Document bakZKQ8LoL1BGJxdRG951Yy7k

Monday August 22, 1963 Part III Environmental Protection Agency Allegations That Chemical Substances Cause Significant Adverse Reactions to Health or the Environment; Recordkeeping and Reporting Procedures 0000108* 73 3817a Federal Register / Vol. 40. No. 163 / Monday. August 22. 1903 / Rules and Regulations ENVIRONMENTAL PROTECTION AGENCY 40CFR Part 717 IOPTS-43001B; TSHFRL 2370-71 Records and Reports of Allegations That Chemical Substances Cause Significant Adverse Reactions to Health or the Environment; Recordkeeping and Reporting Procedurea AGENCY; Environmental Protection Agency (EPA). action: Final rule. SUMMARY: This rule implements section 0(c) of the Toxic Substances Control Act (TSCA). The rule requires manufacturers and certain processors of chemical substances and mixtures to keep records of significant adverse reactions to health or the environment alleged to have been caused by a substance or mixture. EPA tnay also inspect and require reporting of such records. effective date: 30 days after OMB provides the Control Number but no aooner than September 21.1983. FOR FURTHER INFORMATION CONTACT; Jack P. McCarthy. Director. TSCA Assistance Office (TS-799), Office of Toxic Substances. Environmental Protection Agency. Rm, E-S43. 401 M St., SW., Washington. D.C. 20460, Toll free: (800-424-9005). in Washington. D.C.: (554-1404), outside the USA: (Operator 202-55+-14W). SUPPLEMENTARY INFORMATION: I. Introduction Section 6(c) of the Toxic Substances Control Act requires that "any person who manufactures, processes, or distributes in commerce any chemical substance or mixture" must keep "records of significant adverse reactions to health or the environment, as determined by the Administrator by rule, alleged to have been caused by the substance or mixture." Section 8(c) requires that allegations of adverse reactions to the health of employees be kept for 30 years, and all other allegations be kept for five years. EPA may inspect these records and require submission of copies of such records. EPA proposed a rule to implement section 8(c) of TSCA. which was published in the Federal Register of July II.1980 (45 FR 4700B). Approximately 160 written comments were received on the proposal and public meetings were held in Washington. D.C-. Newark. N.].. and Houston. Texas. This preamble explains the final rule's provisions and addresses by topic the changes made from the proposal. A separate document titled "Responses to Individual Comments" presents EPA's responses to individual, substantive comments. This document is available to the public in the administrative record of this rulemaking. After considering the comments, the Agency in this final rule has changed certain provisions of the proposed rule, clarified others and significantly reduced the number of firms subject to recordkeeping and reporting provisions as proposed. These changes will improve the quality and accessibility of records kept end will focus the recordkeeping responsibility on those firms generally recognized to be part of the chemical industry. A. Purpose of the Rule The rule defines "significant adverse reactions" to chemical substances and mixtures and establishes a system of recordkeeping and reporting that will: 1. Create a historical record of significant adverse reactions alleged to have been caused by substance or mixture. EPA can examine such records whenever a chemical is discovered to present possible risks to human health or the environment. 2. Provide a means to identify previously unknown chemical hazards end to reveal patterns of adverse effects that might otherwise either not be noticed or go undetected for long periods of time. B. Outline ofRule Provisions Key provisions of the final rule are as follows; 1. The definition of "significant adverse reactions" places an increased emphasis on reactions that impair normal activities of humans or other organisms in the environment. Reactions that are "known human effects" do not have to be recorded. Also exempt from recording are environmental reactions directly attributable to spills or other incidents that have been reported to the Federal government. 2. Firms subject to the rule include manufacturers of chemical substances. Such manufacturers are also responsible for collecting allegations relating to their processing activities and distribution in commerce activities. Processors, that are not also manufacturers, are subject to the rule if they ere engaged in activities described in Standard Industrial Classification (SIC) codes 28 or 29il. 3. A retailer is exempt from this rule unless it 4a also a manufacturer or a processor subject to the rule. A firm whose sole activity is the distribution of chemical substances, (i.e.. a distributor that it not also a manufacturer or a processor) is exempt. Also exempt are manufacturers or manufacturing sites whose only activity involves mining or other extractive industry functions. 4. Firms are required to keep written and signed allegations. A firm must also record an oral allegation unless the firm requests the alleger to submit the allegation in writing. 5. Records of allegations received at any applicable plant site are to be kept at the company's headquarters or at a location central to its chemical operations. 8, No automatic reporting provision is included in the rule. Required reporting of any records kept under this rule will be by letter or by notice in the Federal Register. II. Significant Adverse Reactions A. Proposed Definition ond Comments The key element in this regulation is the definition of significant adverse reactions. The objective of the definition is to establish a file of significant adverse reactions that can be useful in finding unexpected or unrecognized problems. The core of the definition of significant adverse reactions in the proposed rule read as follows: Significant adverse reactions are reactions that may indicate a tendency of a chemical aubstance or mixture to cause long-lasting or irreversible damage to health or the environment * *. The proposed definition then listed certain examples or "indicators" of both health and environmental effects that should be considered significant. The human health indicators in the proposed definition further defined "significant" as a function of the reaction's duration or persistence after cessation of exposure. But, the proposal specifically attempted to avoid requiring recordkeeping of "one-time" reactions, Therefore, a reaction that did not persist beyond the period of exposure would be considered significant only if it were experienced repeatedly upon exposure. These indicators were developed in response to the following language in the Conference Report on section 8(c) of TSCA: The seriousness, duration, and the frequency of reactions should be taken into account in establishing what constitutes a significant adverse reaction For example, if an individual reports that a chemical aubstance causes his or her eyes to become inflamed and to tear, such reaction may be attributed to an isolated allergic reaction However, if several persons report similar reaction, then the reaction may indeed be significant. Because the ultimate Significance of adverse reactions is difficult to predict, the MCD 000018374 Federal Register / Vol. 43. No. 163 / Monday. August 22. 1983 / Rules and Regulations 33179 conferee* intend that the requirement to retain record* err on the side of safety. Some very senou* neurological disorder*, for instance, at fir*! present what appear to be trifling symptoms. (Toxic Substances Control Act. Conference Report, H R. Rep No. 941679. 94th Ccmg. 2d Sess. 61 (197b] ) Indicators of significant environmental reactions centered on gradual or sudden changes in the composition of plant or animal life in an area. The Agency received a substantial number of comments on the definition of significant adverse reactions. A majority of the comments from chemical companies and industry groups criticized the definition as being too vague or too broad to be useful, targeting the phrase "may indicate a tendency" as the major cause of this ambiguity. There was also criticism that the human health indicators did not accomplish the purpose of eliminating the recording of one-time effects. The concepts of duration of the reaction or persistence beyond cessation of exposure were also criticized, especially because examples such as headache or nausea were used. Comments from industry claimed that such reactions are common in workers end not usually associated with effects of a long-lasting or irreversible nature, either actual or potential. These commeniers recommended, instead, that the concept of serious impairment of normal activities be included in the definition: they also favored eliminating the human health indicators. On the other hand, environmental and labor groups criticized the proposed definition as being too restrictive. These commenters stated that this definition of health effects should be broadened to include serious one-time, short-lived, or reversible effects. In addition, these commenters objected to requiring recordkeepers to make a preliminary judgment about the long-lasting or irreversible nature of reported reactions. Commenters also disagreed with regard to the environmental indicators. Certain commenters wanted them eliminated. They claimed that many of the indicators could reflect adverse effects caused by natural or seasonal changes (e g fish kills due to natural algal blooms) which might be wrongly ascribed to a substance, effluent, or process. However, environment.il groups commen'i'd that the environmental indicators were not broad enough because they did not include daniagr to microbial life or the abiotic environment--oir. soil, water, or man-made or man-modified structures. B. The Final Definition After careful consideration of the comments, the Agency made cerlain modifications in the structure, emphasis, and application of the definition of significant advene reactions. The final definition reads as follows: Significant adverse reaction* are reaction* that may indicate a substantial impairment of normal activities, or long-lasi.ng or irreversible damage to health or the environment. The Agency agreed with comments that the definition needs to state more directly the Agency's concept of what adverse reactions are significant. Toward this end the Agency removed from the definition the modifying phrase "a tendency of a chemical substance or mixture to cause", in its place the definition contains a second descriptor of what is (or may be) significant, "a substantial impairment of normal activities '. The Agency believes that these changes add clarity and give the final definition an additional dimension not possessed by the proposed definition. In terms of human health the concept of a substantial impairment of normal activities will, of course, encompass physically manifest damage, Such as cancer, an organ dysfunction, a birth defect, or a neurological disorder. But. it can also include subjectively experienced adverse reactions that may not be physically verifiable but may presage a more serious effect. A substantial impairment of normal activities can also be an adverse environmental effect, e.g. reduced reproductive capabilities of a species, reduced agricultural productivity, or adverse behavioral alterations as observed by the alleger. Recordkeepers must exercise a substantial amount of judgment when comparing allegations received (i.e. the staled adverse reaction within the allegation) to this definition. Therefore, the definition retains the qualifier "may indicate" in order to require recordkeepers to consider for inclusion in the file those reactions of an apparently less serious nature that could point toward a future or more serious, underlying effect. In this way EPA is satisfying (he intent of Congress that "records err on the side of safety". C. Reactions That Kfust Be Recorded The Agency has removed the indicators of human health Bnd environmental reactions from the definition of significant adverse reaction end modified them for use in a new section of the regulation--S 717.12. Significant adverse reactions that must be recorded. Paragraph (a) of S 717.12 lists four groups of reactions to human health These are intended to provide examples of the range of reactions that should be considered "significant" and. thus, recorded. These types of reactions include: 1. Long-lasting or irreversible damage, such as cancer or birth defects. 2. Partial or complete impairment of bodily functions, such as reproductive disorders, neuorological disorders, or blood disorders. 3. An impairment of norma! activities which is experienced by ah or most of the persons exposed at one time. 4. An impairment of normal activities which is experienced each tine en individual is exposed. It Is not difficult to classify physically manifest reactions such as cancer, birth defects or reproductive disorders as significant adverse reactions. These reactions meet the criteria of longlasting or irreversible damage, or impairment of normal activities^ It is more difficult to classify those reactions of an apparently less serious nature that may be indicators of future problems. The Agency cannot predict and list in this regulation all such reactions. Therefore, reactions covered by 3. and 4. above include two criteria. First, they involve an effect that impairs normal activities, which can include both job and non-job related activities. Second, these effects are repeatable. That is. effects have been experienced by a group of people (even if n involves only one incident), or the effect has been experienced by one person several times and such reaction involves the same chemical substance, mixture, process, or effluent. These recordable reactions may at first appear to be open-ended. However, as explained later in this preamble, the Agency has included a conditional exemption of known human effects. This exemption will, therefore, place a certain limitation upon the recordable nature of reactions that may fall intu groups 3. and 4. above. Environmental reactions that must be recorded are outlined in paragraph (c) of | 717.12. They are. for the most part, similar in wording to the environmental indicators in the proposal. However, the Agency did agree with comments that changes in the composition of fungal and microbial life in an area can signal the presence uf a significant adverse ecological condition. Therefore, language has been added to the regulation to ensure that effects on these organisms are not ignored. Also the Agency agreed with comments that long-lasting or irreversible contamination of the MCD 000016875 38180 Federal Register / Vol. 48. No, 163 / Monday. Aucust 22. 1983 / Rules and Regulations physical environment, especially in the humans. Results of in vitro testing or case of ground water resource, is a animal testing related to the substance . significant adverse reaction to the in question may not be considered the environment that should be recorded. equivalent of a known human effect. For Contamination of physical example, a company cannot decide to environmental resources, especially those portions with a limited selfcleansing capability, can have unavoidable consequences for the dependent biota. Therefore the Agency believes that requiring companies to keep such allegations could alert both exclude from their records an allegation that a substance caused sterility in a worker solely because the scientific literature contains studies showing that the substance caused sterility in laboratory animals. them and the Agency to previously . Exemption From Recording undetected contamination or En viranmento! Effects unexpected consequences of existing effluents. Any duplication or overlap with reports of spills or other incidents already reported to the Federal government will be avoided through an Commenters asserted that the Agency should exempt known environmental effects in the same way as known 'human effects. If the Agency were to exemption discussed later in this allow such an exemption, we would preamble. want to apply similar caveats to it as D. Exempting Known Human Effects are applied to the known human effects exemption. There are several In connection with the definition itself, another major comment by many companies and industry groups promoted the concept of exempting "known effects" from the recordkeeping requirements of the rule. Commenters claimed that such sn exemption would be the most effective way of supporting one of the purposes of the rule--the identification of previously unknown chemical hazards. The exemption of known effects, they asserted, would keep the section 8(c) files from becoming filled with information about reactions differences, however. Allegations of adverse human health effects relate to one species and. often, will involve workers within a contained workplace where levels and types of exposure can be readily observed or quantified and compared with the literature. There are. however, many more variables involved in the case of environmental reactions. The problem becomes one of trying to fit an instance of environmental damage with reports in the literature. One would almost have to have a perfect match-up to substances that are already well with the species of animals or plants characterized in the scientific literature affected, levels of exposure (if known) or in reports to the Agency. Also, such and numerous other variables in order an exemption would prevent duplicative to satisfy the caveats in the definition recordkeeping It would be consistent and reach a point where the exemption with similar provisions in the Agency's TSCA section 8(e) policy statement (43 could be properly applied. Take, for example, a case in which an allegation FR 11110) and the enforcement policy statement regarding section 6(a)[2] of the Federal Insecticide. Fungicide and Rodenlicide Act (FIFRA) (44 FR 40716). After consideration of these comments, the Agency has determined that it is in keeping with the purpose of the rule to exempt known human effects from the recordkeeping requirements. The definition of known human effects ( 717.3(c)) covers commonly recognized human health effects resulting from states that use of substance x has adversely affected birds and certain livestock. If the literature cites only adverse effects of substance x on birds, then the exemption could not be applied because the effect on livestock is not also described. However, en exemption from recording certain environmental reactions is included in paragraph (d) of f 717.12. This exemption is based more exposure lo a substance as described in on the problem of duplication of the scientific literature, in product recordkeeping and reporting labeling, or in material safety data requirements than it is on whether the sheets. However, the exemption would reaction is "known" in the literature. A not apply if the reaction was a significant adverse reaction to the significantly more toxic effect than environment would not have to be previously reported, or if the reaction recorded if the alleged cause is directly resulted from a lower exposure level, a shorter exposure period, or a different exposure route than previously reported. It must be emphusized that this exclusion applies strictly to effects observed in or known to occur in attributable lo an incident of environmental contamination that has already been reported to the Federal government under any applicable authority. III. Appropriate Allegations and Recordable Reactions A. Written and Oral Allegations The Agency received considerable comment about the appropriate format and content of allegations that must ultimately be recorded- One specific issue involved oral allegations. Most companies commenting opposed the concept of being required to record oral allegations. Their basic position is that if an allegation contains information of specific concern, that it is fair to require that it be written down and signed. Environmental groups and labor unions commented that the Agency should require recording of ora) allegations, especially in the case of employees. Their contention was that a worker would be much more inclined to relate a problem orally to a supervisor than to commit such allegations to writing. However, one union representative was opposed to oral allegations because they would be transcribed by the company, with no review by the alieger. EPA agrees that a written and signed allegation is a superior type of allegation to deal with under this rule. It expresses the circumstances of the significant adverse reaction in the alleger's own words. The fact that it is written and signed also attests to the alleger's own seriousness of concern about the reaction. However, the Agency is also concerned about the potential consequences of a criterion that would recognize only written allegations. The Agency would in no wayiptend that such s requirement become an excuse for ignoring problems brought to a company's attention orally. Consequently, both written and oral allegations are subject to the rule. A company must take one of two actions with respect to oral allegations. It must transcribe the oral allegation into written form, or it must inform the alieger that his allegation may be recordable under this rule and request that he submit a written and signed allegation. It then becomes the responsibility of the alieger to provide the company with the allegation in written form. If the alieger does not respond to the company's request for a written allegation then the company is not obligated to take any further steps. Dy taking one of the two actions outlined above a firm will satisfy EP.Ys concern that the firm recognize oral allegations and Inke steps to consider such allegations for ultimate inclusion in their section 8(c) file. A final point concerns which company officiui(s] shad be responsible for recognizing and dealing with oral Federal Register / Vol. 48, No. 1G3 / Monday. August 22. 1903 / Rules and Regulations amai allegations. Commenters were opposed to having such company officials designated by rule, arguing that such a decision should be left up to the Individual firms. EPA agrees that the company is in the best position to determine which of their officials shall be responsible for handling oral allegations. However, the Agency does want to make clear that it expects companies to educate their line supervisory personnel regarding oral allegations so that a worker who wishes to make such allegation does not have to seek out some unknown or far removed company official in order to have his allegation heard. B. The Reaction's Cause Another issue involved the stated cause of the reaction. The allegation must clearly state the alleged cause of the adverse reaction by naming or identifying one or more of the following: (1] a specific chemical substance or mixture (2) an article containing a substance (3) a company process or operation involving a substance, or (4) an effluent, emission, or other site discharge. Commenters objected to allegations being allowed to cite articles, processes or emissions, but the Agency retained these criteria because in many cases a worker, consumer, or plant neighbor may not know the name of a specific chemical or mixture that it the perceived cause of a reaction. C. AJleger Feedback EPA is not requiring firms to set up a formal ellcger feedback program. However, the Agency strongly encourages firms to inform allegers regarding the ultimate disposition of their allegations. The Agency is aware that many firms have voluntarily developed such a feedback mechanism in connection with section 8(e) of TSCA. We encourage firms to implement similar practices of communication with persons submitting allegations that may be recordable under this rule. D. Recordable Reactions A firm may keep in its file any allegation received- However, a firm must at a minimum keep records of significant adverse reactions of the type outlined in \ 717.12--Significant adverse reactions that must be recorded. The criteria for both human heallh and environmental reactions have been discussed in Unit II of this preamble, along with the exemptions of known human effects and the exclusion for environmental reactions that have resulted from incidents previously reported to the Federal government. In summary, all allegations received by a firm may not necessarily be recordable. The allegation must meet certain criteria of form and content. Then, the reaction cited must meet the definition of a significant adverse reaction and not be subject to the exemptions in i 717.12. A final factor, which will be discussed in detail in the next unit of this preamble, is that firms subject to the rule are required to collect (i.e. consider for recordkeeping) allegations only from certain chemical processing operations that they own or control. . Hypothetical Examples The following hypothetical examples are presented in order to heip illustrate the rule's provisions. Hypothetical Examples ftei turn AaogrdaOl* tma mcw )> CoftWMtt (1) Several min suOrmi report eJamvng Mt around n* (Mntal W gev* N* 'fui FV' (?) On* worker nn 74: wnantret ha * rtaxM to won found chamc*1 W ho has aewoKcH not* foods. 0) A war*or *.tm 74: on aava-ai oceaitona wn*n ho has aorkad w.th chemical X ho has fltsmoncoa prtgii-g ringer* and nousoa Tno waratura turn thai tno*o rooneno O'* known to a> oiDOSuro *.*'* ** 100 part* par rv<.n n via workpsca ar Hooravor. th* plant morvtor.ng racordt show mat tonwa ot enarrKOl IfiMwdonci aieaoo 20 parts par miiyon. (4) On day whan 74 Hirwivi was M'F, a plant nrghoor calls tha company to eomptfn mi aomathing m iha *" rs mak.ng non wes A tempera often: a*e trial tha aiogaton p* tuomniod m writing pul nothing 4 ftjosaouantly roco>v*d (S| A tarmrn wmaa to a cnomeai plant mat rw lam pone aaama to ha** baeom# W4-h-4:oo horn tho company t wan* d-seotai tteri'h locatae ao*;*"i to ha property Th* farmer *1490* mat h-t catll*. whes* onry water SMS* th* pond, ha** astwrancar* wre'i; stiiiooni and on* cat* 01 ocormoo hoovat Samping record* o' i*t wain a> rha fair-fy anowad no srgrvt-cani lavai ol laachaia (6) Ahar pa^vang opt on a naw procasa mvohnng ervortnataa eomeounoa. a ma> aiiagaa 741 tr* contracted pa.niu: aoras on nar rasa mat lasiae aavorei dart cauimg har to m*i work (7) Tha family el a tong-nm* company employaa amtot mat may bfana m* ampler** * vmg sancar * causad by la* many yaara of won around chafttcai Y. Tna cemeany haatn racordt snow mat ma amy*oyaa *d not hotrta iaum eymplom* g^wg hi amproymant but ha did amok* eoaronot. Chanucai T a. how**r a tuaoacted human cercmogan. (B) A consume* ***** mat ana got a anot rmah ma taw tma 7* uaad m* comport/a naw datargam (*) A eonunw wnlas that *y*n with proear uonMehon (racommanonfl. h* get dQ3y and nojo*of m* o* vmat ho me tna eorrpan, a tunwure tavtn remorar (10) A nwgncoi o< a charmca' p'ant wtrtas mat on Mev is h* e*w numarowa daad *ah as wo* a* an orfy lum covamg ma waior downstroom from m* ptanl On May 13 tie plan* hao #*p*r4nc*d a ruptured Hr'1'* pip* that aitowac concentrated w*ate to enter ma nv; Tn* ap*i waa oufy reported 10 m* atato ano to EPA. No y**..__ No___ _________ Yet. Yea.-----------------Y#a._ _ No _ Yaa.. No....... _ ~B>ua Spa" m mathamogioOn*mi* a krwm human oftaei of oxeotura 10 ct^iM-ai w ai the leuot and route 01 looses atpononeoe By m* wonn Not* tuada era not a common-, raoogndad raccoon to enamc*' W nootut Tna raaction aspanancid aacn rm* 04 inemo^a a aspetac Even though the roporiao rascoon m a 'known r**nan an*ci'' tha wont*- icr-t to b* reoaiirdry Okpancnrir.g 9>* roodiori at a much ea irtmui Irvi. man moawtg ftrormabcft ndaia*. Tha oompany tftes* to ask m* akagar to a^mt Vat or*1 ailogatiow m wntmg &nc* hoflvtg wu roomrod. no turn* *:oor py m# oor<earry a roqwoo The ropoft c*tio foo*oduct>vo tftoreart or frm de'act* m Mtm tiiagwn to have boon cauMd by a ' dacha1ge" irgm a mtootai taewty TNs may c*p<s*rt a hrthano imoatoctod probtom ot oftovonmontai eoniammaaon. a Even Vwugh an awaifil orvama ocoittanea. ma roacter was a tucttantai npamom Of noma1 octvoai Alio, pta raacoon m a>gga*B<r* o' entoraen* an tacatai or a pc:mt4ih my* aanoua *"#. Even though ehomBai Yaa aussaeted human earonogan m* rvooft cannot oa oidudad on ff*s (111a furrar, a cannot bo arciuOwd on me aucc^i'.sn that amo*mg waa m* *01* esia# o' ma eancar or mat a may ha** a.i-anc*o in* eorenegamc preoaruas o' chamcai Y Tha company may. hpwavar. pisca m m* Ale auoenca of tha amoamg as a potent*! mtrgatmg lacLor Thar* * no mndonee ma' th* ram occtmao repoaiad>v or that tha oroduc* was u**d more than one* Also, fh*** was no mo^aiion that ma rash was an vnpamnani of ma eantumar a normal actwn a*. Tr* rapaatao raoaa et m* raacMri mas** a raeeraawa along mm tha taet mat ma foanf1 was an aooarant mpawnarri o' normal acmntroa Th* nino" aoos'**i:fr not a "known human *h*ct irow ma aspoataa eonoiwna asaocaiao win usa m ocoordanoa wtm d product a aaanng Th* arvnronmantai foaewn apo*ai to b* aractfy itmeulasu* to an mcioam ot onwontnantaf contammabon onaody raponad to EPA IV. Who Is Subject to the Rule The proposed rule covered all manufacturers, processors, and distributors of chemical substances and mixtures. The Agency proposed to exempt retailers unless they were also a manufacturer or processor. The Agency had to consider a number of factors in determining who should be subject to the final rule. First, there is the statutory language and Congressional intent. Section 6(c) states that "any person who manufactures, processes or distributes in commerce Mcr nOO 16377 38162 Federal Rosier / Vol. 48, No. 1G3 / Monday. Aucust 22. 