMCO HAZARD CLASS AND NUMBER
US DOT CLASSIFICATION No hazard classification.
UN NUMBER
EEC DANGEROUS SUBSTANCE CLASSIFICATION
ADR CLASS NUMBER
EEC SPECIAL RISKS AND SAFETY ADVICE
CAS NUMBER 68439-45-2
TRANSPORTATION AND STORAGE
USUAL SHIPPING CONTAINERS Tank cars Tank trucks Drums
STORAGE TRANSPORT TEMPERATURE
Ambient
ELECTROSTATIC ACCUMULATION HAZARD
STORAG^/TRANSPORT PRESSURE Ambient LOADING/UNLOADING TEMPERATURE Ambient VISCOSITY AT LOADING/ UNLOADING TEMPERATURE
HANDLING AND STORAGE MATERIALS AND COATINGS
SUITABLE
UNSUITABLE
Carbon steel--if moisture control is suitable.
Recommend baked phenolic coating.
Stainless Steel
Aluminum
Zinc Galvanized
THE ABOVE DATA IS BASED ON TESTS AND EXPERIENCE WHICH CONOCO BELIEVES RELIABLE AND ARE SUPPLIED FOR INFORMATIONAL PURPOSES ONLY. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WAR RANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO.
NOVEMBER 1982
Wv OOOOO0578
CH-260
conoco
MATERIAL SAFETY DATA SHEET
Conoco Chemicals Company Houston, TX 77224
1. PRODUCT IDENTIFICATION
MANUFACTURER'S NAME Conoco Chemicals Company
ADDRESS P.O. Box 727, Westlake, LA 70669
TRADENAME "Alfonic" 1216-30 SYNONYMS
REGULAR TELEPHONE NO. (318) 491-5403
EMERGENCY TELEPHONE NO. (318) 491-5142
2. HAZARDOUS INGREDIENTS
MATERIAL OR COMPONENT
%
I
HAZARD DATA
-
3. PHYSICAL DATA
BOILING POINT (F)
432 0 IBP
VAPOR PRESSURE (mm Hg.) <1 9 70F -
VAPOR DENSITY (AIR = 1)
SOLUBILITY IN WATER
Nil
SPECIFIC GRAVITY(H20 =1)
PERCENT VOLATILE BY VOLUME (%) EVAPORATION RATE ( =D
MELTING POINT
APPEARANCE AND ODOR
Clear, colorless liquid. Sweet, pungent odor.
0.909 43-47F
4. FIRE AND EXPLOSION DATA
FLASH POINT (TEST METHOD)
9Q7or K]
AUTOIGN1TION TEMPERATURE
FLAMMABLE LIMITS IN AIR. % BY VOL. LOWER
UPPER
EXTINGUISHING MEDIA
Water spray; carbon dioxide, dry chemical, alcohol-approved foam.
SPECIAL FIRE FIGHTING PROCEDURES
UNUSUAL FIRE AND EXPLOSION HAZARD
Cool exposed equipment with water spray. Self-contained breathing appa ratus should be worn if fighting fires in confined spaces.
VVV 000000579
5. HEALTH HAZARD INFORMATION
FIRST AID
EYES: SKIN:
Flush eyes with large amounts of water for at least 15 minutes. If irritation persists. seek medical aid.
Flush with water, then wash affected area with mild soap and water.
INHALATION:
Remove to fresh air. If breathing has stopped, administer artificial respira tion or oxygen. Seek medical aid.
INGESTION* Do Not Induce Vomiting. If large amounts are ingested, gastric lavage with large amounts * of water or 5 percent sodium bicarbonate by qualified persons. Seek medical aid.
NATURE OF HAZARD
EYES: SKIN:
Irritation may occur with exposure to concentrated vapors. Liquid is con tact irritant. Mav cause corneal inflammation.
Repeated or prolonged contact can cause reddening of the skin, scaling, ana dermatitis.
INHALATION: This material is a negligible hazard due to its low volatility. If vapor is pres ent in high concentrations, irritation to upper respiratory tract may occur.
INGESTION:
Low order of toxicity. No hazard by this route in normal use.
EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: CHRONIC OVEREXPOSURE:
Irritation of contacted areas. Unknown.
THRESHOLD LIMIT VALUE (TLV)
None established.
TOXICITY DATA
SKIN CONTACT:
This specific product has not been tested. very similar product is below.
Acute Dermal LD5q, Rabbits: ca 4 g/kg Skin Irritation Index, Rabbits: 4.3 (Maximum possible score is 8.0)
Data from a
EYE CONTACT:
Eye Irritation Index in Rabbits: 6.5 (Maximum possible score is 110)
INHALATION:
All rats survived one-hour exposure of 6.3 mg/I.
INGESTION:
Acute Oral LD50, Rat: >5 g/kg
SPECIAL PRECAUTIONS:
Avoid Eye Contact
VVV 000000580
6. REACTIVITY DATA
CONDITIONS CONTRIBUTING TO INSTABILITY High temperatures.
INCOMPATIBILITY Can react with strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Should not occur.
7. SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
NEUTRALIZING CHEMICALS
WASTE DISPOSAL METHOD
May be picked up mechanically or with a solid sorbent and sent to an approved landfill or incin erated in accordance with federal, state, and local regulations.
SPECIAL PROTECTION INFORMATION
VENTILATION REQUIREMENTS
Mechanical ventilation may be necessary if working with this product in enclosed areas. Trace amounts of ethylene oxide may be present in the product ana could accumulate in vapor spaces of storage or transport vessels. The ACGIH TLV for ethylene oxide is 10 ppm.
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY (SPECIFY IN DETAIL): If needed, NIOSH approved organic vapor respirators should be worn.
EYE: Chemical goggles or full-face shield to protect from splash.
GLOVES: Rubber or other impervious material to avoid repeated or prolonged skin contact.
OTHER CLOTHING AND EQUIPMENT:
VVV 000000581
Other impervious clothing as needed to avoid repeated or prolonged skin contact.
9. SPECIAL PRECAUTIONS
HAZARD CLASSIHCATION INFORMATION
IMCO HAZARD CLASS AND NUMBER
US DOT CLASSIFICATION No hazard classification.
UN NUMBER
EEC DANGEROUS SUBSTANCE CLASSIFICATION
ADR CLASS NUMBER
EEC SPECIAL RISKS AND SAFETY ADVICE
CAS NUMBER 68551-12-2
TRANSPORTATION AND STORAGE
USUAL SHIPPING CONTAINERS Tank cars Tank trucks Drums
STORAGE TRANSPORT TEMPERATURE
Ambient
ELECTROSTATIC ACCUMULATION HAZARD
STORAGE/TRANSPORT PRESSURE Ambient
LOADING/UNLOADING TEMPERATURE Ambient
VISCOSITY AT LOADING/ UNLOADING TEMPERATURE
HANDLING AND STORAGE MATERIALS AND COATINGS
SUITABLE
UNSUITABLE
Carbon steel--if moisture control is suitable
Recommend baked phenolic coating
Zinc Galvanized
Stainless steel
Aluminum
THE ABOVE DATA IS BASED ON TESTS AND EXPERIENCE WHICH CONOCO BELIEVES RELIABLE AND ARE SUPPLIED FOR
INFORMATIONAL PURPOSES ONLY. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WAR RANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO.
JULY 1982
VVv
00oOosg2
CH-256