1983 / Rules and Peculations any chemical substance or mixture shall maintain records * '."Congress clearly intended for such recordkeeping requirements to be comprehensive and to encompass firms engaged in the production and the major distribution activities of the chemical industry. However, during the development of the proposal it became apparent that there are many thousands of firms that can distribute or process a chemical substance in addition to those firms that are commonly associated with the chemical industry. The Agency also considered for whom the section 8(c) records would have the most immediate value. Certainly, the records will be valuable to the Agency as it investigates specific substances or classes of substances. But. more importantly perhaps, the recordkeeping requirements will become an early warning system for companies regarding previously unrecognized problems with their products or processes. The question then becomes, "for which firms will these allegations have the most meaning?" The Agency believes that recordkeeping responsibility should be concentrated in the hands of those firms that will have the greatest ability and the most incentive to take corrective or preventive action with respect to a potentially harmful substance or mixture. A. Manufacturers Subject to the Rule The Agency has determined that this final rule shall apply to all persons who manufacture chemical substances, except far a narrow category as outlined in B. of this unit. More specifically, the rule applies to firms that manufacture, import, or produce any amount of a chemical substance or mixture for the purpose of obtaining an immediate or eventual commercial advantage. The manufacturer category is the broadest category of firms subject to the rule. Certainly, most of these manufacturers will be companies primarily engaged in activities described in the Standard Industrial Classification (SIC) Major Group 26--Chemicals and Allied Products or SIC 2911--Petroleum Refining. However, numerous other firms produce, manufacture, or import chemicals. These firms may classify themselves in a primary SIC code other than in SIC 28 or 2911. This fact was made clear during reporting for the TSCA Inventory of Chemical Substances. Therefore, a firm should review activities at all its plant sites to determine whether any chemical production, manufacture, or importation occurs. If so. such firm is subject to this rule as manufacturer, regardless of the primary SIC code under which it reports for the purposes of the periodic census. As a manufacturer subject to this rule, a firm has the obvious responsibility to collect allegations regarding substances it manufactures. However, this firm must also collect allegations regarding certain chemical processing and distribution activities it may carry out. Therefore, the Agency believes that it is important to outline for manufacturers their comprehensive responsibilities for collecting allegations. This will be especially important direction for large, multi-industry firms. A manufacturer must collect: 1. Any allegation identifying a chemical substance it manufactures (this includes, of course, any allegation identifying a company process or operation--see unit 111. B. of this preamble and section 717.10 of the rule). 2. Any allegation identifying any of its own processing or distribution in commerce activities with respect to any chemical it manfuactures. 3. Any allegation identifying emissions, effluents, or other discharges from activities described above (again, see unit 111. B. of this preamble). Note that a manufacturer is responsible for any of its processing or distribution activities involving any chemical it manufactures. For any other chemical or mixture it may process, the company is treated just like any other person who processes chemicals manufactured by someone else. See unit C. regarding processors subject to this rule. B. Manufacturers Not Subject to the Rule The Agency has decided to exclude certain manufacturers end sites of manufacture from the requirements of this rule. Exempt are firms or sites whose sole business activities can be classified within the "extractive" industry. More specifically, exempt firms or sites are those whose sole business activities are to mine mineral ores, to extract petroleum or natural gas. to quarry non-melallic minerals (including extraction of salts from seawater or brines), to mine or otherwise extract coal, or to separate gases from the atmosphere. Firms or sites primarily engaged in activities of the type listed within SIC Division Mining, or SIC 2613--Industrial Gases, may be exempt from the requirements of this rule. By sole business activity the Agency means that no further processing or refinement of the extracted material occurs at the site. Such further processing or refinement is considered manufacturing subject to this xuie.J-'or example, the mining of oil shale ore is not subject to this rule but the retorting of the ore to produce shale oil is manufacturing subject to this rule. This exemption is an administrative decision that is in part an outgrowth of the Agency's experience with the TSCA section 6(a) Preliminary Assessment Information rule (47 FR 26992). Persons who manufacture chemicals listed m that rule are required to report cer:ain production-related information to the Agency. However, the rule exempts those who produce the substances only as part of mined substances of undefined or variable composition. Coverage by that rule begins with persons who process or refine the complex mixtures to produce a listed substance. Technically, the act of extracting ore from the earth is "production" of a chemical substance. However, LPA considers that it would be both an inappropriate and an excessive regulatory burden to make the firms or sites solely engaged in extractive activities subject to the recordkeeping and reporting provisions of this rule. Several factors contributed to this decision. First, the inclusion of firms in the extractive industry would affect many thousands of businesses, most of which are small, independent operations. Bureau of the Census statistics indicate that there are 22,358 firms in SIC Division B--Mining, a figure that is more than double the total number of firms that the Agency estimates wiil be subject to the rule as chemical manufacturers and processors. Census data show that of the total number of firms, approximately 21.000 are single unit operations that in total account for only 14 percent of sales within th;s industry group. Second, the vast majority of substances produced by the extractive industry are substances that have been produced for many years. Consequently, a substantial volume of information has developed in the scientific and medical literature regarding the adverse effects of mined materials on health and the environment. This statement about such known effects is not meant to downplay the seriousness of occupational diseases such as black lung or asbestosis. ll only means that, because these are known effects, they would not appear in a company's section 6(c) file were such firm subject to the rule. Therefore, the Agency considers it unreasonable to subject firms in the extractive industry to an additional recordkeeping requirement that may never see an entry. MOD 000016378 Federal Register f Vol. 48. No. 163 / Monday. August 22. 1983 / Rules and Regulations 38183 Third, the Agency considers that for the purposes of this rule other federal regulatory activities adequately oversee Occurrences of occupational illness within the extractive industry. Mine Operators are currently required to keep records and to report instances of occupational injury and illness to the Mine Safety and Health Administration (30 CFR Subchapter M. Part SO). Producers of oil and natural gas are subject to similar regulations administered by the Occupational Safety and Health Administration. Fourth, this exemption will not mean a lost of recordable allegations regarding extracted materials or the inability to obtain specific information as required. The Agency realizes that not all adverse effects of currently extracted materials may be known. It is also possible that previously undeveloped natural resources (e g. oil shale) could present risks to health and the environment. However, any recordable significant adverse reactions to extracted materials are also likely to occur (perhaps even more likely to occur) during further processing or refinement steps. As stated above, such further processing or refinement is subject to this rule. Also, if necessary, the Agency can require reporting on specific substances by persons in the extractive industry under authority of TSCA section 8(a). Finally, even though firms in the extractive industry may be exempt from this rule, they are still subject to the substantial risk notification requirements of TSCA section 6(e). This provision requires reporting of information that reasonably supports the conclusion of substantial risk of injury to health or the environment. The Agency has received submissions from mining concerns under section 8(e) and we expect this type of reporting activity to continue. C. Processors Subject to the Rule There are two types of processors eubject to .this rule. If a company is processing a chemical it manufactures, that company must collect allegations on any of its processing or distribution in commerce activities involving that chemical. See A of this unit. If a company is processing a chemical it docs not manufacture, that company must collect allegations involving that chemical only for those activities described in Standard Industrial Classification (SIC) Major Croup 26-- Chemicals and Allied Products, or SIC code 2911--Petroleum Refining It also must collect allegations relating to any further processing or distribution in commerce of any products resulting from such processing activities. Thus, a firm that processes chemical substances but that is not a manufacturer can be subject to this rule. However, the Agency has decided to limit the applicability of the rule where this type of processor is concerned. The Agency has concluded that the best approach is to concentrate the recordkeeping responsibility with those firms that have at least one plant site engaged in activities within the mainstream of the chemical industry. The Agency believes that such processors are likely to be among the Firms that have the greatest stake in recording and if appropriate, taking positive or corrective action with respect to allegations received. The Agency feels that by focusing the recordkeeping responsibility with these processors the rule enhances the concept of product stewardship, a growing proctice within the chemical industry that continually assesses the potential health and safety risks of substances at each stage from development through disposal. Again, the Agency considers it necessary to outline for processors subject to this rule their specific responsibility regarding collection of allegations. Such processors must collect: 1. Any allegation identifying any chemical substance, mixture, or article resulting only from processing activities as described in SIC 28 or SIC 2911. or identifying the operations involved in making such products (see unit III. B. of this preamble and \ 717.10 of the rule). 2. Any allegation identifying any of its own further processing or distribution in commerce activities of the products described in 1. above. 3. Any allegation identifying emissions, effluents, or other discharges from activities described above. Note that if a company is not a manufacturer of a chemical substance, but is only a processor, it is only required to collect allegations relating to products resulting from activities described in SIC codes 26 and 2911. A processor subject to this rule is not required to collect allegations involving substances it does not produce. For example, an allegation specifically involving a mixture component bought from some other company does not have to be collected (although allegations involving the processing of the component or the new product created would be collected by the processor). As with manufacturers, the Agency believes that processors have a strong incentive to forward allegations on a mixture component to the supplier of that component. The Agency strongiy encourages this passback activity. At this juncture, the Agency wishes to make clear two very important paints relating to processing operations and the use of SIC codes in this preamble and rule. First, when a company is deciding whether it is "engaged in activities described" in SIC codes, it must refer to the descriptions that appear after each four digit code. The company should not rely solely on the listing of substances that appears after the descriptions. These descriptions are generic in nature and refer to the production of categories of chemicals, mixtures, or other chemical products, it is quite possible that a company may be processing chemicals to produce a substance or product that does not specifically appear in the list of substances that follows the generic description. However, the company's activities would be subject to categories contained in the generic description, The second point is that terms used in the SIC codes are not necessarily the same as those used in this rule. For the purpose of this rule, the TSCA definitions of "manufacture" and "process" apply. Activities described in SIC codes 28 and 2911 are categorized by the SIC system as "manufacturing." This term is broader than the TSCA definition of manufacture and encompasses activities referred to as "processing" under this rule. For example, a company referred to under SIC code 28S1 as engaged in the activity of manufacturing paints is. for the purposes of this rule, a processor of the chemicals used to make the paints. Thus, it is subject to this rule as a chemical "processor" engaged in an activity described in SIC code 28 (The company is also a mixture manufacturer under TSCA definitions.) Accordingly, section 717.5(c) of the rule provides that where there is a conflict between the SIC code use of a term and the definition of that term in this rule, the rule definition applies. D. Processors Not Subject to the Rule A processor, who is not also a manufacturer, is not subject to this rule if none of the sites it owns or controls is engaged in activities described in SIC 28 or SIC 2911. The TSCA definition of processor is such that tens of thousands of firms could be made subject to recordkeeping responsibilities of section 6(c). For example, a shoemaker that applies a dye to shoes is. technically, a processor because of the incorporation of that chemical dye into an article for distribution in commerce. Likewise, a MCD 000016879 38184 Federal Register / Vol. 48, Na. 163 / Monday. Augusl 22. 1903 / Rules and Rpgulafions hardware store that adds a pigment to premixed paint is a processor. Such "processing" permeates the economy. To include firms engaged in activities of this nature under (hn rule would create a vast recordkeeping requirement. The economic analysis for the proposed rule estimated that some $43,000 establishments outside of SIC 28 or 2911 could be made subject to this rule as processors. Requiring these establishments to collect allegations would be an administrative nightmare. Further, the public health concerns of section 8(c) would not be harmed by excluding these establishments because they would have a strong incentive to refer complaints about chemicals they "process" to the suppliers of those chemicals--firms that are likely to be subject to this rule. In this final rulemaking the Agency did consider making such "other" processors subject but with an alternative compliance method. The purpose would be to promote the passback of allegations to those required to maintain records. Is brief, such firms could be required to record allegations or they could discharge this responsibility by forwarding such allegations to their supplier. This would be similar to the alternative compliance mechanism for distributors as outlined in the proposed rule. After evaluating this alternative compliance method the Agency has determined that such a requirement could actually inhibit allegation passback as much as it could enhance it If this regulatory requirement were imposed, such firms may take the path of least resistance to satisfy the requirement. Basically, it would be less of an administrative burden to file automatically any complaint or allegation received than it would be to evaluate the allegation, determine to whom such allegation should be sent and do the paperwork, including keeping a copy of all this correspondence. Added to thes^ considerations is the fact that subjecting these numerous processors to an alternative compliance method is still adding substantially to the overall burden of the rule. As a result, the Agency is not implementing an alternative compliance method for processors solely engaged in processing activities outside of SIC 28 and 2911. The Agency is not ruling out the future implementation of such o provision. However. EPA prefers at this time to support the concept of product Stewardship as previously discussed. We strongly encourage those mnnufuciurcrs and processors that are subject to the rule to educate their customers regurding TSCA section 8(c). and to stress the importance of passing back any potentially recordable allegations. E. Retailer and Sole Distributor Exemptions As defined by the rule, a retailer is a person who distributes in commerce a chemical substance, mixture, or article to ultimate purchasers who are not commercial entities. The proposed rule exempted retailers, unless such firms were already subject to the rule as a manufacturer or a processor. This exemption of retailers is retained in the final rule and is expanded to exempt other companies whose sole function is to distribute chemical substances. By sole function the Agency means that such company is not also a manufacturer or processor subject to this rule. For example, a "distributor" who repackages chemical substances is actually "processing for commercial purposes" end. therefore, is a processor. Sole distributors may include wholesale distributors of chemicals as classified in SIC 5161--Chemicals and Allied Products, SIC 5171--Petroleum Bulk Stations and Terminals, and SIC 5172-- Petroleum and Petroleum Products Wholesalers. As stated in the proposed rule, retailers are exempt because the potential for retail employees being exposed is limited, since they generally handle packaged products. Also, highly developed communications exist between retailers and their suppliers regarding consumer complaints. Another factor is that the large number of such retail firms would create a highly dispersed records situation that would not serve one of the purposes of this rule. i.e.. the ability to detect pattens of adverse affects. EPA requested . comment on whether retailers should be made subject to the rule but no comments convinced the Agency that such inclusion would make the rule substantially more effective. There are a number of reasons why the exemption should be expanded to include all sole distributors. First, the incidence of recordable allegations made to such firms is likely to be very low. As commenters have pointed out. the same rationale for exempting retailers could be applied to wholesale distributors. That is. the potential for worker exposure is minimized because the workers normally handle packaged or containerized substances. Second, wholesale distributors receive lew customer or consumer-type allegations, and any that are received ere forwarded to the manufacturer or other supplier. This point was made clear by the economic analysis for the proposed rule to implement section 16(b) of the Consumer Product Safety Act (see item 21 of the public record). Third, exempting these sole distributors from the rule does not necessarily create a gap in Federal government information gathering regarding adverse reactions to human health or the environment. The Agency believes that warehousing accidents and accidental spills related to transporting chemicals are likely to be the major causes of adverse reactions to distributor employees, or the environment. Thus, these incidents would be verified events and are not likely to be the aubject of a ilega lion. They would be recordable in many cases under the Occupational Safety and Health Act. or reportable to EPA or to the Department of Transportation/ U.S- Coast Guard under one of several authorities. However, if an employee of a distributor alleges that normal handling of a certain substance caused a repeated adverse reaction, then the affected person can submit an allegation to the substance's manufacturer. The distributor can also make such on allegation on behalf of its employees. The Agency proposed an alternative compliance method for distributors similar to the alternative compliance method considered for "other" processors (see D. above) Under this proposal, distributors would be required to keep allegations or they could discharge that responsibility by forwarding such allegations to the appropriate manufacturer or processor. It appears, as explained earlier, that such an alternative compliance method could actually be counterproductive. Also, it is the standard business practice of such distributors to forward complaints to their suppliers. Therefore, the Agency' has concluded that imposition of an alternative compliance method is unnecessary. F. Standard Industrial Class/ficaiion (SIC) System The Agency is using the Standard Industrial Classification (SIC) system to help firms determine whether or not they may be subject to this rule. The Bureau of the Census within the U.S. Department of Commerce currently has responsibility for the SIC system. Among other important functions, these SIC codes are standard reference for categorizing basic business activities throughout the U.S. economy Detailed descriptions of subsiancrs or business activities as they relate to certain SIC codes are given in the Standard Industrial Classification MCD C101SS80 Federal Register / Vol. 48. No. 163 / Monday. August 22. 1983 / Rules and Regulations 38185 Manual. 1972 available from the U.S. Government Printing Office. Washington. D C.. 20402--slock number 4101-0066. and the 1977 Supplementstock number 003-005-0176-0. Information regarding the SIC system may also be obtained through the regional offices of the Bureau of the Census, U.S. Department of Commerce. V. Recordkeeping Requirements There are two basic differences between the proposed and final rule regarding recordkeeping requirements. First, records are to be located at the company's headquarters or at any other appropriate location central to their chemical operations rather than being kept at each plant site. The Agency agreed with comments stating that centralized recordkeeping would be more efficient for a company and would have a greater potential to exhibit patterns of adverse reactions. In addition, such centralized recordkeeping will allow more efficient inspections of records by the Agency. Second, the Agency is not including a speciftc form to be used for either recordkeeping or reporting. The Agency agreed with comments that the firms subject to the rule should be allowed to keep information in a format of their own choosing so long as the required information is present. The following required information must be readily accessible under this rule as the allegation record: 1. The orginal allegation as received. 2. An abstract of the allegation and other pertinent information as follows: a. The name and address of the plant site that received the allegation. b. The date the allegation was received. c. The implicated substance, mixture, article, company process or operation, or site effluent, emission or other discharge. d- A description of the alleger (e g., company employee. Individual consumer, plant neighbors, etc.). If the allegation involves a health effect, the sex and year of birth of the affected individual should be recorded, if ascertainable. e. A description of the health effect(s). The description must relate how the health effects became known end the route of exposure, if explained in the allegation. f. A description of the environmental effects], identifying the affected plant nd/or animal species, or contaminated portion of the environment. 3. The results of any self-initiated investigation of the allegation. The regulation does not require a company to perform any investigation in connection with allegations received. However, if a company chooses to investigate the curcumstances of an allegation, then the results of that investigation must be included in the record. 4. Copies of any further required reports or records relating to the allegation. If a company is required to keep any other record or make any other report relating to the allegation (e.g.. Occupational Safety and Health Administration Form 101), then a copy of that record or report must also be placed in the file. This does not include internal records or reports developed or maintained by a company except as provided above. Allegation records are to be readily accessible according to the alleged cause of the significant adverse reaction. Therefore allegations must be filed according to chemical identity, or one of the following if the chemical is not named: mixture identity, article identity, company process or operation, or site effluent, emission or other discharge. The statute requires that records of adverse reactions to the health of employees shall be retained for a period of 30 years from the date such reactions were first reported to or known by the person maintaining such records. The Agency interprets this provision to require firms subject to the rule to retain all such employee health-related allegations, whether or not the allegation was submitted by that firm's own employee. For example, an employee of firm A can submit an allegation to firm B regarding B s chemical that he handles in his own workplace. This is an allegation relating to the health of an employee and. in the Agency's view, such allegation must be retained for 30 years by the producer of the substance in question. Other allegations such as from consumers or those relating to environmental reactions must be retained for a period of five years. Firms arc not required to incorporate existing records (i.e. allegations or similar complaints on file before the effective dale of this rule) into their section 6(c) records. Allegations subject to this rule are those received on or after the effective date of this rule. However, the Agency encourages firms to correlate any allegations subject to this rule with their existing records so that any patterns of adverse reactions can be identified at the earliest possible stage. VI. Inspection aod Reporting Requirements Section 6(c) of TSCA states that upon request of any duly designated representative of the Administrator, each person who is required to keep records shall permit the inspection of such records and shall submit copies of such records. A. Inspections The inspection of section 8(c] records will serve three purposes. First, this records inspection will be a means of monitoring basic compliance with the rule. Agency compliance monitoring staff will conduct inspections of TSCA section 6(c) records on a routine basis. Records for selected chemicals or industry segments also will be inspected on a case-by-case basis. Along with required reporting discussed below, inspections of section 8(c] records will be used to carry out one of the baste purposes of the rule, the identification of patterns of adverse effects. Information obtained during inspections will be correlated with information the Agency obtains through other inspections, reports required under sections 3(d) and 6(e) of TSCA, and other information in the Agency's possession. The third purpose of inspections is to aid in the evaluation of the rule iUelf. The Agency intends to do an ongoing evaluation of the rule (see Unit IX) since section 6(c) requires long-term maintenance of unique information. Comments on the proposed rule expressed concern that the rule did not provide adequate procedural safeguards. Inspections under this rule will be done in full compliance with the requirements of section ll of TSCA. B. Reporting The preamble of the proposed rule discussed the inclusion of an automatic reporting system. Under this proposal, a company would be required to forward records to the Agency if it recorded three or more allegations in one year regarding the same substance. The Agency received a considerable amount of comment on the issue of automatic reporting. Environmental and labor groups generally supported the concept of automatic reporting as a means to detect patterns of adverse effects. Some wanted the reporting trigger made more stringent, e.g., if three similar allegations were accumulated over a period of three to five years, rather than one year. Comments received from chemical companies and industry groups opposed automatic reporting. They pointed toward the increased burden such a requirement would place upon -rccordkeepeis. Coinmenlers claimed that, due lo the unsubstantiated nature of allegations, such a system would 000016881 MCD 381BG Federal Register / Vol. 4fl, No. 163 / Monday, August 22, 1983 / Rules and Regulations flood the Agency with information of questionable quality and usefulness. If any type of automatic reporting system were to be promulgated, companies much preferred submission of an annual statistical summary of allegations--an alternative discussed in (he preamble of the proposat. After having considered the many comments received, the Agency has decided not to institute an automatic reporting provision at this time. The Agency has concluded that tt is not feasible to design an appropriate automatic reporting system until we can determine what kinds of rcceord are being kept under the rule and in what volume. This does not mean, however, that information placed in a section 8(c) file will languish until such file may be inspected. First, the Agency expects that the accumulation of several similar allegations may contribute to the development of a notification of substantia] risk as required by TSCA section Sfc). The Agency has received section 8(e) notices where allegations from workers or customers served as the first indication of a possible problem. Along with subsequently developed test data, these allegations formed part of the information that gave the company a reasonable basis to conclude that their product could pose a substantial risk of injury to health or the environment. The agency believes that the formalization of allegation recordkeeping by this rule will heighten a company's awareness of potential problems with their products and that these allegation records will not exist in a vacuum. Second, the Agency will use reporting authority under section 8(c) to call in records that may relate to substances or classes of substances already under review. Such substances may be the specific recommendations of the Interagency Testing Committee or those that enter the Agency's evaluation process via other avenues such as section 8(c) submissions. For example, if a company submits a section 8(e) notice on a substance that is also produced by several other firms, it would be valuable to know if those other firms have allegations on file regarding that same substance. The rule provides that when reporting of records is required, firms will be notified by letter or by a notice in the Federal Register. VII. Confidentiality When firms nrc required to submit records of allegations, they may assert a claim of business confidentiality for all or part of the information in those records. Any information covered by a claim will be disclosed by EPA only to the extent, and by means of the procedures, set forth in 40 CFR Part 2. Any claims of confidentiality must be made at the time of submission, as provided in 40 CFR 2.203(a)(2) and in the manner specified in 5 717.17 of this regulation. This rule requires submission of two copies of allegation records--one copy indicating whet information is claimed as confidential and a second copy in which this confidential information has been deleted. EPA will presumptively consider failure to submit the second copy as a waiver of the confidentiality claim. However. EPA will notify respondents who claim parts of records confidential that they did not submit the required second copy. This provision affords such persons the opportunity to correct errors within 30 days. Many commenlers objected to providing substantiation of confidentiality claims at the time that records of allegations are submitted to the Agency. They asserted that such substantiation is burdensome and only necessary if the aliegetion becomes subject to a Freedom of Information Act (FOIA) request, After considering these comments the Agency has concluded that a requirement for "up-front" substantiation is not necessary. However, the claim must still be explained briefly at the time of submission indicating the reason for omitting certain facts in the allegation, e g., that a worker's exposure to the substance in question during a certain processing step "reveals confidential process information." The Agency believes that this brief statement is necessary- because EPA needs some understanding of the claims to have a basis for initial denial or granting of FOIA requests and to protect the information. This decision is consistent with confidentiality requirements of the TSCA section 8(d) rule (47 FR 38760. 40 CFR Part 71&--Subpart A) for reporting unpublished health and safety studies and the TSCA section 8(e) policy statement (43 FR 11110) regarding notices of substantial risk. VIII. Economic Impact Coromcnters were critical of the estimates end methodology of the economic analysts published in conjunction with the proposed rule. Many said that the analysis grossly underestimated the cost of review, handle, and report allegations given the breadth of the proposed rule. Also, no estimate made of "start-up" costs, i.e.. cost to set up a file system and train responsible personnel in the disposition of section 8(c) notices. Tile econumic analysis for the final rule takes into consideration several basic charges from the proposed rule, e.g.. the reduced number of firms subject to the rule and no automatic reporting provision, it includes a first year industry-wide administrative (start-up) cost estimate of approximately $15 million. This cost includes establishment of a file system, training appropriate company officials, and educating workers regarding the rule's provisions. The estimates for the amount of time and cost for reviewing and processing individual allegations have also been reevaluated. The ongoing annual cost to industry for processing and filing allegations under the rule is estimated to be between $1.4 million and $2.1 million A separate document titled "Economic Impact Analysis of the TSCA Section 8(c) Significant Adverse Reaction Recordkeeping Rule" explains in more detail the estimated costs and administrative burdens of this rule. This document is available to the public in the public record of this rulemaking. IX. Records Evaluation After enough time has elapsed for the accumulation of some records (approximately 12-18 months from the rule's effective date) the Agency plans to inspect a representative sample of records maintained by both manufacturers and processors in different size categories. A survey of companies' experiences with the rule may also be part of this evaluation- The objective of this evaluation will be to determine the quality and quantity of records being maintained and whether the rule as currently written meets its stated objectives. For example, one area of concern will be whether or not to retain the "known effects" exemption. The Agency will be interested in how often and in what kinds of cases the known effects exemption was applied. The Agency will look to see whether this exemption will have the effect commenters project that it will have. i.e.. preventing the company's section 6(c) file from being filled with commonly occurring or well known adverse effects of substances. However, an adverse reaction must first pass the test of being "significant" before it it filed. Therefore, the Agency may wish to revisit the question of whether it would, in the long run. also be valuable to have a record of such significant adverse reaction allegations even if they are "known effects". Also, the Agency* may reconsider the need for such an exemption if. in the companies' experience, the exemption wot seldom applicable or proved to be MCI) 00001688^ Federal Rpqisler / Vol 40. No. 163 f Monday. August 22, 1933 / Rules and Regulations 351C7 more resource intensive to apply than imply filing any significant adverse reaction allegation received. If this evaluation indicates a need to expand or reduce the requirements of this rule EPA will initiate appropriate procedures to modify the rule. X. Public Record EPA has established a public record for this rulemaking Idocket number OPTS 83001). The record, along with a complete index, is available for inspection from 8:00 a.m. to 4:00 p mMonday through Friday, except legal holidays, in the OPTS Reading Room. Rm. E-107, 401 M St.. SW.. Washington, D.C. 20460, This record includes basic information that the Agency considered in developing this rule. The record includes the following documents: 1. This final rule. 2. The document "Economic Impact Analysis ofTSCA Section 8(c) Significant Adverse Reactions Recordkeeping Rule." 3. Final rule concept paper. 4. Minutes of the Administrator's Toxic Substances Advisory Committee (ATSAC) meetings of July 8.1982. and September 9.1982, at which issues related to the above concept paper were discussed. 5. ATSAC comments and recommendation on the approach to the final TSCA 8(c) rule. 6. Letters to ATSAC from the Chemical Manufacturers Association (September 8,1982) and the National Paints and Coatings Association (September 9.1982). 7. The proposed rule. 8. All comments on the proposed rule. 9. Written summaries of telephone comments on the proposed rule. 10. Transcripts of public meetings on the proposed rule held in Washington. D.C.. Newark. N.).. and Houston. Texas. 11. The document titled "Responses to Individual Comments on the TSCA Section 6(c) Rule" which supplements this preamble and provides responses (0 substantive individual comments on the proposed rule. 12. The Advance Notice of Proposed Rulemaking publish in the Federal Register on March 11.1977 (42 FR 13579). 13. All comments on that Advance Notice. 14. A draft of the proposed rule, dated October 12.1976. sent to selected industry, labor, and public interest groups. 15. All letters of transmits! sent with that draft, and comments received on it. 16. Minutes of a November 13. 1978. meeting with industry and special interest groups to discuss the TSCA section 8tc) draft rule. 17. "Notification of Substantial Risk Under Section 8(e)." March 16.1978 (43 FR 11110). 18. Occupational Safety and Health Administration regulations on "Recording and Reporting Occupational Injuries and Illnesses" (29 CFR Part 1904). and forms revised in 1978. 19. Consumer Product Safety Commission proposed reporting requirements regarding recordkeeping of consumer product safety complaints. November 3.1977 (42 FR 57642). 20. Consumer Product Safety Commission interpretation of policy for "Reports of Substantia) Product Hazards." August 7,1978 (43 FR 34988). 21. "Final Report on the Economic Impact of Proposed Recordkeeping Rules to Deputy Associate Executive Directorate for Economic Analysis. U.S. Consumer Product Safety Commission." Battelle, Columbus. Ohio, March 19. 1979. 22- Minutes of an August 15. 1979. meeting with industry and special interest groups to discuss the TSCA section 8(c) draft rule. 23. Any comments received from the Office of Management and Budget during its review of this rule regarding compliance with the Paperwork Reduction Act or Executive Order 12291 and any EPA response to those comments. 24. Miscellaneous Agency comments, corrections, and correspondence reiaung to the rule. EPA requests that persons who believe there are any errors or omissions in the Public Record notify the Agency within 30 days of the date of publication. Address all correspondence to: TSCA Public Information Office 793). Office of Pesticides and Toxic Substances. Environmental Protection Agency. Rm. E-108, 401 M St.. SW.. Washington. D.C. 20460. XI. Regulatory Assessment Requirements A. Executive Order 12291 Under Executive Order 12201. EPA must judge whether a regulation is "major" and therefore subject to the requirements of a Regulatory impact Analysis. ErA has determined that this regulation is not major because it docs not have an effect of $100 million or more on the economy. It is expected to have a first year maximum cost ofSl7.3 million end maximum yearly cost thoreaftcrof $2.01 million. It dues not have a significant effect on competition, employment, investment, productivity, innovation, or ability of U.S -biised enterprises to compete with foreignbased interprises in domestic or expurt markets. This regulation was submitted to the Office of Management and Budget (OMB) for review es required by Executive Order 12291. Any comments from OMB to EPA and any EPA response to those comments will be available for public inspection in the record for this rulemaking. B. Regulatory Flexibility Act Since this rule was proposed before the effective date of the Regulatory Flexibility Act. 5 U.SC. 601 et seq., the Act's requirements do not apply. Even so. the economic analysis for the rule indicates that, under Agency cnieria. the rule will not have a significant impact on a substantial number of small businesses. C. Paperwork Reduction Act Under the Paperwork Reduction Act of 1980. 44 use 3501 et. seq.. the information provisions of this rule will be submitted for approval to the Office of Management and Budget (OMB). They are not effective until OMB approves them. A notice of that approval will be published in the Federal Register. List of Subjects io 40 CFR Part 717 Environmental protection. Hazardous .materials. Chemicals Recordkeeping and reporting requirements. Significant adverse reactions. Dated. August 11.1963William D. Ruckelsbaus, A dministrator. Therefore. 40 CFR Chapter I is amended by adding a new Part 717 to read as follows: PART 717--RECORDS AND REPORTS OF ALLEGATIONS THAT CHEMICAL SUBSTANCES CAUSE SIGNIFICANT ADVERSE REACTIONS TO HEALTH OR THE ENVIRONMENT SUfiPART A--GENERAL PROVISIONS Sec. 717.1 Scope and compliance. 717.3 Definitions. 717.5 Persons subject to this Pan. 717.7 Persons not subject to this Furt. 717.10 Allegations subject to this Part. 717.12 Significant adverse reactions that must be recorded. 717.15 Recordkeeping requirements. 717.17 Inspection and reporting requirements. 71719 Confidentiality. Authority: Sec. fl|c). Pub L 94^09 0 S:at 20Z9 (15 U.S.C. 2U0r(i.)). MCD 000016883 38100 Federal Register / Vol. 48, No. 1B3 / Monday. August 22. 1983 / Rules and Regulations Subpart A--General Provisions |717.1 Scope and compliance. Section 6 (c) of the Toxic Substances Control Act (TSCA) requires manufacturers, processors, and distributors of chemical substances and mixtures: (a) To keep "records of significant adverse reactions to health or the environment, as determined by the Administrator by rule, alleged to have been caused by the substance or mixture." (b) To "permit inspection and submit copies of such records", upon request of any designated representative of the Administrator. This rule implements section 8(c) of TSCA. Jt describes the records to be kept and prescribes the conditions under which certain firms must submit or make the records available to a duly designated representative of the Administrator. 1717.3 Definitions. Hie definitions set forth in section 3 of TSCA and the following definitions apply to this Part: (a) "Allegation" means a statement, made without formal proof or regard for evidence, that a chemical substance or mixture has caused a significant adverse reaction to health or the environment. (b) "Firm" or "company" means any person, that is subject to this Part, as defined in 717.5. (c) (1) "Known human effects" means a commonly recognized human health effect of a particular substance or mixture as described either in: (1) Scientific articles or publications abstracted in standard reference sources. (ii) The firm's product labeling or material safety data sheets (N1SDS). (2) However, an effect is not a "known human effect" if it: (i) Was a significantly more servere loxic effect than previously described. (ii) Was a manifestation of a toxic effect after a significantly shorter exposure period or lower exposure level than described. (iii) Was a manifestation of a toxic effect by an exposure route different from that described. (d) "Manufacture" or "process" means to manufacture or process for commercial purposes. (e) (1) "Manufacture for commercial purposes" means to import, produce, or manufacture with the purpose of obtaining an immediate or eventual commercial advantage for the manufacturer, and includes, among other things, such "manufacture" of any amount of a chemical substance or mixture: (1) For distribution in commerce, including for test marketing. (ii) For use by the manufacturer, including use for product research and development, or as an intermediate. (2) "Manufacture for commercial purposes" also applies to substances that are produced coincidentally during the manufacture, processing, use. or disposal of another substance or mixture, including both byproducts that are separated from thBt other substances or mixture and impurities that remain in that substance or mixture. Such byproducts and impurities may. or may not. in themselves have commercial value. They are nonetheless produced for the purpose of obtaining a commercial advantage since they are part of the manufacture of a chemical product for a commercial purpose. If) "Person" includes any individual, firm, company, corporation, joint venture, partnership, sole proprietorship, association, or any other business entity, any State or political subdivision thereof, and any department, agency, or instrumentally of the Federal Government. (g) "Process for commercial purposes" means the preparation of a chemical substance or mixture, after its manufacture, for distribution in commerce with the purpose of obtaining an immediate or eventual commercial advantage for the processor. Processing of any amount of a chemical substance or mixture is included. If e chemical substance or mixture containing impurities is processed for commercial purposes, then those impurities are also processed for commercial purposes. (h) "Retailer" means a person who distributes in commerce a chemical substance, mixture, or article to ultimate purchasers who are not commercial entities. (i) "Significant adverse reactions" are reactions that may indicate a substantial impairment of normal activities, or long-lasting or irreversible damage to health or the environment. 0) "Site" means a contiguous property unit. Property divided only by a public right-of-way is considered one site. There may be multiple manufacturing, processing, or distribution activities occurring within a single site. (k) "Substance" means a chemical substance or mixture unless otherwise indicated. (717.5 Parsons sub|ecl to this Part (a) Manufacturers. (1) All manufacturers of chemical substances arc subject lo this Part except as provided in ( 717.7(a). If manufacture of a chcmciul substance occurs at any site owned or controlled by a firm then that firm is subject to this Part. (2) A manufacturer must collect: (1) Any allegation identifying a chemical substance it manufactures and any allegation identifying the operations in the manufacture of any chemical substance it manufactures. (ii) Any allegation identifying any of its own processing or distribution in commerce activities with respect to any chemical substance it manufactures. (iii) Any allegation identifying emissions, effluents, or other discharges from activities described in this paragraph. (3) For the purpose of this Part, owned or controlled means ownership of 50 percent or more of a firm's voting stock or other equity rights, or the power to control the management and policies of that firm. (b) Processors. (1) A person who processes chemical substances, who is not also a manufacturer of those substances, is subject to this Part if such person is engaged in activities described in Standard Industrial Classification (SIC) Major Croup 28--Chemicals and Allied Products, and SIC code 23U-- Petroleum Refining. (2) As a processor subject to this Part such person must collect: (i) Any allegation identifying any chemical substance, mixture, or article resulting only from processing activities as described in SIC 28 or SIC 2911. and any allegation identifying the operational steps involved in producing such products. (ii) Any allegation identifying any of its own further processing or distribution in commerce activities of the products described in paragraph (b)(2)(i) of this section. (iii) Any allegation identifying emissions, effluents, or other discharges from activities described in this paragraph. (c) SIC code. SIC codes applicable to this Part are published in Standard Industrial Classification Manual--1972 end the 1977 Supplement. This manual and supplement may be obtained from the U.S. Government Printing Office. Washington, D-C. 20402--stock number 4101-0006 and stock number 003-0050170-0 respectively. Where there is a conflict between the SIC code use of a term and the definition of that term in this Pari, the definition in this Part applies. 1717.7 Parsons not subject lo this Part. (a) Manufacturers. Persons or site activities are exempt from this Part if the means by which they manufacture a chemical substance solely involves 00001688\A y\CD Federal Register / Vol. 4B, No. 163 / Monday. Auyust 22. lpfll / Rules and Peculations 30189 miring or other solely exlrjclive functions, e.g.. those companies or sites within a company whose sole function is to mine mineral ores, extract petroleum or natural gas. quarry non-metullic minerals (including extraction of salts from seawater or brines), mine or otherwise extract coal, or separate gases from the atmosphere, This exemption may include, but is not necessarily limited to. firms engaged in activities as described in SIC Division B--Mining and SIC Code 2B13-- Industrial Cases. lb) Processors. A processor, who is not also a manufacturer, is not subject to this Part if none of the sites that processor owns or controls is engaged in activities as described in SIC 28 or SIC 2911. (c) Sole distributors. A person solely engaged in the distribution of chemical substances is exempt from this Part, unless such person is also a manufacturer or processor subject to this Part. For example, a "distributor" who repackages chemical substances or mixtures is considered to be a processor and. thus, is not a sole distributor. Sole distributors may include, but arc not limited to. those firms that distribute chemical substances as described m the wholesale trade SIC codes 5161Chemicals and Allied Products. 5171-- Petroleum Bulk Stations and Terminals, and 5172--Petroleum and Petroleum Products Wholesalers. Except Bulk Stations and Terminals. (d) Retoilers. A person who is a retailer is exempt from this Part unless such person is also a manufacturer or a processor subject to this Part. J 717.10 Allegations subject to this Part. (a) Allegations subject to this part are those allegations received on or after November 21.1983 by persons subject to this Part. (b) Allegations subject to this Part are those that: (1) Are submitted either in writing and are signed by the aileger, or are submitted orally. In the case of an oral allegation, the firm must transcribe the allegation into written form, or it must inform the aileger that such allegation may be subject to this Part and request that the aileger submit such allegation to the firm in writing and signed. (2) Implicate a substance that caused the stated significant adverse reaction by one of the following: (i) Naming the specific substance. (ii) Naming a mixture that contains a specific substance. (iii) Naming an article that contains a specific substance. (iv) Naming a companyprocess or operation in which substances are involved. (v) Identifying an effluent, emission, or other discharge from a site of manufacturing, processing or distribution of a substance. (c) Allegations subject to this Pari may be made to a firm by sny person, such as an employee of the firm, individual consumer, a neighbor of the firm's plant, another firm on behalf of its employees or an organization on behalf of its members. (d) EPA intends that firms should, to the maximum practical extent, provide allegcrs with information regarding the ultimate disposition of their allegations. For example, firms could provide a brief notice to (he aileger stating that a record was created under this Part based upon their allegation, or that a record was not created and briefly explain the reasons why not. S 717.12 Significant adverse reactions that must be recorded. (a) Except as provided in paragraph (bj of this section, significant adverse reactions to human health that must be recorded include but are not limited to: (1) Long-lasting or irreversible damage, such as cancer or birth defects. (2) Partial or complete impairment of bodily functions, such as reproductive disorders, neurological disorders or blood disorders. (3) An impairment of normal activities experienced by all or most of the persons exposed at one time. (4) An impairment of normal activities which is experienced each lime an individual is exposed. (b) Firms are not required to record significant adverse reactions that are known human effects as defined in 9 717.3(c). (c) Except as provided in paragraph (d) of this section.'significant adverse reactions to the environment that must be recorded, even if restricted to the environs of a plant or disposal site, include but are not limited to: (1) Gradual or sudden changes in the composition of animal life or plant life, including fungal or microbial organisms, in an area. (2) Abnormal number of deaths of organisms (e.g.. fish kills). (3) Reduction of the reproductive success or the vigor of a species. (4) Reduction in agricultural productivity, whether crops or livestock. (5) Alterations in the behavior or distribution of h species. (6) Long lusting or irreversible contamination of components of the physical environment, especially in the case of ground water, and surface w ater and soil resources that have limited selfcleansing capability. (d) Firms are not required lo record a significant adverse reaction to the environment if the alleged cause of that significant adverse reaction can be directly attributable to an accidental spill or other accidental discharge, emission exceeding permitted limits, or other incident of environmental contamination that has been reported to the Federal Government under any applicable authority. 9717.15 Recordkeeping requirements. (a) Establishment and location of records. A firm subject to this Part shall establish and maintain records of significant adverse reactions alleged to have been caused by chemical substances or mixtures manufactured or processed by the firm. Such records shall be kept at the firm s headquarters or at any other appropriate location central to the firm's chemical operations. (b) Content of records. The record shall consist of the following: (1)The original allegation as received. (2) An abstract of the allegation and other pertinent information as follows: / (i) The name and address of the plant site which received the allegation. (ii) The date the allegation was received at that site. (iii) The implicated substance, mixture, article, company process or operation, or site discharge. (iv) A description of the aileger (e.g.. "company employee." "individual consumer," "plant neighbor"). If the allegation involves a health effect, the sex and year of birth of the individual should be recorded, if ascertainable. (v) A description of the alleged health effect(s). The description must relate how the effect(s) became knowm and the route of exposure, if explained in the allegation. (vi) A description of the nature of the alleged environmental effcct(s), identifying the affected plant and/or animal species, or contaminated portion of the physical environment. (3) The results of any self-initiated investigation with resneel in an allegation. (EPA does not require persons subject to this Part to investigate allegations received, and no provision of this Part shall be construed to imply that EPA recommends, encourages or requires such investigation.) (4) Copies of any further required records or reports relating to the allegation. For example, if an employee allegation results in a requirement for the firm to record the cuse on Occupational Safety and Health Form MOD 000016885 38190 Federal Krister / Vol. 48. No. 163 / Monday. Adjust 22. 1983 / Rules and Regulations 101 or appropriate substitute (see 29 CFR Part 1504 for requirements under the Occupational Safety and 1 icallh Act of 1970). a copy of that OSHA record must be included in the allegation record. (c) File structure- Records must be retrievable by the alleged cause of the significant adverse reaction, which cause may be one of the following: (1) A specific chemical identity. (2} A mixture. (3) An article. (4) A company process or operation. (5) A site emission, effluent or other discharge. (d) Retention period Records of significant adverse reactions to the health of employees shall be retained for a period of 30 years from the date such reactions were first reported to or known by the person maintaining such records. This provision requires persons subject to this Part to retain for 30 years an employee health related allegation, arising from any employment related exposure, whether or not such allegation was submitted by or on the behalf of that recordkeepers own employee. Any other record of significant adverse reactions shall be maintained for a period of five years from the date the information contained in the record was first reported to or known by the person maintaining the record. (e) Transfer of records. (1) If a firm ceases to do business, the successor must receive and keep ail the records that must be kept under this Part. (2] If a firm ceases to do business and there is no successor to receive and keep the records for the prescribed period, these records must be transmitted to EPA- See $ 717.37(c) for the address to which such records must be sent. | 717.17 Inspection and reporting requirements. (a) Inspection. Firms must make records of allegations available for inspection by any duly designated representative of the Administrator. (b) Reporting. Each person who is required to keep records under this Part must submit copies of those records to the Agency as required by the EPA Administrator or appropriate designee. EPA will notify those responsible for reporting by letter or will announce any such requirements for submitting copies of records by a notice in the Federal Register. Such letter or notice will be signed by the Administrator or appropriate designee, and will specify which records or portion of records must be submitted- The reporting period will be specified by the letter or notice but in no case will such reporting period be less than 45 days from the date of the letter or the effective date of the notice. (c) How to report. When required to report, firms must submit copies of records (preferably by certified mail) to the Document Control Officer. Office of Pesticides and Toxic Substances (TS793). Environmental Protection Agency. Washington. DC 20460. 5 717.19 Confidentiality. (a) Any person submitting copies of records may assert a business confidentiality claim covering all or part of the submitted information. Any information covered by a claim will be disclosed by UPA only as provided in procedures set forth at Part 2 of this title. (b) If no claim accompanies a document at the time it is submitted to EPA. the document will be placed in un open file available to the public without further notice to the respondent. (c) To asset a claim of confidentiality for information contained in a submitted record, the respondent must submit two copies of the document. (1) One copy must be complete. In that copy, (he respondent must indicate what information, if any. is claimed as confidential by marking the specific information on each page with a label such as "confidential'', "proprietary", or ''trade secret" end briefly state the basis of the claim. (2) If some information is claimed as confidential, the respondent must submit a second copy of the record. The second copy must be complete, except that a!! information claimed as confidential in the first copy must be deleted. (3) The first copy will be for internal use by EPA. The second copy will be placed in an open file 10 be available to the public. (4) Failure to furnish a second copy when information is claimed as confidential in the first copy will be considered a presumptive waiver cf the claim of confidentiality. EPA will notify the respondent by certified mail that a finding of a presumptive waiver of the claim of confidentiality has been made. The respondent will be given 30 days from the date of receipt of notification to submit the required second copy. If the respondent fails to submit the second copy within the 30 days. EPA will place the first copy in the public file. (Ft Doc SSZ3: Filed ILUNQ CODS SM4-S6-M a 4m| MCI) 000016886 i S-544 161:1851 ENVIRONMENTAL PROTECTION AGENCY REGULATIONS FOR IDENTIFYING HAZARDOUS WASTE (40 CFR 261; 45 33119, May 19, 1980, Effective November 19, 1980; Amended by 45 FR 47833, July 16, 1980; 45 FR 72028, 72037, 72039, 72041, October 30, 1980; 45 FR 74890, November 12, 1980; 45 FR 76620, 76623, November 19, 1980; 45 FR 78529, 78531,78541, November 25, 1980; 45 FR 80287, December 4, 1980; 46 FR 4617, January 16, 1981) |Editor'1; note: New Parts 122. 123 and 124. hPA's consolidated permit program regulations, are published m Environment Reporter -- federal Regulations -- I. at 101:0701. 101 0~>I. and 101 0801. respectively. hPA January IP issued a final list m 13 hazardous wastes from specific sources i-SP l-R 4614) Persons who generate, transport, treat, store or dispose <>l wastes which were listed in 2PI.32 as interim final July IP, 14X0, and as /'mill on Junuan IP -- Kt)7l. kO?T and KOHJ through k()H7 -- must comply im mediate!) with all applicable standards in 40 OR 262--26h and 40 i PR 122 -- 124, those 261.23 Characteristic of reactivity. 261.24 Characteristic of EP toxicity. Subpart D--Lists of Hazardous Wastes 261.30 General. 281.31 Hazardous wastes from non-specific sources 261.32 Hazardous wastes from specific sources. 261.33 Discarded commercial chemical products and associated off-specification materials, containers and spill residues. Appendices (2) Subpart B sets forth the criteria used by EPA to identify characteristics of hazardous waste and to list particular hazardous wastes. (3) Subpart C identifies characteristics of hazardous waste. (4) Subpart D lists particular hazardous wastes. (b) This Part identifies only some of the materials which are hazardous wastes under Sections 3007 and 7003 of RCRA. A material which is not a persons without 1.1) numbers who handle wastes proposed for listing in 261.32 on July 16, I4XM. and adopted January 16 -- K Ml I through k 106 -- must tile a nomicaiion hy April I n. I ox I. *n qualify lor interim Mams under Section 3005(c) oi the Resource Conser vation and Recovery Act, and must tile a permit application and be in compliance with all applicable standards hv July 16, 1981. The agenev also delerred action on sine ' isle and suspended the clfectivc dates ol nine wastes which previously were listed in interim iiii.il lorm. These wastes arc discussed in the l.muary I 6 notice. J PART 261--IDENTIFICATION AND LISTING OF HAZARDOUS WASTE Subpart A--General Appendix !--Representative Sampling Methods Appendix II--EP Toxicity Test Procedures Appendix III--Chcmioul Analysis Test Methods Appendix IV--(Reserved for Radioactive Waste Test Methods] Appendix V--(Reserved for Infectious Waste Treatment Specifications] Appendix VI--(Reserved for Etiologic Agents) Appendix VII--Basis for Listing Appendix VIII--Hazardous Constituents Authority: Secs. 1006. 2002(a). 3001, and 3002 of the Solid Waste Disposal Act, as emended by the Resource Conservation and Recovery Act of 1976. as amended (42 U-S.C. hazardous waste identified in this pari is still a hazardous waste for purposes of those sections if: (1) In the case of Section 4007, EPA has reason to believe that the material may be a hazardous waste within the meaning of Section 1004(5) of RCRA. (2) In the case of Section 7003. the statutory elerrr'rM* are established. (c) A material is "diacarded" if it is abandoned (and not used, re-used, reclaimed or recycled) by being: (1) Disposed of; or 261.2 Definition of solid waste. (a) A solid waste is any garbage, Sec. 6905, 6912, 6921 and 8922). refuse, sludge or any other waste 261.1 Purpose and scope. 261.2 Definition of solid waBte. 261.3 Definition of hazardous waste. 261 4 Exclusions 261.5 Special requirements for hazardous waste produced by small quantity generators. 261.6 Special requirements for hazardous waste which is used, re-used, recycled or reclaimed. Subpart 0--Criteria for Identifying the Characteristics of Hazardous Waste and for Listing Hazardous Wastes 261.10 Criteria for identifying the characteristics of hazardous wastes. 261.11 Criteria for listing hazardous waste. Subpart C--Characteristics of Hazardous Waats 261.20 General. 261.21 Characteristic of ignitability. 261.22 Characteristic of corrosivity. Subpart A--Ganaral 261.1 Purpose and scope. (u| This Purr identifies those solid wastes which are subject to regulation js hazardous wastes under Parts 262 through 265 and Parts 122 through 124 of this Chapter and which are subject to the notification requirements of Section 3010 of RCRA. In this Part: (1) Subpart A defines the terms "solid waste" and "hazardous waste." identifies those wastes which are excluded from regulation under Parts 262 through 265 and 122 through 124 and establishes special management requirements for hazardous waste produced by small quantity generators and hazardous waste which is used, re used. recycled or reclaimed. material which is r.oi excluded under $261.4(a). (Interim final/ [h) An "other waste material" is any solid, liquid, semi-solid or contained gaseous material, resulting from industrial, commercial, mining or agricultural operations, or from community activities which: (1) Is discarded or is being accumulated, stored or physically, chemically or biologically treated prior to being discarded: or (2) Has served its original intended use and sometimes is discarded; or (3) Is a manufacunng or mining by product and sometimes is discarded. (c) A material is "discarded" if it is abandoned (and not used, re-used, reclaimed or recycled) by being: (1) Disposed of; or [Sw. 261.2(b)(3)) 3-27-81 Published bv th BUREAU Of NATIONAL AFFAIRS. INC WASHINGTON DC 20U4/ 115 MOD 000016887 161:1852 FEDERAL REGULATIONS (2) IJiirm-ii >ir inf.mcr.)l(`il. i-xr r|H lli<< mali'iml ir. lining ImiiiiuiI -1:1 n fui`l lur Ihr purpose of rounvi'img usabli: energy; or (3) Physically, chemically, or biologically treated (other than burned or incinerated) in lieu of or prior to being disposed of. (d( A material is "disponed of' if il is discharged, deposited, injected, dumped, spilled, leaked or placed into or on any land or water so that such material or any constituent thereof may enter the environment or be emitted into the air or discharged into ground or surface waters. (e) A "manufacturing or mining by product" is a material that is not one of the primary products of a particular manufacturing or mining operation, is a secondary and incidental product of the particular operation and would not be solely and separately manufactured or mined by the particular manufacturing or mining operation. The term does not include an intermediate manufacturing or mining product which results from one of the steps in a manufacturing or mining process and is typically processed through the next step of the process within a short time. 261.3 Definition of hazardous waste. (a) A solid waste, as defined in 261.2. is a hazardous waste if: (1) It is not excluded from regulation js a hazardous waste under 261.4(b); and (2) It meets any of the following criteria: [i] It is listed in Subpart D and has not been excluded from the lists in Subpart U under 260.20 and 260.22 of this Chapter. (ii| It is a mixture of solid waste and une or more hazardous wastes listed in Subpart D and has not been excluded from this paragraph under 260.20 and 21k).22 of this Chapter. (lii) ft exhibits any of (he characteristics of hazardous waste identified in Subpart C. (Ii) A solid waste which is not excluded from regulation under paragraph (a)(1) of this section becomes a hazardous waste when any of the following events occur: (1) In the case of a waste iisicd in Suhpart D. when the waste first meets the listing description set forth in Subparl D. (21 111 the i am1 of a mixture of sniid waste and one or mure listed hu/utdmis wastes, when a hazardous waste listed in Subpart D is first added to the solid waste. (3) In the case of any other wash; (including a waste mixture), when the waste exhibits any of the characteristics identified in Subpart C. (c) Unless and until it meet9 the criteria of paragraph fd): (1) A hazardous waste will remain a hazardous waste. (2) Any solid waste generated from the treatment, storage or disposal of a hazardous waste, including any sludge, spill residue, ash. emission control dust or leachate (but not including precipitation run-off), is a hazardous waste. Id) Any solid waste described in paragraph (c) of this section is not a hazardous waste if it meets the following criteria: 111 In thu cast* of any solid wuste. it r'oes not exhibit any of the characteristics of hazardous waste identified in Subpart C. (2) In the case of a waste which is a listed waste under Subpart D, contains a waste listed under Subpart D or is derived from a waste listed in Subpart D, it also has been excluded from paragraph [cj under 260.20 and 260.22 of this Chapter. 261.4 Exclusions. (a) Materials which are nut solid wustes. The following materials are not solid wastes for the purpose of this Part: D) li) Domestic sewage; and (ii) Any mixture of domestic sewage and other wastes ihat passes through u sewor system to a publicly-owned treuimont works for treatment. "Domestic sewage" means untrealed sanitary wus'os that pass through a sewer system. /lutvrtni iinuij (2) Industrial wastewater discharges that arc point source discharges subject io regulation under Section 402 of the Clean Water Act. us amended. [Comment: This exclusion applies only to the actual point source discharge. It does not exclude industrial wastewaters while they are being collected, stored or treated before discharge, nor does it exclude sludges that arc generated by industrial wastewater treatment.) (3) Irrigation return flows. 4| Soiircu. npi'iaai :im:lrar or by product material as defined by the Atomic Energy Act of 1954, as amended, 42 U.S.C. 2011 et seq. (5) Materials subjected to in-situ mining techniques which are not removed from the ground as part of the extraction process. (b) Solid wastes which are not hazardous wastps. The following solid wastes are not hazardous wastes: (1) Household waste, including household waste that has been collected, transported, stored, treated, disposed, recovered (e.g.. refuse-derived fuel) or reused. "Household waste" means any waste material (including garbage, trash and sanitary wastes in septic tanks) derived from households (including single and multiple residences, hotels and motels.) (2) Solid wastes generated by any of tne following and which are returned to ihe soils as fertilizers: (i) The growing and harvesting of agricultural crops. (ii) The raising of animals, including animal manures, (3) Mining overburden returned to the mine site. (4) Fly ash waste, bottom ash waste, slag waste, and flue gas emission control waste generated primarily from the combustion of coal or other fossil fuels. (5) Drilling fluids, produced waters, and other wastes associated with the exploration, development, or production of crude oil. natural gas or geothermal energy. [261.4(b)(6) added by 45 FR 72037, October 30, 19801 (6) (i) Wastes which fail the test for the characteristic of EP toxicity because chromium is present or are listed in Subpart D due to the presence of chromium, which do not fail the test for the characteristic of EP toxicity for any other constituent or are not listed due to the presence of any other constituent, and which do not fail the test for any other characteristic, if it is shown by a waste generator or by waste generators that: (A) The chromium in the waste is exclusively (or nearly exclusively) trivalent chromium: and (6) The waste is generated from an industrial process which uses trivalent chromium exclusively (or nearly. MCI) oOOOil 6868 En vi ror>m*nt R#p<jr t*r {Sc. 261.4(bH6)(i)(BU lie HAZARDOUS WASTE CRITERIA .S-5 39 161:1353 exclusively] and the process does not generate bexavalent chromium; and (C) The waste is typically and frequently managed in non-oxidizing environments. (ii) Specific wastes which meet the standard in (i)(A), (B) and.(C) (so long as they do not fail the test for the characteristic of EP toxicity, and do not fail the test for any other characteristic) are (A) Chrome (blue) trimmings generated by the following subcategories of the leather tanning and finishing Industry; hair pulp/chrome tan/retan/ wet finish: hair save/chrome tan/retan/wet finish; retan/wet finish: no beamhouse; through-tha-blue: and shearling. (B) Chrome (blue) shavings generated by the following subcategories of the leather tanning and finishing industry: hair pulp/chrome tan/retan/wet finish; hair save/chrome tan/retan/wet finish; retan/wet finish; no beamhouse; through-the-blue; and shearling. (C) Buffing dust generated by the following subcategories of the leather tanning and finishing industry: hair pulp/chrome tan/retan/wet finish; hair save/chorme tan/retan/wet finish; retan/wet finish: no beamhouse; through-the-blue. (D) Sewer screenings generated by the following subcategories of the leather tanning and finishing industry: hair pulp/chrome tan/retan/wet finish: hAlr save/chrome tan/retan/wet finish: retan/wet finish: no beamhouse; through-the-blue; and shearling. (E) Wastewater treatment sludges generated by the following aubcategories of the leather tanning and finishing industry: hair pulp/chrome tan/retan/wet finish; heir save/chrome tan/retan/wet finish; retan/wet finish; no beamhouse; through-the-blue: and shearling. (F) Wastewater treatment sludges generated by the following aubcategories of the leather tanning and finishing industry: hair pulp/chrome tan/retan/wet finish: hair save/chrome tan/retan/wet finish; and through-theblue. (G) Waste scrap leather from the leather tanning industry, the shoe manufacturing industry, and other leather product manufacturing industries. (H) Wastewater treatment sludges from the production of TiOa pigment using chromium-bearing ores by the chloride process. (6) Solid waste from the extraction, beneficiation and processing of ores and minerals (including coal), including phosphate rock and overburden from the mining of uranium ore. (The second 261.4(b)(6) was added by 45 FR 76620. November 19, 1980] (7) Cement kiln dust waste. (261.4(b)(7) added by 45 FR 76620. November 19, 19801 (8) Solid waste which consists of discard ed wood or wood products which fails the test for the characteristic of EP toxicity and which is not a hazardous waste for any other reason if the waste Is generat ed by persons who utilize the arsenical* treated wood and wood products for these materials' intended end use. (261.4(b)(8) added by 45 FR 78531. November 25, 1980) (r| Hazardous wastes which are exempted from certain regulations. A hazardous waste which is generated in a product or raw material storage tank, a product or raw material transport vehicle or vessel, a product or raw materia! pipeline, or in a manufacturing process unil or an associated non waste-treatment-manufacturing unit, is not subject to regulation under Parts 262 through 265 and Parts 122 through 124 of this chapter or to the notification requirements of Section 3010 of RCRA until it exits the unil in which it was generated, unless the unit is a surface impoundment, or unless the hazardous waste remains in the unit more thap 90 days after the unil ceases to be operated for manufacturing, nr for storage or transportation of product or raw materials. (261.4(c) added by 45 FR 72028, October 30. 1980; amended by 45 FR 80287, December 4. 1980] $ 21.5 Special requirements for hazardous wasts generated by small quantity gancratora. [261.5 revised by 45 FR 76623, Novem ber 19. 19801 (a) A generator is a small quantity generator m a calendar month if he generates less than 1000 kilograms of hazardous waste m that month. (b) Except for those wastes identified in purHgraphs |e) and (f) of this section. a small quantity generator s hazardous wastes are nut subject to regulation under Parts 262 through 265 and Parts 122 and 124 of this chapter, arvd the notification requirements of Section 3010 of RCRA. provided the generator complies with the requirements of paragraph (g) of this section. (cl Hazardous waste that is beneficially used or re-used or legitimately recycled or reclaimed and that is excluded from regulation by 261.6(a) is not included in the quantity determinations of this section, and is not subject la any requirements nf this section. Hazardous waste that is subject to the special requirements of 261.6(b) is included in the quantity delertninaiiims of this seel ion and is subject tu the requirements of this section. (d) In determining the quantity of hazardous waste he generates, a generator need not include. | 1) His hazardous waste when 11 is removed from un-silo storage, or |2| Hazardous waste produced by on site treatment of his hazardous waste |e) If a small quantity generator generates acutely hazardous waste m a calendar month ill quantities greater than set forth below, all quantities of that acutely hazardous waste -ire subiect to regulation under Parts 262 through 265 ami Purls 122 anil 124 of this chapter, and the notification requirements of Section .toil) of RCRA: |1] A total of one kilogram of a commercial chemical products and manufacturing chemical intermediates having the generic names listed in 261.13(e). and uff-npecification cnmmercial chemical products and manufacturing chemical intermediates which, if they met specifications, would have the generic names listed in 261.33(e): or (2) A total of 100 kilograms of any residue or contaminated soil, water or other debris resulting from the clean-up of a spill, into or on any land or water, of any commercial chemical products or manufacturing chemical intermediates having the generic names listed in 261.33(e). (f) A small quantity generator may accumulate hazardous waste on-site. If he accumulates at any time more than a total of 1000 kilograms of his hazardous waste, or his acutely hazardous wnsles 2-20-81 (Sec. 261.6<f I i Publisr-eO ov th BUREAU Of NATIONAL AFFAIRS INC vyASHlNGTQN DC 20037 131 161:1854 FEDERAL REGULATIONS tn quantities greutrr than .irt furlh in pariigraphs (e)(1) or (u)(2) of this section, al) of those accumulated wubU's for which the accumulation limit whs exceeded are subject to refutation under Parts 292 through 2fi5 and Parts 122 and 124 of this chapter, and the notification requirements of Section 3010 of RCRA. The time period of 262.34 for accumulation of wastes on-site begins for u small quantity generator when the accumulated wastes exceed the applicable exclusion level, (g) In order for hazardous waste generated by a small quantity generator to be excluded from full regulation under this section, the generator must: (1| Comply with | 292.11 of this chapter; (2) If he stores his hazardous waste on-sile. store it in compliance with the requirements of paragraph (f) of this section: and (3) Hither treat nr dispose of his hazardous waste in an on-site facility, or ensure delivery to an off-sile storage, treatment or disposal facility, either of which is: (i) Permitted under Part 122 of this chapter; (ii) In interim status under Parts 122 and 265 of this chapter: (Lii) Authorized to manage hazardous waste by a State with a hazardous waste management program approved under Part 123 of this chapter: (iv) Permitted, licensed or registered by a State to manage municipal or industrial solid waste; or (v) A facility which: (A) Beneficially uses or re-uses, or legitimately recycles or reclaims his waste: or (B) Treats his waste prior to beneficial use or re-use. or legitimate recycling or reclamation. (h) Hazardous waste subject to the reduced requirements of this section may be mixed with non-luiztmlmis waste and remain subject to these reduced requirements even though the resultant mixture exceeds the quantity limitations identified in this section, unless the mixture meets any of the characteristics of hazardous wastes identified in SubpHrt C. (i) If a small quantity generator mixes a solid waste with a hazardous waste that exceeds a quantity exclusion level of this section, the mixture is subject to full regulation. 291.6 Special raqulremants tor hazardous waste which is used, ra-uaed, recycled or reoMtmed. f.t) Except as otherwise provided in paragraph (b) of this section, a hazardous waste which meets either nf the following criteria is not subject to regulation under Parts 262 through 265 or Parts 122 through 124 of this Chapter .ind is not subject to the.notiflcation requirements of Section 3010 of RCRA until such time as the Administrator promulgates regulations to the contrary (1) It is being beneficially used or re used or legitimately recycled or reclaimed. (2) It is being accumulated, stored or physically, chemically or biologically treated prior to beneficial use or re-use or legitimate recycling or reclamation. (b) A hazardous waste which is a sludge, or which is listed in Subpart D. or which contains one or more hazardous wastes listed in Subpart D: and which is transported or stored prior to being used, re-used, recycled or reclaimed is subject to the following requirements with respect to such transportation or storage: (1) Notification requirements under Section 3010 RCRA. (2) Part 262 of this Chapter. (3) Part 263 of this Chapter. (4) Subparts A. B. C. D and E of Part 264 of this Chapter. (5) Subparts A. B, C. D. E. G, H. I. J and L of Part 265 of this Chapter. (6) Parts 122 and 124 of this Chapter, with respect to storage facilities. 261.7 Residue* of hazardous wests In empty containers. (261.7 added by 45 FR 76529, November 25. I960) (a)(1) Any hazardous waste remaining in cither (i) an empty container or (ii) an inner liner removed from sn empty container, as defined in paragraph (b) of this section. Is not subject to regulation under Parts 281 through 266. or Part 122 or 124 of this chapter or to the notification requirements of Section 3010 of RCRA. (2) Any hazardous waste in either (i) a container that is not empty or (ii) an inner liner removed from a container that is not empty, as defined in paragraph (b) of this section, is subject to regulation under Parts 261 through 265. and Parts 122 and 124 of this chapter and to ihe notification requirements of Section 3010 of RCRA. (b)(1) A container or an inner liner removed from a container that has held any hazardous waste, except a waste that is a compressed gas or that is identified in $ 261,33{t)of this chapter, is empty if; (1) all wastes have been removed that can be removed using the practices commonly employed to remove materials from that type of container. e.g.. pouring, pumping' and aspirating, and (ii) no more lhan 2.5 centimeters (one inch) of residue remain on the bottom of the container or inner liner. (2) A container that has held a hazardous waste that is a compressed gas is empty when the pressure in the container approaches atmospheric. (3) A container or an toner liner removed from a container that has held a hazardous waste identified in t 261.33(c) of this chapter is empty if: (i) the container or inner liner haa been triple rinsed using a solvent capable of removing the commercial chemical product or manufacturing chemical intermediate; (ii) the container or inner liner has been cleaned by another method that has been shown in the scientific literature, or by tests conducted by the generator, to achieve equivalent removal; or (iii) in the case of a container, the inner liner that prevented contact of the commercial chemical product or manufacturing chemical intermediate with the container, has been removed. Subpart B--Criteria for Identifying the Characteristic# of Hazardous Waste and for Listing Hazardous Wasts ^261.10 Criteria for Identifying the chereeterladea of hazardous waste. (uj 'The Administrator shall Identify and define a characteristic of hazardous waste in Subpart C only upon determining (hat: (1) A solid waste that exhibits the characteristic may: (i) Cause, or significantly contribute to, an increase in mortality or an increase in serious irreversible, or incapacitating reversible, illness; or (ii) Pose a substantial present or potential hazard to human health or the Environment Reporter MCD 000016890 [Sac. 261.10(*(1MIII) 132 , HAZARDOUS WASTE CRITERIA S-:39 161:1855 environment when it is improperly treated, stored, transported, disposed of or otherwise managed: and (2) The characteristic can be: (i) Measured by an available standardized test method which is reasonably within the capability of generators of solid waste or private sector laboratories that are available to serve generators of solid waste: or (ii) Reasonably detected by generators of solid waste through their knowledge of their waste. 261. il Criteria for listing hazardous waste. /Interim final/ (a) The Administrator shall list a solid waste as a hazardous waste only upon determining that the solid waste meets one of the following criteria: (1) It exhibits any of the characteristics of hazardous waste identified in Subpart C. (2) It has been found to be fatal to humans in low doses or. in the absence of data on human toxicity, it has been shown in studies to have an oral LD 50 toxicity (rat) of less than 50 milligrams per kilogram, an inhalation LC 50 toxicity (rat) of less than 2 milligrams per liter, or a dermal LD 50 toxicity (rabbit) of less than 200 milligrams per kilogram or is otherwise capable of causing or significantly contributing to an increase in serious irreversible, or incapacitating reversible, illness. (Waste listed in accordance with these criteria will be designated Acute Hazardous Waste.) (3) It contains any of the toxic constituents listed in Appendix VIN unless, after considering any of the following factors, the Administrator concludes that the waste is not capable of posing u substantial present or potential hazard to human health or the environment when improperly treated, stored, transported or disposed of. or otherwise managed: (i) The nature of the toxicity presented by the constituent. (ii) The concentration of the constituent in the waste. (iii) The potential of the constituent or any toxic degradation product of the constituent to migrate from the waste into the environment under the types of improper management considered in paragraph (a)(3)(vii) of this section. (iv) The persistence of the constituent or any toxic degradation product of the constituent. (v) The potential for the constituent or any toxic degradation product of the constituent to degrade into non-harmful constituents and the rate of degradation. (vi) The degree to which the constituent or any degradation product of the constituent bioaccumulates in ecosystems. (vii) The plausible types of improper management to which the waste could be subjected. [viii] The quantities of the waste generated at individual generation sites or on a regional or national basis. (ix) The nature and severity of the human health and environmental damage that has occurred as a result of the improper management of wastes containing the constituent. (x) Action taken by other governmental agencies or regulatory programs based on the health or environmental hazard posed by the waste or waste constituent. (xi) Such other factors as may be appropriate. Substances will be Hsted on Appendix VIII only if they have been shown in scientific studies to have toxic, carcinogenic, mutagenic or teratogenic effects on humans or other life forms. (Wastes listed in accordance with these criteria will be designated Toxic wastes.) (b) The Administrator may list classes or types of solid waste as hazardous waste if he has reason to believe that individual wastes, within the class or type of waste, typically or frequently are hazardous under the definition of hazardous waste found in Section 1004(5) of the Act. (c) The Administrator will use the criteria for listing specified in this section to establish the exclusion limits referred to in 8 261.5(c). Subpart C--Characteristic* of Hazardous Waata 8 261.20 General. (a) A solid waste, as defined in 8 281.2. which is not excluded from regulation as a hazardous waste under 8 281.4(b). is a hazardous waste if it exhibits any of the characteristics identified in this Subpart. [Comment: 8 282.11 of this.Chapter sets forth the generator's responsibility to determine whether his waste exhibits one or more of the characteristics identified in this Subpart) (b) A hazardous waste which is identified by a characteristic in this subpart, but is not liste d as s hazardous waste in Subpart D, is assigned the EPA Hazardous Waste Number aet forth in the respective characteristic in this Subpart, lids number must be used in complying with the notification requirements of Section 3010 of the Act and certain recordkeeping and reporting requirements under Parts 282 through 265 and Part 122 of this Chapter. (c) For purposes of this Subpart, the Administrator will consider a sample obtained using any of the applicable sampling methods specified in Appendix I to be a representative sample within the meaning of Part 260 of this Chapter. [Comment: Since the Appendix,! sampling methods are not beingformally adopted by the Administrator, a person who desires to employ an alternative sampling method iB not required to demonstrate the equivalency of his method under the procedures set forth in 8 8 260.20 and 26021.] 8M1-21 Charactertattc o< IgnttaMMy. (a) A solid waste exhibits the characteristic of ignitability if a representative sample of the waste has any of the following properties: (1) ft is a liquid, other than an aqueous solution containing less than 24 percent alcohol by volume, and has a flash point less than 60*C (140*F), as determined by a Pensky-Martens Closed Cup Tester, using the test method specified In ASTM Standard D-0&-79, or a Setaflash Closed Cup Tester, using the test method specified in ASTM standard D-3278-78, or as determined by an equivalent test method approved by the Administrator under the procedures set forth in 55 260.20 and 260.21.'1 1 ASTM Standards are available"trots ASTM. ISIS Race Strmf. Philadelphia. PA ISMS. 2-20-81 [Sac. 261.21(a)(1)] Published Ov The BUR EAU OP NATIONAL AFFAIRS. INC WASHINGTON DC 20037 MCD 000016891 133 161:1856 FEDERAL REGULATIONS (2) It is not a liquid and is capable, under standard temperature and pressure, of causing fire through friction, absorption of moisture or spontaneous chemical changes and. when ignited, bums so vigorously and persistently that is creates a hazard. (3) It Is an ignitabie compressed ga as defined in 49 CFR 173.300 and as determined by the test methods described in that regulation or equivalent test methods approved by the Administrator under 9$ 260.20 and 260.21. (4) It is an oxidizer as defined-in 49 CFR 173.151. (b) A solid waste that exhibits the characteristic of ignitabiiity. but is not listed as a hazardous waste in Subpart D? has the EPA Hazardous Waste Number of D001, 9 291.22 Characteristic ot corrastvtty. (a) A solid waste exhibits the characteristic of corrosivity if a representative sample of the waste has either of the following properties: (1) It is aqueous and has a pH less than or equal to 2 or greater than or equal to 12.5. as determined by a pH meter using either the test method specified in the "Test Methods for the Evaluation of Solid Waste, Physical/ Chemical Methods" ' (also described in "MethodsTor Analysis of Water and Wastes" EPA 600/4-79-020. March 1979), or an equivalent test method approved by the Administrator under the procedures set forth in 99 260.20 and 260.21. (2) It is a liquid and corrodes steel (SAE 1020) at a rate greater than 6.35 mm (0.250 inch) per year at a test temperature of 55*C (130*F) as determined by the test method specified in NACE (National Association of Corrosion Engineers) Standard TM-0169 1 as standardized in "Test Methods for the Evaluation of Solid Waste. Physical/Chemical Methods." or an equivalent test method approved by the Administrator under the procedures set forth in 99 260.20 and 260.21. (b) A solid waste that exhibits the characteristic of corrosivity, but is not listed as a hazardous waste in Subpart D. has the EPA Hazardous Waste Number of D002. * This document n available from Solid Waste Information. U S. Environmental Protection Agency. 26 W. St. Clair Street. Cincinnati, Ohio 4S2SS. 'Tlie NACE Standard u available from the National Association of Corrosion Engineers. P O Box 96S. Katy, Texas 77450 9 261.23 Characteristic of reactivity. (a) A solid waste exhibits the characteristic of reactivity if a representative sample of the waste haB any of the following properties: (1) It is normally unstable and readily undergoes violent change without detonating. (2) It reacts violently with water. (3) It forms potentially explosive mixtures with water. (4) When mixed with water, it generates toxic gases, vapors or fumes in a quantity sufficient to present a danger to human health or the environment. (5) It is a cyanide or sulfide bearing waste which, when exposed to pH conditions between 2 and 12.5. can generate toxic gases, vapors or fumes in a quantity sufficient to present a danger to human health or the environment. (6) It is capable of detonation or explosive reaction if it is subjected to a strong initiating source or if heated under confinement. (7) It is readily capable of detonation or explosive decomposition or reaction at standard temperature and pressure. (6) It i9 a forbidden explosive as defined in 49 CFR 173.51. or a Class A explosive as defined in 49 CFR 173.53 or a Class B explosive as defined in 49 CFR 173.B8. (b) A solid waste that exhibits the characteristic of reactivity, but is not listed as a hazardous waste in Subpart D. has the EPA Hazardous Waste Number of D003. 261.24 Characteristic of EP Toxicity. (a) A solid waste exhibits the characteristic of EP toxicity if. using the test methods described in Appendix II or equivalent methods approved by the Administrator under the procedures set forth in 9 260.20 and 260.21. the extract from a representative sample of the waste contains any of the contaminants listed in Table I at a concentration equal to or greater than the respective value given in that Table. Where the waste contains less than 0.5 percent filterable solids, the waste itself, after filtering, is considered to be the extract for the purposes of this section- (b) A solid waste that exhibits the characteristic of EP toxicity, but ia not listed as a hazardous waste in Subpart D. has the EPA Hazardous Waste Number specified in Table l which corresponds to the toxic contaminant causing it to be hazardous. Tabta I.--Maximum Concentration ol Contaminants for Characteristic of EP Toxicity-- Continued EPA MllRUul VMM number Contanenant Maxmsn soncenvauon (Mftgra/na Sms9 0004 ...... Areemc.............. .................... 0005 .......... Sanum ........................... oooe.......... .. Cadmium................................ 0007............ Cbramwn............................... DOOS.............. Mercury.................................. 0010............. Selemum................................ 0011 ............ Sitver...................................... D012............. Endrtn (1.2.3.4,10.10- nexecNoro-i.7-epo*y. 1.4.44.5,6.7,8,6*. octaftya-o-l.t erne, enOo- 5,6-dvnetneno naphthalene 0013............... Undana 11.2.3.4,5.6- hexachUrocyeioheaane. gamma nomar. 0014............. MethoxycMor (i.i.iTneMcro-2^-M lo mabtoKypnerryiiemane). DO'S............ Toaapnene (C,.H,,C4., Taebneai emonnatad camphane, 67-OS percent cMorme). DOIfl............. 2.4.0. (2.4- DieNoTccnanoKvaceao acid). 0017.............. 2,4,5-TP SPvei (2.4.5- aod). 6.0 100.0 10 50 50 02 10 50 0 02 0.4 100 0.5 100 10 Subpart D--Liats of Hazardous Wastaa [Interim final) 9 261.30 General. (a) A solid waste is a hazardous waste if it is listed in thia Subpart, unless it haa been excluded'from this list under 9 9 260.20 and 260.22. (b) The Administrator will indicate his basis for listing the classes or types of wastes listed in this Subpart by employing one or more of the following Hazard Codes: IpnctAN* Waste ............................................................. CgnWn Watt*........ .................................................... Reeeeue Wane........................................... EP Tonic Will*................................................... Acuta Hacaroeua Watia .............................................. ToaeWaaia.................................................... .............. (l) fC) CR) {) (H) (T) Appendix VII identifies the constituent which caused the Administrator to list the waste as an EP Toxic Waste (E) or Toxic Waste (T) in 9 261.31 and 261.32. (c) Each hazardous waste listed in this Subpart is assigned an EPA Hazardous Waste Number which precedes' the name of the waste. This number must be used in complying with the notification requirements of Section 3010 of the Act and certain recordkeeping and reporting requirements under Parts 262 through 265 and Part 122 of this Chapter. (d) The following hazardous wastes listed in 261.31 or 261.32 are subject to the exclusion limits for acutely hazardous wastes established in 261.5: (Reserved) [261.30(d) revised by 45 FR 74890, November 12, 1980] Environment Report* (Sec. 261.30(d)] 134 HAZARDOUS WASTE CRITERIA 261.31 Hazardous waste from nonspecific sources industry n.l l'A hazardous hiisiii No Miu.in K..iS w.r.lu S-544 161:1857 COd* POQ, Foot.. F003........................................... F004 ........................................... |hll f0nowmg SMni hatogonalod sofvenl* utM m degreasing tetrsenlofoethylene. trichloroethylene. methylene chloride. 1 * t-irchforoeiham?. cn'Orvi luirar.nlonda ana chlorinated tiuorocartjons. and .nine's iiom me recovery oi move saivumi n gsgreasing operaiont tho following spent hatogenated sowerne. letrachioroaihyiona, muthytane emends. tnchienoemyiunt. inchioroethana. cniorooenzen* II? lnkHiaiO-i .2.2-iriiiuoroetnarve. ortnc-dicriiorobenjsne. ana thcnioro'iuorometnane. ana me aim bottoms trom me recovery ot these solvents tub tonowing spent non-netogenated sotventa- rylena ycetona ethyl acetate, ethyl benzene, ethyl ether, methyl nobutyi ketone, n-butyt atcohet. cyCohexanone, ana methanol; ana the etitl bottoms trom me recovery ot these solvents. The following spent nqn-natogenated solvents eresols ena cresytrc sod. end nitrobenzene, and the suit bottoms trom the recovery ot these solvents. IT) (I) 0) iT) industry end EPA hazardous west# No. Hazardous waste Hazard code F005............................ The lottowrng soent non-hatogenaiw solvents- toluene, methyl ethyl Ketone, carbon OiSuitioe. isobuianoi. ana pyridine: ina me still bottoms II. T) trom the lecovery o( these solvents FC06........ ................................. Wastewater treatment sludges "om eleclrootating operations except trom the following crocesses 11) suttunc acid anodizing o' alum.num. (T) 12) tin plating on carbon steel. <31 zinc plating (segregated oes-si on carbon steel. () aluminum or zinc aluminum piatmg on caioon steel, 15) cleaning'stripping asaociatea witn tin. zinc and aluminum plating on caroon steel, and 16) ehemcal etching and muling of aluminum F0'9 Wasiewatei treatment sludges trom the cnemicsl conversion cooung O' aluminum F0O? bpent rvnnioe plating bath solutions trom electroplating operations (except tor precious me'SK electroplating spent Cyanide plating bath (R. t) gimiuiivt FOOS............. .............Plating oaui atudgea horn me buttum ot anting batha trom electroplating operations where cyanrdea are used m tho process (except for (R T) D'ecioua moral* electroplating plating bath sludged F009 ......................................... Spent stripping end ciearvng oain soiutione trom electroplating ooetanona where cyanides are used m me procese (except lor precious (H T) metais e ecuopisimg spent stripping ana cleaning bath sotutionsi. FOIO........................................... Quenching oa'h sludge <rom oil bams trom metal heat treating operations where cyanides are used m me process (except lor precious (FI T) metals heal treating quenching bam sludges) Foil .........................Spent cyanide solutions from salt bam pot cleaning trom metal heat (reeling operations (except 'or precious metals heat treating spent (Ft. T) cyanide solutions trom salt bam pot clashing) F0I2 . Ouenching waatewaier treatment sludges from metal heat treating operations whore cysnidas are used m tna process (except'or pxeoous (T) matais heat treating quenching wastewater treatment sludgesl. F014 Cyanidation wastewater treatment taiimg pond sediment from mineral metals recovery operations ................................................................................. fTj FOtS Spent cyan*Je bun solutions from mineral metals recovery operations ........................................................................................ (T| (AT) (261 JI amended hvJi I R 47x U. JuK 16. I^KO; rcMied by 45 FR 74890. November 12, 1980:46 |- R 4617. January I (. I4HI| 11-77 81 [See. 261.311 ubli|h#o by THt BUHtAU 0* NATIONAL Ahf-AlRS INC WASHINGTON DC ^0037 000016893 MOD 117 161:1858 FEDERAL REGULATIONS 261.32 Hazardous waste from specific sources. industry and ERA hazardous waste No Hazardous waste Hazard code Wood Preservation KW1 Inorganic Pigmems K002 K003 K00* .. .. K005 ................... K006 .............. K007 . . . K006 Grg.inic Crujm>ci: K009 *010 ...... KOn.................... *013 ................. K014.................. KOtS................... KOI 6 KOir KO'S................... KOI#................- koto . .. K021. ....... K02? K023 K024 KOM K094 ........... KC25 K026 K027..................... K028 K029.................... KW5 KOM................... K030.................... KOM .................. K103.................... K104 K065.................... K105 .................. inorganic Chemcale; K071 .................. . K073............. ....... K 100 ............... . Pott* ides: K031..................... K032 ................ K033 ................. . K034 K097 .................... K03S.................... KOM.................... K037 .................... KOM.................... KG39 ............. K040 ................... K041......... ............ KOM K042...................... K043...................... KOM .................... Explosives: KOss ........................................... KOsS............................................ K046............................................ K0*7......................................... Blroleum Retlnmq: KOss.................... ....................... KM9............................................ KOSO............................................ K0S1 ............... .......................... K052 ......................... ................. >on and Steel. wwi .......................................... K0#2 ........................................... Bottom sediment sludge Iron if* treatment of wastewaters Irom wood preserving processes (hat use creosote snd/df pentachioroehenoi.... Westewator treatment sludge tom me produciron ot chrome yellow and orange pigments ....... ....................................... . Wtvrewalet treatment sludge from me production ol molybdate orange pigments................................................... ................................................... Wastewater iroaiment sludge ircm me oroouetion ol zinc yellow pigments.......................................................................................................................... Wastewaier uealment sludge iron the production ol chrome green pigments.... ..................................................................................................... WaHcwaior Iroaiment siudqe from me production ol chrome Oxide green pigments (anhydrous end hydrated) .................................................. Westi water treatment sludge (rum the production or iron Diue pigment* .................... ............. ............................................................................ Oven residue Irom the production ol chrome oirde green pigments ................................................................................................... Oistii'niion Bottom* irom the production ol eceiaidohyoe irom oinyiene..... ............................... Oisiiiiniaort side cui* irom me production ol eceiaioenyoe irom emyiene ................................................... ............................................. . Bottom stream item tne w**i*w*ter stripper n the proouction ot acrylonitrile..................................... Bottom stream irom the acetonnnie column in me production ol acryiommie...................................................... ....................................... ..... ............................... Bottoms Irom the acetonitrile purification column m the production ol acrylonitrile.......................................................................................................... . Suit bottoms Irom the asUlation of benryl chloncw .................................................................. Heavy ends or destination residues tram the production ol carbon letracMonde.......................................................................................................... ...... Hsmy ends (sun bottomel irom the ouniicanon column m-me production ol epichiorohydnn................................................................................ ......... Heavy ende Irom the fraceonanon column m ethyl chloride production .... ................................ Haarp aMa #ott lhe dleMaMn of ethylene achionde *i evvytene dichionde production... ............................. Haary aada (ram the MNaton of wnyt eNertde at <rtny* ctaonde monomer production............................................................................................. Aqueous spent antimony catalyst wsste irom Muoromeinane* production........................................................................................................ Ofattabon bottom lara from the production of pnenot/acetone irom cumene ..................................................... ....................... Oupaatun light ends tram the produebon of phtheiic enhydnde from naphthalene.................................................. ....................................... .... ............. Otstaumn bottoma from Pie production ol phthaUc enfiysmoe Irom naphthalene.............................................................................................................. DwMation tight enda from the production d phtnabc anhydride irom ortho-xyiene...................................................................................... OtaUabon bottoma from die productron of phthatie antiyasde irom ortho-xyiene......................................................................... OnUUtion bottoms Irom the production ol nitrobenzene by tne rvusuon ol benzene........................................................................................................ Stripping at* taila from me production ot meaty ethyl pynomes................. -.................................................................................................. Centntuge and diswiabon rescues from toluene dirsocyanete production............................................................................................................. Spent catafyat from the hydrochionriaiof reactor m me production ol t.M tnchioroethane.................. .......................................................................... Waste from me product steam stripper m me production of i.i.i-tncfuoroethane........................................................................ ..................................... Ctattilation oottomt from the pfoduction of t.i.Mncmoroeman*................................ Heavy ends horn me heavy ends column from me production oi vi.t-trieMoroeinane............................................................. .................................... Column bottoms or heavy enda from the combined produebon ol tnchtoroeiftyWrie and perohloroeihyiene........................................... .................. CtSWIafron bottoms from ansina production .............................................................................................................................................................................. Procsss residues from aniline extraction from the production of anbne.................... _ ............... ........................................... Combined wastewater stteams generated from rwrobamene/anrime production ... _ .......................................................... &aHaon or Irectionation column betioms from tne production ol entorooenxenea ........................................................... Separated aqueous stream Irom the reactor product weaning atap m the production ol cNoroMnzerwe.................................................................... Bnne purification mud* from the mercury cett process m chtonna production, where separately prepunhed brme a not used............................... Chlonnatee hydrocarbon waste from the purification step of me diaphragm can process using graphite anodes as cnionne production .......... Waeteweter treatment sludge from me mercury ceil process m enronne production ............................ ........................................................................... By-proAKt salts generated m the production ol MSMA and cacodyl* aed..................................... wastewater ireeimem sludge from the production ol ehiordane..................................................................................................................... __ Wastewater end scrub water from the chlorination ot cydopentadiene m the production ot cniordane..................................................... Filter solids from the filtration at hexachiorocyclopentadiene m the production ol cniordane..................................................... Vacuum slnpper discharge Irom the entordane cnionnator tn the producuon ol ehiordane............................................................................................... Wastewater treatment sludges generated m the production ol creosote ... ......................................................................................................... SMI bottoms Irom toluene reclamation distillation m me production of disultoton ............................................................................................................. Wasiewater treatment studgea from me production of disulfoton....................................... ............................................ .......................... Wastewater from the washing and striooing ol phorate production ............ ...................................................... ...................... Filter case from ma Miration ol diethvionosehorociihKX acid m the production ol phorate............................................................................................. wastewater treatment sludge from me production ot phorate........................ Wastewater treatment sludge from the production of toxaohene...................................................................................... ....... ............. ........... ...... Untreated process wastewater from me production of taxaphene............... ............................ .......................................................................................... Heeyy enda or disuliaiion residues from me astitiation of tetrachforooenzene m the production of 2,S,5-T............................................................. ... 2.B-Qctiiof0phenol waste from the prooucson ol 2.S-D......... ............ ................................................................... Untreated wastewater from me production of 2,4-0..................................................................... ........... ............................. ..................... Wastewater treatment sludge* from me manufacturing and processing of explosives.......................................... ............ Spent carbon from the treatment of wastewater containing explosives................................................................ .................. Wastewater treatment sludge* from the manulaciunng, formulation ana loading ol lead-based whaling compounds. Pmk/red weter from TNT operation*................................................................ . ...... ....... ............. DisaeAred air flotation (OAF) float from me petroleum refining industry............................................................................... Stop os emulsion aonoa from the petroleum reiuung industry............................................................. ....................................... Heat exchanger bwnofo cleaning sludge from the petroleum retimng ndustry....................................................................... API separator sludge from tne petrpleum reining industry........................... ............................................................ ............... Tar* bottoma (leaded) front me petroiaum reiimng nvdusey...................................................................................................... Emnaion control duai/tiudge from the primary produebon of steel tn electric furnaces Spent pacnie nquo> from steel finishing operations.................................................................. IT) <T) <T> (T) U) (T> (T) IT) (T) (T) <R. T) (fl, T) m (T| (T) (T) (T> m IT) m T) (T) fT) <T) m m m (R, T) m IT) (T) IT) (T) (T) O) (T) (T) <T) (T) (T) fT) m m m m <T) fT) (T) (T> fT) fT) (T) rr> m fT) fD fT) (R) <R) D <R> IT) (T) fT) (T) ro fT) (C.T) Environment Reporter MCD 000016894 [Sec. 262.321 11fi HAZARDOUS WASTE CRITERIA ^-544 161:1359 lftOwfW tna EPA hazardous wssl NO. Primary Copper K044................................ Pnmery lud: KOOS................................ Primary Znc: K000..................... K067................... ............. KOM .. ............... Secondary Lead: KOW..................... K100..................... vaiarmary Pharmacaoocan; KW4............................... K101.................... KID2................................ ink Forrxuaneyt kom..................... CokXo K067 Hazardous waste Hazara code AsnS pJant slowdown siurry/iludge resulting from tna Onekemng of blowdown iiu'ry from primary coppar produeaon............. ......................... (T> Surface impoundment bom* cont**-wd in and dredged Irom aurface anpoundmama al primary lead ametkng facaiuaa......................... ............... (T) Sludge from treatment of process wastewater and/or acid plant blowdown from primary ztnc production................................. ......................... ....... Electrolytic anode panes/pudges from primary zmc production.................. .................................................................................................. ........................ Cadmium plant leacnate residue |aon oiaje) from pnmary zinc production ................................................................................................................. (7) (T) (T) Emission control duat/Pudge irom aeconoa/y lead smeiong ................................................................ .......................... ..................................... .......... Waste lescnmg solution irom acid leacn.ng of emission control dual/Pudge irom secondary lead smenmg........................................................ ,T) T) Wastewater eeatmeni sludges generated during tM production ot veterinary pnarmaceuticafa from arsenic or orgaw-wsetac oorrpounaa..... DmtiHanon tar residue* from ids disUiatron of andme-based compound* m the production of veiennary pnarmaceuacal* from arserac or organo-arsenic compounds. Residue from me use of activated carbon for -decolonization m tna production of veterinary pharmaceuticals from arsetsc or nrpenn weenr compounds. (T) (T) |T) Solvent wasne* and sludges, caustic washes and afudget. or water washes and *>udge* from ctaanmg tuba and aiyisseeis uaoo r tna (T| formulation of mfc from pigmenta. Oners, seeps, end sisOMiztra contenting chromium and lead. Ammonia tun kme sludge from colung operations .................................................................................................................................................................... (T) Oecamer tank tar siuge from coking operations................................................................................... ....................................................... ................................ (D |2(S! J2 .intended hv 45 KR 47KJ.I. July lb. IVXO: 45 I R 720.1`>. Octuher .10. 1R(): rtf'iMJU h\ 45 I R 744HO. November 12. IRHO; 46 HR 4617, January Ih. I4KI| 261.33 Discarded commercial chemical products, off'SpecificatloD species, container residues, and residues thereof. [261.33 revised by 45 FR 78541, Novem ber 25. 19801 The following materials or items are hazardous wastes if and when they are discarded or intended to be discarded: (rt) Any commercial chemical product, or manufacturing chemical intermediate having the generic name listed in paragraphs (e) or (F) of this section. (b) Any off-specification commercial chemical product or manufacturing chemical intermediate which, if it met specifications, would have the generic name listed in paragraphs (e] or (f) of this section. (Editor's Note: EPA November 25. 1960. revised 261.33(c) twice. Both versions follow:} (c) Any residue remaining in a container or an inner liner removed from a container that has held any com mercial chemical product or manu facturing chemical intermediate having the generic name listed in paragraph (ei of this section, unless the container is empty as defined in 261.7(b)(3) of this chapter. (Comment: Unless the residue is being beneficially used or reused, or legitimately recycled or reclaimed: or being accumulated, stored, transported or treated prior to such use, re-use. recycling or reclamation. EPA considers the residue lo be intended for discard, and thus a hazardous waste. An example of a legitimate re-use of the residue would be where the residue remains in the container and the container is used to hold the same commercial chemical product or manufacturing chemical intermediate it previously held. An example of the discard of the residue would be where the drum is sent to a drum reconditioner who reconditions the drum but discards the residue.] [261.33(c) revised by 45 FR 78529, November 25, 1980) (c) Any container or inner liner removed from a container that has been used to hold any commercial chemical product or manufacturing chemical intermediate having the generic name listed in paragraph (e) of this section, unless: (1) The container or inner liner has been triple rinsed using-a solvent capable of removing the commercial chemical product or manufacturing chemical intermediate; or [2) The container or inner liner has been cleansed by another method that has been shown in the scientific literature, or by tests conducted by the generator, to achieve equivalent removal: or (3) In the case of a container, the inner liner that prevented contact of the commercial chemical product or manufacturing chemical intermediate with the container, has been removed. [The second 261.33(c) was revised by 45 FR 78541, November 25, 1980) [d) Any residue or contaminated soil, water or other debris resulting from the cleanup of a spill, into or on any land or water, of any commercial chemical product or manufacturing chemical intermediate having the generic name listed in paragraphs (e) or (f) of this Section. [Comment: The phrase `commercial chemical product or manufacturing chemical intermediate having the generic name listed in . . refers to a chemical substance which is manufactured or formulated for commercial or manufacturing use which consists of the commercially pure grade of the chemical, any technical grades of the chemical that are produced or marketed, and all formulations in which 3-27-81 (Sec. 261.33(d)) Published Uv T*E BUREAU OF NATIONAL AFFAIRS INC WASHINGTON DC 20037 MC-D 000016895 M9 161:1860 FEDERAL REGULATIONS the chemical is the sole active ingredient. It does not refer to a material, such as a manufacturing process waste, that contains any of the substances listed in paragraphs (e) or (f). Where a manufacturing process waste is deemed to be a hazardous waste because It contains a substance listed In paragraphs (e) or (fj. such waste will be listed in either IS 261.31 or 261.32 or will be identified as a hazardous waste by the characteristics set forth in Subpart C of this Part.] (e) The commercial chemical productB or manufacturing chemical intermediates, referred to in paragraphs (a) through (d) of this section, are identified as acute hazardous wastes (H) and are subject to the small quantity exclusion defined in 261.5(e). [Comment: For the convenience of the regulated community the primary hazardous properties of these materials have been indicated by the letters T (Toxicity), and R (Reactivity). Absence of a letter indicates that the compound only is listed for acute toxicity.) These wastes and their corresponding EPA Hazardous Waste Numbers are: Hiiroou warn No. Subelance P023 ............. Acetaldehyde. chioro- POO2...................... AcatamMM. N-(imrwiriio<emeihyiV P057....................... Acetamide. 2'ftuoro- POM ............... Acetic acid. Auoro-, aoOum salt P066 . Aeatlmidic Ic4 N-((melhylcar- damoyilovyltho-. methyl eater POO i. ........ 3-<aha-acetonylb*ruYi>-4. hydr^nycoumann and salt* P002 ................i-Aceiyl-2-tnouraa P003.................... Acrolein P070..................... AOiear P004...................... Aidnn POOS..................... AIM alcohol POO....... . . Aluminum phoaphide POO7 ................... 5'(Arr*norr>eiriyi)-3-isoizoiot POO..................... i-aArranopyndine P009..................... Ammonium pacrate (Rl Pi 19 .................. Ammonium vanadate POtO .................... Araarwc a&O P012...................... Artamc (III) ohm POi 1 .................... Arsenic (V) oxide POIt .................. Afsamc pentoxoa P012 .................... Araeme tnoiuda P038 ..................... Arena, diethyl- P054 ..................... AuntMna P0i3.................... Barium cyanida P024..................Senzenamme. <nion> P077...................... Sanzenamine. 4-nio P028...................... Benzene, (cnioromewytlP042...................... 1.2-Benzenediot, 4-[Knydroxy-2-(methyi- ammoMthyt). POl a......... ........... Banzanalhiol P02B .. . Benzyl chionda POl 5...................... Beryllium float POie .............. Sielchloromethyt) emer POl 7 ............... Bmmoecatone POi .............. Brucine PO?1 Calcium cyanide P123 . . Camohen*. oelectHoro- Pi03................ Carbamimidoaaiano aod POiJ.............. Canon bisuitida P022 ..................... CarOon disuthd# Hj/jMouS No Si.I.si.in... W.islu No Swi ounce POOS..................... Carbonyl chionda P033 ................ Chionna eyanide P023 ................... CNeroecaiaidefiyde P024 ..................... p-CnioroaniHna P02..................... 1 (oOMrophanyiHMOu'ea P027...................... 3-ChioropfopioiWle POM..................... Cooper cyanide* P030...................... Cyanide* (acHuMe cyen.de aaita). not *t*ewhere adeemed Post................. ..... Cyanogen P033..................... Cyanogen omonda P03.......... ....... Oienerophanytarama P037 ................... Dtewrih POOS...................... Oloihyteralne P039.... .................. O.O-Oeihyl S(2-(atnynhio|*tnyl] phoa- phoroanMoate P041...................... OietiM-P-ni'roeiwM pnoephate P040...................... O.O-Dlethyi Opyrazmyt phoaphorothioat# P049...................... OiiaopropyiBuorephoaphate P044....................... Omethoatt P045 ...................... 3.3-Dvnethyl-1-(m#dvtho|-2-but*/ion*. O* ((methytamnoMarbonyll own* P0?1...................... O.O-Otmelty O-p-mbopbenyt phosphoro- thoata P062 PQ46 PU47 . OmethylnrtrOMmme .. . alpha. avna-Oimeinyionenetnyiamine .................a 6-0*wro-o-cr#*oi and aaita P034 . 4,6-Oinitr>o-cycion*xylph*not P048 ............. 2.4-Oinnrotpnenoi P0?n ... Omoaao POflA ... Dsmoeonoramioe. pctamemyi- P039 ................. Oaudoion PI.M9 2 4-Dilhratnuret p- 09 ... D.trooyrop"osohonc aod. tetraethyl esier PjoO . . .. Endoaudan P068 .. Endomaa POM . . Endrm P042 . Eomecmnne P04 .................. Eihanamna. i.i-dnn*thyi-2'onenyi- P084 ............ Elhanamme N-m*rrn4-Nnitroso- Pioi .................... Eihyl eyamoe P054 ............... Elfryiaienunt P097 ................ Femphur POM....................... flUOMM P057 ..................... Fluoroacaiamide POS8 ................... Fluoroacaiie aciC. sodium salt 0065..................... Fulmen* acid. mercury(H) sail |fl.T) P0S9.................... HeptaciMor P0S ................... l.2.3,4.l0.10.He.achiOfO-6.7 eoory t.4,44.5.8.7.8. Ba-octahydro-endo.endoI .4 S.BHjimetnanonaphthaien* PQ37.................... ' 2.3.4,i0.iO-n*acnioro-6.7-epoyi 4.4a.S4.7.9<8a-dcianvoro-ando.eiio< P060....... l 4:S.8-demetnanonapnthalene l.2.3.4.l0.10-H*xacnioro>tl4.4a.5.B.Ba- hesahydro-t.4 5.8-endo, enao-dimettv aixmaphthatene P004...................... 1,2.3.4,KS,H>VHeicacnoro-i.4.4a,5.8,6a- hexenydro-1.4 5.6-endo.exoametnanonaohmaien* P060 .................... MenacrtOfOh*alryio-*io.#'odimalhanonaohthalane 062..................... Hexaetnyi letraphoaohaia PUB...................... MydrazmacafOotnioamide Pobb..................... Hydrazine. m#thy- P063....................... Hydrocyanic acid POM..................... HyOrogen cyanide POM.... ................. Hydrogen pnoepTxde P084...................... laocyerxc acid, methyl eater PO07...................... 3(2MH*oaantena. BHammometnyiv P092...................... Mercury. leeeteto-OKiftenyi- POBS ,, .... Merctay fuKranm (R,T) POifl..................... Methane. orytoaicNoro- Pti2 .... Methane, lavanme- (R) pub .... Methtnempt, tnefitoro- P059...................... 4.7-Methno>iH>idene, 1,4.5,67,6,a-hep. iachiorp-3a,4,77a-tetrehydroP066..................... Methomyt P067 .................... 2-Methytazmdme P066 .................... Methyl hydrazine P064 ..................... Methyl eocyenate POBB..................... 2 Metfwaactomtnie P071...................... Methyl pvatNon PQ72 ................... alM-ftuMhytmeutM P073 ................ . NMKei cerMnyl 0074 .. .. .... Nickel cyanide 0074 ..................... Nicmi(II) orentoe 0073 .. Nienei tetracardonyl oo7s Nicotine end tans P07B....... . Nnnc owe 0077.. . B-Nitroename P07B..................... Nitrogen dioxide P078.................. NnrogenOD Oxide P076..................... Nitrogemiv) oxide 0061....................... Nitrogiyoenne |R) P082....................... N-NH/oeodnneihyiem(ne P0B4..................... N-NaroeomethyNinytBffyne P050.............. ........ 5-Nofborn*ne-2,3^lm#tnanol. 1.4.8,8,7.7. neaacnioro. cyeae uftie Poes.......... .......... OctameffryipyrpphpepftoraflMoe P067...................... Oinemn owde 0067.. ................ Oartajm letroMde POM....................... 7 -OxatMcyclo(2.2.1 ]heptane-2.3- diearboryiic ead P089....................... PeratMcn PC34..................... Phenol, 2-cydohexyt t.B-dmnrd0048............ .......... Phenol, 2.4H)m<trp0047_____ __ ____Phenol. 2 4-dnitr&-6 motfua P020........-............. Phenol. 2,4-d*Wrd-(1<metfiytprod|fl)- POM.... .............. .. Phenol. 2.4.B-tnra(rD-. ammonium see (R) P03B............ Phenyl dchtoroaiwne POM................. .. Phenylmercunc eon POM.................... .. N-PhehyRMoiXM POM...................... Phorst P09S.................. .. Phoagene P096.... .................. pnoephine P(Mi............--..... Phoepnohc aad. eater diethyl, ptwotsienyt 0044 .................... OhoaphorodithKMC acid, O O-dimethyl s. (2-(memyiennoh2-exoetriyij*(ier 0043..................... Phoaphoroliuonc acid, biMi.meinyetnyi}. aatar P094................. Phoapnoroiniow aad. 0.0-*eihyi S- P0B9 . . <etnyithio}meihyi eater PhoepnorothioCi acid. O.C-dieihyl 0-(p-rM- irophenyi) eater 0040 ................... Phoephorotnoic ecu, O-O-Oem/i O- pyre> znyi'eater P097 .................. PneepnoroRhow aotk C.O-dvnemyl CXp- Pt to ............... POTS .............. (<dimetnytminoNeuttonyi)pnenviJeetr oiumoane, tetraethy*PoteeeMti cyanide ' P099 ............... Potaaeum silver cyanide P070 . Propenel,. 2-mthyl-2.(rnetnyitFMOtv ^ [(methyiamina)carbonyi)o>ime Pioi. . Proeanamtriie Oo27..................... Propanemtnie, 3-chloro- "069 ..... .... Propaneiwile. 2-hydrOxy-2 moinyl- 0001...................... i.2.3*Aooenetnoi. trwtral- (Rl 0017.................... 2-Prooenone. 1-cron- o i Q2................... Prooergyi *<ohot P003..................... z-Propnat 9005 ...................... 2-Propdn.i^ PQ67...................... 1.2-Propyiefwnina Pi 02..................... 2-Prepyn.t-ol P008 ...................... 4<PyrKSnamine P075...................... Pyndme. (S>-3^l-metnyt-2-oy'roiidinyiK and salts Pm ................... Pyrophoephoric acM. tetraethyl aster P'03....................... Sannourua Pi Or Silver cyanide 0105...................... Sodium azide 0'06...................... Sadum cyende oio? Svonaum *uhm OiOB..................... Strvehmdwi-10-one, and tens F"018..................... StrychrwdifvlO-one, 2.5-dimethoiry- PiOB...................... Sdychrane and salt* Pii5..................... Sultunc and. thaMwnR) *i P109 ..........^___ Tetraathykjitl xopyruphuaohate Pi lb......... ............. Tedaethyl lead PHI....................... Tatraettiytpyrcpnoapnate Pi 12.... ................. TetrennrwiieUieiie 0062.................. .. Tetraphoepnonc actp, Dexeetnyt anar P113.... ............. .. ThaiBc oxide Pits...... ........... ... ThaMumflll) oxide Pi 14....................... ThaHlumfl) aaianwa P118....!.................. TheWurryi) waa P045...................... Thidfanox P04#._................... ThtomdodKaieantc dtarrxd# Environment Reporter [Sec. 261.331)) 120 HAZARDOUS WASTE CRITERIA S-539 161:1361 H4I1I0CU** w*l NO ^un1Cd POM ........... ThoonaflCI Pile ............. TTkoaomcoreazM P026 -- . ___ Ttamaae. (2-cfaoropharV1 POTT______ _____ TNm, I i if-- i' POM_____ ____ TTioura*. enam*pin .............. Toiagnana PUB.................... TneNpromalhanadXOl P119.................... VtMOe tM. imiienuin UK P120.................... VanadNro pamoaida PiiO.................... venMHprKV) oxm POOi ............ ...... Wirtwm pi 21 ................... Zinc cyvww P122.................... Znc pftMprwM (B.T> (f) The commercial chemical products or manufacturing chemical intermediates, referred to in paragraphs (a), (b). and (d) of this section, are identified as toxic wastes (T) unless otherwise designated and are subject to the small quantity exclusion defined in & 261.5(a) and (f). [Comment: For the convenience of the regulated community, the primary hazardous properties of these materials have been indicated by the Letters T (Toxicity), R (Reactivity). I (Ignitability) and C (Corrosivity). Absence of a letter indicates that the compound is only Listed for toxicity.) These wastes and their corresponding EPA Hazardous Waste Numbers are: Hazardous Warn No. SuMtanca K001...................... Acatauehvde (ii jo34...................... Acataraanyoa. t/cmoro- U187 . Acalamidv M athOnvBP'ir'yi) UOOS...................... AoaiapfMP u-SH iiuoroo / ,i UT12...................... Aeone loo t-tn.'ajro' U144 ................ AC4lK.3t 5 'PBO 581' U2U ................. Acatw tea iraibum<l| 4II Li002 ................... Acaiuna <i> U003...................... Acatomrla (l T) U004...................... Acatppna'vjia UOOS...................... 2-Acai>iaiTiifxji'uofna U006...................... Acatyt cno'U* (C.R.Tj U007........ ............. AciyiaTM*oa U008...................... Acrylic acid H) 1)009 .................... AcryonitrM Ul50..................... Alanma. 3 (D-6is<2.cr'iO'041hyl)ainir0] pha*ivi. iUQ11...................... Amiiro* U012.................... AiMtii'a ii *i U014 ................... Aufamine U01S...................... AxMerm* U010 ................... Azmnot2'.3 jAipyrrohxi 2 aiindoie-4.7- *ona. 6-nminQ-A.i.ii jiTMAocarDonyi) oxyimeity 1-1 ,'B.2.8.aa.Bb-na,ianydftP 8a.meinoiiv*9-matny<' U1S7...................... Banaijacaainiwyiana. ' 2-dPiydr<>-3- U016 main*. .......... 0njlc)icrr1t"* uOie .... 3.4-B#ntae"fl na Ul 17....................Bentai cr.frfla U014 . 8ei(jrtf>rieana U018.................. 1.2'Sanraninracana U094.................... 1.2-aenjar-iracana, 7.1? dimeinyl- U012 .................Banztr'emme (i T) L/C14...................... Benza/iaim/ie 4.4 -oarooon^doyiO'aiN.N- d'mawy- U049 ................. Benzanamwe 4-^nioro 2-matny|. U003............... ....... aaraarwirnna. N.N ttimertiy*-4.pnanyiaz- Hwr90u* 4414 NO SjCfiance H2V00u UII No. SuMWK* U'S8........................ Banzanamne. 4.4 -maihyienecal2-eloro- U?22 Oantwiai'Niia, 2-mawyi. nytfocmonda ui*1 . ifiz CiJIWlw. g^waffiH-i-nmn tMsawftn uoJB aaAMAaaoaho awl * u.<yo-*t*n4. cPiWopnaoyi>.*ipna-hyarp>y, any aatar 0030..................... . Santana. l-bromo-t-pnanoxy- U037...................... Sanzana. cfxoro- 0190....................... i.t-BamanadMarboxylle ad anhydrtda 0026 ................. 1.2-6anzanacarbOye aod. CM2>atfiylhexyi)] Mtar U069................ .. l,2-8anzanadicart)o>n*c acd. ditxrtyi aatar 0086.................. ... 1,2-8anzana<hGboxylic acid. Oiathyl aatar 0102.. ............... 1,2-8anzanadlcart>oiyic acid, <kmattiyt aatar Ui07....................... i^-aamanaatearwiyM aod. dt-n-acy aatar U070....................... Banzana. i.2-dNon> 0071...................... Banzana. l,3-dtcraon> U072... Banzana. i,44#cnton> U0i7... Barwna. (dtehterematry)- U223...................... Banzana. 1.3-dHaoeyanatoniathyl- (R.T) U23&-. Banzana. dtmairy-(l.T) U201... 1,3-BanaanadW U127... Banzana, haiacntoro- U068. Banzana. haxahydr- (i) U18S...................... Banzana. hydroxy- U220... Oaraana. inamyt- U106... Llioe.. Banzana. i-many-1-2.4-dinivoBanzana. l-matftyi-t.S-dwxtro ll203... Banzana. l.2'matnytanattozy-4-a*y<- U141...................... Banzana. 1.2-watny>anadM3zy-4-propanyt- DO90 .................. . Banzana, l,2-matiyanadiO*Y-4-propylU06S .................... Banzana. (1-matryaby). (I) U168...................... Banzana. Niro- (i.T) U1B3... Banzana, panueNoro- U18S...................... Barwana. parmanornwr U020... Banzanaaurtanc acid enwnda (C.fl) U020... Bamanaaurtory chionda (C.R) U207...................... Santana, 1.2.4.5-tatraentoro- 1)023... Banzana, (tncNoromatnyD-fC.n.T) 0234.. . Banzana. I.S.Btanrtro- (H,T) U021 ................... Banzidma U202..................... ' 2-Banzi*otfazolin.3ona, l.l ipomda 0120...................... Banzo(|.k)iHcran 0022.. Banta)pyrna U022____ _______ 3.4-Banzopyrana LM97...................... p-eanroatimona 0023 ................. Sanzotnenionda (C.R.T) 0050 1.2-Banzpnananuvana U065...................... 22 -BMwxana (l.T) 0021..................... (i.1-BienanviM.4'-dtarNna U073................ ...... (1,1'-Bplwryt)-4.4'-a4inna. 3.3`-d>eNors- 0091 (i.r-BnanyiH.4'-aajnna, 3.3-dimadv. oxy- 0095_________ __ (i,i'-Btohany(M.4'-4tainaia. &3`-dMia0y- 0024 ......... ........ Bt8(2<Moroathoxy) mathana 0027 .................. Batf^NoroaopoDyi) atf>ar 024......................BistdimatnynniocarDamoyi) dtauffida 0028 .......... .... .. Biatf-athyWaxytl pnuiNata 0246......--........... Bremina eytmda 0225...................... Bromoiorm 0030 ... .............. 4-Bromcenany* pnanyl athar 0128____ ___ --... 1.3-BoUPana,i1.2,3,,4-naxacn*oro- 0172.. ...... ....... )-Sl4naiNna, N-Outyi-N^xtroao0035...................... ButantK ae>a. 4-(Bw<2-cnkxoatnynarNno) oanaant 0031 .................. i-Suianot <) U1S9...................... 2-SuUnena <1.T> ui80...................... 2-eutanena panW <fl,D 0053.____ _______ 2-Butanat 0074...................... 2-Butana. M-dMMoro- (i.T) 0031-.... ........-__ n-Buryt awnoMri 0136......................- Caeezytc and 0032 .................. Cataum otvomata 0236..................... Caroanae 4O0. atnyi aatar 0178.................. Carbamo and, matrynitroao-, athyt aatar 0178 .................. .. Cartwnada, N^Wyi-N-nttroao- Ui77...... ...............Cartoanada. N-mady-N-ottroao- U219......................Carbanada, traoU097.................... .. Carbamoyl eruonda. dimaoy. 0215..................... Carbonic aod. OithaHiumti) *aH 0158..................... CarbonocMondK add. many aatar (I.T) 0033 .................. Carbon oxydbonda (R.T) 02tt..................... Carbon wracNonoa 0033 -------------- Cartxxy (kjonda (RT) 0034 .... .......Otorw W7M........ .......... CTfortmOw* 1* N1 M1 'MA " I. uw* ............. waomacoaiiaa 0037 .............. . CtaaroOanzana U245.................... 1 -(p-CMdiubwmyf) S mzffwiy t- matiywdai 2 waac aoC 0039.................... 4-CNorwn-orHQl L04t............ ...... )-C7don2.3-apa>prqpana 0042.................... 2 CNoready vay amv 0044___________ CMonXorni 0046________ __ CNoromatfy matry a(har 0048------- --------- o-CNorophanoi 0049.. ....--...... 4-Oitoro-ptoliadlna, IbdrocHorida 0032.................... Oaonac aad. rnnut un 0050.. .__ ___ Crvyaana 0051 ..... .. ........ Craoaota 0052....... ........... Craaoa 0052 ................ Craaytc tod 0053 ........... Cratonawariyoa 0246...... .... Cyanogan bremM U197.......... 1.4- Cydohaaadwn6dtona 0056............ Cyetobzzana (I) 0057...... ...... 0130........... Oydoftaaarana (I) 1 .S-Cmlagantaaana, 1^JA53-Am- eNoro. 0056-..-.... ... U240............ Cyctopnoapnanda A44-C. uttaandaatzw U0S9.......... ... Oaunpmypn U060...._ 0081............. COO DOT 0142............ Oacacf*jioootatiydro-i 3.4-matnanp-2H- 0082............ P|Nto6ytatfl.dl parftan a ona oiaaata 0133_______ oamma (R.T) 0221_______ DOM OWtanoiotaana OtbanztaJtlanOvacana 0063......... .. i.2:9,6-Obanzanbiracznz 0064....*____ ij:7,8-0anzepyrana DfcarstoJJpyrana 0066........ .. i.2-0(brorip-3-04Qrpprdpana 0066......... OMytoMMMta &H2J OcNoroaiy) dBappropyWapraroamaia 0070................. ..... oOicMonpOamna 0071------------------ m-OKHorobamna 0072............ .......... p-OKMorebOTiana U073................. U074 ..................... 1.4- OdMar-2-butana O.T) 0075____________ DKMprpddluprpmaViana 0192...................... 3.5- OcMarp-N-<1.1-dwnady-2-propyiy) uoao............. ...... OieMam oipnanyt dteftoroathana U061..._............... OMKoro dipnanyi tnemorbatnana 0076........ ........... i.t-Oehtoroabyana U079......... .......... i^-OcHartwdyana U02S.................... DtcNoraaffy adw 0081.............. . 2.4-OtcfdorwjNanol 0062............. ...... 2.8-OcNotdpnanai 0240............. ...... 2.40icWoropi*iptyqaoe add. aaR8 wid uoes................. . 1.2-OMhieraeropana ' 0064.................... 1.3-Dtttuaroerawn* 0065............ ...... 1.2:3.1 mapoyii.aana S.T) 0106-............ .... 1,4-Caatryana dazda 0066................. .. h.N-Dtathyfyaana 0067................. .. Q.Qdaay 6 maty dantopnoapnaia 0086.................... Dw*y NMaia 0069.................... OMthyMUbaantfi- - UI46.................... I^Q4yyi>3.8p/li*flrattpn> 0090 ................. OibydroiaatnPa 0091 ................. 3.3'-C4matho,rybariadlna 0092 ................ Dxnavyamna (I) 0093 ................. Qimadniziiwaaicbaniani 0094 ...... 7,tt-Oimattyban(a)anwraoana 0096 3.3'-CNwiagiyaanudbia 0096 ................. aipnajtpaa OxnatrybanzyWpdroaaruiuOa m 0097 ................. oanathytearbamoyt tntonda 0096............. ...... i.i-OMwvynydram 0099.................... i .2-oxnaflynyttaiina 0101 ................. 2.4-OanatfypnaM( 0102 ...-............ Oimavy pfttfiakata 2-20-81 (Sac. 261.33(f)] Published by thE BUREAU OE NATIONAL AFFAIRS. INC WASHINGTON OC 20037 MOD 000016897 139 18T:1882 FEDERAL REGULATIONS Mazvdou* whh No. SuOatanca Hizanjoui watt* no. SuOatano* Haxanloua Waai* No Substance moa................. ,V6im**y udat# U105.................... 2.-0U)oWum UtM.................... 2.6-OMtmoluoM Ut07......... ......... iry phTMM uioa............. ..... 11 ntwn uioa.................... i.a oipnnyinyanana Ulio........... ....... Otpropytamto* (!) U111.................... PINpwpyWWMiWi* U001.................... Effwwl (0 U17 U097 EthanamM, H-athyMI-nlboaPEMm, U-dhramp- U076 EMM, 1.1-dKNtfV- U077 Ethan*. t.l-dcfaoro- Ut 14.................... I.f fton--!ftt*c<hwnw*WulL acM Ut3t___ _______ Ehm. 1 11 TT t h--rrtnrn U024.............. -- Ethan*. i.v-tm*thrt*Mm(wy)lbi*(aehioro- U003.................... EOtanarwtl* <1, T) U117.................... Ethan*.i,t'-oxyp|*- 0) U02S . Ethan*. M'-osytraJa-crtoro- Ut#4 Ethana, pantacNoro- U20a Ethan*. i.i.iJ-tawenmw. ua Ethana, t.t4.2 ta*ctw*- U21*....... ............. EMMMOMtld* U227........... ..... . EMM, I.IJ-MhlpO' U043................... EMna.tNoro- U0*2-----------------Ethan*. i-cMmatnory- U078........... EMna. t.i4cNwo- U07................... Ethana, BaM-tJ-atcNoro- U2I0------ __ Em, t.1.U-taaMor Ui?3------- ---- -- Ethanol 2^<<n*oaa*ww)0- U0O4.................. . EMnon*. 1-pharryt- uoos.................... Ethanoyl cMorid* (CAT) UU2---------------- Eff* aoatata (i) Utta.................... Ethyl acrytaM <l) U2M.--............... E*y eartawta turatian) U039,.__........-- Ethyl 4,4-dtohton>bw>iaata Um--.............. EmyWMtaaMRhiocmanae W4 UM7.................. . Etytan* dtvomkt* uorr----------------- mmamw UtH............ .. EMM* aMi I.T) Ult9.................... EthytaM thwaaa Utl?.................... Ethyt 9tar<l) U070--- ------------- BhtMan* 4kMon*a Uii*.................... EthytutoMnytata on*................... EB* maMnaautlonaia Ut30................... FarMdastmn Ut20._........... . FkOTMN* Ut22............. ...... ForniaMarryfl* U123.................... Formic acid (C.T) y24_________ __ Furan U'25.................... 2-FurancarboxaiO*nyM (I) U147........ .......... 2.S^nnaon* UJ13................ .. Furan. tatranydrfr (I) UI2B___________ FurMMfll u<24............. . Furturan (t> U206................. . D-Gtaopyranoa*, 2-dtasy2{3-mdtfiyi-3-ni- U129.......... ....... Qtt'nd)tatMh|Mi U193............ ....... OuaftdM*, N-n#o*o-N-m*hy1.N'n<txo- U12*................... nairaiWBroOutMaaiw Ui29..._------------ H*uanoicyel0h*un* (gamma war) Ui30.................... H*atntoroci:iup*ni*i>*i LM31---------------- iiaaaoWoioaentw Ui32................. . i ttamonaonan* U243....................HasacMoropropan* U133......... -........ uoao.......... ......... Hytnana. 1.2-aMtfy- U099.................. Hydraan*. l.t-dMavyUOW................... Wydraana. 1.1-dbnaam. ___ ___ Uioa.......Hydraana. 1.2-olphary- U134.................... Hydrefluorle kM (C.T) U134 "ntnoin fhwiQa (T T) U135................... tlydrppl au*da U099.................... Hydroparoada. t-madyt-pharyatiy (h> ui36......... _ Hoitymaaym*rM omoa U1I8 .,.............. MMdiieMMNM U137.......__........ lnaino[t.2.3-oa)pyT*na U24S............. ...... moomathaetn U' 39.................... Iron deatran uuQ................. . laoiKhjit ataahal (i.T> uwi.................... uaaahaa Ui42............. ..... k*pom ui43.................... uaaiocamtn* ut4.................... i*ao aeataia uus.................... L*ao phoaphata U146............ -..... Load aubaoatata U129.................... undm ui 47.................... Maiwc aaimnai Ui4a . UaietehydruM* ui**.. MitonoMiaa ut Muntnian Ui&i... U1S2... Mareurr Mathaorytorwa* E.T) UO02 Uathanarwna. wawatty*- at uo... MathM. bramo- U045..................... Mathana, entoro- (1,7) uoae... U068.. mama M*ewwahcayMathana. Oerorao- U080..................... MaMn*. dtoMoro* U075..................... Mathana. aeNorodMuaro- ms#..................... Mathana. iod Lit t................... Matnanaautfonte aetd. atnyt aatar U2i t................... Mathana. taffachtoro- ui2i ............ .... Maatawa. arttwaroBiaro. uiS3.............. ..... MatnanaMei (t.T U22S.................... m#mm. atiwno- U044................ . Mathana. nertoro- U121.................... Mathana. MtHarottgom- ui23.................. . Mathanote too (C.T) U036.................... 4.7-Mamarwtdan, i J.4.SJ.74E oeu ChWr3*.4.7.7a-t*trahydro- Lit**,------------ tWOMl W Ui5S,_.............. .. MaMpyrtana U134..................UaPtyt ateahot (l) DO29................... MaPtyi Oromtda Uiae .................. 1-Mathytutadtan* (I) U04*___________ Map* t**MKf.T) U158............ .. MaPtyt chtoaoearbonat* (l.T) U229........ ........... MathylehtBrotonn U157.............. ..... 3 MaPtytttictanOyaM UiS6.................... 4,4' Mattytanahlaff laaoruanPna) U132................ .. IZ MaP*anaM(3.4.piOaorophanoO U068.................... MaPtyfna brtyruda UOOO.................... Mathytana chtoMa Ut22................ MaPtyMMOM* utsa.................... Map* *pt katoM (IT) ut#0 . ................. MaP* athyt fcatona paraM* (W.T) 0130.................... Matnyt uiei............ ....... Map* aobutyi kmbm (D U102................ Mathyt maPtaMyMW ff.T) Ut3................... N Math)i If^atrNMroao*tanttn Ui6t................ .. 4-Mat* 2i3amanon* (1) ui4................. ... Mathrhhtwaut U010................. . Mnoyan C U0S9.................... 9.12-NaohthooanoMno. raS^Mt-a-aeotyt- lO((3-tiww-24.E*maoay-aipha-L-tyii' naaopyranooyOopyO-7J.9.lO tatfahyPa. a.a,li-pft^ipiy-i-4WBtho<y- U'64................ . NMhtftatan* U047.............. ..... NaphthtMM. 2-chlon>> Uiaa............... . T.o MaphMtanadtaM U236............ ..... .. 2.7-NaptMhataMdauPorte IM 3.T-t03'9mag*Ht,v Mchawy()-*,*-d*))-tia (awtK9 ammo 4 hydrwry)-.aPaaoPMm uh Ui6.................... 1.4/taphPiaqunon* Ui7.................... i-Mpntnytamo>* uisa.................... 2-Napmnytamna ut97.................... aiprNophptytaaia U16S.................... batt-Naehthytamtna U026.................... 3-NaphPtytaran*. matf*>- N.W42-eofo- Ul9.................... NttroPanaana (1.T) U170.................... p-Mtrophand Ui 71 .................. 2-NKroprapan* (I) ui 72................... N-N*oaodl-n-Outytan*n* u 173................... N-NihoaodliMnatawwta U174 .............. N-NitoaodathytaMta UMI.................... N NPaao N orwytamna ui 76.................... N-Namao N atnyluraa U177.................... N-Nroao-N4na*tytLaa U17#.............. ...... N-Nitroao-N-ntathykiratiana Ui 79...... ............. N.Nwoa<ipioaM>na -- Ui0................... N-Nnroaopyrrondma U181..................... 5-Nrtro-o.toMaM* U193.................. . 1.2-0**tNo*an*. 2.2-do>3* UOM..................... 2H-1.3.2-Oxazac)hQ*pftonn*. 2-(b4<2- cMorp- othyhamnollavahydo-. mida 2. Ui 15................... OMrana (I.T) U041.................... Onran*. 2-(ehJarometnyt)U182.................... PMOertyM U163.................... FamacmaraMnaan* Ui*4 ................. rawtacNcuoatnai# U'65.................... Pantaehinromireoaniona U242.................... PantacMorooMnot U166 U17 1>h*ntaa*na (I) Phanaeaan uiu Fhanot J046 Phanol, 2-cMoro- 0039.................. . Phanol, 4-cNon>3-mathyl- uoei Phanol, 2,4-dlohtao. uc2 utoi Phanot. 2.a^ptfnoroPh*n 2.4-dmeihyb ' Ut70.............. ..... Wtonou 4-mtro- U242 Phanol. pantacMorcv U212 Phanol, 2.3.4>toffaeNoro> U230------ --------- Mtonoi. 2.4.S-tnchKn> U231.................. PhM 2,4,6-tncNoroU137............... . t.lG4i,2-ohor*anoipyrono U149...-------------- Wioaphcnc acid, taod aatt U067......... .......... PhooBhModWuoie aod. nr rutij. s- mathytaatar uiafl.................. . Phoapaoroua autdda (R) Ui90.................... Phthaiic waiydnd* , U191..................... 2-Pcoun* U199.................... PronamWe Ui 94................... 1-Prapanamna (l,T) UltO................... i-Propanamna, N-erooyl- <l) uoea.................... Propana. l.2-dfcro*no-3-ch*Of- u'49........ ftopptaanmo ut71.................. Propana, 2-mtro- (l) U027...--............. Propana, 2.2'o*yda[2-chfP- U193................... 14-Propan* aulton* U23S.................... 1-Propanol, phoaphata (3:1) U12P.................... I-Propanol. 2.3-aoory U140.................... 1-Propanol. 2-mathya (i.T| U002._................... 2-Prop*non* |l| U007.................... 2-Prop*n*mJ* U0*4...................... Propana. 1.3-dicMoroU243................... i-Propan*. i,i.2.3,3.3-n**cMor. U00*.................... 2-Propananrtnt# U152.................... 2-Propanan.tnla, 2-matr*- <l,7) UOM.................... 2-PropancNC acad (l) Ui 13............... . 2-Propano* aod. athyl aatar (l> Ut 19............... . 2-Proparmc aexl 2-metnyl-. atnyt aatar Ui92................... 2-Propanoic aed, 2-mathyt-, motnyt aatar (l.Tl U233.................... propnnie aod. 2-(3.44-tneMeropnano>yV u i4.................... n-propytamma (I.T) U093.................... PrgpylaM aeNonda U19S.................... Pyndin# U<55................... Pyndata. 2-((2-(dknathyiamino>-2-tnanytfr mmol- U179.................... Pyrx*na. haxanydco-NHUuoao- U191 Pyndn#. 2-methyV U164 4(iHt-Pynmnon*. 2.3^hhytPo-9-mathyl2-trwxp- U190................. . Pyrrole. tetrahydro-N-nrtroaoU200.................... Raaarpma U201.................... Raaonanot U202.................... SacchMvt and aatta U203.................... Safrol# U204........ .......... Satamoua acid U204.... ..... .. ....... Salarmm aoxlda U20S............ ... Sallium (PauHda (R.T) uois................... L-Sadna. Mynacarata (aatar) U233........ .. ........ Sihwi UO90.................... 4.4'-Saib*n*dlol, aieha.aipna'-di*thyk U209.................... Straptawjtocm U'3S.................... Suftur hydrid* ui03................... Suitude acid, dm*try aatar ui99.................... Suttur ohoaehM* <R) U20S.................... Sudia aatanda (R.T) U232.................... 2.4,9-T U207.................... i ,2.4>Tatracworooanoana U2M--......-.... 1.1,14-TatrMNafoaMn* U209,............. .. i.1.24-T*trachtor*th*n* U2iQ.................... TatrachtanaittylaM Environmant Rpporipr MCI) 000016898 (Sac. 261^3(f)l 140 HAZARDOUS WASTE CRITERIA 539 161:1863 Haiardova Wun to. SuMtanc* U212................... . 2.3.4.4-TtracNoroptMno< " U2t3.............. .... . Tatranyttoturan ) U2U.................. . ThaflwmU) acatata U21S............. ..... . ThalUum(i) cartxmata U214.............. . . ThaWum(I) cNenM uai7._................ ThaNMnOI mtrata U21S................... . TNoacatanwta U1S3................... . Thiomainanot <*,T) uzn............... . . Tttouraa U244...,,.............. . Tfwam U220...-.............. . Tokiana U221................... ToiwanMamma U223................... . Toluana araocyanata (P.T) U222.................. . O-Totutdina hydroehlonaa U011................... . iH-i^.a-TnaMt-S-amna U2J6................... . l,i.l.Tncn>oaatfw U22T................... . i,t,2-TneniorMiwoa U226................... . TrtcNoroatnana U224..................... TinJiloroatrvtaoa UI21......... .. . Tnc**o>o"iono*fcicofl>atf>ato U230................... . 2,4.S-Tnch*0fuc*anot U231............... .... . 2.4,S-TMcNorocftanoi U232........... ....... . 2.48-Tnctaowaneayacatic acid U234 .................. . aym-Tnmvooanzana (R.T) UIS2................... . 1.3,S-Tnoana, 2,,6-inmathY*- U235.................. . Tna.3-awomopropyi> phoapnata U234................... . Trypan Mua U237................... . UraieS. Sttotf-cMoromatfryllammoJ- U237_................ . UracS muatart UM3 . Vinyl cMonda U239................... . Xytana (1) U200................... . Yonmtiarvifrcarfioavlc aod. 11.174- maffwxy-18-[(3.4.S.tnmatnoxy baraoytloiyK matftyl aataf. Appendix I--Representative Sampling Methods The methods and equipment used for sampling waste materials will vary with the form and consistency of the waste materials to be sampled. Samples collected using the sampling protocols listed below, for sampling waste with properties similar to the indicated materials, will be considered by the Agency to be representative of the waste. Extremely viscous liquid--ASTM Standard D140-70 Crushed or powdered material-- ASTM Standard D346-75 Soil or rock-like material--ASTM Standard D420-69 Soil like material--ASTM Standard 01452-65 Fly Ash-like material--ASTM Standard D2234-78 (ASTM Standards are available from ASTM. 1918 Race St.. Philadelphia. PA 19103) Containerized liquid wastes--"COLIWASA" described in "Test Methods for the Evaluation of Solid Waste. Physical/ Chemical Methods." ' U.S. Environmental Protection Agency. Office of Solid Waste. Washington. D.C. 20480. |Copies may be obtained from Solid Waste Information. U.S. Environmental Protection Agency. 26 W. 5 Clair St., Cincinnati, Ohio 45266) Liquid waste in pits, ponds, lagoons, and similar reservoirs.--"Pond Sampler" described in "Test Methods for the Evaluation of Solid Waste. Physical/ Chemical Method*." 1 This manual also contains additional information on application of these protocols. 'These methods are slso described in "Samplers and Sampling Procedures for Hatardoua Waste Streams." EPA 000/2-80-014. [anuary I960. Appendix II-- EP Toxicity Teat Procedure A. Extraction Procedure (EP) 1. A representative sample of the waste to be tested (minimum sizd 100 grams) should be obtained using the methods specified in Appendix I or any other methods capable of yielding a representative sample within the meaning of Part 260. [For detailed guidance on conducting the various aspects of the EP see "Test Methods for the Evaluation of Solid Waste, Physical/ Chemical Methods." SW-646, U.S. Environmental Protection Agency Office of Solid Waste. Washington. D.C. 20460.l] 2. The sample should be separated into its component liquid and solid phases using the method described in "Separation Procedure" below. If the solid residue 1 obtained using this method totals less than 0.5% of the original weight of the waste, the residue can be discarded and the operator should treat the liquid phase as the extract and proceed immediately to Step a. 3. The solid material obtained from the Separation Procedure should be 1 Coplai may be obtained from Solid Waste information. U.S. Environmental Protection Agency. 24 W. St. Clair Street. Cincinnati. Ohio 45208. 'The percent solids is determined by drying the filter pad si SO* C until it reaches constant weight and then calculating the percent aolids using the following equation: (watgtii ot pea + som> - (tare wmgm ot pad) x too % aoSda mutt wwgm ot aampta evaluated for its particle size. If the solid material has a surface area per gram of material equal to. or greater than. 3.1 cm2 or passes through a 9.5 mm (0.375 inch) standard sieve, the operator should proceed to Step 4. If the surface area is smaller or the partiole size larger than specified above, the solid material should be prepared for extraction by crushing, cutting or grinding the material so that it passes through a 9.5 mm (0.375 inch] sieve or, if the material is in a single piece, by subjecting the material to the "Structural Integrity Procedure" described below. 4. The solid material obtained in Step 3 should he weighed and placed in an extractor with 16 times its weight of deionized water. Do not allow the material to dry prior to weighing. Foi purposes of this test, an acceptable extractor is one which will impart sufficient agitation to the mixture to not only prevent stratification of the sample and extraction fluid but also insure that all sample surfaces are continously brought into contact with well mixed extraction fluid. 5. After the soiid material and deionized water are placed in the extractor, the operator should begin agitation and measure the pH of the solution in the extractor. If the pH is greater than 5.0, the pH of the solution should be decreased to 5.0 0.2 by adding 0.5 N acetic acid. !f the pH is equal to or less than 5.0, no acetic acid should be added. The pH of the solution should be monitored, as described below, during the course of the extraction and if the pH rises above 5.2. 0.5N acetic acid should be added to bring the pH down to 5.0 : 0.2. However, in no event shall the aggregate amount of acid added to the solution exceed 4 ml of acid per gram of solid. The mixture should be agitated for 24 hours and maintained at 20*-40` C (68*-- 104* F) during this time. It is recommended that the operator monitor and adjust the pH during the course of the extraction with a deuce such as the Type 45-A pH Controller manufactured by Chemtrix, Inc., Hillsboro. Oregon 97123 or its equivalent, in conjunction with a metering pump and reservoir of 0.5N acetic acid. If such a system is not available, the following manual procedure shall be employed: 2-20-81 (Appandix It] Published bv THE BUREAU OF NATIONAL AFFAIRS INC. WASHINGTON DC 20037 MOD 000016899 Ut 161:1864 [a] A pH meter should be calibrated in accordance with the manufacturer s specifications. |b) The pH of the solution should be checked and. if necessary. 0.5N acetic acid should be manually added to the extractor until the pH reaches 5.0 2: 0.2. The pH of the solution should be adjusted at 15, 30 and 60 minute intervals, moving to the next longer interval if the pH does not have to be adjusted more than 0.5N pH units. [cl The adjustment procedure should be continued for at least 6 hours. [d] If at the end of the 24-hour extraction period, (he pH of the solution is not below 5.2 and the maximum amount of acid (4 ml per gram of solids 1 has noi been added, the pH should be adjusted to 5.0 . 0.2 and (he extraction continued for an additional four hours, during which ihe pH should be adjusted at one hour intervals. 6. At the end of the 24 hour extraction period, deionized water should be added to the extractor in an amount determined by the following equation: V = (20)(W) -- 16(W) -- A V = ml deionized water to be added W- weight in grams of solid charged to extractor A= ml of 0.5N acetic acid added during extraction 7. The material in the extractor should be separated into its component liquid and solid phases as described under "Separation Procedure." 8. The liquids resulting from Steps 2 and 7 should be combined. This combined liquid (or the waste itself if it has leas than Vt percent solids, as noted in Step 2) is the extract and should be analyzed for the presence of any of the contaminants specified in Table I of 261.24 using the Analytical Procedures designated below. Separation Procedure Equipment: A filter holder, designed for filtration media having a nominal pore size of 0.45 micrometers and capable of applying a 5 3 kg/cm1 (75 psi) hydrostatic pressure to the solution being filtered shall be used. For mixtures containing nonabaorptive solids, where separation can be affected without imposing a 5.3 kg/cm: pressure differential, vacuum filters employing a FEDERAL REGULATIONS 0.45 micrometers filter media can be used. (For further guidance on filtration equipment or procedures see 'Test Methods for Evaluating Solid Waste. Physical/Chemical Methods.") Procedure: 3 (i) Following manufacturer's directions, the filter unit should be assembled with a filter bed consisting of a 0.45 micrometer filter membrane. For difficult or slow to filter mixtures a prefilter bed consisting of the following prefilters in increasing pore size (0.65 micrometer membrane, fine glass fiber prefiher. and coarse glass fiber prefilter} can be used. (iil The waste should be poured into the filtration unit. (iii) The reservoir should be slowly pressurized until liquid begins to flow from the filtrate outlet at which point the pressure in the filter should be immediately lowered to 10-15 psig. Filtration should be continued until liquid flow ceases. (iv i The pressure should be in creased stepwise in 10 psi increments to 75 psig and filtration continued until flow ceases or the pressurizing gas begins to exit from the filtrate outlet. <v) The filter unit should be de pressurized. the solid material removed and weighed and then transferred to the extraction apparatus, or. in the case of final filtration prior to analysis, discarded. Do not allow the material retained on the filter pad to dry prior to weighing. (vi) The liquid phase should be stored at 4*C for subsequent use in Step 6. B. Structural Integrity Procedure Equipment: A Structural Integrity Tester having a 3.18 cm (1.25 in.) diameter hammer weighing 0.33 kg (0.73 lbs.) and having a free fall of 15.24 cm (6 in.} shall be used. This device is available from Associated Design and Manufacturing Company, Alexandria. VA.. 22314. as Part No. 125, or it may be fabricated to meet the specifications shown in Figure 1. Procedure: 1. The sample holder should be filled with the material to be tested. If the sample of waste is a large monolithic block, a^tortion should be cut from the block having the dimensions of a 3.3 cm (1.3 in.) dtameter x 7.1 cm (2.8 in.) cylinder. Fora fixated waste, samples may be cast in the form of a 3-3 cm (1.3 jn.) diameter x 7.1 cm (2.8 in.) cylinder for purposes of conducting this test. In such cases, the waste may be allowed to cure for 30 days prior to further testing. 2. The sample nolder should be placed into the Structural Integrity Tester, then the hammer should be raised to its maximum height and dropped. This should be repeated fifteen times. 3. The material should be removed from the sample holder, weighed, and transferred to the extraction apparatus for extraction. Analytical Procedures for Analyzing Extract Contaminants [Revised by 45 FR 72041. October 30. 1980} 1 This procedure is intended to result in separa tion o( the "tree" liquid portion of the waste from any solid matter having a particle size 0 45 urn. If the sample will not filter, various other separation techniques can he used to aid in the fillrauon. As described above, pressure filtration is employed to speed up the filtration pro cess This does not alter the nature of the separa tion. If liquid does not separate during fillrauon. the waste can be centrifuged. If separation occurs during centrifugation the liquid poruon (centri fugate) is filtered through the 0 45 am filter prior to becoming mixed with the liquid portion of the waste obtained from ths initial filtration Any material that will not pass through the filter after centrifugation u considered a solid and is ex tracted. The test methods for analyzing the extract are as follows: (1) For arsenic, barium, cadmium, chromium, lead, mercury, selenium. Bilver. endrin, lindane, methoxychlor, toxaphane. 2,4-D(2.4-dichlorophenoxyacetic acid) or 2,4,5-TP (2.4,5-lrlchlorophenoxypropionic acid): "Test Methods for the Evaluation of Solid Waste. Phyaical/Chemical Methods.*' (SW-446), U.S. Environmental Protection Agency, Office of Solid Waste, Washington, D.C. 20460. (2)(Reserved) For all analysee, the methods of standard addition shall be used for quantification of species concentration. Environment Reporter 000016900 HOD {Appendix II] M2 HAZARDOUS WASTE CRITERIA S-539 161:1865 ELASTOMERIC SAMPLE HOLDER FABRICATED OF MATERIAL FIRM ENOUGH TO SUPPORT THE SAMPLE Figure 1 COMPACTION TESTER 2-20-81 Pubushtfl by Th BUREAU OF NATIONAL AFFAIRS iNC WASHINGTON OC 20037 [Appendix 111 MCD 000016901 H3 161:1866 Appendix III--Chemical Analysis Test Methods Tables 1.2 and 3 specify the appropriate analytical procedures, described in "Test Methods for Evaluating Solid Waste" (SW-646), which should be used in determining whether the waste in question contains a given toxic constituent. Table 1 identifies the analytical class and the approved measurement techniques for each organic chemical listed in Appendix VII. Table 2 identifies the corresponding methods for the inorganic FEDERAL REGULATIONS species. Table 3 identifies the specific sample preparation and measurement instrument introduction techniques which may be suitable for both the organic and inorganic species as well as the matrices of concern. Prior to final selection of the analytical method the operator should consult the specific method descriptions in SW-646 for additional guidance on which of the approved methods should be employed for a specific waste analysis situation. TaMs 1.--Analytical Charactmmtkx ot Organic Compound Samplahandtag CHaa/ftacaen NaruGC OC/US Acreiaai................................ AcryWiMa.. Acrymwaa. Oamana..... .............. SarauuetwsMW.......... Barattalpyrana.................... SanaoaicMortda...'.. ............. Baivyl cMoflPa.................... BanMbWuoanMna............ Btat?-4grMSloeyfnaPMna| Oatf tWauaffnQ--w...... S^fWnwMBtiroriiSMSa*.-- CarPori taee^aortpa.....--.... CNorotorm................ -..... CNoremafm...... .......... .... 2-CMorephanoi Cwyaana .... Craowta..... CraaoM).... Ciaayw nil..................... OcWcmO--anart).............. OtNoroamanaW...... ...... ftcnonjmatfwia........... .... On*iompwanoY acaOc acw OcnotmqpaM............ 2,*OmaSiypnanol......... .. Onraantana...................... wawi gndrtn...... Ethyl amar. Ftnatt*hyda Forme too .. MptMHor... Haxacfseretesadiana Hoamoroamana.... UaMc arvtydrtda. Ma>i)l atfiyl nawoa . Maihyi aotaityl kalona NapMwana......... ...... Napthoqunona........... Niaabanzana...... .... A.*Wropnanol................ PanMartyda inmar of .. VotaMa................................ .. voiasia................................. . VoWOa............... ............... .. VotaMa................................. Eiaaettua/w*................... .. SlOtHPLO... .. >a0MMa/6N................... ... 80(HPLC)... . **ettfc*#/8N.................. .......,,.................. . voMMa or bMoaeta/BN... . ExtactaMa/SN................... .. S.10 (HPIQ... . VottSa................................. . Votaata................................ . Vcwaa................................. . veiaea... ,, ............. ......... . VaWSa.............. ................... . Exvae>abia/BN.................. ................... . EitracttMa/SN.................... .................... ...... . Emcnon BN.................... ..................... . vaMSa................................. ........_......... .. . voww................................. .................. ...... . VoMM --.............................. . ...........,,..... . . EabaotMa/BN.... . Emeaata/BN .. . ferSacMMa/BW... 8.10 (HPIO... .......... . . Eancuma/A....... ........... ............. . . 6<aauwiFi/A.... . 6mtnm/BN.... . WMSi...................... -..................... ,,.......... . YoMM..... . ExmcHBH/A...................... . EamMt/w ExvacuttaM........................ ExVactattfa/SN..................... ExiraetaWa/A........................ . Exnetawa/BN..................... . EMMiaMarP....................... YowHa......... ....................... ............. ............ VataMa .............................. ExmeMta/BN..................... .......................... . Eamctatta/P...................... EmactatwreN................. . EnactaBta/BN.................... ExaaeiatM/BN..................... ExVactaM/SN .................. ........... .... ........ ExPaetatta/P...................... .. ............... ,,........ ExnctaMa/SN..................... ........ .............. VCMMa .. . ErtaclaOta/BN................... .. 8.32fHPtQ.. YotaWa.................................. votnia........ ........................ acta<*a/BN..................... EmaetaHa/BN..................... ExVaetaWa/BN..................... ExvactaM'A........................ Vetawa.................................. 824 824 8.24 8.24 825 82S 626 824 626 926 62* 624 8.24 8.24 8.24 826 ejB 8.29 924 8.24 124 824 8 25 8 25 18.2S 826 6.25 626 5.24 824 8.25 825 8.25 8.25 8.25 82S 8.25 824 0.24 8.29 8.25 B.25 625 8.2$ 825 825 825 8.24 6.25 6.25 826 82S 8.25 624 6.24 Corwansonal QC OatacB 6.03 8.01 1.03 8.02 810 8.10 8.12 SOI 8.12 8.10 8.01 8.01 8.01 8.01 8.01 6.00 8.08 60S SOI 8.01 aoe 601 6.01 8.04 8.10 8.10 8.04 6.06 SOI 6.02 6.12 8.01 8.01 6.40 6.12 8.04 60S 8.04 8.00 8.00 6.01 6.02 801 6.05 600 8.12 6.12 8.12 8.12 6.08 60S 8.01 801 802 6.01 6.02 8.10 808 6.08 8.04 801 NSO FlO NSO PlO FlO FID ECO HSD ECO FlO MSO HSO M3D HSO HSO HSO ECO HSO HSO HSO PlO HSO HSO FlO, ECO FID ECO FlO. ECO FlO. ECO HSO P ECO HSO HSO HSO ECO FID. ECO FID. ECO FlO. ECO FlO. ECO HSO F FlO FlO FiO HSO ECO ECO ECO ECO HSD ECO. FID FlO FlO FlO FID FlO FlO ECO. FlO FlO ECO. FID ECO. FID FlO Environment Raportar MCD Of!00l690a {Appendix III) 144 HAZARDOUS WASTE CRITERIA TaMe t.--Analyacai Charactensbcs of Organic Chemical*--Continued Compound Svw handing (KN'IiHW Haaauremant tachnujua* Non-GC___ matnoda Corwantonai QC/MS GC Oatactor Pemecworoeneno*..................... . Eatreeu&ie/A....................................... ECO PhttWK annyme..................... .. ExtredaOM/BN.................................... .......... 6.25 TaeocWorcbanaanatal--............ .... EiVacnHa/BN........... .... .................... ........... Volt ............ .... Vdatta.................................................. ............ .... ExtactaWaM.............................. ........ ............ Toluano................ .... Vdatta.................................................. ........... Tgfcjonadwnw.......................... ExbacuUa/BN.................................... ........... Tgfeiana OWocyenaie(e)............. Ejnrocuwa/nonaquaoua..................... ........... 6.25 8.2* 8.24 6.24 S 24 8.25 8.25 SOB 8.22 a.oa a.oe 8.06 8.0* 6.12 8.01 6.01 804 8.02 8.06 ECO, FIO FPO ECO. FIO ECO, FIO ECO. FID ECO. FID ECO HSO HSO ECO PIO FIO TrttJboroflucrgnadan*............... .... VoMHa.................................................. .......... TrleMorephanoda). 2.4,5-TF (S6*w)... .... Exbadabia/A.................................... .......... .... EWdaUa/A....................................... ........... rncNoraprepan*. .... VoMBa................................................. .......... Vinyl dWda............................. .... VoMW.................................................. ............ Vlniddana craonda .... VoMB*.................................................. ............ Xylene.......................................... .... VoMBa.................................................. ............ 8.24 8.25 8.25 8.24 8.24 8.24 8.24 8.01 804 8.40 8.01 8.01 6.01 802 HSO HSO HSO HSO HSO HSO PIO ' Analyw fcr (ftwrtlwna and oarbaada; H Iti-- ara cmant m a rabobatwaan H I and 5 1. {new* thouid bm corwd ECO EtacTon capfcn OatatOT FID - Flam* tonttabon WUCtOr FPO - Fltma ghdomaew ditector: HSO -= HMda apwMe awcwr HPLC - High primw liquid chromoiogrbpny; NSO NnrogaA-apbCrte oatactor. PtO - PhouNoroanon da- TaMe 1--Analytical Charactamdca of inorganic Spec** Spadaa Samp* handeig daw Anttmomr......................................... DlgeWon............ Arwme............................................ Hydtde................ Barium............................................ Dtgeebon............. Cadnwm......................................... Ogeebon............. Chromium....................................... Dtgawcn............. CyvbOw................... ..................... Hyttroiyaa........... lead................................................ Ogeeapn............. Mammy........................................... Cold Vapor........ Meboi.............................................. Pigwaon............ SoWVum........................................ Hydtde dgaaacr SWar............................................... Qiginon............ HaaauraiwfH tadwgua Atomic beorWon-iumace/fteme.................. Atomic abeotbbon-fleme................................. Atoribc abaorbtioiMiimace/flame.................. Atomic abaorMon-lumaea/NaiTia ............... Atomic abaomwn-iumaoa/nama.................. Atome abaoniBoo-apacvoacapy.................... Atomic abaorMon-tumacb/llame.................. Atomc atwormon........................................... Atome aoaomo<>**urnaca/aamo.................. Atomic abaorbOorwtumaca/liame.................. Atomic 4b*orbbon-tum*ce/Kame ............... MWwd number a SO 8.51 a.52 8 S3 8.54 e.SS a.96 a S7 8 56 6.56 6.60 TaM* 3.--Sample Praparton/Sampia Introduction handing aaw ffltyanal cftaraflanaaci oI waata1 Fhad Paata Solid vpitta............. Purpaand vap. Purga and rap liaadwwa. Daaci naadapaca... yacbon. SamMoMBW Ovact Shaba out.. and nonvoMM. Shan* out... Shaw out Soxmat somcaaon inorganic........ Diract mpcBon. Dgaaban..... . 0>oa*twn..... QigaaBon. rTfonOI........ .. Hydrtda........ . Hydrtda Procedure and Method NumberfsJ Digestion--See appropriate procedure for element of interest. Direct injection--*.80 Headipsee--8.82 Hydride--See appropriate procedure for element of interest. Purge & Trap--8.83 Shake out--8.84 Sonicat ion--A 85 ' For purpoam oI PM Table. fluid ratara to readily pouraMa uquda. which may or may not contain auapandad pared** Paata Mia matanala. whA# fluid m the aanaa ot HowaOiMy. can ba etougnt ot M bamg Ihmotropic or plaatc m nalura. a.g pamta. Sow matanala era Stosa wastaa wtach can ba han ded without a comanar (l a., can ba p4ed up without appra- cfltole eogng). 161:1867 3-27-81 [Appendix HI] Publ-shert bv THE BUREAU OF NATIONAL AFFAIRS INC WASHINGTON DC 20037 lit 161:1868 Appendix Vll.--3*&s for Usung Hazardous wastes | Njipenilik Ml amended hv 4S bR 47XVV Inis |h. 1 'KO. revised hv 4 < 1 N 74y(). SdvomllOl IJ. 1 >)K(I: 4i> i'r 4(. 17, .1 it n li ;i rv f ft. 1 *J.K 11 FEDERAL REGULATIONS Appendix VII--Baals for Listing Hazardous Waata EPA hazardous ra1i Nn Hazardous constituent* for which kited F001 ............... Telrechkwoethyfene, methylene chloride tncNoroetityiene. 1.1.1-tnchioroetnane. carton tetraertonda. cfkonziaiM ikioro- cartons. F002.................- TetreeNoroettiyMne, meffi^ene chonde. tnemoroeinytene, vt .1-tncioroiriane, Chlorobenzene, I.1.2-tneM0(O-1.2.2 vt- huoroethane. ortho-diehtorobenzane, MNorofborometnane. POOS.................... NA. FOOD.................... Cresoti and creeykc aod, n/irobenzene F005.................... Toluene, methyl ethyl ketone, carton OtUfida, isobutanol. pynAne. F006.................... Cadnsum. heiavateni chromium. nickel. cyanide (complexed) FOOT................... Cyarede (aaitai, FOOfl........ ........... Cyarade (aaitai. Foot.................... Cyanoa (aana). FOtO ................. CyanaM (salts). FOtt ................... Cyanide (sens) F02........ .......... Cyemde (eompmetn. FOU .................. Cyarsde (corrvMied). Pots.........,,........ Cyanide (tans). F0I9.................. _ Hexavalent chromium, cyanide (com plied). <001............. -- Pentadkorcphenoi. emend. 2-chlorophenoi. P-tfUoro-m-cresot 2,4-4meytoh*rrvl, 2,4-dnrtropnerwt. tncNoroonendl, teradkoroonends. 2.4-dmiboehenM, ere. soeoie, ervysene, naphthalene, fluoranth ene. benzo(b)fluorntMne. bemde)pyTem. ndeno(l.2,3-ed)pyrene, bendOanotraeene. ooenzlajanthacene. canaphthaiene K002.................... Hexavalent ovomajm, mm KOOO______ __ _ Hexavalent dvommm. lead K0O4 ... Hesavalant chromxjm K0O9..................-- Hesavaiem chromium. *M. K006.................... Henvaient ehrerrusn. K007 .. Cymde {complied). heiavaienf chrona- i*n. K006................... Heaavaient chromaim. K009.................... Okordorm. Icrmauehyde. methylene chid nde, methyl enksnoe. paraldehyde. formic aod KO10.................... Chiordorm. lormaidehvde. methylene che>- nce. methyl cdonoe. pi'aMenyde. formic acad, chioroacataioanyda KO 11 ........ ...... Acrytorvinta, aeaionwe. hydrocyanic acid. KOI3 .. Hydrocyarue end- ecrynrMnle. eoeKmitrlle. Kill4 AeatorMiiM. acrylartmle KO IS ................. Benzyl cniunde. cnioiobeniana. toluene, benzotnchionoe. KOlfl................... Heaedkorateozene. neradkorotutadiene. evton tetrachloride, hexachtoroeinane. oamNoroethyMne <017.................... EpMtkorohydnn. UHomethere (Mchoromathyl) ether and da (2-chMr- oethyt) ethers), tncxeoropropana. detkd* oprdpanda. Appsndix VII--Basis for UMng Hazardous Waste--Continued EPA hazardous wtm No Hazardous constituents lor wtveh listed KOifl.................... 1.2-dicniofuethane. tncMoroethyiene, hexscfUoroOuiadene. heaectkarabenxene. <019................... ElhjMna OKSkpnde. l.i.l-lrlcfkoroetnene. i.i ,2-thchioroemana, letradkoitethanaa |t.l.2.2-MVacfkoroeihene and 1.1.1.2-tetracdoroethana). tncikoroathyiana. te- taefiloroethyiene. carton tetrachloride, efkorotorm. yvyyt ctkonda. vmysoena efkortoa. K020................... Ethylene dichionde. 1,1.1-McNoraetnane. i.t.2-*ichioroetnana, tatrachkeoamanea (1.1.2.2-tetrecrtorbethene and 1,1,1.2-tonchoroetriana), trichloroethylene. tetfadkoroethyiena. carton tetraetkonde. dkordorm, vinyl ctkonda. vtnyDdana ctuewat. K021............ ..... Anomony, carton tatfacfkortda. chloroform. K022................ . Phend. tars (poiycydtc aromaBe hydrocar bons). <023.................. Phthaac armydnda. mdeic annydnda. K024.................. Rithakc anhydno*. t.A-naprwnodumone. K02S........... ..... Meta-dewoOentene. 2.4-dtmtrotduona. K026................. Paraldehyde, pyndinee. 2-picdlne. K027.................. Toluene dweoeyanaia. tduana-2, 4-damme. K026.......... ....... I.t.l-tncikcroatnane, vinyl cnionde. <029................. 1 J-dKMoroaoiana, i.i.i-tncnkxoathana. vinyl chlonde. vinylldena chlonda, cNoro- torm. <030.................. HaMcmorobenzena. hexachkjroOutadene. heiecdoroemane. 1,1,1.2-ietrecrko- roathana, t.i.S.S-tatratfkofoathana, at* ytene dKMonde. K09i.................. Araane. <032__ _______ Haucfkorocyclopantadwna. K033................... HaeadkorocydopanUdana. K034___ ______ HanachtorocydopantadMna. K02S......... ........ Creoeote. chryyene. naphthalene, fluor anthene tanzo(b) tiuorenmena. taruoialpyrana. indano(i.2.3-cd) pyrene, banzdalanttiraeane. dMnzo(a>wncana. acanaphthalana. K038 ......- Toluene, pnoepnorodursoK and phoaphoro-Vadc aod aatara. K0T7................. Toiuana. phoapnorodtihido and pnoaphoro-ViiO'c aod ealers. K03S.................. Phorate, lomnaidehytM. pnoaphorodUtkdc and phoaphorotfuoic acid aatara. K039.................. PhoapnoroaPkdc and phoaphorottuaw aod was K040.................... Pnarata. lormaMtfiyde. phaaphdodkhiae and phoepnorothioio acid aatara. K04t............ ..... Toxaphene. K042...... ............ HenacfkaroOeniene. ortho-diehlorooan- zena. K0492.4-ddkorotkianoi. 2,-diehlgrophed. 2.4.a-Wdkoophand. K044_____ ____ N.A. Ka.___ ______ N.A. K04S............ ... Lead. Appondix Vll Basis for Listing Hazardous Waste --Continued EPA hazardous waste No. Hazardous conethuents <t when Dated *047.................... NA K04S.................... HeaevaMni Chromium, lead. K049.................. Hasavalent chromwen. MM. K050........-........... Hexavlant chromium. KOSt.................... Hexavalent chromaim. lead K052.._............... Lead. *060........... Cyarkda, napthalane, phenokc compounda. name. *061......-............ HenavalecH chromium, lead, eadnvum. <062................... Hesavalant chromium. Mad. K064.................... Lead, cadmium. KOflJ.................... Lead, cadmium. <060.................... Lead, cadmum. <047 ..... ............ Laed, Cadmium. <066.................... Lead, cadmum. <069..................... Hesavalant chromium, MM, cadmium. <07i ................... Mercury. <073 .................... CMorotorm. carton tetrachloride, hexacholroathana. tnchioroethana. letracmoro- sthyMns, dictkoroathyMne, l,l.2J-letradkoroethena. <063.................... Amhn*. diphenylamina. mtoberaana. pharv ytanadumna. K0S4.................... Araanc. KOSS.................... Benzene. dcNorobehzenei, K066.............. .. <097.................... zenea. tavacMorotanzanaa. pentecMorobeuene. hexachioroOanzene, penzyl cfkohda. LaM. hexavalent chromium. Phenol, naphthalene. <093.................... Phthatic anhydride, maleic anhydride. <094.................... PhtTwnc anhydnda. K09S.................... 1.1.2-tnchloroethene. i.l.t J tetractkoroaih- ana. l,t,2.2-tetraetkoroethane. <096....... ........ l.2-didkoroainna, i.i.l-tnchloroetnane. 1.1.2-tneNoroelhna. <097.................... Chiordane. fteptsehlor. <099.................... Tosaphana. <099 <100 kioi <102 . 2.4-dctHoropnanoi.2.4,6-ircMoropheroi. . Hesavalant chtomum. mm. cadmum. . Arsamc, . Arsanc. <103.................... Arahna. nilrobenzane. phenylenediamina. <104 . Aniline, benzene, dipherryiamme, nitroberv xene. phsnyienediemine K10S.................... Benzene, manocniorctenzene. dicnloro- benzenes. 2.4.S-triciiioropnenoi <106................... Mercury. N A.--vreste is hazardous Because h lain me teal (or tha characlenanc of >enita0iliiy, corroanniy. or reaewny. Environment Reporter MCD 000016904 [Appendix Vll] 'a2 HAZARDOUS WASTE CRITERIA S-539 161:1869 Vppendix VIII--Hazardous Constituents ^Appendix Vlll amended by 45 FR 47833. July 16, 1980: 45 FR 74890. November 12, 1980; 45 FR 78541, November 25. 1980) Aoelaldehvdp Acetonitrile 3- (lpha-Acetonyll>onzyl|-4-hyilrixyi;uumHnn unit suits 2-Acetylaminofluorene Acetyl chloride 1 - Acety 1-2-thiourea Acrolein Acrylamide Acrylonitrile Aflaloxins Aldnn Allyl alcohol Aluminum phosphide 4- Aminobiphenyl 6-Amino-1.ta.2.e.au.ab-hexahydro-8- (hydroxymethylJ-8a-methoxy-5melhylcarbamate azirino(2'.3':3.4) pyrrolo(1.2-a)indole-4.7-dione (ester) (Mitomycin C) 5- (Aminomethyl)-3-isoxazoiol 4-Aminopyndine Amilrole Aniline Antimony and compounds. N.O.S.1 Aramite Arsenic and compounds. N.O.S. Arsenic acid Arsenic pentoxide Arsenic Irioxlde Aurumini! AzuHorino Dunum and compounds, N.O.S. Barium cyanide Benz(e|acridine Benz(a)anthracene Benzene Benzenearsonic acid Benzcnethiol Benzidine Denzoja janlhracene Benzofbjfluoranthene Benzo[j]fluoranthene Benzo|a|pyrene Benzoquinone and isomers (Added by 45 FR 74890, November 12. 1980] Ocnzotrichloride Benzyl chloride Beryllium and compounds. N.O.S. Bis(2-chloroethoxy|methane Bis(2-chloroelhyl) ether N,N-Bis(2-chloroeihyl)-2-naphthy]amine Bis(2-chloroisopropyl) ether Bis(chloromethyl) ether 8is|2-elhylhexyl) phthalate Bromoaceione Bromomeihune 4-Hrumophenyl phenyl ether ' lh<- alilirevirtlion N O S signifies thone member* of (he general data 'not otherwise specified" by name in ihia haling. Brucine Z-Butenone peroxide Butyl benzyl phthalate 2-sec-Butyl-4.6-dinitrophenoI (DNBP) Cadmium and compounds. N.O.S. Culcium chromate Calcium cyanide Carbon disulfide Chlorambucil Chlordane (alpha and gamma isomers) Chlorinated benzenes, N.O.S. Chlorinated ethane. N.O.S. Chlorinaled fluorocarbons (Added by 45 FR 74890. November 12. 1980] Chlorinated naphthalene. N O.5. Chlorinated phenol. N.O.S. Chloroucetaldehyde Chloroalkyl others p-Chloroaniline Chlorobenzene Chlorobenzilate l-(p-Chlorobenzoyl)-5-methoxy-2- methylindole-3-acetic acid p-Chloro-m-cresol 1- Chloro-2.3-epoxybutane 2- Chloroethyl vinyl ether Chloroform Chloromethane Chloromethyl methyl ether 2-Chloronaphthalene 2- Chlorophenol 1- (o-Chloropheny I (thiourea 3- Chloropropionitrile alphn-Chlorolnluene Chromium and compounds, N.O.S. Chrysene Citrus red No 2 Cicil Furs | Ndik'il in 4S | R 74890. November 12. 1980) Copper cyanide Creosote C resol (Added by 45 FR 74890, November 12, 198Q) Crcsylic acid (Added by 45 FR 74890, November 12, 1980) Crotonaldehyde Cyanides (soluble salts and complexes). N.O.S. Cyanogen Cyanogen bromide Cyanogen chloride Cycasin 2- Cyclohexyl-4.6-dinitrophenol Cyclophosphamide Daunomycin ODD DDE DDT Diallate Dibenz)a.h]acndine Dibenz|a.t|acridine !)ibenz|a,h|anthracene(Dibenzo(a,h| anthracene) 7H-Dibenzo(c.g]carbazola Dibenzo| a, e (pyrene Dibenzo(a,h]pyrene Dibenzo(a,i]pyrene 1.2- Dibromo-3-chloropropane 1.2- Dibromoethane Dibromomethane Di-n-butyl phthalate Dichlorobenzene. N.O.S. 3.3'-Dichlorobenzidine 1.1 -Uichlorue thane 1.2- Dlchloroe thane irana-l,2-Dichioroethane Dichloroethytene. N.O.S. 1.1- Dichloroethylene Dichloromethane 2.4- Dichlorophenol 2,6-Dichlorophenol 2.4- Dichloropbenoxyacetic acid (2,4-D) Dichloropropane Dichlorophenylarstne 1.2- Dichloropropane Dichloropropanol. N.O.S. Dichloropropene. N.O.S. 1.3- Dichloropropene Dieldrin Diepoxybutane Diethyiarsine 0.0-Diethyl-S-(2-ethylthiojethyl ester of phosphorothioic acid l,2-Diethylhydrazine 0.0-Diethyl-S-melhylester phoephorodithioic acid 0,0-Diethylphosphoric acid. 0*p-mtrophenyl ester Diethyl phthalate 0,0-Diethyl-0*(2-pyrazinyl)phophorolhioate Diethylstilbestrol Dlhydrosafrole 3.4- Dihydroxyalpha-(methylamlnoJ-methyl benzyl alcohol Di-isopropylfluorophosphate (DFP) Dimethoate 3,3'-Dimethoxybenzidine p-Dimethylammoazobenzene 7.12-Dimethylbenz(a (anthracene 3,3'Dimethylbenztaine Dimethylcarbamoyl chloride 1.1- Dimethylhydrazine 1.2- Dimethylhydrazine 3.3- Dimethyl-l-(methy)thio)-2-butanone-0- ((methylamino) carbonyl)oxime Dimethylnitrosoamme alpha.alpha-Dimethylphenethylamme 2.4- Dimethylphenoi Dimethyl phthalate Dimethyl sulfate Dinitrobenzene. N.O.S. 4.6- Dinitro-o-cresol and salts 2.4- Dinitrophenol 2.4- Dinitrotoluene 2.6- Dinitrotoluene Di-n-octyl phthalate 1.4- Dioxane Diphenylamme 1.2-Diphcnylhydrazme Di-n-propylnitrosamine Disulfoton 2.4- Dithlobiuret Endosulfan Endrin and metabolites 2-20-01 Publisher! by THE BUREAU OF NATIONAL AFFAIRS INC WASHINGTON 0C 20037 [Appendix VIII] 147 MCD 000016905 161:1870 FEDERAL REGULATIONS Epichlorohydnn Ethyl carbamate (urethan) (Added by 45 FR 74890. November 12. 19801 Ethyl cyanide EthylencOisdiihincnrhHmate |EBDC) Ethylcnemnne Ethylene oxide Fthylc'iiethiouroa Ethyl mnlhaneRulfiinaie Fluoriiiithirne Fluorine 2Fluoronceiumide Fluoroncetic acid, sodium null Formaldehyde Glycidylaldehyde Halomethane. N-O.S. Heptachlor Heptachlor epoxide (alpha, beta, and gamma isomers) Hexachlorobenzenc Hexachlorobutadiene Hexachlorocyclohexane (all isomers) Hexachlorocyclopentadiene Hexachloroeihane 1.2.3.4.l0.10-Hexschloro-l,4.4a.5,8.8ahexabydro-l,4;5.8-endo.endodimethanonaphthalene Hexachlorophene Hexachloropropene Hexaethyl tetraphoaphate Hydrazine Hydrocyanic acid Hydrofluoric acid [Added by 45 FR 74890, November 12. 1980) Hydrogen sulfide Indeno(l,2.3-c.d)pyrene lodomelhane Isocymuc acid, methyl eater Iron Dcxtrun (Added by 45 FR 74890. November 12. 1980) ho hutvI udsohol (Added'by 45 FR 78544. November 25. 1980] Isosafrole Kepane Lasiocarpine Lead <inii compounds. N O.S 1- eud ucetulc Lead phosphate Lead subacetate Maleic anhydride Malonomlrile Melphalan Mercury and compounds. N.O.S. Methapyrilene Methomyl Methoxychlor [Added by 45 FR 74890. November 12. 1980) 2- Methylaziridine 3- Methylcholanthrene 4,4'-Methylene-bis-(2-chloroamline) Methyl ethyl ketone (MEK) Methyl hydrazine 2-Methyliaclonitril* Methyl methacrylate Methyl methanesullonale 2 -Methyl-2-(mcthylthu> Jpropionuldehyde-o- (methylcurbonyl) oxime N-Mt:lhv! N'-nitru N-mirosuRuunidini* Methyl puruthion Methylthiouracil Mustard gas Naphthalene 1.4 Naphthoquinone 1 Napnthylamme 2N.tphihvlummo 1 - N.iph l hy 1-2-thiourea Nickel and cnmpoumls. N.O.S. Nickel carbonyl Nickel cyanide Nicotine and suits Nitric oxide p-Nilroamlmc Nitrobenzene Nitrogen dioxide Nitrogen mustard and hydrochloride salt Nitrogen mustard N-oxide and hydrochloride suit Nitrogen peroxide Nitrogen telroxidc Nitroglycerine 4-Nitrophonol 4- Nitroqumohne-l-oxide Nitrosamine. N.O.S. N-Nitrosodi-N-butyiamine N-Nitrosodiethanolamine N-Nitrosodiethylamine N-NUraaodimethylamine N-Nitrosodi-N-propylamine N-Nitroso-N-ethyluree N-Nitrosomethylethylamine N-Nitroso-N-methylurea N-Nitroso-N-methylurethane N-Nitrosomethylvinyiamine N-Nitroaomorpholine N-Nitrusonomicotinc N-Nitrosopiporidine N-Nilrnsopyrrobdlno N-Niirosogn rcosme 5- Nitro-o-toluidine Qctamethylpyrophosphoramvde Osmium tetroxide 7-OxabicycIo(2.2.1]heptane-2.3-dicarboxylic acid Parathion Pentachlorobenzene Pentachloroethune Pentuchioromtrobenxene (PCNB) Pentacholorophenol Phenacetm Phenol Phenylenediamme Phenyl dichloroarsine Phenylmercury acetate N-Phenylthiourea 2-Picoline (Added bv 45 FR 74890m November 12. 1980) Phosgene Phosphine Phosphorothioic acid. O.O-dimethyl ester. O- ester with N,N-dimethyl benzene sulfonamide Phthfllic acid esters. N.O.S. Phlhalic anhydride Polychlorinated biphenyl, N O.S. Potassium cyanide Potassium silver cyanide Pronamide 1,3-Propane suilone Propionunle Propylthiouracil 2-Propyn-i-ol Pryidine Reserpine Recorcinul (Added by 45 FR 74890. November t ? lo0| Saccharin Safrole Seleniuus acid Selenium and compounds. N.O.S. Selenium sulfide Selenoureu Silver and compounds. N.O.S. Silver cyanide Sodium cyanide Streptozotocin Strontium sulfide Strychnine and salts 1.2.4.5- Telrachlorobenzene 2.3,7,8 Telruchlorodibcnzo-p-dioxin (TCDD) Tetrachluroetharu!. N.O.S. 1.1.1.2- Tetrachloroethane 1.1.2.2- Tetrachloroethane Tetrachloroethene (Tetrachloroethylene) Tetrachloromelhane 2.3.4.6- 1 etrachlorophenol Tetraethyldithiopyrophosphate Tetraethyl lead Tetraethylpyrophosphate Thallium and compounds. N.O.S. Thallic oxide Thallium (I) acetate Thallium (l) carbonate Thallium (!) chloride Thallium |1| nitrate Thallium selenite Thallium (I) sulfate Thioacetamide Thiosemicarbazide Thiourea Thiuram Toluene Toluene diamine o-Toluidine hydrochloride Tolylene diisocyanate Toxaphene Trlbromomethene 1.2.4- Trichlorobenzene 1,1.1 -Trichloroethane 1.1.2- Trichloroethane Trichloroethene (Trichloroethylene) Trichloromethanethiol 2.4.5- Trichlorophenol 2.4.6- Trichlorophenoi 2.4.5- TrichIorophenox.yacetic acid (2.4.S-T) 2.4.5- Trichlorophenoxypropiomc acid (2.4.S- TP) (Silvex) Trichloropropane. N.O.S, 1.2.3- Trichloropropane 0.0.0-Triethyl phosphorothioata Trinitrobenzene Tria(1-azrtdinyl)phosphine sulfide Tris^.a-dibromopropyl) phosphate Trypan blue Uracil mustard Vanadic acid, ammonium salt Vanadium pentoxide (dust) Vinyl chloride Vinylidene chloride Zinc cyanide Zinc phosphide Environment Reporter [Appendix VIII) 143 AICQ 0000/005. fl ERA LIST OF OVER 450 CHEMICALS REQUIRED TO REPORT UNDER SDr'ERFUND The following draft list, now being reviewed by the Office of Management A Budget, comprises over 4S0 chemical substances for which EPA would require reporting under sections 103(Kb) of Superfund, covering hazardous releases. Over IX hazardous constituents, originally Included in the list by EPA, have C ~ been dropped (Inside EPA, March 20, p4). Besides the list that follows, EPA also proposes to require reporting of Resource Conservation A Re covery Act hazardous wastes, by industry and chemicals contained in the waste, considered reportable be* cause they exhibit at least one of the hazardous waste characteristics listed under RCRA section 3X1: ignitability, corrosivity, reactivity, and toxicity. This list will appear in next week's issue of Inside EPA. The following shows the chemicals required for reporting, alphabetically. The letter at the end of each listing corresponds to the minimum quantity released for which reporting is required, as follows: X 1 lb.; A - 10 lbs.; B * IX lbs.; C * 1,000 lbs.; D * 5,OX lbs. Chemicals and minimum amounts for which Superfund reporting is required. Material-Quantity Aoetaldehyde-C Ammonium dtrate, debaaoO Arsenic UichJorido-D 4-Bromophenyl phenyl ether-X Acenaphthylene* X Ammonium fluobonte-D Anenic trichloridwD Butyl acetate-D Acenaphthenr-X Ammonium HuoridoD Arsenic trioxida-D Butyl benzyl phthalatoX Acetic acid-C Ammonium hydroxidaC Anenir trisulfid^D n-Buty] phthalata-B Acetic inhvdride-C Ammonium oxalatoD Asbestoa-X Butylamine-C Acetone cyanohydrm-C Ammonium stlicofluondwC Barium cyanide-A Butyric add-D Acetyl bromide-D Ammonium suifamatwD Benz [ajanthracena-X CadmiuflaX Acetyl cWonde*D Ammonium ulfidO'D BanzawaC Cadmium acetata-B Acrokin-X Ammonium sulfltoD Benztdine-X Cadmium bromida-B Acrylonitrile*!) Adipic acidD Aldrin-X Ammonium tartrate-D Ammonium thJOcyanata-D Ammonium thiotulfatD Benzo IblfluoranthenwX Benzo [k| fluoranthene-X Benzojshi) perylenwX Cadmium chlorida-B Calcium anetute-C Calcium arsanitwC Ally! alcohol- B Amyl acetatwC Banzo{alpyrenX Calcium cerbtda-D Ally! chloride*C AniknaC Benzoic Add-D Calcium chromate*C Aluminum aulfat^D Anthracene-X BtnzoniuiJa-C Calcium cyanide-A Ammoraa-B Antimony-X Benzoyl chloride-C Caldum dodecylbenzem Ammonium acetatD Antimony pentachlorfd^C Benzyl ehloride-B eulfonata-C Ammonium benzoaie-D Antimony potassium uxtrata-C Berylliunv-X Caldum hypochloiitwB Ammonium bicarbonite-D Antimony tribromidwC Beryllium chioride-D CaptamA Ammonium tuchromna-C Antimony trichloride*C Beryllium fluonde-D Carbaryl-B 4 Ammonium bifluonda-D Antimony trifluorid-C Ammonium bisulftte-D Antimony trioxida-D Beryllium nitrate-D Carbofuran-A Bis(2*chloroethoxy) methana-X Carbon disulfida-D Ammonium cubamatwD Anenio-X Bia(2*chloioethyl) ether-X Carbon tatrachloridwD Ammonium carbonataD Arsenic actd*X Bis (2-chlorouopjopyD ether-X Carbon tetrachloridwD Ammonium chiorid*D Arsenic disulfida-D Bromomethane-X Qilordane-X Ammonium chromata-C Arsenic pentoxidwD Bis (2-ethylhexyl) phthalata-X ChtoaM*A INSIDE E.P.A. - March 27,1981 9 ----- t Chtorobenzene B ChlorodibromomeihaneX pChlorenvcresoVX Chloroe thane X 2-Chloroethyl vinyl ether-X Chloroform-D Chlofomethane-X Chloromethyl methyl ether-X Chloronaphthilene (all uomenVX 2-ChloronaphthalcneX OilorophenoFX 2- ChIorophenol-X 4-Chlorophen) 1 phenyl eiher-X Chlorosulfoiue acid-C Chlorpyrifos-X ChromiuieX Chromic acetateC Chromic add-C Chromic sulfateC Chromoui chlorideC Chrypcne-X Cobaltoui bromide-C Cobaltous formate-C Cobaltous sulfamateC Copper-X Copper cvanideX CoumaphovA CresoFC CrotonildehydeB Cupric aeetatc-B Cupric acetoarseniteB Cupric chiondc-A Cupric nitrateB Cupnc oxalate- B Cupnc aulfate-A Cupnc ruitate ammonmed-B Cupric tartrate-B Cyanide-X Cyanogen chloride- A CydohexaneC 3- Cyclohe\)K,6-dmitrophenol-X 2. 4-D Aod-B 2,4-D Esters-8 DDD-X DDT-X DDE-X Diazinon-X Dibenz | a.h ] anthraoene (Dibenzola.hlamhraceneVX Dibenzo (a.el pyrene-X Dibenzo|a,h| pyrene-X Dibenzo|a,ij pyrene-X Dibromomethaiw-X Dv-n-butyl phthalateB Dicamba-C DichlobenihC Dichlone-X Dichlorobenzene (all isomersVB Dichlorobenzidine (alt isomersFX 3.3'-Dichloroben2idmeX Dichlorobromomeihane-X Dichioroethane (all isomers>-X 1.1-Dichloroethane-X 1.2- Dichloroethane- X Dichloroethylene uil isomersV-D 1.1-DichloroethyleneD 1.2- DichloroethyleneD Diehloromethane-X Dichloronaphthalene (all kaomers>X Dichlorophenol (all isomersVX 2,4-Dichlorophenoi-X 2,6-DichlorophenoyX Dichloropropane (all uomersy-D Dichloropropene Dichloropropane mixtureD Dichloropropene(i) (all bomershD 1,3-DichloropropeneD 2,2-Dichloropropionic add-D Dichlorvot-A Dieldrin-X DiepoxybutaneX DiethylamineC DimethylamineC DiethylarnneX Diethyl phthalateX 7,12Dimethylbenz|a] anthraceneX Dinu nitrosamifieX 2,*DunethylphenoFC Dimethyl phthalateX Dinitrobenzene (all LaomersKC 4,6-Dinitreo-cretol-X Dinitropheno! (all isomersFC Dinitxotoluene (all iiomersfC 2,4-DinitrotolueneC 2,6-DimtrotolueneC Di-rv-octyl phthalateX DFepropylnitroumineX Diquat-C Ditulfoton-X Diuron-B Dodecylbenzenenilfonic add-C Endosulfan (all UomertFX Eniotulfan sulfateX Endnn and metaboUteeX EipchiorohydriihC EthioivA Ethyl benzene>-C Ethyl cyanideX EthylenediamineC Ethylene dibromideC Ethylene dichlorideD EDTA-D Ferric ammonium atrate-C Ferric ammonium oxalateC Ferric chloride-C Ferric fiuorideB Ferric nitreteC Ferric sulfateC Ferrous ammonium sulfateC Ferrous chlorideB Ferrous aulfate-C Fluoran ihene-X Fluorene-X FormaldehydeC Formic add-D Fumaric add-D FurfuriMT CuthiorvX Hepuchlor-X Heptachlor epoxide-X HtxachlorobenzeneX HexachlorobutadieneX Hexachlorocyctohexane (all isomenhX HexachlorocyclopentadieneX Haxachloioethane-X Hcxachlorophene-X Hydrochloric- aadD (Hydrogen chlorideO Hydrofluoric add-D (Hydrogen fluoride) Hydrocyanic abdA (Hydrogen chloride) Hydrosulfuric add-B (Hydrogen sulfide) lndeno(1.2,3-cd)pyreneX lodomethane-X lsophorone-X IsopreneC laopropanolamine dodecyl- benzencsulfonateC Kelthane-D KeponeX Lead-X Lead acetiteD Lead anenaieD Lead chlorideD Lead fluoborateD Lead fluondeC Lead iodideD Lead nitreteD Lead photphate-X Lead stearateD Lead nibacetateX Lead sulfateD Lead sulfide-D Lead thiocyanateD Lindane-X Lithium chromateC Malathion-A Maleic add-D Maleic anhydrideD MercaptodimethueB Mercuric cyanideX Mercuric nitnteA 10 Mercuric uiifiie A Mercuric thiocyinato-A Mercurous nitrate-A Mprcury-X Mcthoxyehlor-X Methyl mercaptan-B Methyl methacryUteD Methyl parathion-B Mevinphot-X Mexacarbate-C MonoethylamineC M onome thy lamineC Naled-A NaphthaleneD Napththenic acid-B Nickel-X Nickel ammonium sulfste-D Nickel chloride-D Nickel carbonyl-X Nickel cyanide-X Nickel hydroxide-C Nickel nitrateD Nickel sulfateD Nitric add-C NitrobenzeneC Nitrogen dioxide-C NitrophenoJ (aU isomen)-C 2-NitrophenoFC 4-NitrophenoFC MNitrosodi-n-butytamineX N-NitrosodiethinolimineX N-Nitrosodiethylamino-X N-NitrosodimethylamineX N-Nitrosodiphenylamine-X N-Nitrosodi-n-propylanuno-X N-Nitrosomethylethylamine-X N-Nitroiomethylvinylamine-X NitrotolueneC OctachloronaphthateneX Piriformaldehyde-C Ptrithion-X PemachJorobenxeneX Pentachloroe thane-X PenuchlorophenoFA PhenanthreneX Phenol-C Phenyl dichloroarsineX Phenylmercury acetateX PhosgeneD Phosphoric add-D PhocphorueX Phosphorus oxychloride-D Phosphorus pentasulfideB Phosphorus trichloride-D Polychlorinated biphenyl(s)-A Potenturn anenaie-C Potaasum araenito-C Potassium bichromate-C Potaasum chromateC Potassium eyarudeA Potassium hydroxide-C Poussum permanganate-B Potassium silver cyanide-X PtopargiteA Propionic aeid-D Propionic anhydride-D Propykne Oxide-D Pyrene-X Pyrethnn>C Cfulnoline-C Radionuclide -X Rasordno^C Setenioui aad-X Selenium-X Selenium oxide-C Selenium sulfidoX SUver-X Silver cyanide-X Silver nitrate-X Sodium-C Sodium anenatoC Sodium arsenite-C Sodium bichjromatC Sodium btfluoride-D Sodium bisulfite-D Sodium chromate^ Sodhtm cyanide-A Sodium dodecylbenzenc wlfoaateC Sodium fhioride-D Sodium hydrosulfide-D Sodium hydroxide^: Sodium hypocruorite-B Sodium mcihylatfrC Sodium nitrite-B Sodium phosphate, dibesto-D Sodium phosphate, tribano-D Sodium selenitic Strontium chromate-C Strychnine and aaiteA Styrene-C Sulfuric add-C Sulfur monochtonde-C 2.4.5- T add-B 2.4.5- T amineeB 2.4.5- T esiereB 2.4,M saltvB 2.4.5- TP acid-B 2.4.5- TP add erters-B Tetrachlorobenrcne- X 1.2.4.5- Tetrachlorobeiene-X 2,3,7,8-Tetrachlorodjbenzop. dioxin-X Tetrachloroethme (all isomers)-X 1,1,1,2-Te trachloroe thane-X 1,1,2,2,-Tetrachloroethane-X Tetrachloroethene (TetrachloroethylenehX Tetrichloromethane-D Tetrachlorophenol (aU isomenhX 2.3.4.6- Tetrachlorophenoi-X TDE-X Tetraethyl kad-B Tetraethyl pytophoaphate-B Thallium-X ThaUic oxidfrX Thalbum (I) acetate-X Thallium (I) carbonateX Thalbum (I) chloride-X Thallium (!) nitrate-X Thallium (I) seknite-X Thalbum (I) sulfate-C Toluen^C Toxaphene-X Tribromomethane-X Trichlorobenzene (all uomert)-X 1.2.4- TrichlorobenzenX TrichlorfomC Trichloroethane (all isomersVX 1.1.1-Trichloroc thane-X 1.1.2- TrichioroethaneX TrichloroethyleneC Trichloropheno) (all laomersVA 2.4.5-Trichiorophenol-A 2.4,Trich!orop henoi- a Triethanolamine dodecylbenzenesulfonate-C Triethylamine-D Trimethy lamineC Uranyl acetateD Uranyl nitrateD Vanadium pentoxideC Vanadyl sulfateC Vinyl accuteC Vinyl chlorideX Vuiylidene chlorideD XyieneC XyknoFC Zino-X Zinc acetateC Zinc ammonium chlorideD Zinc borateC Zinc bromideD Zinc carbonateC Zinc chlorideD Zinc cyamdeA Zinc fhiorideC Zinc formateC Zinc hydrocutfiteC Zinc mtrateD Zinc phenobulfonateD Zinc phoaphideC Zinc slicofluorideD Zinc sulfateC Zirconium nitrateD Zirconium potaasum fluondeD Zirconium sulfateD Zirconium tetrachlorideD INSIDE C^JL -March 27,1981 MCCD 0000 ,y00 EPA'S LIST OP HAZABC S WAS! tS auzwew. w .r The following list of Rnourc* Conscnmtion A Rdcovtry Act (RCRA) htzaiOoui waittt, now under review by the Office of Management A Budget (OMB), mey be Aibjtct to reportini requirement! under sections i 03(a) end (b) of Superfund when released K quantities of at least one pound. The wastes, are considered hazardous bocaum they exhibit at least one of the hazardous waste characteristics Usted under RCRA section 3001: ignittbility, corro*vity, reactivity, and toxidty. (Last eeek'i Inside EPA - March 27, p 9 - reported thoac chemicals for which re* leases in specified amounts would be included.) Although several of the hazardous wastes in the following lilt may also be included in EPA's propoeed list of chemical substances (Inside EPA. March 27, p9K the reportable quantities may differ from Ust to Bet. When a hazardous material occurs on both lists, "the nature of the material prior to" the release determines which re* portable quantity is applicable, according to EPA's draft notification requirement, also under review by OMB (In* ride EPA, March 27, p 1). For example, the release of 50 pounds of a chemical product which has a reportable quantity of 100 pounds is not subject to reporting requirements under section (a) and (b) if "after the release the substance becomes a hazardous watte," the draft notification requirement says. However, "a subsequent spill of one pound or more of that hazardous waste is considered a reportable event," according to the draft notice. The following lists hazardous wastes by industry ("nonspecific sources"); the reportable quantity is one pound for all. The letter at the end of each section indicates the hazardous quality: I * ignitabiUty, C corrosiv ity. R reactivity, and T * toxicity. Huardoua wrote from nonspecific sources Gunk The following spent halogensted toNeots used in demesne: tetfacMoroetjiyifnc. wchloroeihykne. methylene emend. 1,1, l-tnchiereethsm. cmboa tetrachloride, and chlorinated fluorocarbons. and sludge* from the lecovery of them aetvenu in degreasing operations (T> The following meat hatogensced setvean. tetnchloraethytone, chlorobenzene. 1.1. 2-crtcMofwJ. 2. J-trtfluoroathane. urthodichlOfofevrueiM. and tnchloroAuoromethsne; and the lull bottom ftotn the mcovary of them solvents <T) The following .pent non-hakmenated solvents: xylene, eas tern. ethyl aritite. ethyl benzene, ethyl ethet. methyi bo butyl ketone, obutyl alcohol cyclohexanone, end methanol; and Che 10U bottoms from the rocovury of these solvents (1) The folioavis spent non-halogeanted utvenis: emoti and cmylic acid. and nitrobenzene; end the sUO bottoms from the recovery of them sohronti (T) The following spent non-hsloaenated solvents: toluene, meth yl ethyl ketone, carbon disulfide, isobutanot, and pyridine; snd the mil bottoms from the recovery of them solvents (l, T> Wastewater treatment shsdps from aiectropUtinf operations except from the following proceesee: (1) sulfuric arid anodis ing of aluminum: (2) tin plating on carbon stoel; O) Zinc plating (mgregated beat) on carbon steel; (4) aluminum or zinc-aluminum plating on carbon steel: (5) ckMung/stripping associated with tin, zinc snd aluminum piaring on carbon steel; snd (b) chemical etching and milling of aluminum fT) Wutcwatcr tieetment iludges from the chemical conwrwon coating of aluminum fT) Spent cyanide pitting hgth solutions from electroplating op erations (except for precious metals electroplating spent cyanide plating bath solutions |R. T) Hating bath sludges from the bottom of plating baths from electroplating operations where cyanides are ud in the pro earn (except for praaoiu meials eketroptatihg plating bath sludges (ft. T) Spent itnpping and cleanme bath solutions from ekcvopteiing operations where cyanides are used In the process (ea cept for predous im tab electroplating spent stripping and denning oath solutions (R, T) Quenching bath sludge from ofl baths from metal heat tree* ing operations where cyanides ate used in the procem (except for pieooui metals heat-tieattng quenching bath sludges (R, T) Soent eyarude solutions from salt bath pot ckMing from mm tal heat treating operationsfeaceptfor ptedoui metakbaat treating cyanide sohitions from salt hath pot daanbig) f^U T) Quenching wastewater treatment sludges from metal heat treating operations wham cyanides am used in the proem (esccpt for previous mauls heat tmting quenching was* water treatment dodges) <T) Spent cyanide bath toiuuora from mineral metals recovery operations (R, T) Wood Ptmervetioo bottom mdiment tiudge from the tteatment of wastewaters from wood preserving prooeaeet that urn creosote and/or pentachlorophenol (T) Inorronk Hgneott Wastewater treatment tiudge from the production of dironm yellow and orange pigmenu fT) Wastewater treatment tiudge from the production of moiyk date orange pigments IT) Wastewater treatment sludge from the prodocoon of zinc yellow pigments (T) Wmtewater treatment tiudge from the production of chrome gmen pigments <T) Wastewater treatment tiudge from the production of chrome oxide green pigments (anhydrous and hydrated fT) Wastewater treatment tiadge from the production of iron blue pigments (T) Oven residue from the production of chrome oxide green pig ments CT) Qegmic Outtictii Distillation bottoms from the production of acetaldehyde from ethylene (T) * Distinction side cutrfrom the production of acetaldehyde from ethykne (T) Botiom siieam from the wastewatet smpper in the produc tion of acrylonimk (R> bottom stream from the acetonitrik column in the produc tion of acfylonitrik (R.T) bottoms from the acetonitrik purification column m the production of acrylonitrile (T) Still bottoraa from the distillation of benzyl chloride IT) Heavy ends or dkoflabon rendusi from the product!on of carbon tetrachloride IT) Heavy ends istil bottoms) from the purification column m the production of epichloeobydrin (T) Heavy enri from the fractionation cetumn in ethyl chlonde production (D Heavy ends from the dktiOetion ofethykne JidUoride ia ctftr* knt dkhloride production (T) Heavy ends from the distilsdoe of vinyl chloride ia vinyl chloride monomer production IT) Aqueous spent antimony catalyst wane from ftnotomethanm praduetten (T) DktiDitton botiom ten from the praductiBe of pbewol/acatooa from cumene (T) DktHUtloe Hght ends Horn (he production of phthatic anhyd ride from naphthalene (T) INSIDE E-FA- - Afff 3,Ittl f OOOOl^06 MCD Dtsiftoflrm l^tt cods from toe production of pktonBc atop* Mil fro* oribwayiene CD OMlattw bottom from toe piodoction of phtoaftc ankydrido ftom octhmajrbn* <T> DWBt(-- kotlom fno dN pwtortta of aioowAMaa Ip At miration of banana (T) ut^np ma ttoh from toe production of methyl ethyl pyrid- Gratftfur Mediation ittidum from lotoene dfeocymw piodactina (h. T) tjrti catbyat from the hydrocfclorinaior reactor to toe produm gM of 1.1.l-tricMosoathnne CD Vm from tor product itivara (tripper to toe peodorton of 1.1. |.uiclilroethane CD DMlation bottoms from the piodoction of 1.1, l<tricMoro etiM*m Heavy rods from the heavy ends column from toe production af 1.1. Mrichloroethane (T) Cohifw bottoms or heavy ends from the eomMned production of tfichloroeihylrac and pcrchloecothylone CD SOtflilKMi bottoms from anfltoe protection (T> Pima ivOdurs from aniline extracooa from toe production ofaniline (Tl Combined wasirwtter streams psaantad from aitrobaniena/ anikne production (D Distillation or fractionation eoiumn bonome from the produc oen of chlorobenienes CD Separated aqueous stream from (he reactor production wmto bn step in the production of chloicbtoion-- CD iaorpnir Oeniab Irtnr purification muds from ths mnreury mil promts in chtonne production, where mpnramly propunflad brine is not uacdm Chlorinated hydrocarbon. wte from toe purification step of the diaphragm cell procem uring graphite anodes to chlorine production CT> Wastewater treatment ilodpe from toe nwreury ceil process in chloruie production <T) Byproduct sails fenerared in the production of MSMA and moodylie acid CD Wmtcwater tiestmrnt dudge from toe production of dtior* dine (Tl W'astewater and scrub waltr from the cNottoation of cydopan* tatoenr m the production of tolordane CD rater solito from the nitration of haaaddomeycloponudtong to the production of cMordant CD Vacuum stripper dnehtrae from tin eMordana chlorinetor to the production of chlordana CD Wmtcwater treatment dodges prmnmd to too production of atomic CD ita bottoma from toluena mdnmation dbtflatioe to too pro duction of dtiutfoten CD Waatewster ueatment budges from the production of dtoutfm ton CD Wactewatrr from toe omMng and itripping of phonm production (T) FOtvr cake from toe filtration of djetoylphaiphcrcHthiek atod m the production of phonm (D t from dm production of Waotawamr aoacaumt dudge from too produetioo of taso phone CD Untmaaed prarum wmscwater ton toe prediction of team phono CD i oe dtotiBatton retiduot from the Iinterim of mOMhlorobontfno to the production ti2.4,5>T(T) im from toe production of L 4-0 Untnaaad wggaewtmr from the production of 14-0 <D Wastewater titotraent dwdges from the mooufoebiriog ni piooctong of eaplotims tA) Spent carbon from toe tiootmont of oaatrsnter rnntdatog cxplotivoa (A) Wmtcwater tmetmmit tiudges from the masnifactitring. for* mutation and loading of land baaed initiating compound! CD Flak/rad water from TVT cpomtiansCRI Pstrte--Roteteg Diaaohwd air flotation (DAF) float from the petroleum icflntog iadustry (D Stop oil cmtdtiee totids from the petroleum mflittog industry CD Hoet exdianger bundto denting dudpa from the petroleum wfbdng industry CD API separator tiudgs from too petroleum refining mdintry CD Tank bottoms fleeted) from ths patrolaum fencing iodowry CD Emsamon control dust/riutee from the pnranry production of stool in electric furnaces CD Spent pickle liquor from stool (bushing operations (C. D Secondary Lend Fmisnnn control dutt/dudgr from secondary itad tmeiong CT) Wua leeching solution from aad leaching of enuaion control dust/dudgr from secondary lead tmeiong FT) Votorinnry Wunssns*^ Wastewater tresiraem budges federated dunng toe production of mtennary pharmaceubcob from arsentc or organo-arsenic compounds CT) Dietilation tar mtidues from the distillation of intone-based compounds to the production of vewrinary pharmaceuticals from anraic or ocpnoaneaic compounds CD hotidue from thauam of activated carbon for dscotoritation to toa production of mtartnaryphamiscouticals from inane or ntfsnn nmoif compounds CT) ttParmiMm Sclvsot washos and budges, caustic wishos and budget, or wstor washes and budges from deankig tubs and aquipmest umd In the formulation of ink from pigmenm. driers, sospa, and stabihaeti coauSning chromium and lead CD "a Ammonia idi tone budge from coking operations CD Potantor tank tar budgs from cotong operations CD MCD 000016909 It